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Annexure I:
Certificate of accredited consultant
Annexure II
Copy of TOR letter TOR Letter
Annexure III
Copy of Earlier EC with compliance report
Annexure IV
Air Water Consent
Annexure V
EC Compliance letter
Annexure VI
Raw data of all AAQ measurement for 12
weeks of all stations as per frequency given in
the NAQQM Notification of Nov. 2009
Annexure VII
Annual report of heath status of workers with
special reference to Occupational Health and
Safety
INDIA PESTICIDES LIMITED • IIPL CIN No . U24112 UP 1984PLC006894
Phase I, UPSIDC Industrial Area, Sandila
District Hardoi PIN 241127 U.P. INDIA
Website: www.indiapesticideslimited.com
Email : [email protected]
To,
The
Om Hospital
Station Road Near - Old Kerosene Depot,
Sandila (Hardoi)
Su b: Agreement of Doctor's visit to the factory.
The Doctor of Om Hospital will visit Mis. India Pesticides Limited once in a week
(Four times a month). We will pay Rs. 15,000.00 (Fifteen Thousands Only) on
monthly basis against above said four visits.
This agreement will be valid up to one year from the date of commencement.
~ ~'P ....~-«5J (Dr. Vineet Verma)
(General Manager) Om HGSpital
India Pesticides Limited Sandi1a Hardoi
Sandila, Hardoi
Dr. Ajay ~ . : tnag ~ r ,
Date: 01.07.2016
Regd. Office: Swarup Bhawan, 35A, Civil lines, Bareilly243 001. Phone: 05812567476 Office: Water Works Road, Aishbagh. Lucknow 226 004 (INDIA)
Tel. : +915222653602,2653603 , 3255885,2653622, 7499494587, Fax: + 915222653610
COrJTROl TERMITE EFFECTIVELY USE CHLORM
Thyro care" Think Thyroid . Think Thyrocare.
"U::O n_~.., Thyrocare ..
· TT c." ~~ e : Thyrocare Technologies Limited q 0-37/3, TTC M I ~ C, Turbhe, Navi Mumbal 400703 Murnbal400 7(Q 022 3090 0000 I 4125 2525 ~ [email protected] e www . thyrocar~ . com
NAME : MR SHYAMVEER SINGH (SOY/M) SAMPLE COLLECTED AT :
REF. BY : INDIA PESTICIDES LTD INOlA PESTICIDES l TDPEsnCIDES l TO. UPSIOC INDUSTRIAL AREA, SANDlLA. HARDOI
TEST ASKED: AAROGYAM 1.2
TEST NAME TECHNOLOGY VAlUE UNITS REFERENCE RANGE
TOTAL TRIIODOTHYRONINE (TJ) C.L.I.A 137 ng/dl 60200
TOTAL THYROXINE (T4) C.L.I.A 10.2 ~g/dl 4 .512
THYROID STIMULATING HORMONE (TSIl) C.I'!>:I.A 3.90 ~IU/rnl 0.35.5
Comment5: SUGGESTING THYRONORMALCY
Ple••e correlate with clinical conditions.
Method:
T3 COMPETITIVE CHEMI LUMINESCENT IMMUNO ASSAY J
T4 COMPETITIVE CHEMI LUMINESCENT IMMUNO ASSAY
TSH ULTRA SENSITIVE SANDWICH CHEMI LUMINESCENT I.MMUNO ASSAY
End of report
Sample Collected on (SCT) : 20 Mar 2017 09:00
Sample Received on (SRT) : 21 Mar 201700:31
Report Relea.ed on (RRT) : 21 Mar 2017 02:38
lO lO o
~ r-..... N ..... o
Sample Type
labcode ·
Barcode
: SERUM
: 200341498/UTT06
: 84474760
Dr.Durgaprasad N Agrawal MD Dr.Caesar Sengupta MD
• Page: 6 ot6
Reporting conditions overleaf (
mailto:[email protected]
Olnlcal Significance
m..
Thyroc are ' ~ Think Thyroid. Think Thyrocare .
.. : Thyrocare Technologies Umlted 9 037/3, TIC M I DC, Turbhe, Navl Mumbal ~ 400703 3090 0000 / 4125 2525 a [email protected] • www.thyrocare.com
NAME
REF. BY
: MR SHYAMVEER SINGH (50Y/M)
: INDIA PESTICIDES LTD
TEST ASKED AAROGYAM 1.2
TEST NAME
SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPEsnODES LTD. UPSIDC
INDUSTRIAL AREA. SANDILA. HARDOI
TECHNOLOGY VALUE UNITS
EST. GLOMERULAR FILTRATION RATE (eGFR) CALCULATED 108 mL/min/1. 73 m2
Reference Range :
> = 90 : Normal
60 89 : Mild Decrease
45 - 59 : Mild to Moderate Decrease 30 44 : Moderate to Severe Decrease
15 29 : Severe Decrease
The normal serum aeatlnlne reference interval does not necessarily retlect a normal GFR for a patient. Because and moderate kidney Injury is poorly inferred from serum creatinine alone. Thus, it Is recommended for clinical
IabOralDrtes to routinely estimate glomerular filtration rate (eGFR), a "gold standard" measurement for assessment rI renal functfon, and report the value when serum creatinine is measured for patients 18 and older, when ..,..optIate and feasibIe_ It cannot be measured easily in clinical practice, instead, GFR is estimated from
-..uans using serum creatinine, age, race and sex. This provides easy to 'Interpret information for the doctor end peHent on the degree of renal Impairment since it approximately equates to the percentage of kidney function nmaJrmg. Application of CKDEPI equation together with the other diagnostic tools in renal medicine will further
IrnprcM! the deb!ction and management of patients with CKD.
Levey AS, Stevens LA, Schmid CH, Zhang YL, Castro AF, 3rd, Feldman HI, et al. A new equation to estimate
glomerular filtration rate. Ann Intern Med. 2009; 150(9):60412.
Please correlate with clinical conditions.
Method : CKDEPI Creatinine Equation
Sample Collected on (SCT) 20 Mar 2017 09:00
Sample Received on (SRT) 21 Mar 2017 00:31
Report Released on (RRT) 21 Mar 2017 02:38
Sample Type SERUM Dr.Durgaprasad N Agrawal .' Dr.Caesar Sengupta MD
Labcode
Barcode
200341498/UTI06
84474760 Page: 1 of6
Reporting conditions overleaf (
mailto:[email protected]
ThyrCJc are ' ~ ' Think Thyroid . Think Thyrocare .
REPORT
.CotpOrute . O/If~ : Thyrocare Technologies Umited 9 037/3, nc MIOC, 'KJrbhe, Navl Mumbai 400703 3090 0000 /4125 2525 Gii [email protected] • www.thyi.oeare.com
: MR SHYAMVEER SINGH (50Y/M)
REF. BY : INDIA PESTICIDES LTD
TEST ASKED: AAROGYAM 1.2
TEST NAME
SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HARDOI
TECHNOLOGY VALUE UNITS
IRON PHOTOMETRY 100.3 IJg/dl
Reference Range :
Male: 70 180
Female: 60 180
Method: FERROZINE METHOD WITHOUT DEPROTEINIZAnON
TOTAL IRON BINDING CAPACITY (TIBC) PHOTOMETRY 364 IJg/dl
Reference Range :
Male: 225 535 IJg/dl Female: 215 535 IJg/dl
Method:· SPECTROPHOTOMETRIC ASSAY
1M. TRANSFERRIN SATURATION CALCULATED 27.55
Reference Range:
13 45
Method: DERIVED FROM IRON AND nBC VALUES
Please correlate with clinical conditions.
SlIm"" Collected on (SCT) : 20 Mar 2017 09:00
SIImpie ReceIved on (SRT) : 21 Mar 201700:31
Report Released on (RRT) : 21 Mar 2017 02:38
SlimpieType : SERUM Dr.Durgaprasad N Agrawal MD Dr.caesar Sengupta MD
Labcode : 200341498/UTT06 Page: 2 of6
Barcode : 84474760
Reporting conditions overleaf (
Thyrocare" Think Thyroid. Think Thyrocare.
Corporate Offtce : Thyrotare Technologies Umlted 9 037/3, TIC M IDC, Turbhe, Navl Mumbai 400703 MIDC,Tu.etQ22 3090 0000 /4125 2525 ~ [email protected] • www.thyrocare.com
: MR SHYAMVEER SINGH (SOY/M)
: INDIA PESTICIDES LTD
TEST ASKED : AAROGYAM 1. 2
TECHNOLOGY
SAMPLE COLLECTED AT : INDIA PEsnODES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HAROOI
VALUE UNITS NORMAL RANGETEST NAME
BLOOD UREA NITROGEN (BUN) PHOTOMETRY 15.8 mg/dl 7.920
CREATININE SERUM PHOTOMETRY 0.73 mg/dl 0.61.1
URIC ACID PHOTO"'ETRY 4.4 mg/dl 3.57.2
CALCIUM PHOTOMETRY 9.78 mg/dl 8.810.6
BUN / SR.CREATININE RATIO CALCULATED 21.64 Ratio 9:123:1
PIeaH correlate with clinical conditions.
