AR3 11101* · Functional Guidelines for Evaluating Inorganic Analyses, September, 1992, with modifications for use within Region III. INFORMATION REGARDING REPORT CONTENT Table

wUNITED STATES ENVIRONMENTAL PROTECTION AGENCY A np _ g

REGION mCENTRAL REGIONAL LABORATORY

201 DEFENSE HIGHWAYSUITE 200

ANNAPOLIS, MARYLAND 214O1

DATE : March 31, 1995

SUBJECT: Region III Data QA Review

FROM : Cynthia E. CaporaldRegion III ESAT RPO (3ES30) >"" " '

TO : Chris CorbettRegional Project Manager (3HW24)

Attached is the inorganic data validation report for the KeystoneSanitation Site (DAS R3074, SDG # 0740130R and 0740131R) completedby the Region III Environmental Services Assistance Team (ESAT)contractor under the direction of Region III ESD.

Also attached is the Regional Acceptance Form (RAF) for DAS R3074.-

If you have any questions regarding this review, please call me at(410) 573-6832.

Attachment

cc: Chuck Campbell, Gannett Fleming Environmental Engineers

TID File: 03950329

AR3 11*1*01*

Environmental Systems & ." --oic is :;.:.Environmental Services Assistance Teams Phone: (410) 268-7705Regions Fax:(410)268-84721419 Forest Drive; Suite 104Annapolis, Maryland 21403

DATE: MARCH 28, 1995SUBJECT: INORGANIC DATA VALIDATION (IM2 LEVEL)

DAS R3074 SITE: KEYSTONE SANITATIONPROM: HARI PRASAD^ MAHBOOBEH MECANIC

DATA REVIEWER SENIOR OVERSIGHT CHEMIST

TO: CYNTHIA E. CAPORALEESAT REGIONAL PROJECT OFFICER

THROUGH: DALE s. BOSHARTESAT TEAM MANAGER

OVERVIEW

The sample set for DAS R3074 consisted of thirty-three(33) aqueous samples analyzed for total metals andchloride (Cl) by Chemtech Consulting Group (CHEM) as aDelivery of Analytical Services (DAS) project. Themetals were analyzed according to the Statement of Work(SOW) 10/91 for Low Concentration Inorganics [ILCOl.l],and the Cl analyte was analyzed according to the EPAMethod 325.3. Included in the sample set were two (2)field blanks and two (2) field duplicate pairs.

SUMMARY

All analytes including Cl were successfully analyzedfor all samples.

The samples were delivered under two (2) Sample DeliveryGroups (SDGs) and the data validation was also performedon an SDG basis. The results for the Contract RequiredDetection Limit (CRDL) standard recoveries were common toboth SDGs. Areas of concern with respect to datausability are listed below, according to the seriousnessof the problem.

MINOR ISSUES

The continuing calibration blanks (CCB) in SDG 0740131Rhad reported results greater than the InstrumentDetection Limit (IDL) for the aluminum (Al), calcium (Ca)and sodium (Na) analytes. The reported results for these

AR3UU05

Page 2 of 4

analytes in the affected samples which are less than fivetimes (< 5x) the blank concentration may be biased highand have been qualified "B".

The laboratory duplicate results were outside the controllimit for the lead (Pb) analyte in SDG 0740130R. Thereported results and quantitation limits for thisanalyte are estimated and have been qualified "J" and"UJ", respectively.

The ICP serial dilution results were outside the controllimit for the manganese (Mn) analyte in SDG 0740131R.The reported results and quantitation limits for thisanalyte in the affected samples are estimated and havebeen qualified "J" and "UJ", respectively.

The initial and final CRDL standard recoveries werelow and high, respectively, for the beryllium (Be) andselenium (Se) analytes. The reported results for theseanalytes which are less than 2X.CRDL and quantitationlimits are estimated due to opposing bias effects and .have been qualified "J" and "UJ", respectively.

The CRDL standard recoveries were low for the followinganalytes: arsenic (As), cadmium (Cd), Pb, potassium (K)and Na. The reported results which are less than 2x CRDLand the quantitation limits for these analytes may bebiased low and have been qualified "L" and "UL",respectively, unless superseded by the "J", "UJ" or "B"qualifiers.

The CRDL standard recoveries were high for the Ca, copper(Cu) and thallium (Tl) analytes. The reported resultsfor these analytes in the affected samples which are lessthan 2x CRDL may be biased high and have been qualified"KM, unless superseded by the "B" qualifier.

The continuing calibration blanks had negative resultswith absolute values greater than the IDLs for thecobalt (Co) and Mn analytes in both SDGs, and the bariumanalyte in SDG 0740131R only. The quantitation limitsfor these analytes in the affected samples may be biasedlow and have been qualified "UL", unless superseded bythe "UJ" qualifier.NOTES

The sampler had incorrectly assigned the sample numberfor the station location RW-22D as 074013OR22 on theChain of Custody. This discrepancy has been corrected

Page 3 of 4

by the sampler by assigning a new sample number(0740130R44) for this station location. (See memo fromthe sampler dated 2/8/95 in Appendix B.)

The As, Pb, Se and Tl analytes were analyzed using theICP method (trace analyzer), and had IDLs less than orequal to the CRDLs.

The field duplicate results were within the controllimits (± CRDL, 20% RPD) except for the Pb and Clanalytes in SDG 074013OR, and the Cu and Pb analytes inSDG 0740131R. The concentrations for these analytes andthe precision estimates are given below.

Analyte Concentration fucr/L) Difference

0740130R22 0740130R44

0740130R Pb 2.7 ND 2.7Cl ND 5500 5500

0740201R24 0740201R32

0740131R CU 74.9 187 85.6+Pb 6.8 10.9 4.1

ND = Not Detected.+ = % RPD instead of difference in Mg/L.

The data were reviewed in accordance with the NationalFunctional Guidelines for Evaluating Inorganic Analyses,September, 1992, with modifications for use withinRegion III.

INFORMATION REGARDING REPORT CONTENT

Table 1A is a summary of qualifiers added to the results from thelaboratory during validation.

ATTACHMENTS

TABLE 1A SUMMARY OF QUALIFIERS ON DATA SUMMARY AFTER DATAVALIDATION

TABLE IB CODES USED IN COMMENTS COLUMN

TABLE 2 GLOSSARY OF DATA QUALIFIER CODESt

TABLE 3 DATA SUMMARY FORMS

AR3U1407

Page 4 of 4

APPENDIX A RESULTS REPORTED BY LABORATORY FORM Is

APPENDIX B SUPPORT DOCUMENTATION

DCN: HP503A04.KEY

Page 1 of 2TABLE 1A

SUMMARY OF QUALIFIERS ON DATA SUMMARYFORM AFTER DATA VALIDATION

NON-POSITIVE DETECTED

ANALYTE SDG SAMPLES AFFECTED* VALUES VALUES BIAS COMMENTS*

Al 074013 1R 131R04,131R07, B High CCB(31. 6/ig/L) -201R06,201R14,201R24,201R26

As 074J0130R All samples except L UL Low CRL(62%f57%)-130R12,130R20,130R21,130R30

0740131R All samples except" L UL Low CRL(62%,57%) ,.131R07,131R29

Ba 0740131R 201R33 UL Low CCN(-2 . 0/zg/L) '

Be 0740130R All samples UJ CRM(78%,120%)

0740131R All samples UJ CRM(78%,120%) -

Cd 0740130R All samples UL Low CRL(80%) •

0740131R All samples UL Low CRL(80%) .

Ca 0740130R 131R31 K High CRH(144%, 142%) ,

0740131R 201R33 B High CCB(22 .CRH(144%,142%)

CO 0740130R 130R22,131R13 UL Low CCN(-2 . 3/ig/L) •

0740131R All samples except UL Low CCN(-2 .3/xg/L) .201R15,201R32

CU 0740130R 130R02,130R21, K High CRH(121%, 138%) -131R03

0740131R 201R06,201R16, K High CRH(121%, 138%) •201R23

Pb 0740130R All samples except J UJ DUP(2.7jug/L) •130R12,130R17, CRL(64%) .130R19,130R20,131R13

+ All samples begin with the prefix "0740".* See explanation of Comments on Table IB.

AR3IHQ9

Page 2 of 2

TABLE 1ASUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

NON-POSITIVE DETECTED

ANALYTE SDG SAMPLES AFFECTED* VALUES VALUES BIAS COMMENTS*

Pb 0740130R 130R12,130R17, J DUP(2.7Mg/L) -130R19,130R20,131R13

0740131R 131R04,131R07, L UL Low CRL(64%) .131R29,201R06,201R14-201R16,201R23,201R33

Mn 0740130R 130R22 UL Low CCN(-2.2^g/L)

0740131R 131R29,201R16, UJ SD(19%) •201R23 CCN(-2.2/ig/L)

131R04,131R07, J SD(19%) .201R11,201R06,201R14,201R15,201R24,201R26,201R32

201R33 UL Low CCN(-2.2/ig/L)

K 0740130R All samples except L UL Low CRL(72%,83%) •130R25,131R03,131R10

0740131R All samples L UL Low CRL(72%,83%).

