ANNUAL REPORT OF ENVIRONMENTAL MONITORING STICKNEY … · Subject: Annual Report of Environmental Monitoring for the Stickney Avenue and Tyler Street Landfills CEC Project 130-998

us EPA RECORDS CENTER REGION 5

479000

ANNUAL REPORT OF ENVIRONMENTAL MONITORING

STICKNEY AVENUE AND TYLER STREET LANDFILLS LUCAS COUNTY, OHIO

Prepared For: CITY OF TOLEDO

DIVISION OF SOLID WASTE 3962 HOFFMAN ROAD

TOLEDO, OHIO

Prepared By: CIVIL & ENVIRONMENTAL CONSULTANTS, INC.

TOLEDO, OHIO

CEC Project 130-998

December 2013

Civil & Environmental Consultants, Inc.

3232 Executive Parkway, Suite 105 | Toledo, OH 43606 | p: 419-724-5281 f: 41 9-724-5286 | www.cecinc.coin

TABLE OF CONTENTS

1.0 STICKNEY AVENUE LANDFILL 1 1.1 Annual Leachate Monitoring 1 1.2 Annual Explosive Gas Monitoring 2 1.3 Annual Inspection and Maintenance 3

2.0 TYLER STREET LANDFILL 2.1 Aimual Leachate Monitoring 4 2.2 Annual Explosive Gas Monitoring 5 2.3 Annual Inspection and Maintenance 5

3.0 2014 REPORTING PERIOD FOR THE STICKNEY & TYLER LANDFILLS 6

APPENDICES

Appendix A - Leachate Monitoring Well Field Data Sheets Appendix B - Leachate Monitoring Well Analytical Reports Appendix C - Explosive Gas Monitoring Field Data Sheets Appendix D - Leachate Monitoring Well, Explosive Gas Probe and Landfill Inspection Forms


Civil & Enyironmental Consultants, Inc.

December 30, 2013

Mr. Michael A. Gifford (SB-7J) U.S. EPA, Region 5 77 West Jackson Boulevard Chicago, Illinois 60604

Dear Mr. Gifford;

Subject: Annual Report of Environmental Monitoring for the Stickney Avenue and Tyler Street Landfills CEC Project 130-998

This report was developed by Civil & Environmental Consultants, Inc. (CEC) on behalf of the City of Toledo (City) to document the results of 2013 annual environmental performance monitoring activities for tJie Stickney Avenue and Tyler Street Landfills in accordance with the Administrative Order on Consent, Docket No. V-W-97-C-433. The activities associated with the 2013 aimual environmental performance monitoring event documented within this report include the aimual explosive gas and leachate monitoring results and facility inspections for both landfills, consistent with the procedures established in the Operation and Maintenance (O&M) Plan.

1.0 STICKNEY AVENUE LANDFILL

1.1 Annual Leachate Monitoring

Leachate sampling was completed at the Stickney Avenue Landfill (Stickney) on September 25-26, 2013. Leachate samples were collected fi-om the six leachate monitoring wells (S-MW-21LP, S-MW-24LP, S-MW-27LP, SMW-30LP, S-MW-33LP, and S-MW-35LP), as well as from the two leachate sentinel monitoring wells (S-MW-36LP and S-MW-37LP) by representatives of CEC. Field datai sheets for each leachate monitoring well at Stickney are included in Appendix A. Also included in Appendix A is a copy of the water quality meter calibration record.

The annual leachate samples were sent to Belmont Laboratories (Belmont) in Englewood, Ohio for analysis of the annual target compound list provided in the O&M Plan. Additionally, and for quality control/assurance purposes, a duplicate, a matrix spike, a matrix spike duplicate, and one field blank were collected and analyzed for the annual parameter list. A trip blank, for VOCs only, was also included with the samples collected firom the leachate sentinel wells. Laboratory

3232 Executive Parkway. Suite 105 | Toledo. OH 43606 | p; 419-724-528! f: 419-724-5286 | www.cecinc.com

Mr. Gifford - U.S. EPA CEC Project 130-998 December 30, 2013 Page 2

analytical reports for the leachate sampling activities completed during the September 2013 sampling event are included in Appendix B.

Tables 1-8, included in Appendix C, summarize the laboratory analytical data reported for the current and past sampling activities completed for the Stickney leachate monitoring wells and sentinel wells. Values footnoted with a "J" on the data summary tables represent estimated values that were reported between the method detection limit (MDL) and the laboratory practical quantitation limit (PQL).

Consistent with the O&M Plan, monitoring wells S-MW-21LP, S-MW-24LP, S-MW-27LP, S-MW-30LP, S-MW-33LP, and S-MW-35LP were analyzed for the target compotmd list consisting of PCBs, heptachlor, aldrin, DDT, mercury, and polyaromatic hydrocarbons (PAHs). A review of the 2013 leachate results for Stickney indicates that the data are similar to previous aimual sampling events. Each of the analyzed parameters were reported below the laboratory practical quantitation limits (PQLs) in these monitoring wells; however, three isolated parameters were reported between the MDL and PQL; mercury in S-MW-24LP and S-MW-33LP, acenapthene in S-MW-30LP, and naphthalene in S-MW-21LP.

As required in the consent order, the two sentinel wells (S-MW-36LP and S-MW-37LP) are monitored for a slightly different parameter list to evaluate possible contaminant migration from the adjacent XXKem property. These wells are analyzed for PCBs, dimethylaniline and volatile organic compounds (VOCs). PCBs were reported below the PQL with the exception of Aroclor 1260 in sentinel well S-MW-37LP. Dimethylaniline was not detected in either sentinel well. Benzene, chlorobenzene, chloroethane, ethylbenzene, and m,p-xylene were reported at or above the PQL in sentinel well S-MW-36LP, while 1,1-dichloroethane, 2-butanone, 4-methyl-2-pentanone, acetone, benzene, chlorobenzene, ethylbenzene, m,p-xylene, o-xylene, toluene and vinyl chloride were reported at or above the PQL in sentinel well S-MW-37LP.

1.2 Annual Explosive Gas Monitoring

CEC personnel monitored 15 methane gas probes or punch bar locations on September 27, 2013. A Methane Monitoring Field Data Sheet (MMFDS) for these monitoring activities is included in Appendix D. The O&M Plan states that explosive gas monitoring is required to be completed quarterly for the first two years following implementation of the O&M Plan, semiaimually for the following three years, and annually thereafter. Annual explosive gas monitoring was completed for the September 2013 event (i.e., seventh year of explosive gas monitoring) and will continue to be completed on an annual basis.


Mr.Gifford-U.S.EPA CEC Project 130-998 December 30, 2013 Page 3

The MMFDS documents the gas pressure, percent methane, percent Lower Explosive Limit (LEL), percent oxygen, percent carbon dioxide and depth to water in each of the gas probes or pimch bar locations. Also documented on the MMFDS are the weather-related monitoring parameters including ambient barometric pressure, ambient air temperature, relative humidity, and observed weather conditions.

As mentioned in previous reports, gas probes SP-GP-1 IS, 1 ID, 12, 14, and 15 were unable to be located or have been covered by soil; therefore, prmch bar sampling was completed in the vicinity of the unlocated probes. However, diuing the September 2013 gas monitoring event, S-GP-12 was located and measured while the other probes remain unlocated. The results of the gas probe sampling indicate that no landfill gas was reported at any of the Stickney gas probes diuing the September 2013 monitoring event, with exception of gas probes S-GP-IOS, S-GP-IOD, and S-GP-12; therefore pimch bar sampling was also conducted in the vicinity of these probes. Punch bar sampling was also completed in the general vicinity of the unlocated probes as well as S-GP-2D, which was unable to be measured because water was observed in the instrument tubing. No explosive gas was reported at any of the punch bar locations during the September 2013 monitoring event.

1.3 Annual Inspection and Maintenance

Inspection field forms for the annual inspection activities completed for the Stickney Landfill, the leachate monitoring well system, and the explosive gas monitoring system on September 25 and 27, 2013 are included in Appendix E. The Stickney Landfill generally appears to be in good condition; however, there are a few minor areas that could require future attention. The removal of overgrown vegetation would be beneficial along the north and south fence lines, as well as portions of the east fence line around the fire station and north of the fire station. Additionally, removal of vegetation would also be beneficial at the edge of the asphalt parking lot along the rock berm, as well as on the unpaved areas of the landfill to the north and south of the parking lot. Three small washout areas were observed along the top of the slope of the riverbank just below the berm. A small circular depression (about 6-8 feet in diameter and about 3-4 feet in depth) was observed approximately 150 feet south of S-MW-21LP. A shallow depression was also observed in the asphalt (approximately 50 feet by 25 feet and 1-2 feet in depth) just north of S-MW-37LP. Appropriate actions will be taken in 2014 by the City to address the noted maintenance activities.


Mr. Gifford - U.S. EPA CEC Project 130-998 December 30,2013 Page 4

2.0 TYLER STREET LANDFILL

2.1 Annual Leachate Monitoring

Leachate sampling activities were completed at the Tyler Street Landfill (Tyler) on September 26-27, 2013. Leachate samples were collected from eight of the nine leachate monitoring wells (T-MW-19LP, T-MW-21LP, T-MW-23LP, T-MW-25LP, T-MW-27LP, T-MW-29LP, T-MW-31LP, T-MW-33LP) by representatives of CEC. Similar to previous events, a leachate sample was not collected from leachate monitoring well T-MW-35LP because it was dry during the 2013 sampling event. Field data sheets for leachate monitoring wells at Tyler are included in Appendix A.

The annual leachate samples were sent to Belmont for analysis of the annual target compound list provided in the O&M Plan. Additionally, and for quality control/assurance purposes, a duplicate, a matrix spike, a matrix spike duplicate, one field blank, and one trip blank were collected and analyzed for the annual parameter list. Laboratory analytical reports for the leachate sampling activities completed during the September 2013 sampling event are included in Appendk B.

Tables 9-17, included in Appendix C, summarize the laboratory analytical data for current and past sampling activities for the Tyler leachate monitoring wells. Values footnoted with a "J" on the data summary tables represent estimated values that were reported between the MDL and the PQL. All data for the field blank were reported below their respective PQLs. Note that m+p xylene was reported at an estimated concentration in the trip blank.

Consistent with the 0«&M Plan, monitoring wells T-MW-19LP, T-MW-21LP, T-MW-23LP, T-MW-25LP, T-MW-27LP, T-MW-29LP, T-MW-31LP, and T-MW-33LP were analyzed for the target compound list consisting of PCBs, heptachlor, aldrin, DDT, mercury, and PAHs. A review of the 2013 leachate results for Tyler indicates that the data are similar to previous annual sampling events. The analyzed parameters were reported below the laboratory PQLs in these monitoring wells, except for naphthalene in leachate monitoring wells T-MW-19LP and T-MW-29LP, which was detected above the PQL. Additionally, two isolated parameters were reported between the MDL and PQL, including mercury in T-MW-19LP and T-MW-29LP and acenapthene in T-MW-23LP, T-MW-25LP, and T-MW-27LP.

Civil & Environmental Consultants. Inc.

Mr.Gififord-U.S.EPA CEC Project 130-998 December 30, 2013 Page 5

2.2 Annual Explosive Gas Monitoring

CEC personnel monitored 16 methane gas probes or pimch bar locations and four gas blower locations on September 27^ 2013. The O&M Plan states that explosive gas monitoring is required to be completed quarterly for the first two years following implementation of the O&M Plan, semi-annually for the following three years, and annually thereafter. Annual explosive gas monitoring completed for 2013 was the seventh year of explosive gas monitoring. Explosive gas monitoring will continue to be completed on an annual basis.

The MMFDS for the September 2013 annual monitoring activities is included in Appendix D. The MMFDS documents the gas pressure, percent methane, percent LEL, percent oxygen, percent carbon dioxide, and depth to water in each of the gas probes, punch bar locations, and gas blower locations. Also dociunented on the MMFDS are the weather-related monitoring parameters, including ambient barometric pressme, ambient air temperature, relative hiunidity, and observed weather conditions.

The results of the gas probe sampling indicate that landfill gas was reported at T-GP-IOS and T-GP-IOD during the September 2013 monitoring event at Tyler. Note that there are no occupied structures in the vicinity of these probes and results of the punch bar sampling during this event indicate that no gas was reported at this location; as such, it poses no threat to human health. Explosive gas was reported in four blower system monitoring locations during the September 2013 event, including the horizontal well, pre-system, between the two tanks, and post-system. The blower system was not operating at the time of the September 2013 event. As mentioned in previous reports, gas probes T-GP-07S, 07D, 1 IS, 1 ID, 12S, 12D, and 15 could not be located or are covered by soil; therefore, punch bar sampling was conducted in the general vicinity of these locations at the Tyler landfill. No explosive gas was reported at any of the pimch bar locations.

2.3 Annual Inspection and Maintenance

Inspection field forms for the aimual inspection activities completed for the Tyler Landfill, the leachate monitoring well system, and the explosive gas monitoring system on September 26 and 27, 2013 are included in Appendix E. The Tyler Landfill appears to be in good condition; however, as documented on the inspection forms, excessive vegetation was noted along the perimeter fencing, landfill cap, the rock let downs and the riprap surface along the Ottawa River, as well as along the perimeter access road. Some signage along the Ottawa River is obstructed by vegetation or is damaged/missing. The flush mounts of GP-IOS and GP-IOD were raised above ground level. Appropriate actions will be taken in 2014 by the City to address the noted maintenance activities.


Mr. Gifford-U.S.EPA CEC Project 130-998 December 30, 2013 Page 6

3.0 2014 REPORTING PERIOD FOR THE STICKNEY & TYLER LANDFILLS

In accordance with the O&M Plan, during the 2014 reporting period for the Stickney and Tyler facilities, the aimual leachate sampling, explosive gas monitoring, and inspections are scheduled to be completed in September; the annual report is scheduled to be completed in December, and maintenance will be completed as needed.

Should you have any questions or conunents regarding the environmental monitoring programs, please contact the undersigned at your convenience.

Sincerely,

CIVIL & ENVIRONMENTAL CONSULTANTS, INC.

Jicholas A. Bohlana / Tnomas R. Covrett, (SPG Project Manager Project Principal

Enclosures:

ct: Tim Christman, Ohio EPA-CDO (w/Appendices) Paul Jayko, Ohio EPA-NWDO (w/Appendices) Dan Pittman, City of Toledo-Division of Solid Waste (w/Appendices) Archie Lunsey, Ohio EPA-NWDO (Letter) Edward Moore, Director, City of Toledo-Department of Public Service (Letter)


APPENDIXA

LEACHATE MONITORING WELL FIELD DATA SHEETS

Civil & Environmental Consultants. Inc.

APPENDIX A-1: STICKNEY AVENUE LANDFILL


Calibration Record

site:

Inetruments: pH/CondA"emp Meter: Explosive eas Meter

1 2 3 Dale:

Time:

pH4:

pH7:

pH 10:

Cond. 1413:

pH Slope:

Cond. Slope:

CH4 2.5 %:

LEL 50%:

06.P

t)0

• • ^ /i^:/n q/JV'-3

<^12 .

H.fOl ^..01

i.dD : 7.00 l.os

C{. q ̂

iHlS. /cJ 1 \

.

• — •

?HO.I ^HO'I

IO0.\% 100.07. lOOÎJ

HULL aASSOCIATCS. INC. TOLEDO. OHIO F:\DOC_WORKVCALIBRATIONRECORD.XLS

GROUNDWATER MONITORING WELL FIELD DATA SHEET

MONITORING POINTr^rtiJ "Z/LP

DETECTION;

ASSESSMENT:

NAME: ADDRESS: CONTACT:

FACILITY INFORMATION PROJECT NUMBER:

TELEPHONE:

WH-

COORDINATES: N

E

MONITORING WELL DATA CONDITION OF WELL: r

GROUND SURFACE ELEVATION:

TOTAL DEPTH (FROM GROUND SURFACE):

SCREENED INTERVAL (INCLUDING SAND PACK):

SCREENED FORMATION:

CASING MATERIAL/DIAMETER:

TOP OF CASING ELEVATION:

TOTAL DEPTH (FROM TOP OF CASING);

SCREENED DEPTH (SCREEN ONLY):

WEATHER:

BAROMETRIC PRESSU JRE:

WEATHER CONDITIONS WIND DIRECTION;

TEMPERATURE (®F): 70*

PERSONNEL PRESENT:

MEASURED TOTAL DEPTH (FROM TOO:

VOLUME OF STATIC WATER:

FIELD MEASURED PATAMETERS

STATIC WATER LEVEL (FROM TOO:

GROUNDWATER ELEVATION:

DATE OF PURGING:

PURGING METHOD: Jd(

PURGING DATA

lA

PURGING RATE:

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Initital 1 2 3 4 '5 6/Finai

Time /Q>OI lu/yf lioOl PH (o.^l (fi.lb LÔ (p.^ro Temp. n.xt, a,?</ Spec. Cond. Z.'glO l.'&IO Corr. Cond.

Redox Pot. -7V.A -S7..9 •st'S D.O. /.I,? 1 1, ol hO% Turbidity la.Q 7 itz

Water Level* iO-Oj |0«OM iti.Olf /0..0V

VOLUME TO PURGE CALCULATION TABLE

Weil casing Galions Per Fool Feet of Standing swell Total Volume to

Diameter (in.) of Depth Water Volumes Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

• measurement from top of casing

DATE/TIME OF SAMPLING:

SAMPLING METHOD:

ih HPIO SAMPLING DATA

SAMPLING RATE (IF USING DEDICATED PUMP):

STATIC WATER LEVEL (AFTER SAMPLING): JH

NOTES

A^lr IrvjL fjntA'cd-\v)A. (>vi \fiuli £M^ torrorfWyA .K Irv tait (OK) £0P / tA,«»ui^ fi.jfp'kc +0 EXPLOSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %IL: 0


MONITORING POINT

DETECTION;

ASSESSMENT:

1

AME:

3DRESS:

ONTACT:

S4'.ck_^ (\y/t . t ' FACILITY INFORMATION

PROJECT NUMBER:

TELEPHONE:

UckL^rj-

170

3RDINATES: N

E

MONITORING WELL DATA

CONDITION OF WELL: *>^-1 • s. Ac VcJ ry

r W -Cls-iU

ROUND SURFACE ELEVATION:

TAL DEPTH (FROM GROUND SURFACE):

REENED INTERVAL (INCLUDING SAND PACK):

REENED FORMATION;



TOTAL DEPTH (FROM TOP OF CASING):


EATHER: O-ROMETRIC PRESSURE:

WEATHER CONDITIONS WIND DIRECTION:

TEMPERATURE ("F):


RSONNEL PRESENT:

INSURED TOTAL DEPTH (FROM TOO:

LUME OF STATIC WATER:

TE OF PURGING:

RGINGMETHOD: tâ(|

RGING RATE: tit

isurement from top of casing

EmME OF SAMPLING:

PLING METHOD:

'\\ziVb m;L L\j ^ H lO»

STATIC WATER LEVEL (FROM TOO: GROUNDWATER ELEVATION:

PURGING DATA

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Initital 1 Y^fp 4 5 SFInal

/^cr20 1X7 1\0 7-03 7-^3 7.na

5 nxi Cond. ^.1(77 XPHin |2r)i| 1-97^ 1711 /.97/

Cond.

x Pot. -\xfl -Mlrrr (rr

1 %1 I.Ofll l>0!? 1 rti 7S9i r Lever 77^ 8 ."is


Well casing

Diameter (In.)

Gallons Per Fool

of Depth

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

SAMPLING DATA SAMPLING RATE (IF USING DEDICATED PUMP):

STATIC WATER LEVEL (AFTER SAMPLING):

z. I oOi^l J7\

NOTES

;SIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL: o


MONITORING P0INT:S"NJ_£^

DETECTION:

ASSESSMENT:

NAME: ADDRESS: CONTACT: ( 4. ft-M- UckU-xrf-


TELEPHONE:

COORDINATES: N

E




SCREENED FORMATION:

MONITORING WELL DATA CONDITION OF WELL:

CASING MATERIALJDIAMETER;




WEATHER:

BAROMETRIC PRESSURE:

WEATHER CONDITIONS WIND DIRECTION: TEMPERATURE (°F):

U w-7

PERSONNEL PRESENT:





GROfeiNDWATER ELEVATION:

DATE OF PURGING:

UîcU u3^^rOL.AT^

PURGING DATA

PURGING METHOD:

PURGING RATE:

TIME OF PURGING:

VOLUME PURGED: l£OH

/tlsod

WELL VOLUMES PURGED

Initital 1 2 3 4 5 6/Final

Time /s-09 ISlff KI<T /S-(.C PH

Temp, prt.f)'/ /fo-5?y 1 c>« /fa7.5 Spec. Cond. S.r/Art \JiOL, lA-itj Con. Cond.

Redox Pol. -'iI.L -5^7 -OoM D.O. I.S-7 l.2u Turbidity is ,Y- lO.S. (?-9 Water Level* /(?. fr) /ros //-d9 /rr;9


Well casing

Diameter (in.)

Gallons Per Foot

of Deptti

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0:041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

* measurement from top of casing

SAMPLING DATA

DATEmME OF SAMPLING: ('^ SAMPLING RATE (IF USING DEDICATED PUMP):

U)iZ^r<Jl STATIC WATER LEVEL (AFTER SAMPLING):

f (^ (\ /. /!<> SAMPLING METHOD:

NOTES

j^!r cpxTtttilugP^ gtW i itr

sfL.nck |>u^. EXPLOSIVE GAS READING PRIOR TO 2 f TO STATIC WATER LEVEL: %CH4: 21 %LEL: cJ


tk/IONITORING POINT:y-MU/^t^P

DETECTION:

ASSESSMENT:

FACILITY INFORMATION

AME:

DDRESS:

ONTACT:

<A^cJCtJL PROJECT NUMBER:

TELEPHONE:

OORDINATES: _N

'E



3TAL DEPTH (FROM GROUND SURFACE):

GREENED INTERVAL (INCLUDING SAND PACK):

:REENED FORMATION:





if" p\rr.

cATHER:

ROMETRIC RIC PRESSURE: T

WEATHER CONDITIONS

WIND DIRECTION:

TEMPERATURE {°F):

=1 1 d

FIELD MEASURED PATAMETERS RSONNEL PRESENT:

ASURED TOTAL DEPTH (FROM TOO:

-UME OF STATIC WATER:



TE OF PURGING:

RGING METHOD:

RGING

PURGING DATA

l ui) ̂ urtJ RATE:

TIME OF PURGING:

VOLUME PURGED: I9Z7

WELL VOLUMES PURGED


mi i9sS Ml (a(nH <>"7^ (j>X^

p. rr.ftP 17, 17'10 7'if) Cond. iQUif

Cond. — xPot. -lis -VH 'lli> -73.7 -73.7

?„1H Lll |v?>l i,ai dity %.l 31 1 t%s (^.IS 7.7>S r Level* ^0\ ?rcî T-OI


Well casing

Diameter (in.)

Gallons Per Fool

of Depth

Feet of Standing

Water

3 Well

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

jsurement from top of casing

EH'IME OF SAMPLING:

PLING METHOD:



NOTES

SIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4; %LEL: -A




MONITORING POINT

DETECTION:

ASSESSMENT:

PROJECT NUMBER:

TELEPHONE:

COORDINATES: _N

E

MONITORING WELL DATA CONDITION OF WELL: -f^c^cKy



SCREENED INTERVAL (iNCLUotNG SAND PACK):

SCREENED FORMATION:

CASING MATERIAUDIAMETER:




WEATHER:



. TEMPERATURE (®F):

FIELD MEASURED PATAMETERS PERSONNEL PRESENT:




GROVNDWATER ELEVATION:

DATE OF PURGING:

PURGING METHOD:

PURGING RATE:

PURGING DATA

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Initital 1 2 3 4 5 6/Flnal

Time V5Z2* ni'f i-StSr PH U.T'i (F.7^ L.TS" Temp. J Zi.7«' ti.flfO Xtc76

Spec. Cond. H.'iK r.otp? CoiT, Cond,

Redox Pot. -to."] -11#."Z^ -H'} D.O. d-^ 0*1 > 6ry6 Turbldltv Hl'l/ n (5-.! Water Level* It-*? It.'i'i' WAi


Well casing

Diameter (In.)

Gallons Per Foot

of Depth

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

' measurement from top of casing

DATE^-IME OF SAMPLING:

SAMPLING METHOD:

. SAMPLING DATA SAMPLING RATE (IF USING DEDICATED PUMP):

yJcU tjl STATIC WATER LEVEL (AFTERSAMPLING):

tJb •Vw\p>V>* . ^

rxM.JrIftA

NOTES hvu_ tO<L5 Cor^bJltJ, A-r fTK< uCV t^lrvJ iJCll iStJ

EXPLOSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL:

aJy^r4rihy


MONITORING POINT

DETECTION: '

ASSESSMENT:

Ê: DDRESS: 3NTACT:

DORDINATES:

FACILITY INFORMATION UflL [»- ' PROJECT NUMBER:

*7V.'tX*ty Av-Ci TELEPHONE:

N

E

^tOUND SURFACE ELEVATION:

OTAL DEPTH (FROM GROUND SURFACE):

CREENED INTERVAL (iNCLUDtNG SAND PACK):

CREENED FORMATION:

cATHER: o4- Cltîy

MONITORING WELL DATA CONDITION OF WELL: prtvArvC^

â<JovJ lutll t<Y 4t> e^trtelpj

• ^ CASING MATERIAUDIAMETER: Z"

— TOP OF CASING ELEVATION: '—-


SCREENED DEPTH (SCREEN ONLY): ~

IVROMETRIC PRESSURE:

ERSONNEL PRESENT:

"VS >.60 f>v

WEATHER CONDITIONS • WIND DIRECTION:

• TEMPERATURE (°F):

M E. ^

EASURED TOTAL DEPTH (FROM TOO:

3LUME OF STATIC WATER:

FIELD MEASURED PATAMETERS , 9ê<Jg.



PURGING DATA TEOF PURGING:

RGING METHOD: M'

RGING RATE: 3^0 PJ /f?/^ ^pli •

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Initital 1 2 3 A 5 6/FinaI

irtm. /cW? fOS2 ('.tH (nillf (o % ?

n n.o>7 /1. * n.Sf: : Cond. c.oiti S.d££

Cond. — w Pnt -rik.o

n A "l.T^ 1.79 l.^rh I .r^Cp riif c.on .T . IFT tr Level* aojtL 30.1A 2.0 J? ?fn7^


Well casing

Diameter (in.)

Gallons Per Foot

of Depth

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3


TEaiME OF SAMPLING:

PLING METHOD: I/JCH


STATIC WATER LEVEL (AFTER SAMPLING): 1L

NOTES

DSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: £> %LEL:


MONITORING POINTrS^Vj^^P

DETECTION:

ASSESSMENT:

NMVIE:

ADDRESS:

CONTACT:


<^•1-: Not. ̂ PROJECT NUMBER:

TELEPHONE:

1^0'tfr v/H

COORDINATES: N

E

MONITORING WELL DATA CONDITION OF WELL: OK




SCREENED FORMATION:





~H^JUC7

WEATHER: -y



• TEMPERATURE ("F):

ME

FIELD MEASURED PATAMETERS PERSONNEL PRESENT:



J- U<rj f-STATIC WATER LEVEL (FROM TOO:


DATE OF PURGING:

PURGING METHOD:

PURGING RATE:

PURGING DATA

AtOAi/ j TIME OF PURGING:

VOLUME PURGED:

0?S3

WELL VOLUMES PURGED


Time lOOi looi im PH u 7o U-j r>i7 um Temp. )5MH M.Ty K. 10 Spec. Cond. zm Corr. Cond.

Redox Pot. -m D.O. /.LO [SS-Turbidity

Water Level* /()tC33 - ' —

lHi2.

VOLUME TO PURGE CALCULATION TABLE Well casing Gailons Per Foot Feet of Standing 3Weli Total Volume to

Diameter (in.) of Deptti Water Volumes Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3


DATEH'IME OF SAMPLING: °ti ? lOc)

SAMPLING METHOD: 1 SAMPLING DATA


STATIC WATER LEVEL (AFTER SAMPLING): <100.

^\>d% LiPtVPL ^ ^-e-'freie Sc/flT

NOTES



MONITORING POINT:^'/^ T7tP

DETECTION:

ASSESSMENT:

MAE-.

ODRESS:

ONTACT:

. FACILITY INFORMATION A/<. PROJECT NUMBER:

TELEPHONE: _m±22S-

OORDINATES:

MONITORING WELL DATA N CONDITION OF WELL:

E • A 4 ROUND SURFACE ELEVATION:



REENED FORMATION:





Pu'C

EATHER:

ROMETRIC PRESSURE:


TEMPERATURE ("F):

FIELD MEASURED PATAMETERS RSONNEL PRESENT:

ASURED TOTAL DEPTH (FROMTOC):


STATIC WATER LEVEL (FROMTOO: Hli.lz'HyC'


TE OF PURGING:

PURGING DATA

RGING METHOD: U^tll TIME OF PURGING:

RGING RATE: VOLUME PURGED: 2

WELL VOLUMES PURGED

Inititat 1 2 3 4 5 6/Flnal

(91 2. (nri^

n

Cond. -f iny-i ion Cond.

rPot. 7 s'^ 7M lS,i^ 1.90 L% I.7.?

dity 1% LAVAI* M.t3 JIM9 I I //1/1



Well casing

Diameter (in.)

Gailons Per Foot

of Deptti

Feet of Standing

Water

3 Weil

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

EH-IME OF SAMPLING;

PLING METHOD:

SAMPLING DATA 1^)0- SAMPLING RATE (IF USING DEDICATED PUMP):

fA. / / IA) (-r V STATIC WATER LEVEL (AFTSFI SAMPLING):

NOTES 'I'JJJML

5IVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL: o

APPENDIX A-2: TYLER STREET LANDFILL



MONITORING h/'/9L?

DETECTION: '

ASSESSMENT: —

AME:

ODRESS:

DNTACT:

_l^frrr IY f clfV

n ^


TELEPHONE:

OORDINATES: tOA JJA

N

E



3TAL DEPTH (FROM GROUND SURFACE):

CREENED INTERVAL (INCLUDING SAND PACK):

CREENED FORMATION:

_£JA.

(\ji

JLU-





AJA

EATHER: cat r

^ROMETRIC PRESSURE: 20.


TEMPERATURE ("F): /F ,

OL

RSONNEL PRESENT:

EASURED TOTAL DEPTH (FROMTOC):



C- H oy STATIC WATER LEVEL (FROMTOC):


TE OF PURGING:

RGING METHOD: n P W v

IRGING RATE: t^00y.^L J ^

PURGING DATA

TIME OF PURGING:

VOLUME PURGED: ii9ddf^

WELL VOLUMES PURGED

Initltal 1 2 3 4 5 6/Final

A use l2o 1 '(2^7 /Jlrt-7 iÔl ~7.Sfe l-HT 7.WC. lAt

IP- lb.77 iH.17 IH-FV H 93 c. Cond. S-. -^7 2 WF *. Cond.

ox Pot. -1.7 -/!. ( -/.S" -1.5 I.SD h?7

dily ,^7 it Level* Ho 3 H.ii (7.i;


vyell casing

Diameter (in.)

Gallons Per Fool

of Depth

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

iasurement from top of casing

TE/TIME OF SAMPLING:

MPLING METHOD;

SAMPLING DATA //-^7 SAMPLING RATE (IF USING DEDICATED PUMP):

J STATIC WATER LEVEL (AFTER SAMPLING):

NOTES CAW pp W,r\tlv3 Wi»ll ir, i«ifi P" j

OSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL: M


MONITORING POINlry-HtjII

DETECTION: —

ASSESSMENT;



—I y (e f re I * OH

PROJECT NUMBER:

TELEPHONE:

COORDINATES:

-fciiL

_N

E





SCREENED FORMATION:

ISJ A

rvA





_AJA. jUd.

AJA

-&U-

WEATHER:

BAROMETRIC PRESSURE: Pi'

WEATHER CONDITIONS ^ WIND DIRECTION:

TEMPERATURE (°F):

PERSONNEL PRESENT:

MEASURED TOTAL DEPTH (FROMTOC):



SVRO t Mrtyt STATIC WATER LEVEL (FROM TOO:


DATE OF PURGING:

PURGING METHOD:

PURGING RATE:

PURGING DATA

MOO

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

InHltal 1 • 2 3 4 5 6/Final

Time Irll^ (lit U^l nî PH 7'Jl 1,^1 lAl T 31 Temp. n.iJl (t.u Spec. Cond. i.l2y 3.^0 Corr. Cond.

Redox Pol. 3.. 3s JL-') 3.9 D.O. 1>H7 ?l.63L 19 2.29 Turbidltv if.h Water Level' 1^2,^ SSl art


Well casing

Diameter (In.)

Gallons Per Foot

of Depth

Feet of Standing

Water

3 Well

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3



SAMPLING METHOD: 7//^.—M-

OTII


STATIC WATER LEVEL (AFTER SAMPLING): £2jja.

NOTES

rofirof)/rJ . k,t li^g f. OHILIS, ly LfUu) jy/'CtJ (r> Ln^-"',1^ fi " • -h ope.r-A.-k



MONITORING

DETECTION: —

ASSESSMENT: —

AME: DDRESS: ONTACT:


l^le-r

Sr«^nf f Lxtf kKg>rf / PrH-T.A^

PROJECT NUMBER:

TELEPHONE:

DORDINATES: _AZd_ _N

E

MONITORING WELL DATA CONDITION OF WELL: OnNC(




REENED FORMATION:

_A^

MiA. -AM-





fijA

tJA JJA. A/4

cATHER: r ROMETRIC PRESSURE:

WEATHER CONDITIONS • WIND DIRECTION: ^ ̂ i^Ph.

TEMPERATURE ("F): CifP*'

RSONNEL PRESENT:

ASURED TOTAL DEPTH (FROMTOC):

.UME OF STATIC WATER:




/^.V9

TE OF PURGING:

RGING METHOD:

RGING RATE:

PURGING DATA

U)rlf bJ^ratei

'-fon t-j TIME OF PURGING:

VOLUME PURGED: /0O9

'jHdOrriL

WELL VOLUMES PURGED


4 iMf /pi/<r ;A/? JdXI i.ii -7.VS 1.H7 I,H9 7rY<?

n 10. IS 31-72: airT/. Cond. *;.o(oO £'-23,1. fMi s.33^

Conri — wPol. 2'

hHl i.Hi irii H'i'S U'f »r LftvftI* /V,l$


Well casing

Diameter (in.)

Gallons Per Foot

of Depth

Feet of Standing

Water

3 Well

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

Tsurement from top of casing

TEmME OF SAMPLING:

PLING METHOD: J2 LA.

SAMPLING DATA ef-/ SAMPLING RATE (IF USING DEDICATED PUMP):


< \£>0

NOTES

llaf f I f hclcti/ —fg> <v,,y _L4L± t~»Jl A<l<iL^4>cr "fo g^trA-k- p DSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL:


MONITORING POINTrf-MtJ-

DETECTION:

ASSESSMENT:


FACILITY INFORMATION Tylcf

SVrrcH—ToH PROJECT NUMBER:

TELEPHONE:

Lock. ^

COORDINATES: fO A _N E

MONITORING WELL DATA CONDITION OF WELL: 1




SCREENED FORMATION:

_£JA.

-fcJA.




