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Benzene Version 5. Effective Date 21.02.2011 Safety Data Sheet Regulation 1907/2006/EC 1/15 Print Date 23.02.2011 MSDS_GB 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Material Name : Benzene Product Code : Q9112, Q9169 REACH Registration No. : 01-2119447106-44-0023, 01-2119447106-44-0019, 01-2119447106-44-0022, 01-2119447106-44-0020, 01-2119447106-44-0021 1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : Raw material for use in the chemical industry. The substance/product is registered with strictly controlled conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such. 1.3 Details of the supplier of the substance or mixture Manufacturer/Supplier : SHELL TRADING INTERNATIONAL LIMITED 80 Strand London WC2R 0ZA United Kingdom Telephone : +44 (0)20 7546 5000 Email contact for MSDS : [email protected] 1.4 Emergency Telephone Number : +44 (0) 151 350 4595 2. HAZARDS IDENTIFICATION 2.1 Classification of substance or mixture Regulation (EC) No 1272/2008 (CLP) Hazard Class & Category Hazard statement

BENZENE: Shell MSDS (2011)

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  • Benzene Version 5.

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    1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier

    Material Name : Benzene Product Code : Q9112, Q9169 REACH Registration No. : 01-2119447106-44-0023, 01-2119447106-44-0019,

    01-2119447106-44-0022, 01-2119447106-44-0020, 01-2119447106-44-0021

    1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : Raw material for use in the chemical industry. The substance/product is registered with strictly controlled

    conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such.

    1.3 Details of the supplier of the substance or mixture Manufacturer/Supplier : SHELL TRADING INTERNATIONAL LIMITED

    80 Strand London WC2R 0ZA United Kingdom

    Telephone : +44 (0)20 7546 5000

    Email contact for MSDS

    : [email protected]

    1.4 Emergency Telephone Number : +44 (0) 151 350 4595

    2. HAZARDS IDENTIFICATION

    2.1 Classification of substance or mixture

    Regulation (EC) No 1272/2008 (CLP)

    Hazard Class & Category Hazard statement

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    Flammable liquids, Category 2 H225

    Harmful in contact with skin., Category 2 H315

    Causes serious eye damage., Category 2 H319

    ASPIRATION HAZARD, Category 1 H304

    Germ Cell Mutagenicity, Category 1B H340

    CARCINOGENICITY, Category 1A H350

    Specific target organ toxicity - repeated exposure, Category 1; Blood.; Blood-forming organs.

    H372

    67/548/EEC or 1999/45/EC

    Hazard characteristics

    R-phrase(s)

    Highly flammable. Toxic. R45, R46, R11, R36/38, R48/23/24/25, R65

    2.2 Label Elements Label Name : BENZENE EC Number : 200-753-7 EC Annex I Number : 601-020-00-8 Labeling according to Regulation (EC) No 1272/2008 Symbol(s) :

    Signal Words : Danger CLP Hazard statements : PHYSICAL HAZARDS:

    H225: Highly flammable liquid and vapor. HEALTH HAZARDS: H315: Causes skin irritation. H319: Causes serious eye irritation. H340: May cause genetic defects. H350: May cause cancer. H372: Causes damage to organs through prolonged or repeated exposure. H304: May be fatal if swallowed and enters airways. ENVIRONMENTAL HAZARDS: Not classified as environmental hazard according to CLP criteria.

    CLP Precautionary statements

    Prevention : P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P243: Take precautionary measures against static discharge.

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    P280: Wear protective gloves/protective clothing/eye protection/face protection. P202: Do not handle until all safety precautions have been read and understood.

    Response : P303+P361+P353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P301+P310: IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. P331: Do NOT induce vomiting.

    Labeling according to Directive 1999/45/EC EC Symbols : F Highly flammable.

    T Toxic.

    EC Classification : Highly flammable. Toxic. Carcinogenic, category 1. Mutagenic, category 2.

    EC Risk Phrases : R45 May cause cancer. R46 May cause heritable genetic damage. R11 Highly flammable. R36/38 Irritating to eyes and skin. R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. R65 Harmful: May cause lung damage if swallowed.