Se 0740130R All samples except J UJ CRM(82%,124%)131R03

0740131R All samples UJ CRM(82%,124%)

Na 0740130R 131R31 L Low CRL(86%,88%) x

0740131R 201R33 B High CCB(19.8/ig/L)CRL(86%,88%) '

Tl 074013OR 131R03 K High CRH(131%) '

+ All samples begin with the prefix "0740".* See explanation of Comments on Table IB.

A R 3 I H I O

Page 1 of 1

TABLE IBCODES USED IN COMMENTS COLUMN

CCB = The continuing calibration blank had a result > IDL(the result is in parenthesis). The reportedresults which are < 5x the blank concentration maybe biased high.

CRL = The CRDL standard recovery was low (< 90%) [%recovery is in parenthesis]. The reported resultswhich are < 2x CRDL and quantitation limits may bebiased low.

CCN = The CCB had a negative result with absolute value> IDL (the negative result is in parenthesis). Thequantitation limits may be biased low.

CRM = 'The initial and final CRDL standard recoveries werelow and high (> 110%), respectively [% recoveriesare in parenthesis]. The reported results which are< 2x CRDL and quantitation limits are estimated.

CRH = The CRDL standard recovery was high [% recovery isin parenthesis]. The reported results which are <2x CRDL may be biased high.

DUP = The laboratory duplicate results were outside thecontrol limit (± IDL) [difference in Mg/L is inparenthesis]. The reported results and quantitationlimits are estimated.

SD = The ICP serial dilution results were outside thecontrol limit (10% D) [% D is in parenthesis]. Thereported results and quantitation limits areestimated.

AR3UU

TABLE 2

GLOSSARY OF DATA QUALIFIER CODES (INORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

U = Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) = Confirmed identification.

B s Not detected substantially above the level reportedin laboratory or field blanks.

R » Unusable result. Analyte may or may not be presentin the sample. Supporting data necessary toconfirm result.

CODES RELATED TO QUANTITATION(can be used for both positive results and sample quantitationlimits):

J = Analyte Present. Reported value may not be-accurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L » Analyte present. Reported value may be biased low.Actual value is expected to be higher.

[] = Analyte present. As values approach the IDL thequantitation may not be accurate.

UJ «• Not detected, quantitation limit may be inaccurateor imprecise.

UL = Not detected, quantitation limit is probablyhigher.

OTHER CODES

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APPENDIX A

RESULTS REPORTED BY LABORATORY

FORM Is

AR3UI.I7

SDG 0740130R

AR3UM8

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE NO.

ANALYSIS DATA SHEET

0740130R02Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-IIl'

Lab Code: CHEM Case No.: R3074 SAS No.: SDG No.: 0740130R

Matrix (soil/water): WATER Lab Sample ID: 38194 S

Level (low/rned) : LOW Date Received: 01/31/95

Concentration Units: ug/L

CAS No.

7429-90-57440-36-07440-38-2 •7440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

Concentration

25.0 .5.02.0

26.11.01.0

206005.02.09.5

60.02.0

72307.10.2010.0400

3 .03.0

78909.02.0

11411500

C

UUU

UU

UuBUU

BUUBUU

UU

Q

*

M

PPPPPPPPPPPPPPcvPPPPPPPPc

Before :After:

Comments

ColorCOLORLESSCOLORLESS

ClarityCLEARCLEAR

Viscosity

FORM I AA - LCIN ,'lLCOl.O000004

.AR31UU19

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE NO

ANALYSIS DATA SHEET

0740130R05Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-IIlj



Level (low/med) : LOW Date Received: • 02/01/95


CAS No.

7429-90-57440-36.-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc-Chloride

Concentration

25.05.02.07.11.01.0

207005.02.051.960.02.2

23701.00.2010.0234

3.03.0

56109.02.04.0

5000

C

UUUBUU

UU

u

uuuBUU

UU'U

Q

•

*

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AB - LCIN : ILC01.0000005 .

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740130R12'Lab Name:. CHEMTECH CONSULTING GROUP Contract: US EPA R-IIl'

Lab Code: CHEM Case No.: R3074 SAS No.: . SDG No.: 0740130R


Level (low/med): LOW Date Received: 01/31/95


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2 •7440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.04.0

36.61.01.0

69805.02.0

54360,05.7

27008.50.20

10.0414

3 .73.0

2660 '9.02.0

73.95000

C

UU

UU

UU

U

BUUB

U

UU

U

Q

*

M

PPPPPPPPPPPPPPCVPPPPPPPPC

Before:After :

Comments


Clarity ViscosityCLEAR'CLEAR

•

FORM I AC - LCIN ILC01.0

000006 .

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740130R17Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III





CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.03 .71.01.0

151005.02.0

35760.011.7

48703.00.20

10.01040

3.03.0

76709.02.0

22.314500

C

UUUBUU

UU

U

BUU

UU

UU

Q

*

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AD - LCIN ILC01.0000007

U.S. EPA - CLP


ANALYSIS DATA SHEET






GAS No.

7429-90-57440-36-0744CT-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

Aluminum'AntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

Concentration

25.05.62.1

45.11.01.0

51805.02.039.060.02.8

32002.80.2010.0

7983 .03.0

3820. 9.02.011.8

12500

C

UU

UU

UU

U

BUU

UU

UUB

Q

*

M

PPPPPPPPPPPPP .PCVPPPPPPPPC

Before :\fter:

Comments


Clarity .CLEARCLEAR

Viscosity

FORM I AE - LCIN ILC01.0000008AR3UU23

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740130R19"Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III





CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2'7440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-5'7440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmium•CalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

Concent rat ion

25.05.02.06.81.01.0

71805.02.0

11260.06.0

57802.60.20

10.09793.03.0

69309.02.0

22.410000

C

UUuBUU

UU

U

BUU

UU

UU

Q

*

M


Comments:

Color Clarity ViscosityBefore: COLORLESS ' CLEAR _________After: COLORLESS CLEAR __________

FORM I AF - LCIN nnnnnn ILCOl.o000009

AR3UU21*

U.S. EPA - CLP


ANALYSIS DATA SHEET


Lab Cods: CHEM Case No..: R3074 SAS No.: SDG No.: 0740130R

Matrix . (soil/water) : WATER Lab Sample ID: 38192 S



CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2744'0-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.06.7

47.8.1.01.0

141005.02.0

15660.04.9

718022.20.20

10.01160

3.03.0

43309.02.0

25.613500

C

UU

UU

UU

U

UU

uuuu

Q

*

*

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AG - LCIN . ILC01.0000010

AR3U.1.25

U.S. EPA - CLP


ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

•

Analyte

AluminumAnt imonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

Concentration

25.05.0 '5.593.41.01.0

179005.02.04.560.02.0

40101.40.20

10.0831

5.53.0

67309.02.06.3

6500

C

UU

UU

UUBUU

BUU

U

UUB

Q

*

M


Before :After:

Comments


Clarity .CLEARCLEAR

Viscosity

FORM I AH - LCIN ILC01.0000011

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE NO,

ANALYSIS DATA SHEET


Lab Code: CHEM Case No.: R3074 SAS No.: SDG No.: 074013OR

Matrix (soil/water): WATER Lab Sample ID: 38197 s



CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02 .0

36.31.01.0

18705.02.0

41.060.02.7

1400 '1.00.2010.0

4903 .03.0

14309.02.010.0

5000

C

UUU

UU

UU

U

UUUBUU

UUBU

Q

*

M


Before :After:

Comme>nts


ClarityCLEARCLEAR

Viscosity

FORM I AI - LCIN 'n00012 ILC01-°

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE NQ

ANALYSIS DATA SHEET


•_

Lab .Code: CHEM Case No.: R3074 SAS No.: SDG No.: 0740130R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440'-62-27440-66-6

Analyte


Concentration

25.05.02.0

51.21.01.0

170005.02.03.0

60.02.0

65801.00.2010.0

24903.93.0

45609.02.04.0

13000

C

UUU

UU

UUUUU

UUU

U

UUU

Q

*

M

P.PPPPPPPPPPPPPCVPPPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AJ - LCIN 000013 ILC01.0

AR3 11.1*28

U.S. EPA - CLP


ANALYSIS DATA SHEET




Level (low/med): LOW • Date Received: 01/31/95


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.0 .5.05.5

56. .21.01.0

191005.02.048.060.62.0

47801.40.2010.0294

5. -83.0

29109.02.015.4

' 7500

C

UU

UU

UU

UU

BUUB

U

UUB

Q

*

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AK - LCIN 0 0 0 0 .1 4 ILC01. 0

AR3U1.29

U.S. EPA - CLP


ANALYSIS DATA SHEET _






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

37.61.01.0

18005.02.0

42.460.02.0

13301.00.20

10.0454

3 .03.0

14109.02.012.3

5500

C

UUU

UU

UU

UU

UUUBUU

UUB

Q

*

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AL - LCIN ILC01.0000015

AR3IUl*30

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740131R03 'Lab Name :. f CHEMTECH CONSULTING GROUP Contract: US EPA R-III





CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2 •7440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

51.91.01.0

253005.02.0

11.260.02.0

63101.00.20

10.011500

7.23 .0

1540011.32.07.7

19500

C

UUuuuuuuuuuu

u

uB

Q

*

M

PPPPPPPPPPPPPPcvP'PPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

.

