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Axial transport and residence time of MSW in rotary kilns
Part I. Experimental
S.-Q. Li a,b,*, J.-H. Yan a, R.-D. Li a, Y. Chi a, K.-F. Cen a
aDepartment of Energy Engineering, Zhejiang University, Hangzhou 310027, PR ChinabDepartment of Thermal Engineering, Tshinghua University, Beijing, 100084, PR China
Received 17 October 2000; received in revised form 28 December 2001; accepted 31 December 2001
Abstract
Experiments on the influences of operational variables on the axial transport of both heterogeneous municipal solid waste (MSW) and
homogenous sand are conducted in a continuous lab-scale rotary kiln cold simulator. Compared with sand, the residence time of MSW has a
relatively large discrepancy with the ideal normal distribution due to the trajectory segregation of MSW components. The residence time at
different axial zone is quite different due to the varied bed depth profile along the kiln length. MSW has a longer mean residence time (MRT)
and a lower material volumetric flow (MVF) than sand because of the higher hd than sand. The increment of both rotating speed and kiln
slope reduces MRT, and increases MVF. Exit dam has a significant impact on the MRT and the influence of internal structure group
consisting of various axial ribs and circular ribs is mainly determined by the height of circular ribs. Inside wall roughness also has effect on
MRT through changing the bed regimes. For a case with the certain inlet and exit bed depths, the product of MRT and MVF holds at a
constant within the limits of experimental errors in spite of the changing experimental variables.
D 2002 Published by Elsevier Science B.V.
Keywords: Rotary kiln; MSW; Axial transport; Mean residence time; Material volumetric flow
1. Introduction
Rotary kilns have been widely employed in chemical and
metallurgical industries as heterogeneous noncatalytic gas–
solid reactors. The typical applications include drying or
heating of wet solids, mixing or grinding of powders,
calcining of limestone, clinkering of cementitious materials,
reducing of iron ore or ilmenite, etc. [1–3]. Rotary kilns
continue to find new applications in such gas–solid reac-
tions, despite challenges from newer and more specialized
reactors such as fluidized bed and spouted bed.
In recent years, rotary kilns have played an important
role in the thermochemical treatment of municipal solid
wastes (MSW). Rotary kiln system is one of the most
promising incineration processes since it can simultane-
ously treat wastes as liquids or solids of various shapes
and sizes and easily achieve the flexible adjustment by
altering kiln inclination, rotational speed, etc. Rotary kiln
as a primary gasification chamber, followed by a secon-
dary combustion chamber, can fulfil the complete destruc-
tion and detoxification of hazardous wastes, meanwhile
minimize emissions of dioxins and heavy mental. All these
unique features enable rotary kiln irreplaceable in MSW
incineration. ‘Siemens Schwelbrenn’, ‘Noell Conversion’
and ‘Westinghouse O’Connor’ processes are updated rep-
resentatives of rotary kiln incinerators [4,5].
Pyrolysis, on the other hand, is an attractive alternative to
incineration as a waste treatment option with respect to
minimum environmental emissions and maximum resource
recovery [6,7]. Rotary kiln pyrolyser also has many unique
advantages over other types of reactors. For instance, slow
rotation of inclined kiln enables the well mixing of wastes,
thereby the more uniform pyrolytic products. Also, the
flexible adjustment of residence time can make pyrolysis
reaction perform at a perfectly optimum condition conven-
iently. With a view to different resource recovery option,
rotary kiln can be properly designed to yield mainly the
synthesis gas, e.g., ‘Landgard’ Process [8], or to make the
high calorific tars as well as porous carbon black, e.g.,
‘Kobe Steel’ Process [9].
Mean residence time (MRT) of solids through rotary kiln
is one of the most important parameters, which not only
directly influences mass and heat transfer, but also deter-
0032-5910/02/$ - see front matter D 2002 Published by Elsevier Science B.V.
PII: S0032 -5910 (02 )00014 -1
* Corresponding author. Tel.: +86-10-62782108.
E-mail address: [email protected] (S.-Q. Li).
www.elsevier.com/locate/powtec
Powder Technology 126 (2002) 217–227
mines chemical reaction degree of gas and solid phase. In
order to optimize the design and operation of rotary kiln, it
is necessary to develop the simplified empirical expressions
to enable the proper predicting of the volumetric flow of
material (MVF) as well as MRT. Sullivan et al. [10]
originally conducted the experimental research on the sol-
ids’ MRT in rotary cylindrical kiln and derived the empirical
equation of MRT correlating various operational variables,
kiln geometry parameters and material properties. Subse-
quently, Vahl and Kingma [11] and Kramers and Kroock-
ewit [12] made further experiments on the holdup as well as
MRT in a horizontal or inclined cylinder, respectively. The
effect of internal structures is one of remarkable research
community. Chatterjee et al. [13] studied the effect of ring
formation, Matchett and Sheikh [14] studied the effect of
both number and angle of axial flight, and Rutgers [15]
considered the influences of shapes of kiln entrance and exit
end faces. Furthermore, the residence time distribution
(RTD) in rotary drums were researched by Abouzeid and
Fuerstenau [16] and Sai et al. [17] adopting tracer stimulus-
response techniques, or by Wes et al. [18] using atomic
absorption spectroscopy methods. In addition, as the prac-
tical field-scale rotary kiln was concerned, Groen et al. [19]
performed corresponding investigations in a high-temper-
ature kiln, while Schofield and Glikin [20] studied them in
an intensive gas-flow fleeting kiln.
