ANEXO A: Tablas de Base de Datos SIPGLUZ

iab

ia d

e A

nexo

s 22

1i151

200E

S C

ompo

nent

e / to

rrnu

ia

ire

so ~

ole

c~

rre

sio

n

~rii

e

mp

era

tur~

olu

me

n i~

ac

tor ~

ce

d ZR

A

i WS

RK

M

etan

o C

H4

16.0

43

667

-116

.66

0.09

88

0.01

08

0.28

8 0.

0108

E

tano

C

2H6

Pro

pano

C

3H8

¡-B

utan

o C

4H10

n-

But

ano

C4H

10

i-Pen

tano

C

5H12

n-

Pen

tano

C

5H12

n-

Hex

ano

C6H

14

n-H

epta

no

C7H

16

n-O

ctan

o C

8H18

n-

Non

ano

C9H

20

n-D

ecan

o C

10H

22

Sul

furo

de

Hid

roge

n H

2S

Dio

xido

de

Car

bono

C0

2

Nitr

ogen

o N

2

Agu

a H

20

C

7+

o

ANEXO 6: Procedimiento cálculo ecuaciones cúbicas

Fuente: Manual del Ingeniero

Z O O O O O O - - 7 - ~ a o o m o m o m o o o

m Z 8 O 0 0

O

O

t-0

0

~ 8 8 8 0 ~ 8 Z ~ O O 0 8 & ~ r I " " " 9 " " - ? " " " " " 0 0 "

0 0 0 0 0 0 0 0 0 0 0 0 0 0 ~

0 0 0 0 0 0 0 0 m 0 0 ~ a ~ o m m m a a o T r T r o z ? $ m

0 0 0 0 0 0 8 8 0 0 0 0 0 ~

z; T--

C?

7

Trcn

m $ 3 a 3 0 0

~z2x23 , - O 0 0 0

r - - m - 0 m . -

. - o 0 2 0 0 0

o 0 0

m c n

o 0

0

b C n m m O v

2 0 0 0 4 0 0

m c n - m m , , , c o b 0 0 0

- 0 0 0 0 ! 2 0 0 0 0 0

0 0 0 0 0

a a 0 m

0 0 0 0

m

U 0 U . - . - C O U O O O I U Z I

q 0 0 0 9 0 0 0 0 0 q 0

< O b $ a - N r

O 0 0 0 0 0 0 0 0

O c n W 0 0 a 3 0 3 o z z o g 2 g g U 0 , 0 0 0 , 0 0 , 0

0 0 0 0 0 0 0

m . - m m z T r 0 0 0 0 0

0 0 0 0 0 0

0 m P - m ~ m 0 0 a 0 0 0 0 0 0 ~ r - ~ m c o a 3 T r m b c n w m o W o o O r - - . - m ~ 0 0 w m ~ 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

a 0 P 4 - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

a + O Y . - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0

0 a D m a O $ b c 0 N - 0 0 0 0 0 0

0 0 0 0 0 0 0 0

9 "

~ m V m 0 0 0 m 0 0 m 0 m

p $ 2 ! s ~ s ~ ~ ~ ~ c ~ x

o r a r - m m m a a m o 0 V b r - m o w c 0 0 r o o r T r P 4 - 0 - 0 0 0 0 0 0 ~ 0 0 0 0 0 ~ 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0

O V O C D N b C O V r q a O q t - C O V V W r O

0 0 0 0 0 0 0 0 0 0

O

0 4 : Z 2 ? Y Y 2 Z : Z : 4 U 6 ó 0 0 0 0 c 5 ó ~ ó ó 0 6

0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0

m a 0 0 Z O

r o

0 0 0 ~ 0 0 0 0 0

0 0 0 0 0 0 0

m 0 - m a 0 W 0 0 0 0 0 C o o o o o o r ~ ~ t - 0 ~ c 0 0 0 0 0 0 0 0 0 0 - o = 0 0 0 ~ 0 0 0 - 0 0 ~ 0 0 0 0 c

c n ~ a m . - m m t - ~ - o c o O o . - m b r . a 3 - m m O b T r m O C

0 0 0 0 0 0 0 0 0 0 0 0 0 C

O -

m 0 0 o . - m m o m 0 0 O ~ m T r a m o O m o c ~ 0 0 0 0 0 0 - a N m 0 0 ~ 0 0 0 0 0 ~ 0 0 ~ 0 W 0 0 0 0 0 0 0 0 0 0 0

m m 0 3 O w w w b O m O C 0 0 0 N 0 m r - m 0 c n m C 0 0 0 0 0 0 0 0 u J ' c D C

o o o o o o o o o 0 ~ 0 c

. - 0 0 m m . - ~ b m u J O o

c o r - . - a 0 0 0 0 0 o . - 0 T r c 0 m m o o 0 0 0 0 0 w m 0 u ~ 0 0 0 0 0 0 r - 4 0 0 0 0 0 0 0 0 c ~