FORM I AM - LCIN ILC01.0000016 .

U.S. EPA - CLP


ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

25.31.01.0

68905.02.032.260.02.1

63301840.2010.09813.03.0

29409.02.025.9

7000

C

UUuuuuuu

uuuuuu

Q

*

M


ColorBefore : COLORLESSAfter : COLORLESS

Comments :

Clarity. CLEARCLEAR

Viscosity

FORM I AN - LCIN n n rv n <• n ILC01. 0000017

AR 3 I U U 3 2

U.S. EPA - CLP


ANALYSIS DATA SHEET


Lab Code: CHEM Case No.: R3074 ' SAS No.: SDG No.: 0740130R

Matrix (soil/water): WATER Lab Sample ID: 38224 .S



CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2 .7440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc.Chloride

Concentration

. 25.05.02.019.71.0l.'O

48805.02.0

34.660.03.6

36405.90.20

10.05983.03.0

50309.02.052.2

8500

C

UUUBUU

UU

U

BUUBUU

UU

Q

*

M


ColorBefore: COLORLESSAfter : COLORLESS

Comments :

Clarity .CLEARCLEAR

Viscosity

FORM I AO - LCIN ILC01.0000018

AR3I'M..33

U.S. EPA - CLP



0740131R10 "Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III





CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

33.75.02.0

73 .51.01.0

70605.02.2

12960.02.0

610015.90.20

10.01640

3 .03.0

71109.02.0

14911500

C

BUU

UU

UB

UU

UU

UU

UU

Q

*

M

PPPPPPPPPPPPPPCVPPPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AP - LCIN ILC°l-°000019

U.S. EPA - CLP


ANALYSIS DATA SHEET


Lab'Code: CHEM Case No.: R3074 SAS No.: SDG No.: 0740130R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.0

' 2.028.9i.o'1.0

37505.02.0

40260.09.0

23004.00.20

10.09563.73.0

30809.02.0

34.96500

C

UUuuuuuu

BUU

U

Uu

Q

*

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

.'

FORM I AQ - LCIN . ILC01.0000020

AR3 11*1*35

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE N

ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

54.21.01.0

269005.02.0

97.060.02.0

67402.30.2010.09103.03.0

60109.02.0

20.08000

C

UUU

UU

UU

UU

BUuuuuu

Q

*

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AR - LCIN ILC01.0000021

U.S. EPA - CLP


ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-0 .7440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

91.61.01.0

285.005.02.077.060.02.0

61101.00.2010.0

14003.03.0

146009.02.045.4

13500

C

UUU

uuuuuuuuuuuuu

Q

*

M

PPPPP'PPPPPPPP'PCVPPPPPPPPC

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AS - LCIN _„ ILC01.0000022

U.S. EPA - CLP




Lab Code,: CHEM Case No.: R3074 SAS No.: SDG No.: 07.40130R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.01.0.1.01.0

49.55.02.03.0

60.02.0

15.01.00.2010.02003.03.0

17.09.02.04.0

5000

C

UUUUUUBUUUUUUUUUUUUBUUUU

Q

*

M

P~PPPPPPPPPPPPPcvPPPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AT - LCIN ILC01.0

000023AR3UU38

SDG 0740131R

AR3|l*l*39

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740131R04 -Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III


Matrix (soil/water): WATER Lab Sample ID: 38229 3



CAS No.

7429-90-57440-36-07440-.38-27440-39-37440-41-77440-43-97440-70-2 .7440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc .Chloride

Concent rat ion

31.55.02.051.61.01.0

136005.02.0

84.7,84.82.0

63605.40.2010.09203.03.0

110009.02.0

13723000

C

BUU

UU

UU

BU

BUU

UU

UU

. Q

E

M

PPPPPPPPP .PPPPPcvPPPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AA - LCIN nrmnno ILCOl000003

AR3|i*l*l*0

U.S. EPA - CLP


ANALYSIS DATA SHEET




Level (low/med) : LOW Date Received: 02/02/95


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

26.45.09.8

30.21.01.0

67705.02.0

16160.02.5

44202.6.0.20

10.0787

3.03.0

39009.02.0

13.88500

C

BU

UU

UU

U

BUU

UU

UUB

Q

E

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AB - LCIN n H H n A ILC01

U.S. EPA - CLP


ANALYSIS DATA SHEET



Matrix (soil/water) :' WATER Lab Sample ID: 38228 S



CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440*-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.0

13.51.01.0

78205.02.0

26373.54.6

342013.40.20

10.04013.03.0

37009.02.0

19.68000

C

UUUBUU

UU

B

UUBUU

UUB

Q

E

M

PP 'PPPPPPPPPPPPCVPPPPPPPPC

ColorBefore: COLORLESSAfter : COLORLESS

Comments :

Clarity ,CLEARCLEAR

Viscosity

FORM I AC - LCIN ILC01000005

AR3 IJ*I* 1*2

U.S. EPA - CLP



0740131R29Lab Name: CHEMTECH CONSULTING GROUP . Contract: US EPA R-III

Lab Code: CHEM Case,No.: R3074 SAS No.: SDG No.: 0740131R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.08 .9

1591.01.0

407005.02.0

31.260.02.0

100001.00.20

10.0623

3.03.0

104009.02.05.9

11500

C

UU

UU

UU

UU

UUUBUU

UUB

Q

E

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

--

FORM I AD - LCIN ILCO1000006

U.S. EPA - CLP

LOW CONCENTRATION. INORGANICSEPA SAMPLE NO.

ANALYSIS DATA SHEET '


Lab 'Code: CHEM Case No.: R3074 SAS No.: SDG No.: 0740131R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70r27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-777S2-.49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

26.15.02.0

824i.o'1.0

153005.02.04.2

60.02.0

26107.80.20

10.05963.03.0

247009.02.04.0

5000

C

BUU

UU

UUBUU

BUUBUU

UUUU

Q

E

M


Before :After :

Comments


ClarityCLEAR.CLEAR

• Viscosity

FORM I AE - LCIN' . ' ILC01000007AR3 11*1*1*1*

U.S. EPA - CLP








CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concent rat ion

26.05.02.0

11.91.01.0

40105.0

. 2.060.21202.4

47505.20.20

10.05293.03.0

40709.02.0

. 37.912000

C

BUUBUU

UU

BUUBUU

UU

Q

E

M

PP 'PPPPPPPPPPPPCVPPPPPPPPC

Before :After:

Comments


Clarity .CLEARCLEAR

Viscosity

FORM I AF - LCIN ILC01000008

AR3 11*1*1*5

U.S. EPA - CLP


ANALYSIS DATA SHEET ,






CAS NO.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAnt imonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

Concentration

25.05.02.0

54.91.01.0

58505.02.0

12.7 ,60.02.7

51201.00.20

10.01140

3.03.0

44109.0

. 2.022.7

11500

C

UUuuuuuu

uuuuuuu

Q

E

M

PPPP

• PPPPPPPPPPcvPPPPPPPPc

Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

-

FORM I AH - LCIN rt n n A 1 H ILC01000010AR3UH6

U.S. EPA - CLP








CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.04.21.0 '1.0

34105.02.0

31760.02.8

14101.00.20

10.0419

3.03.0

26409.02.0

20.45000

C

UUUBUU

Uuu

BUUBUU

UU

U

Q

E

M


Before :After:

Comments


ClarityCLEAR

. CLEAR

Viscosity

FORM I AG - LCIN 000009

AR3II+UU7

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740201R24Lab Name: CHEMTECH CONSULTING'GROUP Contract: US EPA R-III