SCREENED DEPTH (SCREENONLY):

JdA. _LLA. A/A

WEATHER: r lô^^ BAROMETRIC PRESSURE: .IMS-


TEMPERATURE (°F): 11

PERSONNEL PRESENT:




STATIC WATER LEVEL (FROMTOO:

GROUNDWATER ELEVATION: ^

DATE OF PURGING:

PURGING METHOD:

PURGING RATE:

PURGING DATA

<^ L y>ftn I >T

TIME OF PURGING:

VOLUME PURGED:

/9S0 IGfOOw^l

WELL VOLUMES PURGED

Initital 1 2 3 4 5 6/Flnal

Time \9'A?. ' i.'JV.S PH

—r—r

7.11 7-iif> Temp. f &.&«?• IS ,90 \S.17 rS,«/7 Spec. Cond. 7.0«S n.i7J 7.HP9 Corr. Cond. -• Redox Pot. 10. g il.d. D.O. ?-.di /.ts 1.9's Turbidity i(?tl 9.97 Water Level' ToP Top TOP TITP TPP


Well casing Gallons Per Foot Feet of Standing swell Total Volume to

Diameter (in.) of Depth Wafer Volumes Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3



SAMPLING METHOD:

l/xu/n ItHsr Ulrl.l



A;*- Iv'nf NOTES

{jJaeJ Ajla^\cr EXPLOSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: £= %LEL:


MONITORING

DETECTION:

ASSESSMENT:

FACILITY INFORMATION MHE:

ODRESS:

ONTACT:

Ijlf f [TtflyJo . Ot;

PROJECT NUMBER:

TELEPHONE:

yJc)-?97?

OORDINATES: _N

E

MONITORING WELL DATA CONDITION OF WELL: ^-JCX d.




GREENED FORMATION:

JJA. klA

UA -OA-





MA. JLLJL

£ATHER:__£J_£OLL

^ROMETRIC PRESSURE:

WEATHER CONDITIONS • WIND DIRECTION:

TEMPERATURE ("F):

ERSONNEL PRESENT:






TE OF PURGING;

ItGING METHOD:

RGING RATE:

idr II fJi T

PURGING DATA

±£. z Uni n

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Cond.

• rnnri

K Pnl

LAvet*

Initital

JLifi-

2^ tiOL 4JJ2. 'n.%7

mi iMk. am.

ILSL I .30

liM. CoAdC

LU.

m. IM.

ml

im (p(?C>t

ISA.

UA.

6/Final

iSSl

a.c?C.|

/.JlJ

2al


Well casing

Diameter (In.)

Gallons Per Foot

of Deptti

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3


TEmME OF SAMPLING:

MPLING METHOD: // 3

uJîi i.i:-ârcf



> iryj

NOTES rtVLû-sIf

ft

OSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL:


MONITORING POINTfFU^^Z^^

DETECTION:

ASSESSMENT:


s+. FACiUTY INFORMATION PROJECT NUMBER:

TELEPHONE:

COORDINATES: N

E

MONITORING WELL DATA CONDITION OF WELL: <^4k^-(^c'hry




SCREENED FORMATION:

CASING MATERIAL7DIAMETER:




WEATHER: BAROMETRIC PRESSURE: <0-7


TEMPERATURE f F): •7 " /T

n'4'» ''

PERSONNEL PRESENT:



o Ft


JLyi STATIC WATER LEVEL (FROM TOO:


/^•90

DATE OF PURGING:

PURGING METHOD:

PURGING RATE:

PURGING DATA

TIME OF PURGING:

VOLUME PURGED: IIHZ

WELL VOLUMES PURGED

Inltitai 1 2 3 4 5 6/Final

Time x:

nî I7^v [IRl 1-75-7 pH nr.î 1M<4 1.H.9 -7,5^3 Temp. t^.lb Spec. Cond. b>*irxf Corr. Cond. -

Redox Pot. -d.') ID.O.

Turbidity

Water Level' trfpr3l

VOLUME TO PURGE CALCULATION TABLE Well casing Gallons Per Foot Feet of Standing 3 Well Total Volume to

Diameter (in.) of Depth Water Volumes Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3



SAMPLING METHOD:


STATIC WATER LEVEL (AFTER SAMPLING): <W0 '^Ljf)io

NOTES iA'^r fTUt riO i/iAe^+'tir^ rj-vt uJell C&^ ̂ /TV

rE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: %LEL: EXPLOSIVE


MONITORING POINT:T:./s^f^.^ \lf

DETECTION:

ASSESSMENT:

AME:

ODRESS:

ONTACT:

leJL.


Vylof f Itiujft H

PROJECT NUMBER:

TELEPHONE;

OORDINATES: u&lA. N

E





GREENED FORMATION:

A)^

A/A




SCREENED DEPTH (SCREENONLY):

MA. JJA. hi A

EATHER: C(f£Xr

AROMETRIC PRESSURE:


TEMPERATURE (°F):

ERSONNEL PRESENT:

EASURED TOTAL DEPTH (FROM TOO:



Qo'ir STATIC WATER LEVEL (FROM TOO:


sy

PURGING DATA .TE OF PURGING:

IRGING METHOD:

IRGING RATE:

9 •/it/a Iti-tl LlJrarrj R-SO /M f*

TIME OF PURGING:

VOLUME PURGED: 1000^1

WELL VOLUMES PURGED


e lb(.0.[r) ">,3D T5^l 7,.20 7M(r 7. J/-

ip. is.oQ /.-S.rt,? 0. Cond. u.isr^ H.2HI w.aot. H-m •/.Jo?-. Cond.

w Pol. Pi W / !•%

liditv M ii.9 K5i? s;.(oe er Level* lto,£7 /t.Tg- /t.?? 1(0.12 /b.76


Well casing

Diameter (in.)

Gallons Per Foot

of Depth

Feel of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 X x3

^surement from top of casing

TEmME OF SAMPLING;

VIPLING METHOD: tA>pH u^.'Tfîrc(



r>-f/

NOTES Cryy>^^c4-^t^ j^cll g»-y> f cdr [iv/ jtcl fW

.OSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4: MA. %LEL:


MONITORING P0INT:THM'^ 'S?C P

DETECTION:

ASSESSMENT:


J{:U FACILITY INFORMATION

T->Ur St oH PROJECT NUMBER:

TELEPHONE: ^tq^qTL-^l.</l7

MONITORING WELL DATA COORDINATES:

±IA. N

E




SCREENED FORMATION:

MAMA MA MA

CONDITION OF WELL: - <^1\C.4-




SCREENED DEPTH (SCREEN ONLY): _AJ4_ tJA

WEATHER:


WEATHER CONDITIONS

WIND DIRECTION:

TEMPERATURE (°F): IMA

PERSONNEL PRESENT:

MEASURED TOTAL DEPTH (FROMTOC);


FIELD MEASURED PATAMETERS ()ao^

( STATir V STATIC WATER LEVEL (FROMTOC):


DATE OF PURGING:

PURGING METHOD: Ij L) i 7 Ac J

PURGING RATE:

PURGING DATA

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED

Inititai 1 2 3 4 5 6/Finai

Time 7 01

PH 1^.92 l,t2x -7.1^ 7. 1? Temp. aiaji Spec. Cond. 5-,(0.?^ 5.«W SSTfiT ^•7V fi.T^7 CXxT. Cond.

Redox Pot. Î7.f -/7Y D.O. 3.J«f •s.i«/ Turbidity /^.Jl nn n tWater Level* l%0^


Weil casing

Diameter (in.)

Gallons Per Foot

. of Depth

Feet of Standing

Water

swell

Volumes

Total Volume to

Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 X x3

6 1.469 x x3

' measurement from top of casing

DATEH'IME OF SAMPLING:

SAMPLING METHOD: lOcH irJ ttCi/cl

SAMPLING DATA



NOTES

READING PRIOR TO STATIC WATER LEVEL: %CH4: ^ %LEL: >

Q

EXPLOSIVE GAS READING PRIOR TO STATIC WATER LEVEL:


MONITORING POINT-Ff^j/'^S^F

DETECTION:

ASSESSMENT:

MME:

DDRESS:

ONTACT:

i >1


r-/)c^

PROJECT NUMBER:

TELEPHONE:

OORDINATES: N

E





GREENED FORMATION:





£ATHER: (A^

^ROMETRIC PRESSURE:


TEMPERATURE ("F):

IH (^t.^ ̂

FIELD MEASURED PATAMETERS K(r^'h RSONNEL PRESENT:


-UME OF STATIC WATER:



P.eUvi"ry<)fPA^

TE OF PURGING:

IRGING METHOD:

RGING RATE:

VOtll

PURGING DATA

TIME OF PURGING:

VOLUME PURGED:

WELL VOLUMES PURGED Initital 1 2 3 4 5 6/Final

e

p.

Cond.

Cond.

w Pot. y

idity y''

V Level?''^


Well casing Gallons Per Foot Feet of Standing swell Total Volume to

Diameter (In.) of Depth Water Volumes Purge (Gal.)

1 0.041 X x3

2 0.163 X x3

4 0.653 /

X x3

6 1.469 X x3


SAMPLING DATA TEH-IME OF SAMPLING: vct <70^*^ SAMPLING RATE (IF USING DEDICATED PUMP):

MPLING METHOD: STATIC WATER LEVEL (AFTER SAMPLING):

UJLH Of) StAwj) (f. ^1 1(1 tr^-^

NOTES

OSIVE GAS READING PRIOR TO STATIC WATER LEVEL: %CH4; %LEL:

APPENDIX B

LEACHATE MONITORING WELL ANALYTICAL REPORTS


APPENDIX B-1: STICKNEY AVENUE LANDFILL


Monday, October 28, 2013

Analytical Results

omnie'-irar^rwGe-Gc^^^

Nicholas Boland

Civil & Environmental Consultants, Inc. - Toledo 3232 Executive Parkway, Suite 105 Toledo, OH 43606

TEL: (419)724-5281

FAX -

RE: 130-998 Work Order: 1311442

Belmont Labs received 8 sample(s) on 9/27/2013 for the analyses presented in the following report.

Belmont Labs attests that all analytical methods were performed using acceptable methods, and that the QA/QC procedures stipulated in these methods were followed.

If you have any questions regarding the test results, please feel free to call me at (937) 832-8242.

Respectfully submitted.

TcX/vx^pr\

Taryn Mancine

Project Manager

Certifications: NEI-AP/NELAC-#04130

Ohio EPA Drinking water - #836

VAP-#CL0032

Ohio EPA Drinking water (Micro) - #872

25 Holiday Drive Englewood, Ohio 45322 1.937.832.8242 1.937.832.2868 Fax

Belmont Labs Date: 10/28/2013

CLIENT: Civil & Environmental Consultants, Inc. - Toledo Lab Order: 1311442 Project: 130-998

Work Order Sample Summary

**The results of analyses performed on the following samples submitted to Belmont Labs are found in this report.**

Field Sample ID Lab ID Matrix Method Reference Subcontract Lab

130-998;MW-35LP:Z092513 1311442-01 Leachate EPA 245.1

SW8081

SW 8082

SW 8270C


SW8081

SW8082

SW 8270C

30-998;MW-21LP + MS/MSD:Z09251 1311442-03 Leachate EPA 245.1

SW 8081

SW8082

SW 8270C

130-998:MW-24LP:Z092513 1311442-04 Leachate EPA 245.1

SW 8081

SW 8082

SW 8270C

130-998:Duplicate:Z092513 1311442-05 Leachate EPA 245.1

SW 8081

SW 8082

SW 8270C

130-998:FB-1:Z092513 1311442-06 Water EPA 245.1

SW 8081

SW 8082

SW 8270C


SW 8081

SW 8082

SW8270C

ImontLabS Date: 10/28/2013

ENT: Civil & Environmental Consultants, Inc. - Toledo Lab Order: 1311442 ]ect: 130-998


**The results of analyses performed on the following samples submitted to Beimont Labs are found in this report.**



SW 8081

SW 8082

SW8270C


CLIENT: Project:

Civil & Environmental Consultants, Inc. - Toledo 130-998

Lab Order: 1311442

Lab ID: Client Sample ID:

1311442-01 130-998:MW-35LP:Z092513

Collection Date: 9/25/2013 10:52:00AM Matrix: Leachate

Analysis Result MDL PQL Qual Units Dilution Batch Date Prepared Date Analyzed

HG EPA 245.1 Analyst: TL

Mercury BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 11:30:00AM 10/8/2013 9:00:00AM

PEST_8081 SW8081 Analyst: KSW

4,4-DDT BDL o:0217 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 5;44:00PM

Aldrin BDL 0.0168 0.0500 ug/L 1 1340^ 9/30/2013 9:04:00AM 10/2/2013 5:44:00PM

Heptachlor BDL 0.0181 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 5:44:00PM

Surrogate: Decachlorobiphenyl 83.0% 55-135 1340004 9/30/2013 9:04:00AM 10/2/2013 5.44:00PM

SuiTogale: Tetrachloro-m-xylene 39.0% 30-125 1340004 9/30/2013 9:04;00AM 10/2/2013 5:44:00PM

PCB_8082 SW 8082 Analyst; KSW

Aroclor 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9:00;00AM 10/2/2013 5:44:00PM

Aroclor 1221 BDL 0.124 0.500 ug/L I 1340003 9/30/2013 9:00:00AM 10/2/2013 5;44:OOPM

Aroclor 1232 BDL 0.232 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 5;44:00PM

Aroclor 1242 BDL 0.233 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 5:44;00PM

Aroclor 1248 BDL 0.147 • 0.500 ug/L I 1340003 9/30/2013 9:00:00AM 10/2/2013 5:44:00PM

Aroclor. 1254 BDL 0.196 0.500 ug/L 1 ,1340003 9/30/2013 9:00.00AM 10/2/2013 5:44:00PM

Aroclor 1260 BDL 0.249 0.500 ug/L 1 1340003 9/30/2013 9:OO;O0AM 10/2/2013 5:44;00PM

Surrogate: Decachlorobiphenyl 83.0% 48-146 1340003 9/30/2013 9:00:00tV^ 10/2/2013 5:44:00PM

Surrogate: Teb'achloro-m~xylene 39.0% 28-127 1340003 9/30/2013 9:00:00AM 10/2/2013 5;44:00PM

PAH_8270 SW 8270C Analyst: KSW

Acenaphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10,'9/2013 i2;05:00PM

Benz(a)anthraccne BDL 0.0840 0.260 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05;00PM

Benzo(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

Benzo(b)fluoranthenc BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 12:05:00PM

Benzo(k)f1uorantliene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

Chrysenc BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3;50;00PM 10/9/2013 12:05:00PM

lndeno( 1,2,3-cd)pyrene BDL 0.0566 0.220 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

Naphthalene BDL 0.0651 lO.O ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

P>Tene BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

Surrogate: Witrobenzene-dS 91.6% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 12:05:00PM

SwTOgate: 2-Fluoiobiphenyl 78.4% 50-104 1340044 9/30/2013 3;5O:O0PM 10/9/2013 12:05:00PM

Surrogate: Teiphenyl-d14 80.5% 37-135 1340044 9/30/2013 3:50;00PM ia'9/2013 12:05:00PM

Imont Labs Date: 10/28/2013

ENT: Ject:


Lab Order: 1311442

bID: ent Sample ID:

1311442-02 130-998;MW-33LP;Z092513

Collection Date: 9/25/2013 1:32:00PM Matrix: Leachate

ilysis Result MDL PQL Qual Units Dilution Batch Date Prepared Date Analyzed

EPA 245.1 Analyst: TL

-ury 0.0000477 0.0000243 0.000200 J mg/L 1 1340234 lDM/2013 11:30:00AM 10/8/2013 9:00:00AM

T_8081 SW8081 Analyst: KSW

DDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 6:09:00PM'

in BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 6:09:00PM

achlor BDL 0.0181 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 6:09;00PM

'gate: Decachlorobiphetiyl 94.0% 55-135 1340004 9/30/2013 9:04:00AM 10/2/2013 6:09:00PM

ygate: Tetrachloro-m~x^'lene 44.0% 30-125 1340004 9/30/2013 9:04:00AM 10/2/2013 6:09:00PM

t_8082 SW 8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:09:00PM

lor 1221 BDL 0.124 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:09;00PM

lor 1232 BDL 0.232 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:09:00PM

lor 1242 BDL 0.233 0.500 ug/L 1 1340003 9/30/2013 9;00:00AM 10/2/2013 6:09:00PM

lor 1248 BDL 0.147 0.500 ug/L 1 1340003 9/30/2013 9;00:00AM 10/2/2013 6:09:00PM

lor 1254 BDL 0.196 0.500 ug/L 1 1340003 9/30/2013 9.00:00AM 10/2/2013 6:09:00PM

lor 1260 BDL 0.249 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:09:00PM

gate: Decachlorobiphenyl 94.0% 48-146 1340003 9/30/2013 9:00:00AM. 10/2/2013 6:09:00PM

'gale: Teh-acblora-m-xylene 44.0% 28-127 1340003 9/30/2013 9:00:00AM 10/2/2013 6:09:00PM

l_8270 SW 8270C Analyst: KSW

aphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31;00PM

»aiithracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

o(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 12:31:00PM

i>(b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50;OOPM 10/9/2013 12:31:00PM

o(k)fluorantl]ene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:OOPM 10/9/2013 12:31:00PM

»ene BDL 0.0625 10.0 ug/L 1^ 1340044 9/30/2013 3;50:00PM 10/9/2013 12:31:00PM

>z(aji)antliracene BDL 0.0742 0.200 ugL 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

o(l,2.3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

thalene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

e BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

gale: NUrobeneene-dS 84.8% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

gate: 2-Fluowbiphenyl 66.8% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM

gale: Terphenyl-dU 70.4% 37-135 1340044 9/30/2013 3:50:00PM 10/9/2013 12:31:00PM


CLIENT: Project:


Lab Order: 1311442


1311442-03 130-998;MW-21LP + MS/MSD;Z092513




Mercuiy BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 11:30;00AM 10/8/2013 9:00:00AM


4,4-DDT BDL 0.0217 0.0500 ug/L I 1340004 9/30/2013 9:O4;00AM 10/2/2013 6:34:00PM

Aldiin BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM \QtmO\3 6:34:00n4

Heptachlor BDL 0.0181 0.0500 ug/L 1 1340004 9/30/2013 9;04:60AM 10/2/2013 6:34:00PM

Smrogale; Decochlombiphenyl 74.0% 55-135 1340004 9/30/2013 9;O4:00AM 10/2/2013 6:34:00PM

SwTogate: Tetrachloro-m-xylene 61.0% 30-125 1340004 9/30/2013 9;O4:O0AM 10/2/2013 6:34:00PM

PCB_8082 SW 8082 Analyst: KSW

Aroclor 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:34:00PM

Aroclor 1221 BDL 0.124 0.500 ug/L I 1340003 9/30/2013 9;00:00AM 10/2/2013 6:34:00PM




Aroclor 1254 BDL 0.196 0.500 ugiL 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:34:00PM


Surrogate: Decachlorobiphertyl 74.0% 48-146 1340003 9/30/2013 9:00:00AM 10/2/2013 6:34:00PM

Surrogate: Tebachloro-m-xylene 61.0% 28-127 1340003 9/30/2013 9:00:00AM 10/2'2013 6:34:00PM


Acenaphthene BDL 0.0350 10.0 ug/L I 1340044 9/30/2013 3:50:00PM lQ/9/2013 12:57:00PM

Benz(a)anthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Ben2o(a)pyreTie BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12;57;00PM

Behzo(b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 12:57:00PM

Benzo(k)fluoranthene BDL 0.0574 1,70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12;57:00PM

Chryscnc BDL 0.0625 10.0 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Indeno( 1,2,3-cd)pyrenc BDL 0.0566 0.220 ug/L I 1340044 9/30/2013 3;50:00PM I0.'9/2013 12:57:00PM

Naphthalene 1-S4 0.0651 10.0 J ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Pyrene BDL 0.0613 10.0 ug/L I 1340044 9/30/2013 3;50.00PM 10/9/2013 12:57:00PM

Surrogate: Nitrobenzene-dS 94.2% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Surrogate: 2'Fluoivbiphenyl 77.4% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 12:57:00PM

Surrogate: Terphenyl-dl4 68.9 % 37-135 1340044 9/30/2013 3:50:00PM 10/9/2013 12.57.00PM

i;6;Qf25^


ENT: ]ect:


Lab Order: 1311442

bID: ent Sample ID:

1311442-04 130-998:MW-24LP:Z092513


ilysis Result MDL PQL Qua! Units Dilution Batch Date Prepared Date Analyzed


-Tiry 0.0000754 0.0000243 0.000200 • J mg/L 1 1340234 10/4/2013 11:30;00AM 10/&/2013 9:00:00AM

T_8081 SW 8081 Analyst: KSW

DDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9;04:OOAM 10/2/2013 6:59;00PM

n BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9;O4;00AM 10/2/2013 6:59:00PM

icfalor BDL 0.0181 0.0500 ug/L I 1340004 9/30/2013 9:04:00AM 10/2/2013 6:59:00PM

gate: Decachlorobiphenyl 54.0% S-04 55-J35 1340004 9/30/2013 9;04:00AM 10/2/2013 6:59;00PM

gale: Tetrachloro-m-xylene 67.0% 30-125 1340004 9/30/2013 9:04:00AM lQ/2/2013 6:59:00PM

1

;_8082 SW 8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9;O0:O0AM 10/2/2013 6:59:00PM

lor 1221 BDL 0.124 0.500 ug/L I 1340003 9/30/2013 9:00:00AM 10/2/2013 6:59:00PM

lor 1232 BDL 0.232 0.500 Mg/L I 1340003 9/30/2013 9:00:00AM 10/2/2013 6:59:00PM

lor 1242 BDL 0.233 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:59:00PM

lor 1248 BDL 0.147 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 6:59.00PM

lor 1254 BDL 0,196 0.500 ug/L 1 1340003 9/30/2013 9;O0:0OAM 10/2/2013 6:59:00PM

lor 1260 BDL 0.249 0.500 ug/L I 1340003 9/30/2013 9:00:OOAM 10/2/2013 6:59:00PM

'gale: Decachlorobiphenyl 54.0% 48-146 1340003 9/30/2013 9:00:00AM 10/2/2013 6:59:00PM

gale: Tebachloto-m-xylene 67.0% 28-127 1340003 9/30/2013 9:00;00AM 10/2/2013 6:59:00PM

L8270 SW 8270C Analyst: KSW

aphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 1:24;OOPM

,a)anthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24;00PM

o(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1;24:00PM

a(b)fluoraDthene BDL 0,0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

o(k)f1uoranthcne BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

icne BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

iz(a,h)anlbracene BDL 0:0742 0.200 ug/L 1 1340044 9/30/2013 3;50:00PM 10/9/2013 1:24:00PM

o(l,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24;00PM

Ihalene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

e BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

gale: Nilrobenzene-d5 92.3% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

gale: 2-FIuoiobiphenyI 74.2 % 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 1:24:00PM

late: Terphenyl-dI4 75.8% 37-135 1340044 9/30/2013 3:50:00PM 10/9/2013 l:24:OOPM


CLIENT: Project:


Lab Order: 1311442

Lab ID: Client Sample ID;

1311442-05 130-998;Duplicate;Z092513




Mercury BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 I1:30:00AM 10/&/2013 9:00:00AM

PEST_8081 SW8081 Analyst: ksw 4.4-DDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 7:25:00PM

Aldrin BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9:M:00AM 10/2/2013 7:25:00PM

Heptachlor BDL 0.0181 0.0500 1

ug/L I 1340004 9/30/2013 . 9:04:00AM 10/2/2013 7:25:00PM

SujTogate: Decachtorobiphenyl 52.0% S-04 55-135 1340004 9/30/2013 9:04:00AM 10/2/2013 7:25:60PM

SuiTogate: Tetrachloro-m-x^'lene 51.0% 30-125 1340004 9/30/2013 9:04:00AM ip/2i/2013 7:25:00PM


Arocloi 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:25:00PM

Arpclor 1221 BDL 0.124 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:25:00PM

Aioclor 1232 BDL 0.232 0.500 ug/L 1 1340003 9/30/2013 9:60:OOAM 10/2/2013 7:25:00PM



Aroclor 1254 BDL 0.196 0,500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:25:00PM

Aroclor 1260 BDL 0.249 . 0..500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:25:00PM

Surrogate: Decachtorobiphenyl 52.0% 48-146 1340003 9/30/2013 9;00:00AM 10/2/2013 7:25:00PM

Surrogate: Tebachloro-m-xylene 51.0 %, 28-127 1340003 9/30/2013 9;0O:O0AM 10/2/2013 7:25:00PM


Acenaphlhene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:D0PM 10/3/2013 10:05:00PM

Benz(a)anthracene BDL 0.0840 0.260 ugO. 1 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05:00PM

Beiizo(a)pyrene BDL 0.0820 0.200 ug/L J 1340044 9/30/2013 3;50;00PM 10/3/2013 10:05;00PM

Benzo(b)fluoranthene BDL 0.0527 0.170 ug/L I 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05:00PM

Benzo(k)fluoranthenc BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05:00PM

Chrysene BDL 0.0625 10.0 ug/L I 1340044 9/30/2013 3:50:b0PM 10/3/2013 10:05:OOPM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3;50:00PM 10/3/2013 10:05:00PM

Indeno(i ,2,3-cd)pyrene BDL 0.0566 .0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05;OOPM

Naphthalene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50;00PM 10/3/2013 10:05:00PM

Pyrene BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05:00PM

Surrogate: Nitrobeniene-dS 84.1%, 50-110 1340044 9/30/2013 3;50:00PM 10/3/2013 10:05:00PM

Surrogate: 2-FluoiobiphenyI 67.3% 50-104 1340044 9/30/2013 3:50:00PM 10/3/2013 10:05:00PM

Surrogate: Teiphenyl-d 14 67.8% 37-135 1340044 9/30/2013 3:50;00PM 10/3/2013 10:05:00PM


ENT: lect:


Lab Order: 1311442

bID: 1311442-06 Collection Date: 9/25/2013 5;13;00PM ent Sample ID: 130-998:FB-1:Z092513 Matrix: Water

lysis Result MDL PQL Qual Units Dilution Batch Date Prepared Date Analyzed


iiry BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 I1;30:00AM 10/8/2013 9:00:00AM


DDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9;O4:O0AM 10/2/2013 7:50:00PM

3 BDL 0,0168 0.0500 ug/L 1 1340004 9/30/2013 9;04:00AM 10/2/2013 7;50:00PM

ichlor BDL 0.0181 0.0500 ug/L 1 1340004 9/30/2013 9;04;00AM 10/2/2013 7:50:00PM

gate: DecachhrobiphenyJ 122% 55-135 1340004 9/30/2013 .9:04:00AM 10/2/2013 7:50:00PM

gate: Tetrachloro-m-xylene 69.0% 30-125 1340004 9/30/2013 9:04:00AM 10/2/2013 7;5O:O0PM

_8082 SW 8082 Analyst: KSW

or 1016 BDL 0.238 0..500 ug/L 1 1340003 9/30/2013 9:00;00AM 10/2/2013 7:50:00PM

or 1221 BDL 0.124 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

or 1232 BDL 0.232 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

or 1242 BDL 0.233 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

or 1248 BDL 0.147 0..500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

or 1254 BDL 0.196 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

or 1260 BDL 0.249 0..500 ug/L 1 1340003 9/30/2013 9:00:(lpAM 10/2/2013 7:50:00PM

gate: Decachlowbipheny! 122% 48-146 1340003 9/30/2013 9:00:00AM 10/2/2013 7:50:00PM

gate: Tetrachloro-m-xylene 69.0% 28-127 1340003 9/30/2013 9:0O;O0AM 10/2/2013 7:50:00PM

_8270 SW 8270C Analyst: KSW

iphthene BDL 0.0350 10.0 ug«. 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1;50:OOPM

a)aiithracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:0aPM 10/9/2013 1:50:00PM

>(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

<b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 l:50;00PM

t(k)fluoranthene BDL 0.0574 1.70 ugL 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

ene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

2(a.h)anthracene BDL 0.0742 0.200 ug4. 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

D{l,2,3-cd)pyrcne BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

halene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 I:50:00PM

e BDL 0.0613 10.0 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

âte: Nitrobenzene-dS 104% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50:00PM

late: 2-Fluowbipheny1 83.6% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 1:50.00PM

late: Te)phenyl-dJ4 98.7% 37-135 1340044 9/30/2O13 3:50:00PM 10/9/2013 1:50:00PM


CLIENT: Project:


Lab Order: 1311442


1311442-07 130-998:MW-27LP:Z092513



HG EPA 245.1 Analyst: XL

Mercuiy BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 11:30:00AM 10/8/2013 9:00:00AM


4,4'-DDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM \mnO\3 8:15:00PM

Aldrin BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM llV2n013 8:15:00PM

Heptachlor BDL 0.0181 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 8:15:00PM

Smrogate: Decachtorobiphenyl 108% 55-135 1340004 9/30/2013 9:04:00AM 10/2/2013 8:15«IPM

Surrogate: Tetrachloro-m-xylene 52.0% 30-125 1340004 9/30/2013 9:04:00AM 10/2/2013 8:15:00PM

PCB_8082 SW8082 Analyst: KSW



Aroclor 1232 BDL 0.232 0.500 ug/L I 1340003 9/30/2013 9:00:00AM 10/2^013 8:1S:OOPM


Aroclor 1248 BDL 0.147 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM lonnon 8:15:00PM

Aroclor 1254 BDL 0.1% 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2'2013 8.15:00PM

Aroclor 1260 BDL 0.249 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM lfl®2013 8:15:00PM

Surrogate: Decachlorobiphenyl 108% 48-146 1340003 9/30/2013 9:00:00AM 10/2C013 8:15:00PM

Surrogate: TebacMoro-m-xylene 52.0 % 28-127 1340003 9/30/2013 9:00:00AM 10/2/2013 8:15:00PM


Acenaphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

Benz(a)anthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 1051/2013 2:26:00PM

Ben2o(a)pyrenc BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3.50:00PM 10/9/2013 2:26:00PM

Benzo(b)fluoranlhene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:.50:00PM 10/9/2013 2:26:00PM

Benzo(k)fluorantheDe BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26;00PM

Chrysene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:.50:00PM 10/9/2013 2:26:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

lndeno( 1,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

Naphthalene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

Pyrene BDL 0.0613 10.0 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

Surrogate: Nitrobenzene-d5 85.6% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:OOPM

Surrogate: 2-Fluoiobipbenyl 80.6% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 2:26:00PM

Surrogate: Teiphenyl-dl4 73.7% 37-135 1340044 9/30/2013 3:50:00PM 1^9/2013 2:26:00PM


ENT: lect:


Lab Order: 1311442

bID: ent Sample ID:

1311442-08 130-998:MW-30LP:Z092513




Jiy BDL 0.0000243 0.000200 mg/L 1 1340234 10/4/2013 11:30:00AM 10/8Q013 9:00:00AM

r_8081 SW8081 Analyst: KSW

IDT BDL 0.0217 0.0500 ug/L 1 1340004 9/30/2013 9:04:00AM 10/2/2013 8:40:00PM

3 BDL 0.0168 0.0500 ug/L 1 1340004 9/30/2013 9.04:00AM 10®2013 8:40:00PM

chJor BDL 0.0181 0.0500 ugA. 1 1340004 9/30/2013 9:04:00AM 10/2/2013 8:40:D0PM

gate: Decachhivbiphenyl 110% 55-135 1340004 9/30/2013 9:04:00AM 10/2/2013 8:40:00PM

late: Tetrachloro-m-xylene 59.0% 30-125 1340004 9/30/2013 9:04:00AM 1(V2/2013 8:40:001^

_8082 SW 8082 Analyst: KSW

or 1016 BDL 0.238 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 8:40:00PM

or 1221 BDL 0.124 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM lon/ion 8:40:00PM

)r 1232 BDL 0.232 0..500 ugA 1 1340003 9/30/2013 9:00:00AM 10/2/2013 8;40:00PM

or 1242 BDL 0.233 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 8:40:00PM

jr 1248 BDL 0.147 0..500 ug/L 1 1340003 9/30/2013 9;00:00AM 10/2/2013 8:40:00PM

or 1254 BDL 0.196 0.500 ug/L 1 1340003 9/30/2013 9:00:00AM 10/2/2013 8:40:pOPM

>r 1260 BDL 0.249 0.500 ug/L 1 1340003 9/30/2013 9:00:00M4 10/2/2013 8:40:00PM

gate: Decachtotabiphenyl 110% 48-146 1340003 9/30/2013 9:00:00AM 10/2/2013 8:40:00PM

gate: Tetrachloro-m-xylene 59.0% 28-127 1340003 9/30/2013 9:00:00AM 10/2/2013 8:40:00PM


iphthene 1.94 0.0350 10.0 J ug/L 1 1340044 9/30/2013 3:50:00I>M 1 1 3:21:00PM

a)aiithracere BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

<b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM iO/IO/2013 3:21:00PM

<k)nuoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

one BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:2I:00PM

z(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

3(l,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

halene BDL 0.0651 10.0 ug/L 1 1340044 9/3(^2013 3:50:00PM 10/10/2013 3:21:00PM

: BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

late: Nitrobenzene-dS 83.9% 50-110 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM

late: 2-FIuotobiphenyl 77.6% 50-104 1340044 9/30a013 3:50:00PM 10/10/2013 3;21:00PM

>ate: Terphenyl-dI4 68.4% 37-135 1340044 9/30/2013 3:50:00PM 10/10/2013 3:21:00PM


CLIENT: Civil & Environmental Consultants, Inc. - Toledo Lab Order: Project: 130-998

1311442

Mercury Analysis -Quality Control

Analyte Result

Rqxrrting

, Limit Units

Spike Source %REC

Level Result %REC Limits RPD

RPD Limit Notes

Batch 1340234-PREP HG W

Blank (1340234-BLKl) Prepared: 10/04/13 Analyzed: 10/08/13

Mercury BDL 0.000200 mg^L

LCS (1340234-BSl) Prepared: 10/04/13 Analyzed: 10/08/13

Mercury 0.00646 0.000200 mg/L 0.006250 103 80-120

LCS Dup (1340234-BSDl) Prepared: 10/04/13, Analyzed: 10/08/13

Mercury 0.00644 0.000200 mg/L 0.006250 . 103 80-120 0.3 20

Matrix Spike (1340234-MSl) Source; 1311442-03 Prepared: 10/04/13 Analyzed: 10/08/13

Mercury 0.00625 0.000200 mg/L 0.006250 ND 100 70-130

Matrix Spike Dup (1340234-MSDl) Source: 1311442-03 Prepared: 10/04/13 Analyzed: 10/08/13

Mercury 0.00631 0.000200 mg/L 0.0062.50 ND 101 70-130 1 30


ENT: Ject:


Lab Order: 1311442

Organochlorine Pesticides by EPA Method 8081 - Quality Control

Repotting Spike Sotirce %REC RPD

lyte Result Limit Units Level Result %REC Limits RPD Limit Notes

ch 1340004-PREP PP W

ik(1340004-BLKl) Prepared: 09/30/13 Analyzed: 10/02/13

ODD HDL 0.0500 ug/L

DDE DDL 0.0500 ug/L

DDT BDL 0.0500 ug/L

in BDL 0.0500 ug/L

i-BHC BDL 0.0500 ug/L

i-Chloidane BDL 0.0500 ug/L

BHC BDL 0.0500 ug/L

rdane BDL 0.500 ug/L

-BHC BDL 0.0500 ug/L

Ihn BDL 0.0500 ug/L

>$ti]fan I BDL 0.0500 ug/L

isulfan D BDL 0.0.500 ug/L

isulfnn sulfate BDL 0.0500 ug/L

in BDL 0.0500 ug/L

in aldehyde BDL 0.0500 ug/L

in ketone BDL 0.0500 ug/L

na-BHC BDL 0.0500 ug/L

na-Chlordane BDL 0.0500 ug/L

ichlor BDL 0.0500 ug/L

ichlor epoxide BDL 0.0500 ug/L

oxychlor BDL 0.0500 ug/L

phene BDL 0.500 ug/L

•gale: Decachloroblphenyl 1.58 ug/L 1.000 158 55-135 S-02

tgale: Tetrachlora-m-xylene 0.780 ug/L 1.000 78.0 30-125

(1340004-BSl) Prepared: 09/30/13 Analyzed: 10/02/13

DDD 0.670 0.0500 ug/L 0.5000 134 67-123 L

DDE 0.590 0.0500 ug/L 0.5000 118 64-118

DDT 0.560 0.0500 ug/L • 0.5000 112 67-135

n 0.480 0.0500 ug/L 0.5000 96.0 52-103

-BHC 0.510 0.0500 ug/L 0.5000 102 60-131

-Chlordane 0.560 0.0500 ug/L 0.5000 112 62-117

BHC 0.520 0.0500 ug/L 0.5000 104 62-115

BHC 0.520 0.0500 ug/L 0.5000 104 64-126

0.630 0.0500 ug/L 0.5000 126 64-127

sulfan I 0.420 0.0500 ug/L 0.5000 84.0 48-118

sulfan n 0.500 0.0500 ug/L 0.5000 100 50-128

sulfan sulfate 0.680 0.0500 ug/L 0.5000 136 53-164

n 0.690 0.0500 ug/L 0.5000 138 60-137 L

n aldehyde 0.790 0.0500 ug/L 0.5000 158 61-137 L

n ketone 0.670 0.0500 ug/L 0.5000 134 67-142

la-BHC 0.450 0.0500 ug/L 0.5000 90.0 6.5-116

ia-Chlordane 0.700 0.0500 ug/L 0.5000 140 70-110 L

Lchlor 0.420 0.0500 ugT, 0.5000 84.0 43-126

ichlor epoxide 0.560 0.0500 ug/L 0.5000 112 65-118


CLIENT: Project:


l.ab Order: 1311442


Repotting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes

Batch 1340004-PREP PP W

LCS (1340004-BSl) .• . Prepared: 09/30/13 Analyzed: 10/02/13

Mcthoxychlor 0,870 0.0500 ug/L 0.5000 174 52-161 L

Surrogate: Decochlorobiphenyl 1.62 ug/L 1.000 162 55-135 S-02

Surrogate: Tetrachloro~m-xylene 0.610 ug/L 1.000 61.0 30-125

LCS Dup (1340004-BSDl) Prepared: 09/30/13 Analyzed: 10/02/13

4.4-DDD 0.720 0.0500 ug/L 0.5000 144 67-123 7.19 10 L

4,4'-DDE 0.640 0.0500 ug/L 0.5000 128 64-118 8.13 10 L

4,4-DDT 0.620 0.0500 ug/L 0.5000 124 67-135 10.2 10 . R

Aldrm 0.500 0.0500 ug/L 0.5000 100 52-103 4.08 17

alpha-BHC 0.550 0.0.500 ug/L 0.5000 110 60-131 7.55 11

alpha^Chlordane 0.590 0.0500 ug/L 0.5000 118 62-117 5.22 10 L

beta-BHC 0.560 0.0500 ug/L 0.5000 112 62-115 7.41 11

delta-BHC 0.560 0.0500 ug/L 0.5000 112 64-126 7.41 11

Dieldhn 0.660 0.0500 ug/L 0.5000 132 64-127 4.65 10 L

Endosulfan I 0.440 0.0500 ug/L 0.5000 88.0 48-118 4.65 10

Endosulfan n 0.530 0.0500 ug/L 0.5000 106 .50-128 5.83 10

Endosulfan sulfate 0.780 0.0500 ug/L 0.5000 156 53-164 13.7 12 R

Endrin 0.720 0.0500 ug/L 0.5000 144 60-137 4.26 10 L

Endrin aldehyde 0.840 0.0500 ug/L 0.5000 168 61-137 6.13 10 L

Endrin ketone 0.730 0.0.500 ug/L 0.5000 146 67-142 8.57 10 L

gamma-BHC 0.480 0.0500 ug/L 0.5000 96.0 6.5-116 6.45 10

ganuna-Chlordane 0.670 0.0500 ug/L 0.5000 134 70-110 4.38 10 L

Heptachlor 0.440 0.0500 ug/L 0.5000 88.0 43-126 4.65 12

Heptachloi epoxide 0.590 0.0500 ug/L 0.5000 118 6.5-118 5.22 10

Methoxychlor 0.940 0.0500 ug/L 0.5000 188 52-161 7.73 10 L

Sunogate: Decochlorobiphenyl 1.67 ug/L 1.000 167 55-135 S-02

Surrogate: Tetrachloro-m-xylene 0.680 ug/L 1.000 68.0 30-125

l>;:gageM^^2i5

mont Labs Date: 10/28/2013

:NT: ect:


Lab Order: 1311442


Rcponing Spike Source %REC RPD yte Result Limit Units Level Result %REC Limits RPD Limit Notes

h 1340004-PREP PP W

rU Spike (1340004-MSl) Source 1311442-03 Prepared: 09/30/13 Analyzed: 10/02/13

DDD 0,480 0.0500 ug/L 0.5000 ND 96.0 70-130

5DE 0.380 0.0500 ug/L 0.5000 ND 76.0 70-130

5DT 0.410 0.0500 ug/L 0.5000 ND 82.0 70-130

1 0.370 0.0500 ug/L 0.5000 ND 74.0 70-130

BHC 0.460 0.0500 ug/L 0.5000 ND 92.0 70-130

-Chlordane 0.400 0.0500 ug/L 0.5000 ND 80.0 . 0-200

3HC 0.590 0.0500 ug/L 0.5000 ND 118 70-130

BHC 0.390 0.0500 ug/L 0.5000 ND 78.0 70-130

rin 0.480 0.0500 ug/L 0.5000 ND 96.0 70-130

sulfan I 0.320 0.0500 ug/L 0.5000 ND 64.0 70-130 M

sulfim II 0.360 0.0500 ug/L 0.5000 ND 72.0 70-130

iulfan sulfate 0.580 0.0500 ug/L 0.5000 ND 116 70-130

n 0.520 0.0500 ug/L 0.5000 ND 104 70-130

u aldehyde 0.540 0.0500 ug/L 0.5000 ND 108 70-130

n ketone 0.610 0.0500 ug/L 0.5000 ND 122 0-200

ia-BHC 0.380 0.0500 ug/L 0.5000 ND 76.0 70-130

la-Chlordane 1.19 0.0500 ug/L 0.5000 ND 238 0-200 M

chlor 0.470 0.0500 ug/L 0.5000 ND 94.0 70-130

ichlor epoxide 0.440 0.0500 ug/L 0.5000 ND 88.0 70-130

3xychlDr 0.750 0.0500 ug/L 0.5000 ND 150 0-200

gale: Decachlowbiphenyl 1.39 ug/L 1.000 139 55-135 M gate: Tetrachlow-m-xylene 1.15 ug/L 1.000 lis 30-125

Ix Spike Dup (1340004-MSDl) Source: 1311442-03 Prepared: 09/30/13 Analyzed: 10/02/13

)DD 0,430 0.0500 ug/L 0.5000 ND 86.0 70-130 11.0 25

IDE 0.320 0.0500 ug/L 0.5000 ND 64.0 70-130 17.1 25 M

>DT 0.360 0.0500 ug/L 0.5000 ND 72.0 70-130 1.3.Ci 25

I 0.250 0.0500 ug/L 0.5000 ND 50.0 70-1.30 38.7 25 M, R

BHC 0.340 0.0500 ug/L 0.5000 ND 68.0 70-130 30.0 25 M. R

Chlordane 0.330 0.0500 ug/L 0.5000 ND 66.0 0-200 19.2 200

IHC 0.510 0.0500 ug/L 0..5000 ND 102 70-130 14.5 25

BHC 0.350 0.0500 ug/L 0.5000 ND 70.0 70-1.30 10.8 25

•in 0,420 0.0500 ug/L 0.5000 ND 84.0 70-130 13.3 25

ulfan I 0.270 0.0500 ug/L 0.5000 ND .54.0 70-130 16.9 25 M

ulfan n 0.340 0.0500 ug/L 0.5000 ND 68.0 70-1.30 5.71 25 M

ulfan sulfate 0.530 0.0500 ug/L 0.5000 ND 106 70-130 9.01 25

1 0.470 0.0500 ug/L 0.5000 ND 94.0 70-1.30 10.1 25

1 aldehyde 0.470 0.0500 ug/L 0.5000 ND 94.0 70-130 1.3.9 25

1 ketone 0.590 0.0500 ug/L 0.5000 ND 118 0-200 3.33 200

a-BHC 0.310 0.0500 ug/L 0.5000 ND 62.0 70-130 20.3 • 25 M

a-Chlordane 1.31 0.0500 ug/L 0.5000 ND 262 0-200 9.60 200 M

;hlar 0.340 0.0500 ug/L 0.5000 ND 68.0 70-130 32.1 25 M.R

:hIor epoxide 0.380 0.0.500 ug/L 0.5000 ND 76.0 70-1.30 14.6 25

xychlor 0.700 0.0500 ug/L 0.5000 ND 140 0-200 6.90 200

ate: Decachlorobiphenyl 0.620 ug/L 1.000 62.0 55-135


CLIENT: Civil & Environmental Consultants, Inc. - Toledo Project: 130-998

Lab Order: 1311442


Raiting Analytc Result Limit Units

Spike Source %REC

Level Result %REC Limits

RPD

RPD Limit Notes

Batch 1340004 - PREP PP W

Matrix Spike Dap (1340004-MSDl) Source: 1311442-03 Prepared; 09/30/13 Analyzed: 10/02/13

Surrogate: Tetrachloro-m-xylene 0.360 ug/L I.OOO 36.0 30-125


ENT: lect:


Lab Order: 1311442

Polychlorinated Biphenyls by EPA Method 8082 - Quality Control

lyte Result

Reporting

Limit Units

Spike Source %REC

Level Restilt %REC Limits RPD

RPD

Limit Notes


k(1340003-BLKl) Prepared; 09/30/13 Analyzed: 10/02/13

lor 1016 BDL 0,500 ug/L

lor 1221 BDL 0.500 ug/L

lor 1232 BDL 0.500 ug/L

lor 1242 BDL 0.500 ug/L

lor 1248 BDL 0.500 ug/L

lor 1254 BDL 0.500 ug/L

lor 1260 BDL 0.500 ug/L

*gate: Decachlorobiphenyl

gate: Telrachloro-m-xylene

1.58

0.780

ug/L

ug/L

1.000 158 48-146

1.000 78.0 28-127

S-QC


lor 1016 5.65 0.500 ug/L 5.000 113 69-138

lor 1260 6.69 0.500 ug/L 5.000 134 70-131 L

gate: Decachlorobiphenyl

'gale: Tetrachloro-m-xylene

1.54

0.760

ug/L

ug/L

1.000 154 48-146

1.000 76.0 28-127

S-QC

Dnp (1340003-BSDl) Prepared: 09/30/13 Analyzed: 10/02/13

lor 1016 5.94 0.500 ug/L 5.000 119 69-138 5.00 14

lor 1260 7.30 0.500 ug/L 5.000 146 70-131 8.72 19 L


gate: Tetrachloro-m-xylene

1.78

0.760

ug/L

ug/L

1.000 1 78 48-146

1.000 76.0 28-127

S-QC

ill Spike (1340003-MSl) Source: 1311442-03 Prepared: 09/30/13 Analyzed: 10/02/13

or 1016 11.6 0.500 ug/L 5.000 ND 232 41-163 M

or 1260 4.71 0.500 ug/L 5.000 ND 94.2 50-111



0.820

0.640

ug/L

ug/L

1.000

1.000

82.0

64.0

48-146

28-127


CLIENT: Project:


Lab Order: 1311442


Repoiting Spike ' Source •/oREC ^ RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes


Matrix Spike Pup (1340003-MSDl) Source: 1311442-03 Prepared: 09/30/13 /^lyzed: 10/02/13 Aroclor 1016

Aroclor 1260

12.5 4.71

0.500

0.500

ug/L

ug/L

5.000

5.000

ND

ND

251

94.2

41-163

50-111

7.70

0.00

17

22

M

Sunvgate: Decachlombiphenyl

Surrogate: TetrachIoro-m~xylene

0.750

0.650

ug/L

ug/L

1.000

1.000

75.0

65.0

48-146

28-127


ENT: lect:


L^b Order: 1311442

Semivolatile Organic Compounds by EPA Method 8270C - Quality Control

yte Result Reponiog

Limit Units Spike Level

Source Result %REC

%REC Limits RPD

RPD Limit Notes

ch 1340044 - PREP SVOCW

k (1340044-BLKl) Prepared: 09/30/13 Analyzed: 10/09/13

sphthcne BDL 10.0 ug/L

[a)antliracene BDL 0.260 ug/L

D{a)pyrene BDL 0.200 ug/L

)(b)nuoiai>thene . BDL 0.170 ug/L

3(k)fluorantliene BDL 1.70 ug/L

sene BDL 10.0 ug/L

iz(a,h)anthracene BDL 0.200 ug/L

o(l,2,3-cd)pyrene BDL 0.220 ug/L

thalene BDL 10.0 ug/L

le BDL 10.0 ug/L

gale: Nilrobenzene-d5 34.0 ug/L 40.00 84.9 5O-1J0

gate: 2-Fluombipheayl 33.9 ug/L 40.00 84.7 50-104

gate: Terphenyl-dl4 36.9 ug/L 40.00 92.2 37-135


'hylnaphthalene 37.0 10.0 ug/L 50.00 73.9 10-200

iphthene 36.3 10.0 ug/L 50.00 72.7 53-95

iphthylene 37.0 10.0 ug/L 50.00 73.9 48-98

-acene 44.2 10.0 ug/L 50.00 88.3 60-97

;a)anthraceiie 43.5 0.260 ug/L 50.00 87.1 72-114

Xa)pyrene 42.1 0.200 ug/L 50.00 84.1 50-113

Xblfluoranthene 36.5 0.170 ug/L 50.00 72.9 48-111

j(Eji.i)perylene 43.4 10.0 ug/L 50.00 86.7 44-122

)(k)fluoranthene 38.0 1.70 Ug/L 50.00 75.9 35-125

,ent 39.7 10.0 ug/L 50.00 79.5 62-106

z(a3i)anthniceue 41.3 0.200 ug/L 50.00 82.6 47-119

mthene 52.2 10.0 ug/L 50.00 ' 104 54-108

cue 39.8 10.0 ug/L 50.00 79.7 53-97

o{1.2.3-cd)pyrene 41.5 0.220 ug/L 50.00 83.0 49-124

halene 34.4 10.0 ug/L 50.00 68.8 47-86

uthrene 38.0 10.0 ug/L 50.00 76.1 54-96

e 40.7 10.0 ug/L 50.00 81.4 53-107

late: Nitrobenzene-d5 36.6 ug/L 40.00 91.6 50-110

gate: 2-FIuorobiphenyl 30.1 ug/L 40.00 75.2 50-104

gate: Teiphenyl-dl4 34.9 ug/L 40.00 87.4 37-135


CLIENT: Project:


Lab Order: 1311442

Semivolatile Organic Compoiinds by EPA Method 8270C - Quality Control

Analyte Result

Rqxtiting

Litnit Utiits

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

Limit Notes

Batch 1340044-PREP SVOC W

LCS Diip (1340044-BSDl) Prepared: 09/30/13 Analyzed: 10/03/13

2-MethyInaphthalene 40.5 10.0 ug/L 50.00 81.0 10-200 9.14 50

Accnaphthene 40.3 10.0 ug/L 50.00 80.7 53-95 10.4 19

Acenaphthylene 40.1 10.0 ug/L 50.00 80.2 48-98 8.17 17

Anthracene 49.8 10.0 ug/L 50.00 99.7 60-97 12.1 12 L,R

Benz(a)anthiacene 48.5 0.260 ug/L 50.00 97.0 72-114 10.8 12

Benzo(a)pyrene 46.4 0.200 ug/L 50.00 92.8 50-113 9.83 19

Benzo(b)fluoranthene 41.9 0.170 ug/L 50.00 83.8 48-111 13.9 26

Ben2o(g3i,i)perylene 45.6 10.0 ug/L 50.00 91.2 44-122 4.99 31

Benzo(k)fluorantheDe 48.3 1.70 ug/L 50.00 96.7 35-125 24.0 29

Chiysene 44.5 10.0 ug/L 50.00 89.0 62-106 11.3 12

Dibeiiz(a,h)anihracene 44.3 0.200 ug/L 50.00 88.7 47-119 7.15 28

Fluoranthene 57.1 10.0 ug/L 50.00 114 54-108 9.08 13 L

Fluorene 45.3 10.0 ug/L 50.00 90.7 53-97 12.9 18

Indeno(l ,2,.^-cd)pyrene 44.0 0.220 ug/L 50.00 88.0 49-124 5.85 29

Naphthalene • 38.3 10.0 ug/L 50.00 76.6 47-86 10.8 13

Phenanthrene 43.4 10.0 ug/L 50.00 86.7 54-96 13.1 12 R

Pyiene 46.7 10.0 ug/L 50.00 93.4 .53-107 13.8 22

Sunvgate: Nitrobenzene-d5 37.7 ug/L 40.00 94.3 50-110

Sunvgale: 2-Fhiombiphenyl 32.2 ug/L 40.00 80.4 50-104

Surrogate: Teiphenyl-dJ4 39.8 ug/L 40.00 99.6 37-135

Matrix Spike (1340044-MSl) Source: 1311442-03 Prepared: 09/30/13 Analyzed: 10/03/13

Accnaphthene 38.4 10.0 ug/L 50.00 ND 76.8 70-130

Acetiaphthylene 39.5 10.0 ug/L 50.00 ND 79.0 70-130

Anthracene 42.4 10.0 ug/L 50.00 ND 84.8 70-130

Benz(a)anthracene 35.7 0.260 ug/L 50.00 ND 71.4 70-130

Benzo(a)pyrene 33.4 0.200 ug/L 50.00 ND 66.7 70-130 M

Benzo(h)fluoranthene 30.9 0.170 ug/L 50.00 ND 61.7 70-130 M

Benzo(g,h,i)petylene 32.7 10.0 ug/L 50.00 ND 65.4 70-130 M

Chtysene 10.0 ug/L 50.00 ND 66.1 70-130 M

Dibenz(a,h)anthracene 31.3 0.200 ug/L 50.00 ND 62.5 70-130 M

Fluoranthene 45.7 10.0 ug/L 50.00 ND 91.5 70-130

Fluorene 40.8 10.0 ug/L 50.00 ND 81.6 70-130

lndeno(l ,2,3-cd)pyrene 0.220 ug/L 50.00 ND 63.5 70-130 M

Naphthalene 37.2 10.0 ug/L 50.00 1.54 71.2 70-130

Phenanthrene 10.0 ug/L 50.00 ND 74.0 70-130

Pyrene 37.7 10.0 ug/L 50.00 ND 75.3 70-130

Sunogate: Nitrobenzene-dS

Sunogate: 2-Fbioiobipbenyl

Sunogate: Terphenyi-dI4

3P.S

31.6

29.7

ug/L

ug/L

ug/L

40.00

40.00

40.00

99.4

79.0

74.2

50-110

50-104

37-135


MT: ict:


Lab Order: 1311442


Repotting Spike Source %REC RPD

rte Result Limit Units Level Result %REC Limits RPD Limit Notes

h 1340044 - PREP SVOC W

rix Spike (1340044-MS2) Source: 1311474-02 Prepared: 09/30/13 Analyzed: 10/03/13

iphtfaene 34.9 10.0 ug/L 50.00 ND 69.8 70-130 M

iphthylene 36.6 10.0 ug/L 50.00 ND 73.1 70-130

acene 36.2 10.0 ug/L 50.00 72.4 70-130

'a)anthracene 32.4 0.260 ug/L 50.00 ND 64.8 70-130 M

j(a)pyTcne 29.9 0.200 ug/L 50.00 ND 59.8 70-130 M

3(b)fluoranthene 27.2 0.170 ug/L 50.00 ND 54.4 70-130 M

j(g,h,i)pcryleDe 30.5 10.0 ug/L 50.00 ND 60.9 70-130 M

;eiie 30.3 10.0 ug/L 50.00 ND 60.6 70-130 M

2(a,h)anthracene 29.3 0.200 ug/L 50.00 ND 58.6 70-130 M

anthene 41.2 10.0 ug/L 50.00 ND 82.5 70-130

ait 37.5 10.0 ug/L 50.00 ND 75.0 70-130

o(l,2,3-cd)pyrenc 29.6 0.220 ug/L 50.00 ND 59.2 70-130 M

halene 34.1 10.0 ug/L 50.00 ND 68.1 70-130 M

inthrenc 33.1 10.0 ug/L 50.00 ND 66.1 70-130 M

le 33.2 10.0 ug/L .50.00 ND 66.5 70-130 M

gate: Nitrobenzene-dS 3S.S ug/L 40.00 97.0 50-110

gate: 2-Fluotvbiphenyl 28.8 ug/L 40.00 72.0 50-104

gate: Terphenyl-dJ4 28.3 ug/L 40.00 70.8 37-135

ix Spike Dup (1340044-MSDl) Source: 1311442-03 Prepared: 09/30/13 Analyzed: 10/03/13

ipbthene 38.1 10.0 ug/L 50.00 ND 76.3 70-130 0.627 20

jphthylene 39.5 10.0 ug/L 50.00 ND 79.0 70-130 0.00 20

icene 39.2 10.0 ug/L 50.00 ND 78.4 70-130 7.92 20

a)anthracene 38.6 0.260 lig/L 50.00 ND 77.3 70-130 7.94 20

)(a)pyrene 36.3 0.200 ug/L 50.00 ND 72.6 . 70-130 8.53 20

(b)(luorajithene 35.4 0.170 ug/L 50.00 ND 70.9 70-1.30 13.8 20

(8,h,i)peiylenc 35.6 10.0 ug/L .50.00 ND 71.3 70-130 8.66 20

;ne 35.0 10.0 ug/L 50.00 ND 70.0 70-130 5.79 20

z(a,h)anthracene 34.2 0.200 ug/L 50.00 ND 68.4 70-130 8.95 20 M

inlliene 45.2 10.0 ugO. 50.00 ND 90.4 70-130 1.19 20

me 40.6 10.0 ug/L .50.00 ND 81.3 70-130 0.417 20

)(l,2,3-cd)pyrene 34.9 0.220 ug/L 50.00 ND 69.7 70-1.30 9.34 20 M

halene 36.2 10.0 ug/L 50.00 1.54 69.4 70-130 2.48 20 M

nthrene 36.9 10.0 ug/L 50.00 ND 73.8 70-130 0.244 20

e 38.3 10.0 ug/L 50.00 ND 76.6 70-130 1.68 20

{ale: Nilrobenzene-dS 40.4 ug/L 40.00 101 50-110

{ate: 2~Fliiorobiphenyl 32.0 ug/L 40.00 80.0 50-104

{ate: Terphenyl-dl4 30.5 ug/L 40.00 76.2 37-135


CLIENT: Project:


Lab Order: 1311442

SemivoIatOe Organic Compounds by EPA Method 8270C - Quality Control

Reponing Spike Source %REC RPD

Analyte Restilt Limit Units Level Result %REC Limits RPD Limit Notes


Matrii Spike Dup (1340044-MSD2) Source: 1311474-02 Prepared: 09/30/13 Analyzed: 10/03/13

Acenaphthene 32.3 10.0 ug/L 50.00 ND 64.6 70-130 7.68 20 M

Acenaphthylene 34.1 10.0 ug/L 50.00 ND 68.2 70-130 7.05 20 M

Anthracene 35.8 10.0 ug/L 50.00 ND 71.5 70-130 1.14 20

Benz(a)anthracene 34.0 0.260 ug/L 50.00 ND 68.1 70-130 4.97 20 M

Benzo(a)pyTene 32.3 . 0.200 ug/L 50.00 ND 64.6 70-130 7.62 20 M

Benzo(b)f1uoranthene 29.4 0.170 ug/L 50.00 ND 58.8 70-130 7.85 20 M

Benzo(g,h,i)perylene 34.3 10.0 ug/L 50.00 ND 68.5 70-130 11.7 20 M

Chiysene 30.5 10.0 ug/L 50.00 ND 61.0 70-130 0.559 20 M

Dibenz(a,h)anthracene' 32.7 0.200 ug/L 50.00 ND 65.3 70-130 10.9 20 M

Fluoranthene 41.4 10.0 ug/L 50.00 ND 82.8 70-130 0.387 20

Fluorene 35.7 10.0 ug/L 50.00 ND 71.4 70-130 4.92 20

Indeno(l .2.3-cd)pyrene 32.9 0.220 ug/L 50.00 ND 65.8 70-130 10.5 20 M

Naphthalene 33.1 10.0 ug/L 50.00 ND 66.2 70-130 2.83 20 M

Phenanthrene 33.0 10.0 ug/L 50.00 ND 66.0 70-130 0.151 20 M

Pyrene 34.1 10.0 ug/L 50.00 ND 68.2 70-130 2.61 20 M

Sunx)gate: Nitrobenzene-^5 38.6 ug/L 40.00 96.5 50-110

Sunvgate: 2-Fluorobiphenyt 28.1 ug/L 40.00 70.4 '50-104

Surrogate: Tetphenyl-dl4 28.0 ug/L 40.00 70.0 37-135


Civil & Environmental Consultants, Inc. - Toledo Lab Order: 1311442 130-998

Notes and Definitions

Surrogate result is outside of acceptance limits. The remaining number of surrogates within acceptance limits satisfies method criteria for producing valid data.

The surrogate recovery for this sample is outside of estabhshed control limits due to a sample matrix effect. '

The surrogate recovery is outside of accpetance limits high, but there were no target analytes present in the sample.

RPD outside of accepted recovery Umits.

Matrix spike and/or matrix spike duplicate recovery outside of acceptance limits.

Laboratory control sample recovery outside of acceptance limits high, sample results are below detection limits. Sample data is still acceptable.

Analyte detected below quantitation limits. Estimated concentration for TlCs.

Analyte is below detection Umits

Sample preservation was met unless otherwise noted.

I^sj?age;23;^-25n

Belmont''Labs' The tnvironme/iidi Service Company.

ANALYTICAL REQUEST CHAIN OF CUSTODY internal lab

Order Number

Purchose Order No. T Quote No. aient Project

Cofoporry

Address

5 Z/V 2> £>n ^(oxU-ku'i lof City. Store, Zip

Nume ANALYSIS REQUESTED (Enter dn "X' in the IDOA nelow to intlu .He rpquesl .ind circle pipiervniivel

Company

Mailing Address

g City, Slate-, Zip

Ptione No

tc-. Zip .

• Rush analysis required - results required by Contact Belmont Labs prior to sending rush samprles

-(Date)

Special Instructions:

Additional QC Requirements: level 2, Level 3, Level 4 ICIwrges Apply!

Regulotorv Tvoe

• NPDES • BUSTR

Collected In Stole of

CLIENT SAMPIE IDENTIFICATION Dote Sampled Time Comp Grab Moltw / / / / Only

idis-i. 3 ) ) )

V 1 AM •3-5 L e; ^ 3 %IVTZ LeU4f 3 1 \ 1 Itio 'ii'tg.ijiu OIL?! lo'lt? O /|3

rvM-zicp-r itiO Y- LM.MC 1 3 3 3 iTC-m: irD'TlSO LauLi.tk. 3 I 1 1

i/v>ln UuCJti > 1 \ 1 t'VJ-'hV: FM • 2rO^Z5"l'^ nfr<(i3 1113 < LirtjO 3 \ ( 1 1*502,^-13 9lz7h-y /sr/S" X 3 I ( 1 I'iiy 9^8 ''t^'zoLr' zsn'y HMIS 3 \ ( 1

—( 3. CHAIN

OF CUSTODY

(if lequlredl

Relinquished by:

Dote/Time ^ ^by: Dote/Ttme 8

Dote/Time 5Vo^„„êived of lot/by:

Method of Shiprnem: CoolerTemp ^ ^ Custody Seals • No

Date/Time (fjV.

Sampled by:. Date Client Comments

Belmont Labs • 25 Holiday Drive • Englewood, OH 45322 • 937.832.8242 • Fax 937.832.2868 • www.belmontlabs.com Wso/Zip . s . Ji .. ^.s • ^ i i a • '

DISTRIBUTION: WHITE - Labofolory YFII n\A/ . riwxnt


Sample Receipt Summary

1311442

Client; Civil & Environmental Consultants, Inc. - Toledo

'roject: Stickney-Tyler GW Monitoring

Project Manager; Taryn Mancine

Project Number: 130-998

teport To: Jicholas Boland >232 Executive Parkway, Suite 1 roledo OH 43606 'hone: (419) 724-5281 ax:

Receipt Temp (C): 4.0 VO Due Date; 10/11/2013 5:00:00PM Custody Seals True

TAT (Days): 10 Container Intact True

deceived By: Scott Pander COC/Labels agree True

deceived By: Scott Pander Received on ice True

leceived: 9/27/2013 9:20:00AM VOC vials had zero head space False

.ogged In By: Peggy Whitaker Approved Container True .ogged In By: Peggy Whitaker Sufficient volume received True

ogged In: 9/27/2013 2:47:00PM Received within NT True

Shipped By: FedEx

imples Received:

aboratory ID: Field ID: Date/Time Sampled: Matrix:

311442-01 130-998:MW-35LP:Z092513 9/25/2013 10:52:00AM Leachate

311442-02 130-998:MW-33LP:Z092513 9/25/2013 1:32:00PM Leachate

311442-03 130-998:MW-21LP + MS/MSD:Z092513 9/25/2013 4:10:00PM Leachate


311442-05 130-998:Duplicate:Z092513 9/25/2013 1:32:00PM Leachate

311442-06 130-998:FB-1:Z092513 9/25/2013 5:13:00PM. Water


311442-08 130-998:MW-30LP:Z092513 9/25/2013. 7:15:00PM Leachate

ample Notes:

APPENDIX B-2: TYLER STREET LANDFILL AND STICKNEY AVENUE LANDFILL SENTINEL WELLS


Monday, October 28, 2013

Analytical Results

e EnvironraiOTtal Si^

Nicholas Boland

Civil & Environmental Consultants, Inc. - Toledo 3232 Executive Parlovay, Suite 105 Toledo, OH 43606

TEL: (419)724-5281

FAX -

RE: 130-998 Work Order: 1311474

Belmont Labs received 13 sample(s) on 9/27/2013 for the analyses presented in the following report.

Belmont Labs attests that all analytical methods were performed using acceptable methods, and that the QA/QC procedures stipulated in these methods were followed.

If you have any questions regarding the test results, please feel free to call me at (937) 832-8242.

Respectfully submitted.

TTxrvxiprv

Taryn Mancine

Project Manager

Certifications: NELAP/NELAC - #04130 VAP - #CL0032

Ohio EPA Drinking water - #836 Ohio EPA Drinking water (Micro) - #872

25 Holiday Drive * Englewood, Ohio 45322 * 1.937.832.8242 * 1.937.832.2868 Fax


CLIENT: Civil & Environmental Consultants, Inc. - Toledo Lab Order: 1311474 Project: 130-998


**Tlie results of analyses performed on the following samples submitted to Belmont Labs are found in this report.**



SW 8081

SW 8082

SW 8270C

30-998:MW-31LP+MS/MSD:Z0926i: 1311474-02 Leachate EPA 245.1

SW 8081

SW 8082

SW 8270C


SW 8081

SW 8082

SW 8270C


SW 8081

SW 8082

SW 8270C


SW 8081

SW 8082

SW 8270C

130-998:Duplicate:Z092613 1311474-06 Leachate EPA 245.1

SW 8081

SW 8082

SW 8270C

130-998: FB-2;Z092613 1311474-07 Water EPA 245.1

SW 8081

SW 8082

SW 8270C


ENT: ]ect:


Lab Order: 1311474


**The results of analyses performed on the following samples submitted to Belmont Labs are found in this report.**


130-998:MW-23LP:Z092713 1311474-08 Leachate

130-998:MW-21 LP:Z092713 1311474-09 Leachate

130-998:MW-19LP:Z092713 1311474-10 Leachate

130-998;MW-36LP:Z092613 1311474-11 Leachate

130-998;MW-37LP:Z092613 1311474-12

130-998:18-1 :W092613 1311474-13

Leachate

Water

EPA 245.1

SW 8081

SW 8082

SW 8270C

EPA 245.1

SW 8081

SW 8082

SW 8270C

EPA 245.1

SW 8081

SW 8082

SW 8270C

NA

SW 8082

SW 8260B

NA

SW 8082

SW 8260B

SW 8260B


CLIENT: Project:


Lab Order: 1311474

Lab ID: 1311474-01 Collection Date: 9/26/2013 3:21:00PM Client Sample ID: 130-998:MW-33LP:Z092613 Matrix: Leactiate



Mercury BDL 0.0000243 0.000200 mg/L 1 1340235 10/4/2013 1I:30:OOAM 10/8/2013 3:30:00PM


4.4'-DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55;OOAM 10/9/2013 2:42:00AM

Aldiin BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:5S:00AM 10/9/2013 2:42:00AM

Heptachlor BDL 0.0181 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 2:42:00AM

Surrogate: DecachlorobiphenyJ 48.0% S-04 55-135 1340047 10/1/2013 8;55:00AM 10/9/2013 2:42:00AM

Surrogate: TetracMoro-m-xylene 61.0% 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 2:42:00AM


Aroclor 1016 BDL 0.238 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 2:42i)0AM

Aioclor 1221 BDL 0.124 0.500 ug/L 1 1340048 10/1/2013 S:58:OOAM 10/9/2013 2:42:00AM

Aroclor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 2:42:00AM




Aroclor 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:5S:00AM 10/9/2013 2:42:00AM

Surrogate: Decachlowbiphenyl 48:0 % 48-146 1340048 10/1/2013 8:58;00AM 10/9/2013 2:42:00AM

Surrogate: Tettachloro-m-xylene 61.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 2:42:00AM


Acenaphtbene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM

Benz(a)anthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM


Benzo(b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:I8:OOPM

Benzo(k)fluoraTithene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18rOOPM

Chrysenc BDL 0,0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18;OOPM

Indeno( 1,2.3-cd)pyrcne BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18;OOPM



Surrogate: Nitrobenzene-d5 84.9 %, 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM

Surrogate: 2-Fluoiobipheny! 81.0% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM

Surrogate: Teiphenyl-dJd 73.7% 37-135 1340044 9/30/2013 3:50:00PM 10/9/2013 3:18:00PM


ENT: ject:


Lab Order: 1311474

I) ID: 1311474-02 lent Sample ID: 130-998:MW-31 LP+MS/MSD:Z092613




:uiy BDL 0.0000243 0.000200 mg/L 1 1340235 10/4/2013 11:30:00AM 10/8/2013 3:30:00PM


DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 3:07:00AM

in BDL 0.0168 0.0500 ug/L i 1340047 10/1/2013 8:55:00AM 10/9/2013 3:07:00AM

achlor BDL 0.0181 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 3:07:00AM

}gate: DecachhrobiphenyJ 39.0% S-04 55-135 1340047 10/1/2013 8:55:00AM 10/9/2013 3:07:00AM

tgole: TelracMoro-m-xylene 51.0% 30-125 1340047 10/1/2013 8:5S:00i4M 10/9/2013 3:07:00AM

t_8082 SW 8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:07:00AM

lor 1221 BDL 0.124 0.500 ug/L 1 . 1340048 10/1/2013 8:58:00AM tO/9/2013 3:07:00AM

lor 1232 BDL 0.232 0.500 tig/L 1 1340048 10/1/2013 8:58:00i4M 10/9/2013 3:07:00AM

lor 1242 BDL 0.233 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:07:00AM

lor 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:07:00AM

lor 1254 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:07:00AM

lor 1260 BDL 0.249 0.500 ugiT. 1 1340048 10/1/2013 8:58.00AM 10/9/2013 3:07:00AM

gate: Decachlorobiphenyl 39.0% S-QC 48-146 1340048 10/1/2013 8:5g:OOAM 10/9/2013 3:07:00AM

gate: Tebachloro-m-xylene 51.0% 28-127 1340048 10/1/2013 8:S8:00AM 10/9/2013 3:07:00AM


iphtheue BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:.50:00PM 10/4/2013 12:29:00AM

»aiithracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

>(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

>(b)fluoraiithene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50.00PM 10/4/2013 12:29:00AM

>(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

«ne BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

iz{a,h)anthracene BDL 0.0742 0.200 ug/L 1 .1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

>(l,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

Jialene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

e BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

jate: Nitrobenzene-dS 83.1 % 50-110 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

late: 2-Ftuowbiphenyt 64.3% 50-104 1340044 9/30/2013 3:50:00PM 10/4/2013 12:29:00AM

late: TetphenyI-dI4 65.2% 37-135 1340044 9/.302013 3:50.00PM 10/4/2013 12:29:00AM

