BIOBROM (DBNPA)...Whether you are a manufacturer, transporter, distributor or end user, we hope that the information contained in this Safety Handbook will prove useful in your handling

PRODUCT DESCRIPTION

Safety HandbookBIOBROM (DBNPA)

Year Edition Remarks Approved by6/2011 16/2016 2 Approved edition R.L

DBNPA SAFETY HANDBOOK 3

CONTENTS

INTRODUCTION ......................................................................................................................5ICL-IP SUSTAINABILITY POLICY ..............................................................................................6GLOSSARY OF COMMONLY USED ABBREVIATIONS ..........................................................8

1. PRODUCT DESCRIPTION

1.1 PRODUCT DESCRIPTION ...................................................................................131.2 IDENTIFICATION .................................................................................................131.3 PHYSICAL PROPERTIES ......................................................................................14

2. PACKAGING

2.1 PLASTIC SACKS ....................................................................................................182.2 PLASTIC PAILS .....................................................................................................192.3 BIG BAGS .............................................................................................................202.4 PLASTIC JERRICANS ............................................................................................212.5 INTERMEDIATE BULK CONTAINER (IBC) .........................................................222.6 L-RING DRUMS....................................................................................................232.7 MARKING AND LABELING..................................................................................24

3. TRANSPORTATION

3.1 PACKAGING AND TRANSPORTATION ..............................................................313.2 DRIVER’S LOADING CHECK LIST ........................................................................363.3 DRIVER’S ROAD REMINDERS .............................................................................38

4 EDITION 2, 2016

4. USER GUIDE

4.1 GENERAL SITE RECOMMENDATIONS ...............................................................414.2 PROCESS SAFETY MANAGEMENT REGULATIONS ...........................................454.3 HAZARDOUS EXPOSURE LIMITS .......................................................................464.4 PROTECTIVE CLOTHING .....................................................................................464.5 RESPIRATORY PROTECTION PROGRAM ...........................................................47

5. EMERGENCY RESPONSE

5.1 FACILITY EMERGENCY ACTION PLANNING .....................................................515.2 TRANSPORT EMERGENCY RESPONSE ..............................................................525.3 HAZARD IDENTIFICATION ..................................................................................535.4 CLASSIFICATION OF THE SUBSTANCE ..............................................................545.6 FIRE FIGHTING ....................................................................................................605.7 SPILLS OR LEAKS.................................................................................................615.8 EMERGENCY REPAIRS ........................................................................................625.9 EXPOSURE TO DBNPA ........................................................................................63

6. OPERATORS GUIDE

6.1 OPERATOR HEALTH MONITORING ..................................................................676.2 OPERATOR/DRIVER SAFETY TRAINING.............................................................69

APPENDIX

A. TYPICAL QUALITY SPECIFICATIONS ...........................................................................73B. REFERENCES .................................................................................................................74


INTRODUCTION

This Safety Handbook has been compiled by ICL Industrial Products (ICL-IP) Ltd. as a part of its continuing commitment to the principles of Product Stewardship, and is intended to provide a guide to the safe handling and use of DBNPA products.

DBNPA is effective in the control of bacteria, algae, slime and fungi in industrial water systems. DBNPA can be safely used by untrained persons following the few basic precautions which are clearly indicated on each receptacle.

Whether you are a manufacturer, transporter, distributor or end user, we hope that the information contained in this Safety Handbook will prove useful in your handling of these products. Information is also provided to assist regulatory and transportation authorities in determining if DBNPA is being handled or transported properly, and to assist medical personnel in case of accident involving this product.

DBNPA is not a substance to be used casually. It is a hazardous chemical which can be used safely if its properties are understood and the necessary safety precautions are observed. Safety is the personal responsibility of everyone working with DBNPA. Managers and supervisors should be well versed in the safe handling practices required and enforce their implementation. Operators should be well trained in the use of safety equipment and safety procedures.

Note: The relevant Safety Data Sheet should be consulted before undertaking any activities involving DBNPA.

The handling of DBNPA is strictly regulated by international agreements and government regulations. As new information is continuously becoming available, anyone handling this substance must keep up-to-date on relevant practices and regulations.

ICL-IP emphasizes the need for safe handling of DBNPA, the integrity of the containers and the prominent display of instructions and warnings.

For further information about DBNPA, please contact your local ICL-IP office. website: www.icl-industrial.com

We also welcome your comments and input on the content and presentation of this Safety Handbook.

6 EDITION 2, 2016

Although the information and recommendations set forth herein (hereinafter “Information”) are presented in good faith and believed to be correct as of the date here-of, ICL Industrial Products makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the person receiving it will make their own determination as to its safety and suitability for their purposes prior to use.

In no event will ICL Industrial Products be responsible for damages of any nature whatsoever resulting from the use or reliance upon the Information.

In the event of a discrepancy between the contents of the safety handbook and the updated SDS, then the SDS will prevail (see ICL-IP website for latest version www.icl-ip.com)

NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.

ICL-IP SUSTAINABILITY POLICY

The managers and employees at ICL-IP are committed to sustaining economic growth without harming our planet or exhausting its resources while improving the quality of life for its current and future inhabitants.

ICL-IP practices Sustainable Development in the knowledge that it makes good business sense and will incorporate sustainability considerations in all operations and business decisions in alignment with a commitment to the global Sustainable Development effort.

This will be achieved by:• Maintaining a balance between economic, environmental and social needs of

present and future generations• Developing a companywide culture of Sustainable Development• Complying with all national and international regulatory requirements including

emergency regulatory requirements in cooperation with local emergency authorities

• Implementation of enforcement and risk management plans


• Adoption of Responsible Care and Product Stewardship principles • Certification of all production facilities to ISO 14001/ OHSAS 18001/ ICL internal

“Green Facility” certification • Transparency and voluntary reporting according to the GRI (Global Reporting

Initiative) model• Focusing R&D on design and development of sustainable products and solutions• Use of best available and economical technologies (BAT) to ensure conformance

to legal requirements and beyond• Minimizing the corporate environmental footprint including ongoing reduction of

greenhouse gas emissions• Commitment to safety by striving for zero accidents and ensuring a good

working environment for employees and contractors• Encouraging downstream users, transporters and suppliers, to adopt good

practices for safe handling of chemicals and to minimize emissions during use and disposal of products and packages

• Promoting programs in support of the community and social involvement• Upholding the principles of human rights both in and outside the workplace • Adoption of a Code of Ethics• Corporate governance according to principles and rules that ensure

accountability, fairness, and transparency in relationships between management, the Board, shareholders and other stakeholders

• Educating and training all managers and employees to be fully aware of the Sustainability Policy and to be committed to its implementation

• Supplying resources needed for implementation of this policy

8 EDITION 2, 2016

GLOSSARY OF COMMONLY USED ABBREVIATIONS

ACC American Chemistry Council (US), formerly Chemical Manufacturers AssociationACEP Approved Continuous Examination Program (CSC)ACGIH American Conference of Governmental Industrial HygienistsADR European Agreement concerning the International Carriage of Dangerous Goods by RoadBPD Biocidal Products Directive (BPD 98/8/EC)CAS Chemical Abstract ServiceCEFIC European Council of Chemical manufacturers FederationsCERCLA Comprehensive Environmental Response, Compensation & Liability Act (US)CFR Code of Federal Regulations (US)CHEMTREC Chemical Transportation Emergency Center (US)COMAH Control of Industrial Major Accident Hazards Regulations (UK)COSHH Control of Substances Hazardous to Health Regulations (UK)CSC International Convention for Safe Containers (IMO)CWA Clean Water Act (US)DBNPA 2,2-dibromo-3-nitrilopropionamideDOT Department of Transportation (US)EmS Emergency Schedule (IMO)EPA Environmental Protection Agency (US)FIFRA Federal Insecticide Fungicide and Rodenticide ActGHS Globally Harmonized SystemHSE Health and Safety Executive (UK)IATA International Air Transport AssociationIDLH Immediately Dangerous to Life and HealthIMDG International Maritime Dangerous Goods codeIMO International Maritime OrganizationISO International Standards OrganizationMAK Maximum Concentration at the Workplace (Germany)MFAG Medical First Aid Guide (IMO)SDS Safety Data SheetNFPA National Fire Protection Association (US)NIOSH National Institute of Occupational Safety & Health (US)NOS Not Otherwise SpecifiedNTP National Toxicology Program (US)OSHA Occupational Safety and Health Administration (US)OES Occupational Exposure Standard (UK)PEL Permissible Exposure Limit (OSHA) (US)


