SINGHANIA UNIVERSITY

CURRICULUM AND SYLLABUS

B.Tech In Chemical Engg

CODE SUBJECT TEACHING SCHEME EXAMINATION SCHEME Lect. Tut. Pract./

Drg. Paper TW Oral Pr Total

Programming languages. 1 - 2 - - - 50** 050

Environmental Engineering 3 - 2 100 25 - - 125

Total of Part – I 18 - 12 500 150 - - 650

CODE SUBJECT TEACHING SCHEME EXAMINATION SCHEME Lect. Tut. Pract./

Drg. Paper TW Oral Pr Total

Semester-I

Semester-II

Total of Part – II 18 - 12 500 150 - - 650

BCE-101 Engineering Mathematics-I 4 - - 100 - - - 100 BCE-102 Applied Science – I 4 - 2 100 25 - - 125 BCE-103 Fundamentals of

BCE-104 Basic Electrical Engineering 3 - 2 100 25 - - 125 BCE-105 Basic Civil and

BCE-106 Engineering Graphics – I 3 - 2 100 - - - 100 BCE-107 Manufacturing Practices - - 2 - 25 - - 025

BCE-201 Engineering Mathematics-II 4 - - 100 - - - 100 BCE-202 Applied Science – II 4 - 2 100 25 - - 125 BCE-203 Engineering Mechanics 3 - 2 100 25 - - 125 BCE-204 Basic Electronics Engineering 3 - 2 100 25 - - 125 BCE-205 Engineering Graphics – II 1 - 2 - 50 - - 050 BCE-206 Basic Mechanical Engineering 3 - 2 100 25 - - 125 Communication Skill * - - 2 - - - - -

Semester I (Engineering Mathematics-I)

Unit 1 Matrices: Rank, Normal form, System of Linear Equations, Linear Dependence and Independence, Linear and Orthogonal Transformations. Eigen values, Eigen Vectors, Cayley – Hamilton Theorem. Application to problems in Engineering (Translation and Rotation of Matrix). Unit 2 Complex Numbers & Applications: Argand’s Diagram, De'Moivre's theorem and its application to find roots of algebraic equations. Hyperbolic Functions, Inverse Hyperbolic Functions, Logarithm of Complex Numbers, Separation into Real and Imaginary parts, Application to problems in Engineering. Unit 3 Infinite Series: Infinite Sequences, Infinite Series, Alternating Series, Tests for Convergence, Absolute and Conditional Convergence, Range of Convergence. Differential Calculus: Successive Differentiation, Leibnitz Theorem. Unit 4 Expansion of Functions: Taylor's Series and Maclaurin's Series. Differential Calculus: Indeterminate Forms, L' Hospital's Rule, Evaluation of Limits. Unit 5 Partial Differentiation and Applications: Partial Derivatives, Euler's Theorem on Homogeneous Functions, Implicit functions, Total Derivatives, Change of Independent Variables. Unit 6 Jacobian: Jacobians and their applications. Errors and Approximations. Maxima and Minima: Maxima and Minima of Functions of two variables, Lagrange's method of undetermined multipliers. Text Books: Higher Engineering Mathematics by B.V. Ramana (Tata McGraw-Hill). Advanced Engineering Mathematics by Erwin Kreyszig (Wiley Eastern Ltd.). Reference Books: Advanced Engineering Mathematics, 7e, by Peter V. O'Neil (Thomson Learning). Advanced Engineering Mathematics, 2e, by M. D. Greenberg (Pearson Education). Higher Engineering Mathematics by B. S. Grewal (Khanna Publication, Delhi). Applied Mathematics (Volumes I and II) by P. N. Wartikar & J. N. Wartikar (Pune Vidyarthi Griha Prakashan, Pune).

Both schemes are exactly half for Chemistry and Physics each Chemistry

Semester I (Applied Science – I)

Unit 1 : Solid state and materials chemistry Crystallography:- Unit cell, Bravais lattices, Cubic crystals - CN, APF, radius ratio. Three laws of crystallography, Weiss indices and Miller indices with numericals, X-ray diffraction – Bragg’s Law and numericals. Crystal defects (point and line defects) and their effects on properties of crystals. Zinc sulphide – structure and applications as luminescent. Molecular electronics:-Basic concepts. Study of following molecules for their structures and properties on the basis of orbitals, chemical bonding, band theory, electrical conductivity, applications in electronics such as in diodes, transistors, ICs, photovoltaic devices, sensors etc. 1.Conductive polymers-polypyrrole, polythiophene 2.Pure carbon compounds- graphite, single wall and chiral carbon nano-tubes, fullerenes 3. Liquid crystals 4.Charge transfer compounds-tetrathiofulvalene.

Unit 2 : Volumetric analysis Standard solutions and their preparations, various ways of expressing concentrations of solutions, equivalent weights in different types of reactions. Volumetric analysis – acid-base, complexometric, oxidation-reduction, precipitation – with specific examples, theories of indicators used in above titrations, titration curve (acid-base only) numericals on all above. Unit 3 : Polymers

Definition and important terms: Monomer, Polymer, Polymerization, Degree of polymerization (Dp), Glass transition temperature (Tg), Molecular weight, Polymer dissolution. Classification on the basis of - a) Polymerization mechanism – (step and chain polymers , brief mechanism should be explained), b) Polymerization reactions – (addition and condensation), c)Thermal behaviour–(thermoplastics and thermosetting), d)Types of monomers– (homopolymer and copolymer). Commercial Polymers–Synthesis, properties and applications- Polyethylene (PE), Polypropylene (PP), Polyvinyl chloride (PVC), Polystyrene (PS), Phenol formaldehyde (PF), Acrylonitrile butadiene styrene (ABS), Epoxy resin . Compounding of Plastics. Rubbers-Synthesis, structure, properties and applications of a) Natural rubber–isolation, Polyisoprene. b) Vulcanized rubber-Valcanisation of rubber by sulfur. c) Synthetic rubber-Styrene – Butadiene rubber, Silicon rubber and Neoprene rubber. Speciality polymers –Basic concepts and applications of conductive, liquid crystalline, thermally stable and biodegradable polymers. Polymer composites, Recycling of polymers. Term work : Any four experiments 1. To standardize KMnO4 solution by preparing standard oxalic acid and to estimate ferrous ions. 2. To standardize Na2S2O3 solution by preparing standard potassium dichromate and to estimate percentage of copper from brass. 3. To determine phenol by iodometric method. 4. To determine molecular weight of a polymer using Ostwald viscometer. 5. Preparation of (any one ) polystyrene, urea formaldehyde, phenol formaldehyde and its characterization. 6. To determine chloride ions from solution by Volhard method. 7. To determine calcium from the given sample of cement by volumetric method. Term work is based on performance and regular checking of the experiments. Reference Books : 1.Chemistry, Raymond Chang. (Tata McGraw Hill). 2.Principles of the solid state, H.V. Keer (New age international publishers). 3.Polymer Science, V.R. Gowarikar (Wiley Eastern Ltd.). 4. Inorganic quantitative analysis, Vogel. (Prentice Hall). 5. Text book of engineering chemistry, R.N. Goyal and Harrmendra Goel, (Ane books India). Laboratory Manual : 1. Laboratory Manual on Engineering Chemistry, Sudharani (Dhanpat Rai Publishing Company).