Level (low/med): LOW : Date Received: 02/02/95


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

36.1 •5.02.08.21.01.0

90205.02.0

74.960.06.8

556052.40.20

10.0489

3.03.0

3620 '9.02.0

20.610500

C

BUUBUU

UU

U

UUBUU

UU

Q

E

M


Before :After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AJ- LCIN . ILCOI

U.S. EPA - CLP


ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.01.61.01.0

112005.02.011.160.02.2

39001.00.2010.0494

3.03.0

38809.02.04.0

6500

C

UUUBUU

UU

U

UUUBUuuuu

Q

E

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORMIAI-LCIH ILC01

U.S. EPA - CLP


ANALYSIS DATA SHEET

0740201R26"Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III





CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-2 •7440-47-37440-48-47440-50-87439-89-6 .7439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

51.05.02.3

1071.01.0

89205.02.0

69.360.04.0

399015.8 -0.20

10.04623.03.0

39009.02.011.3

7500

C

BU

UU

UU

U

UUBUU

UUB

Q

E

M


Before :After:

Comments


ClarityCLEAR•CLEAR

Viscosity

FORM I AK - LCIN 000013 ILC01

AR3 11*1*50

U.S. EPA - CLP


ANALYSIS DATA SHEET






CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.02.09.91.01.0

96705.02.9

18760.010.9

572051.40.20

10.04903 .03.0

38909.02.0

28.614000

C

UUUBUU

UB

U

UUBUU

UU

Q

E

M


Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

FORM I AL - LCIN 00001 4 ILCO1

U.S. EPA - CLP


ANALYSIS DATA SHEET


Lab Code: CHEM Case No.: R3074 'SAS No.: . SDG No.: 0740131R




CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

25.05.0"2.01.01.01.0 .

19.85.02.03.060.02.0

15.01.00.2010.0

2003 .03.0

21.69.02.04.0

S'OOO

C

UUUUUUBUUUUUUUUuuuuBUUUU

Q

E

M

PPPPPPPPPPPPPPcvPPPPp.PPPc

Before:After:

Comments


ClarityCLEARCLEAR

Viscosity

a

FORM I AM - LCIN 000015 ILC01

AR3 11*1*52

APPENDIX B

SUPPORT DOCUMENTATION

AR3|l*l*53

"Ke^5t<taifc Scuiitat.c.

J'v Halliburton NUSJfc *%<i B M > A^ ^ A %»X JLA J. m /l ^ OQ*a 01,4 C**<*IA C~l.,~ In j •. i*_/"•• n> D D o D A T T r*i M taglebchooiRoad,Suite415lxVJK.rlJK.Ai. 1 U IN________________________ Wayne, PA 19087-1710

(610)971-0900_ FAX:

February 8, 1995

Project Number 0986

Ms. Annette LageRegional Sample Control Center iRSCC', CoordinatorUSEPA Region III Quality Assurance Brancn201 Defense Highway, Suite 200Annaoolis, MD21401

Reference: ARCS III ProgramEPA Contract No. 68-W8-0037

Subject: MEMO TO FILELow Concentration Metais/Chlorioe, DAS No. R3074Keystone Sanitation Landfill (KSL) SiteRemedial Investigation/Feasibility Study (RI/FS)EPA Work Assignment No. 37-52-3SL9

Dear Ms. Lage:

An error on the chain-of-custody (COO form was noted by Chemtech for samples shipped on January30, 1995 under DAS number R3074. The sample with station location RW-22D wds accidentallyassigned the same DAS sample number (0740130R22) as station location RW-22. Chemtechrepresentative Babak Morovati called on January 31 and sent a Telephone Record Log to me byfacsimile. The project manager, William Went worth, was contacted on-site and verified this problem.The problem was solved by assigning RW-22D a new and unique DAS sample number of 0740130R44.The resolution of this problem was given to the Chemtech representative on February 1, 1995 via afacsimile response using the Telephone Record Log (a copy of which is attached to this letter). A copyof this memo to file should be available for review by the ESAT data validators when the data packagecomes back. Please call if you have any questions.

Respectfully Submitted,

Russell Sloboda

RS/rs

cc: Christopher Corbett (ERA)Babak Morovati (Chemtech)Rayomond Bhumgara (Gannett Fleming)William Wentworth (Halliburton NUS)Garth Glenn (Halliburton NUS)File

Enclosure

A Halliburton Company ________ A R 3 I \\ \i 5 ii

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AR3U1.58

ftulO - U.S. EPA -- CLP

• a

LOW CONCENTRATION INORGANICSIDL

Tab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III


Instrument ID Number: CV Method: CV Date: 01/15/95

-;- Concentration Units: ug/L

.Analyte

Wavelength]orMassNumber(WOMN)

| AluminumAntimonyArsenic'BariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLead(Magnesiumj Manganesej MercuryNickel

Wave-Length(nm)

253.7

Potassium) |SeleniumSilverSodiumThalliumVanadium2,incChloride

Integ.Mass Time(m/z) (sec)

.

Comments :

Back-ground j CRDL

100522011

5001010101002

5001 10j 0.2

. | 20| 750

310500101020

5000

IDL

0.20

.CV: SPECTRO- PRODUCTS MERCURY ANALYZER

' •-- • - - .- •- • •- - - - - - - - - -

—— FORM XII AA - LCIN ILC01.0

000037AR31M.6Q

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSIDL

Lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III

Lab Code: .CHEM Case No.: R3074 SAS No.: SDG No.: 0740130R

Instrument ID Number: PO Method: P Date: 01/15/95


Comments:PO: ICP 6IE TRACE ANALYZER

Analyte

1AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercury[NickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

WavelengthorMassNumber(WOMN)

•

.Wave-Length(nm)

308.2206.8189.0493.4313.0226.5317.9267.7228.6324.7271.4220.4279.0257.6

231.6766.5196.0328.0588.9190.9292.4213.8

Mass(m/z)

Integ .Time(sec)

•

Back-ground CRDL

100522011

5001010101002

500100.220750

31050010

' 1020

5000

1

IDL

255.02.01.01.01.0105.02.03.0602.0151.0

102003.03.0109.02.04.0

FORM XII AB - LCIN ILC01.0

000038

SDG 0740130R

;AR3UI*62

U.S. EPA - CLP '

-LOW CONCENTRATION INORGANICS

CRDL STANDARDS

Lab Name: CHEMTECBTCONSULTING GROUP Contract: US EPA R-III



Analyte


W0MN

Initial Final

True Found %R Found %R

200.0010.004.0040.002.002.00

1000.0020.0020.0020.00200.004.00

1000.0020.000.4040.00

1500.006.0020.00

1000. 00*20.0020.0040.00

193.038.992.5040.771.552.11

1441.9019.7119.9524.20185.434.08

1030.8020.030.2141.66

1074.004.9021.09863.4026.1618.9243.04

9790CS2102Cza)106

( L44j99100(J1P9310210310052104(272)CU)

95108

196.05. 13.14

2.2940.072.391.60

1416.9019.7921.3827.68203.962.57

1005 .2020.59

40.611239.80

7.4719.82878.1120.0619.4242. .96

98131cu>100<T20)d~(142*5~$107(£38)102dp101103

102(783)QHs599dJP10097107

M

PPPPP>P'PPPPPPPPNRPPPPPPPPNR

FORM III AA - LCIN ILC01.0000027

AR3U1463

U.S. EPA - CLP

LOW CONCENTRATION INORGANICS

BLANKS


Lab. Code: CHEM Case No.: R3074 , SAS No.: SDG No.: 0740130R

Analyte


W0MN

InitialCalib.Blank C

25.0005.0002.000-1.0101.0001.000

10.0005.0002.0003 .00060.0002.000

-16.830-1.3100.20010.000200.0003.0003.000

-10.2409.0002.0004.000

5000.000

UuuBUUUUUUUUBBUUUUUBUUUU

Continuing Calibration Blanks

1 C 2 C 3 C

25.000'5.0002.0001.0001.0001.000

10 .0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.000

3 .0003.00010.0009.0002.0004.000

5000.000

Uuuuuuuuuuuuuuuuuuuuuuuu

25.0005.0002.0001.0001.0001.00010.000.5.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

5000.000


25.0005.0002.0001.0001.0001.00010.0005 .0002.0003 .00060.0002.00015.0001.0000.20010.000200 .0003.0003.00010.0009.0002.0004.000

5000.000

UUUUUUUUUUuuuuuuuuuuuuuu

Prep.Blank

C

25.0005.0002.0001.0001.0001.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

UUUUUUUUUuuuuuuuuuuuuuu

M

p~PPPPPPPPPPPP•HJ Hj nP 'PPPPPPc

000029FORM V AA - LCIN nnnnnn ILC01.0

: U.S. EPA - CLP

- " ""- LOW CONCENTRATION INORGANICS •

BLANKS



Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadJMagn.es ium•CanganeseRercury[NickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

