ANNEXURE –A DETAILS OF PRODUCTS Sr. no. [ MT/month ] · 2017. 9. 12. · Sr. no. Name of Product Quantity [ MT/month ] 1 ... 12 Sulphuric acid [98%] 3.86 13 Sodium Per Sulphate

Annexures to Form – 1 & Pre Feasibility Report Proposed Project for manufacturing of Dyes Intermediates of

M/s Jay Dyechem, Narol-Vatva Road,Ta : City, District : Ahmedabad, Gujarat.

ANNEXURE –A

DETAILS OF PRODUCTS

Sr. no.

Name of Product Quantity [ MT/month ]

1. Sulpho OAVS And / OR

25.0 [ Real ]

2. 3 Aniline 2,4 Di Sulphonic Acid And / OR

3. 4 – NAPSA And / OR

4. BLUE HEGN BASE And / OR

5. 4 CAP [ 4 Chloro 2 Amino Phenol] And / OR

6. C ACID And / OR

7. Sulpho C Acid And / OR

8. PERI ACID And / OR

9. Acetyl Bronner’s Acid

Name of By Products

1. Laurent’s Acid 15.0

2. Spent Sulphuric Acid Max. 350


M/s Jay Dyechem, Narol-Vatva Road, Ta : City, District : Ahmedabad, Gujarat.

ANNEXURE – B

Details Of Raw Materials Consumption

Sr. No.

Name of Raw Material Consumption [MT/Month]

SULPHO OAVS

1 OAVS 18.05

2 Sulphuric Acid 29.23

3 Oleum [23%] 45.73

4 Ice 150.42

5 Salt 22.56

3 ANILINE 2,4 DI SULPHONIC ACID

1 Sulphanilinc Acid 11.11

2 Oleum [23%] 33.33

3 Water 11.11

4 Ice 22.22

4 NAPSA

1 PNCB 12.96

2 Oleum [23%] 38.89 3 Nitric acid [98%] 9.07 4 Water 183.33 5 Salt 44.45 6 Caustic soda 7.41

7 NaSH 33.33

BLUE HEGN BASE

1 Water 92.59 2 Lime stone powder 7.72

3 Ethylene DiAmine 22.22

4 PNCBOSA 18.52

5 HCl [28%] 92.59



6 Acetic acid 4.32

7 Cast Iron powder 15.43

8 Caustic lye [48%] 6.48

9 Chloramide 6.94

10 Sodium Bi Carb 6.17

11 Oleum [23%] 92.59

12 Sulphuric acid [98%] 3.86

13 Sodium Per Sulphate 14.66

14 Ice 246.91

15 Water-washing 30.86

4 CAP

1 Water 138.88

2 2,5 Di Chloro Nitro Benzene 41.67

3 Caustic Flakes 33.33

4 HCl 86.81

5 Salt 20.83

6 C I powder 41.67

7 Caustic 13.89

C ACID

1 Naphthalene 27.78

2 Sulphuric acid 109.29

3 Oleum [ 65%] 100.43

4 Nitric acid [70%] 23.61

5 Water 200.62

6 MgO 30.86

7 C I powder 24.69

8 Soda Ash 30.86

9 Dilute Sulphuric acid 18.52



SULPHO C ACID

1 C acid 27.78


3 Oleum [65%] 65.41

4 Glauber salt 34.05

5 Water 134.41

PERI ACID

1 Naphthalene 41.79


3 Nitric acid [62%] 37.99

4 MgO 24.70

5 Lime stone powder 87.39

6 Cast iron powder 41.79

7 HCl 9.50

8 Acetic acid 1.90

9 Water 113.98

10 Dilute Sulphuric acid [30%] 12.65

Acetyl Bronner's Acid

1 Water 146.81

2 Bronner's Acid 20.973

3 Caustic lye 25.168

4 Acetic Anhydride 11.326

5 Salt 22.232

Annexures to Form – 1 & Pre Feasibility Report for Proposed Project of Dyes intermediates manufacturing of


