Acrylic Resin Injection of Wet Joints in Concrete Channel Drain

Rev.No. Date Description Prepared Checked Approved 0 27.05.2008 First Issue NGMW NYP //SM 1 18.06.2008 First Revision NG MW. SRE~~SM

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Issued by:

Method Statement No: 25045-02200-10-3GS-C-019 (Rev. 1)

Date Overseas Bechtel, Inc.

0 STATUS 3: REVISE & RESUBMIT. WORK MAY NOT PROCEED.

0 STATUS 4: REVIEW NOT REQUIRED. WORK MAY PROCEED.

PERMISSION TO PROCEED SHALL NOT CONSTITUTE ACCEPTANCE OR APPROVAL OF DESIGN DETAILS, CALCULATIONS, ANALYSIS, TEST METHODS, OR MATERIALS DEVELOPED OR SELECTED BY CONTRACTOR AND SHALL NOT RELIEVE CONTRACTOR FROM FULL COMPLIANCE WITH CONTRACT TECHNICAL SPECIFICATIONS AND DRAWINGS.

0 STATUS1:WORKMAYPROCEED.

0 STATUS 2: REVISE & RESUBMIT. WORK MAY PROCEED SUBJECT TO INCORPORATION OF COMMENTS INDICATED.

DOCUMENT REVIEW STATUS

Civil Works

ACRYLIC RESIN INJECTION OF WET JOINTS IN CONCRETE CHANNEL DRAIN

Sinohydro-Gamuda-WCT Joint Venture

Method Statement

twmurray

Accepted

castillo

3.2 Drainage

Page 1 of 7

5. APPENDIX

4. QUALITY ASSURANCE

3. ENVIRONMENTAL ISSUES 3.1 Environment Impact Assessment 3.2 NOIA Environmental Contractor Requirement 3.3 Contractual Requirement 3.4 Emergency Procedure

2. HEAL TH & SAFETY 2.1 Risk Assessment 2.2 Safety and Health Requirements 2.3 Protective and Safety Equipment 2.4 Contractual Requirements 2.5 Information to Personnel 2.6 Emergency Procedures 2. 7 Permit Requirements

1. SCOPE OF WORK 1.1 Objectives of the Method Statement 1.2 Scope of Application 1.3 Material and equipment 1.4 Method of RASCOflex Injection

1.4.1 Preparation works prior to injection of RASCOflex 1.4.2 Injection of RASCOflex AMO

TABLE OF CONTENTS

SGW JV - Method Statement for Injection of Wet Joints in Concrete Channel Drain

MS NO: 25045-02200-1 O-JGS-C-019 (Rev.1)

Page 2 of7

4. Holes will be drilled using 20mm diameter drill-bit at angle of 45° - 60° to the horizontal from the concrete surface to intersect the plane of discontinuity. A free standing wooden template showing 60° will be used to guide driller. Please refer to Appendix 2.

3. Position of injection packers will be marked at a distance of 200rnm away from the joint at 300mm centre-to-centre (staggered spacing). Please refer to Appendix 1.

2. Dirt will be removed manually to expose the joint and determine extent of injection required.

1. Standing water in the drain will be constantly drawn down by electrical pump or vacuum cleaner to minimal level to facilitate injection works.

1.4.1 Preparation works prior to injection of RASCOflex

1.4 Method of RASCOflex Injection

a. RASCOflex AMO resin (material submittal no.: 25045-D 1000-1 O-CDD-C-066) b. SikaGrout 114 (material submittal no.: 25045-D2200-10-CDD-C-008)

The following materials will be used in the works.

Items Equipment Purpose 1. RASCOR Injection pump unit To inject RASCOflex Qel into the joints 2. RASCOR Injection packers To facilitate injection 3. Drill (c/w drill-bit) To drill holes for insertion of the injection

packers 4. Electrical Water Pump To dewater standing wafer in the drain 5. Scrapper I Hand Tools Clean and prepare the concrete surface 6. Concrete cutter Grooving of treated joints 7. Generator Set Power supply

1.3 Material and Equipment The following equipments are required to perform the works:

The method statement includes; cleaning and preparation of the concrete surfaces, drilling injection ports, injecting of RASCOflex methacrylamide dual component resin and sealing the joint surfaces with polymer modified repair mortar.

1.2 Scope of Application RASCOflex acrylic resin is proposed because of its application can be carried out against water pressure and suitable to be used in damp or wet substrate.

1.1 Objectives of The Method Statement To describe the sequence of operations associated with the injection of RASCOflex acrylic resin to seal water pathways in construction joints and expansion joints that are constantly wet.

1. SCOPE OF WORK


MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

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Page 3 of7

2.3 Protective and Safety Equipment

• Eyewash solutions/bottle • Safety goggles • Protective gloves • Safety Helmet with company logo • Safety Boots I Shoes • High Visibility Vest • Hearing Protection ( if required )

2.2 Safety and Health Requirements

Refer to Appendix 5.

2. SAFETY AND HEAL TH

2.1 Risk Assessment


8. Polythene sheet will be placed over the repair mortar and allow to cure for at least 7 days.

7. The groove will be make good with non-shrink concrete repair mortar SikaGrout 114. The repair mortar will be applied in accordance to manufacturer's technical data sheet attached in Appendix 4.

6. After the resin has fully polymerized, cut groove on concrete surface 30mm wide (15mm each side of the joint) along the joint with concrete cutter. Chip out concrete to form groove 20mm deep.

5. After retrieval of the injection packers, drill holes will be made good using SikaGrout 114.

4. Injection will be carried out between packer holes and flash polymerize the resin coming out of the joint surface with a gas torch. Risk assessment associate with the use of gas torch is incorporated in Appendix 5: 2. 1 Risk Assessment.

3. When water stops running from the joint then re-inject with RASCOflex AMO resin set to gelling time 180seconds or more at higher pressure to get the acrylic resin coming out from the joint surface.

2. The drilled holes will be injected with RASCOflex AMO resin set to gelling time of 60seconds. Gelling time is changed to suit water flow from the cracks. Gelling time is changed using Accelerator or Retarder added into the mix before injection. Gel time of the mixture will tested prior to injection.

1. RASCOflex AMO 2-component acrylic resin will be mixed and prepared in accordance to manufacturer's recommendations. Please refer to product's technical data sheet in Appendix 3. Special two component pump with products mixed at the head of the pump nozzle will be used. Therefore, mixing time and pot life is not applicable. Resin is injected into drill holes via special injection packers.

1.4.2 Injection of RASCOflex AMO


MS NO: 25045-D2200-10-3GS-C-019 (Rev.1)

Page 4 of7

2. 7 Permit Requirements 1) Electrical tools operation competency certificate

2.6 Emergency Procedures

In the event of an accident, the following shall be activated: 1) The area Supervisors shall act as the Rescue Team Leader and attend to the

accident 2) He shall inform the Emergency Controller ( Project Manager ) of the accident 3) In the absence of the Project Manager, the Construction Manager shall act as the

Emergency Controller 4) The Emergency Controller shall alert the Emergency Response Team, comprising

of First Aiders to attend the accident when required 5) The Emergency Controller shall alert the Fire Fighting Team should there be a fire 6) The Rescue Team Leader shall alert the Emergency Controller for additional

assistance from other Rescue Team Leaders 7) The Emergency Controller shall arrange for transportation to sent victim to Clinic or

Hospital when required 8) The Accident area shall be barricaded and cordoned off and not to remove any

potential evidence 9) A watchman shall be engaged to protect the area from unauthorized entry 10) The Emergency Controller shall call for a post mortem meeting after the emergency

with the people involved in the emergency 11) The ES&H representative shall organize the Safety Committee to perform a Full

Accident Investigation 12) The ES&H representative shall inform OBI Safety representative of the accident and

submit a report 13) All information leading to the accident including information, description, photos,

time and location, sources, witness statements, police or medical reports shall be prepared and submitted by the Project Manager

2.5 Information to Personnel

Communication shall be made through:- • STARRT Program • Tool Box Meeting • Safety Induction • Notice board I memo

2.4 Contractual Requirements

• Safety Induction for l\Jew Employees • PPE Requirements • Inspection of Machinery • Emergency Procedures • Welfare Facilities • First Aid Requirements • Defensive Drivers Training

SGW JV..;... Method Statement for Injection of Wet Joints in Concrete Channel Drain

MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

Page 5 of7

3.4.1.3 Initial Response Actions

Upon completion of his evaluation of the magnitude and severity of the spill incident, the SRC shall select and initiate one or more of the following response actions as appropriate.