WoMN



1 C 2 C 3 C

31.6405.0002.000-'2.0001.0001.00022.7105.000

C .26g3.00060.0002.00022.470<<2 . 18j£0.20010.000200.0003.0003.00019.8509.0002.0004.000

BUUBUUBUBUUUBBUUUUUBUUU

25,0005.0002.0001.0001.0001.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

Uuuuuuuuuuuuuuuuuuuuuuu

. 25.0005.0002.0001.0001.0001.00015.3005.0002.0003.00060.0002.00015.2101.000

10.000200.0003.0003.00011.8709.0002.0004.000

UUUUUUBUUUUUBU

UUUUBUUU

Prep.Blank

C

-

M

PPPPPPPPPPPPPPCVPPPPPPPPNR

4

FORM V AB - LCIN ILC01.0000030

; AR3UU65

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSEPA SAMPLE NQ

' DUPLICATES

0740130R22DLab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-IIl'



Comments:

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMe'rcuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincChloride

WOMN

i

ControlLimit

2.00

200.0

4.00

Sample (S)C

25.0005.0002.00036.2901.0001.000

1873 .3005.0002.00041.00060.0002.710

1397.8001.0000.20010.000489.980

3.0003.000

1428.7009.0002.00010.040

5000.000

UUU

Uuuuu

uuuBUU

uuBU

Duplicate (D)C

25.0005.0002.00036.4301.0001.000

1871.4005.0002.00041.46060.0002.000

1394.8001.0000.20010.000500.0203.0003.000

1434.2009.0002.00010.150

5000.000

UUU

UuuuuuuuuBUU

uuBU

RPD

0

0

1

2000

2

0

1

Q

*

M


FORM VIII AA - LCIN ILC01.0000033

AR3 11*1*66

U.S. EPA - CLP

; LOW CONCENTRATION INORGANICSANALYSIS RUN LOG (A)

,ab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III


Instrument ID Number: PT> , Run No. : 1 Method: P

Start date: 02/24/95 End date: 02/24/95

EPA Prep .Sample j BatchNo. Number

SO |SSs "-SICVICVICVICVICBJCRIftjRSICSAICSABCCVCCB— \

•

PBW j 02229508PLCSW0740130R200740130R210740130R020740130R300740130R250740130R440740130R120740130R18CCVCCB —1-0740130R190740130R050740130R170740131R03

Time

14151417142114231424142514291433143814421451150615191523152615291545

02229508PJ155202229508PJ160202229508P02229508P02229508P02229508P02229508P02229508P02229508P

02229508P02229508P02229508P02229508P

1607161016131617162016241628163116341645165016541657

D/F

1.001.001.001.001.001.001.001.001.001.001.001.001.00

. 1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00iJoo1.001.00

Analytes

•AL

X

X

X

XXXXXXXXXXXXXXXXXXXXXXX

S|A|BB sx|xX

X

XXXXXXXXX

X

X

XXXXXXXXX

xjxXXXXXXXXXXXXX

XXXXXXXX

A

XX

X

XXXXXXX

BE

XX

X

XXXXXXX

x|xXXXXXXXXXX

x|xXXXX

XXXX

XXXXXXXXXXXXXXX

cD

XX

X

XXXXXXX

C|C|C|C|FA R o

x|x|x

X

X

XXXXXXX

xjxxjxXXXXXXXXXXXXXX

x|x

u E

x|xX

x|x|x

X Xx|xXXX

XX

X

X

1XXXX

PB

XX

X

x|x

MG

X

X

X

Xxjx|xxjxjxxjxjx

xjx|x|x|xxjxxjxxjxxjx

x|xxjxXX

x|x|x|xXXXXX

XXXXX

x|xXXXXXXX

XXXXXXX

XXXXXXXXXXXXX

XXXXXXXXXXXXX

XXXXXXXXXXXXXXXX

XXXXXXXXXXXXXXXXXX

XXXXXXXXXXXXXXXXXX

MN

XX

X

XXXX

HG

x|_XXXXXXXXXXXXXXXXXX

_

—

N|KI

XX

X

XXX

X

sE

X

Xx^X

XXX

X

XXX

xjxjxXXXXXXXXXXXXXXXXXXX

XXXX

A|NG

X

XX

XXXXXX

xjx|xxjxjxXXXXXXXXXXXXXXX

XXXXXXXXXXXXXXX

XXXXXXXXXXXXXXX1

A

X

X

X

XXXXXX

TL

X

X

XXXXXXX

V

XX

X

XXXXXX

x|x|xXXXXXXXXXXXXXXXX

XXXXXXXXXXXXXXXX

XXXXXXXXXXXXXXXX

zN

Xx|

X

XXXXXXXXXXXXXXXXXXXXXXX

FORM XVI AA - LCIN ILC01.01

000044":AR3|l_l*67

U.S. EPA - CLP

LOW CONCENTRATION INORGANICSANALYSIS RUN LOG (A)



Instrument ID Number: PO Run No.: 1 Method: P


EPASampleNo.

0740131R100740131R280740131R270740131R310740131R090740131R08CCVCCB -30740131R13zzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzCCVCCB-H-0740130R22D0740130R22S0740130R220740130R22LZZZZZZZZZZZZzzzzzzZZZZZZZZZZZZzzzzzzCCVCCB-S"

Prep.BatchNumber

02229508P02229508P02229508P02229508P02229508P02229508P

02229508P

02229508P02229508P02229508P02229508P

Time

17021715171917221726173017331736174517491753175718001805181418171823182718301833185118551910191519231932193619511956195920022005

D/F

• 1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.005.001.001.001.005.001.001.001.001.00

Analytes

AL

XXXXXXxxX

s|B

Xx|x!X:XXxxX

x

XXX

XX

xXXxXX

XX

A|sXxxXXXxXX

xXxxXX

XX

BA

XXXXXXxxX

xXXXXX

XX

B|E

XX!x|XXXxixix

xXXxXX

XX

c|D

Xx|X!XXXxxX

xXxxxx

XX

cA

XXXXXXXXX

c|R|x|x|x|Xx|XXxix!

1

XXX

XX

XX

XXXXXX

XX

co|x|x|x|XXXXxX

XXXXXX

XX

cux|x|x!XXXXXX

xXXXXX

XX

FE 1x|Xx|Xx|XXXX

XxXXXX

XX

PiB

XXx|Xx|x|XXX

XXXXXX

XX

M|G|

XXx|XXx|XXX

XXX

XX

XX

MN

XXx|XXXx|XX

XXXXXX

XX

HG

—

I

—

N|I

Xx|x|Xx|x|x|x|X

XXXXXX

XX

K

XXXx|x|Xx!XX

XXX

xX

XX

s|E

Xx|Xx|Xx|x|X

x!

XXXXXX

XX

A|G

Xx|Xx|Xx|x|Xxj

XXXXXX

XX

NA

Xx|XXXXXXX

XXX

XX

XX

TL

XXXXXXXXX

XXXXXX

XX

V

XXXXXXXXX

XXXXXX

XX

zN

XXXXXXXx]X 1HirxXXXXX

XX

FORM XVI AB - LCIN ILC01.01

000045

, " "" U.S. EPA - CLP


Lab Name: CHEMTECH CONSULTING GROUP ' Contract: US EPA R-III


Instrument ID Number: PO Run No.: 1 Method: P


IS PASampleNo.

ZZZZZZZZZZZZZZZZZZCRY.LRSICSAICSABCCVCCB

| —————

Prep.BatchNumber

Time

201420212027204520542105211021132116

———

D/F

1.001.001.001.001.001.001.001.001.00

Analytes

AL

XxXXXx

sB

XxXXXx

AS

XxXxXx

BJA

xxXxXx

1

BE

XXXXxX

cD

XXXXxX

cA

XXxXxX

cR

xXXXXX

co

XXXXXX

cu

XxXXXX

FE

XxXxXX

PB

XxXxXx

MG

XXXXXX

MN

XXXXXX

HG

I

NI

XXXxXX

K

XXXxXX

sE

XXXXXX

AG

XXXXXX

1

NA

XXXXXX

TL

XXXXXX

v

XXxXX•x

i

zN

x|XxXXX

FORM XVI AC - LCIN ILC01.01

000046AR3 1.1*1*69

03/15/1995 10:51 201-557-1333 CHEMTECH PAGE

CONSULTING GROUP. INC. 11U Houca 4 • Engliwood. Now JarMy O7631 Pnon*: (2O11 367-6868 F«»: (8O1I 387.1

CASE NARRATIVES

Case Number: R3074 SDG Number: 074013QR

a. Number of Samples and Date of Sample Receipt:

13 water samples were received by the laboratory intact on January 31 and Feb 1.199S.

b. Parameters:

These samples were analyzed for Low concentration TAL Metals and Chloride.

c. Analytical Techniques:

1. Samples were digested for ICP analysis by EPA CLP Method.2. Samples were analyzed for TAL metals (except Mercury) by ICP Trace Analyzer by CLP Method..3. Samples were digested and analyzed for Mercury by Cold Vapor CLP Method.4. Samples were analyzed for Chloride hy F.PA Method 325.3.

d. QA/QC Samples:

The Preparation Blank (PB) and the Laboratory Control Sample (LCS), were digested and analyzed along withthe samples. The Preparation Blank results were found to be less than the Contract Require Detection Limits(CRDL's) and are reported on Form III.