RCRA Resources Conservation and Recovery Act (US)REL Recommended Exposure Level (NIOSH) (US)RID Regulations concerning the International Carriage of Dangerous Goods by Rail (Europe)RQ Reportable QuantitySARA Superfund Amendments and Reauthorization Act (US)SCBA Self Contained Breathing ApparatusSTEL Short Term Exposure LimitTEFC Totally Enclosed Fan Cooled Electric MotorTLV Threshold Limit Value (ACGIH) (US)TSCA Toxic Substances Control Act (US)TWA Time Weighted AverageUL Underwriters Laboratories (US)UN United Nations

1. PRODUCT DESCRIPTION

1.1 PRODUCT DESCRIPTION ......................................................................... 13

1.2 IDENTIFICATION ....................................................................................... 13

1.3 PHYSICAL PROPERTIES ............................................................................ 14


PRODUCT DESCRIPTION

1.1 PRODUCT DESCRIPTION

2,2-Dibromo-3-nitrilopropionamide can be supplied as a powder, a granulate or as a Solution formulation.

DBNPA Technical 100%, powder

DBNPA Granulate

DBNPA Solution in a non regulated solvent* and water

* Solvent DPG - Dipropylene glycol Solvent PEG - Polyethylene glycol

1.2 IDENTIFICATION

UN Number – Technical grade 2811Toxic solid, Organic n.o.s.(2,2-Dibromo-3-nitrilopropionamide)

UN Number – Granulate 3077Environmentally hazardous substance, solid, n.o.s.(2,2-Dibromo-3-nitrilopropionamide)

UN Number Solution formulations - Generally not regulatedRegulated by DOT for bulk shipments only (UN No. 3082)

CAS Number2,2-dibromo-3-nitrilopropionamide 10222-01-2

Formula2,2-dibromo-3-nitrilopropionamide, C3H2Br2N2O

Br ON C C C NH2

Br

14 EDITION 2, 2016

SynonymsDBNPA, 2,2-dibromo-3-nitrilopropionamide, 2,2-dibromo-2-cyanoacetamide

Trade namesBiobrom C-103, Biobrom C-103 L, Biobrom C-103 LP,Biobrom C-100 G, Biobrom AS

Chemical Family Halogenated cyanoacetamide

AppearanceColor: white to off - white powder or granulate, or clear to amber liquidOdor: mild antiseptic

1.3 PHYSICAL PROPERTIES

Characteristic 100% Powder 20% SolutionBoiling Point Decomposes Not applicableMelting Point 123 to 125 °C -20 to -25 °CFlash Point None 159 to 165 °CAuto ignition temperature Not Available Not AvailableVapor pressure Not applicable 2266.5 Pa (20 °C)Decomposition Temperature 190 °C Not applicableMolecular Weight 241.84 Not applicableDensity 2.375 g/ml 1.16 to 1.21 g/mlFlammable limits in air Will not support combustion

Solubility in water 17 ± 0.05 g/l at 25.7°C

Solubility of DBNPA in other solvents g/100g at 25°CAcetone 35Ethanol 25Dimethyl formamide 120Polyethylene glycol 120

Dust FlammabilityDBNPA is not classified as a flammable substance for transportation. The dust is weakly explosive (KST value 92, class I). It is not sensitive to ignition by static electricity (Minimum Ignition Energy > 500 mJ).

PRODUCT DESCRIPTION

2. PACKAGING

2.1 PLASTIC SACKS .......................................................................................... 18

2.2 PLASTIC PAILS ........................................................................................... 19

2.3 BIG BAGS ................................................................................................... 20

2.4 PLASTIC JERRICANS .................................................................................. 21

2.5 INTERMEDIATE BULK CONTAINER (IBC) ................................................ 22

2.6 L-RING DRUMS.......................................................................................... 23

2.7 MARKING AND LABELING........................................................................ 24

PACKAGING


STANDARD DBNPA PACKAGING

DBNPA is packaged in convenient forms for practical use.

Solid – powder or granulate• 25 Kg Valve Woven P.E.Bags for DBNPA powder• 20 Kg Plastic pails for DBNPA granulate• 227 Kg Big bags for DBNPA granulate

Solution formulations• 20 Liter Jerricans• 240-300 Kg Plastic drums for DBNPA solution• 1000-1500 Liter IBC’s

All DBNPA Solution packaging is supplied with a vent. DBNPA is shipped in freight containers. When opening a container at its destination, cautiously open the doors completely and allow the container to be aired for 15 minutes before entering and before any unloading operations are started.

Palletized drums, bags or pails should be stacked no more than three pallets high. Palletized big bags should be stacked no more than two pallets high.

Exceeding this limit may damage the packaging.

Drums should be shipped and stored upright. They should be supported so that there is no danger of a drum being moved accidentally or falling.

DBNPA pails should not be used for any other purpose other than the original DBNPA filling. The receptacles should be kept tightly closed except when in use.

The Shelf Life of DBNPA is 3 years

This DBNPA substance should never be stored in a home or office building. It should only be stored in a well ventilated warehouse, in an area that is adequately marked and locked.

Drums should be issued “First-in, First-out”, and should be inspected for external damage every three months. After any unusual incident in the warehouse which could damage the drums or the bags, they should be inspected.

If there are any signs of spills or leakages, take appropriate action as indicated in section 5, emergency response.

Receptacles with signs of external damage should never be sent to a customer. The supplier should be consulted for instructions on disposal of damaged drums, or bags.

18 EDITION 2, 2016

2.1 PLASTIC SACKS

Net Weight 20 / 25 KgMaterial LDPEUN code UN 5H3/Y25/SDimensions (cm) 13 X 58 X 38

PALLET DETAILSDimensions (cm) 100 X 120 X 96No of units per pallet 42Gross weight of pallet 1078

CONTAINER DETAILSQuantities per container according to shipping destination

20 foot containers

Destination Number of pallets

Total number of sacks

Net weight (Kg)

Gross weight (Kg)

Europe 20 840 21,000 21,568Japan 20 840 21,000 21,568USA - Warehouse 18 756 18,900 19,411USA - Direct 17 714 17,850 18,333India 19 798 19,950 20,490Korea 17 714 17,850 18,333

1000 mm1200 mm

Height 960 mm

PACKAGING


2.2 PLASTIC PAILS

Net Weight 20 KgMaterial LDPEDimensions 31 Dia. X 36 cm

PALLET DETAILSDimensions (cm) 100 X 120 X 90No of units per pallet 24Gross weight of pallet 534

CONTAINER DETAILSQuantities per 20 foot container according to shipping destination

Destination Number of pallets

Total number of pails

Net weight(Kg)

Gross weight (Kg)

All 20 480 9600 11060

1000 mm 1200 mm

Height 900 mm

20 EDITION 2, 2016

2.3 BIG BAGS

Net Weight (Kg) 227Material Polypropylene and linerUN code UN13H4/YDimensions 89 X 89 X 40 cm

PALLET AND CONTAINER DETAILS

Size (Kg) 227Dimensions (cm) W100 X L120 X H95No of units per pallet 3Net weight of pallet (Kg) 681No. of pallets per container (20 ft) 20Net weight per container (Kg) 13,620

1000 mm1200 mm

Height 950 mm

PACKAGING


2.4 PLASTIC JERRICANS

20 LiterNet Weight 20 KgMaterial HDPEUN code UN 3H1/X1.9/250Dimensions (cm) 29 x 26 x 39

PALLET DETAILSDimensions (cm) 100 X 120No of units per pallet 16Gross weight of pallet 357

22 EDITION 2, 2016

2.5 INTERMEDIATE BULK CONTAINER (IBC)

1000 LiterNet Weight 1000-1500 KgMaterial HDPEUN code UN 31HA1/Y/Typical Dimensions (cm) 100 X 120 X 116

PACKAGING


2.6 L-RING DRUMS

220 LiterNet Weight 240-300 KgMaterial HDPEUN code UN 1H1Dimensions (cm) 58 Diameter X 94

PALLET DETALSDimensions (cm) 100 X 120No of units per pallet 4Net weight of pallet 1040 Kg

24 EDITION 2, 2016

2.7 MARKING AND LABELING

LabelsLabels are used for marking packages.