V c o c o N t - m 0 0 0 0 0 0 . - 0 T r a o m m 0 0 0 0 0 0 0 a ~ a 0

0 0 0 0 0 0 0 0 0 0

0 0

m r ~ O C n a 0 o o o a - T r o 0 0 0 0 ~ ~ U ~ O O O O O O c ~

a ~ T r a 0 0 0 0

g & g g g % % g 0 0 0 0 0 . - T U , 0 0 0 0 0 8 0 0

0 0 z 0 0 O m o o c ~ 0 0 - - . U ! 0 0 0 0 c ~

V a D O O O O o o m m o o o o m . - o C l 0 0 0 ~ - u ! 0 0 0 0 0 c 1

Z E Z z z o o o c i

o r a 0 m m - C ) T r - 0 0 0 " U )

o o o c i

o a 0 0

o ? ? o

0 C l

-

0 C '

0 K

ANEXO D: Constantes Lee-Kesler

Fuente: Reid - Prautnitz - Poling

ANEXO E: Propiedades Termodinámicas para Gases Ideales

Fuente: Charle A. Passut and Ronald P. Danner

. - . - - . . / .

' j . :2-% r-7 . i r t p ~ ~ i r \ ( , and Enfropy I

Charlui A. P a s s u t and R o n a l d P. D a n n e r i

/),,,JIJ~IJII~.III 111 ~.'III.I~I~~~II/ K I I~~I ICI~~~I I~ , 'l'l~(: I'CJII~.Y~~~VILII~~ Sliil~: Uiiit~r.4i1!1, I J ~ i i i ~ ~ # i l y pork, illl. 11:;jo:

The occ<:pied-voluec of ihe ideal gas eniliolpy, heul copocily, ond entropy of 89 compoun~lr, rnbslly hydro-

corbon~, hove been rzprrscn\cd by o s c l of ihrce ihermodynornically conr i~t i~nl polynoniicilr. The conriunt,

{or 1112,~: equolionr, der ived b y ininiii~izing the dcvialion: in u11 ihree propcri;cs siniu U. an* 9 usl Y # are l ab i~ .

!atcd ipgeihrr with l h t a v e r a g e oiid maxirnurn 3ercenl dcviolion for aath compoundllhe overol1 crrcr 1

/+ aiiolysir indicara lhol llicrrriodynaniic consirtcncy con b e inaintainad wliilt y i c l d i n ~ crc<:llcnt p r e d i c l i ~ o . . ior the Iliree properlies. I

id::;l ;irolwc.riies iirc l i~cqiici i t ly rccliiiri~c! iii corruliitioiir iií c ~ i l I ~ : : l ~ i ~ ~ , 11i::it coli:icity, iiiiil c i i l i~u~ iy . 111 ~ei ieri i l , tiiew Cp* = B + ? (7T f 3.CTJ .f 4 RT' + 5 t'7.4

p u b l i s l i ~ ~ ~ i: f~al 9 5 e ~ i t ! ~ i i ~ ~ ) y , Iitiit c i i ] ~ i t ~ ~ i l ~ , UI~(I eiitmj>y YL;.u~s iii tiibiiiii; loriii. 'l'liesc v:iliics wcrc cnrrccte<l lor thc

'1, h'(P - Y',!') + '1, P(7" - T&d] + '5 (. )

n i c~ l~ r i i l s r ycigiit i.lini!~c tto 1110 ci:rl>oii-it> I,:iais. 1:rcqiieii~ly ~viierc is t l iu ~ I Y C t c t ~ ~ ] w r n l i ~ r t [W 1116 ~~i i t rop!* v i l i ; ik i ( i l i i k is 1iici.c coiivt.riiciit ia 1i:ivc -tllcsc vv;iiric.s i.~.l)i.c*sciiletl by .

(lOí?), ii i id c! is l l \c COIIS~IIII~ of i i iLe~r: i l io~i. $?[\U>! ioi., 1 iiiuy ;:iijI)~ti(:;il er!:i;~~i(:iis for co1111iuttr : i ~ i j ; I i cu l i i ~~ i~ . 1)c I t i r~ l io r ~ i r n ~ ) l i l i a l by coinl,iiiiiig tic' coiirilri i i~ basi :oi)i-

-;c\-ci.;il iii~ilii;il> II~VC; l>(*:ii ii..;c.tl t f i c i l ) ~ : i i i i iiiiiil'.lic:ii es- l;~1.~i1111.0 Lcrnls wilIi !,hc colrstaiil c' 10 givu E(lrluli~i~l 5 : , . ~ i o l i ~ . I:I .I;I~ .\LJl ' . " i 'c- I~ i~i~;~l 1);iL:i l ~ ~ ~ ~ k - l ' c t r o l c u ~ ~ ~ I'T..i" I t ~ f i i i i i i ~ " (1971), t i stt. tif tlirco i ~ i ( I ~ . ~ x ~ i i l ~ ~ i i t ~iu!y~ioi i i inl S* 1 ) Iii T f 2 CI' f 07'' $.