ANNEXURE – C

DETAILS OF MANUFACTURING PROCESS

1.] SULPHO OAVS :

Sulphonation

Drawing / Isolation

Filtration

Centrifuge

Sulpho OAVS [ wet cake ] [1662] [65%]

OAVS[1200] Sulfuric acid [98%] [1943] Oleum [23%] [3040]

Ice[10000] Salt [1500]

Spent Acid [30%] [16021]



2.] 3-ANILINE 2,4 – DI SULPHONIC ACID :

Sulphonation

Drawing / Isolation

Filtration

Centrifuge

3-Aniline 2,4–Di Sulphonic Acid [ wet cake ] [2250] [65%]

Sulphanic acid [1000] Oleum [23%] [3000]

Ice [2000] Water [1000]

Spent Acid [30%] [4750]



3.] 4 – NAPSA [ 4-Nitro 2-Amino Phenol Ortho Sulphonic Acid ] :

Sulphonation

Dumping

Filtration

Centrifuge

4-Nitro 2-Amino Phenol Ortho Sulphonic Acid [ wet cake ]

[1350] [65%]

PNCB [700] Oleum [23%] [2100]

Water [4900] Salt [1400]

Spent Acid [30%] [7808]

Nitration Nitric Acid [98%] [490]

Hydrolysis + Reduction + Isolation

Caustic Soda [400] Water [5000] NaSH [1800] Salt [1000]

Filtration

Centrifuge

ML to ETP [8632]



4.] BLUE HEGN BASE :

Condensation

Filtration

Centrifuge

Blue HEGN Base [ wet cake ] [810] [65%]

Water [1500] LSP [ 250] EDA [720] PNCBOSA

ML to ETP [5070]

Isolation HCl [3000]

Reduction C. I. Powder [500] Acetic Acid [140] Caustic Lye [210] Water [1500]

Filter Press

Centrifuge

ML to ETP [3300]

Iron Sludge [700]

Washing Water [1000]

Condensation Chloranile [225] Sodium Bicarb [200]

Filtration

Drying Vapour Loss [235]

Cyclization

Oleum [23%] [3000] Sul. Acid [98%] [125] SPS [ 475]

Dumping Ice [8000]

Centrifuge

ML to ETP [11330]

Filtration



5.] 4-CAP [ 4-Chloro 2-Amino Phenol ] :

Hydrolysis

Filtration

Centrifuge

4 - CAP [360]

Water [1000] 2:5 DCNB [ 600] Caustic Flakes [480]

ML to ETP [1980]

Isolation HCl [450] Salt [300]

Reduction C. I. Powder [600] HCl [150] Caustic Lye [200] Water [1000]

Filter Press

Centrifuge

ML to ETP [3135]

Iron Sludge [800]

Washing Water [1000]

Isolation HCl [ 650 ]

Filtration




6.] C – ACID :

Sulphonation

Neutralization

Filtration

C Acid [1012 ] [80%] [ 810 – Real ]

Naphthalene [900] Sul. Acid [3541] Oleum [65%] [3254]

Water [4000] MgO [1000]

ML [6460]


Reduction C.I. Powder [800] Soda Ash [1000] Water [5000]

Filter Press

Wet cake [1350]

ML to ETP [4150]

Iron Sludge [2400]

Isolation

Filtration

Dil H2SO4 [600]




7.] SULPHO C – ACID :

Sulphonation

Dumping

Filtration

Centrifuge

Sulpho C Acid [ wet cake ] [2325] [60%] [1395 – Real ]

C Acid [1550] Sulphuric Acid [2700] Oleum [65%] [3650]

Water [7500]

ML to ETP [14975]

Isolation Glauber Salt [1900]



8.] PERI ACID :

Sulphonation

Neutralization

Filter Press

PERI Acid [700 ] [94%] [ 658 – Real ]

Naphthalene [1100] Sul. Acid [2200]