Physics

Unit 4 : Interference and electron Optics Interference:- Interference of waves, Interference due to thin films of uniform (with derivation) and non-uniform thickness (without derivation), Fringe width, Newton’s Rings, Applications of Newton’s Rings for determination of (i) wavelength of incident light / radius of curvature of Plano convex lens (ii) refractive index of a given liquid; Michelson’s interferometer, applications for determination of (i) wavelength of a monochromatic source (ii) refractive index /thickness of a transparent material; Engineering applications of interference (i) Testing of optical flatness of surfaces (ii) Nonreflecting / Antireflection coatings. Electron Optics :- Motion of an electron in electric (parallel, perpendicular) and magnetic (extensive, limited) fields, crossed fields. Electrostatic and magneto static focusing, Scanning electron microscope (SEM) , Bainbridge mass spectrograph. Unit 5 : Diffraction and ultrasonic Diffraction : - Diffraction of waves, classes of diffraction, Fraunhoffer diffraction at a single slit (geometrical method), conditions for maxima and minima, Intensity pattern due to a single slit, Plane diffraction grating, conditions for principal maxima and minima, intensity pattern; Resolving power, Resolving power of a grating. Ultrasonics :- Ultrasonic waves, Piezo-electric effect, Production of ultrasonic waves by Piezoelectric oscillator, Magnetostrictive effect, Production of ultrasonic waves by magnetostrictive oscillator, properties of ultrasonic waves, Applications of ultrasonic waves (i) Scientific- Echo sounding, Sound signaling, depth sounding, SONAR, cleaning of dirt etc (ii) Engineering –thickness measurement, cavitation, Ultrasonic cleaning, Nondestructive testing, Flaw detection, Soldering, Drilling and welding (iii) Medical- for diagnostics and treatment Note: Discuss any one application for 4 marks Unit 6: Polarisation and nuclear physics Polarisation :- Introduction, production of plane polarised light by refraction (pile of plates), Law of Malus, Double refraction, Huygen’s theory of double refraction, Cases of double refraction of crystal cut with the optic axis lying in the plane of incidence and (i) parallel to the surface (ii) perpendicular to the surface (iii) inclined to the surface, Retardation plates-quarter wave plate (QWP), Half wave plate (HWP); Analytical treatment of light for the production of circularly and elliptically polarised light, Detection of various types of light (PPL, CPL, EPL, Upl, Par PL), Optical activity, Specific rotation, Polaroids Nuclear Physics :- Nuclear fission in natural Uranium-Chain reaction, Critical size. Nuclear fuels, Nuclear fusion, and thermonuclear reactions-P-P and CN cycles, Particle accelerators-cyclotron, betatron. Reference Books: 1.Optics, Jenkins and White (Tata Mcgraw Hill) 2.Text Book of Optics, Brijlal and Subramanyam (S. Chand and Company) 3.University Physics, Young and Freedman (Pearson Education). 4.Fundamentals of Physics, Resnick and Halliday (John Wiley and Sons). 5. Concepts of Modern Physics-Beiser (Tata Mcgraw Hill) Term Work: Any Four experiments 1.Determination of wavelength by using diffraction grating. 2.Newton’s Rings (Determination of wavelength/radius of curvature /refractive index of a liquid). 3.Experiment on ultrasonic waves. 4.Resolving Power of a telescope / grating. 5.Determination of specific rotation by Laurent’s half shade polarimeter. 6.Demonstration of Lissajous figures (principles of interference and polarisation) using a CRO, phase measurement. 7.Michelson’s interferometer 8. Determination of e/m by Thomson’s method. 9.An experiment on polarization. (Determination of polarising angle for glass and to determine refractive index of glass using Brewster’s law Or Experimental verification of law of Malus). 10.Determination of wavelength of the given source by Fraunhoffer diffraction at a single slit. Term work is based on performance and regular checking of the experiments.

• To learn and acquire art of computer programming • To know about some popular programming languages and how to choose a programming

language for solving a problem using a computer • To learn to program in C

1. Program Planning Concepts

Algorithm; Advantages of Generalized Algorithms; How to Make Algorithms Generalized; Avoiding Infinite Loops in Algorithms – By Counting, By using a Sentinel Value; Different ways of Representing an Algorithm – As a Program, As a Flowchart, As a Pseudo code; Need for Planning a Program before Coding; Program Planning Tools – Flowcharts, Structure charts, Pseudo codes; Importance of use of Indentation in Programming; Structured Programming Concepts – Need for Careful Use of “Go to” statements, How all programs can be written using Sequence Logic, Selection Logic and Iteration (or looping) Logic, functions. 2. Programming Languages

What is a Programming Language; Types of Programming Languages – Machine-level, Assembly-level and High-level Languages, Scripting Languages, Natural Languages; Their relative Advantages and Limitations; High-level Programming Language Tools – Compiler, Linker, Interpreter, Intermediate Language Compiler and Interpreter, Editor, Matlab, GUI ; Overview of some popular High-level Languages – FORTRAN, COBOL, BASIC, Pascal, C, C++, JAVA, LISP; Characteristics of a Good Programming Language; Selecting a Language out of many Available Languages for Coding an Application; Subprograms. 3. Program Testing and Debugging

Definition of Testing & Debugging; Difference between Testing and Debugging; Types of Program Errors; Testing a Program; Debugging a Program for Syntax Errors; Debugging a Program for Logic Errors, Concept of APIs/Libraries. 4. Program Documentation

What is Documentation; Need for Documenting Programs and Software; Forms of Documentation – Comments, System Manual, User Manual; Documentation Standards and Notations. 5. Programming in C Language

Character set, Constants, Variables, Keywords and Comments; Operators and Operator Precedence; Statements; I/O Operations; Preprocessor Directives; Pointers, Arrays and Strings; User Defined Data Types – Structure and Union; Control Structures – Conditional and Unconditional Branching Using “if”, “switch”, “break”, “continue”, “go to” and “return” Statements; Loop Structures – Creating Pretest Loops using “for” and “while” Statements; Creating Posttest Loops using “do…while” statement; Functions – Creating Subprograms using Functions; Parameter Passing by Value; Parameter Passing by Reference; Main Function.

Objectives

Semester I (Fundamentals of Programming

Languages)

Semester I (BASIC ELECTRICAL ENGINEERING)

SECTION – I Unit 1.General: Concepts of emf., p.d. and current, resistance, effect of temperature on resistance. resistance temperature coefficient, insulation resistance. S.I. units of work, power and energy. Conversion of energy from one form to another in electrical, mechanical and thermal systems. batteries and cells, their types, primary cells and secondary cells, Lead Acid, Ni-Cd and Ni-MH batteries, current capacity and cell ratings. charging , importance of initial charging and discharging of batteries. series and parallel battery connections, maintenance procedure. Unit 2. D.C.Circuits: Classification of electrical networks, Ohm's law, Kirchhoff’s law and their applications for network solutions. Simplifications of networks using series and parallel combinations and star-delta conversions, Superposition theorem, Thevenin’s theorem and maximum power transfer theorem. Unit 3.Electromagnetism: Magnetic effect of an electric current, cross and dot conventions, right hand thumb rule and cork screw rule, nature of magnetic field of long straight conductor, solenoid and toroid. concept of m.m.f., flux, flux density, reluctance, permeability and field strength, their units and relationships. simple series and parallel magnetic circuits, comparison of electrical and magnetic circuit, force on current carrying conductors placed in magnetic field, Fleming’s left hand rule. Faradays laws of electromagnetic induction, statically and dynamically induced e.m.f., self and mutual inductance, coefficient of couplings. energy stored in magnetic field.

B) Single phase transformers: Construction, principle of working, e.m.f. equation, voltageand current

Term work: The term work shall consist of record of minimum eight exercises and experiments, out of which Group A is compulsory and any five experiments from Group B should be conducted. Group A 1. Wiring Exercises: a) Study of various wiring components (wires, switches, fuse, sockets, plugs, lamp holders, lamps etc. their uses and ratings). b) Control of two lamps from two switches (looping system). c) Staircase wiring. d) Use of Megger for insulation test and continuity test of wiring installations and machines. 2. a) Study of fluorescent tube circuit. b) Study of compact fluorescent lamp(CFL). c) Study of HID lamps such as mercury vapour lamp /sodium vapour lamp. 3. a)Study of safety precautions while working on electric installations and necessity of earthing. b) Introduction to energy conservation and simple techniques to achieve it.

SECTION – II Unit 4. Electrostatics and AC fundamentals: A) Electrostatics field, electric flux density, electric field strength, absolute permittivity, relative permittivity, capacitance and capacitor, composite dielectric capacitors, capacitors in series and parallel, energy stored in capacitors, charging and discharging of capacitors and time constant. B) Sinusoidal voltages and currents, their mathematical and graphical representation, Concept of instantaneous, peak(maximum), average and r.m.s. values, frequency , cycle, period, peak factor and form factor, phase difference ,lagging, leading and in phase quantities and phasor representation. rectangular and polar representation of phasors. Unit 5. Single phase A.C. Circuits: Study of A.C. circuits consisting of pure resistance, pure inductance, pure capacitance and corresponding voltage-current phasor diagrams and waveforms. Development of concept of reactance, study of series R-L, R-C, R-L-C circuit and resonance, study of parallel R-L, R-C and R-L-C circuit, concept of impedance , admittance, conductance and susceptance in case of above combinations and relevant voltage-current phasor diagrams, concept of active, reactive and apparent power and power factor. Unit 6. Polyphase A.C.Circuits and Single phase Transformers:

A) Polyphase A.C.Circuits: Concept of three-phase supply and phase sequence. voltages, currents and power relations in three phase balanced star-connected loads and delta-connected loads along with phasor diagrams.

ratios. losses, definition of regulation and efficiency, determination of these by direct loading method. descriptive treatment of autotransformers and dimmerstats.