The labels relate to:Hazard risk markingConsumer product identificationConsumer use informationMedical treatment guides.

PlacardsPlacards are used for marking transport containers and provide:1. Product identification2. Hazard risk marking.

Diamond Shaped Labels and PlacardsDiamond shaped labels and placards are internationally recognized danger identification for hazardous substances.

For DBNPA solid products:Toxic Symbol: Skull and crossbonesBlack printing on a white background

The hazard class number “6” shall appear in the lower corner of the danger label and placard.

For DBNPA granulate:Environmentally hazardous symbol: Seven vertical stripes in upper half Black printing on a white background.The hazard class number “9” underlined shall appear in the lower corner of the danger label and placard.

Sizes:Label size: 100 mm x 100 mm, except for small packages only able to bear smaller labels.Placard size: Not less than, 250 mm x 250 mmDBNPA PACKAGING 23

PACKAGING


Orange PanelThe orange panel with the UN number and the Hazard (Kemler) identification number, is required by the ADR/RID Regulations. Some countries, such as the UK and Israel, require the UN number and the Hazchem emergency action code.

The hazard (Kemler) identification number of solid DBNPA is 60 indicating that the substance is toxic.

The hazard (Kemler) identification number of granulated DBNPA is 90 indicating that the substance is environmentally hazardous.

The Hazchem Emergency Action Code for DBNPA is• 2X for solid• 2Z for granulate

26 EDITION 2, 2016

PACKAGING


TRANSPORTATION

3. TRANSPORTATION

3.1 PACKAGING AND TRANSPORTATION .................................................... 31

3.2 DRIVERS' LOADING CHECKLIST ............................................................... 36

3.3 DRIVERS' ROAD REMINDERS ................................................................... 38

TRANSPORTATION


This chemical, 2,2-Dibromo-3-nitrilopropionamide, does not appear specifically by name in the lists of hazardous materials. It has been assigned to one of the “not otherwise specified” entries in accordance with its dangerous properties. All conditions of this entry must be met for shipping, transportation and related handling functions.

The following is a summary of the main regulations and requirements regarding the transportation of DBNPA products according to international regulations.

3.1 PACKAGING AND TRANSPORTATION

United Nations (Orange Book)There has been considerable harmonization between the Orange Book and the various international regulations. These model regulations have been adopted in the various regulations, agreements and codes specified in this section. Many of the sections are numbered in the same way and much of the text is identical.

IMDG CodeDBNPA technical (solid) DBNPA technical (granulate) DBNPA

solution (liquid)

Shipping name

Toxic solid, Organic n.o.s. UN no. 2811(2,2-Dibromo-3-nitrilopropionamide)

UN no. 3077 Environmentally hazardous substance, solid, N.O.S., (2,2-Dibromo-3-nitrilopropionamide)

Not regulated for transportation

Hazards Class

6.1: Poisons 9: Miscellaneous Dangerous Substances and Articles.

Packing group

II:- medium danger III: Substances presenting low danger

Marking Marine Pollutant Marine PollutantEmS F-A, S-A F-A, S-FHazards Class

6.1: Toxic substances 9: Miscellaneous Dangerous Substances and articles

Packaging Packing instruction P002, IBC 08

Packing instruction P002, IBC 08

Stowage Stowage Category B Stowage Category ASegregation “Separate from”

explosives. “Away from” substances liable to spontaneous combustion, oxidizers and infectious substances

No specific segregation specified

32 EDITION 2, 2016

The technical name, 2,2-Dibromo-3-nitrilopropionamide, should be shown in parentheses immediately following the proper shipping name as shown above.

Stowage Category A:• Cargo ships or passenger ships carrying less than 25 passengers: on deck or

under deck• Other passenger ships: on deck or under deck

Stowage Category B:• Cargo ships or passenger ships carrying less than 25 passengers: on deck or

under deck• Other passenger ships: on deck only

Part 6 - Freight Containers• Require approval in accordance with the International Convention for Safe

Containers. (CSC)• Safety Approval Plate permanently affixed to each approved container.

Part 7.3 - Special precautions in the event of an incident involvingdangerous goodsThe emergency procedures for ships carrying dangerous goods are contained in the supplement. For DBNPA products, the EmS schedules are given in the above table. The Medical First Aid Guide (MFAG) is also contained in the supplement and is for use in accidents involving dangerous goods.

TRANSPORTATION


DOT RegulationsTable of Hazardous Materials 49 CFR 172.101

DBNPA technical (solid)

DBNPA technical (granulate)

DBNPA solution (liquid)

Shipping Name

Toxic solid, Organic N.O.S. (2,2-dibromo-3-nitrilopropionamide)

Environmentally hazardous substance, solid, N.O.S., (2,2-Dibromo-3-nitrilopropionamide)

for bulk shipments only Environmentally Hazardous Substance, liquid, N.O.S. (2,2-dibromo-3-nitrilo propionamide)

UN number 2811 3077 3082Hazard Class 6.1 Toxic 9: Miscellaneous

Dangerous Substances and Articles.

9: Miscellaneous Hazardous Material

Guide number (Emergency Response Guidebook, 1996)

154 171 171

Packaging group

II III III

Vessel Stowage

Category B Category A Category A

Ships: Cargo: on deck or under deck, passenger: on deck only

Cargo or passenger vessel: on deck or under deck

Cargo or passenger vessel: on deck or under deck

Aircraft: cargo: 100 Kg/pKg passenger:25 Kg/pKg

No limit No limit

34 EDITION 2, 2016

ADREuropean Agreement Concerning the International Carriage of Dangerous Goods by Road

According to: Table A - Dangerous Goods list DBNPA are classified as:

DBNPA SolidToxic solid, organic, N.O.S, T2 (Toxic substance without subsidiary risk, solid)Packaging instructions P002 and IBC 08 apply.Flexible IBCs shall be sift-proof and water resistant or shall be fitted with a sift-proof and water resistant liner (B4).

Special provisions for carriage:Loading, unloading and handlingCV13 Special provisions for spills in a vehicle or container.CV28 Precautions with respect to foodstuffs.S9, S19 Provisions for stopping near public places and supervision of loads above 5,000 Kg.Hazard identification number for labeling transport units.Hazard Identification Number, No. 60.

DBNPA GranulateEnvironmentally hazardous substance, Solid, N.O.S, M7 (pollutant to the aquatic environment, solid)Packaging instructions P002 and IBC 08 apply.Flexible IBCs shall be sift-proof and water resistant or shall be fitted with a sift-proof andwater resistant liner (B3).

Special provisions for carriage:Loading, unloading and handlingCV13 Special provisions for spills in a vehicle or container.Hazard identification number for labeling transport units.Hazard Identification Number, No. 90.

DBNPA SolutionNot regulated for transportation

RID (Europe)Regulations concerning the International Carriage of Dangerous Goods by RailThese regulations are similar to the ADR agreement.

TRANSPORTATION


IATA RegulationsDangerous Goods Regulations, 51st Edition, January 2010

Shipping name

Solid: Toxic solid, Organic N.O.S. UN no. 2811(2,2-dibromo-3-nitrilopropionamide)

Granulate: Environmentally hazardous substance, solid, N.O.S. UN no. 3077(2,2-dibromo-3-nitrilopropionamide)

Stowage Solid Granulate SolutionCargo Aircraft Only Packaging instruction

615100 Kg/package

Packaging instruction 911400 Kg/package

Not regulated for transportation

Passenger and Cargo Aircraft

Combination Packaging 61325 Kg/package single packaging not permitted

Packaging instruction 911400 Kg/package

Limited Quantity Y6131 Kg/package

Y91130 Kg/package

Local Regulations

United Kingdom and IsraelRegulations apply to the transport of 200 Kg or more of a toxic substance of packing group II.

