20
Band formation

Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Embed Size (px)

Citation preview

Page 1: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Band formation

Page 2: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne2/m*

Semiconductors

Metal Insulator Semiconductor

Page 3: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

GaAs, AlAs, InAs, InP, GaP, AlP, InN, GaN, AlN, InSb, GaSb, AlSb and ternaries and quaternaries. AxB1-xCyD1-y

IV, III-V, II-VI Semiconductors

Page 4: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator
Page 5: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Rede do diamante

Rede cristalina do diamante, do silício e do germânio

C, Si ou Ge

Rede cúbica de face centrada

Usados para eletrônica...

Duas redes transladadas de¼ da diagonal central

Cada átomo está ligado a 4 outros

Page 6: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Tabela periódica dos elementos

IVIII V

Page 7: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Rede Zincblend

Rede cristalina do GaAs, InP, AlGaAs, InAlAs...

Ga, In, Al

As, P

... e na opto-eletrônica

Page 8: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Si Si

Si Si

Si

SiSiSi

Si

Si

Si

Si

Si

Si

Si

Elétrons ligados(BV)

Qual a energia necessária para liberar estes elétrons?

Page 9: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Si Si

Si Si

Si

SiSiSi

Si

Si

Si

Si

Si

Si

Si

Elétrons livre(BC)

Falta de 1 elétron“buraco”

Page 10: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

E= hc/E= 1240 / (eV/nm)E= 1,24 / (eV/m)

Page 11: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

GaAs

AlAsInP InAs

InxGa1-xAsGaxAl1-xAs

GaP

InxGa1-xP InxAl1-xAs

Page 12: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

SemicondutoresEn

ergi

a do

elé

tron

BC

BV

Eg

Ener

gia

do e

létr

on

BC

BV

Eg

Eg pequeno

Posição Posição

Facilidade para elétrons saírem da BV para a BC

Temperatura e luzProbabilidade: exp(-Eg/kT)

Page 13: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

(.m) d/dT

Silício 3 x 103 -70 x 10-3

Cobre 2 x 10-8 4 x 10-3

Mecanismos de condução diferentes

+

- T

T

Aumento no número de portadores de carga

O aumento das vibrações cristalinas dificulta a passagem do elétron = m/ne2

Page 14: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Nível de Fermi

f(E) = 1/(1 + exp((E-EF)/kT))

EnergiaEF

1

f(E)

T = 0K

T ≠ 0K

BV

BC

EF

Material intrínseco

Page 15: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Dopagem p e n• Dopagem n se introduz um elemento com 1 elétron a mais

que o átomo a ser substituído.Exemplos: P no lugar de Si, Si no lugar de Ga, S no lugar de

As. As impurezas passam a se denominadas doadoras. Haverá um excesso de elétrons para condução.

• Dopagem p se introduz um elemento com 1 elétron a menos que o átomo a ser substituído.

Exemplos: B no lugar de Si, Si no lugar de As, Zn no lugar de Ga. As impurezas passam a se denominadas aceitadoras. Haverá um excesso de buracos para condução.

Page 16: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Dopagem p e n

IVIII V Em relação ao Si:

mais um elétron (grupo V) – tipo n

Si – Ne + 3s2 3p2

As: Ar + 3s2 3p3

B: He + 3s2 3p1

menos um elétron (grupo III) – tipo p

Page 17: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

As Si

Si Si

Si

SiSiSi

Si

Si

Si

Si

Si

Si

Si

“Sobra” 1 elétron

Qual a energia necessária para liberar este elétron?

Impureza doadora

Page 18: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Material tipo nEn

ergi

a do

elé

tron

BC

BV

Posição

Ed

Ener

gia

do e

létr

on

BC

BV

Posição

Ed

Do + Ed = D+ + e-

+

Page 19: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

B Si

Si Si

Si

SiSiSi

Si

Si

Si

Si

Si

Si

Si

“Falta” 1 elétron

Qual a energia necessária para liberar este elétron?

Impureza aceitadora

Page 20: Band formation. Semiconductors are insulators at 0 K and as the temperature rises their conductivity increases. = ne 2/m* Semiconductors Metal Insulator

Material tipo pEn

ergi

a do

elé

tron

BC

BV

Posição

Ea

Ener

gia

do e

létr

on

BC

BV

Posição

Ao + Ea = A- + h+

Ea

-