More recently, Wightman and Muzzio [21] emphasized
that a research community focusing on the segregation of
multimixed particles in rotary cylinder. Donald and Rosse-
man [22] firstly performed experimental studies in a hori-
zontal system and identified three patterns of segregation:
radial, axial and end longitudinal. Gupta et al. [23] described
qualitative mechanisms of axial segregation, stating that a
difference in the dynamic reposing angles of two pure
components is a necessary (though not sufficient) condition
of band formation. Nakagawa et al. [24] recently employed
magnetic resonance imaging to study axial segregation.
Boateng and Barr [25] and Bridgewater et al. [26] studied
the mechanism of radial segregation, respectively.
However, previous researches on axial transport in rotary
kilns are mostly concentrated on the studies of small
cementitious and metallurgical particles, which are rela-
tively homogeneous in nature. Although rotary kilns have
been extensively used as reactors for MSW incineration or
pyrolysis, so far, there have been few attempts on extrap-
olating the experiences and correlation developed from
homogeneous materials to heterogeneous MSW. In this
part, comparative studies are conducted between homoge-
neous sand and irregular MSW in a rotary kiln cold
simulator (I.D. 0.3� 1.8 m). Impacts of material character-
istics (in terms of the dynamical angle of repose), kiln
geometry characteristics (i.e., roughness of kiln wall, exit-
end dam and internal structures) and operational parame-
ters (i.e., kiln inclination and rotational speed) on both
MRT and MVF are examined. Simplified formulas of MRT
and MVF are proposed on the basis of the experiment
results in Part II of this work.
2. Experimental
2.1. Setup
A cold simulator of rotary kiln, 0.3 mm in diameter and
1.8 mm in length, shown schematically in Fig. 1, was
employed for the experiments. The cylinder was made of
plexiglass so that the solid motion can be viewed. The
rotational speed is variable within the range of 0.5–10 rpm
(revolution per minute). The angle of kiln inclination can be
easily adjusted between 0j and 5j by altering the height of
the supporter at kiln inlet end. The feed rate of materials was
adjusted to a certain amount that keeps the inlet depth of the
solids on a desired value during each run. That is, the inlet
depth of solid bed responds to the feed rate of materials,
which is practically equal to the flow rate of materials under
the steady state, one to one, under the same operational
conditions. Therefore, the inlet bed depth instead of material
feed rate were selected as one of the operating parameters,
which was kept at 70 mm in all runs.
In order to study the impact of internal structures on solid
material motion, axial ribs and circular ribs were specially
designed, as shown in Fig. 2. The grouped types and
Fig. 1. Schematic of rotary kiln cold simulator ((1) Funnel, (2) Belt conveyor, (3) Tracer addition point, (4) Feed chute, (5) Rotary cylinder, (6) Position
plate, (7) Belt wheel, (8) Position wheel, (9) Jockey wheel, (10) Slope angle adjustor, (11) Supportor, (12) Varible motor, (13) Exit chute, (14) Sample
collector).
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227218
geometric factors of the different kinds of axial ribs and
circular ribs are listed in Table 1.
2.2. Materials
Two categories of materials were employed for experi-
ments. One was reconstituted MSW consisting of 49.9 wt.%
wood chips, 17.0 wt.% paper plates and 33.1 wt.% waste
tyres. The mixture has irregular shape, size and heteroge-
neous property. Also, homogeneous sand was used as
another category for a contrast, which has higher density,
regular shape and similar size. The physical properties of
both kinds of materials are given in Table 2.
As was reported in earlier literatures [11–20], the bulk
characteristics of solids in terms of the dynamic angle of
repose, hd, exert significant influences on the transport and
mixing of the solids in the kiln. Here hd is measured
according to the Rotating Drum-Method (Henein et al.
[27]). This measurement is done under one of the most
general bed rotation cases of the kiln, rolling regime, and it
can reflect the real dynamical bulk characteristics of solids
in kiln. For all hd measuring of various materials, the kiln
rotates at 4 rpm and fill ratio of solids in the kiln is about
15%–20%. hd of sand is about 29.7j while that of MSW
mixture is 48.5j.In order to study the influence of wall roughness on
MRT and MVF, the inside kiln wall are covered by the
finer or coarser emery cloths. The wall friction factor of
solids is defined as the tangent function of the wall friction
angle. The latter is measured by a special shear-plate-
analyzer with an easy adjusting shear angle. A plate, which
has the same roughness with the tested wall, is fixed on
the adjustable shear plate. A layer of tested solids is laid
on the plate. Then, the plate is gradually tilted until the
solids begin to fall along it. At that time, the slope of the
plate with respect to the horizontal line is just the wall
friction angle of solids. As shown in Table 2, compared to
the smooth inside wall, the friction coefficient, f, increased
dramatically (69–243%) with finer emery cloth setting.