The Hazchem Emergency Action Codes for DBNPA:

Description UN Number Hazchem EAC CodeDBNPA Solid 2811 2XDBNPA Granulate 3077 2Y

36 EDITION 2, 2016

3.2 DRIVER’S LOADING CHECKLISTThe following is a suggested checklist for DBNPA solid, based on European Agreement concerning the Carriage of Dangerous Goods by Road (ADR) regulations and good practice. The shipper should also ensure that all local regulations are complied with.

❏ Container is marked clearly at both sides and at each end with the UN No. (2811), Hazard Identification Number 60 and Hazard Placard no. 6, Toxic Solid. Vehicles need only be placarded if the container placards are not visible

❏ Vehicle is equipped with at least two portable dry powder fire extinguishers or equivalent, of at least two and twelve Kg capacity, unused and checked within the past year.

❏ Approved portable lamps are available to each member of the crew

Vehicle has the following emergency equipment:❏ Eye rinsing liquid❏ Wheel blocks❏ Two self-standing warning signs❏ Suitable warning vests, protective gloves, eye protection and an emergency escape mask

for each member of the crew❏ A shovel, drain seal and plastic container for collection of material.

❏ Vehicle has a certificate of approval for dangerous goods. The validity of the approval shall expire not later than one year after inspection date.

❏ Driver and assistant driver have valid licenses to operate dangerous goods vehicles, issued or renewed within the past five years, together with a valid training certificate and means of identification.

❏ Hazardous transport unit does not consist of more than one trailer

❏ The vehicle is not carrying any materials incompatible with DBNPA at the same time (Explosives, substances liable to spontaneous combustion, organic peroxides and oxidizing substances, and infectious substances)

❏ DBNPA will be kept apart from food stuffs and animal feed.

Shipping papers include:❏ Shipping name: Toxic solid, Organic n.o.s. UN no. 2811 (2,2 Dibromo-3-

nitrilopropionamide)❏ Container/vehicle packing certificate❏ Quantity being shipped, including number and description of packages.❏ The name and address of the consignor and consignee

TRANSPORTATION


❏ All papers concerning the transport of the dangerous goods are kept in a holder on the inside of the door on the driver’s side of the vehicle

❏ Driver has approved route to destination with specified stops. No alternative routes will be used or unauthorized stops made.

❏ Vehicle has a full fuel tank before loading DBNPA

❏ Containers have been fastened with all the twist lock corner fittings.

38 EDITION 2, 2016

3.3 DRIVER’S ROAD REMINDERSThe driver and assistant driver of any vehicle transporting DBNPA should complyWith the following requirements:

Supervision of vehicles (ADR regulation section 8.4)

Parking the hazardous goods transport unit should be under one of the following conditions:• Supervised parking lot, attendant aware of the nature of the load, and how to

contact the driver.• Vehicle parking lot where unit is not likely to suffer damage.• Open space separated from public highway and public dwellings, where public

does not normally pass.

Miscellaneous requirements (ADR regulation section 8.3)• No passengers are allowed.• The crew shall know how to use fire-fighting appliances.• A driver or driver’s assistant may not open a package containing DBNPA.• Portable lighting apparatus shall be spark proof.• No smoking is permitted during handling operations in the vicinity of the vehicle

and inside the vehicle.• The engine is to be shut-off during all handling operations unless required to

drive pumps, hoist, etc.• Parking brakes are to be applied whenever parked. Trailers without braking

devices shall be restrained from moving by applying wheel chocks.• If the vehicle is parked on a road at night or with poor visibility, warning signs are

to be placed 10 meters ahead of and behind the vehicle.

TRANSPORTATION

4. USER GUIDE

4.1 GENERAL SITE RECOMMENDATIONS ..................................................... 41

4.2 PROCESS SAFETY MANAGEMENT REGULATIONS ................................. 45

4.3 OCCUPATIONAL EXPOSURE LIMITS ....................................................... 46

4.4 PROTECTIVE CLOTHING ........................................................................... 46

4.5 RESPIRATORY PROTECTION PROGRAM ................................................. 47

USER GUIDE


4.1 GENERAL SITE RECOMMENDATIONS

As DBNPA is a toxic or environmentally hazardous material, storage areas should be carefully designated and supervised. Local regulations must be complied with.

This is a guide is to be used for the selection and supervision of a DBNPA storage area.

The storage areas can be supplier distribution warehouses, third party distribution houses or user storage areas.

The storage area should be located at least 100 meters, and preferable 200 meters, from any school, hospital or concentration of 10 or more private dwellings, and at least 25 meters from the nearest occupied building, or public road.

The amount of DBNPA stored at the user site should be kept to a minimum.

Worksite should be enclosed with a low curb or wall, called a dike, to contain any spilled material and prevent the dispersal of fire fighting water.Within the diked area, there should be no sewer connection. However, a sump should be provided for collecting and pumping away any collected fire fighting water.

Arrangement of the storage area should take into consideration the potential evolution of large quantities of toxic fumes which would be hazardous to the surrounding areas.

Provide adequate ventilation to extract fumes from indoor storage areas in the event of a fire.

DBNPA pallets should not be stored closer than 1.2 meters (4 feet) from a wall or ceiling.

DBNPA should never be stored in a basementBuildings should be at least 10 meters apart to allow strengthened approach roads for emergency vehicles on two sides of the installation.

Building construction should be fire resistant and provisions made for potential fire fighting activities, according to relevant local and national codes, and in consultation with the local fire brigade. The fire fighting installation should include provision for an adequate supply of water. Fire extinguishers and hydrants should be distributed around the area.

42 EDITION 2, 2016

Electrical installation:Junction boxes and light fittings should be dust tight. Cast iron (epoxy-base coated) or a non-metallic material is suitable.

Use TEFC (Totally Enclosed Fan Cooled) motors of cast iron or steel construction with epoxy-base coating.

Floors should be of impervious construction, preferably concrete.

Safety and SecurityAny area where DBNPA is used or stored should be enclosed so that unauthorized persons and animals are prevented from entering the area.

Adequate lighting should be provided to allow sufficient night surveillance. Surveillance should be provided 24 hours a day.

Provide clearly marked personnel escape routes without obstructions including adequately sized doors and windows.

Provide special remote eating and changing areas with adequate supplies of clean water for washing and showers. Provide a smoking area remote from the operating area.

A telephone should be provided which is freely available and readily accessible for the reporting of accidents or emergency situations.

A windsock should be clearly visible from all points on the site and replaced as required for indicating wind velocity and direction.

Emergency equipment cabinets should be installed not more than 30 meters or ten seconds walking distance from any location in the storage area.

Non freeze safety showers and eyewash fountains should be provided, clearly marked, well lighted and with unobstructed access. They should be located close to the DBNPA storage area and not more than 30 meters or 10 seconds walking distance from any location in the storage area. Provide an alternative supply of clean water.

Handling DBNPAAll management and operating personnel involved in the use or handling of DBNPA should undergo safety training, in addition to the specific task training. Only experienced well-trained operators should be allowed to receive and unload DBNPA receptacles.

USER GUIDE


The management should ensure that emergency response plans have been made and coordinated with the local emergency response authorities.

Precautions should be taken from the moment the shipment of DBNPA arrives at the site gate.

Ensure that road and rail vehicles cannot be moved during a transfer operation.

DBNPA is shipped in freight containers. When opening a container at its destination, cautiously open the doors completely and allow the container to be aired for 15 minutes before entering and before any of the unloading operations are started.

The drums should not be handled roughly.

No open flame heating is allowed. Keep the DBNPA receptacles away from heating coils.