1. Pre-Digested Spike (PDS)

Sample 0740130R22 was analyzed as the Pre-Digestion Spike (PDS), and the results are reported on Form"VII". ALL % Recoveries arc within the control limits.

2. Duplicate (DUP)

Samples 07401 MUM was analyzed as Duplicates (DUP), and all % RPD's are within the control limits excqrlead. These results are reported on Form VIII.

3. Serial Dilution

Sample 0740130|tM was analyzed as Serial Dilution analysis with 4 X dilution. The % Differences arreported on Form X, and all are within the control limits except manganese.

The results of samples are reported on Form I's. The units are in ug/L for aqueous samples.

.... AR3IH70

1 . U.S. EPA - CLPV

• LOW CONCENTRATION INORGANICS

COVER PAGE



SOW No.: ILC01.0

EPA SAMPLE_NO. Lab Sample ID.--Q740130R02 38194 S074013OR05 38217 S0740130R12 38201 S0740130R17 38218 S0740130R18 • 38202 S;0740130R19 ' 38216 S0740130R20 38192 S074;0130R21 38193 ' S-07S0130R22 : 38197 S0740130R22D 38198 • 320740130R22S '. 38199 DS0740130R25 ' 38196 S0740130R30 ' 38195 S0740130R44 -38200 S0740131R03 38219 S

: 074013.1R08 " 38225 S0740131R09 38224 S0740131R10 38220 S0740131R13 38226 S0740 31R27 38222 S

-.'••- <- .,-:---- • - ; . . . ICP ICP/MSWere ICP and ICP/MS interelement corrections applied? Yes/No YES YESWere ICP and ICP/MS background corrections applied? Yes/No YES YES

If yes-were raw^data generated beforeapplication of background corrections? Yes/No NO NO

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcopy data package and in the computer-readable data submittedon floppy diskette has been authorized by the Laboratory Manager or theManager's designee-âs-êrified by the following signature.

Signature: C- ^ ZXX "_____ Name: PARVEEN HASAN

te i _____&2> /Q& faS_____ Title: QA/QC COORDINATOR

' COVER PAGE AA - LCIN IliCOl. 0

000002

U.S. EPA - CLP


COVER PAGE



SOW No.: ILC01.0

EPA SAMPLE NO. Lab Sample ID.0740131R28 38221 S0740131R31 38223 S

ICP ICP/MSWere ICP and ICP/MS interelement corrections•applied? Yes/No YES YESWere ICP and ICP/MS background corrections applied? Yes/No YES YES

If yes-were raw data generated beforeapplication of background corrections? Yes/No NO NO

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcopy data package and in the computer-readable data submittedon floppy diskette has been authorized by the Laboratory Manager or theManager's designee --as"-verif ied by the following signature.

Signature: GFTk/ /*______ Name: PARVEEN HASAN

Date: ______O=>/C£> M T Title: QA/QC COORDINATOR———————7r/—>COVER PAGE AB - LCIN ILC01.0

000003 /

CrEITlIECHChloride-

:y\H00-$EPA MCAWW Method 325.3 (Mercuric Nitrate)

' Method Detection Limit: 5 'mg/Lect

Resport Page J _ of ^- Logbook No.:Analyst; m,^ jpAfi V Supervisor:Date of Analysis; o2- /o<$ / e^~ Review Date :

5'1

ife'

I

f

}

No.

1

2

3

4

5

6

7

8

9

10

11

12

*a-Pr iV15

16

Sample IDNumber

/ /.CU (<L_

^r-lhqsO- 3 S \c\ 2.

38le,3

• 38194

• 3-lc/S

-381^6— <R 9 1 CJ ^3 O 1 i '

.3S«9S(0)

, 3Stq<K§

-,qg2CO

-^8201

j&tetu. V

i3 J> \'~*L'(qF{$*,)• SSSLî.

iL - ? £J «K -*Y

•7*1 3 ' T~ t *?J

SampleVolume(mL)

50

BO

50

c

t;o0

<50

.-=SO

,50

SP

50

J5P

qn

50

5n

DilutionFactor

•-

*"-

-

-

-

-

*

-

-

>

-

- .

-

-—

Vol. OfHg(N03)2

(mL)

o-l30- . A

I M5

G-.15{.2g

0- 851- Mo

Cr 0t

&--2-So-6«rC-M5

o-\

2.S-S

1-35

nc

TitrationVol. MinusBlank (mL)

30-2-0

1 35

0-65

V 15"

0-15

1 30

c -)o

c-15"e-\.r^-ST0-3b-. —

O ft . *j*** o *

1 * " J

1-00

Chloride

(mg/L)

<5-o

4 90 M

13- So

^•50

J)-^«

1-50

13-0

^5-o

61 MS5-oo

<S-c^ f i - p - 'â^-d\to -SO

Ift.etCalculations: mL of HafNO3>2 X Norm. fN=<S'OU-M } x 35450

Sample \.Standard True Value: 2 9-0 mq/I

*SR = sgRCfil'^ff' ma/L> - SR(^5~G ma/Li

rol. (mL)jX Smr»l Volume ro-SfmL^ X 100

Std. Volurae(o-£ mL)X Std. Added ( qq- o mg/L) * ^

(r;3R=Spike Recovery, SSR=Spiked Sample Result, SR=Sample Result rEH, Rev. 7/90 - . 000131

LOGBOOK PAGE NUMBER:

AR3 11*1*73 *****

CK-miECHChloride"

ifEPA MCAWW Method 325.3 (Mercuric Nitrate)

Method Detection Limit: 5 mg/L

Report Page ^ of 2- /\ .Logbook No.:Analyst: Nfr/ov? ^/ Supervisor:Date of Analysis :_c _/®il/_fL£l Review Date:

No.

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

Sample IDNumber

- A82./7- ^ ?2. 1 £

-3821*7

- 3'§2.10

- 3S2£)' 3?2 2_

- -^§2^3

- .3S2-2.V

41*

fi cat.c—- ^82zT

- 3$22£

>J-d,-^ /, vck_—

r- ————— ' ——— ""

SampleVolume(mL)

50

50

5C

CO

.50

.hr

"=50

SoJ50

50

50

enJ50

An__ ————— r- —————

zz — -

DilutionFactor

V,

-

•-

-

-

_

'

-

—

-

7._,™"-7 —— — — *"*

Vol. OfHg(N03)2

(mL)

6- &c

1-35/VW?

3** **o 5

• \-2*>

I- U5.e-ô

c- 25-6-1 5

<21-lo

o -Io

*-<*sc0-1&-

3\ \0-lfc

— — — — — — . —


o-'oO

1-Mb

V^5

M5"

1 35

0-80

c-itT

0-8T5<51-6C-

0-lti

d-&S3»-0i_

—— — —— ——

Chloride

(mg/L)

3 <re

1*4 \50

I9"50

\V^"c

»330

5- c o

<5-e8-5

c"5'<\J 1< 5-«56

-j. 00

6-£ o

309-^0

^5-0IT=»

fl,VlA

Calculations: mL of HorNO3)2 X Norm. ( N= C-OlMI > X 35450

Star

%SR

tsR=5

Sample iidard True Value: ma/]

= SSRC ma/L> - SRT ma/L

761. .(mL)J

\ X Smnl Volume r mL} X 100Std. Volume( mL)X Std. Added( mg/L)

Spike Recovery, SSR=Spiked Sample Result, SR^Sample Result

EH, Rev, 7/90 - x ux io 0001.39LOGBOOK PAGE NUMBER:________ "