BUN KINETIC W ASSAY.
SCRE ~n NINE ENZVMAnC METHOD
URIC - Uricase I Peroxidase Method CM.C ARSENAZO III METHOD, END POINT.
WCR DERIVED FROM SERUM BUN AND CREATININE VALUES
s.mple Collected on (SCT) : 20 Mar 2017 09:00
S.mple Received on (SRT) : 21 Mar 2017 00:31
Report Released on (RRT) : 21 Mar 2017 02:38
S.mpleType : SERUM Dr.Durgaprasad N Agrawal MD Dr. Caesar Sengupta MD
;; ~ Labcode : 200341498/UTI06 Page: 30f6
Barcode : 84474760Ii ~ -- ~. ..... iiiN --..-&&:0
Reporting conditions overleaf (
REF. BY
TEST ASKED: AAROGYAM 1.2
Thyrocare" Think Thyroid . Think Thyrocare.
Corporate OffIce: Thyrocare Technologies Umlted 9 0-37/3, TIC M 10C, Turbhe, Navj Mumbai 400703 MroC,Tu~~22 ~ 3090 0000 / 4125 2525 [email protected]'ll • www.thyrocare.com
: MR SHYAMVEER SINGH (50Y/M) SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC
: INDIA PESTICIDES L TO INDUSTRIAL AREA, SANDILA, HARDOI
TEST NAME TECHNOLOGY VALUE UNITS 'NORMAL RANGE
TOTAL CHOLESTEROL PHOTOMETRY 282 mg/dl 125-200
HDL CHOLESTEROL DIRECT PHOTOMETRY 54 mg/dl 3580
LDL CHOLESTEROL DIRECT 'PHOTOMll'RY 157 mg/dl 85-130
TRIGLYCERIDES PHOTOMETRY 429 mg/dl 25-200 TCI HDL CHOLESTEROL RATIO CALCULATED 5.3 Ratio 3-5 LDL / HDL RATIO CALCULATED 2.9 Ratio 1.53.5
YLDL CHOLESTEROL CALCULATED 85.8 mg/dl 5 - 40 N~HDLCHOuenE ROL CALCULATED 228.5 mg/dl
-Thyrocare_ Think Thyroid. Think Thyrocare.
[email protected] • www.thyrocare.com
Corporate Offlce : Thyracare Technologies Umlted 9 0-37/3, TTC MIDC, Turbhe, Navi Mumbai 400703 MIDC, TU~d)22 3090.0000 /4125 2525 ~
REF. BY
: MR SHYAMVEER SINGH (SOY/M)
: INDIA PESTICIDES LTD
TEST ASKED: AAROGYAM 1.2
TEST NAME! TECHNOLOGY
ALKAUNE PHOSPHATASE PHOTOMETRY
BIURUBIN DIRECT PHOTOMETRY
SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTlODES LTD. UPSIDC
INDUSTRIAL AREA, SANDILA, HARDOI
VALUE UNITS NORMAL RANGE
102.6 U/I 53 128
0.19 mg/dl
NAME
REF. BY
: MR SHYAMVEER SINGH (50Y/M)
: INDIA PESTICIDES LTD
TEST ASKED : HEMOGRAM
TEST NAME
HbAlc (HPLC NGSP Certified)
HbAlc
ThYfocare" Think Thyroid. Think Thyrocare.
: Thyrocare Technologles Limited 9037/3, TIC M IDC, Turbhe; Navi Mumbai 400703
"' 3090 0000 /4125 2525 ~ [email protected] G www.thyrocare.com
, REPORT -
SAMPLE COLLECTED AT : INDIA PESTIaDES LTDPESTIClDES LTD. UPSIDe
INDUSTRIAL AREA, SANDILA, HARDOI
- 6 PART (DIFF),HBA
TECHNOLOGY VALUE UNITS
• H.P.L.C 4.9 %
Reference Range : "
Below 6.0% - Normal Value
6.0% - 7.0% - Good Control
7.0% - 8.0% - Fair Control
8.0% - 10% - Unsatisfactory Control
Above 10% - Poor Control Method: Fully Automated H.P.L.C. using Biorad Variant II Turbo, NGSP Certified.
AVERAGE BLOOD GLUCOSE ( ABG) CALCULATED 94 mg/dl
Ref..ace bnge :
90 - 120 mgfdl : Excellent Control
121 - 150 mgfdl : Good Control
151 - 180 mgfdl : Average Control
181 - 210 mg/dl : Action Suggested > 211 mgfcl : Panic Value
(Note: Average 6jood Glucose value Is calculated from HBAlc value and It Indicates Average Blood Sugar
level over past three months.) Method : Derived from HBAlc values
Pi.... correlate with dlnlcal conditions.
Sample Collected on (SCT) : 20 Mar 2017 09:00
Sample Received on (SRT) : 21 Mar 2017 00:17
Report Released on (RRT) : 21 Mar 2017 03:51 . Sample Type : EDTA Dr.Durgaprasad N Agrawal MD Dr.Caesar Sengupta MD
Labcode : 200340282/UTT06 Page: 1 of2
Barcode : 84355560
Reporting conditions overleaf (
mailto:[email protected]
ThYfocare"{1 Think Thyroid . Think Thyrocare.
~~ce : Thyrocare Technololles Umlted 9 D-37/3, TTC M IDC, Turphe, Navl Mumbai - 400703 ImDlal ....'OO 70~ 022 - 3090 0000 /4125 2525 ~ [email protected] ., www.thyrocare.com
NAME : MR SHYAMVEER SINGH (50Y/M) SAMPLE COLLECTED AT :
REF. BY : INDIA PESTICIDES L TO INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HARDOI
TEST ASKED : HEMOGRAM - 6 PART (DIFF),HBA
TEST NAME
TOTAL LEUCOCYTES COUNT
VALUE UNITS REFERENCE RANGE
7.05 X 103 / ilL 4 - 10
NEUlROPHILS 65.2 % 40-80
LYMPHOCYTE PERCENTAGE 26 % 20-40
MONOCYTES 3 .3 % 0-10 .,.EOSINOPHILS 5 % 0-6 e
ThYfocare'" Think Thyroid. Think Thyrocare.
: Thyrocare Technologtes.Limlted ~ 0-37/3, TIC M10C, Turbhe, Navi Mumbai - 400703
@ 022 - 3090 0000/4125 2525 Z· [email protected] • www.thyrocare.com
: MR SHYAMVEER SINGH (SOY/M)
REF. BY : INDIA PESTICIDES LTD
TEST ASKED: COMPLETE URINE ANALYSIS
SAMPLE COLLECTED AT : INDiA ,PESTICIDES LTDPESTICIDES LTD. UPSIOC INDUSTRIAL AREA, SANDILA, HARDOI
TEST NAME OBSERVAnON UNITS REFERENCE RANGE
• To Obtain Counts In Cells I HPF Divide the Cells I ul ~Y 5
Please correlate with clinical conditions.
Method: Manual Dipstick Method
- End of report-
---.- - .--- - - ----Sample ~olJected on (SCT) : 20 Mar 2017 09:00
Sample Received on (SRT) : 21 Mar 2017 01:12
Report Released on (RRT) : 21 Mar 2017 02:47
COMPLETE URINOGRAM
_RINARY GLUCOSE
URINARY BIURUBIN
URINE KETONE
SPEOFIC GRAVITY
URINE BLOOD
PH
URINARY PROTBN
UROBILINOGEN
NITRITE
URINARY LfUCOCYTES
COLOUR
APPEARANCE
BILE SALT
BILE PIGMENT ·
EPITHEUAl. CEUS
CASTS
,.r-ifrRYSTALS
r.l3ACTERIA
Negative
Negative
Negative
1.01
Negative
6
Negative
0.2
Negative
Negative
Pale Yellow
Clear
Negative
Negative
1-2
Absent
Absent
Absent
mg/dl
mg/dl
mg/dl
Cells/ul·
mg/dl
mg/dl
Cells/ul·
Negative
Negative
Negative
1.003-1.030
Negative
S-8
Negative
Annexure VIII
MSDS of Chemicals
1
Bispyribac-sodium-MATERIAL SAFETY DATA SHEET
Manufacturer/information service:
ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]
1. Chemical Product Identification
Product Name: Bispyribac-sodium
Molecular Formula: C19H17N4NaO8
Molecular Weight: 452.355
Structural Formula:
Chemical Name: Sodium 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy] benzoate
Form: Solid
Color: White
Odor: Odorless
CAS No.: 125401-92-5
2. Composition / Information on Ingredients
Composition CAS No. Content %
Bispyribac-sodium 125401-92-5 95.0
Other ingredients 5.0
3. Hazards Identification
2
Adverse Human Health Effects: Effect of over exposure: We have never faced the poisoning problem attributed to bispyribac-sodium technical on laboratory researchers, factory workers and users, however, over-exposure experiments on animals showed that the administration of an extra-ordinary
large quantity of bispyribac-sodium technical may cause hypoactivity, abnormal walking and prostration.