Operators that could be exposed to DBNPA dust should wear goggles and a dust filter.

When dry, DBNPA powder is non-corrosive. Protective measures should be taken when there is the possibility of dusting conditions or the decomposition of DBNPA.

Receptacles should be kept dry and tightly closed.

Use only clean and dry utensils for handling DBNPA.

Make sure that the equipment for handling DBNPA is clean and dry before starting a process including DBNPA. Clean the equipment of all trace materials after process completion.

Do not start a batch process involving DBNPA unless the process can be completed.

Prevent contact of DBNPA with chemicals such as oxidizers, reducing agents or bases.

Filters of dust collecting systems which are contaminated with DBNPA have to be disposed of in an approved manner at an approved disposal facility. Consult with the local authorities for information on these regulations and facilities.

Work with DBNPA should be carried out with a high standard of housekeeping and personal hygiene.

Provide up to one or two drums of 10% sodium carbonate solution for dealing with DBNPA spills.

Provide clean, dry, empty receptacles or overpacks for dealing with spills or damaged DBNPA drums.

44 EDITION 2, 2016

Sample Checklist for a DBNPA Handling Facility

Yes NoToxic hazard signs displayed (for DBNPA solid)Storage away from schools, hospitals or private dwellingsMinimum amount is being storedArea surrounded by curb or dikeSewer connections with quick closureSump to prevent contamination of sewers and water coursesAdequate ventilation in storage buildingsClear space 1.2 m. from walls and ceilingNearest building - 10 meter gapReinforced road for emergency vehiclesFire resistant building constructionFire fighting hydrantsFire fighting extinguishersDust and vapor tight electrical fittingsTEFC electric motorsImpervious floorArea enclosed and secure – no unauthorized entryAdequate lighting24 hour surveillanceClearly marked escape routesRemote eating, changing and smoking areasEmergency telephoneWind sockEmergency equipment cabinets, showers and eye-washPrevent vehicles from moving during handling operationsNo open flame heatingPersonal protection equipment used when unloading or handlingGood housekeeping and personal hygieneProvide neutralizing agentAvailability of overpacks for collecting spills

USER GUIDE


4.2 PROCESS SAFETY MANAGEMENT REGULATIONS

USA• Facilities handling HIGHLY HAZARDOUS CHEMICALS over a threshold quantity

(29CFR1910.119): For DBNPA there is no threshold quantity.

The management is required to prepare EMERGENCY ACTION PLANS to minimize the consequences of a hazardous release of this toxic material. This written emergency action plan describes the measures taken to prevent any release and the activities of the workers and community services in the event of a release.Workers, including contractor workers, are to be given adequate training and refresher courses to implement this emergency action plan. Compliance audits are to be made before starting up a facility and after changes have been made in a facility or its operation procedures. Deficiencies and the corrections made are to be documented to assure that the facility can be put into safe operation.Changes may have to be reflected in emergency action plans.A compliance audit is to be repeated every three years.All incidents, which result in a release of hazardous materials or could have resulted in the release, are to be investigated. The results of the investigation and corrective actions recommended and taken are to be documented.

• Toxic Chemical Release Reporting (40 CFR 372) DBNPA is not listed

• CERCLA (40 CFR 302) DBNPA is not listed

Europe & UK - Directive 96/82/EG (SEVESO guidelines) COMAH (UK), BRZO (NL)The purpose of this directive is to prevent and limit the consequences of major accidents involving a dangerous substance. DBNPA is not listed in these regulations, but does fall under the category of toxic for DBNPA solid (lower tier 50 tons, top tier 200 tons) substances, whose inventory is cumulative, with respect to other substances in the same category.

Granular DBNPA, which is environmentally hazardous, has a lower tier of 100 tons and an upper tier of 200 tons. Therefore specific safety reports and emergency plans may have to be prepared and accidents involving DBNPA may have to be reported under these regulations.

46 EDITION 2, 2016

4.3 HAZARDOUS EXPOSURE LIMITS

Exposure limit values go under different names in the various standards, countries, time periods and populations.

Generally, the exposure limit is specified as TWA, Time Weighted Average, for an eight or a ten hour workday and a STEL, Short Term Exposure Limit for fifteen minute, five minute periods or a ceiling value not to be exceeded.

Some of the limits are called TLV, Threshold Limit Values (ACGIH), REL, Recommended Exposure Limit (NIOSH) or OES, Occupational Exposure Standard (UK - HSE - COSHH).

There is also an ERPG, Emergency Response Planning Guideline value for planning exposure limits for the civilian population that includes children, the elderly and disabled persons.

The United States (ACGIH, OSHA, and NIOSH) and United Kingdom authorities have not determined occupational exposure limits for DBNPA.

The manufacturer’s recommended exposure limit is 0.25 mg/m3

4.4 PROTECTIVE CLOTHINGThe protective clothing required for workers, under routine operating conditions, should be sufficient to allow the worker to escape the operating area, if there should be a release of hazardous material.

Dust masks, goggles, gauntlets and full body covering clothing should be worn when handling DBNPA, or when there is a possibility of dusty conditions.

Contaminated work clothes should be placed in closed containers until laundering. The clothes should be laundered under supervision, by the employer and not laundered at home.

USER GUIDE


4.5 RESPIRATORY PROTECTION PROGRAMUnder routine operating conditions, when working with DBNPA, a gas mask is not necessary, but a dust filter should be used.

However, should DBNPA begin to decompose, a full face gas mask with a new, unused chlorine/bromine canister should be used to escape the area.

The face piece should be full face made of neoprene or other non-natural or non-butyl rubber elastomer. Eyeglasses cannot be worn with regular face pieces. Special face pieces or face piece adapter kits can be supplied for use with special eyeglass frames.

Color coding of gas mask filters differ under different regulations.

U.S. Code of Federal Regulations 29 CFR 1910.134, Chlorine, Color coded: White, with a yellow stripe.

European Standard, EN 141,Inorganic gases, Type B, Color coded: Grey.

It should be emphasized that the filter life is limited, even at low vapor concentrations (no more than 20 minutes continuous use). While wearing a gas mask, the operator should immediately leave the area on detecting any smell, taste or irritation of the eyes A self contained breathing apparatus should be worn to reenter an area where DBNPA is decomposing and when the oxygen content, is less than 19.5%, or if odor is detected while wearing a gas mask.

The self-contained breathing apparatus should be stored in a clean sanitary cupboard, conveniently located. Whenever possible, respirators should be individually assigned for hygenic purposes and to assure a good fit. After each use, they should be inspected, cleaned and disinfected. It should also be cleaned and disinfected each month, even if the respirator has not been used. A record should be kept of the inspection date, and what was found at the time. The breathing air cylinders of the self-contained breathing apparatus, should be tested and maintained in accordance with the local pressure vessel regulations.

A new operator should be trained in respirator use, and fitting the face piece before starting his assignment. A record should be kept of the training and fitting dates.

Contact lenses must not be worn with a respirator.

Canisters should not be used after expiration date.

48 EDITION 2, 2016

Respirator RegulationsA respirator protection program is required in the U.S., and is recommended for other locations:

• Written standard procedures governing the selection and use of respirators shall be established.

• Written procedures shall be prepared, covering safe use of respirators in dangerous atmospheres that might be encountered in normal operations or in emergencies.

• Training shall provide an opportunity to handle the respirator, have it fitted properly, test its face-piece-to-face seal, and wear it in normal air and a test atmosphere

• A record shall be kept of inspection dates and findings, for respirators maintained for emergency use.

• There shall be an annual inspection and evaluation to determine the effectiveness of the respiratory program including respirator condition and correct gas mask, face-piece fitting.

