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ALTERNATIVE SPIRAL WOUND GASKET FILLER MATERIAL TO REDUCE FLANGE FACE CORROSION
Paul Welsford AMIMechE, Flexitallic LtdOGA 2017 – Subsea UK
PREVENTING FLANGE FACE CORROSION
>300 PLATFORMS
>8,000KM OF PIPELINES
> 1 MILLION GASKETED
FLANGE CONNECTIONS
PREVENTING FLANGE FACE CORROSION
“Every flange connection in a plant is an essential built-in weakness that allows
the overall plant to be stronger in the long-term by giving it the power to be
maintained safely and upgraded with relative ease.
All it takes is one of these weak links to not be strong enough for the whole
system to fall apart.”
- Some Smart Pipeline Engineer
PREVENTING FLANGE FACE CORROSION
CONTENT
• Corrosion – the hidden enemyCorrosion: challenges & mechanisms
• Current products on the marketWhere are we at?
• The New Solution
• Testing
• Summary
PREVENTING FLANGE FACE CORROSION
Bolted flange joints can be vulnerable to
gasket degradation and
flange face corrosion
PREVENTING FLANGE FACE CORROSION
CORROSION – challenges & mechanisms
Detection Waste HSEShutdown
(Unscheduled)Cost
PREVENTING FLANGE FACE CORROSION
Traditional Sealing Materials
• Graphite is widely used for spiral wound gaskets. An electrical conductor and highly “noble” so promotes corrosion.
• Mica is sometimes chosen in place of graphite however it exhibits very poor sealingcharacteristics.
• PTFE is not fire safe. Associated with increasing crevice corrosion in certain applications.
PREVENTING FLANGE FACE CORROSION
GALVANIC SERIES OF METALS IN SEAWATER
• Seawater is an electrolyte with well known
effects on different materials
• Graphite is the most noble, causing corrosion
of common stainless steels
• Relative position in the table, distance apart,
contact area, temperature, flow rate all affect
corrosion
PREVENTING FLANGE FACE CORROSION
CORROSION – challenges & mechanisms
1. Flange and gasket material remain important criteria
to avoid corrosion
2. Choosing the right gasket can have significant
impact on galvanic corrosion prevention
3. The selection of traditional gasket materials leads to problems
PREVENTING FLANGE FACE CORROSION
Market need for new materials
and corrosion resistance
combining optimum sealing properties
PREVENTING FLANGE FACE CORROSION
New Material (CORRICULITE) Development
• Formulation optimised for corrosion applications
• Inert, non-conductive filler material prevents the onset of galvanic
corrosion
• Improved sealing performance compared to graphite-filled spiral
wound gaskets
• Fire safe to API 6FB
PREVENTING FLANGE FACE CORROSION
Evaluates gasket
materials
resistance to
seawater induced
corrosion
Evaluates gasket
sealing capacity
under “real world”
conditions in a
flanged connection
Measures leakage
rates against a
gasket stress with
internal pressure at
different
temperatures
AMTEC
sealing test
PRODUCT PERFORMANCE VALIDATION
Corrosion
testing
Submerged
testing
Records the
electrochemical
potential of sealing
materials
Electrochemical
evaluation
PREVENTING FLANGE FACE CORROSION
1.00E-08
1.00E-07
1.00E-06
1.00E-05
1.00E-04
1.00E-03
1.00E-02
1.00E-01
1.00E+00
1.00E+01
1.00E+02
0 20 40 60 80 100 120 140 160 180
Leak
rat
e [m
g/m
/s]
Gasket stress [MPa]
Graphite Corriculite Mica
AMTEC SEALING TEST
• A flatter line in better as it indicates resilience to unloading in service
• New Material significantly tighter than both graphite and mica
x500
x100,000
PREVENTING FLANGE FACE CORROSION
CORROSION TESTING
PTFE Isolator
PTFE Isolator
PTFE Isolator
PTFE Isolator
PTFE Isolator
THERMICULITE
NEW MATERIAL
NEW MATERIAL
GRAPHITE
Control sample
No visible corrosion
No visible corrosion
Corrosion due to presence of graphite
PREVENTING FLANGE FACE CORROSION
ELECTROCHEMICAL EVALUATION
• The graphite gasket initiates corrosion at a level around half that of the New Material sample.
0
50
100
150
200
250
300
-5
0
5
10
15
20
25
30
35
Vo
ltag
e (m
V A
g/A
gCl)
Time
Co
rro
sio
n P
ote
nti
al (
mA
)
Corriculite Current (mA) Graphite Current (mA) Voltage Step (mV)
PREVENTING FLANGE FACE CORROSION
SUBMERGED TESTING
• https://vimeo.com/210782491
• VIDEO
PREVENTING FLANGE FACE CORROSION
SUBMERGED TESTING
• Flange assemblies submerged in seawater and pressurized with Nitrogen.
• New Material (4%)
• Graphite (17%)
• Mica (20% in 1 hr)460
480
500
520
540
560
580
600
620
0 25 50 75 100 125 150 175 200 225 250 275 300 325 350P
ress
ure
(p
si)
Time (Hours)
Corriculite Graphite Mica
PREVENTING FLANGE FACE CORROSION
FIRE SAFETY – API 6FB
• Pass achieved
• Zero leak rate measured
PREVENTING FLANGE FACE CORROSION
SUMMARY
• Addresses shortcomings of current materials on
the market.
• Extends equipment life by preventing corrosion
• Eliminates safety & environmental risks
• Reduces downtime & production losses
• Reduces costs associated with maintenance
• Maintains seal integrity even in an external fire
situation
www.corriculite.com
PREVENTING FLANGE FACE CORROSION
THANK YOU
ANY QUESTIONS?
www.Corriculite.com