CI~LIII I~I~I~'~ (VI. i ~ I c : i I &LIS i : i i t I ~ : t I ~ ~ ~ , II~-:IL v:~li:~i.ity, niii l I : I I L ~ L ) O ~ ' l a B7" f '/r b'T' +- G ( S ) (ir : giveri. ;\ii i i i<le~~eiielr i i l se1 of coii.st:iiib ¡S ~ i rbv id id lor r;trh ~mlyi ioini i i l :!:u1 Il i i is oiic c;riiiiul K ( i Iruiir olio cquntion to tlie ~ [ l i n r 11y Ilie stsiiilaril ~ l ic . r t t iudgi i i~ i i ic loriiiiilii-¡.e., 611 = /Cp'dT iiiiil AS' = J(Cpw/l')tI'l'. '1'lii.s iiicrliod l i r c v i ics grc31<.r ngcur;rcy iii fi<tiii# oí ~ l i c i i i t l i \~ i~ lu: i l liroperlics a l the esl~riisc o l kiii~ 1licri~odyiüiiiiic:i1Iy iiii-ciiisistciit. Iii n rccriit, ~~tibl icl i t ioi i , l'liii!li c t ul. (1971) rcvic\vcd tltc

~)iiblislic.tl cclu:itioiis lor l>redictiii;: itle:il #iis Iic:it c:il>cirity ri i i(1 ~> iewi i ie i l n li\liii~ o l coiisrniits lar l l i c itlc~a1 x;is lient iii))uc¡ly

,o[, iiiiiiici"ous Iiytlrocurl>oici uird rr1:itctl cciiiij>ouircls iii tlio furiy :

C/,v M (1 + bT c7Ia d- r1'laa (1)

l l~ l t ies ror LIIC ei~ti.o,iy cii(1 011tli111~~y CIII 1x1 . ~ ~ r c ~ l i c ~ u i l froi!~ tliis c i l i ia t i~t i 1)y tlia nl)j~ruliri:i lc tliri.ii~ocIyiiiiniic i~lntioi is. l !o \ r t~vr r , :-i!iit! Io'i5 i~ i . . . iirctir:~vy for . -. CIIIII:II~IY-~II~ . . . , - . ~)IILI.OIIY . - -

.. v llli(.> i5 illl~\~ir:lllli! IIQ; 1.I1is ~il.,,l:!~l!!l?., >illl.c. ~~llll ; l l~Ll l : l l l l l ! : lL ( ' --. .- . . . . . . - . . ! : ' c4ipiici:y h11:i.Gr is 11ut t l ~ ~ ~ r ~ t i c u l l ~ ~ v i i i i ~~ i : i i ~ i c ( I to [ollutv

' ' a 1): l )~ r i i c ! i l :~ i ' ~ ~ o I y i i o ~ ~ i i : ~ l . :I'lti: III~~~IIOII i l c s c r i l ~ ~ l lwlotv ):icl(!s- ~ I !c~n iw l~ i i : i i~ i i vn I Iy C U I I ~ ~ ~ ~ ~ ~ I I L c i~~~ : i i i o i i s \vil11 ~ ( 1 0 1 1

. . .., . - .-. ri:c~~rscy ior 311 t111,cc IIIIJIICI~L~~-s:

m ' 1 l'iir loriiis of tlie ctliiirtiuiis ii-il t\.ci.c':ia Icllows. E'or tlic 8 : 1 ; ; q ! ~ ~ l i ~ l l ~ l y :

wlicrc thc constnnl (: iioiv coiilniii:; l l ic luse crorrcrt ir111. . .

Tl ie t l i ~ l u buws u 4 \vere O lJtc/lb n l O O I i for tlie eirtlinlpy riiitl O l ~ t u / l b '11 n l OOR aiid 1 nti i i pr<r*slire Cor tI!c F.!IIIII~~-- tlic siiiiie ics tliose iisccl f¿r thr A l ' ~ . l ~ c ~ r i r c l i I'rojecf 4.: t:iIiIcis. (11 slioiild be i i o l ~ l t l iu t t l i cy ,)asc.s. cn i i~ io t bo ut-l !o: n sysloi i~ iii wliicli n clieiiiical reuc:ioii Iins occurrctG) 'I'lic 011-

~ l i i t l l ~y , I ici i l cuoncity, niirl ciilropy dnlu iixtl iii I)I~,:? c:ori.c. Iutioiis wero tnkoii f ioin Al'I Rcsmrcli 13rojccl' -ii. i .iili i i i c csc:cl>tioii of SO,, Has, aird iJI.18 wilicl\ wcr: r l i ~ i i i i t r i li-oni hlcl lr ide eL nl. (1963). l'lie eirtire ieiiipcrr tu l r? ru i iu :iviriltille l r o i i ~ ~1;o r\PI-I~I'-L.I d1i.t.n !va3 includcd. l'h i <Ir~i.o( r ~ f ~ h o ~mlyiiorniirl iir Erliiutioii 2 \vua cliowir 11). b i I ~ i ) i c i i ~ ~ ~ l i u Iii~l~i-~)vvad occ\ii'iicy obtirl~iact tr l l l i u t I t l i t i i~~\u l ~ u n i i : t ~ ~ i i i i i s ,

LIIC iiicrcnscd coiirl>lcsily o l 1110 criiiiiioiis.