However, f increased only about 6–25% from the finer
emery cloth to the coarser one.
2.3. Experimental methods
To determine MRT and MVF, the system must be
adjusted to achieve the steady state, which is reached when
the output of materials is equal to the feed rate of materials.
The steady-state flow rate of materials, volumetric or molar,
was measured by collecting sample successively within a
certain time and quantifying it. As is widely known, the
residence time of solids through rotary kiln is not a constant,
but a probability distribution. Hence, the mean and variance
of residence time are experimentally obtained by the stim-
ulus-response techniques of tracers. Generally, the method
for RTD measurement of MSW is hardly available in current
literatures, though that of homogeneous sand has been
described in detail [16–18]. In this work, experiments were
taken by introducing the dyed tracers consisting of 9 wood
chips, 15 paper plates and 36 waste tyres. The ratios of three
kinds of tracers are 47.9, 16.9 and 35.2 wt.%, which are
quite similar to those of original mixed wastes (i.e., 49.9
wt.% wood chips, 17.0 wt.% papers and 33.1 wt.% tyres). In
fact, it is difficult to feed all tracers to kiln inlet end at the
same time. Also, it is infeasible to label every tracer and
measure its time one by one in such a short time interval.
Thus, all tracers are divided into three groups and dyed red,
white and yellow (each of which consists of 3 wood chips, 5
papers and 12 tyres). As the steady state is reached, three
groups of tracers are successively fed to the kiln inlet and
the corresponding inlet time for each group is recorded. At
the kiln outlet, they were collected after a certain time
interval, until all tracers finished their excursion through
the kiln. Meanwhile, the residence time of tracers in each
sample interval was recorded (here, the inlet-time differ-
ences of three group were taken into account). The mean
and variance of residence time of the tracers are expressed
below:
MRTcXI
i¼1
tiEðDtiÞ; ð1Þ
r 2cXI
i¼1
ðti �MRTÞ2EðDtiÞ; ð2Þ
Table 1
The grouped types and geometric factors of internal structures
Group No. Axial ribs Circular ribs
Number Height
(mm)
Number Height
(mm)
Exit dam 1 – – 1 30
Exit dam 2 – – 1 50
12b-4n 12 20 4 30
12b-7n 12 20 7 30
12n-4n 12 10 4 30
12b-4b 12 20 4 50
Fig. 2. Schematic of internal structures ((1) Cylinder, (2) Circular ribs, (3)
Longitudinal ribs).
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227 219
where I is the sequence of sampling interval, Dti is the
interval of the ist sampling interval, and ti is the retention
time of tracers in the ist interval. E(Dti) can be expressed as
the ratio of the number of tracers in ist sampling interval to
that of the total tracers, i.e.:
EðDtiÞ ¼ NðDtiÞ=XI
i¼1
NðDtiÞ: ð3Þ
Usually, the relative variance is used to express the
dispersing extent of RTDs, which satisfies the relation:
r 2r ¼ r 2=MRT2: ð4Þ
3. Results and discussions
Table 3 summarizes the detailed experimental results for
MRT (together with r and rr) and MVF of the MSW in
rotary kiln simulator with various rotating speeds, kiln
slopes, exit-end dams, internal structures and walls of
different roughness. In the following sections, the effect of
each variable both on MRT and MVF will be discussed
accordingly.
3.1. Residence time distribution of MSW and sand
The previous studies on residence time of solids in
rotary kiln are scarcely concentrated on the heterogeneous
MSW, but on the homogeneous particles instead. For
instance, Abouzeid and Fuerstenau [16] concluded that
residence time of dolomites in rotary kiln is approximately
subjected to a normal distribution by employing the axial
dispersion model. The comparison between experimental
results and theoretical calculation for RTD of both sand
and MSW are shown in Figs. 3 and 4, respectively. As for
sand, the probability of tracers by experiment in each
sample interval (Dti) fits well with the theoretical normal
distribution function. However, it is noted that, for MSW,
there exists a relatively large discrepancy between exper-
imental value and theoretical curve, other than rr2 of
MSW is much larger than that of sand under the same
condition. It can be explained that, as tracers consist of
three components with various shapes, sizes and densities,
the variance in residence time would arise from axial
segregation instead of axial mixing (particle collision). In
fact, the axial segregation causes the deviation of meas-
ured RTD from the normal distribution (this view will be
further verified in Part II of this work). In addition, the
alternate band formation of the various components (i.e.,
the visible axial segregation) that has been studied and
emphasized in a batch kiln system by some investigators
[21–24] does not occur in this experiment. According to
Donald and Rosseman [22], the alternate band formation
in batch system may not arise in continuous system where
the length of system is not adequate for particles to
demix. Gupta et al. [23] stated that a difference in hdof all pure components at a particular rotation speed is
one of the necessary (though not sufficient) conditions of
band formation. From Table 2, the hd difference among
three components of MSW is not significant. The rotating
speed is only an order of magnitude smaller than that in
the study of Gupta et al. Thus, it is induced that the axial
segregation of MSW in kiln won’t be violent enough to
form alternate bands, especially for such a system with a
limited ratio of length to diameter (L/D = 6).