Group B 4. Determination of temperature rise of medium resistance such as shunt field winding. 5 .Verification of Kirchhoff’s laws and Superposition theorem. 6. Verification of Thevenin’s theorem. 7. Study of R. L. C. series circuits. 8. Verification of current relations in three phase balanced star and delta connected loads. 9. Single phase transformer a)Voltage and current ratios. b) Efficiency and regulations by direct loading. Note: College should provide printed text and figures for Group A experiments and only printed text for Group B experiments. Text Books :

1. A Textbook of Electrical Technology Volume- I – B.L.Theraja, S.Chand and Company Ltd., 2. New Delhi. 3. Basic Electrical Engineering, V.K.Mehta, S.Chand and Company Ltd., New Delhi. 4. Electrical Engineering- G.K.Mittal 5. Theory and problems of Basic Electrical Engineering- I.J.Nagrath and Kothari,

Prentice-Hall of India Pvt. Ltd. Reference Books :

1. Electrical Technolgy- Edward Hughes, Seventh Edition, Pearson Education 2. Elements of Electrical Technology- H.Cotton, C.B.S. Publications 3. Basic circuits analysis by John Omalley Shawn Mc Graw Hill. 4 Principles of Electrical Engineering by Del. Toro, PH

a) Role of Civil Engineer in the construction of buildings, dams, expressways and infrastructure projects for 21st century. Importance of an interdisciplinary approach in engineering.

b) Basic Areas in Civil Engineering Surveying, Construction Engineering, Project Management, Transportation Engineering, Fluid Mechanics, Irrigation Engineering, Structural Engineering, Geotechnical and Foundation Engineering, Environmental Engineering, Quantity Surveying, Earthquake Engineering, Infrastructure Development, Town Planning, Remote Sensing.

Tor and High Tensile Steel. Concrete types - PCC, RCC Prestressed and Precast. Introduction to smart materials. Recycling of materials.

b) Substructure-Function of Foundations, (Only concepts of settlement and Bearing capacity of soils.) Types of shallow foundations, (only concept of friction and end bearing pile).

c) Superstructure - Types of loads :- DL and LL, wind loads, earthquake considerations. Types of Construction-Load Bearing, Framed, Composite. Fundamental requirements of masonary.

d) Introduction to automation in construction:- Concept, need, examples related to different civil engineering projects.

a) Various types of maps and their uses. Principles of survey. Modern survey methods using levels, Theodolite, EDM, lasers, total station and GPS.

Introduction to digital mapping. Measuring areas from maps using digital planimeter. b) Conducting simple and differential levelling for setting out various benchmarks, determining

the elevations of different points and preparation of contour maps. Introduction to GIS Software and other surveying softwares with respect to their capabilities and application areas.

Semester I (Basic Civil and Environmental Engineering)

Section I Unit 1: Introduction to Civil Engineering

Unit 2: Materials and Construction a) Use of basic materials cement, bricks, stone, natural and artificial sand, Reinforcing Steel-Mild,

Unit 3: Uses of maps and field surveys

a) Concept of Environment - biotic and abiotic factors. Concept of the ecological cycle. Impact of the human behaviour and the technological advancements on the environment. Need for conserving natural resources and preserving the environment. Engineer's role in achieving sustainable development. Environmental Impact Assessment (EIA).

a) Concept of an integrated built environment-natural and manmade. Principles of planning, viz. Aspect, Prospect, Roominess, Grouping, Privacy, Circulation, Sanitation, Orientation, Economy. Role of by-laws in regulating the environment.

energies to meet the increased demand. Methods of harnessing energies. b) Sources, causes, effects and remedial measures associated with 1. Air Pollution

2.Water treatment :- Objective, drinking water standards, pollution,introduction to waste water treatment. 3. Noise Pollution 4. Land Pollution

Term Work: Any 8 Practical Exercises from those given below should be carried out, record to be submitted in the field book and file which will form a part of termwork.

1. Study of any 4 types of maps and writing their uses. 2. Exercise on use of dumpy level and laser level. 3. Measurement of area of irregular figures by digital planimeter. 4. Drawing of plan elevation & section for a residential building, single storeyed

framed/load bearing structure. Preparing schedule of openings [On half imperial sheet.] 5. Determination of coordinates of a traverse using Global Positioning system (GPS) 6. Measurement of distance by EDM and comparing it with the distance measured using

tape. 7. Visit to a construction site for studying the various construction materials used, type of

structure, type of foundation and components of superstructure – submission of visit report.

8. Demonstration of use of any 4 Civil Engineering softwares. 9. Making a poster (Full imperial sheet size) in a group of 4 students, related to

Energy/Environment. 10. Presentation in a group of 4 students, any case study related to Energy/Environment.

TEXT BOOKS:

1. Surveying and Levelling --- Kanetkar and Kulkarni, PVG Prakashana 2. Environmental Studies D.L.Manjunath – Pearson Education. 3. Building Construction --- Bindra Arora; Dhanpat Rai publication. 4. Text book of Environmental Studies-Erach Bharucha-UGC, Universities Press.

Section II Unit 4: Ecology and Eco System

b) Introduction to solid waste management, Disposal of electronic wastes. Unit 5 :Planning for the Built Environment

b) Use of various eco-friendly materials in construction. Concept of green buildings. Unit 6: Energy and Environmental Pollution a) Types of energy:- conventional and non-conventional. Need for harnessing alternative

SECTION – I

Semester I (Engineering Graphics – I)

UNIT – I Drafting Technology and Introduction to Any Drafting Software/Package Layout of drawing sheets, sizes of drawing sheets, different types of lines used in drawing practice, Dimensioning – linear, angular, aligned system, unidirectional system, parallel dimensioning, chain dimensioning, location dimension and size dimension. Tolerances – methods of representing tolerances, unilateral and bilateral tolerances, tolerance on linear and angular dimensions, geometrical tolerances. Symbols used on drawing, surface finish symbols, welding symbols. Advantages of using Computer Aided Drafting (CAD) packages, applications of CAD, basic operation of drafting packages, use of various commands for drawing, dimensioning, editing, modifying, saving and printing/plotting the drawings. Introduction to 3D primitives. UNIT – II Curves used in Engineering Practice Ellipse, Parabola, Hyperbola, normal and tangents to these curves, Involute, Cycloid, Epi-cycloid, Hypo-cycloid, Archimedean Spiral, Helix on cone and cylinder. UNIT – III Orthographic Projections Reference planes, types of orthographic projections – First angle projections, Third angle projections, methods of obtaining orthographic views by First angle method, Sectional orthographic projections – full section, half section, offset section. UNIT – IV Auxiliary Projections Auxiliary planes – Auxiliary Vertical Plane (AVP), Auxiliary Inclined Plane (AIP), symmetrical auxiliary view, unilateral auxiliary view, bilateral auxiliary view.

SECTION – II UNIT – V Isometric Projections Isometric view, Isometric scale to draw Isometric projection, Non-Isometric lines, construction of Isometric view from given orthographic views and to construct Isometric view of a Pyramid, Cone, Sphere. UNIT – VI Interpretation of Given Views/Missing Views Identification of lines/edges and surfaces, visualization of given orthographic views, adding a missing/third view, adding a sectional view, to convert a given view in to a sectional view. UNIT – VII Freehand Sketching Free hand sketching -- FV and TV of standard machine parts – Hexagonal headed nut and bolt, foundation bolts, shafts, keys, couplings, springs, screw thread forms, welded joints, riveted joints.

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Semester II (Engineering Mathematics – II)

Unit 1 Differential Equations (DE): Definition, Order and Degree of DE, Formation of DE. Solutions of Variable Separable DE, Exact DE, Linear DE and reducible to these types Unit 2 Application of DE: Applications of DE to Orthogonal Trajectories, Newton's Law of Cooling, Kirchoff’s Law of Electrical Circuits, Motion under Gravity, Rectilinear Motion, Simple Harmonic Motion, One–Dimensional Conduction of Heat, Chemical problems Unit 3 Fourier Series: Definition, Dirichlet's conditions, Full Range Fourier Series, Half Range Fourier Series, Harmonic Analysis and Applications to Problems in Engineering. Integral Calculus: Reduction formulae, Beta and Gamma functions. Unit 4 Integral Calculus: Differentiation Under the Integral Sign, Error functions. Curve Tracing: Tracing of Curves, Cartesian, Polar and Parametric Curves. Rectification of Curves Unit 5 Solid Geometry: Cartesian, Spherical Polar and Cylindrical Coordinate Systems. Sphere, Cone and Cylinder Unit 6 Multiple Integrals and their Applications: Double and Triple integrations, Applications to Area, Volume, Mean and Root Mean Square Values, Mass, Center of Gravity and Moment of Inertia. Text Books: Advanced Engineering Mathematics, 7e, by Peter V. O'Neil (Thomson Learning). Higher Engineering Mathematics by B. S. Grewal (Khanna Publication, Delhi). Reference Books: Advanced Engineering Mathematics by Erwin Kreyszig (Wiley Eastern Ltd.). Advanced Engineering Mathematics, Wylie C.R. & Barrett L.C. (McGraw-Hill, Inc.) Higher Engineering Mathematics by B.V. Ramana (Tata McGraw-Hill). Advanced Engineering Mathematics, 2e, by M. D. Greenberg (Pearson Education).

