a. Project title “The Authentication of Sacral Artefacts for Sustaining The Communitarian Viability” b. Acronym PATRIPICTc. The Project’s abstract

The main goal of the project “The Authentication of Sacral Artefacts for Sustaining The Communitarian Viability”

(PATRIPICT) is the providing an innovative service of authentication, studying, evaluation and investigation of sacral artefacts by using an integrated system of modern methods on the bases of the methodology of study and preserving or restoring sacral artefacts. We tackle as the main effect an increasing of the patrimonial value of these artefacts, as well as, an increasing of the cultural touristy interest.

We are going to use within the integrated system the following methods: FTIR, RAMAN, UV-VIS, EDAX, RMN, DSC, DTG, raze-X, SEM, AFM, XRF, radiography, biological methods both for the wood support and for the polychrome sheets. The artefacts of this project are icons on wood support dating from the period of 1500-1600 years and are located in Targoviste – Stelea Church Romania.

d. The general objectives and their future results

The fundamental objective of the project is the elaboration of an innovative service of authentication, studying, evaluation and investigation of sacral artefacts by using an integrated system of modern methods. The following steps will be check in order to achieve the fundamental objective: ►The elaboration of the data library of advanced modern methods involved in the investigation of sacral artefacts;►Providing the research methodology in integrated modern methods on fresh and laboratory wetherined wood support and pigments;► Providing the research methodology in integrated modern methods wood support and pigments of artefacts;► Providing the innovative service as standards and methodologies in integrated methods;

The general objectives Results►The elaboration of the data library of advanced modern methods involved in the investigation of sacral artefacts;

◘ The state of the art rapport;

►Providing the research methodology in integrated modern methods on fresh and laboratory wetherined wood support and pigments;

◘ The logical scheme of the modern methods in the integrated system on fresh and laboratory wetherined wood support and pigments;

► Providing the research methodology in integrated modern methods wood support and pigments of artefacts;

◘ The logical scheme of the modern methods in the integrated system on fresh and laboratory wetherined wood support and pigments;

► Providing the innovative service as standards and methodologies in integrated methods;

◘ Monogarphy about the general standars and methods, specific methodologies succesfuly used in this project.

e. The Coordinator of the Project

University of BucharestBd. Mihail Kogălniceanu, Nr. 36-46,Sector 5,Cod poştal70709, Bucureşti,România,

Te/Fax: +40(1)313 17 60, http://www.unibuc.ro

f. The partners

The first partner P1: The National Institute for Reaserch and Developing of Electrical Engineering ICPE-CASplaiul Unirii nr. 313, Bucuresti 030138, ROMANIA,

Tel.: 0040-21-346.72.31, 346.82.97, Fax: 0040-21-346.82.99, e-mail: office@icpe-ca.rohttp://www.icpe-ca.ro

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The second partner 2: The National Institute for Reaserch for Preserving and Restoring Calea Victoriei 12, sector 3, 030026 Bucureşti

Tel./Fax: (4021) 3127225;E-mail: contact@patrimoniul-cultural.ro

g. Financial Authority

National Center of Programme Management – CNMPProgramme 4 – Consortium in the Priority Research Aria

h. the project period 18.09.2007 – 18.09.2010

i. The activities of the partnersResults Activities◘ The state of the art rapport; CO The raport about the methods FTIR, RAMAN, EDAX.

P1 The raport about the methods DSC, DTG, biologice, AFM, SEM, raze-XP2 The raport about the methods XRF, luminiscenta, fluorescenta.

◘ The logical scheme of the modern methods in the integrated system on fresh and laboratory wetherined wood support and pigments;

CO Results and area of the methods FTIR, RAMAN, EDAX, microanalysis. Papers and scientific communications.P1 Results and area of the methods DSC, DTG, biologice, AFM, SEM, raze-X. Papers and scientific communications.P2 Results and area of the methods XRF, luminiscenta, fluorescenta. Papers and scientific communications.