Corrcloiionol Molhcid

Siiii.c? Lhc c:t~iaki i i~s iii thc ciliiiiliciii iirci liiic:ir, :r Ijiii.i\ i i iot i iof~ oí s6ti~tioll wnti iii(Iicfitc(I. 'I'IIC tIirce :Ii!fcr :IIL 'iI: 1: l !.ylics ( c1111 in l~~~~ II(:IIL ci ip; ic i~y~ niid c i \ l ro~iy) w r a irrit:~pl,l

: ¡ t i IIIIL. i r ~ i i ~ r i ~ IY]. 'l'lir x v c i i ccclliciciiis tu Liic th i rc il:li:i Lioii5 .\rcro nrrniippi iii tlie coclficiciil i i i i i l r is I;I 1. ,-! .hill])C'?: tu1.c innlrix wiis 1)rcl)ni.ed LO sutisly Equutiuii G:

. .

. I ! : /:licrc O, C, D, 8, uiid urc iIriirccl c~rlfieicliir, ,vir)i lbc 'I'ttc ~ubiCr¡l>ti deliote W W S niid ~ 3 l ~ n i i i ~ ~ ~ c s ~ ) c c ! ~ \ el: . 1 ' ' i i i tha~p i : iii l ~ l ~ i / i b hiid ti10 l c 1 1 1 1 ~ ~ ~ 1 t i i ~ e iii 'lt. ! 3'0 solvo for tlie v ~ I u c s iii 1Iie 1-41 matrix, fhc 1 TI iiiiitris ; . m hrrl ~rui!sloriiic(l irito A S(I\III~C IIIIIL~~S b y 1 1 1 ~ 1 t i p l ~ i : i ~ F(lcii:

, ' 1 Tu ulioiii corrcspoiidencc * I i t r i i l t l Lu iicl~li~esicil. " Lioir G byt l i c trniiqGse o l llrc [TI ni:itris, (TIT;,, -

. . - , . . 1 z

, l , .

Ind. FCQ. Charn. ?roce,, @ , t . gst..lop, V o l l l. So. a;, f6 i71 5 3

I

Tliti ~ r u l t oi thlr operotlon lu:

h. \\.hei.ei[~] and IC] are rhs resiiltcriit nintricea: - l'liai:;t j r ~ a t r i x mny be e\*alualae<l 11s itivcrliii,! Llie [S] - niiiiris. T l ie riiatrix [S] is rquivnleiit to n sirniilkii~r.ous 1ensG s q u n ~ ~ s aiinlyt:a for the tliree seta of ideal eqiintiocis. A ~ ) roo l ot thi.1 j>rocediire is given by Zelcrnik ni id Conloi i (1961). 'l'lii! [ f j matrix in Equntioii 8 caii be iiii<rrkrl 11' slniitliircl

,wlur i-ioli tochniques to fiiid the vnlues iii the cocfficieiit in:i- t r i s l.:.: 1.1 Ilo\vevrr. this inatris ~>oswssas ce rb i i i rlx?rial.prop- crtics iv$icli m1.1 sitnp:dy the i.iversioii. l'ho [SI inntrix is ~:ositivc, :qmnictri~, ~ n d i ~ o n s i i i ~ llar. 'i'licrclorc, tlie n r e t h d o' 3 3 ' ~ F y cnn.w used tb inrer t the mntrix (Lal)idiis, 1962)

-'This ii'ethod minimires rouhd-ofl errorti in t l ie i i iv ersion. Yie Ctolksky method wi l l not be.described licre, bu t was b c i l t ii. !o jlhe computer program developeri to solve for Llie i t l t~al ga 1 propartr coefficients. '.. ..

..nitiml *rk wi. tl ie c luat io iu shows-ed !hnt lorciiig t l ic en iha l l *~ cquat io~ i through O n t OOR wriu ai i uiiiieceswry nnd unclejirniile restriction eva? thou~); the bacc for ti ic vnliics is 3 fil ; OOR. Since none oí tlie dato. are iii the rnngc olO"n iiiid . tirice no emp i r i c~ l quat ion for t l ie ciithnlliy .ciiii be ex- (rn~olnted outsidc the reni? oí (he n r r i l ~ i l l c dota; tliero is Jo spl~nrent Iws rmm the ndditipii o1 n coiistniit, Lcrn1)e.r- %un t i nde l~ i i den i km, to the enthalpy equntioii. Iii ths %me \vas tho heat capacity equ t i o i i hiis n coiiskiii~, terni. 'Yian the tnthaipy equation is diííorentinlcd. A ~ n i n tlie Iient a p s t i t y is not p r e d i c w to iero n t absoliite zero 1)iit tl ie Muation lor Cp* u not npplicable iii this rniiEe. 'J'lie t~'iisLniit k m ;nEqt iot ion 4 (G3 is tlie j)&ickd eiitroliy a l 1111- irlcnl :% n t the ciosen base tempernture of iOR niitl iiiiit I)ressiiri '&S \.alue tomes out of the &grcssioii niinlysirr, i i i i t l o i ic t F\ii i. sitice there L no dntn in this rcgioii, tl ie ~rrerlicte<l &e Iins i i t) real sigr.iicanc~. The temprat i i re l im i ta t io is qie data aie showii i.1 Table 1.