Both schemes are exactly half for Chemistry and Physics each Chemistry

Semester II (Applied Science – II)

Unit 3 : Water and phase rule Water :- Chemical analysis of water-hardness, chloride content, alkalinity- numericals. Ill effect of hard water in steam generation, preventive measures. Softening of water by zeolite-with numericals and ion-exchange process. Phase rule :- Gibb’s Phase rule and the terms involved in it with examples. One component system – Water and Sulphur. Reduced phase rule. Applications and limitations of phase rule. Term Work: Any four experiments 1. To determine total alkalinity of water sample. 2. To determine chloride content of water sample by Mohr’s method. 3. To determine temporary and permanent hardness of water sample by EDTA method. 4. Spectrophotometric / colorimetric estimation of Fe++ from the given solution. 5. To construct a phase diagram for a binary system, naphthalene and benzoic acid and find eutectic point. 6. Study of corrosion of metals in medium of different pH. 7. Analysis of mixture of phosphoric acid and hydrochloric acid using indicators and pH meter separately. 8. To determine moisture, volatile matter and ash content of a given sample of coal. Term work is based on performance and regular checking of the experiments. Reference books : 1.Materials science and engineering an introduction, William D. Callister, (Jr.,Wiley. publisher) 2. Principles of the solid state, H.V. Keer, (New age international publishers). 3. Text book of engineering chemistry, R.N. Goyal and Harrmendra Goel, (Ane books India). 4. Text book of Physical chemistry, Samuel Glasstone (Mcmiillon and Co. Ltd.) Laboratory manual 1. Laboratory manual on Engineering Chemistry, Sudharani (Dhanpat Rai publishing company) 2. Applied Chemistry theory and practical O.P. Virmani and A.K. Narular (New Age International publishers).

Unit 2 : Corrosion and its prevention Corrosion:- Definition, atmospheric corrosion-mechanism, Wet corrosion-mechanism, Electrochemical and galvanic series, Factors affecting corrosion-nature of metal, nature of environment, Pourbaix diagram. Methods of prevention of corrosion-cathodic and anodic protection. Metallic coatings, Electroplating, Hot dipping, blacodizing, powder coating Surface conversion coating.

Unit 1 : Fuels and combustion Fuels : Definition, classification of fuels, calorific value and its units. Determination of calorific value – Bomb calorimeter, Boy’s colorimeter – numericals. Solid fuels : Coal, classification of coal, proximate and ultimate analysis of coal, numericals based on analysis of coal - Dulong and Goutel formula. types of carbonisation of coal-low temperature and high temperature carbonization. Liquid fuels : Origin of petroleum, composition of petroleum, refining of petroleum, octane number of petrol, cetane number of diesel, power alcohol, biodiesel. Gaseous fuels : Composition, properties and applications of natural gas, treatment products such as CNG, LPG, LNG. Hydrogen gas as a fuel, production, properties, storage and transportation. Rocket propellants-characteristics, classification. Combustion : Chemical reactions, calculation on air requirement for combustion – numericals

Unit 5 : Lasers and superconductivity Lasers :- Requirement for lasing action (stimulated emission, population inversion, pumping), Characteristics– monochromaticity, coherence, directionality, brightness. Various levels of laser systems with examples (i) Two level laser system- semiconductor laser (ii) Three level laser system- Ruby laser and He-Ne laser. Applications i)Communication systems-fiber optics in brief, ii)Information technology holography-construction, reproduction. Superconductivity :- Introduction to superconductivity, Properties of superconductors (zero resistance, Meissner effect, critical fields, persistent currents), isotope effect, BCS theory. Type I and type II Super conductors, Applications (super conducting magnets, transmission lines etc), DC and AC Josephson effect Unit 6: Semiconductor physics and physics of nano particles Semiconductor physics :- Band theory of solids, Classification of solids on the basis of band theory, Types of semiconductors, Introduction to the concept of electrical conductivity, conductivity of conductors and semiconductors. Hall effect and Hall coefficient, Fermi-Dirac probability distribution function, Position of Fermi level in intrinsic semiconductors (with derivation) and in extrinsic semiconductors (variation of Fermi level with temperature (without derivation)), Band structure of PN junction diode under zero bias, forward bias and reverse bias; Transistor working, PNP and NPN on the basis of band diagrams, Photovoltaic effect, working of a solar cell on the basis of band diagrams and Applications. Physics of Nanoparticles :- Introduction, Nanoparticles, Properties of nanoparticles (optical, electrical, magnetic, structural, mechanical), Brief description of different methods of synthesis of nanoparticles such as physical, chemical, biological, and mechanical. Synthesis of colloids. Growth of nanoparticles, Synthesis of metal nanoparticles by colloidal route, Applications of nanotechnology-electronics, energy, automobiles, space and defence, medical, environmental, textile, cosmetics.

Reference Books: 1.Principles of Physics, Serway and Jewett (Saunders college publishing) 2.Introduction to Solid State Physics, Kittel C (Wiley and Sons) 3.Laser and Non-Linear Optics, B.B.Laud (Oscar publication) 4.Physics of the Atom, Wehr and Richards (Addison, Wesley) 5.Nanotechnology, Principles and Practices, Dr.S.K.Kulkarni (Capital Publishing Company) Term Work: Any four experiments 1.Determination of band gap of a semiconductor. 2.Characteristics of a solar cell, calculation of fill factor, To plot power vs. resistance graph and hence to calculate value of R for maximum value of workable power. 3.Hall effect and determination of Hall coefficient. 4.Characteristics of photocell/photo diode. 5.Diode characteristics (Ge/Si, LED, Zener) 6. Synthesis of metal nanoparticles (gold/silver) by the chemical route. 7.Measurement of diameter of a thin wire using a laser. 8.To find refractive index of glass using a laser (using Snell’s law). ( may show demonstrations of polarisation and diffraction). 9. An experiment based on laser (e.g.: To find number of lines /cm of a given grating using a laser source/ to find beam divergence/true beam width ) 10.Determination of width of a slit using a laser. Term work is based on performance and regular checking of the experiments.

Physics Unit 4 : Wave particle duality and wave equations Wave Particle Duality :- Wave particle duality of radiation and matter, concept of group velocity and phase velocity; Uncertainty principle, Illustration of electron diffraction at a single slit. Wave Equations :- Concept of wave function and probability interpretation, Physical significance of the wave function, Schrodinger’s time independent and time dependent wave equations, Applications of Schrodinger’s time independent wave equations to problems of (i) Particle in a rigid box (infinite potential well), Comparison of predictions of classical mechanics with quantum mechanics (ii)Particle in a non-rigid box (finite Potential Well)- Qualitative (results only);

Term Work Term work consists of the following. a) Statics-(Any three experiments from the list below) 1. Verification of law of parallelogram of forces/ polygon of forces. 2. Support reaction of simple / compound beams. 3. Determination of coefficient friction of belt/inclined plane. 4. To determine forces in Space Force System. b) Dynamics- 1. Curvilinear motion.

Semester II (Engineering Mechanics)

Section-I (Statics) Unit 1. Resultant of coplanar force system. A. Principle of statics, Force systems, Resolution and composition of forces, Resultant of concurrent forces. B. Moment of a force, Couple, Varignon’s theorem, Equivalent force couple system, Resultant of parallel and general force system. Distributed forces, Centroid of plane lamina and wire bends. Unit 2. Equilibrium of Force system. A. Free body diagram, Equilibrium of concurrent, parallel and general forces in a plane, Equilibrium of three forces in a plane, Types of beams, simple and compound beams, type of supports and reaction. B. Resultant and Equilibrium of concurrent and parallel forces in a Space. Unit 3. Analysis of structure and friction. A. Two force member, Analysis of plane trusses by method of joint and method of section, cables subjected to point loads. Multi force member, Plane frames. B. Friction - Application of friction on inclined plane, wedges, ladders and flat belt.

Section-II (Dynamics) Unit 4. Rectilinear motion of particles. A. Kinematics- Basic concepts, Equations of motion for constant acceleration and motion under gravity, Variable acceleration, Motion curves, Relative motion and dependant motion. B. Kinetics- Newton’s second law of motion and its applications. Unit 5. Curvilinear motion of particles. A. Kinematics-Basic concepts, Equation of motion in cartesian, path and polar coordinate, Motion of projectile. B. Kinetics-Newton’s second law of motion. Motion in cartesian and path coordinate of a particle. Unit 6. Work energy and impulse momentum principle for particle. A. Work, Power, Energy, conservative forces & Potential Energy , Conservation of energy, Work energy principle for motion of particle. B. Linear Impulse & Momentum, Conservation of momentum, Direct central impact and coefficient of restitution, Impuse momentum principle.

2. Determination of coefficient of restitution. c) Exercise-At least two examples on each part of the units should be solved during practical hours under the guidance of the concerned teacher. d) Assignment- Minimum five numerical examples from each unit given by concerned teacher. Note: Examples in Exercise and Assignment should be unsolved problems from text and reference books prescribed in the syllabus.