Secure the spill area, removing injured personnel and evacuating the work site as necessary, and placing temporary barriers, fences and warning signs where needed.

3.4.1.2 Spill Contingency Equipment and Supplies

Where required, the following equipment and supplies may be required or may be made available for deployment at the Work Site.

Earth-moving machinery Submersible pumps and hoses Emergency lighting Absorbent materials Tool kits Large tools including non-sparking shovels, spades and pickaxes Storage containers Personal protective equipment Communications system

3.4 Emergency Procedure

3.4.1 Incident Control and Response

3.4.1.1 Notification Requirement

The SRC (Spill Response Coordinator) will alert the designated SRT (Spill Response Team) should there be any environmental incidents. The SRT will also notify OBI site representative

All the activities effecting environment should be under the rules and regulations of Qatar supreme council for environment and natural resources

Effective measures are to be in placed to ensure environmental parameter requirements are complied.

3.3 Contractual Requirement

Significant Requirements is attached in Appendix 1 - Final SCE Standards, 9 June 2003 particularly section 6.0 (Water Quality), 7.0 (Air Quality), 8.0 (Waste), and 9.0 (Noise).

3.2 NOIA Environmental Contractor Requirement

References: 1. ES&H Plan Appendix 10 Environmental Management Plan Table 6.1 2. CECP - 5.1 Noise and Vibration Control 3. CECP - 5.2 Air Quality Management 4. CECP - 5.3 Water Quality Management 5. CECP - 5.4 Erosion and Sedimentation Control 6. CECP - 5.8 Waste Management 7. CECP - 5.9 Storage of Potentially Polluting Materials 8. CECP - 5.10 Incident and Control Response

3. ENVIRONMENTAL ISSUES 3.1 Environment Impact Assessment



MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

Page 6 of7

4.3 Follow Up and Evaluation

Internal checklist shall be adopted.

4.2 Inspection & Testing

Internal testing and inspections performed by SGW.

4 QUALITY ASSURANCE 4.1 Contractual Requirement

To follow SGW JV Quality Assurance Plan.

3.4.1.5 Records and Files

Records of all inspections performed in conjunction with the provisions of this plan shall be made part of the Spill Documentation Records.

3.4.1.4 Cleanup, Removal and Disposal

When a spill or discharge of an appreciable quantity of pollutants or contaminants occurs of such magnitude and severity to warrant special attention (i.e. involving a hazardous material or large oil spill) the SRC shall summon the SRT to assist with spill containment, cleanup, removal and disposal activities. The SRC shall supervise and direct the SRT while implementing appropriate spill response.

Protect the safety of personnel and equipment, whether company or private, as appropriate. Activate the SRT and direct spill cleanup efforts as soon as safely possible. Take actions to halt or plug an ongoing discharge or spill and construct a containment berm. Notify the Site Construction Manager and SH Manager. Take steps to prevent a fire. Notify the Fire Protection Department as needed. Collect samples and monitor the spill site as necessary. Use a detector to check for flammable vapors particularly in holes or depressed areas. Establish a command post for co-ordination of spill response activities. Where hazardous substances are discharged, ensure that personnel approach the spill site from the upwind side. Notify Site Project Manager, OBI and SH Manager or the SRT when a spill is beyond the resource capabilities and request additional support. In co-ordination with the SH Manager, ensure that the SRT and all personnel involved in spill response activities wear appropriate personal protective clothing and equipment upon entering the spill site. Provide assistance when requested should Client assume direction and control of spill response activities.


MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

Page 7 of7

Item Appendix No Description

5.1 Appendix 1 Position of Drill Holes I Packer along Construction Joint

5.2 Cross Section A-A Indicates Position of Appendix 2 Injection Packer Intersect Construction Joint

5.3 Appendix 3 RASCOflex AMO Technical Data Sheet

5.4 Appendix 4 SikaGrout 114 Technical Data Sheet

5.5 Appendix 5 Safety & Health Risk Assessment

5.6 Appendix 6 Environment Impact Assessment

5.7 Appendix 7 MSDS for RASCOflex AMO

5.8 Appendix 8 MSDS for SikaGrout 114

5 APPENDIX

List of Appendix:


MS NO: 25045-02200-1 O-JGS-C-019 (Rev.1)

Position of Drill Holes I Packer along Construction Joint

Appendix 1

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Appendix 2

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RASCOflex AMO Technical Data Sheet Appendix 3


MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

A-r;omPonent B-concentrate B·powder Supplied form Liquid Liquid Powder Material colour Purple Transparent White Container type Canister Canister Pot Container size 25 litres 5 litres 7509 Container colour Black White White Container lid colour Red Viscosity at zo-c 12 mPa s Application temperature From -1o•c to +ao·c Compressive strength Approx. o. 16 N/mm2

Swelling capacity Approx.15% pH value of mix Approx, 8.0 to 11.0 Start of polymerisation at 2o•c Approx. 2-3 min Storage/shelf life In original packaging, from +s·c to +25"C. in dark location: 12 months Transport class SDRIADR UN 3426 free UN 1444

• max 30 kg per box Transportation rules 0-100 lit none none • box with etiquette

UN1444 • powder extinguisher • max 30 kg per box

101-320 lit 2 kg tested and sealed none • box with etiquette • special transportation documents UN1444 • briefed driver from 320 lit on not permitted!

Technical/Physical Data

Features • High frost and temperature resistance • Technkal application possible in all situations • High chemical resistance •· Reactive and reversible swelling action • No adhesion required to sides of joint/crack • Unsuitable for potable water applications

Use RASCOflex AMO is a special material particularly suited for all waterproofing applications subject to high temperatures or frost and for waterproofing works to chemically or faecally contaminated substrates - whether for the remedial grouting of cracks and joints or, in conjunction with the RASCOtec systems, for preventive waterproofing solutions.

RASCOflex AMO is a versatile, modified injection grout based on a special formulation of 2-component acrylic resins (acrylamides).

OBP Technical data sheet RASCOflex AMO Item no. 1401.511 1 .050

System Engineering for waterproof structure.

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ltASCOR - Expertise in preventive and remedial water proofing.

Phone:+ 41(O)1'"857 11 11 fax:~ 41 (D) 1-857 11 00 [email protected] www.rascor.com

Tedmlcal data sheet 2301.5111.0SOE 0!!.12.2005 rt

Rescor International Ltd. Gewerbestrane -4 CH-4!162 Steinmaur Switzerland

The details rel1:1ting to the use and application of our products are based on the present state of our knowledge and experience. Due allowance 5halJ be made in the U5e and application of the products for preject-speclfic circumstances and conditions. Up-to-date versions of the Technical Data Sheets are available on-line at www.rastor.com. Our General Terms of Business snail apply.