SDG 0740131R

-.--- ....__U_,S. EPA - CLP


CRDL STANDARDS

Lab Name: CHEMTECH_CONSULTING GROUP Contract: US EPA R-III

Lab Code: CHEM _ "~ Case No.: R3074 SAS No.: SDG No.: 0740131R

. . ... Concentration Units: ug/L

Analyte


W0MN

Initial Final

True Found %R Found %R

200.0010.004.0040.002.002.00

1000.0020.0020.0020.00200.00

4.001000.0020.000.4040.00

1500.006.0020.00

1000.0020.0020.0040.00

193.038.992.5040.771.552.11

1441.90' 19.71

19.9524.20185.43

4.081030.8020.030.21

41.661074.00

4.9021.09863.4026.1618.9243.04

9790

C62.102COP106(14499

100CI21/

9310210310052104c25C [2}105CHH13195108

196.0513.142.2940.072.391.60

1416.9019.7921.3827.68203.96

2.571005.2020.59

40.611239.80

7.4719.82878.1120.0619.4242.96

98l3JkCS_T,100(T20VQ3 Q

< 142/99107(13_8102cs:101103

102CScSF

99<jOi-10097107

M

PPPPPPPPPPP'PPPNRP>PPPPPPPNR

FORM III AA - LCIN ^ rt n rt , o ILC01000019AR3 11*1*76

U.S. EPA - CLP


BLANKS



Analyte


WOMN

InitialCalib..Blank C

25.0005.0002.000-1.0101.0001.00010.0005.0002.0003.00060.0002.000

-16.830-1.3100.20010.000200.0003.0003.000

-10.2409.0002.0004.000

5000 .000

UUuBUUUUUUUuBBUUuuuBUUUU


1 C 2 C 3 C

25.0005.0002.000•i.ooo1.0001.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003 .00010.0009.0002.0004.000

5000.000


25.0005.0002.0001.0001,0001.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

5000.000


25.0005.0002.0001.0001.0001.00010.0005.0002.0003 .00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

UUUUuuuuuuuuuuuuuuuuuuu

Prep .Blank

C

25.0005.0002.0001.0001.0001.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

Uuuuuuuuuuuuuuuuuuuuuuu

M

~PPPPPPPPPPPp itjUM^1PPPPPPPc

FORM V AA - LCIN ILC01000021

AR3IH77

i .. ." i-J^'r-"'""-'-' : 'u.s. EPA - CLP----- LOW CONCENTRATION INORGANICS

BLANKS



Analyte

AluminumAntimonyArsenicBarium .BerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumLManganeseFMercuryI NickelPotassiumSeleniumSilverSodiumThalliumVanadiumZiricChloride

W0MN


Continu.

l

C 3 1 • 6Ap)

2.000G2.00JJ1.0001.000

r2TT7io~5.000

<<2.26Q)3.00060.0002.00022.470< 27lQ£L0.20010.000200.000• 3.0003.000

rTg.sso;9.0002.0004.000

ing Calibration Blanks

C 2 C 3 C

BUUBUU>BUBUUUBBUU'UUUBUUU

25.0005.0002.0001.0001.000

" 1.00010.0005.0002.0003.00060.0002.00015.0001.0000.20010.000200.0003.0003.00010.0009.0002.0004.000

UUuuuuuuuuuuuuuuuuuuuuu

25.0005.0002.0001.0001.0001.00015.3005 .0002.0003.00060.0002.00015.210

• 1.000

10.000200.0003.0003.00011.8709.0002.0004.000

UuuuuuB.uuuuuBU

UuuuB.UUU

Prep.Blank

C M

PPPPPPPPPPPPPPCVPPPPPPPPNR

FORM V AB - LCIN rtrtrtnnO ILC01000022

AR3|i*l*78

U.S. EPA - CLP


SERIAL DILUTION

0740201R24LLab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III



Comments:

Analyte


WOMN

Initial SampleResult (I)

C

36.0705.0002.0008.2501.0001.000

9021.000' ' 5.000

2.00074.86060.0006.770

5555.10052.390

10.000488.5803.0003.000

3618.2009.0002.00020.580

BUUBUU

UU

U

UBUU

UU

Serial DilutionResult (S)

C

125.00025.00010.0005.0005.0005.000

9129.00025.00010.00061.200300.00010.000

5667.00042.650

50.0001000.00015.00015.000

3383 .10045.000.10.00020.000

UUUuuuuuuuB

UUuuuuu

%Difference

100

100

1

18

100219

100

6-

100

Q

E

M

P~PPPPPPPPPPPPPNRPPPPPPPPNR

FORM X AA - LCIN ^nnAOl ILC01000027AR3 11.1*79

•Ra

U.S. EPA - CLP


,ab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III

Lab Code: CHEM Case No.': R3074 SAS No.: SDG No.: 0740131R

Instrument ID Number: PO Run No. : 1 Method: P

Star'; date: 02/24/95 End date: 02/24/95

4

EPASampleNo.

1 SO ,SSSS

j ICVICVICVICV[ICBKRIMRS[ICSAICSABCCVCCB — \ZZZZZZZZZZZZZZZZZZZZZZZZzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzCCVCCB-- -7-zzzzzzzzzzzzzzzzzzzzzzzzI

Prep.BatchNumber

Time

14151417142114231424142514291433143814421451150615191523152615291545155216021607161016131617162016241628163116341645165016541657

D/F

1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00

Analytes

AL

X

X

X

—XXXXXXX

XX

—

sB

xX

—xXXXXXXX

XX

—

AsxX

X

XXXXXxX

XX

BA

XX

X

XXXXXxX

XX

BE

xx

x

XXXXXXX

XX

cD

XX

x

XXx.XXXX

XX

cA

X

X

x

XXXXXXX

XX

cR

xx

x

XXXXXXX

XX

coXx

X

XXXXXXx

XX

cuXX

X

XXXXXXx

XX

FE

X

X

X

XXXXXXx

XX

PB

XX

X

XXXXXXX

XX

M|G|

x|

X

X

XXXXXXX

XX

M|N

XXj

X

XxXXXXX

XX

HG

—

—

—

NIXX

x

XXXXXXX

XX

K

X

X

X

XXXXXXX

XX

sE

X

X

x

XXXXXXX

XX

A|G

X

XX

XXXXXXX

XX

N|A

X

X

X

XXXXXXX

XX

TL

X

X

—

XXXXXXXX

XX

V

XX

X

zN

XX

X

-XXXXXXX

XX

XXXXXXX

XX

FORM XVI AA - LCIN . ILCO11

000036AR3H*l*8.Q

U.S. EPA - CLP




Instrument ID Number: PO Run No. : 1 Method: P


j EPAj Sample

No.

Prep.BatchNumber

Analytes

Time D/F |A|S|A|B|B|C|C|C|C|C|F

|ZZZZZZ • 1702 1.00||ZZZZZZ 1715 l.OOJ|ZZZZZZIZZZZZZ j ' I 17221 1.00IZZZZZZ j 11726j 1.00IZZZZZZ I 1730 1.00I CCVj CCB -3>|ZZZZZZJ0740131R29 | 02229508P0740131R11 | 02229508P0740131R04 02229508P

1733 1.00

074013 1R07|0740201R140740201R230740201R320740201R33|0740201R06CCV

ZZZZZZZZZZZZZZZZZZzzzzzz0740201R240740201R24D0740201R24S0740201R24L0740201R160740201R26CCV

02229508P02229508P02229508P02229508P

173617451749175317571800180518141817

X1.001.001.001.001.001.001.001.00i.oolx

X

X

02229508P|1823 1.0002229508P

02229508P02229508P02229508P02229508P02229508P02229508P

1827| 1.001830J 1.001833J 1.001851 1.001855191019151923193219361951195619592002

1.001.005.001.001.001.005.001.001.001.00

2005J 1.00

B S A

X|X|XX

X

X X

XX

X

XX X

xlxxjx|xxjxjx

X

A|R|OJU.UJ.

P|M|MB G

X|X|XXJX

x|x|xXJXXJX

X X

X|X

X|XX|XXJX

XX X X

Xx|xjxxjxjxjx

X

xjxjxx|x|x|x|x|x

XX

X X

x|x|x|x|xjxjxxjx|x|x|x|xjxxjx|x

X

Xx|xX

X

X

X

X

x|x

X

X

X

X

x|xxjxxjx

X

xjxX

X

X

x|xX

X

NH|N|K|S|A|N

X

X X

I.1.

X XX X

x|xxjxxjxx|xX

X

x|xxjxX|XxjxxjxX X

X X XX|X|.X|X

XJXXJXXJXXJXX X

Xx|x

XX

V

X

x|xX,X

X

X

X

.LU.X

X

X

X

x|xxjx

X

X

X

FORM XVI AB - LCIN ILCO11

000037AR3U148I

- ./"-.,- .7.- - U.S. EPA - CLP

VT LOW CONCENTRATION INORGANICSANALYSIS RUN LOG'(A)

lab Name: CHEMTECH CONSULTING GROUP Contract: US EPA R-III

Lab Code: CHEM Case No.: R3074 SAS No.: SDG No. : 0740131R

Instrument ID Number: PO Run No. : l Method: P


•

EPASampleNo.