from 295'1; iiiiCe Tlii i i l i 's etl;iatioi~s ~ i i i i o t In i iwt l l o cIiiri:ii nbsoliite vniuek t

' The results ~ i v e n in Tnble 11 sliow i~ in rked in i~ i rovr i i ri it over tlie i i idcpndcnt set of tlim eqiint.ioiis rc lwrt t t l ii: 111:. hl'l Tcclii i irnl Data l'h~ok. 111 coiiil);iri..oii l o tl ic cc~rreliriiriir: of Thiiili et nl. for tl ie 75'coinmori l iy~l~oc; i r lwi~is, tlirn. k n Ioss i i i~i icci irr icy iii tl,e j>res:ictioii oT I i r n t r:il):icily, Ini i a docidwl ii i i l)mrenieiit w:ix obt:~iiit<l iii tl io c i i t l iu l ly l)n*~;r- tioiis. Siiiro the eiitlirilpy t l i f i ~ e i i i ~ e s :irc, iii ~eiiernl, I l ie iiiort iiseriil qii:iiitities, tl i in inil>n>\.ciiiciit is si~i i i f ic i i i i t . Piirllirl- more the cqiiatioiis preseiikd iii tliis tvork Iinvc 111s utlrniit: gr of es le i i f l i i i ~ tlie tcinlaniture rriiigt. 011 t l ie oi l ier Iiniirl, tl ir i i c~v ly tfevcl0lrcd eqi,ntioiis Iinve tlir tlisn.(lrniitn~c of Iw.i.1~ oiie (Iqreo 1 i i~ l )c r iii :.lroir Imwcra of T roml):iml da tlic! etliii- tioiirc of lliiiili ct :d.. 'Jiit tlii~ ntltlrtl ronil)l3sily is n iirvr~sii!. wlicii I.Iit? <irlciiitioiri ;irc ~ilil)linl ov;ir i l i c l n r ~ r r t ~ r n ~ ~ ~ r : i L i i i c niiiKc iiiv:i;l:iblo ror iii;, .ijO curii~miiiitls. Iii cuiirliwioii, F~1iiirtioiis 2, 5, : i i i t l 6, t o~c t l i t * r iriili IIii-

coclliriciih iii Tiible 1, rire r cco i i i i i ~~ i i t i e~ l for ~ i rcdict i i ig tlic itleal KUS propertics of the caninmuli<l li:.ie<l. l y i c y rel>re'c.iii n therino<ly~i:ii i i ia~lly cbiisisteiit ,WL df ~t~ i i : t t io i i s ~ v i t l i ~ir i i i i i i i i i i i i overnll ~)iwlict iveerrorj.

rhe onata:its obtained for the enthnlpy, hent ciil)ncity, ni i t l cqualioje o f the 89 compounds nre giveii iii T n l ~ l c 1.

l overnll q revge larcent error nnd mn~ i i n i i i i i error o b ing the nbsolute valucs o l tho eiitliiill)y, entropy are also given. the results of thia work, t l iow of ~ I i e hl'I

iiictrl D n t ~ Oook (1971) nnd l'hiiili c t :il. (1071) nrc The equations of Thi i i l i Iinve bccii roiii-

1iydrocarbonscommuii to h t l i stii(lics.

equntioiis o l tliis w r k i\.oi.c raiiqc. The vnliics o l

'Y a,id cq:mpy f o r comparison witli l l iu rorrolnt.ioiis 111 el al. i jed ' to bo calculntcd ns t l ie 1)rol)orty c l rn i i~c .

4 '

Amcricnii I'clnrleiiiii Ii~wI.iiiiic, "Tccliiiic?l 1):iiii 1hn)k-l'i.inr Iciiiii l t c l i ~ i i i ~~ , " ?ti11 LYI C11:il). 7, \ \ ' I I~~~~I I~ I~~I I , l>.C., l!l7l.

Amcririiii I'clnilciiiii I i i ~ i i t i i i r 1t1lzc:iri:li I'ri>jcci 44 , ".';<.lct.l~il Vnlt~cs of 1'Ir~sit::il ILIIII '~her111tx1y11111)iic I'r1111~:rii~- ttf l l y ~ l r ~ i - cnrboiis i i t i t l I(cl:rLed Coiii ln~oiitl~," 'I'hcrnic~Iy!i:iiiiit.s Ilr.c:~ri.li Ceiilrr, '~LXILS A&Al Uiiivciñi~y, Collcno Sci~i<,ii, 'l'cx. (IIMI~I- . . lcnf tl;il:i slicts!.s cxtnril 1!)72).