Text book (latest editions) 1. Engineering Mechanics statics and dynamics by R. C. Hibbeler, McMillan Publication.

Reference books 1. Mechanics for Engineers - Statics Fourth Edition, by F. P. Beer and E. R. Johnson, McGraw-Hill Publication. 2. Mechanics for Engineers - Dynamics Fourth Edition, by F. P. Beer and E. R. Johnson, McGraw-Hill Publication. 3. Engineering Mechanics statics and dynamics by J. L. Meriam and Craige, John Willey and Son’s publication. 4. Engineering Mechanics by S. P. Timoshenko and D. H. Young, McGraw- Hill publication. 5. Engineering Mechanics by F L Singer, Harper and Rowe publication. 6. Engineering Mechanics by A. P. Boresi and R. J. Schmidt, Brooks/Cole Publication. 7. Engineering Mechanics by Shames I. H., P H I India.

Semester II (Basic Electronics Engineering)

NOTE – ONLY FIRST ANGLE METHOD OF PROJECTIONS IS TO BE USED IN ALL THE UNITS.

UNIT – I Projections of Point and Line Projections of points, projections of lines, lines inclined to one reference plane, lines inclined to both reference planes. (Lines in First Quadrant Only) Traces of lines, Distance between skew lines. UNIT – II Projections of Planes Projection of planes, angle between two planes, distance of a point from a given plane, inclination of the plane with HP and VP, True shape of a plane surface. UNIT – III Projections of Solids Projections of solids inclined to one reference plane, inclined to both the reference planes, projections of cube, right regular prisms, right regular pyramids, right circular cylinder, right circular cone, tetrahedron, frustum of solids. UNIT – IV Sections of Solids Types of section planes, projections of above solids cut by different section planes, True shape of cut surfaces.

UNIT – V Development of Lateral Surfaces (DLS) of Solids. Applications of DLS, method of development, development of lateral surface of above solids, development of lateral surface of cut solids. Term Work : Term Work should be prepared on Five A2 (594X420mm) (Half imperial) size drawing screen using any drafting software/package as detailed below.

Sheet No. – 1 Projection of Line Minimum 2 Problems Sheet No. – 2 Projections of Planes Minimum 2 Problems Sheet No. – 3 Projections of Solids Minimum 2 Problems Sheet No. – 4 Sections of Solids Minimum 2 Problems Sheet No. – 5 DLS of Solids Minimum 2 Problems

Important Note: The problems for Term Work should be different for each student. The Term Work of a batch should be preserved in a form of CD/DVD and the same should be produced before a TW Verification Committee appointed by the University.

Text Books : 1. N.D. Bhatt, Elementary Engg. Drawing, Chartor Pub. House, Anand, India. 2. D. N. Johle, Engineering Drawing, Tata Mcgraw-hill Publishing Co. Ltd..

Reference Books : 3. P.S. Gill, Engineering Graphics. 4. N.D. Bhatt, Machine Drawing, Chartor Publishing house, Anand, India. 5. Warren J. Luzzader, Fundamentals of Engineering Drawing, Prentice Hall of India, New

Delhi. 6. Fredderock E. Giesecke, Alva Mitchell & others, Principles of Engineering Graphics,

Maxwell McMillan Publishing.

Semester II (Engineering Graphics – II)

Unit 1 Thermodynamics Thermodynamic work, p-dV work in various processes, p-V representation of various thermodynamic processes and cycles Ideal gas equations, Properties of pure substance, Statements of I and II laws of thermodynamics and their applications in Mechanical Engineering. Carnot cycle for Heat engine, Refrigerator and Heat pump.

Semester II (Basic Mechanical Engineering)

Unit 2 Energy conversion devices (Theoretical study using schematic diagrams only) Package Boiler, Turbine(Impulse & Reaction turbine, Gas turbine, Hydraulic turbines), Working principle and applications of Reciprocating I.C. engines, Air motor. Reciprocating pumps (single acting & double acting), reciprocating compressor, rotary compressors, fans, blowers, Study of household refrigerator, window air conditioner, split air conditioner Ratings and selection criteria of above devices. Refrigerants and their impact on environment.

Unit 3 Heat Transfer Statement and explanation of Fourier’s law of heat conduction, Newton;s law of cooling, Stefan Boltzmann’s law. Conducting and insulating materials and their properties. Selection of heat sink and heat source. Power Plants ( Description with Block Diagrams) Thermal, Hydroelectric, Nuclear and Solar-Wind Hybrid Power Plants. Unit 4 Machine elements: Power transmission shafts, axles, keys, bush and ball bearings, Flywheel and Governors. Power Transmission Devices Types of Belts and belt drives, Chain drive, Types of gears, Types of Couplings, friction clutch (cone and single plate), brakes (types and applications only) Applications of these devices. Mechanisms:.(Descriptive treatment only) Slider crank mechanism, Four bar chain mechanism, List of various inversions of Four bar chain mechanism, Geneva mechanism, Ratchet and Paul mechanism

1. Assembly and working of 4-bar, 6-bar, 8-bar planer mechanisms 2. Finding relation between input angle and output angle for various link lengths 3. Demonstration of operations of centre lathe (turning, step turning, facing, boring, taper turning,

10. Joule’s paddle wheel experiment. 11. Experimental verification of effect of insulating material on heat transfer References : Text Book: P. K Nag “Thermodynamics”, Tata McGraw-Hill Publishing Co. Ltd Hajra-Chaudhari “ Workshop Technology” Reference Books: 1. Yunus A. Cengel and Boles, “ Thermodynamics “,Tata McGraw-Hill Publishing Co. Ltd 2. Arora and Domkunwar, “Thermal Engineering”, Dhanpat Rai and Sons. 3. R. K. Rajput, “Heat transfer”, S Chand Publication, Delhi. 4 V. B. Bhandari “Design of Machine Elements” Tata McGraw-Hill Publishing Co. Ltd

Unit 5 Materials Used in Engineering and their Applications Metals – Ferrous and Non-Ferrous, Nonmetallic materials, Material selection criteria Design considerations Steps in Design Introduction to manufacturing processes and Their Applications: Casting, Sheet metal forming, Sheet metal cutting, Forging, Fabrication, Metal joining processes. Unit 6 Machine Tools (Basic elements, Working principle and types of operations) Lathe Machine – Centre Lathe Drilling Machine – Study of Pillar drilling machine Introduction to NC and CNC machines Grinding machine, Power saw, Milling Machine. Term work: Term work shall consist of record of any eight experiments out of the following;

knurling, grooving, threading) 4. Demonstration of operations on drilling machines (drilling, reaming, spot facing , counterboring) 5. Demonstration of Two stroke and four stroke engine 6. Study of Package type boilers 7. Study of domestic refrigerator & window air-conditioner 8. Study of power transmitting elements: Coupling, Gears and bearings. 9. Joule’s porous plug experiment

Communication Skill Teaching Scheme: Practical: 02 Hrs. The teacher shall explain in detail, the gist and techniques involved in the following work units to the students. The Students should complete practical work based on the following topics. The teacher shall subsequently formulate the exercises to adjudge the skill sets acquired by the students. These exercises will be undertaken by the groups of the students of suitable strength. Work Unit 1 - Fundamentals of Communication: Elements of communication, types of Communication- diagonal, downward, upward, horizontal communication. Importance of effective communication, manners and etiquettes in communication, stages of communication, ideation, encoding, transmission, decoding, response, general communication, technical communication. , barriers to effective communication, Listening skill, speaking skill, Reading skill, writing skill. Work Unit 2 - Organization and Listening Comprehension in Communication: Spatial organization, chronological organization, order of increasing and decreasing importance, styles of communication, accuracy, brevity, clarity, objectivity, impersonal language, professional speaking ability, listening process, hearing and listening, types of listening- superficial, appreciative, focused, evaluative, attentive, empathetic. Barriers to listening- physical, psychological, linguistic, cultural. Speech decoding, oral discourse analysis, effective listening strategies, listening in conversational interaction, listening to structured talks, pre-listening analysis, predicting, links between different parts of the speech, team listening, listening and notes taking. Work Unit 3 - Speaking Skills: The speech process, message, audience, speech style, feedback, conversation and oral skills, fluency and self expression, body language phonetics and spoken english, speaking techniques, word stress, correct stress patterns, voice quality, correct tone, types of tones, Job interview, interview process, characteristics, of the job interview, pre-interview preparation techniques, interview questions and answers, positive image projection techniques. Group discussion- characteristics, subject knowledge, oral and leadership skills, team management, strategies, individual contribution. Presentation skills-planning,preparation, organization, delivery. Work Unit 4 - Reading and language skills: The reading process, purpose, different kinds of texts, reference material, scientific and technical texts, active and passive reading, strategies-vocabulary skills, eye reading and visual perception,, prediction techniques, scanning skills, distinguishing facts and opinions, drawing inferences and conclusions, comprehension of technical material- scientific and technical texts, instructions and technical manuals, graphic information. Note making- tool for study skills, topicalising, organization and sequencing. Summarizing and paraphrasing. Work Unit 5 - Referencing and Writing skills: Methods of referencing, book references, user guides, references for reports, journal references, magazines and news papers, unpublished sources, internet references, explaining and elucidating. Writing skills - Sentence structure, sentence coherence, emphasis. Paragraph writing. letter writing skills - form and structure, style and tone. Inquiry letters, Instruction letters, complaint letters, Routine business letters, Sales letters.