5. EMERGENCY RESPONSE

5.1 FACILITY EMERGENCY ACTION PLANNING ..................................... 51

5.2 TRANSPORT EMERGENCY RESPONSE .............................................. 52

5.3 HAZARD IDENTIFICATION .................................................................. 53

5.4 CLASSIFICATION OF THE SUBSTANCE.............................................. 54

5.5 FIRE FIGHTING .................................................................................... 60

5.6 SPILLS OR LEAKS ................................................................................ 61

5.7 EMERGENCY RECEPTACLES ............................................................... 62

5.8 EXPOSURE TO DBNPA........................................................................ 63

EMERGENCY RESPONSE


5.1 FACILITY EMERGENCY ACTION PLANNING

USA - OSHA (29 CFR 1910.119n and 29 CFR 1910.120q)Emergency Action plans must be established and submitted to state and local authorities for any facility where Threshold Quantities (TQ) of hazardous substances are handled.

Reportable Quantities (RQ) - U.S.A.DBNPA is classified as a hazardous substance due to its characteristic of reactivity with water. It generates toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or to the environment 40 CFR 261.23 (a) (4).

The disposal of DBNPA is regulated by the US federal RCRA regulations as a hazardous waste, number D003. 40 CFR 261.23 (b).

Any release, leak or spill of 100 pounds (45.4 Kg) or more must be immediately reported to the: National Response Center, phone: 800-424-8802.New Jersey Toxic Catastrophic Prevention Act, Not Listed.

A Facility Emergency Coordinator is to be appointed to the local Emergency Planning Committee.

The plan has to be reviewed and audited every three years. When there is a release of a hazardous material, the Emergency Planning Committee is to be advised of the following information (a transportation related release may be notified to the 911 emergency operator):• That the released material, DBNPA is a toxic material.• The quantity released, the time of the release and its duration.• The media into which the release occurred.• An indication of the health risks and sources for medical advice.• Precautions to be taken by the local community, preferably as established in a

previously prepared emergency plan.• Names and phone numbers for receiving further information on the material.

The Emergency Planning Committee is to be given the following follow-up information:• Actions that were taken to contain the release.• Any acute or chronic health problems that were the result of the release.• Medical advice that was given to the exposed individuals.

52 EDITION 2, 2016

EUROPE & UK: (EC Directive 82/501 with the latest amendments)The European Economic Community has issued regulations on Major Accident Hazards, Directive 82/501/EEC.Storage sites for 50 tons or more of DBNPA (100 tons for granulate) must prepare a written policy for identifying the major accident hazards at their sites and what steps have been taken to prevent and limit the consequences of major accidents. In addition, a safety management system, a training program, planning for emergencies and reporting of major accidents or near misses are to be implemented at these sites.Process sites for 200 tons or more of DBNPA must prepare a safety report, emergency plans, and provide information to the public, in accordance with the schedules contained in the directive.

5.2 TRANSPORT EMERGENCY RESPONSEThe driver of a vehicle involved in an accident while transporting a hazardous material should immediately leave the vehicle, taking with him the shipping papers, and take reasonable measures to extinguish any small fires.

The driver should call for help, and furnish the following information about the hazardous material involved:

• UN number: 2811• Hazard Class Placard.• Hazardous response markings (e.g. EAC Code, NFPA diamond numbers).• Quantity of hazardous material involved.• Emergency contact phone number.

The first responder is generally the local fire department, which should act to:• Protect persons, property and environment.• Contain the release from a safe distance.• Do not get involved in stopping the release.• Ensure that a qualified responder has been called.

The Qualified responder, Hazardous Waste Operations & Emergency Response (HAZWOPER), is called by the shipper of the hazardous material or by the first responder if the shipper has not acted.The Hazardous Materials Technician is qualified to stop the release.Hazardous Materials Specialist provides support to responders with information on the hazardous materials, but he is not authorized to become actively involved in response action.

EMERGENCY RESPONSE


The shipper, the first responder or the qualified responder calls the Hazardous Material Specialist when additional information or procedures are required. Emergency Response Telephone Number should be clearly identified as “EMERGENCY CONTACT” on labels and shipping papers.

• USA: CHEMTREC 1-800-424-9300 National Response Center 1-800-424-8802 ICL-IP AMERICA 1-304-675-1150• UK: National Chemical Emergency Center “CARECHEM 24” 44-1865-407333• EUROPE: ICL-IP Terneuzen B.V. 31-1156-89000• ICL-IP, Israel 972-8-6544475/6• ICL JAPAN: 81-3-6801-8430• CHINA: 86-21-2315-7500 NRCC: 86-532-83889090

5.3 HAZARD IDENTIFICATION

ADR Hazard Identification NumberToxic Solid n.o.s. UN 2811Hazard identification number No. 60EAC Emergency Action Code (EAC)The UK CDG Road - Carriage of Dangerous Goods Regulations require the display of this code number in the UK.The EAC - Emergency Action Code for DBNPA is:2 Use fine water spray.X Prevent material from entering drains and watercourses.Wear chemical protective clothing including gloves and breathing apparatus.Contain and gather spilled material.

54 EDITION 2, 2016

NFPA Hazard Identification: DBNPAHealth hazard: 3 SeriousMaterials that under emergency conditions can cause serious or permanent injury.Areas should be entered only when wearing self-contained breathing apparatus and special protective clothing.

Flammability hazard 0DBNPA does not burn.

Reactivity Hazard 1Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures.

Decomposition of DBNPAIf exposed to a temperature of 190˚C or more, decomposition will take place with the generation of heat and toxic gases such as bromine, hydrogen bromide, CNBr, C2H5Br, CH3Br and nitrogen oxides.DBNPA is not combustible.Check that the free bromine level does not increase over 3 ppm.

5.4 CLASSIFICATION OF THE SUBSTANCE

Regulation (EC) No 1272/2008 aligns the European Union system of classification, labelling and packaging (CLP) of chemical substances and mixtures to the Globally Harmonised System (GHS). DBNPA is classified in accordance to Annex I of this Regulation as follows:

POWDERClassification in accordance with Regulation (EC) No 1272/2008 [CLP/GHS]Acute Tox. 2, H330, Fatal if inhaledAcute Tox. 4, H302 Harmful if swallowedSkin Irrit. 2, H315 Causes skin irritationSkin Sens. 1, H317 May cause an allergic skin reactionEye Damage 1, H318 Causes serious eye damageAquatic Acute 1, H400 - Very toxic to aquatic lifeAquatic Chronic 3, H412 Harmful to aquatic life with long lasting effects Additional OSHA/ WHMIS 2015 hazardsCombustible dust

EMERGENCY RESPONSE


Label elementsLabelling in accordance with CLP Regulation EC (No) 1272/2008

Symbol(s)

Signal Word DANGER

Hazard statementsH330 Fatal if inhaledH302 Harmful if swallowedH315 Causes skin irritationH317 May cause an allergic skin reactionH318 Causes serious eye damageH410 Very toxic to aquatic life with long lasting effects Precautionary statementsP260 Do not breathe dust/fume/gas/mist/vapors/sprayP280 Wear protective gloves/protective clothing/eye protection/face

protectionP284 Wear respiratory protectionP302 + P352 IF ON SKIN: Wash with plenty of soap and waterP304 + P340 IF INHALED: Remove person to fresh air and keep comfortable

for breathingP301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you

feel unwellP330 Rinse mouthP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physician

56 EDITION 2, 2016

GRANULARGHS classificationAcute Tox. 4, H302 Harmful if swallowedSkin Irrit. 2, H315 Causes skin irritationSkin Sens. 1, H317 May cause an allergic skin reactionEye Damage 1, H318 Causes serious eye damageAquatic Acute 1, H400 - Very toxic to aquatic lifeAquatic Chronic 3, H412 Harmful to aquatic life with long lasting effects Additional OSHA/ WHMIS 2015 hazardsCombustible dust Labels and other form of warning Symbol(s)

Signal Word DANGER

Hazard statementsH302 Harmful if swallowedH315 Causes skin irritationH317 May cause an allergic skin reactionH318 Causes serious eye damageH410 Very toxic to aquatic life with long lasting effects Precautionary statementsP261 Avoid breathing dust/fume/gas/mist/vapors/sprayP280 Wear protective gloves/protective clothing/eye protection/face

protectionP301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you

feel unwellP330 Rinse mouthP302 + P352 IF ON SKIN: Wash with plenty of soap and water