Water [3000] MgO [500] Lime Stone Powder [2300]

Gypsum sludge [4000]


Reduction

C.I. Powder [1100] HCl [250] MgO [150] A.Acid [50]

Filter Press

Wet cake [950]

Laurent’s Acid sol. [5033]

Iron Sludge [3000]

Isolation

Filtration

Dil H2SO4 [333]


Washing water [1000]

Dil H2SO4 [150]

Filtration

Wet cake [500]


Laurent’s acid [400]

ML to ETP [4683]



9.] ACETYL BRONNER’S ACID :

Water [3500 lts] Bronner’s Acid [500 kg] Caustic lye [600 kg] Acetic Anhydride [270 kg] Salt [530 kg]

Acetylation 5400kg

Nutch filter & centrifuge ML TO ETP

[4700 kg]

W/c [700 kg]

Drying & Packing [596kg]

Water evaporation [104]



ANNEXURE - D

DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION

DETAILS OF WATER CONSUMPTION :

Sr. no. PURPOSE Consumption, KL/day

1. Domestic 1.0

2. Industrial

a. Process [including ice ] 16.5

b. Boiler make up 4.0

c. Cooling make up 0.1

d. Washing water 0.2

e. Any other – i. Gardening ii. Scrubbing

2.5 0.4

TOTAL [2] Max. 23.7 **

TOTAL [1+2] 24.7

Note : ** - The water consumption will be maximum considering worst case scenario.



DETAILS OF WASTE WATER GENERATION :

Sr. no. PURPOSE Generation, KL/day

1. Domestic 0.8

2. Industrial

a. Process 36.0

b. Boiler blow down 0.02

c. Cooling bleed off 0.0

d. Washing water 0.2

e. Any other – i. Gardening ii. Scrubbing

0.0 0.4

TOTAL [2] Max. 36.62**

TOTAL [1+2] 37.42

Note : ** - The generated waste water will be maximum considering worst case scenario.

Annexures to Form – 1 & Pre Feasibility Report Proposed Project for Dyes intermediates manufacturing of


ANNEXURE – E

DETAILS OF EFFLUENT TREATMENT PLANT

There will be waste water generation from the domestic and industrial activities. The industrial activities includes the waste water from manufacturing process, utilities, washing water and exhausted scrubbing media.

The generated domestic waste water will be disposed through septic tank –soak pit system.

The generated industrial waste water will be collected in the collection tank. Then it will be taken to the neutralization tank and then filtered through filter press. The neutralized waste water will be collected in the holding tank and from there it will be sent to Common MEE system of Vatva for final disposal.

Collection

tank Neutralization

tank Filter Press Holding tank

ETP sludge sent to TSDF

Primary treated effluent sent to Common MEE

system

Raw effluent from the

plant



ANNEXURE – F

DETAILS OF AIR POLLUTION CONTROL MEASURES

DETAILS OF FLUE GAS EMISSION

Sr. No.

Stack Attached

to

Capacity Name of fuel & its

consumption

Stack Height

Air pollution Control System

Parameters

1. Steam Boiler

1 T/hr. Bio Coal @ 1 T/day

11 m Cyclone separator

followed by bag filter

PM < 150 mg/Nm3 SO2 < 100 ppm NOx< 50 ppm

2. D. G. set [ For Emergency Purpose only ]

75 KVA Diesel @ 15 L/hr.

6 m ---- PM < 150 mg/Nm3 SO2 < 100 ppm NOx< 50 ppm

DETAILS OF PROCESS GAS EMISSION

Sr. No.

Stack Attached to

Stack Height

Air pollution Control System

Parameters

1. Sulphonator Vessels

15 m Two stage Alkali Scrubber

SO2 < 40 ppm

2. Nitration Vessels



ANNEXURE –G

DETAILS OF HAZARDOUS WASTE GENERATION AND ITS DISPOSAL

Sr. No.