The detailed r and rr of RTD of MSW under various
rotating speeds, kiln slopes, exit-end dams, internal struc-
tures and wall roughness are given in Table 3. Much
valuable information can be obtained as follows. (1)
Increasing rotating speed or kiln slope leads to relatively
slight increment of r, while rr varies or keeps in a
narrow range from 0.02 to 0.05. (2) The usage of exit
dam can also increases r or rr; but the impact on
variance is less appreciable than that on MRT. (3)
Employment of internal structures promotes both r and
rr remarkably by one order of magnitude (e.g., rr from
range [0.02, 0.05] to range [0.2, 0.4]). However, it must
be stated that the measuring error of RTD’s r and rr is
quite high due to the segregation of MSW properties.
Meanwhile, the measuring precision of both MRT and
MVF can doubtlessly reach an expected level because of
their statistical averaged characteristics. Therefore, more
attention is paid to discussions on MRT/MVF rather than
r/rr in the following paper.
Table 2
Summary of properties, bulk characteristic and wall friction factors of materials
Materials Shapes Bulk density
(kg/m3)
True density
(kg/m3)
Sizes (mm) hd (j) f1 f2 f3 * *
Wood chips Cylindrical 371.5 646.0 U25� 30 47.3 0.525 0.902 0.941
Paper plates Tabulate 104.5 691.7 30� 30� 3 51.9 0.563 1.930 2.331
Waste tyre Arcuate 278.7 1020.0 10� 5� 30 52.9 0.421 0.941 1.102
Mixed MSW* – 225 777.6 – 48.5 0.480 1.003 1.251
Sand Nodular 1342 2660 1.0–2.0 29.7 0.407 0.724 0.768
* Mixed MSW consist 49.9 wt.% woods, 17.0 wt.% papers and 33.1 wt.% tyres.
** f1, f2, f3 are wall friction factor of solids with none, finer and coarser emery cloth setting on inside wall.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227220
3.2. Axial velocity distribution along kiln length
For end-open system, as the bed depth and the fill ratio
of solids in cross-section are different at the different axial
position, the axial cascading velocity of solids is not
constant along the kiln axis. That is, the residence time
in different zone along kiln length is quite different. Figs.
5 and 6 give the axial velocity of sand and MSW under
different axial points, respectively. It can be seen that the
axial velocity of particles increases along the axial direc-
tion. It is due to the decrement of the bed depth or the fill
ratio along the kiln axis. Thus, according to the mass
conservation theory, d(quA)/dx = 0, the axial velocity along
kiln length increases gradually. By the way, as for the
practical rotary kiln reactor, it has various reaction zones
along the axis and the solids have different properties in
every zone. Thus, it is essential to know the detailed
residence time of the solids in each zone. However, up
to now, nearly all the experimental/theoretical works of
solid transport are concentrated on the overall residence
time through the kiln inlet to outlet. The residence time of
solid passing a special reaction zone can be obtained by
integration of the bed axial velocity along the age of this
zone, ti ¼ mzizi�1dz=uðzÞ where z represents kiln axis and i
Table 3
Overall experimental data for MRT and MVF of MSW with different variables
Run number Internal structure Rotated rate (rpm) Inclination (j) MRT (min) MVF (l/min) r rr
1 Smooth wall 2 2.40 11.53 1.56 0.26 0.023
2 3 2.40 8.25 2.62 0.20 0.024
3 4 2.40 5.58 3.73 0.18 0.026
4 4 1.81 7.05 2.53 0.23 0.043
5 4 0.62 11.28 2.18 0.54 0.049
6 6 2.40 4.07 4.24 0.16 0.042
7 8 2.40 3.27 5.50 0.12 0.037
8 Finer emery cloth setting 3 2.40 10.98 2.04 2.65 0.24
9 4 2.40 8.87 3.09 2.02 0.23
10 4 1.81 8.78 2.09 1.75 0.20
11 4 0.62 16.80 1.16 3.84 0.24
12 6 2.40 6.20 4.58 1.19 0.19
13 8 2.40 4.20 4.62 0.85 0.20
14 Coarser emery cloth setting 3 2.40 11.83 1.60 2.10 0.18
15 4 2.40 8.40 2.80 1.70 0.20
16 4 1.81 9.47 1.96 2.23 0.24
17 4 0.62 12.30 1.69 3.82 0.23
18 6 2.40 6.15 3.82 1.43 0.23
19 8 2.40 4.95 4.27 0.97 0.20
20 Exit dam 1 (30 mm) 3 2.40 13.15 1.64 0.43 0.033
21 4 2.40 9.93 2.44 0.37 0.037
22 4 1.81 12.27 1.47 0.37 0.030
23 8 2.40 5.92 4.22 0.30 0.051
24 Exit dam 2 4 2.40 14.80 1.56 0.67 0.045
25 12b-4n 2 2.40 19.67 1.27 4.48 0.23
26 3 2.40 13.90 1.71 3.29 0.24
27 4 2.40 9.75 2.16 2.26 0.23
