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Prof. Jin-Heong Yim Applications of Polymer Materials/2nd Semester, 2005 _________________________________________ Chapter 2_1. 고분자 첨가제의 전개 Outline of Chapter 라디칼 포착제 자외선 흡수제 Hydroperoxide의 비라디칼 분해

Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

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Page 1: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

Applications of Polymer Materials/2nd Semester, 2005_________________________________________

Chapter 2_1. 고분자 첨가제의 전개

• Outline of Chapter•라디칼포착제

•자외선흡수제

• Hydroperoxide의비라디칼분해

Page 2: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

라디칼포착제의특징

Page 3: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

페놀계및인계산화방지제의병용효과

Page 4: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

대표적산화방지제의구조

Page 5: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

페놀계산화방지제

Page 6: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

작용메카니즘

Page 7: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

작용메카니즘

Page 8: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

페놀계산화방지제의사용현황

Page 9: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

사용상문제점_착색NOx가스착색메커니즘

Stilbebequinone 적갈색

Page 10: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

사용상문제점_착색아미드형첨가제 (>NH)에의한착색메커니즘

Page 11: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS (Hindered Amine Light Stabilizer)

Page 12: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS

R: 잔존항장력

Page 13: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

장기열안정제로서의 HALS

Page 14: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의작용기구

Page 15: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의작용기구

Page 16: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의시장동향

Page 17: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS계광안정제

Page 18: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS계광안정제

Page 19: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS계광안정제

Page 20: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의사용상주의점

Page 21: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의사용상주의점

Page 22: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS의사용상주의점

Page 23: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

자외선흡수제의특징과작용기구

Page 24: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

Benzotriazole계자외선흡수제

Page 25: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

Benzophenone계자외선흡수제

Page 26: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

자외선흡수제의사용예

Page 27: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

자외선흡수제의사용시문제점

Page 28: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

자외선흡수_첨가량, 두께Benzophenone계

Page 29: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

Hydroxyperoxide의비라디칼분해

Page 30: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS

Page 31: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

HALS

Page 32: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

황계산화방지제

Page 33: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

황계산화방지제

Page 34: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

황계산화방지제

Page 35: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제

Page 36: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제

Page 37: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제_사용예

Page 38: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제_작용기구

Page 39: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제_작용기구

Page 40: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

인계산화방지제_소비거동

Page 41: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

첨가제병용효과

Page 42: Applications of Polymer Materials/2nd Semester, 2005 ... · 페놀계및인계산화방지제의병용효과 . Prof. Jin-Heong Yim 대표적산화방지제의구조. Prof. Jin-Heong

Prof. Jin-Heong Yim

Hydroperoxide분해성Model; CHP (Cumene Hydroperoxide)