Work Unit 6 – Reports, Resumes and Job Applications: Types of reports, information and analytical reports, oral and written reports, formal and non formal reports, printed forms, letter and memo format, manuscript format, proposals, technical articles, journal articles and conference papers, review and research articles. E-mails, Business Memos, Employment Communication- resume design, resume style, Reference Book: 1. ‘Effective Technical Communication’ by M Ashraf Rizvi, Tata McGraw Hill Publishing Company Ltd. 2. Basic Managerial Skills for all’ E. H. McGrath, Eastern Economy Edition, Prentice hall India. 3. ‘Developing Communication Skills’ Krishna Mohan, Meera Banerji, McMillan India Ltd. 4. ‘Principles and Practice of management’ Dr. P. C. Shejwalkar, Dr. Ghanekar and Dr. Bhivapathaki, Everest publishing House

Subject Code No.

Subject Teaching Scheme Examination Scheme

Total Theory Practical TW/

Drawing

Paper Practical Oral TW

1 2 -- -- -- 50 50

3

2 - 100 50 - - 150

3 2 - 100 -- 50 - 150

- 100 -- -- -- 100

Technical Communication 1

2

- - - - 50 50

4

- -

100

- - - 100

Total 20 10 2 500 100 50 100 750

Subject Code No.

Subject Teaching Scheme Examination Scheme Total

Theory Practical TW/

Drawing

Paper Practical Oral TW

BCE-301 Chemistry I 4 4 100 50 -- -- 150

BCE-302 Fundamentals of Chemical Engineering

BCE-303 Chemical Engineering Fluid Mechanics

BCE-304 Chemical Engineering Materials

BCE-305 Process Calculations 4

Semester - III

Semester - IV

BCE-307 Engineering Mathematics –III

BCE-306

BCE-401 Chemistry II 4 4 100 50 - - 150

BCE-402 Heat Transfer 4 2 100 50 - - 150

BCE-403 Principles of Design 3 - 2 100 - - 50 150

3

- -

100 -

- - 100

4

2 100 50 - 150

Industrial Training I (to be evaluated in

Fifth Semester)

- - - - - - - -

Total 18 10 2 500 150 100 750

BCE-404 Chemical Engineering Thermodynamics I

BCE-405 Mechanical Operations

BCE-406 Workshop Practice - 2 - - - - 50 50

s-s, s-p , p-p overlaps , molecular orbital structure of butadiene, benzene, MO energy diagrams for diatomic molecules H 2 , O2 , CO. Aromaticity-conditions necessary for delocalization of electrons, resonance structures stability rules, resonance in phenol, aniline, ,benzaldehyde ,nitrobenzene molecules, Effect of inductive effect and resonance on pKa and pKb values of acids and bases. Reaction intermediates –carbonations, carbanions, free radicals and their stability. Types of reagents, types of reactions

Unit-II Reaction mechanisms Substitution at saturated carbon (SN

1 , SN2 )- mechanism, kinetics, stereochemistry, factors

favoring. Electrophilic aromatic substitution in benzene and mono substituted benzenes , activating and deactivating groups , nitration, Friedal-Craft reactins, sulphonation,diazotization. Nucleophilic substitution on on carbonyl carbon. Addition of HX on C=C 1,2-Eliminations- E1 mechanism, E 2, ( Saytzeff,Hoffman products ) ,factors favoring. Rearrangements- Beckman , Claisen , Reformatsky.

Conductometry : Conductance by solutions (specific, equivalent ), cell constant , measurement of conductance, conductometric tirations. Potentiometry: Ion selective electrodes, theory of potentiometric titrations, potentiometric titration curves.Flame photometry: Principles of flame photometry, applications

Kinetics : Rate of reaction, rate constant, order of reaction, kinetics of first and second order reactions, numericals on above, Activated complex theory of reaction rates kinetics of complex reactions. Photochemistry : Introduction and importance, Stark-Einstien law,photochemical rate law, examples of photochemical reactions kinetics of i) H2, Cl2 reaction ii) dimerisation of anthracene ,

Unit –I Bonding and reactivity Covalent bonding- Introduction to VBT ( revision ). Molecular orbital theory, MO structures of

Unit-III Instrumental methods of analysis

Unit –IV Kinetics and photochemistry

Chemistry-I

Chromatography and their applications. Batteries: Batteries and their importance,types of cells, terms-capacity, power density, cycle life , energy efficiency, NICAD cell, Lithium batteries ( lithium ion ,polymer electrolyte,lithium alloy ) , Fuel cells ( alkaline, PAFC, polymer electrolyte membrane ) , their applications

Aromaticity, preparation, reactions of pyrrole, furan, pyridine, quinoline.

Dyes- Nomenclature, methods of application, colour and chemical constitution ( chromophore-auxochrome theory), classification of dyes on the basis of chemical structure, diazotization and coupling for azo dyes ,synthesis of crystal violet, alizarin, methyl orange, phenolphthalein.

Practicals 1 Diameter of solute molecule by viscosity measurements. 2 To determine rate constant of first order reaction of acid catalysed hydrolysis of ester. 3 Preparation of benzoic acid from benzamide , crystalisation and purity checking by

TLC. 4 Conductometric titration between strong acid and strong base 5 Conductometric titration between AgNO3 and NaCl 6 To estimate the weight of ferrous sulphate in given solution by potentiometric titration 7 To determine pKa value of weak acid by pH metric titration 8 To find molecular wt. of solute by depression in freezing point of solvent 9 Partition coefficient of a iodine between water and CCl4 10 To estimate sodium ion conc. In solution by flame photometer 11 Colorimetric estimation of cobalt/ nickel ion in solution ( Any seven expts of above )

12 Identification of given organic compound ( with maximum one functional group ) by systematic analysis

( Minimum eight compounds )

Note – practical examination will be for four hours and students will perform TWO experiments( one organic analysis and one other )

Reference Books 1 Instrumental methods of chemical analysis ----B.K.Sharma , Goel publ. ) 2 Instrumental methods of chemical analysis ----Chatwal –Anand

Unit-V Chromatography, Batteries Chromatography ,: Adsoption and partition principles, Study of TLC, column , HPLC, Gas

Unit-VI Heterocyclic compounds , Dyes

3 Organic chemistry –I L Finar volume I and II

4 Engineering Chemistry ---S.S.Dara

5 Physical chemistry –P L Soni

6 Inorganic chemistry –Huheey

7 Inorganic chemistry ----Cotton, Wilkinson

8 Spectroscopy ---Kalsi

Unit-I: INTRODUCTION: introduction to chemical engineering; history of chemical engineering and chemical technology; Scope of Chemical Engineering, Nature of Industries.

Unit-II Basic Chemical Calculations: units and dimensions, conversion and conversion factors.

Basic Concepts: concept of mole, weight percent, mole percent, normality, molarity, molality, vapor pressure, partial pressure.

Unit-III:

Unit Operations: Introduction, Definition, examples like Size reduction, sedimentation, filtration, Distillation, evaporation, absorption, extraction, fluid handling, fluid-solid contacting, fluid-solid separation, fluid storage, mixing, solid handling, crystallization, drying, leaching, size separation.

Unit-IV: Unit processes: introduction to unit processes with simple examples like sulphonation, polymerization, oxidation, hydrogenation, saponifoication, etherification, nitration , chlorination.

Unit-V: Basic concept of chemical processes: Conversion, Yield, efficiency, flow diagram, flow sheets, & block diagram, with examples. Unit-VI: Process instrumentation and safety: Temperature scale, measurement of temperature using bimetallic thermometer, mercury expansion thermometer, gas filled thermometer. Pressure scales & units, measurement of pressure. Level measurement. Flow measurement. Measurement of viscosity. Personal protection devices.

Reference Books

1. Unit operations in chemical engineering by W.L. McCabe and J.C. Smith and Peter Harriott, Mc Graw Hill 5th ed. 1993. 2. Himmelblau, D.H, Basic Principles and Calculations in Chemical Engineering, 5th

Edn., Prentice Hall, New York, 1990.

3. Coulson J M and Richardson J F, Chemical Engineering, Vol. I and II, Pergamon

Press, NY, 1990.