28 4 1.81 12.67 2.00 3.56 0.28
29 4 0.62 24.67 1.18 8.26 0.34
30 12b-7n 2 2.40 16.95 1.02 4.36 0.26
31 3 2.40 15.90 1.69 4.11 0.27
32 4 2.40 11.62 2.33 2.45 0.21
33 4 1.81 15.12 2.13 4.34 0.29
34 4 0.62 21.67 0.98 7.32 0.33
35 12n-4n 2 2.40 19.67 1.33 5.57 0.28
36 3 2.40 12.08 1.84 3.24 0.27
37 4 2.40 9.78 2.71 2.14 0.22
38 4 1.81 15.20 1.91 4.67 0.31
39 4 0.62 22.37 1.20 6.89 0.33
40 12b-4b 2 2.40 24.92 0.87 6.27 0.25
41 3 2.40 15.85 1.47 2.94 0.19
42 4 2.40 12.03 2.04 2.61 0.22
43 4 1.81 15.95 1.38 3.92 0.25
44 4 0.62 26.75 0.84 7.65 0.27
* The inlet depth of solid bed in all runs is 70mm (23% of inner diameter).
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227 221
the zone’s sequence. Axial velocity, u(x), can be calculated
through the empirical correlations (Lebas et al. [28],
Perron and Bui [29]).
3.3. Influences of particle characteristics on MRT and
MVF
The comparison of MRT and MVF between sand and
MSW under the same conditions is shown in Figs. 7 and 8,
respectively. The MRT of MSW is greater than that of sand
for all runs. From the regress curve in Fig. 7, it is obtained
that the former is about 1.43 times of the latter. Contrarily,
MVF of MSW is less than that of sand with the multiple
of 0.625 (1/1.48). From Table 2, it can be seen that sinhdof MSW is 1.50 times of that of sand. Thus, the conclusion
is drawn: the material’s characteristics exerts its influences
on the MRT and MVF mainly in terms of hd; MRT
increases approximately in linear fashion as sinhd of
material increases, while MVF is subjected to the inverse
proportional function of sinhd. These conclusions will be
verified subsequently by the theoretical analysis in Part II
of this work.
3.4. Influences of rotating speed and kiln slope
The impact of rotating speed on the MRT and MVF of
heterogeneous MSW is shown in Fig. 9. As rotational speed
increases from 2 to 8 rpm, MRT decreases nearly in inverse
proportional fashion of rotating speed, while MVF increases
gradually. These conclusions are consistent with those
acquired from the homogenous small particles by others
[11,30]. It may be explained that the axial transport of solids
mainly occurs in the active layer of bed surface, while solids
in the stagnant region under bed surface only turn around the
kiln axis without any axial displacement. As the rotational
speed increases, the times of a particle entering the active
layer per unit time increases, which further results in the
increase of the particle’s axial displacement per unit time
(namely, particle’s axial velocity) [18,31]. Therefore, MRT
decreases and MVF increases.
Fig. 3. Residence time distribution of sand.
Fig. 4. Residence time distribution of MSW.
Fig. 5. Axial speed distribution of sand along kiln axis.
Fig. 6. Axial speed distribution of MSW along kiln axis.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227222
Fig. 10 indicates the effect of kiln slope on the transport
behavior of MSW. When kiln slope angle increases from
0.62j to 2.40j, the MRT decreases in an approximately
linear fashion from 11.28 to 5.58 min, while MVF rises
from 2.18 to 3.73 l/min. It is possible that the increasing
kiln inclination causes the increment of the gravitational
force component in the axial direction of individual
particle during its cascading, i.e., the increment of the
solid axial velocity, which finally causes MRT to decrease
and MVF to increase.
3.5. Influences of exit-end dams
The exit-end dam exerts significant influences on the
MRT and MVF of solids in a rotary kiln. As shown in Fig.
11, MRT of MSW and sand with the 30-mm dam (about
10% of inner kiln diameter) are 78.0% and 71.4% longer
than that with no end constriction, respectively. As for a
higher 50-mm dam (about 16.7% of inner diameter), the
corresponding augment is 165% and 138% for MSW and
sand, respectively. The higher height of dam has, the more
remarkable effect it has on MRT. The affecting extent made
by the 50-mm dam is almost twice of that made by the 30-
mm dam. The reasons for above conclusions lie in two
aspects. First, the usage of exit dam reduces the slope of the
solid bed and then the axial cascading velocity of particles.