EMERGENCY RESPONSE


P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physicianP264 Wash hands thoroughly after handlingP270 Do not eat, drink or smoke when using this productP272 Contaminated work clothing should not be allowed out of the

workplaceP273 Avoid release to the environmentP391 Collect spillageP333 + P313 If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 Take off all contaminated clothing and wash it before reuseP501 Dispose of contents/container in accordance with national and

international regulations

Hazard statementsH302 Harmful if swallowedH315 Causes skin irritationH317 May cause an allergic skin reactionH318 Causes serious eye damageH410 Very toxic to aquatic life with long lasting effects

Additional OSHA/ WHMIS 2015hazardsMay form combustible dust concentrations in air

Precautionary statementsP261 Avoid breathing dust/fume/gas/mist/vapors/sprayP280 Wear protective gloves/protective clothing/eye protection/face

protectionP301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you

feel unwellP330 Rinse mouthP302 + P352 IF ON SKIN: Wash with plenty of soap and waterP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing

P310 Immediately call a POISON CENTER or doctor/physicianP264 Wash hands thoroughly after handlingP270 Do not eat, drink or smoke when using this product

58 EDITION 2, 2016

P272 Contaminated work clothing should not be allowed out of the workplace

P273 Avoid release to the environmentP391 Collect spillageP333 + P313 If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 Take off all contaminated clothing and wash it before reuseP501 Dispose of contents/container in accordance with national and

international Regulations SOLUTIONGHS classificationAcute Tox. 4 H302 Harmful if swallowedEye Damage 1, H318 Causes serious eye damageSkin Sens. 1, H317 May cause an allergic skin reaction

Signal Word DANGER

Hazard statementsH302 Harmful if swallowedH318 Causes serious eye damageH317 May cause an allergic skin reaction

Precautionary statementsP261 Avoid breathing fume/gas/mist/vapors/sprayP280 Wear protective gloves/protective clothing/eye protection/face protectionP301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP330 Rinse mouthP302 + P352 IF ON SKIN: Wash with plenty of soap and waterP333 + P313 If skin irritation or rash occurs: Get medical advice/attentionP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingP310 Immediately call a POISON CENTER or doctor/physic

EMERGENCY RESPONSE


Classification:Acute Toxicity 3 Eye Damage 1 Aquatic Acute 1M factor = 1

GHS05 GHS06 GHS09

Signal word: DangerHazard pictograms

H&P statements as will appear in MSDS and label:H331: Toxic if inhaled.H302: Harmful if swallowed.H315: Causes skin irritation.H317: May cause an allergic skin reaction.H318: Causes serious eye damage.H400: Very toxic to aquatic life.P261: Avoid breathing dust/fume/gas/mist/vapours/spray.P280: Wear protective gloves/protective clothing/eye protection/face

protection.P301+P330+ P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.P302+P352: IF ON SKIN: Wash with plenty of soap and water.P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a

position comfortable for breathingP305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.P310: Immediately call a POISON CENTER or a doctor/physician

60 EDITION 2, 2016

5.5 FIRE-FIGHTINGIt is very important that DBNPA receptacles should not remain in a fire zone, as the heat will lead to decomposition and to production of toxic vapors. If possible, the DBNPA receptacles should be physically removed from the fire zone. Sometimes, it is possible to move the fire source away from the DBNPA receptacles. The closed DBNPA receptacles, involved in the fire should be cooled by the most practical means. Direct contact with water should be avoided unless copious amounts of water can be used.

A fire in an area containing DBNPA should be extinguished with the most appropriate means available. If the DBNPA is itself involved in the fire, use copious amounts of water to extinguish the fire and cool the DBNPA to prevent and arrest its decomposition due to heat.

If there is a DBNPA spill at the same time that there is a fire, the safety procedure for spills has to be immediately implemented:1. Evacuation of a zone, 50 m around the spill zone.2. Self-contained breathing apparatus for the fire-fighters.3. Wearing of impervious and chemical resistant, clothing. This clothing may not be

suitable for fire-fighting.4. Protect water sources from being contaminated by spilled DBNPA.5. Have all non-essential personnel leave the area immediately.

After the fire, all DBNPA containers should be carefully inspected for leaks or any physical damage. The DBNPA supplier should be immediately informed of any unusual conditions, which have been noticed.

On the roadIf a vehicle carrying DBNPA catches fire and no DBNPA leak is detectable, the driver should move the vehicle to an open area, remove shipping and other emergency response documents (MSDS) from the vehicle and make reasonable efforts to extinguish any small fires. He should then:• Notify the local police and the fire department.• Warn other drivers and pedestrians of the danger.• Notify the nearest DBNPA handling facility.• Stay at a safe distance until the incident has been declared resolved by the

responder in charge on the scene.If the driver cannot reasonably extinguish the fire and/or a DBNPA leak is evident, “Spills or Leaks” procedure (Section 5.7) should be followed immediately.

EMERGENCY RESPONSE


5.6 SPILLS OR LEAKS

DBNPA has been shipped for many years with very few accidents. This is due to the care taken in packaging and handling this material.

Only trained, suitably protected personnel should respond to a DBNPA emergency. See section 4.5 of this handbook for the personnel protective equipment recommended for emergency response personnel. If there should be an uncontrolled DBNPA spill or leak, immediately call the fire department, giving them the maximum information. The competent authorities should be informed of the spill in accordance with local regulations. Twenty-four hour telephone advice is available in most countries for DBNPA road transport emergencies, as noted in section 5.2 above.

If there is a DBNPA spill, it should be immediately contained and gathered into covered, clean, dry containers. Prevent the spilled DBNPA from penetrating a water source or sewer system. Dust masks, goggles, gloves and full body covering clothing should be worn if there is no decomposing of the DBNPA.

The area of decomposing DBNPA should only be entered with self-contained breathing apparatus with a full-face mask, impervious fully-encapsulated and chemically inert clothing, should be worn.

After collecting as much as possible into containers, the remaining traces of DBNPA should be flushed to drain with copious amounts of water. A safer practice would be to spread dry Sodium carbonate solution over the traces of DBNPA and then flush to drain with copious amounts of water. Protect the DBNPA from contamination by materials which can cause decomposition. Do not discard DBNPA spill material in the conventional manner. Consult with the local authorities for disposal of DBNPA spill material in an authorized disposal facility.

If a small amount of DBNPA begins to decompose for any reason, the immediate area of 20 meters (60 feet) should be isolated. If a large amount of DBNPA begins to decompose, a distance of 50 meters (150 feet) around the area, should be immediately evacuated.

Further evacuation decisions should be based on the size of the spill, wind intensity, height of the release above the ground, and the relative health level of the people in the area. All non-essential personnel should be kept out of the area. Used, empty receptacles can be rinsed with copious amounts of water and disposed of in the conventional manner.

62 EDITION 2, 2016

5.7 EMERGENCY REPAIRSEmpty, clean, dry, covered receptacles (overpacks) should be available for leaking DBNPA drums and for collecting spilled DBNPA or contaminated absorbent materials. It is difficult to define the protective clothing required for the protection of rescue, fire and emergency repair teams, who have to enter a DBNPA spill area, because of the variety of conditions which can be encountered.

The following points are indicative of the precautions to be taken under various levels of exposure. Dust masks, goggles, gloves and full body covering clothing should be worn when handling a DBNPA spill which is not decomposing. If the DBNPA spill material is decomposing, enter the spill area, only with a self-contained breathing apparatus. This equipment is for limited time depending on the cylinder size and pressure. One apparatus should be provided for each emergency worker who will be expected to enter the danger zone. Two spare cylinders should be provided for each apparatus. This should be sufficient equipment for the initial response.

Encapsulated, chemically inert and impervious clothing will prevent DBNPA from causing chemical burns. Not all protective clothing is suitable for fire-fighting.

EMERGENCY RESPONSE


5.8 EXPOSURE TO DBNPAWhen a person who has been exposed to DBNPA is sent to a hospital, information should be pinned to the person’s clothing stating that he was exposed to DBNPA. If possible, the MSDS should be sent with the patient.