Fundamentals of Chemical Engineering

4. Badger and Banchero, Introduction to Chemical Engineering, 1st Edn., McGraw Hill,

NewYork, 1954.

TW: Based on the study of the Laboratory equipments. Minimum 8.

UNIT 1: INTRODUCTION

Fluid, Properties of fluid, Classification of fluids, Newton’s law of viscosity, Rheological classification of fluids, Pressure and temperature dependence, Types of flow, Lines to describe the flow, Application of fluid flow in Chemical Engineering.

UNIT 2: FLUID STATISTICS AND ITS APPLICATIONS

Hydrostatic equilibrium, Barometric equation, Hydrostatic equilibrium in centrifugal field; Concept of atmospheric, gauge and absolute pressure, manometers, pressure measurement by simple and differential manometer.

Basic equations of fluid flow: Continuity equation, equation of motion, mechanical energy balance equations.

UNIT 3: FLOW OF INCOMPRESSIBLE FLUIDS IN CONDUITS

Shear stress distribution, Relation between skin friction and wall shear, The friction factor; Laminar flow through circular pipe, on inclined plane, through annular space,; Relation between average and maximum velocity, Darcy Weisbach equation, Friction factor chart.

UNIT 4: BOUNDARY LAYER AND DIMENSIONAL ANALYSIS

Concept of hydrodynamic boundary layer, Growth over a flat plate, Different thickness of boundary layer, Fundamental dimensions of quantities, Dimensional homogeneity, Dimensional analysis by Reyleigh’s method and Buckingham’s method, Dimensionless numbers.

UNIT 5: FLOW PAST IMMERSED BODIES

Drag and drag coefficient, Flow through beds of solids, Motion of particles through fluids, Fluidization, Introduction to compressible flow.

Chemical Engineering Fluid Mechanics

UNIT 6: TRANSPORTATION AND FLOW METERING

Pipes and tubings, Joints and fittings, Major and minor losses, Different types of valves,; Flow measurement using orificemeter, venturimeter, pitot tube and rotameter; Pumps: Centrifugal pump, Performance of centrifugal pumps.

Reference Books

1. McCabe, Smith, Hariot, “Unit Operations in Chemical Engineering” , 7th ed., 2. .M. Coulson, J.F. Richardson, with J.R. Backhurst and J.H. Harker, Coulson “Richardson

Chemical Engineering, Volume-1” , 6th ed., Butterworth-Heinemann, 1999 3. R K Bansal, “A Textbook of Fluid Mechanics and Hydraulic Machines”, 9th ed. Laxmi

Publications, New Delhi, 2004 4. Modi, L.P., Seth, S.M., “Hydraulics and Fluid Mechanics”, Standard Book House, New

Delhi,2002 5. Bird R.B., Stewart W.E., Lightfoot E.N. “Transport phenomena” 2ed., Wiley

Publications,2002

3. Metals and their alloys: Iron – carbon diagram, Ferrous and nonferrous alloys, mild steel, special steels, stainless steels, brasses, brasses, aluminum alloys and titanium alloys, high and low temperature material, insulation, refractories. Methods for fabrication, rolling, bending, central punching, revetting, welding. Nickel and its alloys: aluminum and its alloys 9 Lect.

1. James F. Shacketford, introduction to material science, McMillan publishing compony, Newyork ISBN 1990. 2. D.Z. Jestrazebaski, properties of Engg. Materials, 3rd Ed. Toppers.Co. Ltd.

_______________________________________________________________________

1. Introduction to materials and their principle properties, Simple stresses and strains,

Chemical Engineering Materials

Concept of stress, strain, shear stress, shear strain, Hooks law, Elastic limit, stress-strain curve for mild steel and elastomeric materials, factor of safety, Poisson’s ratio, Strain energy due to axial load and impact. Introduction to determination of mechanical properties of materials ASTM methods. Basic principles in their selection for fabrication and erection of chemical plant.

Testing of materials, destructive and nondestructive tests, structure of atom and chemical bonds, crystal structures and their influence on material properties, Deformation and slip processes.

4. Corrosion and its control: Corrosion attack methods, Different types of corrosion: chemical, biochemical, and electrochemical; Internal and external factors affecting corrosion of chemical equipments, Methods to minimize corrosion, corrosion charts for process equipments. Polyaniline and Anticorrossive surface coatings electrochemical corrosion prevention corrosion case studies from the chemical industry

5. Polymers, natural & synthetic: Selection of polymetric materials for equipment linings, fiber reinforced plastic, application of special polymers like Nylon 66, Teflon in engineering. Polymer Composites 6. Ceramic and glasses: Definition of ceramics and glasses; interaction between structure, processing, and properties; Applications of ceramic and glass materials; Crystalline and non-crystalline ceramics, silicates, refractories, clays, cements, glass vitreous silica, and borosilicate. Reference Books

3. J.L. Lee and Evans, Selecting Engineering materials for chemical and process plants, Business Works 1978. 4. “Design of machine elements”, Spott M.M. Prentice Hall. 5 A text book of machine design, Khurmi R.S. and Gupta J.K. 6.Material Science & Metallurgy for Engineers, Dr.V.D.Kodgire, Everest Publishing

House. Practical: 1. Microstructure observation and study of metals and alloys. (Minimum five) low carbon steel, medium carbon steel, high carbon Steel, tin, bronze, brass, phosphor bronze. 2. Study of properties of polymeric materials; impact test and polymeric Tests. 3. Corrosion testing (salt spray test for different samples such as plain carbon steel, chrome plate steel, galvanized steel.) 4. Different types of hardness test on metals. i.e. Rockwell hardness test, Brinell hardness test, Shore scleroscope tests. 5. Izod and Charpy impact test on mild steel, copper, brass and aluminum. 6. Chemical analysis of metals and alloys (Any one element to be analysed e.g. molybdenum from stainless steel, carbon from steel, copper from brass etc. 7. Macrostructure observation: (flow lines observation in forging by macro etching sulphur printing of steel.) 8. Study experiments based in, i) Dye penetration ii) Rubber lining, iii) Ultrasonic test, iv) Heat treatments. * Minimum 8 experiments to be performed from the above suggested practicals.

Distillation, absorption and stripping, extraction and leaching, crystallization, psychrometry, drying, evaporation, introduction to stoichiometry and industrial problems. 6. Combustion

Calorific values, coal, liquid fuels, gaseous fuels, air requirement and flue gases, combustion calculations. Reference Books

1. Stoichiometry by Bhatt & Vora 2. Basic Principles & Calculations in Chemical Engineering by Himmelblau. 3. Chemical Process Priciples Part I by Hougen & Watson

Process Calculations

Unit 1. Basic Chemical Calculations

Introduction to unit processes and operations and their symbols, process flow sheet, Dimensions and Units, Basic Chemical Calculations including mole, equivalent weights, solids, liquids, solutions and their properties, properties of gases. Unit II. Material Balances without Chemical Reactions

Concept, material balance calculations, recycling and bypassing operations, introduction to unsteady state processes. Unit III. Material Balances involving Chemical Reactions

Concept, material balance calculations, electrochemical reactions, recycling and bypassing operations, metallurgical operations. Unit IV Energy Balances

Concept, energy and Thermochemistry, energy balances, heat capacity of pure substances and mixtures, latent heats, enthalpy of pure substances and mixtures, absolute enthalpy, heat of reaction, adiabatic reactions, thermo chemistry of mixing processes, dissolution, liquid-liquid mixtures, gas-liquid systems. 5. Unit VI Stoichiometry and Unit Operations

Professional speaking: Interview process, characteristic of job interview, pre-interview preparation techniques, frequently asked interview questions.

G.D – Nature of G.D, G.D and debate, importance of G.D, strategy of G.D, techniques for individual contribution, group interaction strategy.

Presentation skills– Nature and importance of oral presentation, planning the presentation, preparing the presentation, organizing your presentation, rehearsing and presentation. Improving delivery, checklist for making presentation.

Professional writing: Routine business letters – letter writing skills, form and structure, style and tone, enquiry letters, replies to enquiry letters, P.O, letters urging action, complaint and adjustment letters.

Sales letters – Sales letters, organizing sales letters, opening, body, closing.

Resume and job application – Writing resume, job application letters.

Business memo– Principles and fundamentals, business memo, letter versus memo, form and structure of memo, writing strategies, characteristics of effective memo.

E-mail messages- Principles and fundamentals, advantages of Email messages, characteristics successful Email messages.

Reports – Nature and significance, types of reports, format of reports, writing strategies.

Proposals – Nature and significance, type of proposal, structure of formal proposal, writing tips.

Technical articles– Nature and significance, types of technical articles, journal articles and conference paper, review and research articles, writing strategies.

Soft skills: What are soft skills? , global competition, hard skills (technical skills) versus soft skills, emotional intelligence, interpersonal skills, motivation, leadership skills, decision making, negotiation skills, business etiquette, problem solving skills, conflict management, stress management, crisis management, social understanding, behaviors traits, teamwork.