On the other hand, it causes the increment of bed depth in
kiln. This increment of flow area in cross-section will
decrease axial cascading velocity, either. Finally, the combi-
nation of two reasons above cause the remarkable increase
of MRT. In addition, MVF decreases when employing exit-
end dam. As for the 30-mm dam, the reduction of MVF of
MSW and sand are 34.5% and 27.9%, respectively, and for
the 50-mm dam, the corresponding reduction is 58.3% and
35.2% (shown in Fig. 12). It is doubtless that the usage of
exit dam is an effective method to control the MRT and
MVF of solids. However, it is noted that exit dam has no
such apparent impacts on relative variance rr as it has on
MRT, as seen from Table 3.
Fig. 7. Comparison of MRT between MSW and sand.
Fig. 8. Comparison of MVF between MSW and sand.
Fig. 9. Effect of rotational speed on MSW transport behavior.
Fig. 10. Effect of kiln slope angle on MSW transport behavior.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227 223
3.6. Influences of the internal structures
The internal structures inevitably affect the axial trans-
port of solids [13,14]. The impacts of internal structures on
MRT are different with various groups consisting of a
certain number of axial ribs or circular ribs. Figs. 13 and
14 illustrate the influences of four groups of internal
structures (listed in Table 2) on the MRT of MSW and sand,
respectively. It is found that all these four kind of internal
structures seriously increase MRT of solids. The detailed
conclusions are drawn: as the number of circular ribs in an
internal structure group increases (12b-4n! 12b-7n), the
MRT in 12b-7n case is slightly longer than that in 12b-4n
case for both MSW and sand; as the height of circular ribs
increases from 30 to 50 mm (12b-4n! 12b-4b), the incre-
ment of MRT from 12b-4n to 12b-4b case is more remark-
able. However, with the increasing height of axial ribs from
10 to 20 mm (12n-4n! 12b-4n), the MRT changing ten-
dency of MSW and sand is inconsistent or inexplicit.
According to above, it is concluded that influences of the
internal structure group on MRT are dependent on the height
of circular ribs, while the impacts of the height of axial ribs
is inexplicit. The influence of circular ribs on MRT can be
explained by their similarity to the exit dam whose influence
has been already tested to be remarkable. The impact of
axial ribs on MRT is quite complicated, which not only
changes the solid’s dynamic angle of repose, but also kicks
up some particles from the bed surface to the freeboard
space. These conclusions can be verified by the experi-
ments. For instance, the 30-mm exit dam promotes MRT
with 78.0%; however, the internal structure groups labeled
12b-4n, 12b-7n and 12n-4n, whose circular ribs is also 30-
mm height, only promote the MRT in range of 75% to 108%
with MSW under an condition of rotating speed at 4 rpm
and inclination at 2.40j (Fig. 14).
Since the exit dam (regarded as one special circular rib)
does not exert the same apparent effects on rr as it does
on MRT, here, the great promotion by one-order of magni-
Fig. 11. Effect of exit end dam on MRT.
Fig. 12. Effect of exit end dam on MVF.
Fig. 13. Effect of various internal structures on MRT of MSW.
Fig. 14. Effect of various internal structures on MRT of sand.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227224
tude of rr may be attributed to the presence of axial ribs
(Table 3).
3.7. The influences of inside wall roughness
The inside wall’s roughness, designated by the wall
friction factors of solids ( f), has significant effects on axial
transport. Fig. 15 presents the variation of MRT with
the various f. When the inside wall is smooth with f at
0.480, MRT is rather short. When f increases to 1.003
(viz. the finer emery cloth is set on inside wall), MRT
increases significantly. However, with further increase of f
from 1.003 to 1.251 (the coarser emery cloth setting), the
increment of MRT is not apparent. It can be explained that
the variation of f greatly changes the bulk characteristics
(in terms of variation of hd) and further changes the bed
regimes of solids. As observed, the solid bed in a case of
smooth wall may perform at a slumping regime, in which the
solids cascade as periodic ‘avalanche’ through the kiln
and have a short MRT. When f increases to 1.003, hdincreases from 48.5j to 58j and the rolling regime is well
formed. The variation of both hd and bed regimes greatly
increases MRT. When f continues to increase to 1.251, hdslowly increases up to about 59.5j, the rolling regime also
dominates the bed behavior (that is, the advanced cataract-
ing regime is not yet formed). Thus, the variation of MRT
is small. In addition, the impact of f on MVF of MSW is
shown in Fig. 16. MVF decreases gradually with the
increasing f, and its changing tendency is contrary to that
of MRT.