4. First Aid Measures
Skin Contact: Wash material off the skin in flowing water or shower with soap. If irritation persists, consult a physician immediately.
Eye Contact: Immediately flush with copious amount of water for at least 15 minutes.
Inhalation: Remove the victim to fresh air and keep him warm and quiet. Get a medical attention immediately. If not breathing, clear the airway and give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: Induce vomiting by giving one or two glasses of water. Get a medical attention immediately. If the victim is unconscious or having convulsions, never give fluids nor induce vomiting.
5. Fire-Fighting Measures
Extinguishing Media: Water, dry chemical powder, foam or carbon dioxide
Special Fire Fighting Procedure: Use water, dry chemical powder or carbon dioxide in extinguishing. For a fire in surrounding area, apply water to cool and protect surrounding equipments. Remove containers, if feasible, from the fire area to safe place immediately. Fire fighters should wear protective gears including a positive pressure self-contained breathing apparatus. Evacuate non essential personnel.
6. Accidental Release Measures
Evacuate non essential personnel by roping the area of leak or spill. Evacuate people to upwind of the spilled area. Remove all sources of ignition; No flares, smoking, or flames in the area immediately. Wear protective gears and never work downwind. For small spills, adsorb with inert materials (e.g. dry sand or earth), then place in a waste chemical container for disposal. Flush residual spill (area) with a plenty of water. Prevent spills from entering sewers, watercourses or low areas.
7. Handling and Storage
Handling: Keep out of reach of children
When handling and spraying the product, wear duty working clothes, cap, gloves, glasses and mask to avoid contact with skin, eyes and inhalation of dust, fog and vapours. After
3
work thoroughly wash hands, face and possible exposed areas of body and change clothing.
Storage: Keep containers tightly closed and store in a cool, dark and dry place.
8. Exposure Controls/Personal Protection
Engineering Controls: The use of local exhaust ventilations is recommended. Containers should be kept tightly closed. Make available emergency showers and eye washes in a work area.
Personal Protective Equipment: Wear chemical cartridge respirator with an organic vapour cartridge, airline respirator, positive pressure self-contained breathing apparatus, safety goggles, gloves and boots as appropriate.
9. Physical and Chemical Properties
Density: 1.29 (20°C)
Boiling Point: Not applicable
Melting Point: 223 - 224°C
Vapor Pressure: 5.04 X 10-9 Pa (25°C)
Solubility in Water: 7.33g/100 ml (25°C)
Solubility in Organic Solvents: Slighly to moderately soluble
Log P (o/w): -1.03 (23°C)
10. Stability and Reactivity
Flash Point: Not applicable
Autoignition Temperature: Not available
Explosion Limit: Not available
Stability and Reactivity: Stable under normal conditions
Hazardous Polymerization: Not available
Incompatibility: Not available
Storage Stability: Stable for 3 years if stored in a cool, dark and dry place.
11. Toxicological Information
Acute Toxicity:
Oral: LD50 (Rat) 4,111 mg/kg (male)
2,635 mg/kg (female)
4
LD50 (Mouse) 3,524 mg/kg (male & female)
Dermal: LD50 (Rat) >2,000 mg/kg (male & female)
Inhalation: LD50 (Rat) >4.48 mg/L (4 hours exp.)
Irritant Properties:
Eye irritation: (Rabbit) Slight irritant
Skin irritation: (Rabbit) Not irritant
Allergenic and Sensitizing Effects: Not sensitizing
Mutagenic Effects:
Amest test: Negative (S-9 Mix + or -)
12. Ecological And Ecotoxicological Information
Fish Toxicity: Bluegill sunfish TLm96 >100 ppm
Daphnia magna TLm48 >100 ppm
Rainbow trout TLm96 >100 ppm
Avian Toxicity: Bobwhite quail Acute LD50 (Oral) >2,250 mg/kg
Bobwhite quail Subacute dietary LC50 >5,620 mg/kg
Mallard duck Subacute dietary LC50 >5,620 mg/kg
Earthworm Toxicity: Acute LC50 >1,000 ppm (14 days exp.)
13. Disposal Considerations
Waste should be disposed of in a chemical incinerator equipped with afterburner and scrubber. Do not dump into sewers or into any body of water.
14. Transport Information
Not applicable.
15. Regulatory Information
Not applicable.
16. Other Information
All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is
5
necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.
Product Name: Captan FS
Page 1 of 5
This revision is issued: June, 2012
MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600
Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227
SECTION 1 - PRODUCT & COMPANY IDENTIFICATION
ARYSTA LifeScience South Africa (Pty) Ltd Tel: 031 514 5600 Co. Reg. No.: 2009/019713/07 Fax: 031 514 5611 7 Sunbury Office Park, Off Douglas Saunders Drive, La Lucia Ridge, South Africa, 4019 e-mail: [email protected] Web address: arystalifescience.co.za
Substance: captab Product Name: CAPTAN FS Product Use: Fungicide Creation Date: October 2007 Revision Date: October 13 24 Hr Emergency Number: 082 771 2712 In case of Poisoning: Poison Information Centre 082 446 8946 Tygerberg Hospital: (021) 931 6129 Poison Emergency Enquiries (021) 689 5227 In case of Spillage: HAZMAT: 0800 147 112
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
Common name: Captab (South Africa) Chemical Name: N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (IUPAC) CAS No.: 133-06-2 Chemical Family: N-trihalomethylthio Chemical Formula: C9H8Cl3NO2S (Mol. Wt.: 300.6). Use: Fungicide with protective and curative action. Formulation: Captab: 500 g/kg Flowable fungicide seed-dressing UN number: 3082 Active Ingredient: Captab SYMBOLS: Xn RISK-PHRASE(S): R 36, R 40, R 43
SECTION 3 - HAZARD IDENTIFICATION
Toxicity class: WHO Table; EPA – III A low toxicity fungicide. Likely routes of exposure: Skin and eye contact, inhalation and ingestion. The product may cause eye irritation. Skin contact: Minimally toxic. May cause mild skin irritation and may have moderate sensitizing properties (guinea pig). Ingestion: Minimally toxic. Inhalation: May be irritating to the respiratory system.
SECTION 4 - FIRST AID MEASURES AND PRECAUTIONS
Reactions are not likely to occur unless the absorbed dose is extraordinary. Symptoms of repeated exposure to the product may cause contact dermatitis. When product comes in contact with eyes the effect is redness of and tears. Inhalation: Remove source of contamination or move victim to fresh air and well-ventilated area. Monitor for respiratory distress. Give oxygen or artificial respiration if needed. Seek medical attention if necessary. Skin contact: Remove contaminated clothing, shoes and leather goods. Gently wipe off excess chemical. Wash skin gently and thoroughly with water and non-abrasive soap. Seek medical advice if necessary. Persons who become sensitized may require specialized medical management with anti-inflammatory agents.
Product Name: Captan FS
Page 2 of 5
This revision is issued: June, 2012
MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600
Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227
Eye contact: Immediately flush the eyes with gently flowing lukewarm water for 20 minutes. Obtain medical attention if necessary. Ingestion: Wash out mouth thoroughly with clean water. In case of ingestion of significant quantities of the fungicide, medical advice should be sought immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Advice to physician: No specific antidotes are available against Captan FS poisoning. If a large amount of Captan FS has been ingested in the last few hours, and if copious vomiting has not already occurred, the stomach must be emptied and steps taken to limit gastrointestinal absorption. If the patient is fully alert and nervous system depression is not anticipated, it is recommended to empty the stomach. When vomiting stops after induced emesis, give activated charcoal and cathartic orally by adding sorbitol to the charcoal slurry. Dosage of Activated Charcoal: Adults and children over 12 years: 50 to 100 mg in 300 to 800 ml water. Children under 12 years: 15 to 30 mg in 100 to 300 ml water. Dosage of Sorbitol: Adults and children over 12 years: 1 to 2 mg/kg body weight to a maximum of 150 mg per dose. Children under 12 years: 1.0 to 1.5 mg/kg body weight to a maximum of 50 mg per dose. If sorbitol is given separately, it should be diluted with an equal volume of water before administration. If there are any indications of central nervous system depression, or if the patient fails to vomit within 30 minutes of Syrup of Ipecac administration, measures should be taken to protect the respiratory tract from aspiration of gastric contents, then the stomach should be emptied by gastric intubation, aspiration and lavage with a slurry of activated charcoal. Install activated charcoal following lavage. Unless diarrhoea has already commenced, include a cathartic to hasten elimination. CAUTION: Do not instill fluid so rapidly that overloading of the stomach leads to vomiting or regurgitation, followed by aspiration. Serious electrolyte disturbances may follow catharsis, especially in young children. If contact with the toxicant has been minimal, administration of charcoal without the cathartic, followed by careful observation of the patient, probably represent optimal management.