    EC Safety Phrases : S53 Avoid exposure - obtain special instructions before use. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

    2.3 Other Hazards Health Hazards : Toxic: danger of serious damage to health by prolonged

    exposure through inhalation, in contact with skin and if swallowed. Slightly irritating to respiratory system. Vapours may cause drowsiness and dizziness. Irritating to skin. Irritating to eyes. Harmful: may cause lung damage if swallowed. Possibility of organ or organ system damage from prolonged exposure; see Chapter 11 for details. Target organ(s): Blood. Blood-forming organs. Immune system. May cause heritable genetic damage. May cause cancer. May cause leukaemia (AML - acute myelogenous leukaemia).

    Aggravated Medical Condition

    : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this

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    material: Blood. Blood-forming organs. Eyes. Skin. Cardiovascular system. Immune system.

    Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Eyes. Immune system. Circulatory System (including heart) Blood-forming organs. Blood.

    Safety Hazards : Highly flammable. In use, may form flammable/explosive vapour-air mixture. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire.

    Environmental Hazards : Not classified as dangerous under EC criteria. Other Information : The substance/product is registered with strictly controlled

    conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such. Refer to the industry guidance prepared by Concawe/Cefic for advice on the demonstration of strictly controlled conditions available from : http://cefic.org/Industry-support/Implementing-reach/Documents-and-Tools1/.

    3. COMPOSITION/INFORMATION ON INGREDIENTS

    3.1 Substance Material Formal Name : Benzene CAS No. : 71-43-2 INDEX No. : 601-020-00-8 EC Number : 200-753-7 3.2 Mixtures Hazardous Components Classification of components according to Regulation (EC) No 1272/2008

    Chemical Name CAS No. EINECS REACH Registration No.

    Conc.

    Benzene 71-43-2 200-753-7 01-2119447106-44 100.00%

    Chemical Name Hazard Class & Category Hazard statement

    Benzene Flam. Liq., 2; Carc., 1A; Muta., 1B; STOT RE, 1; Asp. Tox., 1; H319, 2; Skin

    Irrit., 2;

    H225, H350, H340, H372, H304, H319, H315,

    Classification of components according to 67/548/EEC

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    Chemical Name CAS EINECS REACH Registration

    No.

    Symbol(s) R-phrase(s)

    Conc.

    Benzene 71-43-2 200-753-7 01-2119447106-44

    F, T R45; R46; R11; R36/38; R48/23/24/25; R65

    100.00 %

    4. FIRST AID MEASURES

    4.1 Description of first aid measures

    General Information : Keep victim calm. Obtain medical treatment immediately. Inhalation : DO NOT DELAY. Remove to fresh air. If rapid recovery does not

    occur, transport to nearest medical facility for additional treatment.

    Skin Contact : Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.

    Eye Contact : Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the nearest medical facility for additional treatment.

    Ingestion : If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101 F (38,3 C), shortness of breath, chest congestion or continued coughing or wheezing. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Give nothing by mouth. Do NOT induce vomiting.

    4.2 Most important symptoms/effects, acute & delayed

    : Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision. Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory symptoms may be delayed for several hours after exposure. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting in dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Damage to blood-forming organs may be evidenced by: a) fatigue and anaemia (RBC), b) decreased resistance to infection, and/or excessive bruising and bleeding (platelet effect).

    4.3 Indication of immediate medical attention and special

    : Potential for chemical pneumonitis. Potential for cardiac sensitisation, particularly in abuse situations. Hypoxia or negative inotropes may enhance these effects. Consider:

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    treatment needed oxygen therapy. Call a doctor or poison control center for guidance.

    5. FIRE FIGHTING MEASURES

    Clear fire area of all non-emergency personnel. 5.1 Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide,

    sand or earth may be used for small fires only. Unsuitable Extinguishing Media

    : Do not use water in a jet.

    5.2 Special hazards arising from substance or mixture

    : The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will float and can be reignited on surface water. Carbon monoxide may be evolved if incomplete combustion occurs.

    5.3 Advice for fire-fighters : Wear full protective clothing and self-contained breathing apparatus.

    Additional Information : Keep adjacent containers cool by spraying with water.