Acute exposure:Ocular CorrosiveDermal IrritantSensitization: May cause skin sensitizationInhalation: In severe cases pulmonary oedema may develop Irritant to upper

respiratory tractIngestion: Corrosive by ingestion. Abdominal pain, nausea, vomiting and diarrhea

First AidEye contact: Holding the eyelids apart, flush eyes promptly with copious flowing

water for at least 20 minutes. Get medical attention immediately.Skin contact: Remove contaminated clothing. Wash skin thoroughly with mild soap

and plenty of water for at least 15 minutes. Wash clothing before re-use. Get medical attention if irritation persists.

Inhalation: In case of dust inhalation or breathing fumes released from heated material, remove person to fresh air. Keep him quiet and warm. Apply artificial respiration if necessary and get medical attention immediately.

Ingestion: If swallowed, wash mouth thoroughly with plenty of water and give water to drink. Get medical attention immediately.

NOTE: Never give an unconscious person anything to drink!.

Notes to the physician: Corrosive to eyes

In case of ingestion DO NOT induce vomiting. No specific antidote.Treat symptomatically and supportively.

6. OPERATORS GUIDE

6.1 OPERATOR HEALTH MONITORING .................................................. 67

6.2 OPERATOR/DRIVER SAFETY TRAINING ............................................ 69

OPERATORS GUIDE


6.1 OPERATOR HEALTH MONITORING

Workers regularly exposed to DBNPA should be given routine medical check-ups.

This applies to personnel of operations where DBNPA is used, stored, filled, or unloaded.(US Code of Federal Regulations, 29 CFR 1910.120 (f))

There are no regulations or standards indicating a medical test, which would show an overexposure to DBNPA.

It is recommended that complete medical records be kept for each person working in a facility where there is potential exposure to DBNPA vapors.

A sample medical record is provided on the following page.

68 EDITION 2, 2016

MEDICAL RECORD FOR EMPLOYEE EXPOSED

Name: Date of birth:

Address:

Occupation: Date start employment:

Previous history of following disorders Yes / No

(Provide details if necessary)

Skin diseases

Lung diseases

Liver diseases

Kidney diseases

Psychiatric

Neurologic

MEDICAL EXAMINATIONS

Date Test Remarks

SICK LEAVE

From To Reasons

OPERATORS GUIDE


6.2 OPERATOR / DRIVER SAFETY TRAINING

The installation management should be aware of the potential dangers of DBNPA. Management personnel should undergo training in DBNPA specific safety inspections and safety auditing.

Workers involved with DBNPA must have special safety training regarding the precautions to observe in accordance with local regulations. This applies to personnel of operations where DBNPA is used, stored, filled or unloaded.

The safety training for handling DBNPA has to include both theoretical classroom courses and practical hands-on and observation exercises, appropriate to the level of likely exposure of the individual worker to DBNPA.

Records should be kept of each person’s participation in initial training and refresher courses.

The theoretical classroom training should be at least one day.Some of the subjects to be covered should be:• The main types of hazards• Packaging details• Labelling and marking to indicate hazards• Precautions during loading and unloading• Environmental protection• First-aid• Fire-fighting• Selection and use of personal protection equipment• Respiratory protection• Emergency procedures

Refresher training courses should be taken regularly, at least every two or three years, and should include new technical and substance-related developments.The refresher course should be for at least one full day.

70 EDITION 2, 2016

EMPLOYEE SAFETY TRAINING RECORD

Name: Date of birth:

Address:

Occupation: Date start employment:

Education:

Period Institute name Place CertificateHigh SchoolTechnical SchoolUniversityPost GraduateOther

“Company organized” courses:

Course Name Institute name Period Certificate

APPENDIX

A. TYPICAL SPECIFICATIONS .................................................................. 73

B. REFERENCES ........................................................................................ 74


APPENDIX A:

Typical Quality Specifications

DPNPA Technical gradeAppearance White to off- white powderAssay (as DBNPA) % 98 minLoss on drying % 0.5 max

DBNPA GranulateAppearance White to off- white granulesAssay (as DBNPA) % 98 minLoss on drying % 0.5 max

DBNPA Solution 20% in solvent DPGAppearance clear, yellow solutionAssay (as DBNPA) % 20.0 - 23.0Specific gravity 20/20 1.16 - 1.21Viscosity cP at 200c 45

DBNPA Solution 20% in solvent PEGAppearance clear solutionAssay (as DBNPA) % 20.0 minTurbidity, NTU 3.0 maxpH at 25 deg C 2.0 - 6.7Specific gravity 1.216 - 1.300

74 EDITION 2, 2016

APPENDIX B:

REFERENCES

1. ICL-IP DBNPA PRODUCT DATA SHEET (www.icl-ip.com)2. ICL Industrial Products MATERIAL SAFETY DATA SHEET for DBNPA (www.icl-ip.com)3. UNITED NATIONS TRANSPORT OF DANGEROUS GOODS (ORANGE BOOK) Fifteenth Revised Edition, 20074. INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE, 2008 Edition (www.imo.org)5. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF

DANGEROUS GOODS BY ROAD (ADR), 2009 Edition (Restructured) (www.unece.org/trans/danger/danger.htm)6. US CODE OF FEDERAL REGUALTIONS (Issued annually) TITLE 29 - Occupational Safety and Health Administration (OSHA), 2008 TITLE 49 - Department of Transportation (DOT), 2008 (www.access.gpo.gov/nara/cfr/index.html)7. International Air Transportation Association DANGEROUS GOODS REGULATIONS 42nd Edition, January 2010 (www.iata.org)8. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) THRESHOLD LIMIT VALUES, 2009 (www.acgih.org)9. US DEPARTMENT OF TRANSPORTATION EMERGENCY RESPONSE GUIDE BOOK 2008 (http://www.phmsa.dot.gov/hazmat/library/erg)10. National Institute for Occupational Safety and Health (NIOSH) POCKET GUIDE TO CHEMICAL HAZARDS, 2005 Edition (http://www.cdc.gov/niosh/npg/)11. Z. E. Jolles, 1966 BROMINE AND ITS COMPOUNDS

Note: The internet websites are given for reference only, as their contents are continually changing.

Head OfficeICL-IP Makleff House, 12 Kroitzer st.P.O.Box 180Beer Sheva 8410101, IsraelTel: + 972 8 629 7608 Fax: + 972 8 629 7846E-mail: [email protected]

EuropeICL-IP Europe BVPrinsenhof BuildingKoningin Wilhelminaplein 301062 KR, AmsterdamThe Netherlands, NLE-mail: [email protected]

North America and MexicoICL-IP America INC622 Emerson Road, Suite 500St. Louis, Missouri 63141, USATel: + 1 877 661 4272Fax: + 1 314 983 7610E-mail: [email protected]

South AmericaICL BrasilRua George Ohm, 230Torre B, 20° andar BrooklinSão Paulo SP, Brasil 04576020Tel: + 55 11 2155 4500 Fax: +55 11 2155 4507E-mail: [email protected]

Asia PacificICL ChinaRoom 908, Times Square OfficeTower, No. 93Middle Huai Hai RoadShanghai 200021, ChinaTel: + 86 21 2315 7500Fax: + 86 21 5386 3336E-mail: [email protected]

JapanICL JAPAN LtdSumitomo Fudosan Iidabashi Building, 5th fl.,2-3-21, Koraku, Bunkyo-ku,Tokyo, 112-0004, JapanTel: +81 3 6801 8430Fax: +81 3 6801 6970E-mail: [email protected]

Other Asia PacificICL Asia Ltd.Room 2301, 23/F,Allied Kajima Building, 138 Gloucester RoadWanchai, Hong KongTel: + 852 2827 7761Fax: + 852 2824 1502E-mail: [email protected]

July 2016

www.icl-ip.com

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BIOBROM (DBNPA)...Whether you are a manufacturer, transporter, distributor or end user, we hope that the information contained in this Safety Handbook will prove useful in your handling