SECTION 5 - FIRE-FIGHTING MEASURES
Fire hazard and explosion hazard: Slight fire hazard when exposed to heat or flame. Not highly flammable and not explosive. Hazardous decomposition products: Product releases CSCl2, HCl, SOx, NOx, CO and CO2 when exposed to very high temperatures. Extinguishing agents: Extinguish small fires with carbon dioxide, dry or foam chemical. Water spray can be used for cooling of unaffected stock, but avoid water coming in contact with the product. In case of large fires use water spray, fog or regular foam. Dike fire control water for later disposal. Firefighting: Fight fire from maximum distance. Remove container/bag from fire area if possible. Contain fire control agents for later disposal. Use a recommended extinguishing agent for the type of surrounding fire. Water can be used to cool unaffected containers/bags. Avoid inhaling hazardous vapours. Keep upwind. Personal protective equipment: Fire may produce irritating or poisonous vapours (toxic oxides of carbon, nitrogen and sulphur) of combustion. Fire fighters and others that may be exposed should wear full chemical protective clothing and self-contained breathing apparatus.
SECTION 6 - ACCIDENTAL RELEASE MEASURES (SPILLAGE)
Personal precautions: Avoid contact with skin and eyes. Do not breathe in fumes. For personal protection see Section 8. Environmental precautions: Do not allow entering drains or watercourses. When the product contaminates public waters, inform appropriate authorities immediately in accordance with local regulations. Occupational spill: For small dry spills, sweep up with damp earth or sand or other suitable absorbent and taking care not to raise a dust cloud. Place the material into a clean, dry container and cover for subsequent disposal. All contaminated cleaning materials should be placed in closeable receptacles. In situations where product comes in contact with water, contain contaminated water for later disposal. Do not flush spilled material into drains. Keep spectators away and upwind.
Product Name: Captan FS
Page 3 of 5
This revision is issued: June, 2012
MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600
Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227
SECTION 7 - HANDLING AND STORAGE REQUIREMENTS
Handling: Avoid contact with eyes, prolonged contact with skin, and inhalation of dust and vapour. Use with adequate ventilation. Wash hands before eating, drinking, chewing gum, smoking, or using the toilet. Remove clothing immediately if the product gets inside. Then wash skin thoroughly using a non-abrasive soap and put on clean clothing. Do not apply directly to areas where surface water is present, or to intertidal areas below the mean high water mark. Water used to clean equipment must be disposed of correctly to avoid contamination. Storage: Keep out of reach of unauthorized persons, children and animals. Store in its original labeled container/bag in shaded, well-ventilated area, away from heat, sparks and other sources of ignition - NO SMOKING. Store in dry area and protect from temperatures below 00C and above 500C. Avoid breaking the container/bag, spillage or leaks. Do not allow the product to become wet or overheated in storage, decomposition, impaired activity or fire may result. Not to be store next to foodstuffs and water supplies. Local regulations should be complied with.
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
It is essential to provide adequate ventilation. The measures appropriate for a particular work site depend on how this material is used and on the extent of exposure. Ensure that control systems are properly designed and maintained. Comply with occupational safety, environmental, fire, and other applicable regulations. PERSONAL PROTECTIVE EQUIPMENT: Respirator: An approved full-face respirator suitable for protection from dusts and mists of pesticides is required. Limitations of respirator use specified by the approving agency and the manufacturer must be observed. Respirator with P2 filter is recommended. Acceptable exposure limit for Captan: TLV (USA): TWA: 5 mg/m3; A3 (1996) Clothing: Employee must wear appropriate protective (impervious) clothing, boots, hat and equipment to prevent repeated or prolonged skin contact with this substance. Do not wear leather clothing. Gloves: Employee must wear appropriate chemical resistant protective gloves to prevent contact with this substance. Eye protection: The use of a face-shield is recommended. Emergency eyewash: Where there is any possibility that an employee’s eyes may be exposed to this substance; the employer should provide an eye wash fountain or appropriate alternative within the immediate work area for emergency use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Solid – off-white amorphous wettable powder. Odour: Faint odour – characteristic. Explosive properties: Not explosive. Flammability: Not highly flammable. pH of a 1% aqueous solution: 6 - 9 Bulk density: 0.64 g/l Storage stability: Stable for 2 years under normal, dry storage conditions in unopened bags/containers. The product is
stable after 14 days at 54 oC (accelerated storage test). Solubility in water: Soluble in water. Melting point: 158 to 164°C. Boiling point: Captab decomposes. Vapour Pressure: 2.01 x 10-4 Pa at a temperature of 50°C (pure). Octanol/Water partition coefficient: KOW = 610.
SECTION 10 - STABILITY AND REACTIVITY
Stability: Considered stable in unopened containers/bags. Slowly decomposed by heat and moisture. No decomposition if stored and applied as directed. Incompatibility: Avoid contact with alkali materials, such as lime and Bordeaux mixture. Contact with these products will reduce fungicidal activity. Hazardous reactions: Hazardous polymerization will not occur.
Product Name: Captan FS
Page 4 of 5
This revision is issued: June, 2012
MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600
Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227
Hazardous decomposition products: CSCl2, HCl, SOx, NOx, CO and CO2.
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute oral LD50: > 5000 mg/kg in rats. Acute dermal LD50: > 2000 mg/kg in rats. Acute inhalation LC50: > 2.6 mg/l in rats for 4 hours. Dermal sensitization: The product provokes moderate dermal sensitization by skin contact (Guinea pigs – maximization test). Skin irritation: Mildly irritant to skin of rabbits. Eye irritation: Irritating to eyes of rabbits. Carcinogenicity: A two-year study of Captan indicated duodenal tumors in mice after repeated administration of high dose levels. The NOEL (No Observed Effect Level) was 400 ppm. No evidence of carcinogenicity was observed in long-term studies with rats. Information on the mechanism of these tumors establishes a threshold for the duodenal tumors, and indicates that this tumor type is not relevant for human risk assessment at likely exposure levels. Teratogenicity: Animal studies did not detect any teratogenic effects. No human data available. Mutagenicity: Results taken from in-vivo tests suggest that the product is not mutagenic.
SECTION 12 - ECOLOGICAL INFORMATION
Degradability: The product is readily biodegraded in the environment. Mobility: The product has now mobility and does not leach. Accumulation: The product shows no tendency to bio-accumulate in aquatic organisms. ECOTOXICOLOGY: For active ingredients: Birds: LD50: mallard ducks & pheasants > 5000 mg/kg
bobwhite quail 2000 – 4000 mg/kg Fish: Toxic to aquatic organisms (fish and algae), in laboratory experiments. Low toxicity in actual use, due to its hydrolytic instability. LC50 (96 h) bluegill sunfish 0.072 mg/l
harlequin fish 0.3 mg/l brook trout 0.034 mg/l
Bees: ED50 oral: 91 μg/bee contact: 788 μg/bee Daphnia: LC50 (48 h) 7 to 10 ppm Other Aquatic organisms: Moderately toxic to aquatic invertebrates.
SECTION 13 - DISPOSAL CONSIDERATION
Pesticide disposal Contaminated absorbents, used containers, surplus product, etc., should be burnt at > 1000oC in an incinerator, preferably designed for pesticide disposal, or buried in an approved landfill. Comply with local legislation applying to waste disposal. Do not allow material to contaminate ground water system and surface water. Package product wastes: Do not re-use empty container/bags for any other purpose. Do not contaminate dams, rivers, drinking water and boreholes with chemical or used container. Incinerate the material at a facility that complies with local, state and federal regulations.
Product Name: Captan FS
Page 5 of 5
This revision is issued: June, 2012
MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600
Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227
SECTION 14 - TRANSPORT INFORMATION
UN NUMBER: 3082 ADR/IRD: Class: 9 Substance ID no.: 3082 Hazard ID no.: 90 ITEM: 12(c) PACKING GROUP: III Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG/IMO: Packaging group: III Class: 9 Shipping name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG Page: 9029
SECTION 15 - REGULATORY INFORMATION
Symbol: Xn Indication of danger: Harmful Risk phrases: R 36 May cause eye irritation R 40 Possible risks of irreversible effects. R 43 May cause sensitization by skin contact. Safety phrases: S 1/2 Keep locked up and out of reach children. S 13 Keep away from food, drink and animal feeding stuffs. S 22 Do not breathe dust. S 24/25 Avoid contact with skin and eyes. S 36/37 Wear suitable protective clothing and gloves. S 46 If swallowed seek medical advice immediately and show this container and label.
SECTION 16 - OTHER INFORMATION
Packing: Packed in 1, 2, 5, 10, 20, 25 & 50 kg paper lined bags and/or containers and labeled according to South African regulations and guidelines. Disclaimer: The information on this sheet is not a specification; it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage use of the product. It is not applicable to unusual or non-standard uses of the product nor where instructions or recommendations are not followed. All information is given in good faith but without guarantee in respect of accuracy, and no responsibility is accepted for errors and omissions or the consequence thereof.