    6. ACCIDENTAL RELEASE MEASURES

    Observe all relevant local and international regulations. Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. 6.1 Personal Precautions, Protective Equipment and Emergency Procedures

    : Isolate hazard area and deny entry to unnecessary or unprotected personnel. Stay upwind and keep out of low areas.

    6.2 Environmental Precautions

    : Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Use appropriate containment (of product and fire fighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog sprays. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Ventilate contaminated area thoroughly.

    6.3 Methods and Material for Containment and Clean Up

    : For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

    Additional Advice : Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained. The vapour is heavier than air, spreads along the ground and distant

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    ignition is possible. Vapour may form an explosive mixture with air.

    7. HANDLING AND STORAGE

    General Precautions : Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. On guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material.

    7.1 Precautions for Safe Handling

    : Avoid inhaling vapour and/or mists. Avoid contact with skin, eyes, and clothing. Avoid exposure. Obtain special instructions before use. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (

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    document, it is provided for information only. 8.1 Control Parameters

    Occupational Exposure Limits UK Workplace Exposure Limits

    Material Source Type ppm mg/m3 Notation

    Benzene EH40 MEL TWA 1 ppm

    ACGIH TWA 0.5 ppm

    ACGIH STEL 2.5 ppm

    ACGIH SKIN_DES Can be absorbed through the skin.

    EH40 WEL TWA 1 ppm

    EH40 WEL SKIN_DES Can be absorbed through the skin.

    EU OELIII TWA 1 ppm 3.25 mg/m3

    EU OELIII SKIN_DES Can be absorbed through the skin.

    SHELL IS TWA (8 h) 0.5 ppm 1.6 mg/m3

    SHELL IS STEL 2.5 ppm 8 mg/m3

    Additional Information : SHELL IS is the Shell Internal Standard.

    Material Source Hazard Designation

    Benzene EU CARC. Carcinogen/Mutagen

    Predicted No Effect Concentration (PNEC)

    Component Exposure Route Value Remark

    8.2 Exposure Controls

    General Information

    : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate ventilation to control airborne concentrations below the exposure guidelines/limits. Adequate explosion-proof ventilation to control airborne concentrations. Firewater monitors and deluge systems are recommended. Eye washes and showers for emergency use.

    Occupational Exposure Controls Personal Protective Equipment

    : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers.

    Eye Protection : Chemical splash goggles (chemical monogoggles). Approved to EU Standard EN166, AS/NZS:1337.

    Hand Protection : Where hand contact with the product may occur the use of

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    gloves approved to relevant standards (e.g. Europe: EN374, US: F739, AS/NZS:2161) made from the following materials may provide suitable chemical protection: Longer term protection: Viton. Incidental contact/Splash protection: Nitrile rubber. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.

    Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

    Body protection : Chemical resistant gloves/gauntlets, boots, and apron. Where risk of splashing or in spillage clean up, use chemical resistant one-piece overall with integral hood.

    Respiratory Protection : If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for organic gases and vapours [boiling point >65 C (149 F)] meeting EN14387. Where respiratory protective equipment is required, use a full-face mask. Where air-filtering respirators are unsuitable (e.g., airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus.

    Thermal hazards : Not applicable Monitoring Methods : Monitoring of the concentration of substances in the breathing

    zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Examples of sources of recommended air monitoring methods are given below or contact supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods, http://www.cdc.gov/niosh/nmam/nmammenu.html. Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods, http://www.osha-slc.gov/dts/sltc/methods/toc.html. Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances, http://www.hsl.gov.uk/publications/mdhs.aspx. Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA), Germany http://www.hvbg.de/d/bia/index.html. L'Institut National de Recherche et de Securit, (INRS), France http://www.inrs.fr/securite/hygiene_securite_travail.html.

    Environmental Exposure Controls Environmental exposure : Local guidelines on emission limits for volatile substances must

    be observed for the discharge of exhaust air containing vapour.