PBWLCSW0740201R15CRILRSICSAICSABCCVICCB— 1t1

Prep.BatchNumber

02229508P02229508P02229508P

T111

1i

f

Time

201420212027204520542105211021132116

—— —

———

D/F

1.001.001.001.001.001.001.001.001.00

„

Analytes

AL

XxXXXXXXX

sB

XXXXXXXXX

AS

XXXxXXXXX

BA

XXXXxXXXX

1

BE

XXXxxXXXX

cD

XXXxXXXXX

1

cA

XXxxxXXXx

cRXXxxxXXXx

cocu

X XX Xx|xx|xX|Xxjxxjxxjxxjx

F.E

xXXxxXxxX

PB

XxxXXXXXX

MG

XxxxXXXXX

MN

XXxxXXXXX

HG

I

NI

XXxxXXXXX

K

XXxxXxXXX

sE

XxxxxxXXX

AG

XXXxXXXXX

NA

XXXxxxXXx

TL

XXXXxxXXX

V

XXXXxxXX-x

zN

XXXXXXXXX

FORM XVI AC - LCIN ILCO11

.000038

"AR3 11*1*82

1 , U.S. EPA - CLP


COVER PAGE


Lab. Code: CHEM Case No.: R3074 SAS No.: SDG No.: 0740131R

SOW No. : ILC01 i£

EPA SAMPLE NO. Lab Sample ID0740131R04 38229 S MR W0740131R07 38293 S rrfTftlU0740131R11 38228 S0740131R29 . 38227 S0740201R06 38301 S0740201R14 38294 S0740201R15 38304 S0740201R16 38302 S0740201R23 38295 S0740201R24 38296 S0740201R24D • 38297 S20740201R24S 38298 DS0740201R26 38303 S0740201R32 ' . 38299 S0740201R33 38300 S

ICP ICP/MSWere ICP and ICP/MS interelement corrections applied? Yes/No YES YESWere ICP and ICP/MS background corrections applied? Yes/No YES YES

If yes-were raw data generated beforeapplication of background corrections? Yes/No NO NO

Comments:

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcopy data package and in the computer-readable data submittedon floppy diskette has been authorized by the Laboratory Manager or theManager's designeeâa-v^rified by the following signature.

Signature: X^M 1 { ^ _____ -Name: PARVEEN HASAN

Date: _____O 2> / &•& fa £______ Title: QA/QC COORDINATOR————————f ff———————COVER PAGE AA - LCIN ILCO1

'000002

AR3ll*l*83

QE.IKECH ..: .-JSUi.rvG C-:=.O'JP. INC. 110 Route 4 • Englewood. New Jersey 07631 Phone: (201) 567-6868 Fax: (201)567-3.333

CASE NARRATIVES Hto W ""

ICase Number: R3074 SDG Number: 07013R

a. Number of Samples and Date of Sample Receipt:

13 water samples were received by the laboratory intact on Feb 1 and Feb 2.1995.

b. Parameters:

These samples were analyzed for Low concentration TAL Metals and Chloride.

c. Analytical Techniques:

1. Samples were digested for ICP analysis by EPA CLP Method.2. Samples were analyzed for TAL metals (except Mercury) by ICP Trace Analyzer by CLP Method..3. Samples were digested and analyzed for Mercury by Cold Vapor CLP Method.4. Samples were analyzed for Chloride by EPA Method 325.3.

d. QA/QC Samples:

The Preparation Blank (PB) and the Laboratory Control Sample (LCS), were digested and analyzed along withthe samples. The Preparation Blank results were found to be less than the Contract Require Detection Limits(CRDL's) and are reported on Form III.

1. Pre-Digested Spike (PDS)

Sample 0740201R24 was analyzed as the Pre-Digestion Spike (PDS), and the results are reported on Form"VII". ALL % Recoveries are within the control limits.

2. Duplicate (DUP)

Samples 0740201R24 was analyzed as Duplicates (DUP), and all % RPD's are within the control limits exceptlead. These results are reported on Form VIII.

3. Serial Dilution

Sample 0740201R24 was analyzed as Serial Dilution analysis with 4 X dilution. The % Differences arereported on Form X, and all are within the control limits except manganese.

The results of samples are reported on Form 1's. The units are in ug/L for aqueous samples.

, ,o - ooooîEnvironmental Services

CH-mtECHCOMUM»»O»K: Chloride-- •

EPA MCAWW Method 325.3 (Mercuric Nitrate),. , „ Method Detection Limit: 5 mg/L<Uu<?-4: AMci s ,v y/

Report Page _\_ of — V Logbook No.:____Analyst: n\tn >'-MO ^* Supervisor: _____Date of Analysis:_cJ=_/_l£_/JL£_ ' Review Date:__/

No.

~2 i/

3

4

5

6

7

8

9

10

11

12

13

14

15

16

Sample IDNumber

fejc.u .lc_

AKl'W )A Hoi- S- ^&?_2/7

3S2.2.S

-3Sm

- 2. 3

- S&i^H

- saiis:- .3&2qfc

^ 2 1 (»

SS23fcM

-3S^<?4KtC^^Zfit<Ald

• S3ot)- 383c|

SampleVolume(mL)

n.sosoAD

.c;n,50

o

.50

J=>0

so50

.TO

50

50

So '50

DilutionFactor

.-

-

-Ni

-

-

-

-

-

-

s. •

--

•

Vol. OfHg(N03)2

(mL) |

o- 1£7- ko1-2.5

c-«fo«?• MO0-^5

)-5>o6- "7*7

i-l£1-30

6-75"\- 505>l\5eo-lo

o-3oG- 15


o?T 5C

t-15

c -S

>?-ê-s-S'1 2

0-6^

1-05"

l-2o

6-^r1 4

5»-4' —

0% 2.0

c-15"

Chloridei»

(mg/L,)ii

< 5- Oh

•212- 2

II- 5*

^•ooZ1.-W

•50 '.V.fi..1 o • S'oU-c

66- Hfcm-o313-10

< 5 ot

ri-o: f)-oo

Calculations: mL of HafNO3)2 X Norm. (N=o-0|Mj ) x 35450Sample ^

Standard True Value: e?al<^«<9 mg/1

%SR = SSRr ma/L) - SRflO'fO mCT/L

/ol. (mL) 1

J\ X Smol Volume fO-t mL) X 100 1

Std. Volume(o-X mL)X Std. Added ( .zq<fo mg/L) y £( Q- , J

" :SR=Spike Recovery, SSR=Spiked Sample Result, SR=Sample Result 1

EH, Rev. 7/90LOGBOOK PAGE NUMBER:

Chloride- • •

EPA MCAWW Method 325.3 (Mercuric Nitrate)ccue * - - Meth°d Detsction Limit: 5 mg/LReport Page 2- of _2 _ A) Logbook No.: ____'Analyst: rv\tojf*7 _ VJ Supervisor: ______Date 'of Analysis: Q2 /1Q / j~ Review Date: __ / __ /

No.

1

2

3

4

5

6^__

7

8

9

10

11

12

13

14

15

16

Sample IDNumber

- /?S*SC2.

3WC3

- ,9 3 CH

/Jf-t

R i c-

- ———— - ———— -

^

/^- _______

SampleVolume(mL)'

SD '

5.

5c

c.'

So

- ——— ~

^

•

, ——— — —— •

DilutionFactor

--

-s

-

' — — — — .

***

**•'

—— ———————

Vol. OfHg(N03)2

(mL)

1 5o-^rc -35

2-^-1

o-\

^-————

^

""


__•__!- . —————— - .

i-iro-isC-sLT

' 5^vo—

——— — ,

^

W*

Chloride

(mg/L)

II-TD1-50

4 5-C

i$3 *\\<%-o

-

•HV

Calculations: mL of HarNO3)2 X Norm. fN= d'frlMI ) X 35450Sample \

Standard True Value: «*/l1'0 mq/I

%SR - SSRf ma/L) - SRf ma/L)

rol. (mL)i

X Smt>l Volume ( mL) X 100Std. Volume ( . mL)X Std. Added ( mg/L)

"£sR=Spike Recovery, SSR=Spiked Sample Result, SR=Sample Result

EH, Rev. 7/90—— LOGBOOK PAGE NUMBER;

Documents

AR3 11*1*01* · Functional Guidelines for Evaluating Inorganic Analyses, September, 1992, with modifications for use within Region III. INFORMATION REGARDING REPORT CONTENT Table

AR3 11101* · Functional Guidelines for Evaluating Inorganic Analyses, September, 1992, with modifications for use within Region III. INFORMATION REGARDING REPORT CONTENT Table