3.8. The relationship between MRT and MVF
As discussed above, when one of the variables, such as
rotational speed, kiln slope, dynamic angle of repose and
internal-structures, changes, the variation of MRT has the
reverse tendency with that of MVF. It is apparent that the
product of MRT and MVF is just the holdup of solids in
kiln, which is expressed as Holdup =MRT�MVF. Fig. 17
shows the product of MRT and MVF (i.e. holdup) under
different run, in which the values of MRT and MVF are
obtained from Table 3. In a case of smooth wall with open
exit end, in spite of the changing of rotational speed or kiln
slope, the product of MRT and MVF keeps around 19.7 l,
which implies that the overall fill ratio of solids to kiln
vessel is a constant at 15%. As far as the internal-structures,
such as 12b-4n, 12b-7n and 12n-4n are considered, it holds
around 25 l (that’s, overall fill of solids reaches about
18f 19%). The employment of 12b-4n, 12b-7n or 12n-4n
not only similarly enlarges the exit-end bed depth from 0 to
30 mm (while the bed depth at kiln inlet holds 70 mm), but
also expands the bulk characteristics of solids along all kiln
length. Thus, the holdup increases from 19.7 to 25.3 l.
Finally it is drawn that the overall fill ration or holdup of
solids within kiln is just relevant to the inlet bed depth, exit
bed depth and usage of internal structures, but independent
of some operational parameters such as rotational speed or
kiln slope. This conclusion is much meaningful to the scale-
up or design rotary kiln reactor.
Fig. 17. Relationship between MRT and MVF.Fig. 15. Effect of inside wall roughness on MRT of MSW.
Fig. 16. Effect of inside wall roughness on MVF of MSW.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227 225
4. Conclusion
(1) The reconstituted MSW consists of 49.9 wt.% wood
chips, 17.0 wt.% paper plates and 33.1 wt.% waste tyres.
The dynamic angle of repose (hd) reflects the bulk character-istics of solids in kiln. hd of MSW is 48.5j and hd of the
contrastive sand is about 29.3j. The value of hd increases
with the enhancement of wall roughness, but is independent
of the drum rotation speed.
(2) The distribution of residence time of MSW arises
from the axial segregation of different components, but not
the axial collisions. It results in a relatively large discrep-
ancy of experimental RTD with ideal normal distribution.
The variance (r or rr) of MSW is greater than that of sand.
It is noted that the known phenomenon of alternate band
formation does not occur in such a continuous system.
(3) The axial cascading velocity of particles increases
along the axial direction due to the decrement of the bed
depth or the fill area along the kiln axis. Thus, it is essential
to know the detailed residence time of the solids in each
divided zone besides that of the whole kiln, which implies
incoming research intensive.
(4) The difference of the MRT/MVF between the hetero-
geneous MSW and regular sand is related to their dynamic
angles of repose. MRT is approximately a proportion
function of sin hd, while MVF is an inverse proportion
function of sin hd.(5) Increasing either rotating speed or kiln slope results in
the decreasing MRT and increasing MVF. These variables
are both considered as flexible parameters to adjust the kiln
peformance in the practice. The r of RTD shows the same
fashion as MRT with various rotating speed or kiln slope,
while rr keeps in a narrow range from 0.02 to 0.05.
(6) The exit dam has remarkable impact onMRTof solids;
thus, it can also be used as an adjusting tool of the kiln. Impact
of internal structures, which are composed of axial ribs and
circular ribs, on MRT mainly depends on height of circular
ribs. However, exit dam (or circular ribs) does not exert the
same apparent impact on rr as it does on MRT. It is implied
that the axial ribs will have great effect on rr.
(7) The effect of roughness of inside wall on MRT and
MVF can be explained by that the variation of f between the
wall and the solids directly changes the bulk characteristics
of the solids in kiln and further changes the motion regime
of the bed.
(8) For a case with given inlet and exit bed depths, the
holdup in terms of the product of MRT and MVF holds at a
constant within the limits of experimental errors. The
presence of internal structures increases the holdup of
solids.
Acknowledgements
This research was supported mainly by Nation Natural
Science Funds of China (No. 50076037) and partially by
Zhejiang provincial National Science Funds of China (No.
RC99041). We are grateful to Dr. A. -M. Li for helpful
discussion about rotary kiln transport processes. The
contribution of Dr. J. T. Huang and Z. X. Zhang to this
work is gratefully acknowledged.
References
[1] S.J. Porter, The design of rotary driers and coolers, Trans. Inst. Chem.
41 (1963) 272–280.
[2] A.P. Watkinson, J.K. Brimacombe, Limestone calcination in rotary
kiln, Metall. Trans. B 13B (1982) 369–378.
[3] A. Chatterjee, A.V. Sathe, M.P. Srivastava, P.K. Mukhopadhyay, Flow
of materials in rotary kilns used for sponge iron manufacture: Part I.
Effect of some operational variables, Metall. Trans. B 14B (1983)
375–381.
[4] E. Henrich, S. Burkle, Z.I. Meza-Renken, S. Rumpel, Combustion and
gasification kinetics of pyrolysis chars from waste and biomass, J.
Anal. Appl. Pyrolysis 49 (1999) 221–241.
[5] W.-C. Yang, Dynamics of simulated municipal solid waste in a rotat-
ing device, Powder Technol. 72 (1992) 139–147.
[6] A.M. Li, X.D. Li, S.Q. Li, Pyrolysis of solid waste in a rotary kiln:
influence of final pyrolysis temperature on pyrolysis products, J. Anal.
Appl. Pyrolysis 50 (1999) 149–162.