1
Carboxin -MATERIAL SAFETY DATA SHEET
Manufacturer/information service:
ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]
1. Chemical Product Identification
Product Name: Carboxin
Molecular Formula: C12H13NO2S
Molecular Weight: 235.3
Chemical Name: 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxamide
2. Composition / Information On Ingredients
Composition CAS No. Content %
Carboxin 05234-68-4 97%
Other ingredient - 3%
3. Hazards Identification
Component Sympol R phrases
Carboxin Xn R36/38/48
More important danger for the man: none
Dangers for the environment:
Soil DT50
2
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20minutes.Remove contact lenses after first 5 minutes. Then continue rinsing eye. Call a Poison control Center of doctor for treatment advie.
If inhaled: remove person to fresh air. Apply artificial respiration if symptoms indicate. Call a physician.
If on skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20minutes Call a Poison Control Center of doctor for treatment advice.
If swallowed: Call a Poison Control Center of doctor for treatment advice. .Do not induce vomiting unless told to do so by a Poison Control Center or doctor. Do not give anything by mouth to an unconscious person.
5 Fire-Fighting Measures
Fire and explosion hazards: not inflammable and not explosive
Extinguishing media: Non-combustible liquid. Use extinguishing media for underlying cause of fire.
Measures of personal protection: Chemical resistant gloves, protective clothing and eye protection should be wore when handling. Lanuder clothing before reuse. In the absence of adequate ventilation, use NIOSH- certified respiratory protection. Environmental cautions EX: prevent the contamination of the floor and of beds of water.
6 Accidental Release Measures Personal cautions: Avoid all personal contact. Observe good personal hygiene.
Cleaning methods
SMALL SPILLS: Wear protective equipment to prevent skin and eye contamination. Contain-prevent run off into drains and waterways. Use absorbent(soil, sand or other inert material). Collect and seal in properly labelled containers for disposal. Wash area down with detergent and excess water.
LARGE SPILLS: Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours. Contain-prevent run off into drains and waterways. Use absorbent(soil, sand or other inert material). Collect and seal in properly labelled drums for disposal. Wash area down with detergent and excess water. If contamination of crops of crops or waterways has occurred advise emergency services or State Department of Agriculture.
7 Handling And Storage
Handling: wearing protective clothing when handling.
Storage: store in a cold and dry location, be far away from fire, heat, food and feed.
3
Technical protective measures: sufficient ventilation to minimize dust exposure. Protect closed dust handling systems against possible dust explosions. Avoid dust accumulations on building or equipment surfaces.
Fire and explosion protection: not inflammable.
8 Exposure Controls / Personal Protection
Personal protective equipment
Respiratory protection: approved respirator
Hand and skin protection : chemical resistant gloves and protective clothing
Eye protection: goggles
Industrial hygiene: use good industrial hygiene. Wear face shield or goggles, elbow lengh PVC gloves, cotton overalls buttoned to the neck and wrist, washable hat and half face respirator with dust and vapour cartridge. After use and before
eating, drinking or smoking, wash hands, arms and face thoroughly with soap and
water.
9 Physical And Chemical Properties
Appearance: white crystals
Boiling point: not available
Density: 1.45
Water solubility: in water 0.147g/L( 20℃)
Other solubility: Soluble in organic solvents, such as acetone 221.2, methanol 89.33, ethyl acetate 107.7(all in g/L,20)
Ph value: 7.5
Flash point: not-applicable
10 Stability And Reactivity
Reactivity: stable for at least 2 years at ambient temperatures. Stable to hydrolysis at pH 5, pH7, and pH9 (25℃),Ina queous solutions exposed to light,DT50 1.54h (pH 7, 25℃)
Conditions to avoid: In condition of heat and humidity
Hazardous decomposition products: Hydrogen cyanide, cyanide salts.
Hazardous reaction: not applicable
11 Toxicological Information
Swallowed:
4
Moderately toxic, Acute oral LD50 (rat): =1300mg/kg
Eyes:
Eye irritation with contact.
Skin:
Low toxicity, acute dermal LD50 (rat): =1050mg/kg. May cause skin irritation with prolonged exposure.
Inhaled:
Mild irritation to nose and throat.
Long term effects:
No information available.
12 Ecological And Ecotoxicological Information
Aquatic Toxicity
Rainbow trout : 96 hr EC50 2.3 mg/L
Bluegill sunfish : 96 hr EC50 3.6mg/L
Daphnia magna : 48 hr EC50 57 mg/L
Terrestrial Toxicity
Mallard duck : LC50(8d) >5000mg/kg diet
Bee: Not hazardous to bees when used as directed; LD50 >181µg/bee
Environmental Fate:
Carboxin will extensively metabolized in rats and eliminated mainly in urine and , to a lesser extent, faeces. Major metabolites in urine are p-hydroxylated carboxin sulfoxide.4-acetamidophenol and its O-glucuronide.
13 Disposal Considerations
Triple or preferably pressure rinse containers before disposal. Add rinsings to spray tank. Do not dispose of undiluted chemicals on site. If recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, break, crush or puncture and bury empty containers in a local authority landfill. If no landfill is available bury the containers below 500mm in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be burnt.
14. Transport Information
Not applicable.
5
15. Regulatory Information
Not applicable.
16. Other Information
All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.
1
Chlorothalonil -MATERIAL SAFETY DATA SHEET
Manufacturer/information service:
ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]
1. Chemical Product Identification
Product Name: Chlorothalonil
Molecular Formula: C8Cl4N2
Molecular Weight: 265.9
Structural Formula:
Chemical Name: Tetrachloroisophthalonitrile (IUPAC)
Form: crystals
Colour: Colourless
Odour: with a slightly pungent odour
CAS No.: 1897-45-6
2. Composition / Information On Ingredients
Composition CAS No. Content %
Chlorothalonil 1897-45-6 98.0
Others ingredients 2.0
3. Hazards Identification
2
Symptoms of Acute Exposure :An extremely severe irritant to eyes. May cause severe skin irritation and contact dermatitis. Allergic skin reactions are possible.
Hazardous Decomposition Products :Can decompose at high temperatures forming toxic gases.
Unusual Fire, Explosion and Reactivity Hazards :During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
4. First Aid Measures
Skin: Remove contaminated clothes. Rinse and then wash skin with plenty of water immediately.
Eyes: Rinse with plenty of water for several minutes (remove contact lenses if easily possible) immediately.
Ingestion: If swallowed induce vomiting by tickling the back of throat. Be quiet and call a
physician
Notes to physician: No specific antidote if ingested. Treat symptomatically.
5. Fire-Fighting Measures
Extinguishing media
To be used: Powder, water spray, foam, carbon dioxide.
Don’t use: Not applicable
Particular risk: None
Measures of personal protection: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants.
Environmental cautions
EX: Prevent the contamination of the floor and the beds of water.
6. Accidental Release Measures
Personal cautions: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants.
Cleaning methods
EX: The empty container may be decontaminated by rinsing two or three times with water and detergent and scrubbing the sides.
Environmental cautions
EX: Prevent the contamination of the floor and the beds of water.
3
7. Handling And Storage
Handling: Handle the pesticide with gloves and wash the hand after handling. Do not apply to humans, their clothing, or bedding. Do not contaminate food or use on household tanks.
Storage: Store at normal temperatures, away from children, domestic animals, food and feed products, seed and fertilizer. Do not contaminate other stored products or the storage area by handling or storage of this product. Keep in a well-ventilated room.
8. Exposure Controls / Personal Protection
Personal protective equipment
Respiratory protection: Approved respirator
Protective gloves: Rubber gloves
Eye protection: Safety goggles or face shield.
Industrial hygiene: adequate ventilation.
9. Physical And Chemical Properties Appearance: Colourless crystals with a slightly pungent odour;
Melting point: 252.1℃;
Density: 2.0 (20℃);
Water solubility: 0.81 mg/l (25℃);
Other solubility: In xylene 80, cyclohexanone, dimethylformamide 30, acetone, dimethyl
sulfoxide 20, kerosene 9.
Incompatibility(Materials to Avoid): Incompatible with oils;
Hazardous reaction: The substance decomposes on heating and on burning producing toxic and corrosive fumes including hydrogen chloride and nitrogen oxides.
11. Toxicological Information
4
Acute oral LD50 : >5000mg/kg (rat)
Acute dermal LD50 : >10000mg/kg (rabbit)
Acute inhalation LC50 (1hour) :>4.7mg/L 9 (rat)
Contact with the skin:Modertate irritation (rabbit);
Contact with the eyes: Severe irritation (rabbit).
Reproductive effects: Administration of high doses of chlorothalonil to pregnant rabbits through the stomach during the sensitive period of gestation was required to induce abortion in 4 of the 9 mothers. This and other studies suggest that chlorothalonil will not affect human reproduction at expected exposure levels.