Grouting machines, equipment and accessories available on request

5 litre canister 10 litre canister

Item no. 1101.3010.005 Item no. 1101.3020.010

Accessories RASCOflex retarder RASCOflex accelerator

per litre Item no. 1401.5111.050 Supply RASCOflex AMO

Safety notice Suitable protective clothing, gloves and goggles shall be worn. An eyewash bottle shall be kept at hand. Acrylamide is classed as toxic in its liquid state. It is essential that all relevant regulations be observed! The fully polymerized end product is neutral. For details inoformation, please consult the safety data sheet.

General Guideline Different mixing implements shall be used for the A- and B-components; these may only ever be used for the same component. Retarder and accelerator may only be added to the A-component. Accelerated material shall never be retarded and retarded material shall never be accelerated.

Application The A- and B-components are mixed in the ratio 1:1 (by volume). The A-component is supplied ready for use. To prepare the finished B-component from the 8-concentrate, approx. 5 litres of water are first poured into the mixing canister. The B powder is dissolved in the water by stirring or vigorous shaking. The 8-concentrate is then added to this solution. The mixing canister is subsequently filled up to the 25-litre mark with water and the contents very thoroughly mixed. Use of a drill with stirrer attachment is recommended. The ready-mixed B-component may be kept for 2 to 5 days, depending on the storage temperature.

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SikaGrout 114 Technical Data Sheet Appendix 4


MS NO: 25045-D2200-10-3GS-C-019 (Rev.1)

1

Mixing ratio Consistency Water per 25 kg bag Water/Powder Ratio

Dry-pack I Trowellable 3.0 It. 0.12 Plastic consistency 3.25 - 3. 75 It. 0.13-0.15 Flowable (max. 3. 75 - 4.00 lt. 0.15-0.16 strenoth) Highly flowable (max. 4.00 - 4.25 It. 0.16-0.17 flow)

12 months minimum from production date if stored properly in original unopened packaging

Store in a dry area between 5°C and 35°C. Protect from direct sunlight

25 kg bag

Grey Powder

Mixture of Portland cement and graded aggregates

Complies with CRD-C621-83-10.2 and ASTM C1107 as Type C. Tested at Al-Hoty Lab, Bahrain; International Laboratory Services ,Bahrain.

SikaGrout®-114 is an economical and easy to use grout requiring only the addition of water. It offers the following beneficial properties: - Easy to mix - Good flow characteristics - Dual expansion system - Adjustable consistency - High final strengths - Non corrosive and iron free

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Technical Data

Uses SikaGrout -114 is used for grouting in the following: - Machine foundations - Columns in pre-cast construction - Concrete anchors, cavities, gaps and recesses - Base plates - General concrete repairs

Product Description SikaGrout®-114 is a cementitious, free flowing, economical, non-shrink precision grout with high ultimate strength. Suitable for use in tropical and hot climatic conditions.

SikaGrout®-114 Cementitious, Shrinkage Compensated General Purpose Grout

SikaGrout®-114

Product Data Sheet Edition 1, 2004 Identification no. CM-03 Version no.1

2

Clean equipment and mixer immediately after application with water. Hardened material can only be removed mechanically.

Cleaning

Treat exposed surfaces with Antisol-E Curing Compound or use other approved coring methods such as polyethylene sheeting or wet hessian.

Curing

Before pouring, however, let the mixed grout stand for approximately 5 minutes after mixing to allow entrapped air to escape. Pour into the prepared area such that the grout has the shortest distance to travel. Ensure that air displaced by the grout is allowed to escape. When carrying out base plate grouting, ensure a sufficient head of pressure is maintained to keep the mortar flowing. All exposed areas of the mortar surface should be kept as small as possible.

Application

Mix mechanically with a slow speed drill (max. 500 rpm) for at least 3 minutes and until a smooth, even consistency is achieved. Add water according to the desired consistency. For a flowable mix, 3.75 - 4.00 It. per 25 kg bag will be required.

Mixing

Substrate Concrete surfaces should be clean, sound and free from oil, grease, cement preparation laitance and all loosely adhering particles.

Absorbent surfaces should be saturated thoroughly. Metal surfaces (iron and steel) should be free from scale, rust, oil and grease.

Application Details

12. 7 - 13.1 litres per 25 kg bag, depending on water addition Yield

+O.OB % after 28 days Expansion (CRD C621)

approx. 11•10-6 per °C Thermal expansion coefficient

- 35'000 N/mm2 E-Modul (static)

Minimum gap= 10 mm, Maximum= 75 mm per pour Thickness

-14 N/mm2 (at 28 days) at w/p = 0.15, ( 25°C) Flexural strength (BS4551)

1 day -45 N/mm2

28 days -65 N/mm2

3days -55 N/mm2

Compressive Strength (ASTM C109t, w/p =0.15 At25 C

Density at 2511C 2200 kg/m3 (fresh mortar)

Product Data Sheet Edition 1, 2004 Identification no. CM-03 Version no.1 SikaGrout®-114

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Sika Gulf B.S.C (c) Bldg.925, Road 115, Sitra Area 601. P.O.Box 15776 Adliya, Kingdom of Bahrain Tel: ++973 17735 560, Fax: ++973 17732 476 Email; [email protected] Web : http://www.sikagulf.com

The information, and, in particular, the recommendations relating to the application and end-use of Sika products, are given in good faith based on Sika's current knowledge and experience of the products when properly stored, handled and applied under normal conditions. In practice, the differences in materials, substratum and actual site oonditions are such that no warranty in respect of merchantability or of fitness for a particular purpose, nor any liability arising out of any legal relationship whatsoever, can be inferred either from this information, or from any written recommendations. or from any other advice offered. The proprietary rights of third parties must be observed. AR orders are accepted subject to our current terms of sale and delivery. Users should always refer to the most recent issue of the Technical Data Sheet for the product concerned, copies of which will be supplied on request.

Non-hazardous .

Non-toxic under the relevant Swiss health and safety codes.

Do not dispose of into water or soil but according to local regulations.

Accidental splashes to the skin must be washed off with water and soap. Accidental splashes to the eyes or mucous membrane must be rinsed with clean wann water. Seek medical attention without delay . Skin barrier cream, safety goggles and rubber gloves are recommended.

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Remarks Use SikaGrout for grouting only. -Ensure formwork is secure and watertight to prevent movement and leaking during placing and curing. -Where maximum thickness exceeds 75mm, consider the use of Sikacrete 114. -At high temperatures, use chilled water for mixing to keep the grout temperature below 30°C. -In hot weather, base plates and foundations must be shaded from direct sunlight. -Condition bags of grout (temperature below 30°C )prior to use -Depending on requirements and site condition, the addition of up to 100% of, dry, single size and clean aggregates is possible. Trials are recommended to confirm suitability of a~regates to be employed. For additional infonnation on SikaGrout -114 or other grouting materials contact our Technical Services Department.

Product Data Sheet Edition 1, 2004 Identification no. CM-03 Version no.1 SikaGrout®-114

Safety & Health Risk Assessment Appendix 5


MS NO: 25045-D2200-10-3GS-C-019 (Rev.1)

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Environment Impact Assessment Appendix 6


MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

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I MSDS for RASCOflex AMD I Appendix7


MS NO: 25045-02200-10-3GS-C-019 (Rev.1)

Assure the safely of the rescuer. 4.1 Inhalation Remove person from danger area. Supply person with fresh air. Call doctor immediately. 4.2 Eye contact Wash thoroughly for several minutes using copious water - call doctor immediately, have Data Sheet available. 4.3 Skin contact Wash thoroughly using copious water - remove contaminated clothing immediately end call a doctor. Have Data Sheet available. If applicable Dab away with polyethylene glycol 400 4.4 Ingestion Rinse the mouth thoroughly with water.