I.nl>idtis. l... "I)igili i l ¡~~iiii~~iil:i~ii~ii firr ( : I i t ! i i i i ~ -~ i I ICitniiic,t.r-." 1111

240-.í7, Alr4:riirv-llill, Nc~,..\'iirk. S.) ' . , l!lli'Z. - IbfcLtri~I~, Ji. J., I i c i i ~c l , S., I*.hlcrs, .J. (.;., ( ~ t > r c l i , ~ i , S., S:ISi\

I{cporl. Ni,. SP-:IOoI, I9lL3. Th i i i l ~ '1'. I'., I)iiniti, J. l.., lliilii.~lli+~. 11. S.. li;~liii~iiiiir. S.,

1 1 ~ , / r o c ~ ~ r k 1 1 1 I ' rorrx.~. , 50 ( l ). !)S- 104 ( l!i¡ l ). ZCICZII~~, l.'. J., (;I~~III~~I, S., NASA '~'cv;II. S t b i ~ I)-¡l;i, \VX<~I¡IIK-

' I t r :c~ : ive~ for rcviem- J:i~iitnry 27, 1!)72 Arcr:i*.ri:i) Jiiiic 1, l!l7?

l ' l i is w ~ ~ r k w:is S ~ M I I I ~ ~ L ~ I'y Llic Aincri~.:iii ~'~I~II~~IIIII f i i ~ l i i ~ i i r , Uivisioii ol Itcfiiiiiig.

I - - - - - - - - . . - . . . . . . 2 . . . . . . . I : - . . - : : . : - / I , - -? l -c .< l - ' - - - - - - . - - - r - . - . . - - - * - - - . . - _ - -- : - z :. - -: z = :, ..: :. - ........ .l 1- :1 >I i.2 - .-1 1 1 ? I 1 - 3 '1 -1 2 1 C'I - . l I e.? 7 i.? i.? ; 1 . ' . . . . . . . . . . . . . . . . . . . . . . . . . - ,: - - - a - . . ,

C - - ,,,,,, ~ , - = = = ¿ = - , ' = ~ - ? ~ ~ - 3 3 - - O - C i 3 ; 3 0 ~ 3 ~ 0 0 0 ~ 3 0 0 ~ 3 3 ~ 2 = .o 8 ; : -- = : - : l - ~ . ~ ~ . ~ - ~ ~ ~ - % ~ ~ ~ ~ - w - ~ n ~ o - o ~ ~ - m m c a ~ o ~ r > ~ ~ o . - . ~ > o c > c I I ~ * * ~ I - = ~ - I - - ~ ;- - o .p,;,: -r-1(_1.? . . . . . . . - < . x , 1 ~ ~ l ~ ~ ~ b 1 / 3 ? m ~ o - " c a o ~ c > ~ i - r ~ l - ~ 3 ; - . ~ l - i - o l - ~ l - . ~ l ~ m ; = ~ c c . . . . . . . . . . . . . . . . . . . . . . . . . . .=r c, . . . . . $ ;J;;S C I - O ~ - C I ~ C O O I I - ~ ~ ~ - ~ ~ - - C ~ - I ~ ~ ~ - C Y - - ~ T ~ - - - --,--,---?:-=.=, .- .:

4 1 ' - 1 7 i 1 1 1 1 1 1 1 1 1 I I l l l l l ! " " ' I '

4 4 11 d. Eng. Ch.- i r c x . ~ s D c r D.*olop., Vol. 1 ; . NO. 4 . 1972

ANEXO F: Niveles Separador Horizontal

TABLA 5. LONGITUDES DE CUERDAS Y AREAS DE LAS SECCIONES CIRCULARES VS. ALTURAS DE LA CUERDA

0 155 0.724 0.- 021s O.&?1 O.iW QZW 0.877 0207 ü350 O.W4 0312 0.1% 0 . n 5 0 . M 0.216 0.823 0.150 O.= 0879 0 209 03% 0.951 0318 0.157 0718 0 1- 0217 0.874 0.66 0264 0882 0.211 0.1% o 729 0.1014 02111 0.826 D rál 07ñ6 o~ 0.213 o.- 0.963 0,134

~0.159 0.731 5.3013 0.218 0.817 0 1tQ 0.2- 0888 O ?16 0- 0 W 3 0.-

0.160 0 733 0 . l W 0.220 O8?8 O 113 0270 0 . W Oí16 -0 0965 0.- 0.161 0 735 0.!041 0.211 0130 0 l W 0272 0 . m O.:m 0375 Ob61 0343

0 . 1 6 7 0737 o 7051 o t n 0831 o ia I 0174 o . m o : ? n 0.lW 4739 0.1061 0273 0833 0166 0176 0.634 O:?% O.= 0.971 0- '

0.1- 0741 a i o m 0224 oaw o i s r o t ~ e o . m 0 . m a ~ l s oo7:1 0 s

0.1- 0.742 a i m o.= 0835 O l m o.zm o- o m 0.390 onm 0x1 01W 0.7U O.lW9 0 2 X 0836 0 . 1 0 0282 O900 (1231 0.335 39x1 tlm 0.167 0.145 a i m 0.227 o a n ~ 0.171 o i e r o . m o x u 0.1m 0 . 7 ~ a i la a ??O O- o. I R OI= 0.m a:!= 0.400 osso a374 a l t a 0.750 a i c i a om OMO 0.173 ozaa 0.806 a:'= 0.405 0 ~ ~ o . m