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    control measures

    9. PHYSICAL AND CHEMICAL PROPERTIES

    9.1 Information on basic physical and chemical properties

    Appearance : Colourless. Liquid. Odour : Aromatic. Odour threshold : 2.7 ppm Boiling point : 80.1 C / 176.2 F Freezing Point : 5.5 C / 41.9 F Flash point : -11 C / 12 F (Abel) Explosion / Flammability limits in air

    : 1.4 - 7.1 %(V)

    Auto-ignition temperature : 498 C / 928 F Vapour pressure : 10 hPa at 20 C / 68 F Specific gravity : 0.8787 at 20 C / 68 F

    Density : 883 kg/m3 at 15 C / 59 F Water solubility : 1.8 kg/m3 at 25 C / 77 F n-octanol/water partition coefficient (log Pow)

    : 1.95 - 2.13

    Kinematic viscosity : 0.65 mm2/s at 20 C / 68 F Vapour density (air=1) : 2.7 at 15 C / 59 F Electrical conductivity : < 50 pS/m at 20 C / 68 F Evaporation rate (nBuAc=1) : 2.8 Surface tension : 0.03 N/m Molecular weight : 78 g/mol 9.2 Other InformationSaturated Vapour concentration (in air)

    : 320 g/m3 at 20 C / 68 F

    10. STABILITY AND REACTIVITY

    10.1 Reactivity

    : Stable under normal conditions of use.

    10.2 Stability : Stable under normal conditions of use. 10.3 Possibility of Hazardous Reactions

    : Stable under normal conditions of use.

    10.4 Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources. Prevent vapour accumulation.

    10.5 Materials to Avoid : Strong oxidising agents. 10.6 Hazardous Decomposition Products

    : Thermal decomposition is highly dependent on conditions. A complex mixture of airborne solids, liquids and gases, including carbon monoxide, carbon dioxide and other organic compounds will be evolved when this material undergoes combustion or thermal or oxidative degradation.

    Other Information

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    Hazardous Polymerisation

    : No, hazardous, exothermical polymerization cannot occur.

    Sensitivity to Mechanical Impact

    : No, product will not become self-reactive.

    Sensitivity to Static Discharge

    : Yes, in certain circumstances product can ignite due to static electricity.

    11. TOXICOLOGICAL INFORMATION

    11.1 Information on Toxicological effects Basis for Assessment : Information given is based on product testing. Routes of Exposure : Exposure may occur via inhalation, ingestion, skin absorption,

    skin or eye contact, and accidental ingestion. Acute Oral Toxicity : Aspiration into the lungs when swallowed or vomited may cause

    chemical pneumonitis which can be fatal. Low toxicity: LD50 >5000 mg/kg , Rat Acute Dermal Toxicity : Low toxicity: LD50 >5000 mg/kg , Rabbit Acute Inhalation Toxicity : Expected to be of low toxicity if inhaled. High concentrations may cause central nervous system

    depression resulting in headaches, dizziness and nausea; continued inhalation may result in unconsciousness and/or death.

    Skin Irritation : Causes skin irritation. Eye Irritation : Causes serious eye irritation. Sensitisation : Not expected to be a sensitiser. Aspiration hazard : Aspiration into the lungs when swallowed or vomited may cause

    chemical pneumonitis which can be fatal. Mutagenicity : May cause heritable genetic damage. Carcinogenicity : Known human carcinogen. May cause leukaemia (AML - acute myelogenous leukaemia). Reproductive and Developmental Toxicity

    : Does not impair fertility. Not a developmental toxicant.

    Causes foetotoxicity in animals at doses which are maternally toxic.

    Specific target organ toxicity - single exposure

    : Inhalation of vapours or mists may cause irritation to the respiratory system.

    Specific target organ toxicity - repeated exposure

    : Causes damage to organs through prolonged or repeated exposure.

    Blood-forming organs: repeated exposure affects the bone marrow.

    Blood: may cause haemolysis of red blood cells and/or anaemia.

    Immune System: animal studies on this material or its components have demonstrated immunotoxicity.

    Additional Information : Myelodysplastic syndrome (MDS) was observed in individuals exposed to very high levels (50 ppm to 300 ppm range) of benzene over a long period of time in the workplace. The relevance of these results to lower levels of exposure is not known.

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    Exposure to very high concentrations of similar materials has been associated with irregular heart rhythms and cardiac arrest.