4. First aid measures · ·

3.1 To people See point 11and15. Preparation is classified as hazardous in the sense of directive 1999145/EC. May cause cancer. May cause heritable genetic damage. Product is dangerous to health. May cause sensitization by skin contact. Danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of impaired fertility. 3.2 To the environment See point 12.

For complete wording of the R-phrases, refer lo point 16.

2.1 Chemical name content% symbol R-phrases EINECS, B.INCS

Ethanediol 30-50 Xn 22 203-473-3 Acrylamide 5.-<20 T/Xn/XI 45-46-62-25- 201-173-7

48123124125- 20121-36/38-43

Company/undertaking Identification Rascor International AG, GewerbestraBe 4, CH -6162 Sleinmaur Telephone +41 (0) 44-857 1111, Fax +41 (O) 44-657 11 oo Emergency telephone I Office for advice Advisory office In case of poisoning: Tel.: Telephone number of the company in case of emergencies: Tel. +41 (0}44-8571111

RASCOflex AMO (A) Use of the substance/preparation Adhesive sealant

Identification of the substance or preparation

1. Identification of the substance/preparation and of the company/undertaking

Safety Data Sheet according to EC-Regulation 91/155/EEC

1I6 EN Revision: 16.11.2006 Replaces the version of: 09.02.2006 PDF date: 23.11.2006 RASCOllex AMD (A)

•'

7 .1 Handling Tips for safe handling: See point 6.1 Avoid all contact with product. Use as far as possible in closed circuit plants/systems. Ensure good ventilation. Eating, drinking, smoking, as well as rood-storage, is prohibited in worlHoom. Wash hands before breaks and at end of work. Separate storage of protective clothing. Observe directions on label and instructions for use. Use working methods according to operating instructions. Exposed employees should have regular medical check-ups. 7 .2. Storage

Refer to point 13. and for personal protection refer to point B. 6.1 Personal precautions Avoid all contact wilh product. Ensure sufficient supply cl air. Avoid inhalation, and contact with eyes or skin. 6.2 Environmental measures If leakage occurs, dam up. Prevent from entering drainage system. Prevent surface and ground-water infiltration, as well as ground penetration. If accidental entry into drainage system occurs, inform responsible authorities. 6.3 Methods for cleaning up Collect using absorbent material (e.g. Universal binding medium, sand, kieselguhr) and dispose of according to point 13. Clean soiled bottles immediately.

. ~;·, «, ••

5.1 Suitable extinguishing media Water jet spray C02 Foam Extinction powder 5.2 Extinguishing media which must not be used for safety reasons n.e, 5.3 Special exposure hazards arising from the substance or preparation itself. combustion products. resulting gases In case cf fire the following can develop: Oxides of carbon Oxides of nitrogen Ammonia Toxic pyrolysis products. 5.4 Special protective equipment for fire-fighters Protective respirator with independent air supply According lo size of fire Full protection, if necessary 5.5 Further information Dispose of oontaminated extinction waler according to official regulations.

5. Fire-fighting measures

Give copious water to drink - consult doctor immediately. Keep Data Sheet available. If applicable Induce vomiting. 4.5 Special resources necessary for first aid n.c.

2/6 EN Revision: 16.11.2006 Replaces the version of: 09.02.2006 PDF date: 23.11.2006 RASCOflex AMO (A)

Liquid Violet Characteristic 8-8,5 n.av. n.av. n.c. n.a. n.a.

Physic.al state: Colour: Odour: pH-value undiluted: Boiling point/range (°C): Melting point/range ("C): Flash point (9C): Minimum limit of explosion: Maximum limit of explosion:

9. . Physical and chemlc;al propert,es ,i, •I I.,

Tight fitting protective goggles with side protedion (EN 166). Protective working garments (e.g. safety shoes EN 344, long sleeved protective working garments) ·

Additional information on hand protection - No tests have been performed. Selection made for preparations according to the best available knowledge and information on the ingredients. Selection of materials derived from glove manufacturer's indications. Final selection of glove material must be made taking the breakthrough times, permeation rates and degradation into account. Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to manufacturer. In the case of preparations the resistance of glove materials cannot be calculated in advance so it has to be tested before use. The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed.

If OES or MEL is exceeded. 8.1 Respiratory protection: FilterA2P2(EN141) Ai high concentrations: Respiratory protection appliance {insulation device) (e.g. EN 137 or EN 138) 8.2 Hand protection: Chemical resistant protective gloves (EN 374). If applicable Protective nitrite gloves (EN 374) Protective hand cream recommended. 8.3 Eye protection: 8.4 Skin protection:

® WEL-TW A = Workplace Exposure Limit - Long-tenn exposure limit (8-hour TWA (= lime weighted average) reference period) EH40. AGW = •Arbeitsplatzgrenzwert• (workplace limit value, Gennany). I WEL-STEL = Wori<place Exposure Limit - Short-terme exposure limit (15-minute reference period). I BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer Grenzwert• (biological limit value, Gem_iany) I Other Information: Sen = Capable of causing occupational asthma. Sk = Can be absorbed through skin. Care = Capable of causing cancer and/or heritable genetic damage. •• =The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision.

0,3m hn3

Requirements for storage rooms and containers: Store products only unopened, in original packing. Not to be stored in gangways or stair wells. ObsefVe regulations for keeping separated. Spacfal storage conditions: See point 10.2 Protect from direct sunlight and warming. Keep loeked away. Keep out of access to unauthorised individuals.

3/6 EN Revision: 16. 11.2006 Replaces the version of: 09.02.2006 PDF date: 23. 11.2006 RAsconex AMD CA)

:... ·. · · . ·. ·· ·. B~ ·EXposure ·con•rols/personal protection

13.1. for the material I preparation I residue EC disposal code no.: The waste codes are recommendations based on the scheduled use of this product.

'_.:_J ·' •, •r ' ,: ': \ ' ' '13~ '~l)lsposal conslda.ratlom1 -; :·

n.av. n.av. n.av. Not accepted owing to the logP values of the components.

3 Ves(YwVwS)

Water hazasd class (Germany): Self classification: Persistence and degradability: Readily biodegradable (100%/28d •, 100% OECD 301E **) BehavioLU" in sewage plants: Aquatic toxicity: Ecological toxicity: Accumulation: • Aaylamide •• Ethanediol

Yes (skin contact) Care. Cat. 2 Mula. Cat. 2 Repr. Cat. 3 n.c.

See point 15. See point 15. See point 15. · n.av.

11.3. Further Information ClassificaUon according to calculation procedure. The following may occur: Irritation of the eyes Irritant to mucosa of the nose and throat. Skin resorption Effects/damages the central nervous system Coordination disorders

11.2 Delayed and chronic effects Sensitization: Carcinogenicity: Mutagenicity: Reproductive toxicity: Narcosis:

11.1 Acute toxicity and Immediate effects Ingestion, LD50 rat oral (mg/kg): Inhalation, LC50 rat inhal.(mg/lf4h}: Skin contact, LOSO rat dermal (mg/kg): Eye contact:

10.1 Conditions to avoid See point7 Heating 10.2 Materials to avoid Seepoint7 Avoid contact with strong acids. Avoid contact with strong alkalis. Avoid contact with strong oxidizing agents. Reducing agent 10.3 Hazardous decomposition products See point 5.3

1 O. Stability and reactivity

n.c. n.c. Soluble log Pow-1,24 * -12 mPas (20"C)

Vapour pressure: Density (g/ml): Solubility in water: Partition cOefficient (n-octanol/water): Viscosity: * Acrylamide

' I

4/6 EN Revision: 16.11.2006 Replaces the version of: 09.02.2006 PDF dale: 23. 11.2006 RASCOllex AMD (A)

Symbols: T Indications of danger; Toxic R-phrases: 45 May cause cancer. 46 May cause heritable genetic damage. 22 Harmful if swallowed. 43 May cause sensitization by skin contact. 48123124125 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. 62 Possible risk of impaired fertility. S-phrases; 53 Avoid exposure - obtain special instructions before use. 35 This material and its container must be disposed of in a safe way. 36/37 Wear suitable protective clothing and gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Additions: Acrylamida Ethanediol Restricted to professional users. Observe restrictions: Yes Observe law on protection of expectant mothers (German regulation). Observe youth employment law (German regulation).