[7] A.M. Li, X.D. Li, S.Q. Li, Experimental studies on municipal solid
waste pyrolysis in a laboratory-scale rotary kiln, Energy 24 (1999)
209–218.
[8] W.D. Schaefer, Disposing of solid wastes by pyrolysis, Environ. Sci.
Technol. 9 (1975) 98–99.
[9] P.W. Dufton, The Value and Use of Scrap Tyre, Rapra Technology,
England, 1987.
[10] J.D. Sullivan, C.G. Maier, O.C. Ralson, Passage of solid particles
through rotary cylindrical kilns, U. S. Bur. Mines Tech. Pap. 384
(1927).
[11] L. Vahl, W.G. Kingma, Transport of solids through horizontal rotary
cylinders, Chem. Eng. Sci. 1 (1952) 253–258.
[12] H. Kramers, P. Croockewit, The passage of granular solids through
inclined rotary kilns, Chem. Eng. Sci. 1 (1952) 259–265.
[13] A. Chatterjee, A.V. Sathe, M.P. Srivastava, Flow of materials in rotary
kilns used for sponge iron manufacture: Part III. Effect of ring for-
mation within the kiln, Metall. Trans. B 14B (1983) 393–399.
[14] A.J. Matchett, M.S. Sheikh, An improved model of particle motion in
cascading rotary dreyers, Chem. Eng. Res. Des. 68 (1990) 139–148.
[15] R. Rutgers, Longitudinal mixing of granular material flowing through
a rotary cylinder: Part I. Descriptive and theoretical, Chem. Eng. Sci.
20 (1965) 1079–1087.
[16] A.Z.M. Abouzeid, D.W. Fuerstenau, A study of the hold-up in rotary
drums with discharge end constrictions, Powder Technol. 25 (1980)
21–29.
[17] P.S.T. Sai, G.D. Surender, A.D. Damodaran, V. Suresh, Z.G. Philip, K.
Sankaran, Residence time distribution and material flow studies in a
rotary kiln, Metall. Trans. B 21B (1990) 1005–1011.
[18] G.W.J. Wes, A.A.H. Drinkenburg, S. Stemerding, Solids mixing and
residence time distribution in a horizontal rotary drum reactor, Powder
Technol. 13 (1976) 177–184.
[19] G. Groen, J. Ferment, M.J. Grorneveld, J. Decleer, A. Delva, Scaling
down of the calcination process for industrial catalyst manufacturing,
Proc. Int. Symp. Sci. Basis for the Preparation of Heterogeneous
Catalysts, Elsevier, Amsterdam, 1986.
[20] F.R. Schofield, P.G. Glikin, Rotary dryers and coolers for granular
fertilizers, Trans. Inst. Chem. Eng. 40 (1962) 183–190.
[21] C. Wightman, F.J. Muzzio, Mixing of granular material in a drum
undergoing rotating and rocking motions part II segregating particles,
Powder Technol. 98 (1998) 125–134.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227226
[22] M.B. Donald, B. Rosseman, Mixing and de-mixing of solid particles
part III industrial aspects of mixing and de-mixing, Br. Chem. Eng. 7
(1962) 922–924.
[23] S.D. Gupta, D.V. Khakhar, S.K. Bhatia, Axial segregation of particles
in a horizontal rotating cylinder, Chem. Eng. Sci. 46 (1991) 1517.
[24] M. Nakagawa, S.A. Altobelli, A. Caprihan, E. Fukushima, NMRI
study: axial segregation of radially segregated core of granular mix-
tures in a horizontal rotating cylinder, Chem. Eng. Sci. 52 (1997)
4423–4428.
[25] A.A. Boateng, P.V. Barr, Modelling of particle mixing and segregation
in the transverse plane of rotary kiln, Chem. Eng. Sci. 51 (1996)
4167–4181.
[26] J. Bridgewater, W.S. Foo, D.J. Stephens, Particle mixing and segre-
gation in failure zone—theory and experiments, Powder Technol. 41
(1985) 147–158.
[27] H. Henein, J.K. Brimacombe, A.P. Watkinson, Experimental study of
transverse bed motion in rotary kilns, Metall. Trans. B 14B (1983)
191–204.
[28] E. Lebas, F. Hanrot, D. Ablitzer, J.L. Houzelot, Experimental study of
residence time, particle movement and bed depth profile in rotary
kilns, J. Can. Chem. Eng. 73 (1995) 173–179.
[29] J. Perron, R.T. Bui, Rotary cylinder: solid transport predicted by
dimensional and rheological analysis, J. Can. Chem. Eng. 68 (1990)
61–68.
[30] R. Rogers, A Monte Carlo method for simulating dispersion and trans-
port through horizontal rotating cylinder, Powder Technol. 23 (1979)
159–167.
[31] G.R. Woodle, J.M. Munro, Particle motion and mixing in a rotary kiln,
Powder Technol. 76 (1993) 241–245.
S.-Q. Li et al. / Powder Technology 126 (2002) 217–227 227