0.170 0.751 0.1127 0.230 0.842 a l 7 4 0.290 O.QOñ 0341 0.410 0- OBC 0.171 0.753 01137 0231 0843 0175 0292 0.909 0.243 0.415 0985 0 1 > 7 0 ? 5 5 0 ' 1 4 8 0 m 0 . ~ 0 1 7 6 01940911 0245 I 0173 01% 0.1156 ~ 1 í 3 OMS 0.177 0 m 0913 0 . 2 ~ 0.4m 0 . w a399 O114 0 1 9 o . i i a 1 a>* o r o a l n 0.293 o s i r 0 x 0 a 4 n o.- au.

,

a175 0.760 0.1175 o f a 0 . m a120 o x n 0917 o m a 4 ~ 0 o m a411 0.171 0 . ~ ~ 2 0.1185 0 . m 0.849 a t w O X Q 0.9ia o.xs a435 o= 0411 0 . 1 ~ ~ 0.10 01195 0 n 1 0.850 a181 axn osm 0357 I 0.178 0.765 R12W 028 0.652 0 187 0- 092l al5B 0 . M 0993 0.424 0.1M 0.767 01214 0239 0 . m 0 1 U a308 0913 0.262 0.445 U 9 4 0.4I)

O 7 6 0 O 7- 0 1374 0240 O BY O 185 0.310 0 . m O 264 0.150 039á 0- I o 181 0.770 o 1 7 3 a241 oass o t f f i a317 0 . ~ 7 0.266 0.455 6996 o.- 0 187 0 177 O 1/44 0 247 0 857 0 187 0 314 O.Wü 0.2B o i m 0773 o l a 3 a ~ a 0 8 5 ~ o l a 0316 0 . 9 ~ 1 0.771 orm 0.~97 O W Q O ter O rlfr o 1263 a?« o,aw o r e s 0.318 0.931 o 273 0 4 5 o- o.- I

0.066 a403 0.0176 0.125 8661 0.0721 0.185 0777 0 1273 I 0.066 0.407 a m a 2 a l a O.- 00730 0.186 0.7m o l í a 0.067 0 .~00 I I O ~ 0 127 O = 0 0 7 s ! o l a 7 O la O 1293 0- 0503 0.0295 0118 0.568 00747 ! 0 1 m C 7 R l 3 13@J 0 . W (1507 0.0301 0.129 0.870 0.0755 ' 0.189 O.rW 0.1313

a070 0.610 0.0- a i m a673 0.0764 o . 1 ~ 0.7ss 0 . 1 ~ 3 0.071 o.stc 0.031, a l 3 1 0.675 0.0773 o.iot a 7 ~ o i m 0072 0417 o .on t ' 0 . 1 : ~ 0 . 6 n 0 0 ~ 8 1 0 . 1 ~ 0 . 7 a 0.iM3 a073 o sm o 0377 a l a o 61s 0 . 0 7 ~ o ioli r m o 1 x 3 0074 0.U4 0.0- . 0.131 0.ml 0.0198 O 194 0.701 0.1333

0.075 0 527 0 . 0 3 1 0.13) 0 . W O.OB07 0.195 O 792 0.1373 0.075 0530 OOY? 0.136 0.686 0.OB16 0 1% 0 7 9 4 0.1Xl3 -- b A Y E T O O . 3 0.077 0533 00334 0.137 0- OOü75 0197 0?95 0.1393 0.078 0536 00361 0.138 0.690 Om33 0 1- 0 797 O 1473 0.079 o 539 o 03m 0.139 o.mz 0 . w ~ o i w a7se 0.1414

ANEXO H: Coeficiente Global de transferencia de Calor típicos

Fuente: GPSA

l.

FIG. 9-9

Typical Heat Transfer Coefficients, U, and Fauling Resistances, rr

\fater r'O.W2:$ 101) psi G,?s !O -00 1 :I 301) psi Gcs 10.001:1 7 0 0 psi Gcs i0.00 1 i 1000 psi Gas i 0.001 1 Kerosene i0.001'1 MEX r'o.oo=!:~ -4ir i'0.002i \Vater iO.001 :I

Condensing ~ i t . h water 10.002i' C3 or C j i'0.001'1 Napht.ha i0.001i Still Cherhead i13.001

Rich !O.OOli:Lean Oil i'0.WZi CJ LiqrC3 Liq 10.001i hlEil131EA !O .O@. i 100 psi GrisiSOO psi Gas 1000 psi Gas' 1000 psi Gcas lOOo psi Gns'Cond. Cs i0.001 i Steam i0.0005i Reboilers Hot Oil i O . 0 0 2 i Reboilers Henc Transik F'luid r'0.001 i