Classification according to Dangerous Product Regulations incl. EC Directives (67/548/EEC and 1999/45/EC)

6.1J..llll (class/secondary danger/packing-group)

6.11111 {class/packing-group) F-A, S-A n.a

6.1/IU

T1 7

3426 General statements UN-Number: Road/Rall-transport (ADR/RID) Class/packing-group: UN 3426 ACRYLAMIDE, SOLUTION Classification code: LQ: Transport by sea IMDG-coda: EmS: Marina Pollutant: ACRYLAMIDE SOLUTION Transport by air IATA: Acrylamide solution Additional information: Danger code and packing code on request.

I .

OWing to the user's specific condiUons for use and disposal, other waste codes may be allocated under certain circumstances. (2001/118/EC, 2001/119/EC, 2001/573.IEC) 08 04 09waste adhesives and sealants containing organic solvents or other dangerous substances Recommendation: · Pay attention to local and nallonal official regulations Implement substance recycling. E.g. suitable Incineration plant. Do not dispose of with household waste. 13.2 for contaminated packing material See point 13.1 Pay attention to local and national official regulations Approved rubbish dump for special refuse Suitable incineration plant 15 0110 packaging containing residues of or contaminated by dangerous substances

516 EN Revision: 16.11.2006 Replaces the version of: 09.02.2006 PDF data: 23.11.2006 RASCOflex AMO (A)

n.a. =not applicable I n.v., k.D.v. = n.av. =not available/ n.g. = n.c. =not checked WEL = Workplace Exposure Limit EH40, TWA= Long-term exposure limit (8-hour TWA(= Ume weighted average) reference period), STEL = Short-terma exposure llmit (15-minute reference period) I BMGV = Biologlcal monitoring guidance value EH40 AGW = "Arbeitsplalzgrenzwert• (workplace limit value, Germany) I BGW = "Biologischer Grenzwert" (biological limit value, Germany) VbF = Regulations for flammable liquids (Austria) W~K = water hazard class (Germany) - WGK 3 =very hazardous, WGK 2 =hazardous, WGK 1 =slightly hazardous to water VOC = Volatile organic compounds I AOX = Adsorbable organic halogen compounds VwVwS =Administrative Order relating to substances hazardous lo water (Germany) The statements made here should describe the product with regard to the necessary safety pracautions - they are not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge. No responsibility. These statements were made by: Chemical Check GmbH, Seim Staumberge 3, D-32839 steinheim, Tel.: +49 5233 94 17 0, +49 1805~ CHEMICAL I +49 180 52 43 642, Fax: +49 5233 94 17 90, +49 180 50 50 455 ©by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document is forbidden except with consent of the Chemlc:al Check GmbH Gefahrsl:offberatung.

These details refer to the product as it is delivered. Storage class VCJ (Germany): 6.1 A Revised points: 14 The fol lowing phrases represent the prescribed R-phrases for the ingredients {designated in point 2). 22 Harmful if swallowed. 45 May c:ause cancer. 46 May cause heritable genetic damage. 62 Possible risk of impaired fertility. 25 Toxic If swallowed. 48/23124125 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. 48/23124/25 Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with sl<in and if swallowed. 20/21 Hannful by inhalation and in contact with skin. 36/38 lnitating to eyes and skin. 43 May cause sensiUzation by skin contact.

16. Other lnfonnatlon

Observe regulations on prohibition of chemicals. Observe incident regulations. Observe restrictive guidelines 76n69/EEC, 1999/51/EC, 1999n7/EC voe 1999113/EC 0% wlw

616 EN Revision: 16.11.2006 Replaces the version of: 09.02.2006 PDF date: 23.11.2006 RASCOHex AMO (A)

r- 115

Revision; 12.09.2007 Replaces the version of: 19.02.2004 PDF date: 12.09.2007 RASCOflex AMO {Bl

Safety data sheet according to Regulation (EC) No 190712006, Annex II

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING


RASCOflex AMD (B)

Use of the substance/preparation Refer to description of material or preparation.

Company/undertaking identification Rascor International AG, GewertestraBe 4, CH -8162 Steinmaur Telephone +41 (0) 44-857 1111, Fax +41(0)44-857 11 00

E·mail address of the competent person: [email protected], [email protected]

Emergency telephone Advisory office in case of poisoning: Tel.: Telephone number of the company in case of emergencies: Tel. +41 (0)44-8571111

: :.>:.·.:·:"·I I .. . . ,. -a~>ttl\ZA.RD.S IDEt;ITl.FICATION;~·,··c._,:·.·.:· .':, ···~ • • • ~ ., .. I• t:: , . .. ~.I ,1 : I•., " .. , .. , ·'• ·: · . . ..

To people Preparation is not classified as hazardous in the sense of directive 1999145/EC. To the environment k.O.v.

I ... -, ··.: '.<.··3.: ... C,OMPOSITIONllNFORMATION.ON.INGREDIENTS ·'<{·/· .. <: :.;.·, ;~ !;:'.,I , ', '•.:

I ·•· .' '. •' l .. ·~· : •' ' . ! ~ - ' - ' . ' • ... • . . , " ' :l , • - , .• • ' r ,...., ' •

Chemical name I I content% I Symbol I R-phrases I EINECS, ELINCS I

I Realstratlon number fECHA) I DNEL I PNEC I

Ethanediol I Substance for which an EU exposure limit value SDDlies.

<2 I Xn I 22 I 203-473-3 I I I

For complete wording of the R-phrases, refer to point 16.

I 4. FIRST AID MEASURES I

4.1 Inhalation Remove person from danger area. Supply person with l'resh air. 4.2 Eye contact Wash thoroughly for several minutes using copious water. Seek medical help if necessary. 4.3 Skin contact

Wash thoroughly using copious water - remove contaminated clolhing immediately. If skin irritation occurs (redness etc.), consult doctor. 4.4 Ingestion Medical attention recommended. Call doctor immediately· have Data Sheet available.

® WEL-TWA =Workplace Exposure Limit- Long-term exposure limit (B-hour TWA(= time weighted average) reference period) EH40. AGW = "Arbeltsplatzgrenzwert" (workplace limit value, Germany). I WEL-STEL =Workplace Exposure Limit - Short-terme exposure limit ( 15-minute reference period). I BMGV = Biological monitoring guidance value EH40. BGW,. "Biologischer Grenz:wert" (biological limit value, Germany) J Olher Information: Sen= Capable of causing occupational asthma. Sk =Can be absorbed through skin. Care"' Capable of causing cancer and/or heritable genetic damage.