Name of Hazardous Waste

Category Quantity / year Mode of Disposal

1. Discarded containers / barrels / liners

33.1 1.5 MT Collection, Storage, transportation and sold out to Registered Recyclers or sent back to suppliers.

2. Used Oil 5.1 0.02 KL Collection, Storage, transportation and sold out to Registered Recyclers or sent back to suppliers.

3. Chemical sludge from waste water treatment facility including Gypsum Sludge

35.3 300 MT Collection, Storage, transportation and sent to TSDF / cement plant for co-processing.

4. Process Sludge – Iron Sludge

26.1 Max. 1350 MT Collection, Storage, transportation and sent to cement plant for co-processing.

5. Spent Sulphuric Acid [ 25 – 30 % ]

26.3 Max. 4200 MT Collection, Storage, transportation and sent to Novel Acid Management.



ANNEXURE – H PROPOSED TERMS OF REFERENCE

The generic structure of Environment Impact Assessment Study Report will be as

under:

1. Introduction This will cover the location and justification of the proposed project and scoping

and methodology for the EIA study.

2. Project Description

It will include the below mention details.

• Location of the project

• Product profile

• Resources requirement

• Manufacturing process and raw material requirement

• Material handling and storage

• Details on proposed Environmental Management System and

Monitoring.

• Storage and handling of hazardous chemicals

3. Baseline Environmental Description

The data regarding baseline environmental conditions will be collected

/generated as per the guidelines of MoEF. The methodology for collection of

baseline data for each of the component/environmental attribute is as follows: 1. Air

a. The study area will be of 5 Km radius considering the project site as center

and study period will be of one season except monsoon.

b. For estimation of back ground concentration of PM10, PM2.5, Oxides of

Nitrogen (NOx), Sulphur Dioxide (SO2), within study area, and 6 monitoring stations will be established as per the guidelines of CPCB and Ministry of Environment & Forest, Government of India. At each station monitoring will be

carried out on 24 hourly bases twice in a week for entire study period except

monsoon.



2. Meteorology

Meteorological data like wind speed, wind direction, humidity, temperature,

will be collected at the location under consideration / from authorized agency, so

as to prepare wind-rose diagram and to predict the concentration of pollutants

using dispersion models. These data will be collected for a period of 12 weeks.

3. Water

Water samples will be collected and analyzed of raw water supply of the Local

authority supply.

4. Noise

The noise level will be measured once in a study period in Leq. at least at 6

different location within study area using an integrated sound level meter.

5. Land use pattern

The details of Land use pattern will be obtained from Satellite imagery.

6. Identification and Assessment of the Impacts

The activities having the potential to cause environmental impact will be

identified and the degree of impact will be assessed using standard matrix

methods. The following environmental attributes will be considered to establish

the cause-effect relationship with the various activities of the proposed project.

5. Environmental Management and Monitoring Plan

Environmental Management and Monitoring Plan will be prepared based on

the anticipated environmental impact. It will also cover details on Occupational

Health programs and as well as for corporate social responsibilities.

6. Risk Assessment : The study will include risk assessment for storage, handling, transportation

etc. for the raw material(s) and products to be used in the plant. Occupational risk

involved during operational phase of the plant will be assessed and necessary

safety and protective measures will be recommended.

Scanned by CamScanner


M/s Jay Dyechem, Narol-Vatva Road,Ta : City, District : Ahmedabad, Gujarat

ANNEXURE – J

PLANT LAY OUT

Proposed plant Area

Proposed Storage

area

Haz waste

storage area

Office

Security

Green

space

Proposed Utility area

Parking

Proposed Green Area

Proposed Green Area

ROAD

ROAD

Periphery green belt

Proposed ETP area

Documents

ANNEXURE –A DETAILS OF PRODUCTS Sr. no. [ MT/month ] · 2017. 9. 12. · Sr. no. Name of Product Quantity [ MT/month ] 1 ... 12 Sulphuric acid [98%] 3.86 13 Sodium Per Sulphate