Belmont Labs Date; 10/28/2013

CLIENT: Project:


Lab Order: 1311474


1311474-03 130-998:M W-29LP:Z092613


Analysis Result MDL PQL Qual Units Dihuion Batch Date Prepared Date Analyzed

HG EPA 245.1 Analyst; TL

Mercury 0.000154 0.0000243 0.000200 J mg/L 1 1340235 10/4/2013 11;30:00AM 10/8/2013 3:30:00PM

PEST_8081 SW 8081 Analyst: KSW

4.4-DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 3:32:00AM

Aldrin BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013. 3:32:00AM

Heptachlor BDL 0.0181 0.0500 ug/L I 1340047 lQ/1/2013 8:55:00AM 10/9/2013 3:32:00AM

Surrogate: Decachlorobiphenyl 22.0% S-04 55-755 1340047 10/1/2013 8:55:00AM 10/9/2013 3:32:00AM

SwTogate: Telrachloro-m-xylene 37.0 % 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 3:32«)AM




Aioclor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:32:00AM

Aroclor 1242 BDL 0.233 0.500 ug/L I 1340048 10/1/2013 8:58:00AM 10/9/2013 3:32:00AM

Aroclor 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58;00AM 10/9/2013 3:32:00AM



Surrogate: Decachhiobiphenyl 22.0% S-QC 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 3:32:00AM

Surrogate: Tebochioro'tn-xylene 37.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 3:32:00AM


Acenaphtheiie BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Benz(a)anthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 I2:57:OOAM

Benzo(a)pyrene BDL 0.0820 0.200 ug/L I 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Benzo(b)fluorantheDe BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

BeDZo(k)iluoranthene BDL , 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Chrysene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Dibenr(a,h)anthracene BDL 0.0742 0.200 ugT- 1 1340044 9/30/2013 3:.50:O0PM 10/4/2013 12:57:00AM

Indeno( 1,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Naphthalene 11.4 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50;00PM 10/4/2013 12.57:00AM

Pyrene BDL 0.0613 10.0 ug/L I 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00AM

Sunogate: Sitrobenzene-dS 83.9% 50-110 1340044 9/30/2013 3:50;00PM 10/4/2013 12:57:00AM

Sttirogate: 2-Fluotobiphenyl 58.2% 50-104 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57:00Ahl

StiiTOgale: Terphenyl-dl4 54.1 % 37-135 1340044 9/30/2013 3:50:00PM 10/4/2013 12:57.00AM


lENT: ]ect:


Lab Order: 1311474

t>ID: lent Sample ID:

1311474-04 130-998;MW-27LP:Z092613

Collection Date: 9/26/2013 6;59:00PM Matrix: Leachate



nny BDL 0.0000243 0.000200 mg/L 1 1340235 10/4/2013 li:30:00AM 10/8/2013 3:30:00PM


DDT BDL 0.0217 0.0500 ug/L I 1340047 10/1/2013 8:55:00AM 10/9/2013 3:57:00AM

in BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 3:57;00AM

achlor BDL 0.0181 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 3:57:00AM

)gate: Decachtorobiphenyl 33.0% S'04 55-135 1340047 10/1/2013 S:55:00AM 10/9/2013 3:57:00AM

tgate: Tetrachloro-m-xylene 46.0% 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 3:57;00AM

:_8082 SW8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

lor 1221 BDL 0.124 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

lor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

or 1242 BDL 0.233 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

or 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

or 1254 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

or 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

gate: Decachlorobipheny! 33.0% S'OC 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 3:57:00AM

gate: Tebachioro-m-xylene 46.0% 28-127 1340048 10/1/2013 8:58;00AM iO/9/2013 3;57;00AM'


iphthene 2.31 0.0350 lO.O J ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 3:44:00PM

a)antliracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM


>(b)fluotanthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM

>(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3;50:00PM 10/9/2013 3:44;OOPM

rne BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM

z(a,h)anthraceiie BDL 0.0742 0.200 ug/L ] 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM

>(1,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:OOPM

halene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:O0PM 10/9/2013 3;44:00PM

BDL 0.0613 10.0 ug/L I 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM

fare; Nitrobenzene-dS 85.2% 50-110 1340044 9/30/2013 3:50;00PM 10/9/2013 3:44:00PM

late: 2-Fluoiobiphenyl 73.9% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 3:44:00PM

late: Terphenyl-dl4 65.8% 37-135 1340044 9/30/2013 3.50:00PM 10/9/2013 3:44:00PM


CLIENT: Project:


Lab Order: 1311474

Lab ID; Client Sample ID:

1311474-05 130-998;MW-25LP:Z092613




Mercury BDL 0.0000243 0.000200 mg/L 1 1340235 10/4«0!3 11:30:00AM 10/8/2013 3:30:00PM


4.4'-DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 4:22:00AM

Aldrin BDL 0.0168 0.0500 ugA. 1 1340047 10/1/2013 S:55:OOAM 10/9/2013 4:22:00AM


SwTogate: Decachhrobiphenyl 25.0% S-04 55-135 1340047 10/1/2013 8:55:00AM 10/9/2013 4:22:00AM

SwTogale: Telrachloro-m-xylene 48.0% 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 4:22:00AM


Aroclor 1016 BDL 0.238 0.500 ugA, 1 1340048 10/1/2013 8:58:00AM 10/9/2013 4:22d)0AM

Aroclor 1221 BDL 0.124 0.500 ug/L 1 1340048 . 10/1/2013 8:58:00AM 10/9/2013 4:22:00AM






Surrogate: DecacMombipheny! 25.0% S-QC 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 4:22:00AM

Sunogate: Tetrachhro-m-xyiene 48.0 % 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 4:22:00AM

PAH_8270 SW8270C Analyst: KSW

Acenaphthene 1.49 0.0350 10.0 J ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Beiiz(a)anlhracene BDL 0.0840 0.260 ugA. 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Benzo(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50.00PM 10/9/2013 4:10:00PM

Ben2o(b)fluotanthene BDL 0.0527 0.170 ugA, 1 1340044 9/30/2013 3:50:00PM 101/9/2013 4:10:00PM

Benzo(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Chiysene BDL 0.0625 10.0 ug/L 1 . 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10.00PM

Dibenz(a,h)anthracene BDL 0.0742 ' 0.200 ugA, 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Indeno( 1,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM


Pyrene BDL 0.0613 10.0 ugA, 1 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Surrogate: Nitrobenzene-d5 85.9 % 50-110 1340044 9/3iy2013 3:50:00PM 10/9/2013 4:10:00PM

Surrogate: 2-FluorobiphenyI 66.2 % 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 4:10:00PM

Surrogate: Terphenyl-dI4 63.0% 37-135 1340044 9/30/2013 3:50.00PM l(ro/2013 4:10:00PM


ENT: Ject:


Lab Order: 1311474

blD: lent Sample ID:

1311474-06 130-998:Duplicate;Z092613


ilysis Result MDL PQL .Qua! Units Dilution Batch Date Prepared Date Analyzed


:uiy BDL 0.0000243 0.000200 mg/L 1 1340235 10/4/2013 lt:30:00AM 10/8/2013 3:30:00PM


DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:S5:OOAM 10/9/2013 4:48:00AM

ID BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 4:48:00AM

achlor BDL 0.0181 0.0500 ug/L I 1340047 10/1/2013 8;55:00AM 10/9/2013 4:48:00AM

jgale: Decachlorobiphenyl 37.0% S-04 55-135 1340047 10/1/2013 8:55:00AM 10/9/2013 4:48:00AM

)gater Tetrachhro-m-xylene 51.0% 30-125 1340047 10/1/2013 8:55:00A^^ 10/9/2013 4:48:00AM

l_8082 SW8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340048 10/1/2013 8;58:00AM 10/9/2013 4:48:00AM

lor 1221 BDL 0.124 0.500 ug/L I 1340048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

lor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

lor 1242 BDL 0.233 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

lor 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

lor 1254 BDL 0.1% 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

lor 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:58;00AM 10/9/2013 4:48:00AM

gale: Decachlorobiphenyl 37.0% s-oc 48-146 1$40048 10/1/2013 8:58:00AM 10/9/2013 4:48:00AM

gale: Tebachloro-m-xylene 51.0% 28-127 1340048 10/1/2013 8:58:00AM JO/9/2013 4;48:00AM

1_8270 SW 8270C Analyst: KSW

iphtbcDe BDL 0.0350 J 0.0 ug/L 1 1340044 9/30/2013 3i50:00PM 10/10/2013 3:47:00PM

:a)anthracene BDL 0.0840 0.260 ug/L I 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

>(a)pyrene BDL 0.0820 0.200 ug/L I 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

>(b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3;50;00PM 10/10/2013 3:47:00PM

j(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3;50:00PM 10/10/2013 3:47:00PM

lene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

rz(a,h)antliracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

o( 1.2.3-cd)pyrene BDL 0.0566 0.220 ug/L I 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

lhalenc BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3;50:00PM 10/10/2013 3:47;00PM

e BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

gale: NUrobenzene-dS 85.3% 50-110 . 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47;00PM

gate: 2-Fluorobiphenyl 80.9% 50-104 1340044 9/30/2013 3:50:00PM 10/10/2013 3;47:00PM

gale: Teiphenyl-dI4 70.6% 37-135 1340044 9/30/2013 3:50:00PM 10/10/2013 3:47:00PM

llSPageii9jj^:53gisl


CLIENT: Project:


Lab Order: 1311474

Lab ID: 1311474-07 Collection Date: 9/26/2013 7;42:00PM Client Sample ID: 130-998:FB-2:Z092613 Matiix: Water



Mercury BDL 0.0000243 0.000200 mg/L 1 1340235 IQ/4/2013 11:30:00AM 10/8/2013 3:30;00PM

PEST_8081 SW 8081 Analyst: KSW

4,4'-DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM iO/9/2013 5:13:00AM

Aldiin BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 5:13:D0AM


Smrogate: Decachlorobiphenyl 49.0% S-04 55-135 1340047 10/1/2013 8:55:00AM 10/9/2013 5:13:00AM

SwTOgate: Tetrachloro-m-xylene 62.0% 30-125 1340047 I0/I/2013 8:55:00AM 10/9/2013 5;13:00AM

PCB_8082 SW 8082 Analyst; KSW

Aroclor 1016 BDL 0.238 0..500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:13:00AM

Aroclor 1221 BDL 0.124 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:13;00AM

Aroclor 1232 BDL 0.232 0.500 ug/L 1 1340048 I0/I/2013 8:58:00AM 10/9/2013 5:13:00AM


Aroclor 1248 BDL 0.147 0..500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:13;00AM

Aroclor 1254 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5;13:00AM


Surrogate: Decachlowbipheny! 49.0% 48-146 1340043 IQ/1/2013 8:58:00AM 10/9/2013 5:13:00AM

Surrogate: Tetrachhro-m-xy!me 62.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 5:13:00AM


Acenaphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Benz(a)anthracrae BDL 0.0840 0.260 ug/L 1 1340044 9/30^2013 3:50:00PM 10/10/2013 4:56:00PM

Beii2o(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM iO/iaôn 4:56;00PM

Benzo(b)fluoTanthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Benzo(k)fluoiranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Chryscnc BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ug.! 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

lndeno( 1.2.3-cd)p)Tene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Naphthalene ' BDL .0.0651 lO.p ug/L 1 1340044 9/30/2013 3:50:0DPM 10/10/2013 4:56:00PM


Surrogate: Nitrobenzene-d5 90.6% 50-110 1340044 9/30/2013 3:50:00PM 10/ia'2013 4:56;00PM

SwTogate: 2-FIuorobiphenyl 91.8% 50-104 1340044 9/30/2013 3:50:00PM 10/10/2013 4:56:00PM

Surrogate: Tetphenyl-dM 98.6% 37-135 1340044 9/30/2013 3;50:OOPM 10/10/2013 4:56:00PM

I'ylâgellQjbf^


ENT: iect:


Lab Order: 1311474

blD: ent Sample ID:

1311474-08 130-998:MW-23LP:Z092713


ilysis Result MDL PQL Qual Units Diltuion Batch Date Prepared Date Analyzed


iny BDL 0.0000243 0.000200 mg/L 1 1340235 10/4/2013 11:30:00AM 10/8/2013 3:30:00PM


DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:53:00AM 10/9/2013 5:38:00AM

n BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/7013 5:38:00AM

ichlor BDL 0.0181 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 5:38:00AM

gale; DecachlorobiphenrI 42.0% S-04 55-735 1340047 10/1/2013 8:53:00AM 10/9/2013 5:38:00AM

'gate: Tetrachioro-m-xyiene 55.0% 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 5:38:00AM

;_8082 SW 8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ugA. 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

lor 1221 BDL 0.124 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

lor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

lor 1242 BDL 0.233 0.500 ug/L 1 1340048 lO/t/2013 8:58:00AM 10/9/2013 5:38:00AM

lor 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58.00AM 10/9/2013 5:38:00AM

or 1254 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

or 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

gale: Decachlorobiphenyl 42.0% S-QC 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM

gate: Tebachloro-m-xylene 55.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 5:38:00AM


iphthcne 2.27 0.0350 10.0 J ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

a)anthniccne BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM


•(b)fluoranthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 109/2013 5:27:00PM

'(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

ene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

z(aji)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

j(l,2,3-cd)pyrene BDL 0.0566 0.220 ug/L 1 1340044 9/30/2013 3:50:00PM 109/2013 5:27:00PM

balene BDL 0.0651 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50.00PM 10/9/2013 5:27:00PM

\ate: Nitrobenzene-d5 79.0% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

late: 2-Ftuofobiphenyl 67.2% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 5:27:00PM

late: Terphenyl-dI4 59.9% 37-135 1340044 9/30/2013 3:.50:00PM 10./9/2013 5:27:00PM


CLIENT: Project:


Lab Order: 1311474


1311474-09 130-998:MW-21 LP:Z092713

Collection Date: 9/27/2013 11:21;00AM Matrix: Leachate

Analysis Result MDL PQL Qual . Units Dilution Batch Date Prepared Date Analyzed

HG EPA 245.1 Analyst: XL

Merciny BDL 0.0000243 0.000200 mg/L 1 1340235 I(V4/2013 11:30:00AM 10/8/2013 3:30:00PM


4,4'-DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 6:03:00AM

Aldrin BDL 0.0168 0.0500 ugA, 1 1340047 10/1/2013 8:55:00AM 10/9/2013 6:03:00AM

Heplachlor BDL 0.0181 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 6:03:00AM

Surmgate: DecacMombiphenyl 33.0% S-04 55-135 1340047 10/1/2013 8:55:00AM 10/9/2013 6:03:00AM

Sinrogate: Tetrachhro-m-xylene 24.0% S-04 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 6:03:00AM


Aiocloi 1016 BDL 0.238 0.500 ug/L 1 1340048 10/1/2013 8:58dlOAM 10/9/2013 6:03:0(1AM


Aioclor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:03:00AM




Aroclor 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:03:00/lM

Surrogate: DecacMorobiphenyt 33.0% S-04 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 6:03:00AM

Surrogate: Tebochloro-m-xylene 24.0% S-04 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 6:03.00AM


Acenaphtbene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM

Benz(a)anthrBcene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 1(V9/2013 5:54:00PM


Benzo(b)fluotanthene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 1(V9/2013 5:54:00PM

Benzo(k)fluoianthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM

Chrysenc BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM

Dibenz(a,h)anthracene BDL 0.0742 0.200 ugA. 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM

Indeno( 1,2,3-cd)pyrene BDL 0.0566 0.220 ugA. 1 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM


Pyrene BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50;00PM 10/9/2013 5:54:00PM

Surrogate: Nitrobenzene-d5 88.6% 50-110 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM

Sunogate: 2-Fluoiobiphenyl 67.3% 50-104 1340044 9/30/2013 3:50:00PM 10/9/2013 5.54:00PM

Surrogate: Teiphenyl-dl4 60.6% 37-135 1340044 9/30/2013 3:50:00PM 10/9/2013 5:54:00PM


ENT: iect:


l^b Order: 1311474

t>ID: lent Sample ID:

1311474-10 130-998:M W-19LP:Z092713




-Tiry 0.000149 0.0000243 0.000200 J mg/L 1 1340235 10/4/2013 11:30:00AM 10/8/2013 3:30:00PM

T_8081 SW 8081 Analyst: KSW

DDT BDL 0.0217 0.0500 ug/L 1 1340047 10/1/2013 8:55:00AM 10/9/2013 6:28:00AM

D BDL 0.0168 0.0500 ug/L 1 1340047 10/1/2013 g:55:OOAM 10/9/2013 6:28:00AM

ichlor BDL 0.0181 0.0500 ugA. 1 1340047 10/1/2013 8:55:00AM 10/9/2013 6:28:00AM

gale: Decachlorobiphenyl 24.0% S-04 55-735 1340047 10/1/2013 8:55:00AM 10/9/2013 6:28:00AM

gale: Telrachloro-m-xylene 34.0% 30-125 1340047 10/1/2013 8:55:00AM 10/9/2013 6:28:00AM

:_8082 SW8082 Analyst: KSW

lor 1016 BDL 0.238 0.500 ug/L 1 1340048 I0'l/2013 8:58:00AM 10/9/2013 6:28:00AM

lor 1221 BDL 0.124 0.500 ugA. 1 1340048 I0/I/2013 g:.S8:00AM 10/9/2013 6:28:00AM

lor 1232 BDL 0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM

or 1242 BDL 0.233 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM

lor 1248 BDL 0.147 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM

or 1254 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM

or 1260 BDL 0.249 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM

gale: Decachlorobiphenyl 24.0% S-QC 48-146 I34004S 10/1/2013 8:5S:OOAM 10/9/2013 6:28:aOAM

gale: Tebachloro-m-xylene 34.0% 28-127 134004S 10/1/2013 8:58:00AM 10/9/2013 6:28:00AM


iphthene BDL 0.0350 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:.53:00W»1

a)onthracene BDL 0.0840 0.260 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

)(a)pyrene BDL 0.0820 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

<(b)fluoraiithene BDL 0.0527 0.170 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

(k)fluoranthene BDL 0.0574 1.70 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

ene BDL 0.0625 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

z(aji)anthracene BDL 0.0742 0.200 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

j(1.2,3-cd)pyrene BDL 0.0566 0.220 ugA. 1 1340044 9/30/2013 3.50:00PM 10/4/2013 2:53:00PM

lhalene 19.7 0.0651 10.0 ugl. 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

: BDL 0.0613 10.0 ug/L 1 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

'ale: Nitrobemene-d5 93.7% 50-110 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM

'file: 2-Fluowbiphenyl 77.6% 50-104 1340044 9/30/2013 3:50.00PM 10/4/2013 2:53:00PM

'file: Terphenyl-dl4 68.2% 37-135 1340044 9/30/2013 3:50:00PM 10/4/2013 2:53:00PM


CLIENT: Project:


Lab Order: 1311474


1311474-11 130-998:MW-36LP:Z092613




Arocloi 1016 BDL 0.238 0.500 ug/L 1 1340048 I(V1/2013 8:58:00AM 10/9/2013 11:56:00AM

Aroclor 1221 BDL 0.124 0.500 ug/L 1 1340048 10/1/2013 8:S8:00AM 10/9/2013 11:56:00AM

Aroclor 1232 BDL 0.232 0.500 ug/L 1 1340048 ip/1/2013 8:58:00AM 10/9/2013 11:56:00AM

Aroclor 1242 BDL 0.233 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM IQ/9/20I3 11:56:00AM

Aroclor 1248 BDL 0.147 0.500 ug/L I 1340048 10/1/2013 8:58:00AM 10/9/2013 H:56;00AM



Surrogate: Decachlorobiphenyl • 19.0% S-QC 48-146 1340048 10/1/2013 S:58:00AM 10/9/2013 11:56:00AM

Surrogate: Tetrachtoro-m-xylene 64.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 11:56:00AM

VOC8260 SW 8260B Analyst: EAU

1,1,1,2-Tetrachloroelliane BDL 0.213 5.00 ug/L I 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53;00PM

1,1,1-Trichloroetliane BDL 0.233 5.00 ugA. 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53;00PM

1,1,2,2-Tetrachloroethane BDL 0.234 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1;53:00PM

1,1,2-Trichloroethane ' BDL 0.223 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53;OOPM

1,1 -Dichloroethane BDL 0.258 5.00 ug/L I 1341092 10/7/2013 8;45:00AM 10/7/2013 l:53:OOPM

l.l-Dichloroethene BDL 0.344 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM \Onnon 1:53:OOPM

1,1 -Dichloropropene BDL 0.246 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

1,2-Oibramoethane BDL 0.217 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

1,2-Dichloroethane BDL 0.178 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

1,2-Dichloropropane BDL 0.287 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1;53:00PM

1,3-Dichloropropane BDL 0.268 5.00 ug/L ! 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

2,2-Dichloropropane BDL 0.288 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

2-Bmanone BDL 0.393 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

2-Chlorotoluene BDL 0.204 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

2-Hexanone BDL 0.427 20.0 ug/L I 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:0GPM

4-Chlorotoluene BDL 0.235 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

4-Methyl-2-pentanone BDL 0.694 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1;53:00PM

Acetone 14.9 2,52 20.0 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Acetonltrile 37.7 0.280 40.0 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1;53:00PM

Acrolein BDL 0.505 20.0 ug/L \ 1341092 10/7/2013 8:45:00AM 10/7/2013 l:53;OOPM

Acrylonitrile BDL 0.294 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 l:53;OOPM

Allyl chloride BDL 0.257 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Benzene 20.1 0.261 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Bromobenzene BDL 0.190 5.00 ug/L 1 1341092 10/7/2013 8;45:00AM 10/7/2013 1:53:00PM

Bromochloromethane BDL 0.284 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Bromodichloromethane BDL 0.272 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM lOn/2013 1:53:00PM

Bromofonn BDL 0.295 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Bromomethane BDL 0.315 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM '10/7/2013 i:53.00PM

Carbon Disulfide BDL 0.401 20.0 ug/L 1 1341092 10/7/2013 8:45;OOAM 10/7/2013 1:53:00PM

Carbon Tetrachloride BDL 0.291 5.00 ug/L 1 1341092 lOn/2013 8:45:00AM 10/7/2013 1:53:00PM

Ig?!?agej:i^;8f53

Imont Labs

ENT: ]ect:

Date: 10/28/2013


Lab Order: 1311474

bID: ent Sample ID:

1311474-11 130-998:MW-36LP;Z092613

Collection Date: 9/26/2013 10;04;00AM Matrix: Leachate

lysis Result MDL PQL Qual Units Diliuion Batch Date Prepared Date Analyzed

robenzcne 8.17 0.243 5.00 ug/L 1 1341092 lonnon 8:45i00AM 10/7/2013 1:53:00PM

roclhane 14.8 0.247 5.00 ug/L 1 1341153 10/9/2013 9:42:00AM 10/9/2013 5:06:00PM

oform BDL 0.268 5.00 ug/L 1 1341092 10^/2013 8:45;00AM 10/7/2013 1:53:00PM

omethane BDL 0.332 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

2-Dichloroethene BDL 0.284 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

3-DichloropropeDe BDL 0.258 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

mochloromethane BDL 0.231 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

momethane BDL 0.291 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

orodifluoromethane BDL 0.214 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

Lbenzene 736 0.227 5.00 ug/L 1 1341092 iO/7/2013 8:45:00AM 10/7/2013 1:53:00PM

lethane BDL 0.266 10.0 ug/L I 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

ylene Chloride BDL 0.187 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

KI tert-Butyl Elber 2.21 0.246 10.0 J ug/L 1 I34I092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

ITylene 24.9 0.430 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

(ane BDL 1.34 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10^/2013 1:53:00PM

Icne 131 0.248 5.00 J ug/L 1 1341092 10/7/2013 8:45;00AM 10/7/2013 1:53:00PM

le BDL 0.222 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

:hloroethene BDL 0.304 5.00 ug/L 1 1341092 10/7/2013 8;45:00AM 10/7/2013 1:53;00PM

oe BDL 0.221 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

1,2-Dichloroethene BDL 0.237 5.00 ug/L 1 I34I092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

1.3-Dichloropropene BDL 0.215 5.00 ug/L I 1341092 10/7/2013 8:45:D0AM 10/7/2013 1:53;00PM

loroethene BDL 0.260 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53;OOPM

lorofluoromethane BDL 0.220 5.00 ug/L 1 1341092 10/7/2013 8;45:00AM 10/7/2013 1:53:00PM

Chloride BDL 0.228 1.00 ug/L 1 1341092 10/7/2013 8:45:00AM 101/7/2013 1:53:00PM

acetate BDL 0.221 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

late: 4-BromoJluorobenzene 90.0% 66-125 134115S 10/9/2013 9:42:00AM 10/9/2013 5:06:00PM

late: 4-Bmmqfluombenzene ' 105% 66-125 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

late: Dibrotnojluotvmethane 119% 75-130 1341092 10/7/2013 8:45;00AM 10/7/2013 1;53:00PM

late: Dibtvmqfluoirtmethane 84.8% 75-130 1341153 10/9/2013 9;42:00AM 10/9/2013 5:06:00PM

late: Toluene-dS 112% 76-131 1341092 10/7/2013 8:45:00AM 10/7/2013 1:53:00PM

late: Toluene-dS 87.1 % 76-131 1341153 10/9/2013 9:42:00AM 10/9/2013 5.06:00PM

late: ] ,2-Dichloroethane-d4 97.2% 75-124 1341153 10/9/2013 9:42:00AM 10/9/2013 5:06:OOPM

late: 1,2-Dichloroethane-d4 110% 75-124 1341092 10/7/2013 8:45:00AM 10/7/2013 l:53:OOPM

C_TIC NA Analyst: KSW

hylaniline Negative ug/L 1 1340005 9/30/2013 9:08;00AM 10/1/2013 4:08:OOAM


CLIENT: Project:


Lab Order: 1311474


1311474-12 130-998:MW-37LP:Z092613




Aroclor 1016 BDL 0.238 0..500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM


Aroclor 1232 BDL .0.232 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM


Aroclor 1248 BDL 0.147 0..500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM

Aroclor 12S4 BDL 0.196 0.500 ug/L 1 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM

Aroclor 1260 48.0 2.49 5.00 ug/L 10 1340048 10/1/2013 8:58:00AM 10/10/2013 1:44:00PM

Surrogate: Decachlorobiphenyt 24.0% S-QC 48-146 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM

Surrogate: Tetrachloro-rrr-jcylene 52.0% 28-127 1340048 10/1/2013 8:58:00AM 10/9/2013 12:22:00PM

VOC 8260 SW8260B Analyst: EAH

1,1,1,2-Tetrachloroetliane BDL 0.213 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1,1,1-Trichloroetliaoe BDL 0.233 5.00 ug/L 1 1341092 10/7/2013 8:45:00/tM 10/7/2013 2:32:00PM

1,1,2,2-Tenachloroethane BDL 0.234 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1,1,2-Trichloroethane BDL 0.223 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1,1-Dlcliloroelhanc S.62 0.258 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1,1 -Dichloroethene BDL 0.344 5.00 ug/L ' 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1,1 -Dichloropropene BDL 0.246 5.00 ug/L 1 1341092 10/7/2013 8.45:00AM 10/7/2013 2:32:00PM

1,2-Dibromoethane BDL 0,217 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

1.52 0.178 5:oo J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM


1,3-Dichloropropane BDL 0.268 5.00 ug/L 1 1341092 1(^7/2013 8:45:00AM 10/7/2013 2:32:00PM


2-Butanone 32.7 0.393 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

2-Chlorotolucne BDL 0.204 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

2-Heianone 5.81 0.427 20.0 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

4-Chlorotoluene BDL 0.235 5.00 ug/L • 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

4-M«thyl-2-pentanone 46.6 0.694 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Acetone 30.8 2.52 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Acetonltrile 19.1 0.280 40.0 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Acrolein BDL 0.505 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Acrylonitrile BDL 0.294 20.0 ug/L • 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Allyl chloride BDL 0.257 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Benzene 137 0.261 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Bromobenzene BDL 0;190 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Bromochloromethane BDL 0.284 5.00 ug^ i 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Bromodichloromethane BDL 0.272 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Bromofonn BDL 0.295 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Bromomethane BDL 0.315 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Caihon Disuinde BDL 0.401 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Carbon Tetrachloride BDL 0.291 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM


ENT: lect:


Lxib Order: 1311474

a ID: ent Sample ID:

1311474-12 130-998:M W-37LP:Z092613



robenzene 18.2 0.243 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

oethane BDL 0.247 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

[)fonn BDL 0.268 5.00 ug/L 1 1341092 10^7/2013 8:4S:00AM 10/7/2013 2:32:00PM

omethane BDL 0.332 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

VDicUoroelhene 1.41 0.284 5.00 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2;32:00PM

B-Dichloropropene BDL 0.258 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

mochloromethane BDL 0.231 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

momethane BDL 0.291 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

3rodifluoromethane BDL 0.214 5.00 ug/L I 1341092 10/7/2013 8:45:00AM 10/7/2013 2;32:00PM

benzene 1120 11.4 250 ug/L 50 1341146 10/8/2013 8:33:00AM 10/8/2013 4:22:00PM

lethane BDL 0.266 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

|/lenc Chloride 1.63 0.187 5.00 J ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

ten-Butyl Ether BDL 0.246 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

yiene 5380 21.5 500 ug/L 50 1341146 10/8/2013 8:33:00AM 10/8/2013 4:22:00PM

me BDL 1.34 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

me 2630 12.4 250 ug/L 50 1341146 10/8/2013 8:33:00AM 10/8/2013 4:22:00PM

le BDL 0.222 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

hloroethene BDL 0.304 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

ne 114 0.221 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

•1,2-DlcUoroethene 2.63 0.237 5.00 J ug/L 1 1341092 10/7/2013 8:45:00AM I0/7/20I3 2:32:00PM

1,3-Dichloropropenc BDL 0.215 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

oroethene BDL 0.260 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

srofluoromethane BDL 0.220 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

Chloride 2.40 0.228 1.00 ug/L 1 1341092 10/7/2013 8:45:D0AM 10./7/2013 2:32:00PM

acetate BDL 0.221 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

\ote: 4-Bromofluorobenzene 97.4% 66-125 1341146 10/8/2013 8:33;00AM 10/8/2013 4:22:00PM

ate: 4-BwmoJluorobenzene 151 % S-04 66-125 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

ate: Dibromofluowmethane 109% 75-130 1341146 10/8/2013 8:33:00AM 10/8/2013 4:22:00PM

ate: Dibromofluoiximethane 114% 75-130 1341092 10/7/2013 8;45;00AM 10/7/2013 2:32:00PM

ate: Toluene-d8 112% 76-131 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

ate: ToIuene-d8 109% 76-131 1341146 10/8/2013 8:33:00AM 10/8/2013 4:22:00PM

ate: i.2-Dichloroethane-d4 102% 75-124 1341146 10/8/2013 8.33:00AM 10/8/2013 4:22:00PM

ate: 1,2-Dichhroethane-d4 109% 75-124 1341092 10/7/2013 8:45:00AM 10/7/2013 2:32:00PM

;_Tic NA Analyst: KSW

lylaniline Negative ug/L 1 1340005 9/30/2013 9:08:00AM lO/i/2013 4:35:00AM


CLIENT: Project:


Lab Order: 1311474

Lab ID: 1311474-13 Collection Date: : 9/26/2013 10:04:00AM Client Sample ID: 130-998:TB-1:W092613 Matrix: : Water

Analysis Result MDL PQL Qual Units DUiuion Batch Date Prepared Date Analyzed

VOC 8260_TB SW 8260B Analyst: EAH

1,1.1,2-Tetrachloioethare BDL 0.213 5.00 tig/L 1 1341092 10/7/2013 8;45:00AM 1077013 3:48:00PM

1,1,1 -Trichloroelhane BDL 0.233 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

1,1,2,2-Tetrachlorocthane BDL 0.234 5.00 ug/L 1 1341092 10/7/2013 S:45:00AM 1077013 3:48:00PM

1,1,2-Tncbloroethane BDL 0.223 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

1,1-Dichloroethane BDL 0.258 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

1,1-Dichloroetliene BDL 0.344 5.00 ug/L 1 1341092 1(V7/2013 8:45:00AM 107/2013 3:48:00PM

1,1 -Dichloropropene BDL 0.246 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

1,2-Dibromoetliane BDL 0.217 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

1,2-Dichloroethane BDL 0.178 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

1,2'Dicbloropropane BDL 0.287 500 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3;48:00PM

1,3-Dichloropropane BDL 0.268 5.00 ug/L 1 1341092 107/2013 8:45;00AM 10/77013 3:48;00PM

2,2-Dicbloropropane BDL 0.288 5.00 u^ 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

2-Butanonc BDL 0.393 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3;48:00PM

2-Cblorotoluene BDL 0.204 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

2-Hexanone BDL 0.427 20.0 ug/L 1 1341092 10/7/2013 8:45;00AM 1077013 3:48:00PM

4-Chlorotoluene BDL 0.235 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/77013 3:48:00PM

4-Metbyl-2-pentanont BDL 0.694 20.0 ug/L 1 1341092 107/2013 8:45:00AM 1077013 3:48:00PM

Acetone BDL 2.52 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

Acetonitrile BDL 0.280 40.0 ug/L 1 1341092 10/7/2013 8;45:00AM 1077013 3:48:00PM

Acrolein BDL 0.505 20.0 ug/L 1 1341092 107/2013 8:45:00AM 107/2013 3:48:00PM

Acrylonitrile BDL 0.294 20.0 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

Allyl chloride BDL 0.257 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/77013 3:48:00PM

Benzene BDL o:26i 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3;48:OOPM

Bromobenzene BDL 0.190 5.00 ug/L 1 1341092 107/2013 8:45;00AM 10/7/2013 3:48:00PM

Bromocblorometbane BDL 0.284 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

Bromodicblorometbane BDL 0.272 5.00 ug/L 1 1341092 107/2013 8;45:00AM 10/7/2013 3:48:00PM

Bromofoim BDL 0.295 5.00 ug/L 1 1341092 107/2013 8:45:00AM 107/2013 3:48:00PM

Bromometbane BDL 0.315 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107 7013 3:48:00PM

Carbon Disulfide BDL 0.401 20.0 ug/L 1 1341092 107/2013 8:45:00AM 107/2013 3:48:00PM

Carbon Terrachloride BDL 0^291 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/77013 3;48:00PM

Cblorobenzene BDL 0.243 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

Cbloroetbane BDL 0.247 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

Cblororoim BDL 0.268 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

Chloromethane BDL 0.332 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48;00PM

cis-1,2-Dicbloroethene BDL 0.284 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 1077013 3:48:00PM

cis-1,3-Dichloropropenc BDL 0.258 5.00 ug/L 1 1341092 107/2013 8:45:00AM 107/2013 3:48:00PM

Dibromocbloromethane BDL 0.231 5.00 ug/L 1 1341092 1077013 8:45:00AM 1077013 3:48:00PM

Dibromometbane BDL 0.291 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3;48:00PM

Dicblorodifluorometbane BDL 0.214 5.00 ug/L 1 1341092 10/7/2013 8:45:OOA^^ 1077013 3:48:00PM

Etbylbenzene BDL 0.227 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

lodometbane BDL 0.266 10.0 ug/L I 1341092 10/7/2013 8:45:00AM 10/77013 3:48:00PM

Methylene Chloride BDL 0.187 5.00 ug/L 1 1341092 107/2013 8:45:00AM 1077013 3:48:00PM

inont Labs Date: 10/28/2013

NT: set:


Lab Order: 1311474

ID: 1311474-13 Collection Date: 9/26/2013 10;04;OOAM nt Sample ID: 130-998:TB-1:W092613 Matrix: Water

ysis Result MDL PQL Qual Units Dilution Batch Date Prepared Date Analyzed

'1 tcrt-Butyl Ether BDL 0.246 10.0 . ug/L 1 1341092 10/7/2013 8:45:D0AM 10/7/2013 3:48:00PM