Olher information: Sk articulate, va our

104 mg/m3 (vapour) (WEL), 40 ppm EC

8.1 Exposure limit values

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

7.1 Handling Tips for safe handling: See point 6.1 Obseive directions on label and instructions for use. Switch on available suction system. Only use working methods according to operating instructions. Eating, drinking, smoking, as well as food-storage, is prohibited ln work-room. General hygiene measures for the handling of chemicals are applicable. 7.2. Storage . Requirements for storage rooms and containers: Store products only unopened, in original packing. Not to be stored in gangways or &tair wells. Special storage conditions: See point10

. ' ..... '<:3' .. ; · ··:.:,,,'. '.:,:·· • r.··1.(.'HANQLJNGAND.SYORAGE:.:>':

Refer to point 13. and for personal protection refer to point B. 6.1 Personal precautions Avoid contact with eyes. Danger - risk of slipping. 6.2 Environmental precautions If leakage occurs, dam up. 6.3 Methods for cleaning up Collect using absorbent material (e.g. Universal binding medium), and dispose of according to point 13 •

6. ACCIDENTAL RELEASE MEASURES

&.1 Suitable extfnguishing media Adapt to the nature and extent of fire. &.2 Extinguishing media which shall not be used for safety reasons n.c. &.3 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases In case of fire the following can develop: Oxides of carbon &.4 Special protective equipment for fire-fighters Protective respirator with Independent air supply &.5 Further information Dispose of contaminated extinction water according to official regulations.

6. FIRE-FIGHTING MEASURES ]

4.& Special resources necessary for first aid n.c.

@)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~--, 2/5

Revision: 12.09.2007 Replaces the version of: 19.02.2CJ04 PDF date: 12.09.2007 RASCOfteic AMO (B)

'. ii

n.av. n.av. n.av. n.av.

Acute toxicity and Immediate effects Ingestion, LD50 rat oral (mg/kg): Inhalation, LC50 rat inhal.(mgN4h): Skin contact, LD50 rat dermal (mg/kg}: Eye contact:

Delayed and chronic effects

11. TOXICOLOGICAL INFORMATION

Stable when handled and stored correctly. Materials to avoid None known Hazardous decomposition products See point 5.3

.·, •l 1'0. · -sTABILITY AND REACTIVITY

Liquid Transparent Neutral -7 -100 n.av. n.a. -1 Soluble

Physical state: Colour: Odour: pH-value undiluted: BoHing pointlboillng range ("C): Melting point/melting range ("C): Flash point ("C): Density (g/ml}: Water solubility:

'• ~ .. ·'·" ,, .:~ " \~ ·' .. ...,

~ = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision.

8.2 Exposure controls 8.2.1 Occupational exposure controls Ensure good ventilation. This can be achieved by local suction or general air extraction. If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn. Applies only if maximum pennissible exposure values are listed here. Respiratory protection: If OES or MEL is exceeded. Filter A2 P2 (EN 141) Hand protection: Nonnally not necessary. Protective nitrile gloves (EN 374) Protective gloves In butyl rubber (EN 374). Protective PVC gloves (EN 374) Permeation time (penetralion time) in minutes: >480 Eye protection: Nonnally not necessary. With danger of contact with eyes Recommended Tight fitting protective goggles (EN 166) with side protection, with danger of projections. Skin protection: Protective working garments (e.g. safety shoes EN 344, Jong.sleeved protective working gannents) Additional Information on hand protection - No tests have been performed. Selection made for preparatiOns according to the best available knowledge and information on the ingredients. Selection of materials derived from glove manufacturer's Indications. Final selection of glove material must ba made taking the breekthrough times, penneation rates and degradation into account. Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to manufacturer. In the case of preparations the resistance of glove materials cannot be calculated in advance so it has to be tested before use. The exact breakthrough time of the glove material can be

· requested from the protective glove manufacturer and must be observed. 8.2.2 Environmental exposure controls n.av.

-@!>~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 3/5

Revision: 12.09.2007 Replaces lha version of: 19.02.2004 PDF date: 12.09.2007 RASCOflex AMO (B)

·· .. I

Additions:

S-phrases:

Not applicable

Classification according to Dangerous Product Regulations incl. EC Directives (67/548/EEC and 1999/45/EC) Symbols: Indications of danger: R-phrases:

15. REGULATORY INFORMATION

(class/secondary danger/packing group) n.a.

(class/packing group) n.a. n.a

n.a, n.a. n.a.

n.a. General statements UN-Number: Road/Rail-transport (ADR/RID) Class/packing group: Classification code: LQ: Transport by sea IMDG~de: Marina Pollutant: Transport by air lATA: Additional information: Non-dangerous material according to Transport Regulations.

13.1. for the material I preparation I residue EC d[sposal code no.: The waste codes are recommendations based on the scheduled use of this product. Owing to the user's specific concfllions for use and disposal, other waste codes may be allocated under certain circumstances. (20011118/EC, 2001/1191EC, 20011573/EC) 07 07 ot aqueous washing liquids and mother liquors Recommendation: Pay attention to local and national official regulations E.g. suitable incineretion plant. E.g. dispose at suitable refuse site. 13.2 for contaminated packing material See point 13.1 Pay attention to local and national official regulations

13 .. DISPOSAL CONSIDERATIONS. ·

Problems not expected when used correctly. n.v. n.v.

Not hazardous to water. Yes(VwVwS) 100% OECD 301E *

Water hazard class (Germany): Self classification: Persistence and degradability: * Ethanediol Behaviour in sewage plants: Aquatic toxicity: Ecological toxicity:

12. ECOLOGICAL INFORMATION

Further infonnation No classification according to calculation procedure. Classification according to calculation procedure.

n.c. n.g. n.g. n.g. n.g.

Sensitization: Carcinogenicity: Mutagenicity: Reproductive toxicity: Narcosis:

~@)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ I 415

Revision: 12.09.2007 Replaces the version of: 19.02.2004 PDF date: 12.09.2007 RASCOftex AMD (B)

n.a."' not applicable/ n.v., k.D.v. = n.av. =not available /n.g. = n.c. =not checked WEL = Workplace Exposure Limit EH40, TWA= Long-term exposure limit (B·hour TWA (=time weighted average) reference period), STEL = Short-terme exposure limit (15-minute reference period) I BMGV =Biological monitoring guidance value EH40 AGW = "Aibeitsplatzgrenzwert" (workplace limit value, Germany) I BGW = "Biologischer Grenzwert• (biological limit value, Germany) VbF = Regulations fer flammable liquids (Austria) VVGK = water hazard class (Germany)- WGK 3 "'very hazardous, WGK 2 = hazardous, WGK 1 = slightly hazardous to water voe = Volatile organic compounds I AOX = Adsorbable organic halogen compounds VwVwS =Administrative Order relating to substances hazardous to water (Germany) The statements made here should describe the product with regard to the necessary safety precautions - they are not meant to guarantee definite characteristics • but they are based on our present up-to-date knowledge. No responsibility. These statements were made by: Chemical Check GmbH, Belm Staumberge 3, D-32839 Steinheim, Tel.: +49 5233 9417 0, +491805- CHEMICAL I +49180 52 43 642, Fax: "'49 5233 9417 90, +49180 50 50 455 © by Chemical Check GmbH Gefahrstoflberatung. The copying or changing or this document is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.

Legend:

These details refer to the product as it is delivered. Storage class ve1 (Germany): 1 O - 13 Revised points: 1 -16 The following phrases represent the prescribed R-phrases for the ingredients (designated in point 2). 22 Harmful if swallowed.

r==:.~~~~~~~~-16_._0_T_HE~R_l_N_FO~R_M_A_T_IO~N;;.__~~~~~~~~_,I

Safety data &heet available for professional user on request. Observe restrictions: Yes voe 1999/13/Ee n.a.

~<§>,~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 5/5

Revision: 12.09.2007 Replaces the version of: 19.02.2004 PDF date: 12.09.2007 RASCOllex AMO (B)

I

4.1 Inhalation Supply person with fresh air. Call doctor immediately. Remove person from danger area. Keep Data Sheet available. 4.2 Eye contact Wash thoroughly for several minutes using copious water. Seek medical help if necessary. Keep Data Sheet available. 4.3 Skin contact Wash lhoroughly using copious water - remove contaminated clothing immediately. If skin irritation occurs (redness etc.), consult doctor. Keep Data Sheet available. 4.4 Ingestion Call doctor immediately - have Data Sheet available.

