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Supplementary data Feedwater pH affects phosphorus transformation during hydrothermal carbonization of sewage sludge Tao Wang a,b , Yunbo Zhai a,b, * , Yun Zhu c,d , Chuan Peng a,b , Tengfei Wang a,b , Bibo Xu a,b ,Caiting Li a,b , Guangming Zeng a,b a College of Environmental Science and Engineering, Hunan University, Changsha 410082, P. R. China b Key Laboratory of Environmental Biology and Pollution Control ( Hunan University ), Ministry of Education, Changsha 410082, P. R. China c ShenzhenInstitutes of Hunan University, Shenzhen518000, P. R. China d Office of Scientific R& D, Hunan University, Changsha 410082, P. R. China

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Page 1: ars.els-cdn.com · Web viewof Hunan University, Shenzhen518000, P. R. China d Office of Scientific R& D, Hunan University, Changsha 410082, P. R. China Supplementary Figures. S1-S

Supplementary data

Feedwater pH affects phosphorus transformation during hydrothermal

carbonization of sewage sludge

Tao Wanga,b, Yunbo Zhaia,b,* , Yun Zhuc,d, Chuan Penga,b, Tengfei Wanga,b, Bibo

Xua,b,Caiting Lia,b, Guangming Zenga,b

aCollege of Environmental Science and Engineering, Hunan University, Changsha

410082, P. R. China

bKey Laboratory of Environmental Biology and Pollution Control (Hunan

University), Ministry of Education, Changsha 410082, P. R. China

cShenzhenInstitutes of Hunan University, Shenzhen518000, P. R. China

dOffice of Scientific R& D, Hunan University, Changsha 410082, P. R. China

Supplementary Figures. S1-S2.

Page 2: ars.els-cdn.com · Web viewof Hunan University, Shenzhen518000, P. R. China d Office of Scientific R& D, Hunan University, Changsha 410082, P. R. China Supplementary Figures. S1-S

Fig.S1 SEM images and energy spectrum of (a) dried SS and (b) resulting hydrochar

of 260-7.

Page 3: ars.els-cdn.com · Web viewof Hunan University, Shenzhen518000, P. R. China d Office of Scientific R& D, Hunan University, Changsha 410082, P. R. China Supplementary Figures. S1-S

10 20 30 40 50 60 70

0

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3500

85-0798 Quartz 79-1570 Kaolinite① ② 72-1503 Muscovite 84-0853 Aluminum phosphate③ ④

④②③

①④①

③③②②② ①

Inte

nsity

Two-Theta (deg)

sewage sludge

(a)

10 20 30 40 50 60 70

0

500

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3500

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4500

5000

85-0798 Quartz 79-1570 Kaolinite① ②

72-1503 Muscovite 84-0853 Aluminium Phosphate③ ④

09-0345 Calcium Phosphate 45-0339 Sodium Calcium Phosphate⑤ ⑥

200-11

200-9

200-7

200-5

①⑤ ⑤

⑥ ⑥

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nsity

Two-Theta (deg)

200-3

(b)

10 20 30 40 50 60 70

0

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10000

15000

20000

85-0798 Quartz 79-1570 Kaolinite① ②

72-1503 Muscovite 84-0853 Aluminium phosphate③ ④

09-0345 Calcium Phosphate ⑤

④②

③ ③③ ②

② ① ① ① ① ①

Inte

nsity

Two-Theta (deg)

230-3

230-11

230-9

230-7

230-5

(c)

10 20 30 40 50 60 70

0

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85-0798 Quartz 05-0143 Kaolinite① ②

72-1503 Muscovite 72-1084 Aluminium phosphate③ ④

29-0283 Gatumbaite 41-0489 Calcium phosphate⑤ ⑥

⑥ ⑥

②② ④②②③④①

①①①

Inte

nsity

Two-Theta(deg)

① 260-11

260-9

260-7

260-5

260-3

(d)

Fig.S2 XRD patterns of (a) sewage sludge and resulting hydrochars after HTC with

different feedwater pH (3, 5, 7, 9 and 11) at (b) 200C, (c) 230C and (d) 260C.