/lene 1.16 0.430 10.0 J ug/L 1 1341092 10/7/2013 8:4S:ODAM 10/7/2013 3:48:00PM

me BDL 1.34 5.00 ug/L 1 1341092 10/7/2013 8:45;00AM 10/7/2013 3:48;00PM

me BDL 0.248 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

e BDL 0.222 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

hloroethene BDL 0.304 5.00 ug/L 1 1341092 10/7/2013 8:45;00AM 10/7/2013 3:48:00PM

le BDL 0.221 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 107/2013 3:48:00PM

1,2-Dichloroethene BDL 0.237 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48:00PM

1,3-Dichloropropcne BDL 0.215 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48:00PM

oroethene BDL 0.260 5.00 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48:00PM

orofluoromethane BDL 0.220 5.00 ug/L 1 1341092 10/7/2013 8;45:00AM 10/7/2013 3:48:00PM

Chloride BDL 0.228 1.00 ug/L 1 1341092 10/7/2013 8:45:D0AM 10/7/2013 3:48:00PM

acetate BDL 0.221 10.0 ug/L 1 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48;00PM

ja/e: 4'B/vmoJIifOfvben2ene 100% 66-125 1341092 10/7/2013 8:45;00AM 10/7/2013 3;48:00PM

âte: Dibwmqfluoromethane 108% 75-130 1341092 10^7/2013 8:45;00AM 10/7/2013 3:48:00PM

••ate: ToIuene-d8 110% 76-131 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48:00PM

\ate: 1.2-Dichlowethane-d4 102% 75-124 1341092 10/7/2013 8:45:00AM 10/7/2013 3:48:00PM


CLIENT: Civil & Environmental Consultants, Inc. - Toledo Lab Order: Project: 130-^8

1311474

Mercury Analysis - Quality Control

Analyte Result

Rqwrting

Limit Units

Spike Source %REC


RPD

RPD Limit Notes

Batch 1340235-PREP HG W

Blank (1340235-BLKl) Prepared; 10/04/13 Analyzed: 10/08/13

Mercury BDL 0.000200 mg/L

LCS(1340235-BS1) Prepared: 10/04/13 Analyzed: 10/08/13

Mercury 0.00647 0.000200 mg/L 0.006250 104 80-120


Mercury 0.00630 0.000200 mg/L 0.006250 101 80-120 3 20

Matrix Spike (134023S-MS1) Source; 1311474-02 Prepared: 10/04/13 Analyzed: 10/08/13

Mercury 0,00642 0.000200 mg/L 0.006250 ND 103 70-130


Mercury 0.00642 0.000200 mg/L 0.0062.50 ND 103 70-130 0 30


ENT: ]ect:


Lab Order: 1311474


Reporting Spike . Source %REC RPD

lyte Result Limit Uitits Level Result %REC Limits RPD Limit Notes

rh 1340047-PREP PP W

k (1340047-BLKl) Prepared; 10/01/13 Analyzed: 10/09/13

ODD HDL 0.0500 ug/L

DDE HDL 0,0.500 ug/L

DDT BDL 0.0500 ug/L

in HDL 0.0500 ug/L

i-BHC BDL 0.0500 ug/L

i^Thlordane BDL 0.0500 ug/L

BHC BDL 0.0500 ug/L

rdane BDL 0.500 ug/L ' BHC BDL 0.0500 ug/L

rin BDL 0.0500 ug/L

sulfan I BDL 0.0500 ug/L

Îfan n BDL 0.0500 ug/L

sulfan sulfate BDL 0.0500 ug/L

LD BDL 0.0500 ug/L

in aldehyde BDL 0.0500 ug/L

in ketone BDL 0.0500 ug/L

la-BHC BDL 0.0500 ug/L

la-Chlordane BDL 0.0500 ug/L

ichlor BDL 0.0500 ug/L

ichlor epoxide BDL 0.0500 ug/L

oxychlor BDL 0.0500 ug/L

}hene BDL 0.500 ug/L

gate: Decachlorobiphenyl 0.990 ug/L I.OOO 99.0 5S-13S

gate: Tetrachlotv-m-xytene 0.800 ug/L 1.000 80.0 30-125


)DD 0.570 0.0500 ug/L 0.5000 114 67-123

IDE 0.500 0.0500 ug/L 0.5000 100 64-118

»DT 0.550 0.0500 ug/L 0.5000 110 67-135

1 0.450 0.0500 ug/L 0.5000 90.0 52-103

BHC 0.500 0.0500 ug/L 0.5000 100 60-131

Cblordane 0.500 0.0500 ug/L 0.5000 100 62-117

iHC 0.570 0.0500 ug/L 0.5000 114 62-115

BHC 0.550 0.0500 ug/L 0.5000 110 64-126

in 0.570 ' 0.0500 ug/L 0.5000 114 64-127

lulfan I 0.390 0.0500 ug/L 0.5000 78.0 48018

ulfan n 0.410 0.0500 ug/L 0.5000 82.0 .50-128

ilfan sulfate 0.680 0.0500 ug/L 0.5000 136 53-164

1 0.630 0.0500 ug/L 0.5000 126 60-137

1 aldehyde 0.730 0.0500 ug/L 0.5000 146 61-137 L

1 ketone 0.650 0.0500 ug/L 0.5000 130 67-142

a-BHC 0.550 0.0500 ug/L 0.5000 110 65-116

a-Chlordane 0.500 0.0500 ug/L 0.5000 100 70-110

thlor 0.500 0.0500 ug/L 0.5000 100 43-126

:hlor epoxide 0.550 0.0500 ug/L 0.5000 iio 6.5-118


CLIENT: Project:


Lab Order: 1311474

Organocblorine Pesticides by EPA Method 8081 - Quality Control

Reporting Spike ' Source %REC RPD

Analytc Result Limit Units Level Result %REC Limits RPD Limit Notes


LCS (1340047-BSl) Prepared; 10/01/13 Analyzed: 10/09/13

Methoxychlor 0.820 0.0500 ug/L 0.5000 164 52-161 L

Surrogate: Decachlorobipheny! 1.02 ug/L 1.000 102 55-135

Surrogate: Tetrachloio-m-xylene 0.810 ug/L 1.000 81.0 30-125


4,4-DDD 0.650 0.0500 ugO. 0..5000 130 67-123 13.1 10 L,R

4,4'-DDE 0.530 0.0500 ug/L .0.5000 106 64-118 5.83 10

4,4-DDT 0.590 0.0500 ug/L 0:5000 llg 67-135 7.02 10

Aldnn 0.470 0.0500 ug/L 0.5000 94.0 52-103 4.35 17

alpha-BHC 0.480 0.0500 ug/L 0.5000 96.0 60-131 4.08 11

alpha-Chlordane 0.530 0.0500 ug/L 0.5000 106 62-117 5.83 10

beta-BHC 0.540 0.0500 ug/L 0.5000 108 62-115 5.41 11

delta-BHC 0.530 0.0500 ug/L 0.5000 106 64-126 3.70 11

Dieldiin 0.610 0.0500 ug/L 0.5000 122 64-127 6.78 10

Endosulfan I 0.410 0.0500 ug/L 0.5000 82.0 48-118 5.00 10

Endosulfan n 0.430 0.0500 ug/L 0.5000 86.0 .50-128 4.76 10

Endosulfan sulfate 0.750 0.0500 ug/L 0..5000 150 53-164 9.79 12

Endrin 0.670 . 0.0500 ug/L 0.5000 134 60-137 6.15 10

Endrin aldehyde 0.810 0.0500 ug/L 0.5000 162 61-137 10.4 10 L,R

Endrin ketone 0.730 0.0500 ug/L 0.5000 146 67-142 11.6 10 L, R

gamma-BHC 0.520 0.0500 ug/L 0.5000 104 6.5-116 5.61 10

gamma-Chlordane 0.520 0.0500 ug/L 0.5000 104 70-110 3.92 10

Heptachlor 0.520 0.0500 ug/L 0.5000 104 43-126 3.92 12

Heptachlor epoxide 0.560 0.0500 ug/L 0:5000 112 65-118 1.80 10

Methoxychlor 0.790 0.0500 ug/L 0.5000 1.58 52-161 3.73 10

Sunogate: Decachlombiphenyl O.PJO ug/L 1.000 95.0 55-135

Surrogate: Tetrachloro-m-xylene 0.770 ug/L 1.000 77.0 30-125


ENT: lect;


loib Order: 1311474


Reporting Spike Source %REC RPD

yte Result Limit Units Level Result %REC Limits RPD Limit Notes


rix Spike (1340047-MSl) Source 1311474-02 Prepared; 10/01/13 Analyzed: 10/09/13

DDD 0.460 0.0500 ug/L 0.5000 ND 92.0 70-130

DDE 0.300 0.0500 ug/L 0.5000 ND 60.0 70-130 M

DDT 0.400 0.0500 ug/L 0.5000 ND 80.0 70-130

0.350 0.0.500 ug/L 0.5000 ND 70.0 70-1.30

-BHC 0.370 0.0500 ug/L 0.5000 ND 74.0 70-130

-Chlordane 0.340 0.0500 ug/L 0.5000 ND 68.0 0-200

BHC 0.660 0.0500 ug/L 0.5000 ND 132 70-130 M

BHC 0.410 0.0500 ug/L 0.5000 ND 82.0 70-130

'lin 0.450 0.0500 ug/L 0.5000 ND 90.0 70-130

sulfan I 0.290 0.0500 ug/L 0.5000 ND 58.0 70-1.30 M

suICan II 0.320 0.0500 ug/L 0.5000 ND 64.0 70-130 M

sulEin sulfate 0.640 0.0500 ug/L 0.5000 ND 128 70-130

in 0.510 0.0500 ug/L 0.5000 ND 102 70-130

n aldehyde 0.480 0.0500 ug/L 0.5000 ND 96.0 70-1.30

in ketone \ 0.600 0.0500 ug/L 0.5000 ND 120 0-200

la-BHC 0.410 0.0.500 ug/L 0.5000 ND 82.0 70-1.30

na-Chlordane 3.61 0.0500 ug/L 0.5000 ND 722 0-200 M

ichlor 0.720 0.0500 ug/L 0.5000 ND 144 70-130 M

ichlor epoxide 0.440 0.0500 ug/L 0.5000 ND 88.0 70-1.30

oxychlor 0.710 0.0500 ug/L 0.5000 ND 142 0-200

gate: Decochlorobiphenyl 0.520 ug/L 1.000 52.0 55-135 M

gate: Telrachloro-m-xylene 0.600 ug/L 1.000 60.0 30-125

[ix Spike Dup (1340047-MSDl) Source: 1311474-02 Prepared: 10/01/13 Analyzed: 10/09/13

JDD 0.430 0.0500 ug/L 0.5000 ND . 86.0 70-130 6.74 25

)DE 0.290 0.0500 ug/L 0.5000 ND 58.0 70-130 3.39 25 M

)DT 0.360 0.0500 ug/L 0.5000 ND 72.0 70-130 10.5 25

t 0.340 0.0500 ug/L 0.5000 ND 68.0 70-130 2.90 25 M

BHC 0.360 0.0500 ug/L 0.5000 ND 72.0 70-130 2.74 25

Chlordane 0.330 0.0500 ug/L 0.5000 ND 66.0 0-200 2.99 200

IHC 0.630 0.0500 ug/L 0.5000 ND 126 70-130 4.65 25

BHC 0.390 0.0500 ug/L 0.5000 ND 78.0 70-1.30 5.00 25

•in 0.430 0.0500 ug/L 0.5000 ND 86.0 70-1.30 4.55 25

nlfan I 0.280 0.0500 ug/L 0.5000 ND 56.0 70-130 3.51 25 M

iulfan n 0.300 0.0500 ug/L 0.5000 ND 60.0 70-1.30 6.45 25 M

iulfan sulfate 0.600 0.0500 ug/L 0.5000 ND 120 70-130 6.45 25

1 0.480 0.0500 ug/L 0.5000 ND 96.0 70-130 6.06 25

1 aldehyde 0.430 0.0500 ug/L 0.5000 ND 86.0 70-130 11.0 25

1 ketone 0.550 0.0500 ug/L 0.5000 ND 110 0-200 8.70 200

a-BHC 0.400 0.0500 ug/L 0.5000 ND 80.0 70-130 2.47 25

a-Chlordane 0.340 0.0500 ug/L 0.5000 ND 68.0 0-200 166 200

chlor 0.690 0.0500 ug/L 0.5000 ND 138 70-130 4.26 25 M

:hlor epoxide 0.440 0.0500 u^ 0.5000 ND 88.0 70-1.30 0.00 25

xychlor 0.640 0.0500 ug/L 0.5000 ND 128 0-200 10.4 200

"flte: Decachlombiphenyl 0.460 ug/L 1.000 46.0 55-135 M


CLIENT: Civil & Environmental Consultants, Inc. - Toledo Project: 130-998

Lab Order: 1311474


Reporting Analyte Result Limit Units

Spike Source %R£C Level Result %R£C Limits

RPD RPD Limit Notes



Sunx>gate: Tetrachloro-m-xytene 0.590 ug/L 1.000 59.0 30-125

Imont Labs

ENT: iect:

Date: 10/28/2013


Lab Order: 1311474

Polychlorinated Biphenyis by EPA Method 8082 - Quality Control

yte Result

Reporting

Limit Units

Spike Source %REC

Level Result %REC Limits RPD

RPD

Limit Notes

;h 1340048-PREP PP W

k (1340048-BLKl) Prepared: 10/01/13 Analyzed: 10/03/13

lorI0I6 BDL 0.500 ug/L

lor 1221 BDL 0.500 ug/L

lor 1232 BDL 0.500 ug/L

lor 1242 BDL 0.500 ug/L

lor 1248 BDL 0.500 ug/L

lor 1254 BDL 0.500 ug/L

lor 1260 BDL 0.500 ug/L

gate: DecacMorobiphenyl


1.59

0.750

ug/L

ug/L

1.000 159 48-146

1.000 75.0 28-127

S-QC


lor 1016 5.00 0..500 ug/L 5.000 100 69-138

lor 1260 5.30 0.500 ug/L 5.000 106 70-131


gate: Tetrachlom-m-xylene

1.47

0.760

ug/L

ug/L

1.000 147 48-146

1.000 76.0 28-127

S-QC

Dup(1340048-BSD1) Prepared: 10/01/13 Analyzed: 10/03/13

Jor 1016 5.26 0.500 ug/L 5.000 105 69-138 5.07 14

or 1260 5.87 0.500 ug/L 5.000 117 70-131 10.2 19


gate: TetracMoro-m-xylene

1.63

0.800

ug/L

ug/L

1.000 163 48-146

1.000 80.0 28-127

S-QC

rii Spike (1340048-MSl) Source: 1311474-02 Prepared: 10/01/13 /Analyzed: 10/09/13

or 1016 6.93 0.500 ug/L 5.000 ND 139 41-163

or 1260 4.18 0.500 ug/L 5.000 ND 83.6 50-111

gate: Decachlombiphenyl

gate: Tetracbloro-m-xylene

0.620

0.620

ug/L

ug/L

I.OOO

1.000

62.0

62.0

48-146

28-127


CLIENT: Project:


Lab Order: 1311474


Analyte

Repoiting

R«ull Limit Units

Spike Sniiree

Level Result %REC

%REC

Limits RPD

RPD

Limit Notes



Aroclor 1016 10.3 0.500 ug/L 5.000 ND 205 41-163 38.8 17 M.R

Aroclor 1260 4.49 0.500 ug/L 5.000 ND 89.8 50-111 7.15 22

Sunogate: Decachlombiphenyl

Surrogate: Tetrachloro-m-xylene

0.430

0.590

ug/L

ug/L

I.OOO 43.0

1.000 59.0

48-146

28-127

M

IME*agg;26-6p3


ENT: Ject:


loib Order:

Volatile Organic Compounds by EPA Method 8260B - Quality Control

1311474

lytc

;h 1341092-VOC PREP

ik (1341092-BLKl)

Result Rcponiug

Limit Units Spike Level.

Source Result %REC

%REC RPD Limits RPD Limit Notes

Prepared & Analyzed: 10/07/13

.2-Tetrachloroethane BDL 5:00 ug/L

,2-Tetracliloroethane BDL 5.00 ug/L

-Trichloroethane BDL 5.00 ug/L

-Trichloroethane BDL 5.00 ug/L

.2-Tetrachloroethaiie BDL 5.00 ug/L

2-Tetrachloroethane BDL 5.00 ug/L

•Trichloroethane BDL 5.00 ug/L

Trichloroethane BDL 5.00 ug/L

tichloroethane BDL 5.00 ug/L


tichloroetheue BDL 5.00 ug/L

Hchloroethene BDL 5.00 ug/L

tichloropropene BDL 5.00 ug/L

Hchloropropene BDL 5.00 ug/L

tibromoetliane BDL 5.00 ug/L

iibromoethane BDL 5.00 ug/L



tichloropropane BDL 5.00 ug/L






anone BDL 20.0 ug/L

auone BDL 20.0 ug/L

orotoluene BDL 5.00 ug/L


lanone BDL 20.0 ug/L

tanone BDL 20.0 ug/L



hyl-2-pentanone BDL 20.0 ug/L

hyl-2-pentanone BDL 20.0 ug/L

ne BDL 20.0 ug/L

ne BDL 20.0 ug/L

nitrile BDL 40.0 ug/L

'Uitrile BDL 40.0 ug/L

tin BDL 20.0 ug/L

tin BDL 20.0 ug/L

rnitrile BDL 20.0 ug/L

rnitrile BDL 20.0 ug/L

chloride BDL 5.00 ug/L

chloride BDL 5.00 ug/L

ne BDL 5.00 ug/L


CLIENT: Project:


Lab Order: 1311474


Analyte Result

Reponing

Limit Units

Spike Source %REC

Level Result . %REC Limits RPD

RPD Limit Notes

Batch 1341092 - VOC PREP

Blank (1341092-BLKl) Prepared & Analyzed: 10/07/13

Benzene BDL 5.00 ug/L

Bromobenzene BDL 5.00 ug/L


Bromochloromethane BDL 5.00 ug/L

Bromochlorometbane BDL 5.00 ug/L

Bromodichloromethane BDL 5.00 ug/L


Bromoform BDL 5.00 ug/L

Bromofoim BDL 5.00. ug/L

Bromomethane BDL 5.00 ug/L


Carbon Disulfide BDL 20.0 ug/L


Carbon Tetrachloride BDL 5.00 ug/L

Carbon Teuachloridc BDL 5.00 ug/L

Chlorobenzene BDL 5.00 ug/L


Chloroethane BDL 5.00 ug/L

Chloroetharie BDL 5.00 ug/L

Chloroform BDL 5.00 ug/L


Chloromethane BDL 5.00 ug/L


cis-L2-Dichloroethene BDL 5.00 ug/L

cis-1,2-Dichloroethene BDL 5.00 ug/L

cis-1,3-Dichloropropene BDL 5.00 ug/L


Dibromochloromcthane BDL 5.00 ug/L

Dibromochloromethane BDL 5.00 ug/L

Dibromomethane BDL 5.00 ug/L

Dibromomethane BDL 5.00 ug/L

Dichlorodilluoromethane BDL 5.00 ug/L

Dichlorodifluoromethane BDL 5.00 ug/L

Ethylbenzene BDL 5.00 ug/L

Ethylbenzene BDL 5.00 ug/L

lodomethane BDL 10.0 ug/L


Methylene Chloride BDL 5.00 ug/L


Methyl tert-Butyl Ether BDL 10.0 ug/L


m,p-Xylene BDL 10.0 ug/L


n-Hexane BDL 5.00 ug/L

n-Hexane BDL 5.00 ug/L

liiRagejgSjbtis;


ENT: Ject:


Lab Order: 1311474


yte Result Reporting


Source Result %REC

•/oREC Limits RPD

RPD Limit Notes

ch 1341092 - VOC PREP

ik (1341092-BLK1) Prepared & Analyzed: 10/07/13

lene BDL 5.00 ug/L

lene BDL 5.00 ug/L

!ne BDL 5.00 ug/L

ne BDL 5.00 ug/L

chloroethene BDL 5.00 ug/L

chloroethcne BDL 5.00 ug/L

:ne BDL 5.00 ug/L

;ne BDL 5:00 ug/L

1,2-Dichloroethene BDL 5.00 ug/L


• 1,3-Dichloropropene BDL 5.00 ug/L

1.3-Dichloropropene BDL 5.00 ug/L

loroethene BDL 5.00 ug/L

oroethene BDL 5.00 ug/L

Jorofluoromethane BDL 5.00 ug/L

Jorofluoromethane BDL 5.00 ug/L

1 CUoride BDL 1.00 ug/L

. Chloride BDL 1.00 ug/L

1 acetate BDL 10.0 ug/L


'gate: 4-Biomo/Itiorobenzene 51.2 ug/L 50.00 102 66-125

'gale: 4-BromoJluorobenzene 51.2 ug/L 50.00 102 66-125

gate: Dibromojluorometbane 58.6 ug/L 50.00 117 75-130

gate: Dibmmofluoivmethane 58.6 ug/L 50.00 117 75-130

gate: Toluene-dS 57.0 ug/L 50.00 114 76-131

gate: Totuene-dS 57.0 ug/L 50.00 114 76-131

gate: 1.2-Dichlofoethane-d4 55.1 ug/L 50.00 110 75-124

gate: 1,2-Dich1oroethane-d4 55.1 ug/L 50.00 110 75-124


CLIENT: Project:


Lab Order: 1311474


Analyte Result

Reporting

Limit Units

Spike Source %REC

Level Result %REC - Limits

RPD

RPD Limit Notes


LCS(1341092-BS1) Prepared & Analyzed: 10/07/13

1.1.1.2-Tetrachloroetliane 21.1 ug/L 20.00 105 80-123

1,1.1.2-Tetracliloroethane 21.1 ug/L 20.00 105 80-123

1.1.1-Trichloroethane 24.3 ug/L 20.00 122 75-135

l.l.l-Trichlorocthane 24.3 ug/L 20.00 122 75-135

1.1,2.2-Tetrachloroethane 24.8 ug/L 20.00 124 76-133

1,1,2,2-Telrachloroethane 24.8 ug/L 20.00 124 76-133

1.1.2-Trichloroethanc 22.6 ug/L 20.00 113 80-124

1.1,2-Trichloroethane 22.6 ug/L 20.00 113 80-124

1,1 -Dichloroethane 23.9 ug/L 20.00 120 74-136

1.1 -Dichloroethane 23.9 ug/L 20.00 120 74-136

1.1 -Dichloroethene 23.6 ug/L 20.00 lis 61-154

1,1-Dichloroeihene 23.6 ug/L 20.00 118 61-154

1.1 -Dichloropropene 24.1 ug/L 20.00 120 78-135

1,1 -Dichloropropene 24.1 ug/L 20.00 120 78-135

1.2-Dibromoethane 20.4 ug/L 20.00 102 76-125

1,2-Dibromoethane 20.4 ug/L 20.00 102 76-125

1.2-Dichloroethane 22.3 ugA 20.00 112 74-130

1.2-Dichloroethane 22.3 ug/L 20.00 112 74-130

1,2-Dichloropropane 23.6 ug/L 20.00 118 78-126




2.2-Dichloropropane 27.6 ug/L 20.00 138 49-183


2-Butanone 41.6 ug/L 40.00 104 53-157

2-Butanone 41.6 ug/L 40.00 104 53-157

2-Chlorotoluene 23.9 ug/L 20.00 119 75-132


2-Hexanone 40.4 ug/L 40.00 101 64-147

2-Hexanone 40.4 ug/L 40.00 101 64-147



4-Methyl-2-pentanone 42.8 ug/L 40.00 107 74-133

4-Methyl-2-pentanone 42.8 ug/L 40.00 107 74-133

Acetone 36.6 ug/L 40.00 91.6 35-191

Acetone 36.6 ug/L 40.00 91.6 35-191

Acetonitrile 22.2 ug/L 20.00 111 45-166

Acetonitrile 22.2 ug/L 20.00 111 45-166

Acrolein 54.8 ug/L 40.00 137 51-186

Acrolein 54.8 ug/L 40.00 137 51-186

Acrylonitrile ,?? 5 ug/L 20.00 112 64-137

Acrylonitrile 22.5 ug/L 20.00 112 64-137

Allyl chloride 25.9 ug/L 20.00 129 60-150

Allyl chloride 25.9 ug/L 20.00 129 60-L50

Benzene 23.5 ug/L 20.00 117 81-128

Imont Labs

ENT: ject:

Date: 10/28/2013


Lab Order: 1311474


Rqwiting Spike Source %REC yte Result Litnit Units Level Result %REC Limits

rh 1341092 - VOC PREP

(1341092-BSl) Prepared & Analyzed: 10/07/13

mt 23.5 ug/L 20.00 117 81-128

obenzene 21.0 ug/L 20.00 105 83-122

lobenzene 21.0 ug/L 20.00 105 83-122

lochlcromethane 21.9 ug/L 20.00 109 81-127

lochloromethane 21.9 ug/L 20.00 109 81-127

.odichloromethane 23.5 ug/L 20.00 117 79-123

lodicblorcmethane 23.5 ug/L 20.00 117 79-123

loform 22.0 ug/L 20.00 110 59-130

lofonn 22.0 ug/L 20.00 110 59-130

omethane 20.3 ug/L 20.00 102 68-148

lomethane .20.3 ug/L 20.00 102 68-148

>n Disulfide 23.1 ug/L 20.00 116 44-162

>n Disulfide 23.1 ug/L 20.00 116 44-162

m Tetrachloride 24.0 ug/L 20.00 120 64-132

>n Tetrachloiide 24.0 ug/L 20.00 120 64-132

-obenzene 22.5 ug/L 20.00 113 82-122

obenzene 22.5 ug/L 20.00 113 82-122

oethane 24.8 ug/L 20.00 124 48-150

oethane 24.8 ug/L 20.00 124 48-1.50

oform . 24.0 ug/L 20.00 120 74-132

•ofonn 24.0 ug/L 20.00 120 74-132

omethane 19.2 ug/L 20.00 96.2 50-166

-omethane 19.2 ug/L 20.00 96.2 50-166

.2-Dichloroethene 24.0 ug/L 20.00 120 77-134

2-Dichloroethene 24.0 ug/L 20.00 120 77-134

3-Dichloropropene 23.9 ug/L 20.00 119 77-127

3-Dichloropropene 23.9 ug/L 20.00 119 77-127

mochloromethane 21.0 ug/L 20.00 105 69-123

>mochloromethane 21.0 ug/L 20.00 105 69-123

momethane 22.6 ug/L 20.00 113 82-127

imomethane 22.6 ug/L 20.00 113 82-127

orodiiluoromethane 24.0 ug/L 20.00 120 41-145

orodifluoromethane 24.0 ug/L 20.00 120 41-145

benzene 23.4 ug/L 20.00 117 82-126

benzene 23.4 ug/L 20.00 117 82-126

lethane 18.4 ug/L 20.00 92.2 .50-144

rethane 18.4 ug/L 20.00 92.2 .50-144

dene Chloride 21.1 ugd. 20.00 106 69-137

dene Chloride 21.1 ug/L 20.00 106 69-137

,'l tert-Butyl Ether 21.9 ug/L 20.00 110 73-127

d tert-Butyl Ether 21.9 ug/L 20.00 110 73-127

ylene 49.3 ug/L 40.00 123 82-131

Cylene 49.3 ug/L 40.00 123 82-131

tane 27.3 ug/L 22.64 121 41-166

tane 27.3 ug/L 22.64 121 41-166

RPD

RPD

Limit Notes


CLIENT: Project:


Lab Order: 1311474


Rcpoitiiig Spike Source %REC RPD Analyte Result Ljmit Units Level Result %REC Limits RPD Limit Notes


LCS (1341092-BSl) Prepared & Analyzed: 10/07/13 o-Xylene 22.2 ug/L 20.00 111 80-126

o-Xylene 22.2 ug/L 20.00 III 80-126

Styreue 22.2 ug/L 20.00 111 80-127

Styrene 22.2 ug/L 20.00 111 80-127

Tetrachloroethene 21.2 ug/L 20.00 106 43-152

Tetracblorocthene 21.2 ug/L 20.00 106 43-L52

Toluene 23.5 ug/L 20.00 117 84-129

Toluene 23.5 ug/L 20.00 117 84-129

trans-1,2-Dichloroethene 23.2 ug/L 20.00 116 73-132


trans-1,3-Dichloropropene 24.2 ug/L 20.00 121 80-131

trans-1.3-Dichloropropene 24.2 ug/L 20.00 121 80-131

Trichloroethene 20.2 ug/L 20.00 101 79-129


Trichlorofluoromethane 24.5 ug/L 20.00 122 64-163

Trichlorofluoromethane 24.5 ug/L 20.00 122 64-163

Vinyl Chloride 23.4 ug/L 20.00 117 61-1.57

Vinyl Chloride 23.4 ug/L 20.00 117 61-157

Vinyl aeetate 40.4 ug/L 20.00 202 36-205

Vinyl acetate 40.4 ug/L 20.00 202 36-205

Surrogate: 4'Btomofluorobenzene 51.1 ug/L 50.00 102 66-125

Sunogate: 4-Bromqfluorobenzene 51.1 ug/L 50.00 102 66-125

Sunogate: Dibtomojluoromethane 57.2 ug/L 50.00 114 75-130

Sunogate: Dibromofluotomethane 57.2 ug/L 50.00 114 75-130

Surrogate: Toluetie-tJS 53.7 ug/L 50.00 107 76-131

Surrogate: ToIuene-d8 .53.7 ug/L 50.00 107 76-131

Surrogate: 1,2-DicMo>oethane-d4 52.5 ug/L 50.00 105 75-124

Sunogate: J,2-Dichloroetbane-d4 52.5 ug/L 50.00 105 75-124

IMgeigz^pfia


ENT: 'ect:


Lab Order: 1311474


ilyte Result

Repotting

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

Limit Notes

tch 1341092-VOC PREP

SDup(1341092-BSDl) Prepared & Analyzed: 10/07/13

1,2-Tetrachloroelhane 20.2 ug/L 20.00 101 80-123 4.46 11

1,2-Tetracliloroethare 20.2 ug/L 20.00 101 80-123 4.46 II

l-TVichloroethane 23.0 ug/L 20.00 115 75-135 5.58 11

1-Trichloroethane 23.0 . ug/L 20.00 115 75-135 5.58 11

2,2-Teti:achloroethane 24.4 ug/L 20.00 122 76-133 1.79 14

2,2-T«tracliloroelhane 24.4 ug/L 20.00 122 76-133 1.79 14

2-Thchloroethane 22.4 ug/L 20.00 112 80-124 0.755 12

'-Tiichloroethanc 22.4 ug/L 20.00 112 80-124 0.755 12

Dichloroetbane 24.1 ug/L 20.00 121 74-136 0.916 12

Dichloroethane 24.1 ug/L 20.00 121 74-136 0.916 12

Dichloroethene 23.1 ug/L 20.00 115 61-154 2.44 14

Dichloroethcne 23.1 ug/L 20.00 115 61-154 2.44 14

Dichloropropene 22.7 ug/L 20.00 114 78-135 5.77 11

DicUoropropene 22.7 ug/L 20.00 114 78-135 5.77 II

Dibromoethane 19.9 ug/L 20.00 . 99.6 76-125 2.28 43

Dibromoethane 19.9 ug/L 20.00 99.6 76-125 2.28 43

Oichloroethane 22.6 ug/L 20.00 113 74-130 1.29 10

Dichloroetbane 22.6 ug/L 20.00 113 74-130 1.29 10

Dichloropropane 23.4 ug/L 20.00 117 78-126 0.938 10






tanone 43.0 ug/L 40.00 108 53-1.57 3.40 18

tanone 43.0 ug/L 40.00 108 5.3-157 3.40 18

lorotoluene 22.9 ug/L 20.00 114 75-132 4.15 43

lorotoluene 22.9 ug/L 20.00 114 7.5-132 4.15 43

xanone 40.8 ug/L 40.00 102 64-147 0.986 18

xanone 40;8 ug/L 40.00 102 64-147 0.986 18

lorotoluene 20.5 ng/L 20.00 103 80-125 5.45 11

lorotoluene 20.5 ug/L 20.00 103 80-125 5.45 II

:thyl-2-pentanone 42.0 ug/L 40.00 105 74-133 1.86 17

thyl-2-pentanone 42,0 ug/L 40.00 105 74-133 1.86 17

me 37.8 ug/L 40.00 94.4 35-191 3.04 23

me 37.8 ug/L 40.00 94.4 35-191 3.04 23

mitrile 23.4 ug/L 20.00 117 45-166 . 5.13 48

mitrile 23.4 ug/L 20.00 117 45-166 5.13 48

ein 55.8 ug/L 40!OO 139 51-186 1.74 25

ein 55.8 ug/L 40.00 139 51-186 1.74 25

lonitrile 23.4 ug/L 20.00 117 64-137 4.18 18

lonitrile 23.4 ug/L 20.00. 117 64-1.37 4.18 .18

chloride 26.1 ug/L 20.00 130 60-150 0.732 16

chloride 26.1 ug/L 20.00 130 60-1.50 0.732 16

cne 22.6 ug/L 20.00 113 81-128 3.64 10


CLIENT: Project:

Civil & Environmentai Consultants, Inc. - Toledo 130-998

Lab Order: 1311474


Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes


LCS Pup (1341092-BSDl) Prepared & Analyzed: 10/07/13 Benzene 22.6 ug/L 20.00 113 81-128 3.64 10

Bromobenzene 19.8 ug/L 20.00 98.8 83-122 5.99 11

Bromobenzene 19.8 ug/L 20.00 98.8 83-122 5.99 11

Bromochloromethane 22.2 ug/L 20.00 111 81-127 1.27 10

Bromocbloromethane 22.2 ug/L 20.00 111 81-127 1.27 10

Bromodichlorometbane 23.1 ug/L 20.00 116 79-123 1.63 10

Bromodichloromethane 23.1 ug/L 20.00 116 79-123 1.63 10

Bromoform 21.1 ug/L 20.00 10.<i 59-130 4.50 17

Biomoform 21.1 ug/L 20.00 105 59-130 4.50 17

Bromomethane 21.1 ug/L 20.00 105 68-148 3.77 17

Bromomethane 21.1 ug/L 20.00 105 68-148 3.77 17

Carbon Disulfide 22.5 ug/L 20.00 113 44-162 2.67 17

Carbon Disulfide 22.5 ug/L 20.00 113 44-162 2.67 17

Carbon Tetrachloride 22.2 ug/L 20.00 111 64-132 7.75 12

Carbon Tetrachloride 22.2 ug/L 20.00 111 64-132 7.75 12

Chlorobenzene 21.5 ug/L 20.00 . 108 82-122 4.49 10

Chlorobenzene 21.5 ug/L 20.00 108 82-122 4.49 10

Chloroethane 25.1 ug/L 20.00 126 48-150 1.40 33

Chloroethane 25.1 ug/L 20.00 126 48-L50 1.40 33

Chloroform 24.1 ug/L 20.00 121 74-132 0.624 10

Chloroform 24.1 ug/L 20.00 121 74-132 0.624 10

Chloromethane 18.6 ug/L 20.00 93.2 50-166 3.17 18

Chloromethane 18.6 ug/L 20.00 93.2 .50-166 3.17 18

cis-l,2-Dichloroethene 24.2 ug/L 20.00 121 77-134 0.995 11

cis-1,2-Dichloroethene 24.2 ug/L . 20.00 121 77-134 0.995 11

cis-l',3-Dichloropropene 23.7 ug/L 20.00 118 77-127 0.926 12

cis-1,3 -Dichloropropene 23.7 ug/L 20.00 118 77-127 0.926 12

Dibromochloromethane 20.2 ug/L 20.00 101 69-123 4.27 14


Dibromomethane 22,4 ug/L 20.00 112 82-127 1.02 11

Dibromomethane 22.4 ug/L 20.00 112 82-127 1.02 11

Dichlorodifluoromethane 22.6 ug/L 20.00 113 41-145 6.35 21

Dichlorodifluoromethane 22.6 ug/L 20.00 113 41-145 6.35 21

Ethylbenzene 22.4 ug/L 20.00 112 82-126 4.15 11

Erhylbenzene 22.4 ug/L 20.00 112 82-126 4.15 II

lodomethane 18.4 ug/L 20.00 91.8 50-144 0.380 14

lodomethane 18.4 ug/L 20.00 91.8 50-144 0.380 14

Methylene Chloride 21.1 ug/L 20.00 106 69-137 0.0947 12

Methylene Chloride 21.1 ug/L 20.00 106 69-137 0.0947 12

Methyl tert-Butyl Ether 22.3 ug/L 20.00 112 73-127 1.85 11

Methyl tert-Butyl Ether 22.3 ug/L 20.00 112 73-127 1.85 11

m.p-Xylene 46.8 ug/L 40.()0 117 82-131 5.12 11

m,p-Xylene 46.8 ug/L 40.00 117 82-131 5.12 11

n-Hexane 26.7 ug/L 22.64 118 41-166 2.26 17

n-Hexane 26.7 ug/L 22.64 118 41-166 2.26 17


!ENT: ject:


Lab Order: 1311474


Repofting Spike Source %REC RPD

Uyte Result Limit Units Level Result %REC Limits RPD Limit Notes


SDup (1341092-BSDl) Prepared & Analyzed: 10/07/13

/lene 21.1 ug/L 20.00 105 80-126 5.31 12

^lene 21.1 ug/L 20.00 105 80-126 5.31 12

ene 21.5 ug/L 20.00 108 80-127 3.38 40

21.5 ug/L 20.00 108 80-127 3.38 40

Khloroethcne 19.6 ug/L 20.00 98.0 43-152 7.75 26

achloroethene 19.6 tig/L 20.00 98.0 43-152 7.75 26

me 22.8 ug/L 20.00 114 84-129 3.03 11

ene 22.8 ug/L 20.00 114 84-129 3.03 11

'.-1,2-Dicbloroethene 22.8 ug/L 20.00 114 73-132 1.69 11

i-1.2-Dichloioethene 22.8 ug/L 20.00 114 73-132 1.69 11

•.-1,3-Dichloropropene 23.9 ug/L 20.00 119 80-131 1.29 12

t-1,3 -Dichloropropene 23.9 ug/L 20.00 119 80-131 1.29 12

jloroeihene 19.1 ug/L 20.00 95.6 79-129 5.64 12

jiloroethene 19.1 ug/L 20.00 95.6 79-129 5.64 12

Uorofluoromethane 22.8 ug/L 20.00 114 64-163 7.24 16

ilorofluoromethane 22.8 ug/L 20.00 114 64-163 7.24 16

1 Chloride 22.6 ug/L 20.00 113 61-157 3.43 17

I Chloride 22.6 ug/L 20.00 113 61-157 3.43 17

1 acetate 42.1 ug/L 20.00 210 36-205 4.00 27 L

1 acetate 42.1 ug/L 20.00 210 36-205 4.00 27 L

ogale: 4-B)X>mofluorobenzene 53.0 ug/L 50.00 106 66-125

ogate: 4-Bromo/luorobenzene 53.0 ug/L 50.00 106 66-125

ogate: Dibmmq/Juommethane 61.2 ug/L 50.00 122 75-130

ogate: Dibtvmofluoromeihane 61.2 ug/L 50.00 122 75-130

ogale: Toluene-dS 55.5 ug/L 50.00 111 76-131

ogale: Toluetie-dS 55.5 ug/L 50.00 111 76-131

ogale: 1,2-Dichloivelhone-d4 56.2 ug/L 50.00 112 75-124

ogale: ],2-Dichloroelhane-d4 56.2 ug/L 50.00 112 75-124

llsRage.î5!bpll


CLIENT: Project:


Lab Order: 1311474


Analyte Result

Reportiag

Limit Units

Spike Source %REC


RPD

RPD Limit Notes


Blank (1341146-BLKl) Prepared & Analyzed; 10/08/13

1,1,1,2-Tetrachloroetliane BDL 5.00 ug/L

1,1,1 -Trichloroethane BDL 5.00 ug/L

1,1,2,2-Tetrachloroethane BDL 5.00 ug/L

1,1,2-Trichloroethane BDL 5.00 ug/L

Ll-Dichloroethane BDL 5.00 ug/L


1,1 -Dichloropropene BDL 5.00 ug/L

1,2-Dibromoethaiie BDL 5.00 ug/L

1,2-Dicliloroetliane BDL 5.00 ug/L

1,2-DichloroprDpane BDL 5.00 ug/L

1,3-Dicliloropiopane BDL 5.00 ug/L

2,2-EHchloropropane BDL 5.00 ug/L

2-Butanone BDL 20.0 ug/L

2-Chlorotoluene BDL 5.00 ug/L

2-Hexanone BDL 20.0 ug/L


4-Methyl-2-pentanone BDL 20.0 ug/L

Acetone BDL 20.0 ug/L

Acetoniuile BDL 40.0 ug/L

Acrolein BDL 20.0 ug/L

Acrylonitrile BDL 20.0 ug/L

AUyl chloride BDL 5.00 ug/L

Benzene BDL 5.00 . ug/L







Carbon Tetrachloride BDL 5.00 ug/L


Chloroethane BDL 5.00 ug/L



cis-1,2-Dichloroethene BDL 5.00 ug/L


Dibromochloromethane BDL 5.00 ug/L

Dibromomethane BDL . 5.00 ug/L

Dichlorodifluoromethane BDL 5.00 ug/L

Etbylbenzene BDL 5.00 ug/L





n-Hexane BDL 5.00 ugA.

ICf^ge^jpftSc


ENT: lect:


Lab Order: 1311474


•yte Result Repotting

Limit Units Spike. Level

Souice Result %REC

%REC Limits RPD

RPD Limit Notes

ch 1341146 - VOC PREP

Bk (1341146-BLK1) Prepared & Analyzed: 10/08/13

dene BDL .5.00 ug/L

-lie BDL 5.00 ugd.

ichloroethene BDL 5.00 ug/L

ene BDL 5.00 ugd-

;-l,2-Dichloroelhene BDL 5.00 ug/L

1-1.3-Dichloropropene BDL 5.00 ug/L

tloroethene BDL 5.00 ugd-

ilorofluoromethane BDL 5.00 ug/L

1 Chloride BDL 1.00 ug/L


ogale: 4-BivmoJliiombenzene 49.2 ug/L 50.00 98.5 66-125

ogale: Dibwmqfluoromelhane 55.8 ug/L 50.00 112 75-130

ogate: Tohiene-dS 55.1 ug/L 50.00 110 76-131

ogate: J,2'Dichloroethane~d4 53.0 ug/L 50.00 106 75-124

5(1341146-881) Prepared & Analyzed; 10/08/13

,2-Tetiachloroethane 20.4 ug/L 20.00 102 80-123

-Trichloroethane 23.1 ugJL 20.00 115 75-135

' ,2-Tetrachloroethane 23.7 ug/L 20.00 . 119 76-133

-Trichloroethane 22.6 ug/L 20.00 113 80-124

lichloroethane 23.0 ug/L 20.00 115 74-136

tichloroethene 22.1 ug/L 20.00 III 61-154

lichloropropene 22.6 ug/L 20.00 113 78-135

tibromoethane 19.7 ug/L 20.00 98.5 76-125

lichloroethane 21.2 ug/L 20.00 106 74-130

tichloropropane 22.7 ug/L 20.00 114 78-126

Hchloropropane 22.7 ug/L 20.00 113 80-127

tichloropropane 25.8 ug/L 20.00 129 49-183

tanone 43.1 ug/L 40.00 108 53-157

lorotoluene 22.5 ug/L 20.00 112 75-132

xanone 42.8 ug/L 40.00 107 64-147

lorotoluene 20.7 ug/L 20.00 104 80-125

;thyl-2-pentanone 45.1 ug/L 40.00 113 74-133

rne 40.2 ug/L 40.00 100 3.5-191

mitrile 23.2 ug/L 20.00 116 45-166

lein 55.4 ug/L 40.00 138 51-186

loninile 22.0 ugd. 20.00 110 64-1.37

chloride 24.4 ug/L 20.00 122 60-150

:ne 22.6 ug/L 20.00 113 81-128

obenzene 20.4" ug/L 20.00 102 83-122

ochloromethane 21.6 ug/L 20.00 108 81-127

odichloromethane 22.7 ug/L 20.00 113 79-123

oform 21.5 ug/L 20.00 107 59-130

omethane 21.6 ug/L 20.00 108 68-148

>n Disulfide 21.0 ug/L 20.00 105 44-162


CLIENT: Project:


l^b Order: 1311474


Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes


LCS(1341146-BSI) Prepared & Analyzed: 10/08/13 Carbon Tetrachloride 22.5 ug/L 20.00 112 64-132

Chlorobenzene 21.6 ug/L 20.00 108 82-122

Chloroetbane 25.1 ug/L 20.00 126 48-150

Chloroform 23.4 ug/L 20.00 117 74-132

Chioromethane 19.6 ug/L 20.00 98.2 50-166

cis-1,2-Dichlotoethene 23.1 ug/L 20.00 116 77-134

cis-1,3-Dichloropropene 23.2 ug/L 20.00 116 77-127

Dibromochloromethane 20.4 ug/L 20.00 102 69-123

Dibromomethane 22.0 ug/L 20.00 110 82-127

Dichlorodifluoromethane 23.3 ug/L 20.00 117 41-145

Ethylbenzene 22.0 ug/L 20.00 110 82-126

lodomethanc 19.2 ug/L 20.00 96.2 50-144

Methylene Chloride 20.7 ug/L 20.00 104 69-137

Methyl tert-Butyl Ether 21.5 ug/L 20.00 108 73-127

m,p-Xylene 46.1 ug/L 40.00 115 82-131

n-Hexane 25.2 ug/L 22.64 111 41-166

o-Xylene 21.1 ug/L 20.00 106 80-126

Styrene 21.2 ug/L 20.00 106 80-127

Tetrachloroethene 20.1 ug/L 20.00 101 43-152

Toluene 22.9 ug/L 20.00 114 84-129


trans-1,3-Dichloropropene 23.3 ug/L 20.00 117 80-131


Trichlorollnoromethane 23.4 ug/L 20.00 117 64-163

Vinyl Chloride 23.0 ug/L 20.00 115 61-L57

Vinyl acetate 34.8 ug/L 20.00 174 36-205

Surrogate: 4-BiomofIuorobenzeue 51.2 ug/L 50.00 102 66-125

Sunogate: Dibromqfluoromethane 59.6 ug/L 50.00 119 75-130

Sunogale: Toluene-dS 55.6 ug/L 50.00 111 76-131

Surrogate: I.2-Dichloioethane-d4 55.4 ug/L 50.00 111 75-124

Imont Labs Date; 10/28/2013

ENT: lect:

Civil & Environmental Consultants, inc. - Toledo . 130-998

Lab Order: 1311474


lytc Result

Reporting

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

Limit Notes

[rh 134114<i-VOCPREP

Dnp (134114«-BSD1) Prepared & Analyzed: 10/08/13

,2-Tetrachloroelhane 19.9 ug/L 20.00 99.4 80-123 2.29 11

-Trichloroethane • 21.8 ug/L 20.00 109 75-1.35 5.39 11

.2-Tetrachloroethane 23.1 ug/L 20.00 115 76-133 2.82 14

-Trichloroethane 21.6 ug/L 20.00 108 80-124 4.56 12

)ichloroethane 21.4 ug/L 20.00 107 74-136 7.56 12

Hchloroethene 20.7 ug/L 20.00 104 61-154 6.67 14

lichloropropene 21.9 ug/L 20.00 110 78-135 3.14 11

Hbromoethane 19.4 ug/L 20.00 97.0 76-125 1.59 43

tichloroethane 19.4 ug/L 20.00 97.0 74-130 8.91 10

tichloropiopane 21.7 ug/L 20.00 109 78-126 4.41 10

tichloropropane 21.3 ug/L 20.00 107 80-127 6.13 11

hchloropropane 24.3 ug/L 20.00 121 49-183 5.99 13

lanone 38.1 ug/L 40.00 95.3 53-157 12.3 18

lorotoluene 22.4 ug/L 20.00 112 75-1.32 0.580 43

xanone 38.2 ug/L 40.00 95.6 64-147 11.4 18

lorotoluene 20.8 ug/L 20.00 104 80-125 0.337 11

;thyl-2-pentanone 41,8 ug/L 40.00 104 74-133 7.62 17

jne 34.3 ug/L 40.00 85.8 35-191 15.7 23

snitrile 19.7 ug/L 20.00 98.6 45-166 16.0 48

lein 51.3 ug/L 40.00 128 51-186 7.74 25

lonitrile 20.2 ug/L 20.00 101 64-137 8.91 18

chloride 24.0 ug/L 20.00 .120 60-150 1.40 16

me 22.4 ug/L 20.00 112 81-128 0.934 10

obenzene 20.0 ug/L 20.00 99.8 83-122 2.03 11

ochloromethane 22.0 ug/L 20.00 110 81-127 1.60 10

odichloromethane 21.3 ug/L 20.00 106 79-123 6.37 10

oform 20.4 ug/L 20.00 102 .59-1.30 5.01 17

omethane 19.4 ug/L 20.00 96.8 68-148 11.0 17

>n Disulfide 21.8 ug/L 20.00 109 44-162 3.88 17

>0 Tetrachloride 21.7 ugT, 20.00 108 64-132 3.62 12

•obenzene 21.7 ug/L 20.00 108 82-122 0.323 10

'oethane 22.6 ug/L 20.00 113 48-150 10.3 33

'oform 21.9 ug/L 20.00 110 74-132 6.49 10

omethane 20.2 ug/L 20.00 101 50-166 3.01 18

2-Dichloroethene 21.1 ug/L 20.00. 106 77-134 9.18 11

3-Dichloropropene 22.0 ug/L 20.00 110 77-127 5.31 12

mochloromethane 19.7 ug/L 20.00 98.4 69-123 3.79 14

momethaue 21.3 ug/L 20.00 106 82-127 3.37 11

orodifluoromethane 20.8 ug/L 20.00 104 41-145 11.6 21

jenzene 22.0 ug/L 20.00 110 82-126 0.0455 11

lethane 19.6 ug/L 20.00 98.2 50-144 2.11 14

r'lene Chloride 20.8 ug/L 20.00 104 69-1.37 0.337 12

fl tert-Butyl Ether 19.4 ug/L 20.00 97.1 73-127 10.3 11

yleue 46.1 ug/L 40.00 115 82-1.31 0.0434 11

ine 25.2 ug/L 22.64 111 41-166 0.198 17


CLIENT: Project:


Lab Order: 1311474


Reporting' Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes


LCS Dup (1341146-BSDl) Prepared & Analyzed: 10/08/13

o-Xylcne 21.2 ug/L 20.00 106 80-126 0.425 12

Styrere 21.0 ug/L 20.00 10.S 80-127 0.902 40

Tetrachloroethene 20.4 ug/L 20.00 102 43-152 1.43 26

Toluene 22.6 ug/L 20.00 113 84-129 1.23 11

nans-1,2-Dichloroethene 22.2 ug/L 20.00 111 73-132 0.588 11

tram-1,3-Dichloropropene 21.9 ug/L 20.00 110 80-131 6.28 12

Trichloroethene 20.3 ug/L 20.00 102 79-129 1.19 12

Trichlorofluoromethane 21.0 ug/L 20.00 105 64-163 10.6 16

Vinyl Chloride 21.3 ug/L 20.00 107 61-157 7.36 17

Vinyl acetate 33.4 ug/L 20.00 167 36-205 4.22 27

Surrogate: 4-Bmmofluorobenzene 49.4 ug/L 50.00 98.9 66-125

Surrogate: DibromoJIuotomethane 56.1 ug/L 50.00 112 75-130

Sunogate: Toluene-d8 53.6 ug/L 50.00 107 76-131

Sunogate: 1,2-Dichloroethane-d4 51.8 ug/L 50.00 104 75-124


Blank (1341153-BLKl) Prepared & Analyzed: 10/09/13


1,1,1 -Trichloroetbane HDL 5.00 ug/L


1,1,2-Trichloroethane BDL 5.00 ug/L

Ll-Dichloroethane BDL 5.00 ug/L


1,1-Dichloropropene BDL 5.00 ug/L

1,2':Dibromoethane BDL 5.00 ug/L

1,2-Dichloroethane BDL 5.00 ug/L

1,2-Dicbloropropane BDL 5.00 ug/L

1,3-Dichloropropane BDL 5.00 ug/L

2,2-Dichloropropane BDL 5.00 ug/L

2-Butanone BDL 20.0 ug/L


2-Hexanone BDL 20.0 ug/L


4-Methyl-2-pentanone BDL 20.0 ug/L

Acetone BDL 20.0 ug/L

Acetotiitrile BDL 40.0 ug/L

Acrolein BDL 20.0 ug/L

Acrylonitrilc BDL 20.0 ug/L

AUyl chloride BDL 5.00 ug/L

Benzene BDL 5.00 ug/L







ENT: lect:


Lab Order: 1311474


lyte Result Repotting


Souicc Result %REC

%REC Limits RPD

RPD Limit Notes

i;hl3411S3-VOCPREP

»k (13411S3-BLK1) Prepared & Analyzed: 10/09/13

on Disulfide BDL 20.0 ug/L

on Tetrachloride BDL 5.00 ug/L

robenzene BDL 5.00 ug/L

roethane BDL 5.00 ug/L

roform BDL 5.00 ug/L

romethane BDL 5.00 ug/L

,2-DichloroetheDe BDL 5.00 ug/L

,3 -Dichloropropene BDL 5.00 ug/L

smochloromethane BDL 5.00 ug/L

^momethane BDL 5.00 ug/L

lorodifluoromethane BDL 5.00 ug/L

Ibcnzene BDL 5.00 ug/L

netbane BDL 10.0 ug/L

ylene Chloride BDL 5.00 ug/L

yl tert-Butyl Ether BDL 10.0 ug/L

Xylene BDL 10.0 ug/L

xane BDL 5.00 ug/L

lene BDL 5.00 ug/L

ne BDL 5.00 ug/L

chloroetheue BDL 5.00 ug/L

me BDL 5.00 ug/L

-1.2-Dichloroethene BDL 5.00 ug/L

1,3-Dichloropropene BDL 5.00 ug/L

loroethene BDL 5.00 ug/L

lorofluoromethane BDL 5.00 ug/L

1 Chloride BDL 1.00 ug/L


gate: 4-Bromqfluorobenzejie 42.7 ug/L 50.00 85.3 66-125

gate: Dibtomofluoromethane 49.3 ug/L 50.00 98.6 75-130

gale: Totuene-dS 44.4 ug/L 50.00 88.9- 76-131

gate: 1,2~Dichloroethane-d4 48.0 ug/L 50.00 95.9 75-124


CLIENT: Project:

Civil & Environmentai Consultants, inc. - Toledo 130-998

Lab Order: 1311474


Analyte Result

Reporting

Limit Units

Spike Source %REC

Level Result %R£C Limits

RPD

RPD Limit Notes


LCS (1341153-BSl) Prepared & Analyzed: 10/09/13

1.1.1.2-Tetrachloroelhane 19.3 ug/L 20.00 96.5 80-123

1.1.1-Trichloroethane 18.6 ug/L 20.00 93.0 75-135

1.1.2.2-Tetrachloroethane 20.5 ug/L 20.00 102 76-133

1.1.2-Trichloroetliane 19.2 ug/L 20.00 96.0 80-124

1.1-Dichloroethane 17.1 ug/L 20.00 85.6 74-136

1.1 -Dichloroethene 16.7 ug/L 20.00 83.3 61-154

1.1 -Dichloropropene 17.1 ug/L 20.00 85.6 78-135

1.2-Dibromoethane 19.8 ug/L 20.00 99.0 76-125

1.2-Dichloroethane 18.3 ug/L 20.00 91.6 74-130

1.2-Dichloropropane 18.1 ug/L 20.00 90.6 78-126

1.3-DicMoropropane 18.5 ug/L 20.00 '92.6 80-127

2.2-DichloroprDpane 17.8 ug/L 20.00 88.8 49-183

2-Butauone 33.1 ug/L 40.00 82.6 53-157


2-Hexattone 34.8 ug/L 40.00 87.0 64-147

4-Chlorotoluene 21.6 ug/L 20.00 . 108 80-125

4-MethyU2-pentanone 40.1 ug/L 40.00 100 74-133

Acetone 38.0 ug/L 40.00 94.9 35-191

Acetoniuile 19.2 ug/L 20.00 95.8 45-166

Acrolein 29.1 ug/L 40.00 72.8 51-186

Acrylonitrile 15.4 ug/L 20.00 76.8 64-137

Allyl chloride 18.0 ug/L 20.00 89.8 60-150

Benzene 17.5 ug/L 20.00 87.6 81-128

Bromobenzene 21.5 ug/L 20.00 108 83-122

Bromochloromethane 21.2 ug/L 20.00 106 81-127

Bromodichloromethane 19.2 ug/L 20.00 96.0 79-123

Bromoform 22.4 ug/L 20.00 112 59-130

Bromomethane 21.8 ug/L 20.00 109 68-148

Carbon Disulfide 17.9 ug/L 20.00 89.4 44-162

Carbon Tetrachloride 18.5 ug/L 20.00 92.5 64-132

Chlorobenzene 20.1 ug/L 20.00 100 82-122

Chloroethane 17.8 ug/L 20.00 89.0 48-150

Chloroform 18.4 ug/L 20.00 91.8 74-132

Chloromethane 18.2 ug/L 20.00 91.0 50-166

cis-1.2-Dichloroethene 17.1 ug/L 20.00 85.4 77-134

cis-1,3-Dichloropropene 18.2 ug/L 20.00 91.2 77-127

Dibromochloromethane 21.0 ug/L 20.00 105 69-123

Dibromomethane 19.0 ug/L 20.00 95.2 82-127

Dichlorodifluorometbane 17.8 ug/L 20.00 89.2 41-145

Ethylbenzene 18.8 ug/L 20.00 93.8 82-126

lodomethane 18.5 ug/L 20.00 92.3 50-144

Methylene Chloride 18.4 ug/L 20.00 92.0 69-137

Methyl tert-Butyl Ether 17.6 ug/L 20.00 88.2 73-127

m.p-Xylene 39.1 ug/L 40.00 97.7 82-131

n-Hexane 24.2 ug/L 22.64 107 41-166


ENT: lect:


Lab Order: 1311474


Reporting Spike Source %REC RPD lyte Result Limit Units Level Restilt %REC Limits RPD Limit Notes


S(1341153-BS1) Prepared & Analyzed: 10/09/13

irlene 20.0 ug/L 20.00 100 80-126

rnc 20.4 ug/L 20.00 102 80-127

ichloroethcne 21.3 ug/L 20.00 106 43-152

ene 18.2 ug/L 20.00 90.9 84-129

i-1,2-Dichloroethene 18.6 ug/L 20.00 93.2 73-132

i-1,3-Dichloropropene 18.9 ug/L 20.00 94.4 80-131

iloroethene i 20.0 ug/L 20.00 100 79-129

ilorofluoromethane 18.8 ug/L 20.00 94.2 64-163

1 Chloride 19.6 ug/L 20.00 98.2 61-157

1 acetate 13.5 ug/L 20.00 67.6 36-205

ygale: 4-Bromofltiorobenzene 48.0 ug/L 50.00 96.0 66-125

ygale: Dibromofluoromethane 52.7 ug/L 50.00 105 75-130

ogaie: Toluene~d8 48 J ug/L 50.00 96.2 76-131

agate: 1,2-DicMoroelhane-d4 51.0 ug/L 50.00 102 75-124

$Dup(1341153-BSDl) Prepared & Analyzed: 10/09/13

.2-Tetrachloroethane 18,7 ug/L 20.00 93.7 80-123 2.94 11

-Trichloroethane 18.6 ug/L 20.00 93.2 7.5-135 0.107 11

',2-Tetrachloroethane 19.5 ug/L 20.00 97.3 76-133 5.21 14

-Trichlofoethane 18.9 ug/L 20.00 94.6 80-124 1.36 12

Hcbloroethane 15.2 ug/L 20.00 76.2 74-136 11.6 12

tichloroethene 15.9 ug/L 20.00 79.3 61-154 4.92 14

}ichIoropropene 16.6 ug/L 20.00 83.0 78-135 3.14 11

)ibronioetfaaiie 19.3 ug/L 20.00 96.4 76-125 2.66 43

Hchloroethane 19.0 ug/L 20.00 94.8 74-130 3.33 10

tichloropropane 17.7 ug/L 20.00 88.4 78-126 2.51 10

•ichloropropane 18.2 ug/L 20.00 91.2 80-127 1..52 11

tichloropropane 16.7 ug/L 20.00 83.6 49-183 6.03 13

tanone 31.0 ug/L 40.00 77.6 53-157 6.27 18

lorotoluene 20,2 ug/L 20.00 101 75-132 4.69 43

xanone 32.2 ug/L 40.00 80.6 64-147 7.73 18

lorotoluene 20.9 ug/L 20.00 104 80-125 3.20 11

thyl-2-pentanone 38.6 ug/L 40.00 96.4 74-133 3.99 17

>ne 35.5 ug/L 40.00 88.8 3.5-191 6.61 23

rnitrile 17.7 ug/L 20.00 88.6 45-166 7.76 48

lein 25.3 ug/L 40.00 63.2 51-186 14.1 25

lonitrile 16.5 ug/L 20.00 82.6 64-137 7.28 18

chloride 17.6 ug/L 20.00 88.2 60-150 1.74 16

;ne 17.1 ug/L 20.00 8.5..'> 81-128 2.48 10

obenzene 20.9 ug/L 20.00 105 83-122 2.78 11

ochioromethane 20.2 ug/L 20.00 101 81-127 4.69 10

odichloromethane 19.3 ug/L 20.00 96.6 79-123 0.623 10

oform 21.9 ug/L 20.00. 110 59-130 1.94 17

omethane 21.2 ug/L 20.00 106 68-148 3.16 17

>11 Disulfide 16.8 ug/L 20.00 84.0 44-162 6.17 17


CLIENT: Project:


Lab Order: 1311474


) Reporting Spike Source •/oREC RPD

Analytc Result Limit Units Level Result %REC Limits RPD Limit Notes


LCS Dup (134n53-BSDl) Prepared & Analyzed: 10/09/13

Carbon Tetrachloride 18.0 ug/L 20.00 90.0 64-132 2.68 12

Chlorobenzene 19.4 ug/L 20.00 97.0 82-122 3.45 10

Chloroethane 17.4 ug/L 20.00 87.0 48-150 2.22 33

Chloroform 17.6 ug/L 20.00 88.2 74-132 3.95 10

Chloromethane 19.3 ug/L 20.00 96.6 50-166 6.03 18

cis-1.2-Dichloroethene 16.3 ug/L 20.00 81.4 77-134 4.80 II

cis-1,3-Dichloropropene 18.0 ug/L 20.00 90.0 77-127 1.21 12


Dibromomethane 18.9 ug/L 20.00 94.7 82-127 0.527 11

Dichlorodifluoromethane 17.1 ug/L 20.00 85.7 41-145 3.95 21

Ethylbenzene 18.1 ug/L 20.00 90.4 82-126 3.80 11

lodomethane 17.6 ug/L 20.00 87.9 .50-144 4.88 14

Methylene Chloride 17.9 ug/L 20.00 89.4 69-137 2.92 12

Methyl teri-Butyl Ether 16.8 ug/L 20.00 84.2 73-127 4.64 11

m,p-Xylene 37.2 ug/L 40.00 92.9 82-131 4.98 11

n-Hexane 22.2 ug/L 22.64 98.3 41-166 8.35 17

o-Xylenc 19.2 ug/L 20.00 96.0 80-126 4.33 12

Styrene 19.6 ug/L 20.00 98.2 80-127 3.60 40

Tetrachloroethene 20.3 ug/L 20.00 . 102 43-1.52 4.47 26

Toluene 17.6 ug/L 20.00 87.8 84-129 3.47 II

trans-1.2-Dichlorocthene 17.8 ' ug/L 20.00 88.9 73-132 4.67 11

trans-1.3-Dichloropropene 18.6 ug/L 20.00 93.2 80-131 1.28 12

Trichloroethene 19.6 ug/L 20.00 98.2 79-129 1.77 12

Trichlorofluorometliane 17.9 ug/L 20.00 89.3 64-163 5.39 16

Vinyl Chloride 18:5 ug/L 20.00 92.4 61-1.57 6.09 17

Vinyl acetate 11.6 ug/L 20.00 58.0 36-205 1.5.3 27

Surrogate: 4-BiomoJluorobenzene 47.2 ug/L 50.00 94.4 66-125

Sunogale: Dibromofluoromethane 52.7 ug/L 50.00 105 75-130

Sunogate: ToIuene-d8 48.1 ug/L 50.00 96.2 76-131

Suriogate: J ,2~Dichlotoethane-d4 50.6 ug/L 50.00 101 75-124


ENT: |ect:


Lab Order: 1311474


yte Result Reponing


Source Result %REC

%REC Limits RPD

RPD Limit Notes

Eh 1340044-PREP SVOC W

•k (1340044-BLKl) Prepared: 09/30/13 Analyzed: 10/09/13

laphthene BDL 10.0 ug/L

:(a)anthracene BDL 0.260 ug/L

M(a)pyrene BDL 0.200 ug/L

:o(b)fluoranthene BDL 0.170 ug/L

:o(k)fluoranthene BDL 1.70 ug/L

sene BDL 10.0 ug/L

Tiz(a,h)anthracene BDL 0.200 ug/L

io(l,2,3-cd)pyrene BDL 0.220 . ug/L

ithalene BDL 10.0 ug/L

ie BDL 10.0 ug/L

7gate:. Nilivbenzene-d5 34.0 ug/L 40.00 34.9 50-110

ygate: 2-Fluorobiphenyl 33.9 ug/L 40.00 84.7 50-104

7gate: Terphenyl-dJ4 36.9 ug/L 40.00 92.2 37-135


;tfayliiaphthalene 37.0 10.0 ug/L 50.00 73.9 10-200

aphlhene ,36.3 10.0 ug/L 50.00 72.7 53-95

aphthylene 37.0 10.0 ug/L 50.00 73.9 48-98

acene 44.2 10.0 .ug/L 50.00 88.3 60-97

â)anthiacene 43.5 0.260 ug/L 50.00 87.1 72-114

j(a)pyrene 42.1 0.200 ug/L 50.00 84.1 50-113

3(b)f1uoranthene 36.5 0.170 ug/L 50.00 72.9 48-111

3(g3i,i)peiyleiie 43.4 10.0 ug/L 50.00 86.7 44-122

3(k)fluoranthene 38.0 1.70 ug/L 50.00 75.9 35-125

sene 39.7 10.0 ug/L 50.00 . 79.5 62-106

iz(aj])anthracene 41,3 0.200 ug/L 50.00 82.6 47-119

anthene 52.2 10.0 ug/L 50.00 104 54-108

ene 39.8 10.0 ug/L 50.00 79.7 53-97

o(1.2.3-cd)pyrene 41.5 0.220 ug/L .50.00 83.0 49-124

thalene 34.4 10.0 ug/L .50.00 68.8 47-86

antfarene 38.0 10.0 • ug/L 50.00 76.1 54-96

le 40:7 10.0 ug/L 50.00 81.4 53-107

gale: Nitmbenzene-d5 36.6 ug/L 40.00 91.6 50-110

gate: 2-FIuorobiphenyl 30.1 ug/L 40.00 75.2 50-104

gale: Tetphenyl-dl4 34.9 ug/L 40.00 87.4 37-135


CLIENT: Project:


Lab Order: 1311474


Reporting Spike Source %REC RPD Analyte Result Litnit Units Uvel Result %REC Limits RPD Limil Notes


LCS Dup (1340044-BSDl) Prepared; 09/30/13 Analyzed: 10/03/13

2-Metbyliiaphthalene 40.5 10.0 ug/L 50.00 81.0 10-200 9.14 50

Acenaphthene 40.3 10.0 ug/L .50.00 80.7 53-95 10.4 19

Acenaphthylene 40.1 10.0 ug/L 50.00 ; 80.2 48-98 8.17 17

Anthracene 49.8 10.0 ug/L 5o:oo 99.7 60-97 12.1 12 L,R

Benz(a)anthracene 48.5 0.260 ug/L 50.00 97.0 72-114 10.8 12

Benzo(a)pyrene 46.4 0.200 ug/L 50.00 92.8 50-113 9.83 19

Benzo(b)iluoranthene 41.9 0.170 ug/L 50.00 83.8 48-111 13.9 26

Benzo(gJi,i)peiylene 45.6 10.0 ug/L 50.00 91.2 44-122 4.99 31

Benzo(k)11uoranthene 48.3 1.70 ug/L 50.00 96.7 35-125 24.0 29

Chiysene 44.5 10.0 ug/L 50.00 : 89.0 62-106 11.3 12

Dibenz(a,h)anthracene 44.3 0.200 ug/L 50.00 88.7 47-119 7.15 28

Fluoranthene 57.1 10.0 ug/L 50.00 114 54-108 9.08 13 L

Fluorene 45.3 10.0 ug/L 50.00 90.7 53-97 12.9 18

Indeno( 1,2,3-cd)pyrene 44.0 0.220 ug/L 50.00 88:0 49-124 5.85 29

Naphthalene 38.3 10.0 ug/L 50.00 76.6 47-86 10.8 13

Phenanthrene 43.4 10.0 ug/L 50.00 86.7 54-96 13.1 12 R

PjTene 46.7 10.0 ug/L 50.00 93.4 53-107 13.8 22

SurTogate: Nitrobenzene-dS 37.7 ttg/L 40.00 94.3 50-110

Sunvgate: 2-FlHorobiphenyl 32.2 ug/L 40.00 80.4 50-104

Surrogate: Terphenyl-dl4 39.8 ug/L 40.00 99.6 37-135

Matrix Spike (1340044-MSl) Source: 1311442-03 Prepared: 09/30/13 Analyzed: 10/03/13