    12. ECOLOGICAL INFORMATION

    12.1 Toxicity Acute Toxicity

    Fish : Toxic: LL/EL/IL50 1-10 mg/l Aquatic Invertebrates : Harmful: LL/EL/IL50 10-100 mg/l Algae : Harmful: LL/EL/IL50 10-100 mg/l Microorganisms : Harmful: LL/EL/IL50 10-100 mg/l

    12.2 Persistence and degradability

    : Readily biodegradable.

    12.3 Bioaccumulative Potential

    : Does not bioaccumulate significantly.

    12.4 Mobility : Floats on water. 12.5 Result of the PBT assessment

    : The substance does not fulfill all screening criteria for persistence, bioaccumulation and toxicity and hence is not considered to be PBT or vPvB.

    12.6 Other Adverse Effects

    : In view of the high rate of loss from solution, the product is unlikely to pose a significant hazard to aquatic life.

    13. DISPOSAL CONSIDERATIONS

    13.1 Waste Treatment Methods

    Material Disposal : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations.

    Do not dispose into the environment, in drains or in water courses. Waste product should not be allowed to contaminate soil or water.

    Local Legislation : Disposal should be in accordance with applicable regional, national, and local laws and regulations.

    14. TRANSPORT INFORMATION

    ADR 14.1 UN No. : 1114 14.2 Proper shipping name : BENZENE 14.3 Transport Hazard Class

    : 3

    14.4 Packing group : II Classification code : F1 Hazard indentification no. : 33 Danger label (primary risk) : 3 14.5 Environmentally Hazardous

    : No

    RID

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    14.1 UN No. : 1114 14.2 Proper shipping name : BENZENE 14.3 Transport Hazard Class

    : 3

    14.4 Packing group : II Classification code : F1 Hazard indentification no. : 33 Danger label (primary risk) : 3 14.5 Environmentally Hazardous

    : No

    Sea transport (IMDG Code): 14.1 UN No. : 1114 14.2 Proper shipping name : BENZENE 14.3 Transport Hazard Class

    : 3

    14.4 Packing group : II 14.5 Marine pollutant: : No Air transport (IATA):14.1 UN No. : 1114 14.2 Proper shipping name : Benzene 14.3 Transport Hazard Class

    : 3

    14.4 Packing group : II 14.5 Environmentally Hazardous

    : No

    Sea (Annex II of MARPOL 73/78 and the IBC code)Pollution Category : Y Ship Type : 3 Product Name : Benzene and mixtures having 10% benzene or more. Special Precaution : Refer to Chapter 7, Handling & Storage, for special precautions

    which a user needs to be aware of or needs to comply with in connection with transport.

    15. REGULATORY INFORMATION

    The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

    Other regulatory Information Chemical Inventory StatusAICS : Listed. DSL : Listed.

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    INV (CN) : Listed. ENCS (JP) : Listed. (3)-1 TSCA : Listed. EINECS : Listed. 200-753-7 KECI (KR) : Listed. 97-1-99 KECI (KR) : Listed. KE-02150 PICCS (PH) : Listed. National Legislation OE_HPV : Listed.

    Other Information : Restricted to professional users. 15.2 Chemical Safety Assessment

    : A Chemical Safety Assessment was performed for this substance.

    16. OTHER INFORMATION

    R-phrase(s)

    R11 Highly flammable. R36/38 Irritating to eyes and skin. R45 May cause cancer. R46 May cause heritable genetic damage. R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through

    inhalation, in contact with skin and if swallowed. R65 Harmful: May cause lung damage if swallowed.

    CLP Hazard statements H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure.

    Additional Information : If this substance/product is sold onto third parties, confirmation

    that the substance/product will be handled in accordance with 'strictly controlled conditions' needs to be obtained from the third party prior to sale.

    Other Information Further information : The substance/product is registered with strictly controlled

    conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such. Refer to the industry guidance prepared by Concawe/Cefic for advice on the demonstration of strictly controlled conditions available from : http://cefic.org/Industry-support/Implementing-reach/Documents-and-Tools1/.

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    MSDS Version Number : 5.

    MSDS Effective Date : 21.02.2011

    MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment from

    the previous version. MSDS Regulation : The content and format of this safety data sheet is in accordance

    with Regulation 1907/2006/EC. MSDS Distribution : The information in this document should be made available to all

    who may handle the product Disclaimer : This information is based on our current knowledge and is

    intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.