I t eb i l er s

rrin ihr sq fc ->F:~'B~U

ANEXO 1: Datos de tubos intercambiadores de Calor

F~ente: GPSA

Characteristics of Tubing ---

U. 1w <l. 11% V.la6 c111s 0 la ii m,? if 1- '3. 1m 1) IM a i-w u.1- *>.E33 V. Lb36 e). IJlci?

*>.lW % 1416 OlS% *l. 149

Tras-ver. Ycial h sy. Ilrh

0.Olcb ll.UW<)

O.OU1 0.OlIJ

O . l ü r i Z II 1074 O .m-* O.(U+a

UC*Z 0ru.i

OOSll l> IM 15

u. 1 7 V. Wo U. 14 I 4). m 0.114 o. lid .).1W3

.>..m <l.tns

ijB l

O L W i i 2 3 )

0. 1- *'h. 174 *>. 153 e). l+l 0. m S:.. Ii*

.i.m

1'43 1

QW .l.Tlll * l i s .J.";I) <).239 .1.2111 a 1 191 $1. LW v. b.4

.J.@.$ i b S 5

.).iJ>

.l.*&

.>.3(.1 $1.345 .J. s<.i ,1242

.>.165 .l 13

8 1 . 5 3

.,..,:,a , I . ~ I

S 8 2.7

i, T.., -n.w7 - 4 t i U

i i í i i

ANEXO J: Arreglo de Tubos en Coraza

Fuente: Ludwig

. . Table 10.8

H u t Exchangcr T u k <hect Layout Cwnt T a b k I --

.-e --

1 I I I I I I I I 1

' Al lorance m.& lor TW Roda. ' R. O. D . 2% X Tirk Dii. Actual S u m W o1 "U" Tu- ane-hall ihe rbo\ e L ~ u i - .

jj- -.

J . ' . f I 04 E' 1 : -! t ' l U i

For Low-Finiied Tubm f. , (sq. ft.)/(sq. in.)

V .- ca 0 .o, .- 3 3 O - ' x 2 g S 4 I=

ANEXO N: Factor recorrección LMTD enfriadores de aire

Fuente: GPSA

FIG. 10-8

MTD Correction Faaors (1 Puss - Cross Fiow. Both Fluids Unmixed)

FIG. 10-9

MTD Correction Fxtors (2 Pass - Cross Flow. Botti Fluids Unmlxed)

- - - . L. - :, i: - . S -

C. ' . -. m:. P

ANEXO O: Coeficiente global enfriadores cle aire

Fuente: GPSA

FIG. 10-10

Typlcal Overall Heat-Transfer Coefíicients for Alr Coolers 8,.

%\*e

I m l;imih.

L i ~ ~ i . ~ 9 1 5 . a ~ n ~ 1 0

Lh 1 U, 1 Lb 1 Lb

1. Uiillpr Xi =-.ver wlulbxn

!SR r P l ~ bPClU I

Enpinry HJler lid = nlli

Plu*ss HJWr (rd : n rna

Xb :Qe*kne hrd HJtCr Ird nP*;i!

3.15Urttnbnr hrd water 6 : *,,fa& S T.

2. kdroc;ubon !+id roolcrs \ ' t n r a ( a > . <C' at acg. i r m p

l., 2 B ~ I .i

I .o 2.5 4.0 6ll i n i ~

Lb

Ri -- ;a 13 45 3 20 ~n

3. H p i r w m r b a i p s c w b r s

1 9 3,"

4. >Ur m d flw-gas cuobrr L b 00t>-luU oí \illue h ~ t l r c x a r b ~ i L~Z) ( m l ~ m .

31-m ril h inm r*rlhisll&.s 3 3

C. 11C ron&rrem i.rxlcminf

Ranh,. T (1' 1aw 111- IJIW

- - Ri J ' s.5 ~.

25- rdmp T.? i ? 1 2 .Al- r..,,p $ 5 " . .. '. .5

l . 0 , I I '1 3

7 . ~ : ~ l l w t c ~ ~ ~ ~ l i u ~ i ~

linincllbr I;rioii I L

Lb

3 7 4 2 3 3 2 6 1 8 1 2 916

Lh

59

S 2

4.5 3.1

2 1 1 4 117

Lb

Im-l u*

:: 55 35 25 13

t&r..\ Lir 1% iA'i.mIl r.rv hv+.l ni ts*r ti&:.- arhi. aiM.1 Ll, 1 , .n.i-1.41 i a ~ i . 1-awl S r 8 *.siwbhl wttf.nr

k n - 1 val q ~ . ~ ~ x h i ~ ~ l ~ ,u1 f . m ~ u&,?\* \4*-liw b w ~ ~ ~ t t ?*Do ,WPI ? 8 @ ~ l l ~ l l u . ~ ~ 11 a4 f.. +. ..e.* 'Ciwrbrnrw r.>iii~. - I>.hr.arh<.i i ih.i ci,ipv.niii.~ i o <i1~).7~ii.: m i r . i i ini i i \ l n t k r - . x k i c.ilI*i triitl-.r.niir- Irrqii .wwCqi,aiy nlr.

1.1,

I 111 lii

't.

7 &

.l 5

1 ,

3

11.

.;1 1, .-S