Acenaphthene 38.4 . 10.0 ug/L 50.00 ND 76.8 70-130

Acenaphthylene 39.5 10.0 ug/L .50.00 ND 79.0 70-130

Anthracene 42.4 10.0 . ug/L 50.00 ND 84.8 70-130

Benz(a)anthracene 35.7 0.260 ug/L 50.00 ND 71.4 70-130

Benzo(a)pyrene 33.4 0.200 ug/L 50.00 ND 66.7 70-130 M

Ben2o(b)fluoranthene 30.9 0.170 ug/L 50.00 ND 61.7 70-130 M

Benzo(g.h,i)peiylene 32.7 10.0 ug/L 50.00 ND 65.4 70-130 M

Chrysene 33.0 10.0 ug/L 50.00 ' ND 66.1 70-130 M

Dibenz(a,h)anthracene 31.3 0.200 ug/L 50.00 ND 62.5 70-130 M

Fluoranthene 45.7 10.0 ug/L .50.00 ND 91.5 70-1.30

Fluorene 40.8 10.0 ug/L 50.00 ND 81.6 70-130

!ndeno( 1,2,.3-cd)pyrene 31.8 0.220 ug/L 50.00 ND 63.5 70-130 M

Naphthalene 37.2 10.0 ug/L 50.00 1.54 71.2 70-130

Phenanthrene 37.0 10.0 ug/L 50.00 ND 74.0 70-130

Pyrene 37.7 10.0 ug/L 50.00 ND 75.3 70-130

Surrogate: Nitrobenzene-dS 39.8 ug/L 40.00 99.4 50-110

Surrogate: 2-Fluotobipheriyl 31.6 ug/L 40.00 79.0 50-104

Surrogate: Terphertyl-dI4 29.7 ug/L 40.00 74.2 37-135

lli)gage^6^d^

Imont Labs Date; 10/28/2013

ENT: ject:


ioib Order: 1311474


Reporting Spike Source %REC RPD

y«e Residt Limit Units Level Result %REC Limits RPD Limit Notes

A 1340044-PREP SVOC W

rix Spike (1340044-MS2) Source 1311474-02 Prepared: 09/30/13 Analyzed: 10/03/13

aphtheoe 34.9 10.0 ug/L 50.00 ND 69.8 70-130 M

aphtfaylene 36.6 10.0 ug/L 50.00 ND 73.1 70-130

lacene 36.2 10.0 ug/L 50.00 ND 72.4 70-130

.a)anthracene 32.4 0.260 . ug/L 50.00 ND 64.8 70-130 M

j(a)pyiene 29.9 0.200 ug/L 50.00 ND 59.8 70-130 M

o(b)fluoianthcne 27.2 0.170 ug/L 50.00 ND 54.4 70-130 M

o{g.h,i)peryIene / 30.5 10.0 ug/L 50.00 ND 60.9 70-130 M

sene 30.3 10.0 ug/L 50.00 ND 60.6 70-130 M

'iz(a,h)anlhracene 29.3 0^200 ug/L 50.00 ND 58.6 70-130 M

anthene 41.2 10.0 ug/L 50.00 ND 82.5 70-1.30

*ne 37.5 10.0 ug/L 50.00 ND 75.0 70-130

io(l,2,.1-cd)pyrene 29.6 0.220 ug/L .50.00 ND 59.2 70-130 M

thalcne 34.1 10.0 ug/L 50.00 ND 68.1 70-130 M

anlhrene 33.1 10.0 ug/L 50.00 ND 66.1 70-130 M

le 33.2 10.0 ug/L 50.00 ND 66.5 70-130 M

^gate: Nitmbenzene-d5 38.8 ug/L 40.00 97.0 50-110

gate: 2-FliiowbiphenyI 28.8 ug/L 40.00 72.0 50-104

gale: Terphenyl-dI4 28.3 ug/L 40.00 70.8 37-135

lix Spike Dup (1340044-MSDl) Source: : 1311442413 Prepared: 09/30/13 Analyzed: 10/03/13

aphthene 38.1 10.0 ug/L 50.00 ND 76.3 70-1.30 0.627 20

aphthylene 39.5 10.0 ug/L 50.00 ND 79.0 70-130 0.00 20

"acene 39.2 10.0 ug/L 50.00 ND 78.4 70-130 7.92 20

;a)anthracene 38.6 0.260 ug/L 50.00 ND 77.3 70-130 7.94 20

j(a)p>Tene 36.3 0.200 ug/L 50.00 ND 72.6 70-1.30 8.53 20

Xb)iluoranthcne 35.4 0.170 ug/L 50.00 ND 70.9 70-130 13.8 20

Ji(g,h,i)perylene 35.6 10.0 ug/L 50.00 ND 71.3 70-130 8.66 20

icnc 35.0 10.0 ug/L .50.00 ND 70.0 70-1.30 5.79 20

iz(a,h)anthracene 34.2 0.200 ug/L 50.00 ND 68.4 70-130 8.95 20 M

anthene 45.2 10.0 ug/L 50.00 ND 90.4 70-1.30 1.19 20

me 40.6 10.0 ug/L 50.00 ND 81.3 70-130 0.417 20

0(1,2,3-cd)p,VTene 34.9 0.220 ug/L .50.00 ND 69.7 70-1.30 9.34 20 M

thalene 36.2 10.0 ugL 50.00 1.54 69.4 70-130 2.48 20 M

mthrene 36.9 10.0 ugL 50.00 ND 73.8 70-130 0.244 20

e 38.3 10.0 UgL 50.00 ND 76.6 70-130 1.68 20

gate: Nitrobenzene-d5 40.4 ug/L 40.00 101 50-110

gate: 2-Fluombiphenyl 32.0 ug/L 40.00 80.0 50-104

gate: Terphenyl-dl4 30.5 ug/L 40.00 76.2 37-135


CLIENT: Project:


Lab Order: 1311474


Rcpoittng Spike Source %REC RPD Analytc Result Litnit Units Level Result %REC Limits RPD Limit Notes


Matrix Spike Dap (1340044-MSD2) Source: 1311474-02 Prepared: 09/30/13 Analyzed: 10/03/13

Acenaphthene 32,3 10.0 ug/L 50.00 ND 64.6 70-130 7.68 20 h

Acenaphthylene 34.1 10.0 ug/L 50.00 ND 68.2 70-130 7.05 20 h

Anthracene 35.8 10.0 ug/L 50.00 ND 71.5 70-130 1.14 20

Benz(a)anthracene 34.0 0.260 ug/L 50.00 ND 68.1 70-130 4.97 20 h

Benzo(a)pyrene 32.3 0.200 ug/L 50.00 ND 64.6 70-130 7.62 20 h

Benzo(b)fluoianthene 29.4 0.170 ug/L 50.00 ND 58.8 70-1.30 7.85 20 h

Benzo(g,h,i)peiylene 34.3 10.0 ug/L 50.00 ND 68.5 70-130 11.7 20 h

Chiysene 30.5 10.0 ug/L 50.00 ND 61.0 70-130 0.559 20 V

•ibenz(a,h)anthracene 32.7 0.200 ug/L 50.00 ND 65.3 70-130 10.9 20 V

Fluoianthene 41.4 10.0 ug/L 50.00 ND 82.8 70-130 0.387 20

Fluorene 35.7 10.0 ug/L 50.00 ND 71.4 70-130 4.92 20

Indeno(l ,2,.1-cd)p)Tene 32.9 0.220 ug/L 50.00 ND 65.8 70-130 10.5 20 V

Naphthalene 33.1 10.0 ug/L 50.00 ND 66.2 70-130 2.83 20 V

Phenanthrene 33.0 10.0 ug/L 50.00 ND 66.0 70-130 0.151 20 V

Pyrene 34.1 10.0 ug/L 50.00 ND 68.2 70-130 2.61 20 V

Sunvgate: Nit}vbenzene~dS 38.6 ug/L 40.00 P6.J 50-110

Sunvgate: 2-FIuombiphenyl 28.1 ug/L 40.00 70.4 50-104

Surmgale: Terphenyl-dl4 28.0 ug/L 40.00 70.0 '37-135


Civil & Environmental Consultants, Inc. - Toledo Lab Order: 1311474 130-998

Notes and Definitions

Surrogate result is outside of acceptance limits. The remaining number of surrogates within accqitance limits satisfies method criteria for producing valid data.

The surrogate recovery for this sample is outside of established control limits due to a sample matrix effect.

RPD outside of accepted recovery limits.

Matrix spike and/or matrix spike duphcate recovery outside of acceptance limits.

Lahoratoiy control sample recovery outside of acc^tance limits high, sample results are below detection limits. Sample data is still acceptable.

Analyte detected below quantitation limits. Estimated concentration for TlCs.

Negative

Analyte is below detection Emits

Sample preservation was met unless otherwise noted.

Belmont'Labs' The ttivifonrDentai Service Company.

ANALYTICAL REQUEST CHAIN OF CUSTODY Internal Lob

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H Nome

C, Li. I -r ûirfH

ANALYSIS REQUESTED (Enter an "X'm the Do* txNrtvv to inctK.iic reque-i .met ciff le preM-ivanvej

CO in o S 0) O)

CL

^L^l. cyetw-TiVg-City, State, Zip,

Ptrone No ' Emeii Mdress

• Rush analysis required - results required by Contact Belmont Labs prior to sending rush samples

-(Date)


Additional QC iiequirements: level 2, Level 3, Level 4 ICItarges Applyl

OENT SAMPU lOENTIFICAnON

RequtolgfYlYBe • NPOES • BUSTR a RCRA • NELAC • SOWA • VAP • Ottier /» Lj Collected in Slate of ^ ̂

Date Sampled Time Camp

6Y \V#7^ X J

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Z^Jsh^ CHAIN Of

CUSTODY lit required!

Relinquished by bevsrvPwJtr Dote/Time Received by Dote/Time^ 7

Relinquished by: Dale/Time Received at lab by:

AAelhod of Shipment:

Sampled by;.

Cooler Temp ^^/^^^Custody Seals ^^Jl^Yes • No S^lrQ 'lels Date .

Client Comments

Belmont Labs • 25 Holiday Drive • Englewood,OH 45322 • 937.832.8242 • Fax 937.832.2868 • www.belmontlabs.com DISTRIBUTION:

WHITE - Laboratory

Belmont 'Labs' The Environmencal Service Company.

ANALYTICAL REQUEST CHAIN OF CUSTODY

Purchase Order No. Quote No.

^<^0OO'S(i>di(p Client Project , t, ANALYSIS REQUESTED

(Enter an 'X' in ttie lnjx tjelovv to incjic.ili- request and tirtle preservatirrpi

Name rO>cic

Company

Coinpqny . , . / / — ^.uil /Ew.

^ Mailing Address

Ui V. I TK fcuCi Address ' H ̂ '

aty, state, ZID ^

TolJi.dM H>Ccc,

City. Stole. Zip

jcJo.aM 4^600 Id Phone No

Kl'i 11'* Email Address

• Rush analysis required - results required by Contact Belmont Labs prior to sending rush samples


Additional QC Requlremenis: Level 2. Level 3. Level 4 IChorges Apply)

OJENT SAMPU IDeNTinCATION

-H'iy t MuJ-Xpi-P i jrc-i i h

i5o-i^y. HwJ-JlLTi it'^LLiZ

_(Date)

Date Sampled

ReautotofYTYPs • NPOeS • BUSTR O RCRA • NELAC • SOWA • VAP O Other /) jj CoHeded In State of C/ fj

lime

\tUZ.

Comp Grab Main*

UuUJi

1/ o / 1/ 1/ _ o / o / ' i o i / 1/ 1/ 1/ 1; o/ Of o/ IT !

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CHAIN OF

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•Sampled bY:-

RelinqulshedbY: Dole/Time t7 1*9 Received by: / Date/Time^7 ^5/: Relinquished by: Dote/Time Received at lob by: / Dote/Timi

Method at Shipment: S/*£L.

V Dale

Cooler Temp. ~7~^^

i'Si t'c

Custody Seols ^yes • No / ®l$"

Client Comments

Belmont Labs • 25 Holiday Drive • Engiewood, OH 45322 • 937.832.8242 • Fox 937.832.2868 • www.baimontlabs.cnm DISTRIBUTION:

lA/LJITC . I i>«UAMe«a«M<


Sample Receipt Summary

1311474

Client; Civil & Environmental Consultants, Inc. - Toledo

Project: Stickney-Tyler GW Monitoring

Project Manager: Taryn Mancine

Project Number: 130-998

Report To: Nicholas Boland 3232 Executive Parkway, Suite 1 Toledo OH 43606 Phone: (419)724-5281 Fax:

Receipt Temp (C): 4.0 WO Due Date: 10/14/2013 5:00:00PM Custody Seals True

TAT (Days): 10 Container Intact True

Received By: Scott Pander COC/Labels agree Received on ice

True True

Received: 9/27/2013 6:15:00PM VOC vials had zero head space True

Logged In By: Scott Pander Approved Container True Logged In By:

Sufficient volume received True Logged In: 9/28/2013 10:28:00AM Received within HT

Shipped By:

True

Belmont Labs

Samples Received:

Laboratory ID: Field ID: Date/Time Sampled: Matrix:


1311474-02 130-998:MW-31 LP+MS/MSD:Z092613 9/26/2013 4:38:00PM Leachate




1311474-06 130-998:Duplicate:Z092613 9/26/2013 3:21:00PM Leachate

1311474-07 130-998:FB-2:Z092613 9/26/2013 7:42:00PM Water

1311474-08 130-998:M W-23LP:Z092713 9/27/2013 10:21:00AM Leachate

1311474-09 1 30-998:MW-21 LP:Z092713 9/27/2013 11:21:00AM Leachate


1311474-11 130-998:MW-36LP:Z092613 9/26/2013 10:04:00AM Leachate


1311474-13 130-998:TB-1:W092613 9/26/2013 10:04:00AM Water

Sample Notes:

Dn the COC, some of the Sample IDs had a 'G' that was crossed out and a 'Z' put in its place, with initials, but >ome of the bottles still have the 'G' written on them. For the Field Blank, the COC has 'Z\ but the bottles have 1 Won them. SP9/28/13

follow COC. TM 10/1/2013

APPENDIX C

LEACHATE MONITORING WELL ANALYTICAL DATA SUMMARY TABLES


APPENDIX C-1: STICKNEY AVENUE LANDFILL


CITY OF TOLEDO STICKNEY AVENUE LANDFILL

TABLE 1

LABORATORY ANALYTICAL DATA REPORTED FOR S-MW-21LP

11 Parameter Units 7/25/07 6/12/08 6/12/08# 9/23/09 10/6/10 9/16/11 10/3/12 9/25/13

Metals Mercuiy mg/L <0.0002 0.00018 •' 0.00018-' 0.000118-' 0.000164-' <0.0002 <0.0002 <0.0002

PCBs Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

mg/L mg/L mg/L mg/L mg/L mg/L mg/L

<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002

< 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005

< 0.0005 < 0.0005 < 0.0005 <0.0005 < 0.0005 < 0.0005 < 0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT Aldrin Heptachlor

mg/L mg/L mg/L

<0.0005 <0.00005 <0.00005

< 0.00005 < 0.00005 < 0.00005

< 0.00005 < 0.00005 < 0.00005

<0.00005 <0.00005 <0.00005

<0.0005 <0.0005 <0.0005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

PAH'S Acenaphthene Benz(A)Anthracene Benzo(A)Pyrerte Benzo(B)Fluoranthene Benzo(K)Fluoranthene Chrysene Dlbenz(A,H)Anthracene lndeno(1,2,3-Cd)pyr6ne Naphthalene Pyrene

mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L

0.0002-' <0.00026 <0.0002 0.00012-' <0.0017 <0.01

0.00084 •• 0.00099 •' 0.0082 •'

<0.01

<0.010 < 0.00026 < 0.0002 <0.00017 <0.0017 <0.010 < 0.0002 < 0.00022 0.0062 •' <0.010

<0.010 < 0.00026 < 0.0002 <0.00017 <0.0017 <0.010 < 0.0002 < 0.00022 0.0046 <0.010

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.00783 •'

<0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.00532 •'

<0.01

<0.01 <0.00026 <0.0002

<0:00017 <0.0017 <0.01

<0.0002 <0.00022 0.00552 •'

<0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.00154-'

<0.01

Field Parameters Conductivity Dissoived Oxygen pH Redox Potentiai Temperature Turbidity

umhos/cm mg/L S.U. mv "0

NTU

7830 0.10 6.61 -128 13.3 65

9500 5.24 6.76 -58 12.8 92

9500 5.24 6.76 -58. 12.8 92

6640 2.54 6.36 -95

16.8 47

5160 0.20 7.09 -191 17.1 193

3180 1.67 6.72 -107 15.6 17

3130 0

6.77 -99 16.2 77

2810 1.08 6.80 -58.4 16:84 7.22

NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting will) tlie September 2013 event entered by GEO. (J) Estimated value detected between the MDL and the laboratory PQL. (#) Duplicate Sample (-) Not analyzed (*) No sample was collected.

Civil S Environmental Consultants. Inc. City of Toledo -130-998 Fall 2013 Event


TABLE 2


Parameter Units 7/25/07 6/12/08 9/23/09 10/6/10 9/15/11 10/3/12 9/25/13

Metals Mercury mg/L <0.0002 < 0.0002 <0.0002 0.0000288'' <0.0002 <0.0002 0.0000754-'

PCBs Aroclor 1016 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor1221 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0002 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT mg/L <0.0005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Benz{A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Dlbenz(A,H)Anthracene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L <0.00022 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 0.00207'' <0.01 Pyrene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 3270 5370 1580 1180 1390 969 1971 Dissolved Oxygen mg/L 0.29 4.84 2.6 0 4.7 5.1 1.02 PH S.U. 6.87 7.1 6.85 7.65 7.46 7.55 7.02 Redox Potential mv -118 -64 -33 -76 -35 12 -138.6 Temperature -c 16.6 21.6 25.3 18.7 19.6 19.5 18.39 Turbidity NTU 145 435 45 137 62 155 75.8 NOTES; Original table developed by Hull & Associates, Inc. Analytical data starting witti the September 2013 event entered by GEO. (J) Estimated value detected between the IvIDL and the laboratory POL. (#) Duplicate Sample (--) Not analyzed (*) No sample was collected.

Civil & Environmental Consultants, Inc. City of Toledo- 130-998 Fall 2013 Event

CITY OF TOLEDO SnCKNEY AVENUE LANDFILL

TABLE 3


Parameter Units 7/25/07 7/25/07# 6/12A)8 9/23/09 9/23/09# 10/6/10 10/6/10# 9/15/11 9/15/11# 10/3/12 9/25/13

mg/L <0.0002 <0.0002 < 0.0002 0.0000399-' 0.0000283 0.0000654-' 0.0000335-' <0.0002 <0.0002 <0.0002 <0.0002

mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005 mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005 mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.000.5 <0.0005 mg/L <0.0002 <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005 mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005 mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005 mg/L <0.0002 <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 <0.0005

mg/L <0.00005 <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 <0.00005 mg/L <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00025 <0.00005 <o:oooo5 <0.00005 <0.00005 mg/L <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 <0.00005

mg/L <0.01 <0.01 < 0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/L <0.00026 <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 mg/L <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 mg/L <0.00017 OiOOOM-" <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0:00017 <0.00017 <0.00017 <0.00017 mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 mg/L <0.01 <0.01 < 0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/L <0.0002 0.00091 < 0.0002 <0.0002 <00002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 mg/L <0.00022 0.0011 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 mg/L <0.01 <0.01 < 0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 mg/L <0.01 <0.01 < 0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Tihos/cm 3430 3430 5000 4230 4230 4170 4170 4140 4140 saio 3394 mg/L 0.01 0.01 6.63 2.65 2.65 1.03 1.03 1.65 1.65 0 1.29 S.U. 6.28 6.28 6.56 6.08 6.08 6.87 6.87 6.8 6.8 6.58 6.80 mv -116 -116 -115 -127 -127 -154 -154 -130 -130 -66 -60.4 •0 12.8 12.8 13.5 17.1 17.1 16.4 16.4 15.2 15.2 16.5 16.95

NTU 1 1 86 88 88 135 135 34 34 66 19.9

Metals Mercury



PAH'S Acenaphttiene Ben2(A)Anthracene Benzo(A)Pyrene Ben2o(B)Fluoranthene Ber)zo(K)Fluorar)ther)e

hrysene Dlbenz(A,H)Anthracene lndeno( 1.2,3-Cd)pyrene Naphthalene Pyrene

Field Parameters Conductivity Dissolved Oxygen PH Redox Potential Temperature Turbidity NOTES:

Original labia dsveioped by Hull & Associates, inc. Analyticai data starting with the September 20t3 event entered by GEO.

(J) Estimated value detected between the MDL and the laboratory POL

(#) Duplicate Sample

(-) Not analyzed

(•) No sample was coliecied.

Civil & Environmental Consultants, Inc. City ol Toledo-130-998 Fall 2013 Event


TABLE4


Parameter Units 7/25/07 6J^2m 9/23/09 10/6/10 9/15/11 10/3/12 10/3/12# 9/25/13

Metals Mercury mg/L <0.0002 0.000093-' 0.0000824-' 0.000282 <0.0002 <0.0002 <0.0002 <0.0002

PCBs Aroclor 1016 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1221 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1280 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4.4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.0005 <0.00005 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.0005 <0.00005 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.0005 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.005 •• 0.0042-' 0.00372-' 0.00429-' 0.00098-' <0.01 <0.01 0.00194-' Ben2(A)Anthracene mg/L <0.00028 < 0.00028 <0.00028 <0.00028 <0:00028 icO.00028 <0.00028 <0.00028 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Ben20(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Ben20(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Diben2(A,H)Anthracene mg/L 0.00084 < 0.0002 <0:0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L 0.00082 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L 0.00045-' 0.00027-' <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L <0.01 <0.010 <o;oi' <0.01 <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 4130 5720 3920 4140 1790 2350 2350 3444 Dissolved Oxygen mg/L 0.01 4.75 2.28 1.88 1.18 0 0 1.27 PH S.U. 8.51 8.88 8.29 8.98 7.04 8.81 8.81 8.88 Redox Potential mv -144 -145 -149 -119 -113 -70 -70 -73.7 Temperature -0 13.4 13.2 18.9 17.9 17.3 18.2 18.2 17.70 Turbidity NTU 1000 1000 1000 1000 41 80 80 9.75 NOTES: Original taUe developed by Hull & Associates, Inc. Analytical data starting vrith the September 2013 event entered by GEO. (J) Estimated value detected between the MDL and the laboratory POL. («) Duplicate Sample (- ) Not analyzed (') No sample was collected.

Civil & Environmental Consultants, Inc. City ol Toledo-130-998 Fall 2013 Event

CITY OF TOLEDO SnCKNEY AVENUE LANDFILL

TABLES


Parameter Units 7/25/07 6/12A)8 9/23/09 10/6/10 9/15/11 10/3/12 9/25/13 9/25/13#

Metals Mercury mg/L <0.0002 < 0.0002 <0.0002 0.0000538 •" 0.0000284 •* 0.0000493 0.0000477" <0.000200



<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002

<0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <o:ooo5 <0.0005


mg/L mg/L mg/L

<0.00005 <0.00005 <0.00005

< 0.00005 <0.00005 < 0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

PAH'S Acenaphthene Benz(A)Anthracene Benzo(A)Pyrone Benzo(B)Fluoranthene Benzo(K)Fluoranthene Chrysene Dibenz(A,H)Anthracene lndeno(1,2,3-Cd)pyrene Naphthalene Pyrene


0.0013 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 0.0005

0.0061 •' 0.00017-'

0.00092 < 0.00026 < 0.0002 <0.00017 <0.0017 <0.010 < 0.0002 < 0.00022 0.0045 <0.010

<0.01 <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

0.00095 •' <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

Field Parameters Conductivity Dissolved Oxygen PH Redox Potential fetTiperature Furbldltv

umhos/cm mg/L S.U. mv °c

NTU

6400 0.01 6.62 -145 13.2 29

7680 3.74 6.68 -133 14.7 68

6300 1.63 6.46 -126 21.5 86

5360 0

7.05 -108 22.7 80

5420 1.1 7;i -44 19.7 22

5580 0

6;77 -55

19.9 46

5061 0.70 6.75 -86.2 21.78 15.1

5061 0.76 6.75 -86.2 21.78 15.1

NOTES: Original labia developed by Hull & Associates, Inc. Analytical data starting with the September 2013 event emered by CEC. (J) Estimated value detected between the MDL and the laboratory POL. (d) Duplicate Sample (-) Not analyzed (') No sample was collected.

Civil & Environmental Consultants, Inc. City ol Toledo -130-998 Fall 2013 Event


TABLES


1 Parameter Units 7/25/07 6/12/08 9/23/09 10/6/10 9/15/11 10/3/12 9/25/13

Metals Mercury mg/L <0.0002 < 0.0002 0.0000324 •' 0.0000587'' <0.0002 0.0000276 •' <0.000200

PCBs Aroclor 1016 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor1221 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0002 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.0019 •* 0.0018 0.00144 •' 0.0014 •' 0.00133 •• <0.01 <0.01 Benz(A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Dibenz(A,H)Anthracene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L 0.00078 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L 0.00014-' <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L 0.0003 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 5900 5740 5540 5090 4900 5070 5058 Dissolved Oxygen mg/L 0.01 4.15 1.91 1.2 2.3 0.68 1.66 PH S.U. 6.57 6.69 6.37 7.08 7.1 6.89 6.89 Redox Potential mv -175 -138 -130 -140 -140 -65 -64.8 Temperature "0 13.9 18.1 19 21.2 19.4 18.5 17.58

llTurbiditv NTU 26 47 71 49 9 33 5.67 NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti ttie September 2013 event entered by GEO. (J ) Estimated value detected between the MDL and the laboratory POL. (#) Duplicate Sample (--) Not analyzed (') Well was dry: no sample was collected.

Civil & Environmental Consultants, Inc. City of Toledo -130-998 Fall 2013 Event

CITY OF TOLEDO STiCKNEY AVENUE LANDRLL

TABLE 7


Parameter Units 7/25/07 6/12/08 9/23/09 10/6/10 9/15/11 10/3/12 9/26/13

PCBs Aroclor 1016 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 0.0192 <0.0005 Aroclor1221 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 0.00233 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0002 < 0.0005 0.0117 0.00166 <0.0005 0.0199 <0.0005 Aroclor 1260 mg/L <0.0002 < 0.0005 <0.0005 <0.0005 0.000973 0.0148 <0.0005

SEMIVOLAHLE ORGANICS DImethylaniline mg/L <0.01 <0.01 <0.01 <0.01 NO ND negative

VOCs' 4-Methyl-2-pentanone mg/L <PQL <PQL <PQL 0.00128'' <0.02 <0.02 <0.02

Acetone mg/L 0.058 <0.020 0.0269 0.0124-' 0.0159-' 0.0166 •' 0.0149-' Acetonltrlle mg/L <PQL <PQL <PQL <PQL <PQL <PQL 0.0377-' Benzene mg/L 0.022 0.016 0.0157 0.00889 0.0161 0.0201 0.0201 Chlorobenzene mg/L 0.0082 0.0049 •• 0.00682 0.00265-' 0.00755 0.00752 0.00817 Chloroethane mg/L 0.059 0.037 0.0204 0.0179 0.0175 0.0207 0.0148 Ethylbenzene mg/L <0.005 0.029 0.0366 0.00245-' 0.00545 0.0115 0.00736 M,p-Xylene mg/L 0.0043 •• 0.046 0.0874 0.00569 0.0141 0.0416 0.0249 Methyl Chloride mg/L -- 0.0044'' <0.005 <0.005 <0.005 <0.005 <0.005 Methyl tert-Butyl Ether mg/L <0.01 <0.01 0.00117-' 0.00134-' <0.01 0.0023-' 0.00221-' 0-Xylene mg/L <0.005 0.0019 •' 0.0138 <0.005 0.0011 -' 0.0154 0.0013T' Styrene mg/L <PQL <PQL <PQL 0.00069 -* <0.005 <0.005 <0.005 Toluene mg/L 0.0013 •' < 0.005 0.00181 •' <0.005 0.001 -' 0.00155-' <0.005

Reld Parameters Conductivity umhos/cm 5220 6220 1270 3500 3830 3970 3306 Dissolved Oxygen mg/L 0.12 6.1 1.59 1.46 1.7 0 1.55 pH S.U. 6.46 6.7 6.83 7.02 6.95 6.71 6.77

nRedox Potential mv -118 -182 -121 -124 -122 -78 -29.9 [Temperature "C 13.5 14.6 23 17.3 16.2 16.4 14.93 IrTurbidity NTU 13 140 1000 20 2 5 9.21 NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti ttre September 2013 event entered by GEO. (J ) Estimated value detected between tlie li^DL and ttie laboratory POL. (#) Duplicate Sample (--) Not analyzed (') No sample was collected. (1) Volatile Organic Compounds: Only volatile organlcs detected above ttie MDL or laboratory POL are listed.

Tire complete list of sampled organlcs can be found on ttie laboratory analytical report Included In Appendix C.

Civil & Environmental Consultants, Inc. City of Toledo- 130-998 Fall 2013 Event


TABLES


Paimneter Units 7/25/07 6/12/08 • 1

9/23/09 10/6/10 9/15/11 10/3/12 9/26/13

PCBs Aroclor 1016 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.025 0.862 <0.050 Aroclor 1221 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.025 <0.050 <0.050 Aroclor 1232 mg/L <0.0002 < 0.0005 <0.0005 <0.005 <0.025 <0.050 <0.050 Aroclor 1242 mg/L 0.047 < 0.0005 <0.0005 <0.005 <0.025 <0.050 <0.050 Aroclor 1248 mg/L <0.0002 0.074 0.186 <0.005 0.574 <0.050 <0.050 Aroclor 1254 mg/L <0.0002 < 0.0005 <0.0005 0.104 <0.025 0.649 <0.050 Aroclor 1260 mg/L 0.038 0.024 0-: 124 <0.005 0.326 0.443 0.048

SEMIVOLATILE ORGANICS pimethylaniline mg/L <0.01 <0.01 <0 1.01 <0.01 ND ND negative

VOCs' 1,1-Dichloroethane mg/L 0.13 0.072 0.00427 •' 0.053 0.015 0.00243 "* 0.00562

1,2-Dlchloroethane mg/L <PQL <PQL <FjQL 0.00205 •* <0.005 <0.005 0.00152"*

2-Butanone mg/L ~ 0.08 0.00978 •• 0.0238 0.0142"* 0.0107"* 0.0327

2-Hexanone nrig/L <PQL <PQL <FjQL <PQL <PQL <PQL 0.00581"*

4-Methyl-2-pentanone mg/L <1 <0.02 0.00823 •• 0.0542 0.0125"* <0.020 0.0466 Acetone mg/L <1 0.063 0.036 0.0362 <0.02 0.0373 0.0308

Acetonitrlle mg/L <PQL <PQL <FjQL 0.0345"' <0.04 <0.040 0.0191"* Benzene mg/L 0.14 0.11 0.0225 0.133 0.0832 0.0632 0.137

Carbon Disulfide mg/L <1 <0.02 0.00191 •• <0.02 <0.02 <0.02 <0.02 Chlorobenzene mg/L <0.25 < 0.005 <O!OO5 0.0258 0.0141 <0.050 0.0182 Chloroethane mg/L <0.25 0.043 0.011 0.0473 0.0514 0.0348 <0.005

Cls-1,2-dlchloroethene mg/L ~ 0.0045 <O!OO5 0.00846 0.00368 "* <0.005 0:00141"* Ethylbenzene mg/L 2.1 2 0.556 1.8 1.18 1.1 1.12

Hexane mg/L - 0.0034"' <O!OO5 <0.005 <0.005 <0.005 <0.005 M,p-Xylene mg/L 7.6 6.9 2J12 5.16 3.52 3.93 5.38 Methyl Chloride mg/L - 0.013 <O!OO5 <0.005 <0.005 <0.005 <0.005 Methylene Chloride mg/L 0.1 0.0043 •' <O!OO5 <0.005 0.00157 •* <0.005 0.00163"* 0-Xylene mg/L 4.5 3.7 i.2 3.03 1.97 1.91 2.63 Toluene mg/L 1.2 1.4 0.155 0.931 0.222 0.125 0.114 T rans-1,2-dichloroethene mg/L - 0.0028 <O!OO5 0.00325 "• 0.00169"* <0.005 0.00263"*

r rans-1,3-dichloropropehe mg/L <PQL <PQL <RQL 0.00229"* <0.005 <0.005 <0.005

Trichloroethene mg/L - 0.0011 •' <O!O05 <0.005 0.00092"* <0.005 <0.005 Vinyl Acetate mg/L <PQL <PQL <RQL 0.0006"* <0.01 <0.01 <0.01 Vinyl Chloride mg/L ~ 0.013 0.01 3129 0.0155 0.00697 <0.001 0.0024

Field Parameters Conductivity umhos/cm 16200 1900 3820 12900 2040 973 7017 Dissolved Oxygen mg/L 0.03 5.3 2J41 0 2 0 1.78 PH S.U. 6.82 6.98 6)26 7.5 6.79 6.39 6.76 Redox Potential mv -155 -187 -131 -239 -145 -34 75.6 Temperature °C 16.2 14.9 1^6 20.4 17.6 18.1 18.28 Turbidity NTU 188 1000 107 160 43 63 159 II NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti the September 2013 event entered by GEO. (J) Estimated value detected between the MDL and the laboratory POL. (#) Duplicate Sample (--) Not analyzed (*) No sample was collected. (1 ) Volatile Organic Compounds: Only volatile organlcs detected above the MDL or laboratory POL are listed.

The complete list of sampled organlcs can be found on the laboratory analytical report Included In Appendix C

Civil & Environmental Consultants, Inc. City of Toledo-130-998 Fall 2013 Event

APPENDIX C-2: TYLER STREET LANDFILL


CITY OF TOLEDO TYLER STREET LANDFILL

TABLE 9

LABORATORY ANALYTICAL DATA REPORTED FOR T-MW-19LP

Paremeter Units 7/24/07 7/24/07# 6/12Wa 6/12A)8# 9122m 10/5/10 10/5/10# 9/14/11 10/2/12 9/27/13

Metals Mercury mg/L 0.00032 0.0003 0.00036 0.00034

1 (1.000206 I

0.000301 0.00029 0.000175-' 0.000219 0.000149-'

PCBs ArodorlOie Aroclor1221 Arodor 1232 Aroclor 1242 Aroclor 1248 Aroclor1254 Aroclor1260


<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 < 0.0005 < 0.0005 < o;ooo5 < 0.0005 < 0.0005 < 0.0005

< 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005

1

«.0005 !<0.0005 <0.0005 ^.0005 <0.0005 <0.0005 ieO.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0025 <0.0025 <0.0025 <0.0025 <0.0025 <0.0025 <0.0025

<0.0005 <0.0005 <0.0005 0.00254 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT Aldrin Heptachior

mg/L mg/L mg/L

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

< 0.00005 < 0.00005 < 0.00005

<0.00005 < 0.00005 < 0.00005

i 1

<0.00005 <0.00005 <0.00005

1

<0.00005 <0.00005 <0.00005

<0.00025 <0.00025 <0.00025

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

PAH-s Acenaphthene Benz(A)Anthracene Benzo(A)Pyrene Benzo(6)Ruoranthene Benzo(K)Ruoranthene Chrysene Dibenz(A,H)Anthracene lndeno(1,2,3-Cd)pyrene Naphthalene Pyrene

mg/L mg/L mg/L mg/L mg/L

mg/L mg/L mg/L mg/L mg/L

<0.01 <0.00026 0.00068 0.00091 0.0008'' 0.00042''

0.0021 0.003 0.017

0.00067 •"

0.00039 •' <0.00026 0.00075 0.001

0.00082'' 0.00048 •'

0.003 0.003 0.015

0.00053 •'

0.00027 •' < 0.00026 < 0.0002 < 0.00017 <0.0017 <0.010 <0.0002 < 0.00022 0.00043

0.013

0.00042-' <0.00026 < 0.0002 <0.00017 <0.0017 <0.010

< 0.0002 < 0.00022 0.0006 -' 0.016

1 <0.01 <0.00026 ieO.0002 <0.00017 <0.0017 ! <0.01 k).0002 <0.00022 0.00915^

j <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.00682-'

<0.01

<0.01 <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.00387 •' 0.00084^

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 0.0194 <0.01

<0.01 <0.00026 <0.0002 <0.00017 <0.0017

<0.01 <0.0002 <0.00022 0.0197 <0.01

Field Parameters Conductivity Dissolved Oxygen pH Redox Potential Temperature Turtiidltv

umhos/cm mg/L S.U. mv °C

NfU

7410 0.09 6.79 -205 13.1 1000

7410 0.09 6.79 -205 13.1 1000

9250 5.47 6.79 -95

14.2 1000

9250 5.47 6.79 -95 14.2 1000

6370 ; 3.19 1 6.79 I -187 1 14

. 1 15

6150 0

7.34 -189 13.9 72

6150 0

7.34 -189 13.9 72

5200 2.62 7.08 -194 13.5 32

5540 0.33 7.23 -152 13.5 51

4899 1.87 7.48 -1.5 14.82 37.5 II

NOTES: Original tabto developed by HuD A Assodates, Inc. Analytical data starting with the September 2013 event entered by CEC. N) Estimated vahie detected betmn the MDL and the laboratory PQL («) Duplicate Sample {-) Not analyzed (*) No sample was collected.

