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Assalamu’alaikum …^_^. Welcome to Chemistry Learning The … th meeting of the class !!!. “Oxidation-Reduction Reactions” ( Equalization Method of Equation Redox Reaction ). Created by: Nadya Raudotul Jannah 0905699. Aperseption :. In X grade, you have ever studied about redox reaction. - PowerPoint PPT Presentation
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Assalamu’alaikum…^_^
Welcome to Chemistry LearningThe …th meeting of the class !!!
“Oxidation-Reduction Reactions”
(Equalization Method of Equation Redox Reaction)
Created by:Nadya Raudotul Jannah0905699
In X grade, you have ever studied about redox
reaction.
Do you still remember, what is the meaning of oxidation and reduction
reaction?!?
Aperseption :
What do you know about oxidation number?!?
And how to determine the oxidation number of the element?!?
Remember…^_^
LEO SAYS GER
LEO says GER : Lose Electrons = Oxidation
eNaNa10
Sodium is oxidized
Gain Electrons = Reduction
10 CleCl Chlorine is reduced
LEO says GER : - Losing electrons is oxidation, and the substance
that loses the electrons is called the reducing agent.
- Gaining electrons is reduction, and the substance that gains the electrons is called the oxidizing agent.
Mg is oxidized: loses e-, becomes a Mg2+ ion
Mg(s) + S(s) → MgS(s)
Mg is the reducing
agent
S is the oxidizing agent S is reduced: gains e- = S2- ion
Oxidation and Reduction (Redox)It is easy to see the loss and gain of electrons in ionic compounds, but what about covalent compounds? In water, we learned that oxygen is highly electronegative, so:
the oxygen gains electrons (is reduced and is the oxidizing agent), and the hydrogen loses electrons (is oxidized and is the reducing agent)
Exploration :Does each chemical
reaction must be equal?!?
What do you know about equalization of chemical reaction?!?Does the simple
chemical reaction can be equal with spontan method?!?
The Meaning of Oxidation and Reduction (called “redox”) Learning Objectives
After Learning this topic, you are expected to be able to:
Describe how oxidation numbers are used to identify redox reactions.
Balance a redox equation using the oxidation-number-change method.
Balance a redox equation by breaking the equation into oxidation and reduction half-reactions, and then using the half-reaction method.
Concept MapRedox Reaction and Electrochemistry
Electrochemical Cell
Alectrolysis Cell
Redox Reaction
Reaction Equalizati
onCell Potential
Standard Reduction Potential
Half Reaction
Oxidation Number
based onincluding
Is cunducted
by means of
In general, all chemical reactions can be assigned to one of two classes:
1) oxidation-reduction, in which electrons are transferred:
• Single-replacement, combination, decomposition, and combustion
2) this second class has no electron transfer, and includes all others:
• Double-replacement and acid-base reactions
Identifying Redox Equations
Identifying Redox Equations
In an electrical storm, nitrogen and oxygen react to form nitrogen monoxide:
N2(g) + O2(g) → 2NO(g)
• Is this a redox reaction?• If the oxidation number of an element in
a reacting species changes, then that element has undergone either oxidation or reduction; therefore, the reaction as a whole must be a redox.
YES!
Balancing Redox Equations It is essential to write a correctly balanced equation that represents what happens in a chemical reaction• Fortunately, two systematic methods are
available, and are based on the fact that the total electrons gained in reduction equals the total lost in oxidation. The two methods:
1) Use oxidation-number changes2) Use half-reactions
Using Oxidation-Number Changes
Sort of like chemical bookkeeping, you compare the increases and decreases in oxidation numbers.• start with the skeleton equation• Step 1: assign oxidation numbers to all atoms;
write above their symbols• Step 2: identify which are oxidized/reduced• Step 3: use bracket lines to connect them• Step 4: use coefficients to equalize• Step 5: make sure they are balanced for both
atoms and charge
For Example:
Please Look at the Video
Elaboration :What All Reactions that occur in the world
are Redox Reactions?!?
What method that can be used to equal reaction but not redox reaction?!?
Not All Reactions are Redox Reactions
- Reactions in which there has been no change in oxidation number are NOT redox reactions.
Examples:
)()()()( 3
2511111
3
251aqONNasClAgaqClNaaqONAg
)()()()(22
2
1
4
26
2
1
4
26
2
1121lOHaqOSNaaqOSHaqHONa
Using half-reactions A half-reaction is an equation showing just the oxidation or just the reduction that takes place they are then balanced separately, and finally combined
Step 1: write unbalanced equation in ionic formStep 2: write separate half-reaction equations for oxidation and reductionStep 3: balance the atoms in the half-reactions
(More steps on the next slide)
Using half-reactions (Cont’)• Step 4: add enough electrons to one side
of each half-reaction to balance the charges
• Step 5: multiply each half-reaction by a number to make the electrons equal in both
• Step 6: add the balanced half-reactions to show an overall equation
• Step 7: add the spectator ions and balance the equation
For Example:
Please Look at the Video
Any Question ?!?
who can explain the main topic
about this matter?!?
Choosing a Balancing Method
1) The oxidation number change method works well if the oxidized and reduced species appear only once on each side of the equation, and there are no acids or bases.
2) The half-reaction method works best for reactions taking place in acidic or alkaline solution.
Comfirmation:
Conclution Reactions in which there has been change in oxidation number
are called redox reactions. Every redox reactions consists of half reaction (oxidation
reaction) and half reaction (reduction reaction). Oxidation is various types of process that naturally to increase
valence from vital element in that system. Initial oxidation is in the form of reaction from elements with oxygen, then with halogen too, and ultimately its vital elements reaction loses its valence electron.
Reduction is hydrogen addition of intake in any substance, oxidation degree depression of any elements in compound, or electron addition in any elements atom.
Redox reaction quotation must be equal between left and right field. The applied method for equalizing redox reaction is oxidation number and half reaction method.
Evaluation:
Exchange and equalize the following redox reaction equation:
a. Zn(s) + SO42-(aq) Zn2+(aq) + SO2(g)
b. Fe2+(aq) + MnO4
-(aq) Fe3+(aq) + MnO2(s)
c. CN-(aq) +MnO4-(aq)+H2O(l) MnO2(s)
+ CNO-(aq) + OH-(aq)
KEEP OUR SPIRIT AND NO TIME FOR LOSER Thanks for Your Attention !!!
Wassalamu’alaikum…^_^