◘ The logical scheme of the modern methods in the integrated system on fresh and laboratory wetherined wood support and pigments;

All partners, know-how.

◘ Monogarphy about the general standars and methods, specific methodologies succesfuly used in this project.◘Patents.

All partners.

j. The project`s budgetRON

2007 2008 2009 2010 Total

B* C* B C B C B C B C

45000 290000 290000 115000 740 000

32000 256000 256000 96000 640 000

23000 254000 254000 89000 620 000

100000 800000 800000 300000 2 000 000

B*=bugetC*=cofinantion

k. Meetings and events

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- 01.10.2007 The kikoff meeting;- 15.10.2007 the meeting for listing artefats from Stele aChurch –Targoviste.

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- The shooting raports of the WP I.- The WP I raport, 05.12.2007

WP. I.

18.09.2007 - 10.12.2007

The state of the art about the integrated system, artefacts listing

- the consortium meeting on 15.12.2007 about the strategy of the WP II;

WP. II

The integrated system on wood support of artifacts

Result - Raport about the methodology of studying wood support in the integrated system;

Activity II.1 Sampling methodology; Activity II.2 The integrated methods on fresh and laboratory wethered wood support;Activity II.3 The integrated methods on artefacts wood support;Activity II.4 Disemintion –Scientific papers.Activity II.5 Scientific communication.

- The meeting on 05.01.2008 for approving the time table of the WP. II.

WP. II / 2008 Time table

WP. II 01 02 03 04 05 06 07 08 09 10Activity II.1 Sampling methodology;II.1.1.Sampling fresh wood, rosin, wax bees;II.1.2. Sampling wood from artifacts; meet

ingActivity II.2 The integrated methods on fresh and laboratory wethered wood support;

meeting

II.2.1. Analysis separately and in integrated systems on fresh wood.II.2.2 Results and standard on fresh wood.Activity II.3 The integrated methods on artefacts wood support;II.3.1. Analysis separately and in integrated systems on artifacts.II.3.2 Results and standard on wood artifacts.Activity II.4 Disemintion –Scientific papers. workingActivity II.5 Scientific communication. working

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- work-shop 21 may 2008, 1600 organized by the coordonator, amf. R2, Univeritatea Bucuresti

The painting technique on wood support

BUCURESTIBUCURESTI 2008 2008University of Bucharest The Orthodox Faculty of Theology “PATRIARHUL JUSTINIAN”

PROFESSOR COORDINATOR Prof. Univ. Dr. EMANDI ANA

STUDENTSBOCA CRISTINA CATALINA , BRAGADIRU MARIANA

ENE ELENA, JIPA ANDREIANASTASE ANASTASIA, PARUS BEATRICE

- Dissemination WP.II - working

MEETING ATTENDENCE

Institutia coordonatoare: Universitatea Bucuresti Bd. Mihail Kogălniceanu, Nr. 36-46,Sector 5,Cod poştal70709, Bucureşti,România,

Te/Fax: +40(1)313 17 60, http://www.unibuc.ro

http://www.dha27.com/

REGISTRATION FORM

Name Ana Emandi Title Professor

Institution University of Bucharest, Faculty of Chemistry, Department of Inorganic Chemistry

Address 23 Dumbrava Rosie, district 2, Bucharest, Romania

Tel. 04 0788 465 287; 04 021 2231242 Fax 04 021 2231242

E-mail Emandi1988@ARtelecom.net or ancae@b.astral.ro

I wish to contribute a poster x

Please give the exact title of your oral presentation or your poster“Integrated Methods in Studying Wood Support Weathering of Some Sacral Oil Paints from Stelea-Targoviste Church”Authors: Ana Emandi, Ioan Stamatin, Iulian Iordache, Irina Petroviciu, Gheorghe Niculescu

Integrated Methods on Studying Wood Support Weathering of Some Sacral Oil Paints from Stelea-Targoviste Church