Civil A Environmental Consultants, Inc. City of Toledo - 130-998 Fall 2013 Event


TABLE 10


Parameter UnHs 7/24/07 6/12/08 6/12A)8# 9/22/09 10/5/10 9/14/11 9/14/11# 10/2/12 9/27/13

Metals Mercury mg/L <0.0002 0.0001 0.0001 <0.0002 0.000165"* 0.0000617"* 0.0000311 •* <0.0002 <0.0002

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 < 0.0005 <00005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1221 mg/L <0.0005 < 0.0005 < 0.0005 <0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 < 0.0005 < 0.0005 <0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 < 0.0005 <0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 < 0.0005 <0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 < 0.0005 < 0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 < 0.0005 <0.0005 <0.00025 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4.4 - DDT mg/L <0.00005 < 0.00005 < 0.00005 <0.00005 <0.000025 <0.00005 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.000025 <0.00005 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 < 0.00005 <0.00005 <0.000025 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.00046 •* 0.00058 0.00058 •' <0.01 <0.01 <0.01 0.00053 •* <0.01 <0.01 Benz(A)Anthracene mg/L <0.00026 < 0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Beiizo(A)Pyrene mg/L <0.0002 < 0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Ben20(B)Fluoranth8no mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 < 0.010 < 0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Dibenz(A,H)Anthracene mg/L <0.0002 < 0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L <0.00022 < 0.00022 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L <0.01 < 0.010 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L <0.01 0.00062"' 0.00062"' <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 3310 3440 3440 3110 2890 2880 2880 2950 3257 Dissolved Oxygen mg/L 0.39 5.64 5.64 2.71 0.59 2.08 2.08 0.3 2.24 pH S.U. 6.45 6.72 6.72 6.49 7.09 6.71 6.71 6.97 7.31 Redox Potential mv -154 -129 -129 -147 -119 -119 -119 -94 2.9 Temperature •c 13.9 14.6 14.6 13.7 13.5 13.1 13.1 13.1 16.22 Turtiiditv NTU 364 1000 1000 45 52 40 40 17 38.2 NOTES: Original table developed by HuO S Asso Inc. Analytical data starting wMi the September 2013 event entered by GEO. (J) Estlmatad value detected between the MDL and the laboratory POL. (#) Duplicate Sample () Not analyzed

ONosamplewas collected.

Civil & Environmental Consultants, Inc. CItyolToledo-130-998 Fall 2013 Event

CITY OF TOLEDO TYLER STREET LANDHLL

TABLE 11


Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12 10/2/12# 9/27/13

Metals Mercury mg/L <0.0002 0.000072 0.000154 •• 0.0000977 •• 0.000149-' 0.000188-' 0.000179-' <0.0002

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1221 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 0.00445 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT mg/L <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.0026 •• 0.0028 •' 0.00259 0.00263 •* 0.00284'' 0.00296-' 0.00294 -' 0.00227-' Benz(A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Dlbenz(A,H)Anthracene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L <0.00022 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L <0.01 0.0019 •' <0.01 0.00048'' <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 6170 9840 5830 5570 5480 5500 5500 5324 Dissolved Oxygen mg/L 0.1 3.56 2 0 1.5 0.13 0.13 1.41 pH S.U. 6.7 6.9 6.81 7.23 7.08 7.11 7.11 7.49 Redox Potential mv -180 -149 -159 -145 -138 -112 -112 -0.7 Temperature "C 17.8 19.6 20.2 19.4 20.5 19.4 19.4 21.56 Turbidity NTU 0.09 1000 9 8 2 9 9 8.67 NOTES; Original table developed by Hull S Associates. Inc. Analytical data starting wItt) tite iSeptember 2013 event entered by CEC. (J) Estimated value detected between the MDL and the laboratory POL. («) Duplicate Sample (-) Not analyzed (*) No sample was collected.

Civil & Environmental Consultants, Inc. City olToledo-130-998 Fall 2013 Event


TABLE 12


1 Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12 9/26/13

Metals Mercury mg/L <0.0002 < 0.0002 0.0000738 •' 0.0000494 "* <0.0002 <0.0002 <0.0002

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1221 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Heplachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.0021 0.0017"' 0.00117"' <0.01 0.00165"' 0;00218"' 0.00149"" Benz(A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0,0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Dibenz(A,H)Anthracene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L <0.00022 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L <0.01 0.00036 •' <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L 0.0003 0.0028"' <0.01 0.00036"" <0.01 <0.01 <0.01

Field Parameters Conductivity u mhos/cm 8650 12800 8310 7560 7640 7930 7169 Dissoived Oxygen mg/L 0.06 3.6 2.02 0.06 2.04 0.14 1.95 pH S.U. 6.59 6.81 6.77 7.27 7.01 7.09 7.36 Redox Potential mv -179 -159 -176 -159 -147 -113 38.4 Temperature °C 14.6 16.9 17.1 16.2 17.4 14.8 15.47 Turbidity NTU 13.91 84 2 23 2 6 9.97 NOTES: Original tabia developed by Hull & Associates, Inc. Analytical data starting with the September 2013 event entered by CEC.

(J ) Estimated value detected between the MDL and the laboratory POL.


(--) Not analyzed

(') No sample was collected.

Civil & Environmental Consultants, Inc. CItyof Toledo-130-998 Fall 2013 Event


TABLE 13


Parameter Units 7/24/07 6/12/08 9122m 9/22/09# 10/5/10 9/14/11 10/2/12 9/26/13

Metals Mercury mg/L <0.0002 0.000092 •' 0.0000358 •' 0.000195 0.0000543 •" <0.0002 . <0.0002 <0.0002

PCBs ArDclor 1016 Arocior 1221 Aroclor 1232 Arocior 1242 Aroclor 1248 Arocior 1254 Aroclor 1260


<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

< 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 < 0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT Aldiin Heptachlor

mg/L mg/L mg/L

<0.00005 <0.00005 <0.00005

< 0.00005 < 0.00005 < 0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

<0.00005 <0.00005 <0.00005

PAH'S Acenaphthene Benz(A)Anthracene Ben2o(A)Pyrene Benzo(B)Fluoranthene Benzo(K)Fluoranthene Chrysene Dibenz(A,H)Anthracene lndeno(1,2,3-Cd)pyrene Naphthalene Pyrene


0.0023 •• <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 0.00031

0.0016 < 0.00026 <0.0002

<0.00017 <0.0017 <0.010 < 0.0002

< 0.00022 0.00039 •' 0.0011 •'

0.00152-' <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

0.00165 •" <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

<0.01 <0.00026 <0.0002

<0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 0.00158-'

0.00186 •" <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022

<0.01 <0.01

0.00276 •• <0.00026 <0.0002 <0.00017 <0.0017

<0.01 <0.0002

<0.00022 <0.01

0.0009 •'

0.00231'' <0.00026 <0.0002 <0.00017 <0.0017

<0.01 <0.0002 <0.00022

<0.01 <0.01

Field Parameters Conductivity Dissoived Oxygen pH Redox Potentiai Temperature Turbidity

umhos/cm mg/L S.U. mv °G

NTU

7620 0.02 6.69 -177 13.3

1

9350 4.51 6.98 -139 14.2 92

7180 2.34 6.66 -173 13.6 24

7180 2.34 6.86 -173 13.6 24

6820 0:02 7.35 -159 13.8 48

6640 2.08 7.14 -150 16.1 69

6210 0

7.24 -111 13.2 19

6061 1.22 7.44 18.0 13.88 21.2

NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting with the September 2013 event entered by CEC. (J) Estimated value detected tietween the MDL and the latxiratory POL. (») Duplicate Sample (-) Not analyzed (*) No sample was collected.

Civil & Environmental Consultants, Inc. City of Toledo-130-998 Fall 2013 Event


TABLE 14


Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12 9/26/13

Metals Mercury mg/L 0.00016 •' 0.00018'' 0.0000758 •' 0.000248 0.000209 0.0000866-' 0.000154-'

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor1221 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 <0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 0.00261 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005

Pesticides 4.4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.00042 •' 0.0006 •' <0.01 <0.01 0.00042 -' <0.01 <0.01 Benz(A)Anthrac8ne mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Dibenz(A,H)Anthracene mg/L 0.0012 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L 0.0012 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L 0.0078 <0.010 0.00671 •' 0.00079-' 0.00543 -' 0.00674 -' 0.0114 Pyrene mg/L 0.00033 •' <0.010 <0.01 0.00068'' <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 11100 10700 9240 8560 7900 7970 6996 Dissolved Oxygen mg/L 0.03 4.37 2.03 0 2.12 0 1.4 pH S.U. 6.82 6.99 6.97 7.46 7.3 7.35 7.53 Redox Potential mv -208 -173 -193 -184 -190 -149 -7.9 Temperature "0 14.7 14.6 14.3 14.1 14.2 13.5 14.20 Turbidity NTU 121 110 56 122 85 273 186 NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti the September 2013 event entered by GEO.

(J) Estimated value detected between the MDL and the laboratory POL.


(--) Not analyzed

(*) No sample was collected.

Civil & Environmental Consultants, Inc. City of Toledo -130-998 Fall 2013 Event


TABLE 15


Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12

Metals Mercury mg/L 0.00012'' 0.00008 •' 0.0000652 -' 0.000115-' 0.0000952 -' 0.0000476 -' <0.0002

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1221 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 <0.0005 <0.0025 <0.0005 <0.0005 <0.0005

Pesticides 4.4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Aldrin mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00025 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L 0.00042 0.00063 •' <0.01 <0.01 <0.01 <0.01 <0.01 Benz(A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Dlbenz(A,H)Anthracene mg/L 0.0014 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L 0.0011 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L 0.00041 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L 0.00016-' 0.0013-' <0.01 0.00059-' <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 4490 5000 4720 • 4360 4240 4690 4208 Dissolved Oxygen mg/L 0.71 5.84 2.04 0 2.09 0 1.86 pH S.U. 6.41 6.65 6.57 7.03 6.81 6.95 7.26 Redox Potential mv -138 -114 -134 -119 -118 -84 18.8 Temperature °G 12.7 12.8 13.3 13.6 14.9 13.4 14.86 Turbidity NTU 25 18 23 75 19 25 5.08 II NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti ttie September 2013 event entered by CEC.

(J ) Estimated value detected between the MDL and the laboratory POL.


(--) Not analyzed

(*) No sample was collected.

Civil & Environmental Consultants, Inc. City of Toledo -130-998 Fall 2013 Eveni


TABLE 16


Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12 9/26/13 9/26/13#

Metals Mercury mg/L <0,0002 0.000093 •' 0.000046 •' <0.0002 <0.0002 <0.0002 <0.0002 <0.0002

PCBs Aroclor 1016 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor1221 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1232 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1242 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1248 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1254 mg/L <0.0005 < 0.0005 <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 Aroclor 1260 mg/L <0.0005 < 0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

Pesticides 4,4 - DDT mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Aidrin mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 Heptachlor mg/L <0.00005 < 0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005

PAH'S Acenaphthene mg/L <0.01 0.00027 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Benz(A)Anthracene mg/L <0.00026 < 0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 <0.00026 Benzo(A)Pyrene mg/L <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Benzo(B)Fluoranthene mg/L <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 <0.00017 Benzo(K)Fluoranthene mg/L <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 <0.0017 Chrysene mg/L <0.01 <0.010 <0.01 <0.01 <0:01 <0.01 <0.01 <0.01 Dibenz(A,H)Anthracene mg/L <0.0002 < 0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 lndeno(1,2,3-Cd)pyrene mg/L <0.00022 < 0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 <0.00022 Naphthalene mg/L <0.01 <0.010 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Pyrene mg/L <0.01 0.00056 •' <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Field Parameters Conductivity umhos/cm 5780 8720 5880 5480 5170 5420 5797 5797 Dissolved Oxygen mg/L 0.29 3.2 1.38 0.14 1.27 0 3.14 3.14 pH S.U. 6.55 6.83 6.73 7.15 6.99 7.03 7.18 7.18 Redox Potential mv -167 -152 -161 -156 -152 -116 -17.4 -17.4 Temperature "0 21.2 17.6 19.4 21.8 21.5 21.1 22.84 22.84 Turbiditv NTU 2 28 9 46 5 10 17.7 17.7 NOTES: Original table developed by Hull & Associates, Inc. Analytical data starting witti the September 2013 event entered by CEO. (J) Estimated value detected between the MDL and the laboratory POL. (#) Duplicate Sample (-) Not analyzed (*) No sample was collected.

Civil & Environmental Consultants, Inc. City olToledo-130-998 Fall 2013Even1


TABLE 17 \


Parameter Units 7/24/07 6/12/08 9/22/09 10/5/10 9/14/11 10/2/12 9/26/13

Metals Mercury

PCBs Aroclor 1016 Aroclor1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260


PAH'S Acenaphthene Benz(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(K)Fluoranthene Chrysene Dibenz(A,H)Anthracene lndeno(1,2,3-Cd)pyrene Naphthalene Pyrene

Field Parameters Conductivity Dissolved Oxygen H

[Redox Potential emperature urbid||^____^_^_

mg/L


mg/L mg/L mg/L


umhos/cm mg/L S.U. mv "C

NTU

<0.0002

<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005

<0.00005 <0.00005 <0.00005

<0.01 <0.00026 <0.0002 <0.00017 <0.0017 <0.01

<0.0002 <0.00022 <0.01 <0.01

3330 0.04 6.56 -202 15.2 2

0.00035

< 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005 < 0.0005

< 0.00005 < 0.00005 < 0.00005

<0.010 < 0.00026 < 0.0002 <0.00017 <0.0017 <0.010

< 0.0002 < 0.00022 <0.010 0.001 ''

7610 3.79 6.98 -172 16.8 1000

NOTES:

Original table developed by Hull & Associates, Inc. Analytical data starting witti ttie September 2013 event entered by GEO.

(J ) Estimated value detected between the litDL and the laboratory POL.


(-) Not analyzed

(*) Well was dry; no sample was collected.

Civil & Environmental (Consultants, Inc. City ot Toledo -130-998 Fall 2013 Event

APPENDIX D

EXPLOSIVE GAS MONITORING FIELD DATA SHEETS


APPENDIX D-1: STICKNEY AVENUE LANDFILL


STIGKNEY AVENUE LANDFILL TOLEDO, OHIO

METHANE MONITORING RELD DATA SHEET

TESTING COMPLETED BY:

C02/02 INSTRUMENT TYPE:

CALIBRATION GAS:

David Benecke/Steve Hoyt

GEM 2000

15% CH4/15% C02

DATE: 9/27/13

DATE LAST CALIBRATED:

SAMPLING METHOD: Air pump

9/27/13

PRESSURE INSTRUMENT TYPE: _

WATER LEVEL INSTRUMENT TYPE:

GEM 2000

Slope Indicator

Probe Designation

Time of Sampling Pressure^

Percent Combustible

Gas' %LEL'

Percent Gas' Depth to

Water"

Depth to Top of

Screen"'®

Punch Bar Results® Probe

Designation Time of

Sampling Pressure^

initial Sus

tained

%LEL'

O2 CO2

Depth to

Water"

Depth to Top of

Screen"'® Percent Gas'

Percent LEL"

S-GP-1S 1854 0.00 0.0 0.0 0 4.2 16.9 5.42 - 0.0 0

S-GP-1D 1859 -6.78 0.0 0.0 0 14.5 5.1 4.90 - 0.0 0

S-GP-1A 1904 0.00 0.0 0.0 0 14.3 9.8 DRY •- 0.0 0

S-GP-2S 1625 -7.90 0.0 0.0 0 11.8 3.4 3.57 0.0 0

S-GP-2D 1642 30.35 WATER WATER WATER WATER WATER 6.72 0.0 0

S-GP-2A 1659 -0.14 0.0 0.0 0 18.8 1.2 3.96 0.0 0

S-GP-10S 1757 0.00 14.5 14.7 >100% 0.4 16.5 DRY 0.0 0

S-GP-10D 1801 0.00 11.1 11.2 >100% 0.1 16.0 DRY 0.0 0

S-GP-11S 1815 NA NA NA NA NA NA NA 0.0 0

S-GP-11D 1815 NA NA NA NA NA NA NA 0.0 0

S-GP-12 1729 0.00 37.5 37.4 >100% 0.6 11.2 4.65 0.0 0

S-GP-14 1835 NA NA NA NA NA NA NA 0.0 0

S-GP-15 1839 NA NA NA NA NA NA NA 0.0 0

BE-BP-01 1911 - - - - - - - 0.0 0

BE-BP-02 1913 - - - - - - - 0.0 0

NOTES: 1 .

2 . 3 . 4 . 5 . 6 .

7 .

All pressure readings are expressed as inches of H2O.

All readings are 0-100% gas by volume by air. (LEL) Lower Explosive Limit. All depth measurements are expressed in feet. Top of Screen depths from the top of casing as indicated on individual explosive gas probe log. Punch bars are performed within five feet of the gas probe whenever there is water in the gas probe; or within the vicinity of wells that cannot be located. NA indicates that this probe could not be located.

30.16 In. Hg Clear North 5-10 mph

CLIMATOLOGICAL CONDITIONS Ambient Barometric Pressure: Observed Weater Conditions: Wind Direction and Speed: Relative Humidity: Ambient temperature: COMMENTS: The air pump on the GEM-2000 was stopped at S-GP2D to avoid damage to the meter as water was immediately into the tubing during measurement; therefore, no measurements were able to be recorded.

67% 60T

APPENDIX D-2: TYLER STREET LANDFILL


TYLER STREET LANDFILL TOLEDO, OHIO

METHANE MONITORING FIELD DATA SHEET

TESTING COMPLETED BY;

C02/02 INSTRUMENT TYPE:

CALIBRATION GAS:

DavicI Benecke/Steve Hoyt

GEM 2000

15% CH4/15% C02

DATE:

DATE LAST CALIBRATED:

SAMPLING METHOD:

9/27/13

9/27/13

Air pump

PRESSURE INSTRUMENT TYPE: _

WATER LEVEL INSTRUMENT TYPE:

GEM 2000

Slope Indicator

Probe Designation

Time of Sampling Pressure^

Percent Combustible

Gas^ %LEL' Percent Gas^

Depth to Water^

Depth to Top of

Screen*'®

Punch Bar Results® Probe

Designation Time of

Sampling Pressure^

initial Sus

tained

%LEL'

O2 CO2

Depth to Water^

Depth to Top of

Screen*'® Percent Gas'

Percent LEL*

T-GP-01S 1317 -0.13 0.0 0.0 0 20.9 0.1 4.31 - 0.0 0

T-GP-01D 1321 -4.02 0.0 0.0 0 10.1 7.3 5.82 - 0.0 0

T-GP-02S 1338 0.00 0.0 0.0 0 3.0 14.8 DRY - 0.0 0

T-GP-02D 1346 0.00 0.0 0.0 0 18.8 1.5 10.22 - 0.0 0

T-GP-03S 1456 0.00 0.0 0.0 0 17.2 3.0 DRY - 0.0 0

T-GP-03D 1459 0.00 0.0 0.0 0 3.5 9.8 DRY - 0.0 0

T-GP-07S 1434 NA NA NA NA NA NA NA - 0.0 0

T-GP-07D 1434 NA NA NA NA NA NA NA - 0.0 0

T-GP-07A 1434 NA NA NA NA NA NA NA - 0.0 0

T-GP-10S 1238 0.00 69.4 68.9 >100% 0.1 30.4 4.67 - 0.7 14

T-GP-10D 1244 0.00 0.2 0.1 4.0 16.6 5.9 10.05 - 0.0 0 .





T-GP-15 1445 NA NA NA NA NA NA NA - 0.0 0

Horizon. Well 1400 0.00 28.2 28.2 >100% 2.8 11.1 - - 0.0 0

Pre-System 1404 0.00 27.9 27.9 >100% 4.7 9.8 -• - 0.0 0

Btwn GACs 1407 0.00 17.0 17.0 >100% 2.2 11.5 - - 0.0 0

Post-System 1410 0.00 16.9 16.9 >100% 5.4 11.5 - - 0.0 0

NOTES: 1 .

2 . 3 . 4 . 5 . 6 .

7 .

CLIMATOLOGICAL CONDITIONS Ambient Barometric Pressure: _ Observed Weater Conditions: _ Wind Direction and Speed: Relative Humidity: Ambient temperature: COMMENTS:

All pressure readings are expressed as inches of H2O.

All readings are 0-100% gas by volume by air. (LEL) Lower Explosive Limit. All depth measurements are expressed In feet. Top of Screen depths from the top of casing as Indicated on Individual explosive gas probe log. Punch bars are performed within five feet of the gas probe whenever there is water in the gas probe; or within the vicinity of wells that cannot be located. NA indicates that this probe could not be located.

30.16 In. Hq Clear North 5-10 mph 67% 60*F Gas extraction system blower not operational.

APPENDIX E

LEACHATE MONITORING WELL, EXPLOSIVE GAS PROBE, AND LANDFILL INSPECTION FORMS


APPENDIX E-1: STICKNEY AVENUE LANDFILL


FIGUBE^rl LANDFILL INSPECHON FORM STlGKNEY/mJCR LANDFILLS

TOLEDO, OHIO

Today's Date: ^h'l\\'S

Your name:

Are you completing this form for: •

(Please use a separate form for each landfill)

Kem Yes or No

SECURITY

1. Is perimeter fencing intact:

2. Are posted signs present and in good condition:

3. Were gates locked and locks-ifftact:

4. Are gates-wd.ipdcs easy 'I • toopen? '

ACCESS ROAD

5. Does access road have rock surface laya7 (List any areas requiring placement of additional rock.)

6. Is access road and adjacent turf free of ruts? (List any areas requiring repair with rock or top-soil)

\/

r • I

vy I

Stickney Avenue Landfill TVIef Stmt Landfill

Recommended Corrective Action And

Schedule for Completion

r><-rW<t.v%kr.

C)

rvor+k 4crvctV\ lo/u-A-f-i^)

V J

n

Item.

FIGURE 3-1 LANDFILL INSPECTION FORM SirCKNEY/rYLER LANDFILLS

TOLEDO»OmO

Yes or No Recommended Corrective Action And


7. Are grassed areas adiacent to access road free of ruts? (List any areas requiring

lor r VKCETATION

D 8. Is this vegetation

on the top and side slopes free from bare spots and of sufficient density to protect cover y system?

jOnthe jn good V

10. Are the perimet^ trees free from observable stress and frdlen limbs? Y

11. Is the surface free of any evidence of rodents or \J burrowing animals? _

12. Is the sur&ce free of woody vegetation other y th^ perimeter trees?

Yeyi ^ "HA* 6-f fM

n FKGURS3-1

LANDFILL INSFECXION FORM STICKNEY/TVLER LANDFILLS

TOLEDO, OHIO

Item

13. Are the slopes or perimeter features free of any evidence of gas migration (stressed vegetation)?

Yes or No

1

Recommended Correctiye Action And

Sdiedule for Completion

14. Are the slopes or perimeter features free of any evidence of leachate migration (excessive riprap staining or surface water discoloration)?

DRAINAGE AND EROSION CONTROL

V/ (

15. Are draUâge^^s free from obstSnctiOn?

16. Are erosion control materials intact?

17. Are ail surfaces free of erosion rills?

I

r

SETTLEMENT CONTROL

18. Are sur&ce slopes uniform without local depressions or poirded areas? Y

.^.Qr+k 6-f lAi.l-'ST Lp Car , -i'.ec ^tj>r<^siavi S£>'-K ZS' t-z'

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Item

FIGinR£3-l lANDmL INSPECTION FORM STiCkNEYm^ LANDFILLS

TOLEDO, OmO

Yes or No Recommended Correcdve Action And


o

(J

RIVERBANK STABILITY

19. Does slope area appear to be stable and of localized settlement or slumps?

20. Is berm in place at top of slope and fiee of erosion or washouts?

21. Are underdrain outlet pipes (500-foot inter-vats) intact and drain freely?-

22. Are uiidetdr^n outlet -. Pipe markers pt^nt?

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3 5 MA./1 Mflî IrKt*" J O'-'S lactîcJ i>A-

0^ ti^cuOiS

23. Are slope momtoring points intact and appear to be in normal alignment?

24. Are letdown channels intact and free of erosion, damage or debris? Y

25. Is riprap intact and free of localized depressions or voids in riprap slope cover? V

/ fjJi

6lca-r ^

nGinR£3-i LANDFILL INSPFCTIQN FORM STlCKNEY/ryLER LANDFILLS

TOLEDO, bmo

Item Yes or No Recommended Corrective Action. And


26. Is riprap berm at bottom of riprap slope intact and free of erorion \j or undercutting? _J_

27. Is riprap sur&ce free of debris and excessive woody vêtation? Y

Description of recommended action: (attach additional pages as required)

Item Number Description ()

I. J

o FIGURE3-2

MONITORING WELL INSPECTION FORM SUCKNEY/TYLER LANDFILLS

Name; /<ykv^ Uaî' Affiliation: O-"' / ̂ rtv\ MC-M.

Date: Time: Tl^r,

Location/Identification 1. Is the well accessible:

SuifeceSeal 5. Is suil&ce seal damped?

8, Is casing in good. condition?

Internal Casine 11, Is the internal casing at least 1 foot above ground? ^

2. Is the well protected: from traffic?

6; Is the seal secure again^ the casing and ground?

9. Is casing locked? 12. Is internal risd-within 2 inches of topcap?

3. Is the well in low spot or standing water?

10. Is lode in good condition?

13. Is casing free of dd)ris, kinks, bends? .

4. Is the weli laired insiide and out?

7. Is &e seal sloped away from the wellhead?

14. Is c^ in good condition?

o

/

WellLD. Inspected Requires Action

Items/Problems Requiring Action (list number from above)

SMW-21 LP E • SMW-24LP B 0 SMW.27LP •B 0 WfN SMW-30LP , • 10,11 S1TO-33LP • SMW-351J -S3r - • I'OflK SiMW-36LP • cOfll SMW^37LP 10 • lOjll TMW-19LP • 0 TMW-21LP • • TMW-23LP • • TMW-25LP • • 4-

TMW.27LP . • • TMW-29LP • • TMW-31LP • • TMW-33LP D 0 TMW-35LP • •

• •

Attach a detailed description of recommended actions at specific locations : fteJCi oA- |<*ckA.4c fê.<tt,u*A>icr^ -Z7

-^9«.P-5CLP,^-37 SA1«0-ZqtP,-5t>Cl'^.'JucP,^-'S7cJ>

**7 CoCrootuP ««\ ufcUct)^ JS.+ - ̂ 7 LP -"iffj"

FIGURE 3-3 GAS MONITORING WELL INSPECTION FORM

STICKNEY/TYLER LANDFILLS

Name:

Date;

Affiliation: •

Time:

Location/Identification ...Vents Probes 1. Is the probe/vent accessable? ,

5. Is the vent damaged and n^ repair?

7. ê the probes and/or c^ngs damaged and need jepwi?

2. Is the pipbein low spot or ̂ ahding watiE»7

6. Are the vent sampling ports damaged and need repair?

i8: Are probe casings visible?

3. Is probe/vent free of obstruction? ^

9. Is probe ewing subject to being submiQFged?

4. Is the jMobe/vent labeled inside and out?

WeU Probe/Vent LD.

laspecte d

Requires Action

Item^rpblems Requiring Action 0ist number from above)

S-GP-IS B. • S-GP-ID 0 • V S-GP-IA B • S-GP-2S » • S-C3P-2D B - . • S-GP^^2A 'TrW . • S-C»-10S • S-GP-IOD a . . • S-GP-llS 0 • 'ft) /OC.4.4<.

S-GP-llD • • liMOtUS' "k /OCA.'U-

S-GP-12 • . be S-GP-I4 • • .. 4o /oca^ S-GP-I$ •. • •0 BE-BP-OI BL BE-BP-02 0 • . UMALU 4«) tL.ccxii T-GP-OIS 0 • T-GP-OID • • T-GP-02S • • T-GP-02D • • T-GP-03S • • T-GP-03D • •

u

r-!

O

T-GP-07S 0 • -i'- • •

T-GP-07D 0- 0 T-GP-07A • • T-ca»-ios • -a'' i ••*'*•••. «

T-GP-lOP • . • T-GP-llS • • T-GP-UD • 0 T-GP-12S • • T-GP-12D • • T-GP-15 0 •

Horirohtal Well •• . • Pre-System • • Btwn GACs .• . . • POist - Sys • •

• • • :u-•

Attadi a detailed description of reconunended actions at ̂ ecific locations below;

p«-oV>< neA.r 4-<yr~ M neA-i: ) prfri" prfrj*^ »vcff/' A(>^4- pfaleO

l>fi>\a«. V^M^wS•

( i

APPENDIX E-2: TYLER STREET LANDFILL


r'^ HGUBE^-l

LANDFILL mSPECTEON FORM STIGKNEY/XYUSR LANDFILLS

TOLEDO, OHIO

Today's Date:,

Your name: \î

Are you completing this form for: • Stickney Avenue Landflll Qs Xyi^St^t Landflll

(Please use a separate form for each landflll)

' Item Yes or No

SECURITY

1. Is perimeter fencing intact:

2. Are poêd signs present and in good condition:

3. Were gates locked and locks-ifftact:

4. Are gates'wd.locks easy • to open? ^

ACCESS ROAD

5. Does access road have rock surface laya7 (Ust any areas requiring placement of additional rock.)

6. Is access road and ad> jacent turf free of ruts? (List any areas requiring repair with rock or top-soil)

I

Y

Y Y

r


Sdiedule for Completion

.OIA

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C\tMr -prtrwv

r')

! )

O'

Item.

FIGURE 3-1 LANDFILL INSPECTION FORM STTCKNEY/TYLER LANDFILLS

TOLEDO, OHIO



7. Are grassed areas adjacent to access road free of tuts? (List any areas requiring grîng, topsoil or seeding)

VEGETATION

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( )•

()

8. Is this vegetation oh die top and side slopes free fi-pm bare spots and

. of sufficient density to protect cover V system?

9. Is the ptêj^nt An the parldng in good

--. repair ? "

10. Are the perimeter trees firee from observable stress and frdlen limbs?

11. Is the surface free of any evidence of rodents or burrowing animals?

12. Is the surface free of woody vegetation other than perimeter trees?

Y

Y

FIGURE 3-1 LANDFILL INSFECHON FORM SnCKNEY/IYLER LANDFILLS

TOLEDO, OmO

Item

13. Are the slopes or perimeter ̂ tures free of any evidence of gas migration (stressed vegetation)?

Yes or No

V I



14. Are ̂ slopes or perimeter features fiiee of any evidence of leachate migration (excessive riprap staining or surface water discoloration)?

C)

DRAINAGE AND EROSION CONTROL

- •-15. Are draâ|;e;^s free

from obstiijctipn?

16. Are erosion control materials intact?

17. Are all surfaces free of erosion rills?

KJ

i r

I'tVtlorvJVvS

SETTLEMENT CONTROL

18. Are surface slopes uniform without local depressions or ponded areas?

i/ fill Tiv

Item

FIGIJRE 3-1 LANDFILL m^PECnON FORM siiCKmYrii^ LANDFILLS

ITOLEDO, OmO



RIVERBANK STABILmr

C)

19. Does slope area appear to be stable and fiee of localized settlement or slumps?

20. Is berm in place at top of slope and fiee of erosion or washouts?

21. Are underdrain outlet pipes (500-foot intervals) intact and drain freely?-

'J

y

V

A 22, Are undet5drAip outlet . •. Pipe maricers pt^nt?

23. Are slope monitoring points intact and appear to be in normal alignment?

r/w')

24. Are letdown channels intact and free of erosion, damage or debris? r

25. Is riprap intact and free of localized depressions or voids in riprap slope cover? V

FIGURE 3-1 LANDFILL INSPECTION FORM STTCKNEY/TYLER LANDFILLS

TOLEDO, OmO

Item Yes or No Recommended Corrective Action. And


26. Is riprap berm at bottom of riprap slope intact and free of erosion \j or undercutting? _J_

27. Is riprap sur&ce free of debris and excessive woody vegetation? ,

Description of recommended action: (attach additional pages as required)

Item Number Description

i. )

FIGURE 3-2 MONITORING WELL INSPECTION FORM

SUCKNEY/TYLER LANDFILLS

Name; Affiliation; C-t'i 1'Êm/i

Date; *1/t.6'Z-7^/ 5 ^ Time; -rLnn*-»^'t"

Location/Identification SurfeceSeal External Casine Internal r-n«nf> I. Is the well accessible;

S. Is surfrce seal damiêd?

8. Is casing in good. condition?

IL Is the internal casing at least 1 foot above ground? ^

2. Is the wdl protected v from tiaffic?

6^ Is the seal secure agaipSt the casing and jûnd?

9. IS; casing locked? 12. Is internal ris^ whhin 2 inches of top cap?

3f. Is the well in low spot or standing water?

10. lock in good condition?

13. Is casing free of debris, kinks, bends?

4. Is the welt laired inside and out?

7. Is the seal sloped away from the wellhead?

14, Is cap in good condition?

WeULD. Inspected Requires Action

Items/Problems Requiring Action (list number from above)

SMW-21 LP 0 • SMW-24LP • • SMW-27LP 0 • SMW-30LP ^ a . ., • SM\^-33LP - • SMW-35LP . Dr. • SMW-36LP • • SMW-37LP • • TMW-19LP • 'i.lO 11^

TMVV-21LP a • 1 .10 lU

TMW-23LP s • 1,10.iM TMW-25LP a • TMW.27LP •a • 1 ,10 , tv TMW.29LP a • 1, <0 , («/ TMVV-31LP a • 1,<0 ,!«/ TMW-33LP s • 1 10 /<«/ TMW-35LP 0 • 9.(0 liH

• •

Attach a detailed description of recommended actions at specific locations : . ÛttJ. OLU loC.k$ ^ A«rlrK€ Ci«--V t-tUio lOcll <95 |>re»/i'«fcS OTK5^.

«U«.4t> Cofrojbjt AkvlT^ i ^xû^'fe.r

F1GURE3-3 GAS MONITORING WELL INSPECTION FORM

SnCiCNEY/nrLER LANDFILLS

Name: J ^WAffiliation: Wf»j lie,

Date: ^ j-Z-"? fl3 Time: I'ioO-1'^^

n

Location/Identification •i, ...Vwits Probes 1. Is the probe/vent accessible?

S. Is the vent damaged and n^.repair?

7. ê the probes and/or casings damaged and need xepaiir?

2. Is the probe in low spot or ̂ ah^ng water?

6. Are the vent sampling ports danuiged and need repair?

i8: Are probe casings visible?

3. Is probe^rent free of obstnicôn?

9. Is|»x>be casing sulêct to being submo^ged?

4. Is the probe/vent labeled inside and out?

WeU Probe/Vent LD.

Inspecte d

Requires Action

Items/Problems Requiring Action Oist number from above)

S-GP-IS • 0 S-GP-ID • • S-GP-IA • • S.GP-2S . • • S-GP-2D .• S-GPr2A '• • S-GP-IGS. ••tQ- • S-GP-IOD • . • S-GP-llS 0 0

... . . ., ^.. .. ..

S-GP-llD • • S-GP-12 • • S-GP-14 • 0 . S-GP-l? • - J

BE-BP-01 • • BE-BP-02 D • .i4 T-GP-OIS a 0 T-GP-OID H • T-GP-02S B • T-GP-02D n • T-GP-03S • "is T-GP-03D •

C)

/ ^

o T-GP-07S 0 • "lib T-(a»-07D 0 tôcWlt: 4© Cec^'^ T-GP-07A • • U^vfi-laU 4o

T-GP-IOS fl 17;4 • • T-CT-lOP .. .0 . .. • ii:i -T-GP-llS 0 • 4o T-GP-llD • • 4J> /fiLK-k

T-GP-12S • • A /tt £A,J< •

T-GP-12D • 0 Cu^-^tc. -k T-GP-15 • 0 • 4-6

Hbrizohtal Well 0 •

Pre-System 0 • • • Btwn GACs 0 P6^ - Sys •

0 • ••0••• • •

()

Attach a detailed d^tniption of recommended actions at specific locations belpw:

d-l'Ctif /itcci'5 -fe .T-lrP-L'ô^ Lt>. A-xt "5^ pig-j-o-Vx "-^/ o"^ "f-GrP' 11 $. //0 • 7"-frf'/Z'

> t O. T-/^P-/<r . •io Ufv< c.^cr*.\<. aJ'

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Cli*n j'Ai. yjLoX Q-^<-4r'-LC'l-ijv^

Documents

ANNUAL REPORT OF ENVIRONMENTAL MONITORING STICKNEY … · Subject: Annual Report of Environmental Monitoring for the Stickney Avenue and Tyler Street Landfills CEC Project 130-998