Teratogenic effects: Long-term studies indicate that high doses fed to rats caused reduced weight gains for males and females in each generation studied. Female rats given high doses of chlorothalonil through the stomach during the sensitive period of gestation had normal fetuses, even though that dose was toxic to the mothers. A study of birth defects in rabbits showed no effects. Chlorothalonil is not expected to produce birth defects in humans.
Mutagenic effects: Mutagenicity studies on various animals, bacteria, and plants indicate that chlorothalonil does not cause any genetic changes. The compound is not expected to pose mutagenic risks to humans.
Carcinogenic effects: Based on evidence from animal studies, chlorothalonil's carcinogenic potential is unclear. Male and female rats fed chlorothalonil daily over a lifetime developed carcinogenic and benign kidney tumors at the higher doses. In another study, where mice were fed high daily doses of chlorothalonil for 2 years, females developed tumors in the fore-stomach area (attributed to irritation by the compound) and males developed carcinogenic and benign kidney tumors.
Organ toxicity: Chronic studies of rats and dogs fed high dietary levels show that chlorothalonil is toxic to the kidney. In addition to less urine output, changes in the kidney included enlargement, greenish-brown color, and development of small grains.
12. Ecological And Ecotoxicological Information
Effects on birds: Chlorothalonil is practically nontoxic to birds. The LD50 in mallard ducks is 5000 mg/kg. Most avian wildlife are not significantly affected by this compound.
Effects on aquatic organisms: Chlorothalonil and its metabolites are highly toxic to fish, aquatic invertebrates, and marine organisms. Fish, such as rainbow trout, bluegill, and channel catfish are noticeably affected even when chlorothalonil levels are low (less than 1 mg/L). The LC50 is 0.25 mg/L in rainbow trout, 0.3 mg/L in bluegills, and 0.43 mg/L in channel catfish. Chlorothalonil does not store in fatty tissues and is rapidly excreted from the body. Its bioaccumulation factor is quite low . Effects on other organisms: The compound is nontoxic to bees.
5
13. Disposal Considerations Disposal must be in accordance with applicable local regulations. Remove nonusable solid materials and/or contaminated soil for disposal in an approved and permitted landfill. Do not flush into surface water or sanitary sewer systems. Spillage disposal: Do not wash away into sewer. Do not let this chemical enter the environment. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place.
14. Transport Information
Not applicable.
15. Regulatory Information
Not applicable.
16. Other Information
All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.
Phase I, UPSIDe, IndustrtalArea, Sandila
Olstrict·HardOl-241127 .P. INDIA Website : IWW indiapesticldeslimited.com
E-mail : [email protected]
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mailto:[email protected]
PROJECT DETAIL
Mis India Pesticides Pvt. Ltd (Sandila Unit) is located at Plots No. K-6, 7, 8, 9 and K-IO, Phase - I,
UPSIDC Industrial Area, Tehsil-Sandila, Hardoi-(Uttar Pradesh) and total land area is about 2.67
hectares. Industry salient features are given below:
Plot No. ! K-6,7,8 ,9 and 10, (K-2- K-II and D2-D4)*
Location UPSIDC Sandi la, Village Mahfona, Tehsi l-
Sandila,Hardoi, Uttar Pradesh .
Latitude 27° OS' 30.67" N
Longitude 80° 27' 14.97" E
I Nearest State Highway SH-25 (Adjacent to Site - S)
Nea rest Railway Station Sandil a (4 km - W)
Nearest Airport Amausi (70 km)
Nearest Town Sandila Town (6 km)
Project Site is Iocatcd within the Notified Industrial Area ofUPSIDC
*Requcst for inclusion of additional plots made to MoEF&CC on 06 September 2016 vide
letter no. IAiUP/IND2/S8820/2016 consent already granted by the UPPCB to include all the
proposed land as given.
CURRENT STATUS OF POINT - WISE COMPLIANCE
A. SPECIFIC CONDITION
I. State Pollution Control Board may grant
~ 'consent to operate' atter ensuri ng comptete
shifting of dumped hazardous waste from the
I other plant premises of Mis India Pesticides
[' I imited at Lucknow to authorized secure landtiU
I. Air & Water Consent is granted from
UP Pollution Control Board. The
copy of Air & Water Consent is
enclosed as Annexure- J.
11.
Ill.
IV.
V.
site.
National emIssIon standard for Pesticide
manufacturing and formulation industry issued
by Ministry vide G.S.R 46(E) dated 3'd
February 2006 and amended time to time shall
be followed by the unit.
Mlilticyclone followed by bagfilter along with
adequate slack height shall be provided to rice
husk fired boiler and thermic fluid heater to
control particulate emissions.
Two stage water scrubber followed by alkali
scrubber shall be provided to process vent to
control S02, HCL, HBr, H2S and CL2emission.
Two stage water scrubbers shall be provided to
process vent to control NHJ emissions. P20 S
shall be controlkd by water scrubber followed
by demister. The scrubber water shal :1 be sent to
ETP for further treatment. Efficiency of
scrubber shall be monitored regulady and
maintained properly. Scrubbers vent shall be
provided within on-line detection and alarm
system to indicate higher than permissible value
of controlled parameters. At no time, the
emission levels shall go beyond the prescribed
standards. The system should be interlocked
with the pollution control equipments so that in
case of any increase III pollutants beyond
permissible limits, plant should be
automatically stopped. Stack monitoring shall
be done regularly and report sha'll be submitted
to UP Poiliution Control Board (UPPCB) and
Ministry's regional office at Lucknow.
rn order to control odour, outlet of process vents
II. Ii Plant has been designed to ensure I
this. The copy of emission test
reports is enclosed as Annexure-2.
III. The nce husk boiler and hot air
generator are equipped with multi
cyclone and bagfilter and stack
height of 30 meters
IV. Two stage water scrubber followed
by aLkal i scrubber has been provided
for process vent gases like HCI &
Cb which are emission gases emitted
during present products
manufacturing. The scrubber water is
being sent to ETP for further
treatment. There is no emission of
NH3 and P20 S 111 the present
prod ucti on process. Scrubbers are
monitored at every 6 hours for
alkalinity.
Efficiency of scrubbers is monitored
regularly, the monitoring reports is
enclosed as annexure-2.
V. As informed earl ier the process vents
I
VI.
VII.
shall be connected to the incinerator.
In plant control measures for checking fugitive
emission from all the vulnerable sources shall
be provided. Fugitive emission shall be
controlled by providing closed storage, closed
handling & conveyance of chemicals/materials,
mul.ti cyclone separator and water sprinkling
system. Dust suppression system including
water sprinkling system shall be provided at
loading and unloading areas to control dust
emission. Fugitive emission in the work zone
environment, product, raw material storage area
etc. shall be regularly monitored and records
maintained. The emission shall conform to the
limits slipulated by the UPPCB.
For further control of fugitive emission,
fol'lowing steps shall be followed:
a. Closed handling system shall be provided
for chemicals.
b. Reflux condenser shall be provided over
reactor
c. System of leak detection and repair of
pUlllp/pipeline based on preventive
maintenance.
d. The acids shall be taken from storage tanks
to reactors through trap recei ver and
condenser operated on chilled water.
e. Cathodic protection shall be provided to the
underground solvent storage tanks.
VI.
VII.
have been connected to scrubber.
Currently no incinrable gases are
emitted. Whenever the product mix
requires the installation of
incinerator, the same shall be
provided.
CJ.osed storage, handling and
conveyance system have been
provided along with water sprinkling
system. Multi cyclone separators I
have been provided in the bagging
area. Regular monitoring of fugitive
emission is being performed. The
Ambient Air analysis report IS
enclosed as annexure-2.
a. Closed handling system is
provided for chemicals.
b. Reflux condenser is provided
over reactors.
c. System for leak deduction of
chlorine has been installed
Preventive maintenance of all
the critical equipments and
pumps is followed with proper
record keeping.
d. Trap receiver /Priming pots is
connected with pumps.
e. There is no underground storage
tank for storage of sol vents for
the present products.
VIII.
IX .
X.
XI.
XII.
~
A proper leak detection and repair (LDAR)
program for pesticide industry shall be prepared
and implemented as per CPCB guidelines.
Focus shall be given for prevention of fugitive
emissions for which preventive maintenance of
pump, valves, pipelines are required. Proper
maintenance of mechanical seals of pumps and
valves shall be given. A preventive maintenance
schedule for each unit shall be prepared and
adhered to.
Continuous monitoring system for VOCs, Hel,
HBr and chlorine, shall be installed at all
important places/areas. Effective measures shall
be taken immediately. When monitoring resu lts
indicate above the permissible limits. All
necessary steps shall be taken for monitoring of
chlorine, HCI and HBr as well as VOCs in the
proposed plant.
Alarm for chlorine leakage if any the liquid
chlorine storage area shall be provided along
with automatic stalt of the scrubbing system.
The gaseous emission DG set shall be dispersed
through adequate stack height as per CPCB
standards . Acoustic enclosure shall be provided
to the DG sets to mitigate the noise pollution.