4. FIRST AID MEASURES

EC 231-786-S Index 016-060-00-6 Dlammonium peroxodisulphate CAS 7727-54-0

To people See point 11 and 15. Very reactive dust/air mixtures. Product results in a sensitizing effect. Product is oxidizing. Product is dangerous to health. Product results in an irritant effect To the environment See point 12.

· .. 2.. H~RDS UlENTIFIC,A. TION ·.

Emergency telephone Advisory office in case of poisoning: Tel.: Telephone number of the company in case of emergencies: Tel. +41 (0) 44-857 11 11

E-mail address of the competent person: [email protected], [email protected]

Company/undertaking identification Rascor International AG, Geweroestralle 4, CH -8162 Steinmaur Telephone +41 (0) 44-857 11 11, Fax +41 (O) 44-857 11 00

Use of the substance/preparation Refer to description of material or preparation.


RASCOFLEX B-Pulver ( Pot.&lder)

1. IDENl'IFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING I

Safety data sheet according to Regulation (EC) No 1907/2006, Annex II

,@!)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~-, 116

Revision: 12.09.2007 Replaces the version of: 04.04.2006 PDF date: 12.09.2007 RASCOFLEX B-Pulver

,,

7.1 Handling Tips for safe handling: see point 6.1 Switch on available suction system. Keep away from sources of ignition - Do not smOke. Only use explosion-proof equipment. Only use working methods according to operating Instructions. Note danger of explosive-dust Observe directions on label and instructions for use. 7.2. Storage Requirements for storage rooms and containers: Do not store with highly flammable, flammable, or self-igniting materials. Store products only unopened, in original packing. Observe TRGS 515 (Gennan regulation). Keep away from combustible material. Special storage conditions: See point 10 Protect against moisture and store closed.

Refer to point 13. and for personal protection refer to point 8. 6.1 Personal precautions Remove posstble causes of ignition - do not smoke. Avoid Inhalation, and contact with eyes or skin. Avoid build up of dust. Ensure sufficient ventilation. 6.2 Environmental precautions Prevent from entering drainage system. Prevent surface and ground-water infiltration, as well as ground penetration. If accidental entry into drainage system occurs, infonn responsible authorities. 6.3 Methods for cleaning up Collect mechanically and dispose of according to paint 13. Avoid build up of dust. Use no flammable substances.

5.1 Suitable extinguishing media 5.2 Extinguishing media which shall not be used for safety reasons Water C02 Foam Dry extinguisher 5.3 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases In case offire the following can develop: Oxides of sulphur Oxides of nitrogen If applicable: Explosive dust/air mixture 5.4 Special protective equipment for fir~fighters Protective respirator with independent air supply Chemical protection suit 5.5 Further infonnation Oispase of contaminated extinction water according to official regulations.

5. FIRE~FIGHTING MEASURES L

4.5 Special resources necessary for first aid k.D.v.

-@>~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~---, 2/6 Revision: 12.09.2007 Replaces the version of: 04.04.2006 PDF date: 12.09.2007 RASCOFLEX B·Pulver

n.c. No Yes 1,98 ~ 950·1050 kg/m3 -620g/l

Solid, powder White Characteristic n.av. n.a. n.av.

Physical state: Colour: Odour: 10 % pH-value: Boiling point/boiling range ("C): Melting point/melting range ("C): Decomposition tzo-c Flash point ("C): Flammability (solid, gas): Oxidising properties: Density (g/ml): Bulk density: Water solubility:

9. PHYSICAL AND CHEMICAL PROPERTIES

8.2 Exposure controls 8.2.1 Occupational exposure controls Ensure good ventilation. This can be achieved by local suction or general air extraction. If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn. Applies only if maximum permissible exposure values are listed here. Respiratory protection: n.a. If OES or MEL is exceeded. Breathing mask with f111e dust filter necessary (EN 143). Hand protection: Protective nib'ile gloves (EN 374) Minimum layer thickness in mm: 0,11 Permeation time (penetration lime) in minutes: >480 Suitable are, e.g., safety gloves from KCL GmbH Co., D-36124 Eichenzell, e-mail [email protected], following specibtions: Dermatril® Eye protection: Tight fitting protective goggles with side protection (EN 166). Skin protection: Protective working garments. Additional information on hand protection - No tests have been performed. Selection made for preparations according to the best available knowledge and information on the ingredients. Seiection of materials derived from glove manufacturer's indications. Final selection of glove material must be made taking_ the breakthrough times, penneation rates and degradation into account. Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to manufacturer. In the case of preparations the resistance of glove materials cannot be calculated in advance so it has to be tested before use. The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed. 8.2.2 Environmental exposure controls n.av.

@> WEL-TWA = Workplace Exposure Limit • Long-term exposure limit (8-hour TWA (= time weighted average) reference period) EH40. AGW = •Atbeitsplatzgrenzwert" (workplace limlt value, Germany). I WEL-STEL =Workplace Exposure Limit - Short-terme exposure limit (15-minute reference period). I BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer Grenzwert" (biological limit value, Gennany) I Other information: Sen = Capable of causing occupational asthma. Sk = can be absorbed through skin. Care = Capable of causing cancer and/or heritable genetic damage. - = The exposure limit for this substance is repealed through the TRGS 900 (Gennany) of January 2006 with the goal of revision.

I Other information: - BMGV: - 1- WEL-TWA: 10 mg/m3 (inhal. dust), 4 mg/m3 I WEL-STEL: -

{resoir. dusO

I®, Chemical Name aeneral dust limit

8.1 Exposure limit values

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Do not store over 25~c.

[email protected]~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~--. 3/6

Revision: 12.09.2007 Replaces the version of: 04.04.2006 PDF date: 12.09.2007 RASCOR.EX B-Pulver

13.1. for the material I preparation I residue

13. DISPOSAL CONSIDERATIONS n.v.

1 No n.a. n.v. References

Water hazard class (Germany): Self classification: Persistence and degradability: Behaviour in sewage plants: Aquatic toxicity: Daphnia magna EC50/48h 120 mgll* ToxicHy to fish: LC50/96h Onchorhynchus mykiss 76 mg/1 • Toxicity to daphnia: 120 mg/I Toxicity to algae: Scenedesmus 33 mg/l/4d Ecological toxicity:

Further infonnation The following may occur: Irritation of the skin. Irritation of the eyes lrritalion at the stomach Inhalation: Irritation of the respiratory tract May cause sensitization by inhalation.

n.g. n.g. n.g. n.g.

Yes

... 495 k.O.v., Irritant k.D.v., Irritant Irritant

Acute toxicity and immediate effects Ingestion, LD50 rat oral (mg/kg): Inhalation, LCSO ratinhal.{mg/l/4h): Skin contact, LD5D rat demial (mg/kg): Eye contact

Delayed and chronic effects Sensitization: OECD4D6 Carcinogenicity: Mutagenicity: Reproductive toxicity: Narcosis:

. -.'\ , ·11. ·:TOXICOLOGICAL INF.=ORMATIO"f ;.::'; ., . , ·.

Conditions to avoid Seepoint7. Protect from humidity. Heating, open flame, ignition sources Decomposition: > 12o·c Materials to avoid See point 7 Avoid contact with other chemicals. Avoid contact with strong alkalis. Peroxides Reducing agent Metals Organic materials 17 Keep away from combustible material. Hazardous decomposition products See point 5.3

10. STABILITY AND REACTIVITY


4/6

16. OTHER INFORMATION

Symbols: O/Xn Indications of danger: Oxidizing Hannful R-phrases: B Contact with combustible material may cause fire. 22 Harmful if swallowed. 36/37/38 Irritating to eyes, respiratay system and skin. 42/43 May cause sensitization by inhalation and skin contact. S-phrases: (2} Keep out of the reach of children. 22 Do not breathe dust. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 37 Wear suitable gloves.