Authors: *Ana Emandia, Ioan Stamatinb, Iulian Iordachec, Irina Petroviciud, Gheorghe Niculescud

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27th Meeting of Dyes in History and Archaeology Istanbul, 8th till 11th October 2008

a University of Bucharest, Faculty of Chemistry, 23 Dumbrava Rosie, 010184, Bucharest, Romania, b University of Bucharest, Faculty of Physiscs, 405 Atomistilor, Magurele-Ilfov, Bucharest, RomaniacINCDIE ICPE - CA Splaiul Unirii, Nr. 313, Sector 3 74204, Bucharest Romaniad INCDCR, 12 Calea Victoriei, cod 030026, Bucharest, Romania

* author for cprrespondence emandi1988@ARtelecom.net or ancae@b.astral.ro

Abstract

The purpose of this study is clarifying the degradation type of artefacts wood support of ~450 years old, actually wethered by embedding rosin and bees wax 50 years ago. Thus, changes in the infrared spectra of wood samples due to the decay were recorded. Ass the sub-purpose, possibility of the application of the integrated methods: infrared and Raman spectroscopy, EDAX, XPS, AFM to the measurement of the degree of this decay were examined.

Changes in infrared spectra have been recorded with the comparison to wood belongs to different periods of time, fresh bees wax and rosin [1].

Consequently, it had been expected from this study that some changes in molecular structures of wood components would appear even at the initial stage of decay. The shift of the bands at 1730, 1380 and 1050 cm-1 in the FTIR spectra would be better correlated with FT-Raman spectra and the EDAX, XPS, AFM methods [2-4].

Considering the complex decay of rosin, bees wax and wood fiber of the support we developed a paralell the standard protocol of these integrated methods on different types of frash and laboratory weathered wood, bees wax and rosin samples. [3-4].

References

1. İsmail Aydin., Applied Surface Science, Vol. 233, 1-4, 2004, p. 268-2742. B. Hendarto, E. Shayan, B. Ozarska, R.Carr., The International Journal of Advanced Manufacturing Technology., Publisher Springer London, 28, 7-8, 2006 3.C. Paris, C. Coupry., Journal of Raman Spectroscopy, 36, 1 , P. 77 – 82, 2004 4. J. J. Suñol, D. Miralpeix, J. Saurina, F. Carrillo, X. Colom, Journal of Thermal Analysis and Calorimetry, 80, p. 117–121 , 2005

ROLE OF METAL ELECTRONIC PROPERTIES TOWARD THE SECOND-ORDER NONLINEAR OPTICAL RESPONSE A HOMOLOGOUS SERIES OF

(DIHYDROXYAZOBENZENE – PAINTING AZOPIGMENTS) (Cu, Zn) COMPLEXES*Ana Emandi1, I. Iordache2, I. Stamatin2, Silvia Hodorogea2, Vasilica Chivu1, Mirela Calinescu1 1Universitatea Bucureşti, Bd.Mihail Kogălniceanu nr.36-46, sector 5, Bucharest, Romania2Institutul National De Cercetare Dezvoltare Pentru Inginerie Electrica, Incdie ICPE-CA, Splaiul Unirii 313 sector 3 CP 030138, Bucharest, Romania

SCIENTIFIC PAPERS – SUBMITEENG in WORKING

l. links- legislatie in domeniul patrimoniului UE si Romania-pagini complementare de institutii si proiecte

P1 partner chair dr. Chim. Petru Budrugeac e-mail sanda_budr@yahoo.comP2 partner chair dr. Fiz. Gheorghe Niculescu e-mail niculescu.geo@gmail.com

m. The project`s director adressessesDirector de Proiect: prof. univ. dr. Ana EmandiUniversity of Bucharest, Faculty of Chemistry23 Dumbrava Rosie Street, District 2, cod: 020462, Bucharest - RomaniaTel: 0788 465 287; tel/fax : 004021 212 48 47 Fax: 004021 2231242 E-mail: ancae@b.astral.ro emandi1988@ARtelecom.net

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