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Synthetic Oil
Fadilwan-Product DevelopmentPELUMAS PERTAMINA
Page 2
Pelumas Synthetic
Pelumas Synthetic = Base Oil Synthetic + Additive
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All polyphaolefins(PAOs)
Group IV
All Other not include in Group I,II,III or IV
Group V
> 120> 90< 0.03 andGroup III
80 to 120> 90< 0.03 andGroup II
80 to 120< 90> 0.03 and/orGroup I
ViscosityIndex
Saturates(%)
Sulfur(%)
Base OilCatagory
API Base oil Category
Note ;In 1999 , the US National Advertising Divison of Council of Better BussinessBureaus ruled that Group III base oil can be referred to as “SYNTHETIC”
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Karakteristik Base Oil Group 3 vs GrI /Gr II
Properties ASTM Method
Dubase 4 Dubase 6 Yubase 6 Group 1 HVI 95
Group 1 HVI 60
Group 2 VCBS 95
Colour ASTM D1500 L0.5 L0.5 L0.5 L 1.0 L0.5 L1.0 Viscosity kinematics, cSt
o @ 40 oC o @100 oC
D445 17.80 4.09
35.24 6.60
35.70 6.39
51.42 7.20
24.5 4.59
32.75 5.74
Viscosity index D2270 135 145 131 98 101 117 Noack volatility, %loss D5800 15.9 7.3 8.5 12.0 16 12.8 CCS @ -30 oC, cP D5293 1200 3500 4000 - - - Pour point, D5950 -21 -15 -15 -9 -12 -12 Sulfur content, ppm D4294 4 5 14 650 6650 918 Base oil characteristic:
o Saturated, %wt o Aromatic, %wt o Polar, %wt
D2007
99.22 0.66 0.04
98.93 1.04 0.19
98.59 0.91 0.16
72.10 27.10 0.5
75.8 23.9 0.3
93.37 6.07 0.1
Nitrogen Content D3228 26 23 - 11 37 18
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ASTM DefinitionA synthetic lubricant is a product which consists of stocksmanufatured by chemical synthesis and containing necessaryperformance additivesASTM Classification Synthetic Base Fluids
1. Synthetic Hydrocarbon• Alkylated Aromatics • Olefin Oligomers (PAO) : more widely used• Cycloaliphatics
2. Organic Esters• Dibasic Acid Esters• Polyol Esters
3. Others• Halogenated Hydrocarbons• Phosphate Esters• Polyglycol Ethers• Polyphenyl Ethers• Silicate Esters• Silicones
• Blends• Mixtures of the above
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World wide market
• Polyglycol : 38%• Synthesized Hydrocarbon : 33%• Organic Esters : 22%• Phosphate Ester : 5%
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PELUMAS SYNTHETIC
Wide Operating
Temp
LowerPour Point
HigherFlash Point
Better Lubricity
Higher Visc.Index
Thermal Stability
Oxidation Stability
FireResistance
Advantage
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PELUMAS SYNTHETIC
Mix Ability
Seal Compatability
HydrolyticStability
Toxicity
High Cost
Disadvantage
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Mengapa memakai Synthetic Oil?
EnergyTemperature
Wear
Problem SolverProblem Solver
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Friction Forces
Synthetic Oil have low Coef. Friction
Benefit : Fuel Economy and Energy Saving
Higher Friction Forces
Synthetic Oil
Mineral Oil
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Synthetic Oil have High Film Strength
Synthetic Oil
Mineral Oil
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40 oC60 oC80 oC100 oC
Dubase based oil sample shows thicker oil film at low rolling speeds under all temperature
21nm
24.6nm
EHD oil film thickness in 5W-40 PCDO
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Temperature Operating Range
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Summary of Synthetic Base Stock Properties
Solvency & VIFire ResistancePhospate Ester
Compatability & hygroscopic ability
Water versality & low hydrocarbon solubility, No deposit formation & High VI
PAG
Seal and Paint compatability
Solvency and Detergency
Diester
Volatility, Lubricity and oxidation
Low Temperature Properties
Alkylated Aromatic
Additive solubilityBlend with ester
Wide temperature operating range
PAO
WeaknessStrengthsBase Stock
Page 19
Pelumas Synthetic produk PERTAMINA
• Engine Oil : – FASTRON Fully Synthetic 0W-50 – (PAO Base Oil)– FASTRON Synthetic series– FASTRON DIESEL 15W-40
• Synthetic Compressor Oil :– GC Lube Syn series (Diester base oil)
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