Tile company shall upload the status of
compliance of the stipulated environmental
clearance conditions, including result of
monitoring data on its website and shall update
the same periodically it shall simultaneollsly be
VIII.
IX
X
XI
XII
A leak deduction and repair program
has been formulated and is pali of
the production process. Preventi ve
maintenance of all the critical
equipments and pumps is followed
with proper record keeping.
We are regularly monitor ambient air
for the parameters S02, NOx, SPM
(PM 1o & PM 2.5, ), C1 2, HCL, HBr &
CO the repolis is attached as
annexure-2. There is no emission of
VOC' s and HBr during the present
manufacturing operation.
Alarm for chlorine leakage is
instaUed 111 the liquid chlorine
storage area along with automatic
start of the scrubbing system.
All the D.G sets have proper stack
height along with acoustic enclosure.
a. The compliance repOli is
regul arly submitted to the
MoEF&CC and UPPCB.
b. The compl iance repolt IS
regularly uploaded on the
company website. sent to the regional office of MoEF the
XIII.
XIV.
xv.
respective zonal office of CPCB and the
UPPCB. The levels of PM IO, S02, Nox, VOCs,
HCI, HBR, CO and HC (Methane and Non-
Methane) in ambient air and emission from the
stacks shall be monitored and displayed at a
convenient location near the main gate of the
company and at important publ ic places.
Chilled brine circulation system shall be
provided condensate sol vent vapors and reduce
solvent losses. It shall be ensured that solvent
I recovery shall not be less than 95%
Solvent management shall be carried out as
follows:
f. Reactor shall be connected to chilled brine
condenser system.
g. Reactor and solvent handling pump shall
have mechanical seals to prevent leakages.
h. The condensers shall be provided with
sufficient HTA and residence time so as to
achieve more than 95% recovery.
I. Solvent shall be stored in a separate space
specified with all safety measures.
J. Proper earthing shall be provided in all the
electrical equipment wherever solvent
handling is done.
k. Entire plant shall be flame proof. The
solvent storage tanks should be provided
with breather valve to prevent losses.
Total water requirement from groLind water
source shall not exceed 135m3/day and prior
permission shall be obtained from the
CGWA/SGWA.
Xlli.
XIV.
XV.
c. We regularly monitor and
display ambient air and stack
emission near the main gate of
company which IS distinctly
visible to the public.
Has been provided as directed
Currently no solvent based product is
being manufactured.
Solvent management will be
complied with before start of
production of solvent based
products, however reactors are
connected to chil iled brine condenser
system and pumps are provided with
flame proof motors and electric
connections.
Central Ground Water authority
permission has been granted vide
letter no.
(521 )INR/CGWA/20 13-1850 dated
14/11/2014. We monitor daily water
21-4
XVI.
XVII.
XVIII.
XIX.
As proposed industrial effluent generation shall XVI.
not ex.ceed 60 m3/day effluents shall be
segregated into high COD, high TDS and low
CODITDS effluent steams. High COD
effluent/mother liquor shall be incinerated. High
TDS effluent shall be treated through stripper
followed by MEE. Low COD/TDS effluent
shall be treated in ETP. Treated effiuent shall be
recycled/ reused within the factory premises.
Water quality of treated effluent shall be
monitored regularly and monitodng report shall
be submitted to the UPPCB. Domestic
wastewater shall be treated n STP.
No effluent shall be discharged outside the XVII.
premises and "Zero" discharge concept shall be
adopted.
Process eftluent/any waste water shall not be . XVIII.
allowed to mix. storm water. Strom water drain
shall be passed through guard pond.
Incinerator comprising primary & secondary XIX
chamber shall be designed as per CPCB
guidelines . S02, NOx, HCL and CO emission
consumption i~ our plant. The record I.
of water consumption is enclosed as
annxure-3.
The industry is a zero liquid
discharged industry. All the waste
water generated during the process
are treated in a 150 KLD treatment
plant consisting of one equalization
tank, sparger filter (for removed of
suspended inspirits), steam stripper
(for removal of organic compounds.
The em uents from here are taken to
a two stage RO system. . The
permeate IS recycled back In the
process and the reject is further
evaporated in MEE. The condensates
used in process and solid residue
send to TSDF.
AS described the industry is a Zero
liquid discharge unit removed solids
from MEE arc regularly sent to
TSDF. A sample copy of Frol11-1 0 is
enclosed as annexure-4.
Recovered water frol11 RO & MEE is
recycled in the plant.
Process effluent/any waste water IS
not allowed to mix with storm water.
Strom water drai ns are separated and
entire storm water is collected in
impervious guard pond.
Whenever the product mix requires
the installation of incinerator we
stand committed to instal l the same.
S02, NOx, HCL and CO are beingshail be monitored in the stack regularly. I regularly monitored in stack.
Hazardous chemicals shall be stored in tank in XX Flame arresters shall be provided on
tank forms, carboys etc. Flame arresters shall be
xx.
tank farm when ever solvents are
provided on tank farm. Sol:vent transfer shall be stored.
by pumps.
The company shall obtain authorization for XXI We have membership of UP Waste
collection, storage and disposal of hazardous
XXI.
Management Project and we are
waste under the Hazardous waste (Management sending all the generated hazardous
handling and trans-boundary movement) Rules, waste to TSDF. The sample copy of
2008 and amended as on date for management From-lOis enclosed as annexure-4.
of hazardous waste and prior permission from
UPPCB shall be obtain for disposal of solid I
hazardous waste in the TSDF measure shall be
taken for fine fighting facilities 111 case of
emergency membership of TSDF of hazardous
waste disposal sha'" be obtained.
XXII. As proposed, ETP slludge & 'ncineration ash XXII No incinerable ash IS being
shall be sent to TSDF site. High calorific vallues generated.
waste such as spent organic shall be inci nerated. We have membership of UP waste
management project and we are
sending all the generated ETP sludge
to TSDF. The sample copy of From-
lOis enclosed as annexure-4.
XXIII. The company shall strictly comply with the rule XXIII We are complying with the '
& guideline under manufacture, storage and manufacture, storage and import of
impact of hazardous chemicals (MSIHC) rules Hazardous Chemicals (MSIHC)
1989 as amendment in October 1994 & January rules 1989. Under its compliance we
2000. A II transportation of hazardous chemicals ha ve prepared -
shall be as per the Motor vehicle Act (MYA) i. Notification of Site report I
1989. (Schedule-7)
ii. Safety report (Schedule-8)
iii. On-Site emergency plan
XXIV . The company shall undertake following waste
minimization measures.
a. Metering & control of quantities of active
ingredients to minimize waste.
b. Reuse by products from the process as raw
materials or as raw material substitutes in
other process.
c. Use of automobile filling to minimize
spillage.
d. Use of close feeds system in to batch
reactors.
e. Venting equipment through vapour I
recovery system. i
f. Use of high pressure hoses for equipment
clearing to reduce waste water generation.
XXV. The unit shall make the arrangement for
protection for possible fire hazards during
manufacturing process in mater·ial handling.
I Fire fighting system shall be as per the norms.
XXVI. Occupational health survei lIance of the workers
shall be done on a regular basis and records
mainta,ined as per the factory Act.
XXVII. Green belt shall be developed at least in 33% of
(Schedule-II)
iv. Safety Audit (Rule-l 0)
And these reports have been
submitted to concerning authorities.
XXIV Rotameter, Level Gauges weighing
balance & close feed system are
provided by-products are reused in
process. Automated filling system
has been installed. Batch reactor has
been provided with closed feed
system. Venting equipment has been
installed. High pressure hoses will be
used for clearing.
XXV I We are fdlly equipped with tire
fighting & inbuilt safety systems.
We have No-objection certificate
from UP fire department. The copy
of NOC of fire fighting & inbuilt
safety system is enclosed as
annexure-5.
XXVI Occupational health center is
provided and employee 's medical
record is maintained. As per
Factories rules i 950, the med ical
record of employees is maintained in
Form-17 & 27.
XXVII 500 trees of various species have
the plant area in and around the plant premises already been planted.
to mitigate the effects of fugitive emission all
around the plant as per the CPCB Guideline in
consultation with DFO. Thick greenbelt with
suitable plant species sha!! be developed around
the proposed pesticides unit to mitigate the
odour problem. Selection of plant species shall
be as per the CPCB guidelines.
XXVIII. Provision shall be made for the housing for the XXVIII Local construction workers
construction labour within the site with all employed. No worker is residing in I
I necessary infrastructure and faci Iities such as the plant premises.
fuel for cooking, mobile toilets, safe drinking
water, medical health care, creche etc. The
hOLlsing may be 111 the form of temporary I
I structure to be removed after the complet,ion of
the project. All the construction \Nastes shall be
managed so that there is no impact on the
surrounding environment
B. GENERAL CONDITION
The prqject authorities shall strictly adhere to I We are committed to comply all
the stipulations made by the UP Pollution the conditions impose in the Air
Control Board. & water consents order of UP
Poll ution Control Board. The
compliance report of Air & Water
consent is enclosed as annexure-
6.
