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Chemical technology and engineering Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements Applied Chemistry Tomsk 2011

Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Page 1: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

Chemical technology and engineering

Associate professor, PhD, Ostvald Roman

Tomsk Polytechnic University, Institute of Physics and TechnologyChair of Rare, Scattered and Radioactive Elements Applied Chemistry

Tomsk 2011

Page 2: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

INTRODUCTION

CHEMICAL TECHNOLOGY AND ENGINEERING

Page 3: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Time Distribution

Laboratory - 2 hours

Seminars - 8 hours

Consultations - 2 hours

Total classes - 12 hours

Students self study - 10

hours

Final presentation 10

semester

Page 4: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Seminars plan

Introduction into chemical

engineering

Laboratory extraction

Industrial extraction

Distillation and rectification

in chemical technology

Page 5: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

5

Video lectures

Channing Robertson – Professor of the

Stanford University Chemical Engineering

Department

20 lectures Introduction to Chemical Engineering. Introductory course offered by the Stanford University Engineering Department. http://www.youtube.com/watch?v=WgWNQVdhE9A&feature=BFa&list=SPD2D34BCA5468DD9A&index=1

Page 6: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Task for final presentation

Presentation about one of the chemical technology method (method of the semester project)

Title Content, introduction Description one of the chemical

technology methods Example of the method

(technology scheme, graphs, drafts);

Conclusion

Page 7: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Presentation example

Page 8: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

8

Presentation example

Page 9: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

9

Presentation example

Page 10: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

10

Presentation example

Page 11: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

11

Presentation example

Page 12: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

12

Presentation example

Page 13: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

13

Presentation example

Page 14: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

14

Presentation example

Page 15: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

15

Presentation example

Page 16: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

16

Presentation example

Page 17: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

17

Presentation example

Page 18: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Presentation example

Page 19: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Final presentation

Presentation has to based on

semester project

authentic materials (handbooks,

scientific papers and others)

Page 20: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

MASS TRANSFER

CHEMICAL TECHNOLOGY AND ENGINEERING

Page 21: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Mass Transfer

What is the term “the

mass transfer” mean?

What do you remember about mass

transfer?

What is the driving force for mass

transfer?

Page 22: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Mass Transfer

Read the text about mass transfer

process and try to explain words in

bold

Page 23: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Mass Transfer

diffusivity

based on the concentration gradient

estimation

calculation, evaluating

flux

stream, flow

permit

make possible to smth., allow to smth.

driving forces

make possible to realization of some phenomenon

myriad

huge amount of smth.

conversely

vice versa

stagnant

immovable, static

Page 24: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Mass Transfer

transverse velocity

boundary space

transient

temperature remains constant

either

slow movement

isothermal has many aspects

creeping flow

temporary, short term

crosscut rate

multidimensional

both

approach

be right for smth., come near

steady

stable, balanced

interfacial area

conveyance

transposition, movement

Page 25: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Mass Transfer

Page 26: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Material balance

Draw up the material balance table of the sorption column in which process of separation of threefluoride of bromine and pentafluoride of iodine is produced. Starting composition: IF5 – 0.53 mole fraction; BrF3 – 0.47 mole fraction. Requirements to quality of product: content of BrF3 in IF5 less then 0.05 mole fraction, and contamination of BrF3 by IF5 can be 0.2 mole fraction.

Page 27: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

HEAT TRANSFER

CHEMICAL TECHNOLOGY AND ENGINEERING

Page 28: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Heat Transfer

Have you ever heard

such term as “the heat transfer”?

What do you remember about heat

transfer?

What is the driving force for heat

transfer?

Page 29: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Heat Transfer

Read the text about heat transfer

process and try to explain next terms

Conduction model of heat transfer

Convection model of heat transfer

Radiation model of heat transfer

Page 30: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Heat Balance

Page 31: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

CHEMICAL REACTORS

CHEMICAL TECHNOLOGY AND ENGINEERING

Page 32: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Chemical Reactors

What do you

remember about chemical reactors

classification?

What kind of ideal reactors do you

remember?

What are ideality degrees for ideal

chemical reactors?

Page 33: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Chemical Reactors

Page 34: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Chemical Reactors

Read the text about chemical

reactors and answer on following

questions again What do you

remember about chemical reactors classification?

What kind of ideal reactors do you remember?

What are ideality degrees for ideal chemical reactors?

Page 35: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Chemical Reactors

After text reading fill the table of right sentences numbers

1. The chemical reaction proceeds as the reagents travel through this reactor.

2. The flow rate in must be equal flow rate out, otherwise this reactor will overflow or go empty.

3. It can be economically beneficial to operate several this reactors in series or in parallel.

4. At the inlet to this reactor the rate is very high, but as the concentrations of the reagents decrease and the concentration of the products increases the reaction rate slows.

Page 36: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

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Chemical Reactors

After text reading fill the table of right sentences numbers

5. Infinite number of infinitely small reactors operating in series would be equivalent to a PFR.

6. All calculations performed with this reactor assume perfect mixing.

7. Reagents may be introduced into this reactor at loca-tions in the reactor other than the inlet.

Page 37: Associate professor, PhD, Ostvald Roman Tomsk Polytechnic University, Institute of Physics and Technology Chair of Rare, Scattered and Radioactive Elements

Chemical technology and engineering

Associate professor, PhD, Ostvald Roman

Tomsk Polytechnic University, Institute of Physics and TechnologyChair of Rare, Scattered and Radioactive Elements Applied Chemistry

Tomsk 2011