Additions: EC label EC number see point 2 "CE" Obseive res!rictions: Yes Observe youth employment law (German regulation). Observe law on protection of expectant mothers (German regulation). Observe restrictive guidelines 761769/EEC, 1999151/EC, 1999177/EC voe 1999/13/EC: n.a.

Classification according to Dangerous Product Regulations incl. EC Directives (67/548/EEC and 1999/45/EC)

(class/secondary danger/packing group) 5.1/-/111

n.a

5.11111 (class/packing group) F-A,S-Q

02 12

5.1/111

1444 General statements UN-Number: Road/Rail-transport (ADR/RID) Class/packing group: UN 1444 AMMONIUM PERSULPHATE Classification code: LO: Transport by sea IMDG-code: EmS: Marine Pollutant:

·AMMONIUM PERSULPHATE Transport by air IATA: Ammonium persulphate Additional information: Minimum amount regulations have not been taken into account. Danger code and packing code on request.

14. TRANSPORT INFORMATION

EC disposal code no.: The waste codes are recommendations based on the scheduled use of this product. Owing lo the user's specific conditions for use and disposal, other waste codes may be allocated under certain circumstances. (20011118/EC, 2001/119/EC, 2001/573/EC) 06 03 14 solid salts and solutions other than those mentioned in 06 03 11 and 06 03 13 Recornmendation: Pay attention to local and national official regulations E.g. dispose at suitable refuse site. 13.2 for contaminated packing material See paint 13.1 Pay attention to local and national official regulations

,@>~---~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 5/6


n.a. = not appficable I n.v ., k.D. v. = n.av. = not available I n.g. = n.c. = not checked WEL = Workplace Exposure Limit EH40, TWA =Leng-term exposure llmlt (B-hour TWA (=time weighted average) reference pertod), STB. = Short-terme exposure limit (15-minute reference period) I BMGV =Biological monitoring guidance value EH40 AGW = "Arbeilsplalzgrenzwerf' (workplace limit value, Germany) I BGW = "Biologischer Grenzwert" (biological finit value, Germany) VbF = Regulations for flammable liquids (Austria) WGK == water hazard class (Gerrnany) - WGK 3 =very hazardous, WGK 2 = hazardous, WGK 1 = slightly hazardous to water VOC = Volatile organic compounds f AOX = Adsorbable organic halogen compounds VwVwS = Administrative Order relating to substances hazardous to water (Germany) The statements made here should describe the product with regard to the necessary safety precautions - they are not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge. No responsibility. These statements were made by: Chemical Check GmbH, Beim Staumberge 3, D-32839 Steinheim, Tel.: +49 5233 94 17 0, +49 1805- CHEMICAL I +49 180 52 43 642~ Fax: +49 5233 94 17 90, +49 180 50 50 455 © by Chemical Che<:k GmbH Gefahrstoflberatung. The copying or changing of this document is forbidden except with consent or the Chemical Check GmbH Gefahrstoffberatung.

Legend:

5.1 B 1 - 16

These details refer to the product as it is delivered. Storage class VCI (Gennany): Revised points:

~@)~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~-~ 6/6 Revision: 12.09.2007 Replaces the version of: 04.04.2006 PDF date: 12.09.2007 RASCOFLEX B-Pulver

1 .,

I MSDS for SikaGrout 114 I Appendix8


MS NO: 25045-D2200-10-3GS-C-019 (Rev.1)

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T~ CONTAIN Sf.>ILL ANO COLLECT ANb TRAN'SFER - Nili1ACT. ~!!EP SPU .. LS AW,AY FROM SE;lhliERS AND

6. ACCIDENT AL REL&iASE MEASURES

11 ABLE PR~E . ~CONTF)\IN OFWAitER.

N~T EX!i?~CTE~TO PRESENT A SIGNl'P'!CAN'.:F HAZA~E>.

.ROUGHL y wn:;H WAffiER. C<i'XtllSUL T JSHYS lQ.IAN. THQF<{OUGHLY WITH WATER. REMOVE CONTAMINATED

· IERSIST CONqULT PHYJSICJAN.

DO NOT 11\\lDUCE-VOMITING. Gf:Sif ME[i)lCAL AtfTENTION IMMilBDIATEtY

[ I I 1

I I ;

M~ CAWfE IRftl'TATION

''I. COtvfiJ;!OSfTlliJN/ lN_ao&MAllON GR~SIBNTt:f GEMjJN'T Arl!JJ SA~!J~

"If 3. HAZ~RDS IDENTIFICATIO:N

Mll\}Y-CAU~E IRr{lG[iATIOftt .. BUR~.-DAM![i\GE 1(;i,;,-EYE§ --------------~ MIW CAUSESKl!ifllilRRtrATION,

M,A)Y CAUSE IRR.l;y"ATION

iika!PJta·ut'J 14 .~ilfa G:l!1ff B.S .. C. c. P .o. Box 157 Kin dom of Bahrain. - Te:!: ++97;15>17735 560

w;J·

~· BRi\li)UCT NP.ME: §JKAG~~lJT 11·4

5 titici;mon no .. OM-03

Version no:1

MSB$

----

STABILITY:

DECOMPOSITION:

~ES

NO HAZARDOUS ~lliACTIONS V\/HEN STORED AND HANDLED Al:J©ORDING TO PRESCRIBED fN~TRVCTION'S

ST ABU • .JTY AND RSA~1~VITY

1112.0 . PH VALU~:

WATER SQb!JBILl~J_Y __ ,.,,.,.. __ 1 °_Yo ------ • 11·11'

GREY 1~00 KG/M3

COLOUR:

APPEARANCE:

lcLONG T

CONTACT. WE. LONGS EAR NITRILE O~·' ER CH

8. EXPOSl!llli CONTROL§ll'~RSONAL P:f8J'TECTION

GiNrEEmlti50ifi• tnRf<o5iL]~lGeN 70R LG¢AL a>BAUST OED.

ACEl~RQTECTION FACE MASl<,SAFETY GLASSES/CHEMICAL GOGGLES

P~(Prf:CT F~OM fl'R Si);{,'IA:m·(i?~, Af\1

AVOID EVE'M HL Y AFTER USING

TICE! $0 ENT Al

PRODUC7Ti.

/HYG'l'ENJC TICES

A'~r» STORAGG STORE tN QR<t91NAL PAOKAGING. STOR~'1l{f A COOL DRY .. ~ AREA.

MSDS 6dift0n: 1, 2,©:t,i 1€1 ~6. CM~0:3

1 SikaGrout 114 G AND STQRA&E

• 3

e

TRANSPORTATION

14. TRANSPOiT I

f\!_OT ClASSIF~~¢!c

15. REGULATORY l~1PQRMA.T:ION

1:3. ll[SP8SAL C-ONSt:DE'~B1161S

F§:r~·FJ!~~i1·:r:m A5ul31't1~~a~ wi1H RBGUL.A'TION$,, N~fr oo 11ll!~ll'ft7'j!~~I~

,At i . ----~'-----'-,.,~--~~-~--~---~--------

SKIN MAY CAUSE IRRITATION.

INHALATION MAY CAUSE lRRITATl.ON '--~--,---~--~-----------'''"''' __ ,, ,_, _

EYES HARMFUL.

lRRITANT.

INGESTION

USE AND EXPOSURE, N 11. TOXI UNDER EFFECTS.

M®GS editiefl( 1 . ~©:(ii lliienfitioafi'.!:>'n no. OM•OS Vettsiortl,r;i~0;;1

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