II No further expansion or modi fication in the II *Request for incli.lsion of
plant shall be carried out without prior approval
of the Ministry of Environment and Forests. In
case of deviations or allteration in the project
proposal from those submitted to the ministry of
additional plots made to
MoEF&CC on 06 September
2016 vide letter no.
IA/UP/IND2/58820/20 16
clearance, a fresh reference shall be made to the
ministry to assess the adequacy of conditions
imposed and to add additional environmental
protection measures required, if any
III The location of ambient air quality monitoring III
stations shall be decided in consultation with the
UPPCB and it shall be ensured that at least one
station is installed in the upwind and downwind
directions as well as where maximum ground
level concentration are anticipated.
~
The overall noise levels in and around the plant lV.[v .
area be dept well within the standards by
providing noise control measures including
acoustic hoods, si tencers, enclosures etc. on all I
sources of noise generation. The ambient noise
levels sha II conform to the standards prescri bed
under Environment (Protection) Act, 1986 rules,
1989 viz. 75 dBA (Day Time) and 70 dBA
(night time)
The company shall harvested rainwater from the V.
roof-tops of the building and storm water drains
to recharge the ground water and use the same
water for the process acti vities of the project to
conserve fresh water.
V.
VI. During transfer of materials, spillages shall be VI.
avoided and garland drains be constructed to
avoid mixing of accidental spillages with
domestic waste water and storm water drains .
VII. . Usage of personnel protection equipments by al l VII.
employees / workers shull be ensured .
consent already granted by the
UPPCB to include all the
proposed land as given.
We have made two ambient air
monitoring stations equipped with
RDS & PM2.5 in the up wind &
down wind direction. The regular
ambient air monitoring is done by
our plant. The copy of ambient air
monitoring is enclosed as
annexure-2.
Are being complied with
Rain water storage system is
implemented in our plant along
with impervious guard pond. No
recharge to ground water is
prescribed because of being a
pesticide unit.
[s being complied with.
All the workers have helmet,
safety shoes, nose mask and other
VIII. Training shall be imparted to al.1 employees on
safety and health aspects of chemicals handl ing
pre-emp,loyment and routine periodical medical
examinations for all employees shall be
undertaken on regular basis. Training to all
employees on handlling of chemicals shall be
imparted.
IX The company shall also cQmp'ly with all the
environment protection measures and safeguard
I proposed in the project report submitted to the
ministry. All the recommendation made in the
EIA/EMP 111 respect of environment
management, risk mitigation measure & public
hearing relating to the project shall be
implemented.
X The company shall undertake CSR activit,ies
and all relevant measure for im proving the socio
economic condition of the surroundi ng area.
XI The company shall under take Eco-
development measure including community
welfare measure in the project areas for the
overal ll ~ improvement of the environment.
XII A separate Envi ronmental Management Cel I
equipped with full Iledged laboratory facilities
shal 'l be set up -to carry out the environmental
management and monitori ng function.
I XIII The company shall earmark sufficient funds for
I recurring cost pCI' annum to implement the
conditions stipulated by Ministry of
Environment and Forests as well as the State
Government along wi,th implementation.
Schedule for all the condition stipulated herein.
IX.
X.
XI.
XI l.
XIII.
safety PPs which is required.
We have regularly imparted
safety training through our safety
officers, who is well qualified
from Regional Labour Institute
Kanpur.
Is being complied with.
J
We are doing various activities to
Improve the socio economJC
condition of the surrounding area.
For the eco development of the
area we are in the process to plant
various trees along road side of
the industrial area.
We have separate environment
cell equipped with trained man
power along wi th desired
equipment.
The company is committed to
provide suitable funds for
implementing the condlitions of
clearance.
XIV
XV
XVI
XVII
The funds so earmarked for environmental
management/pol 'llution control shall not be
di verted for any other purpose.
A copy of the clearance letter shall be sent by
the project proponent to concerned Panchayat,
Zila parisad/Municipal corporation, Urban local
Body and the local NGO, if any, from who
suggestion/ representation, of any were recei ved
while processing the proposal.
The project proponent shall also submit six
monthly reports on the status of compliance of
the stipulated Environmental Clearance
condition includ ing result of monitored data
(both in hard copies as well as bye-mail) to the
respective Regiona:11 office of MoEF, the
respective Zona] Office of CPCB and the U.P
Pollution Control Board. A copy of
Environmental Clearance and SIX monthly
compliance status reports shall be posted on the
web side of the company.
The Environmental statement for each financial
31 s1year ending march III form-Vas is
mandated shall be submitted to the U.P.
Pollution Control Board as prescribed under the
Environmental (Protection Rules, 1986, as
amended subsequently, shall also be put on the
website of the company along with the status of
compliance of environmental clearance
conditions and shal l be sent to Lucknow
Regional offices of MoEF by e-mai t.
The project proponent shall inform the public I
that the project has accorded environmental
clearance by the Ministry and copies of the
XIV
XV
XVI
XVII
Not applicable as no public
hearing was held. Industry
located in approved industrial
area of UPSIDC.
I
We are regularly submitted
compliance report to MoEF&CC
& UPPCB.
The last environmental statement
is submitted to UPPCB as
prescri be under Envi ronment
Protection rule 1986. The copy of
submission letter is enclosed as
annexure-7.
Already done.
clearance letter are available with the
SPCB/Committee and may also be seen at
website of the ministry at hrt: //envfor.nic.in.
This shall be advertised within seven days from
the date of issues of the clearance letter, at least
In two local newspaper that are widely
circulated in the region of which one shall be in
the vernacular language of the locality
concerned and a copy of the same shall be
forward to concerned regional Office of the
ministry.
I
XVIII The project authorities shall inform the XVIII Shall be complied with.
Regional office as well as the Ministry, the date
of tinancial closure and final approval of the
project by the concerned authorities and the date
of start of the project.
http:hrt://envfor.nic.in
1
Difenoconazole -MATERIAL SAFETY DATA SHEET
Manufacturer/information service:
ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]
1. Chemical Product Identification
Product Name: Difenoconazole
Molecular Formula: C19H17Cl2N3O3
Molecular Weight: 406.3
Structural Formula:
Chemical Name: 1H-1, 2, 4-Triazole, 1-[[2-[2-chloro-4-(4-chlorophenoxy) phenyl]-4-methyl-1, 3-dioxolan-2-yl] metyl]
Form: power
Color: gray white
Odor: Paint
CAS No.: 119446-68-3
2. Composition / Information on Ingredients
Composition CAS No. Content %
Difenoconazole 119446-68-3 95.0
Other ingredients 5.0
3. Hazards Identification
2
Symptoms of Acute Exposure: May cause eye irritation. Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases. Unusual Fire, Explosion and Reactivity Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
4. First Aid Measures
General: Remove the affected person from the danger zone to a well-ventilated room or to fresh air, and protect from undercooling. In case of suspected poisoning: Immediately call a physician.
Eye Contact: Rinse eyes with clean water for several minutes and immediately call a physician.
Ingestion: Repeatedly administer medicinal charcoal in a large quantity of water. Note: Never give anything by mouth to an unconscious person. Do not induce vomiting.
Skin Contact: Remove contaminated clothing and thoroughly wash the affected parts of the body with soap and water, including hair and under fingernails.
Medical Instructions
Antidote: No specific antidote is known! Apply symptomatic therapy. Experiences Specific to Man: No case of human poisoning is on recor
5. Fire-Fighting Measures
Suitable Extinguishing Media: Dry chemical extinguisher, foam, carbon dioxide or water spray (do not use direct jet of water).
Special Hazards during Fire Fighting: Combustion products are toxic and/or irritant. Measures have to be taken to prevent the contaminated extinguishing agent from seeping into the ground or from spreading uncontrollably.
Protective Equipment for Fire Fighting: Use self contained breathing apparatus. Wear protective equipment.
6. Accidental Release Measures
Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.
3
7. Handling and Storage
Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.
8. Exposure Controls/Personal Protection
Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.
Eye Contact: Where eye contact is likely, use chemical splash goggles.
Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and chemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear.
Inhalation: A respirator is not normally required when handling this substance. Use effective engineering controls to comply with occupational exposure limits.
9. Physical and Chemical Properties
Flash-Point: 64 °C
Melting point : 78.6℃
Density: 1.40g/cm3@20℃
Vapor pressure; 3.3×10-5mPa@25℃
PH Value: 5 - 8 (1 %; in deionised water) CIPAC MT 75
Solubility: 15mg/l@25℃
Partition coefficient; KowlogP=4.20@25℃
10. Stability and Reactivity
Stability: Stable under normal use and storage conditions.
Hazardous Polymerization: Will not occur.
Conditions to Avoid: None known.
Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases.
Materials to Avoid: Strong oxidizers.
11. Toxicological Infor