Human values: Morals, values, ethics, integrity, work ethics, virtues, respect for others, caring, sharing, honesty, courage, time management, cooperation, commitment, empathy, self confidence, challenges in work place, spirituality.

Technical Communications

Engineering Ethics: Overview, senses of engineering ethics, variety of moral issues, types of enquiries, moral dilemma, moral autonomy, moral development, consensus

And controversy, profession, models of professional roles, responsibility, ethical theories, self control, self interest, customs, religion, self respect, overview of safety, responsibility and human rights, case study.

Global issues: Globalization, multinational corporations, environmental ethics, computer ethics, moral leadership, code of ethics.

Engineers as managers: Foresight as future managers in organizations, as consulting engineers, as experts, as advisors, as CEO’s, Entrepreneurship skills.

Term Work: Term work and theory are considered to be integral part of the course.

Term work shall consist of a journal consisting of regular assignments and presentations completed in the practical class and at home, the total number of assignments should not be less than twelve, generally covering the topics mentioned above. As far as possible, submission should be word processed on a computer using a standard package by the student himself.

For the purpose of assignments, extensive use of research papers published in technical journals and articles published in magazines and newspapers may be ma\de so that there is no repetition by the individuals. Oral presentations exercises and group discussions should be conducted batch wise so that there is a closer interaction. Students should be sent to industrial visits for exposure to corporate environment.

Reference Books 1. Krishna Mohan and Neers Banarge (1996), Developing Communication Skills,

Macmillan India Ltd. 2. Day (1995), How to write and publish a scientific paper, Cambridge Lowpriced Edition. 3. Bernice Hurst (1996) , Handbook of communication skill, 2nd Edition, Kogan page 4. Strunk W (Jr.) and White E.B., The elements of style, Latest edition, Macmillan

Publishing Company, New York 5. University of Chicago Press Manual of Style, Publ. University of Chicago Press,

(Chicago. Latest Edition). 6. M Ashraf Rizvi , Effective technical communication, Mc graw Hill 7. R.S. Naagarazan, Professional ethics and human values, New Age international

Publishers. 8. Elizabeth Valuance, Business Ethics at work.

2u/∂x2), (2) ∂2u/∂t2 = a2 (∂2u/∂x2) and (3) (∂2u/∂x2) + (∂2u/∂y2) = 0

Norman Richert (Brooks/Cole, Thomson Learning).

ENGINEERING MATHEMATICS – III .

Section I Unit I : Linear Differential Equations (LDE ) Solution of nth order LDE with Constant Coefficients, Method of Variation of Parameters, Cauchy’s & Legendre’s DE, Solution of Simultaneous & Symmetric Simultaneous DE. Unit II : Applications of DE Applications of LDE to chemical engineering problems involving batch reactions and mass spring systems. Solution of Partial Differential Equations (PDE) (1) ∂u/∂t = a2 (∂by separating variables only. Applications of PDE to problems of Chemical and allied engineering. Unit III : Fourier Transform (FT) Fourier Integral theorem. Sine & Cosine Integrals. Fourier Transform, Fourier Cosine Transform, Fourier Sine Transforms and their inverses. Finite FT, Application of FT to problems on one and two dimensional heat flow problems.

Section II Unit IV : Laplace Transform (LT ) Definition of LT, Inverse LT. Properties & theorems. LT of standard functions. LT of some special functions viz. error, 1st order Bessel’s, Periodic, Unit Step, Unit Impulse, ramp, jump, parabolic, Si(t) and Ei(t). Problems on finding LT & inverse LT. Unit V : Vector Calculus Physical Interpretation of Vector Differentiation. Radial, Transverse, Tangential & Normal components of Velocity and Acceleration. Vector differential operator. Gradient, Divergence & Curl. Directional derivative. Vector identities. Line, Surface & Volume integrals. Work done. Conservative, Irrotational & Solenoidal fields. Scalar potential. Green’s Lemma, Gauss’s Divergence and Stoke’s Theorem. Unit VI : Applications of Laplace Transforms & Vector Calculus Applications of Vectors to problems in Fluid Mechanics, Continuity equations, Stream lines, Equations of motion, Bernoulli’s equations. Applications of LT for solving ordinary differential equations, liquid level systems, consisting of single tank and two tanks in series (interacting and non-interacting systems), second order systems (damped vibrator). Text Books: 1. Advanced Engineering Mathematics by Peter V. O'Neil (Cengage Learning). 2. Advanced Engineering Mathematics by Erwin Kreyszig (Wiley Eastern Ltd.). Reference Books: 1. Engineering Mathematics by B.V. Raman (Tata McGraw-Hill). 2. Advanced Engineering Mathematics, 2e, by M. D. Greenberg (Pearson Education). 3. Advanced Engineering Mathematics, Wylie C.R. & Barrett L.C. (McGraw-Hill, Inc.) 4. Higher Engineering Mathematics by B. S. Grewal (Khanna Publication, Delhi). 5. Applied Mathematics (Volumes I and II) by P. N. Wartikar & J. N. Wartikar (Pune Vidyarthi Griha Prakashan, Pune). 6. Advanced Engineering Mathematics with MATLAB, 2e, by Thomas L. Harman, James Dabney and

Introduction to Freundlich and Langmuir theories of adsorption ( revision ) ,adsorption from solution, B.E.T. Theory of adsorption of gases, ,activation energy, , numerical on above.Catalysis- characteristics, types, adsorption theory of catalysis, promoters ,poisons, enzyme catalysis, industrial applications of catalysts;

i) Zeolites- structure, properties (adsorption, catalysis ), applications as catalyst for reactions( amination of alcohol. NO x pollution control, alkylation ,cracking convertion of methanol ),

ii) Co-ordination catalysts- In Wacker process, cabonylation,photolysis of water iii) Oxide catalysts- oxide surface structure,application of V2 O5, Fe2(MoO4) for oxidation.

Carbohydrate: Cyclic structure of glucose, cellulose, starches. Starch based products, Cellulose

acetate, nitrate ,ether. Proteins-formation of peptide linkage, features of peptide linkage, alpha-helical configuration, beta-pleated structure, primary, secondary, tertiary, quaternary structures of proteins. Amino acids-alpha- amino acids, classification, properties and reactions. General introduction of cofactors and coenzymes, catalytic site of enzyme, factors affecting enzyme activity , classification of enzymes. Vitamins and harmones (in short)

Unit-III Spectroscopy

UV-Visible spectroscopy: Lambert-Beer law, λ max , calculation of λ max for olefinic and cyclic structures, instrumentation , interpretation of spectra , applications. IR spectroscopy: Introduction, instrumentation (double beam spectrophotometer) characteristic absorption in functional and finger print regions, interpretation of spectra , applications

SEMESTER IV

Chemistry-II

Unit –I Adsorption and Catalysis

Unit – II Biomolecules

Unit-IV Transition metals and Co-ordination chemistry Electronic configuration of first series transition metals, shapes of d- orbital characteristics(variable oxidation states, magnetic nature, co-ordination, colour of transition metal compounds ). Ligands, C.N. and geometry , nomenclature of complexes, chelates . Theories of co-ordination- i) Werner ii) EAN iii) VBT for tetrahedral and octahedral complexes iv) CFT ( including crystal field splitting in octahedral field, CFSE , for octahedral complexes , applications of CFT )

efficiency of reaction, principles of green chemistry with explanation, . Green pathways for synthesis of adipic acid from glucose, ibuprofen, polycarbonate, indigo, carbaryl, acrylamide

Introduction, scope and importance of biotechnology, organisms involved, types of fermentation, applications of biotechnology for production of ethyl alcohol, glucose from cellulose , n-butanol, antibiotics, energy. Membrane bioreactors, bioremediation.

Characteristics of municipal waste(brief), B.O.D., determination, C.O.D. determination, municipal waste treatment (preliminary, primary, secondary, tertiary).Water /waste treatments: charcoal treatment, reverse osmosis, electro dialysis, ultrafiltration. Types and characteristics of industrial waste( textile ,dairy, paper, tannery, dyeing ), hazardous chemical waste treatments technology ,treatment and disposal. Practicals:

1. Dissolved oxygen in water sample by Winkler method.

2 Estimation of Cu++ ions by spectrophotometer

3 Adsorption of acetic acid on charcoal to verify Freundlich isotherm

4 Determination of purity of sod. Bicarbonate by gravimetry

5 Determination of purity of sod. Carbonate by titration method

6 Determination of C.O.D. of a wastewater

7 Estimation of nickel ions by gravimetry

8 Preparation of tetramine copper (II) sulphate, pot. trioxalato aluminate (any one )

9 Preparation of biodiesel 10 Estimation of glucose/acetone in solution 11 Oxidation of toluene to benzoic acid by oxidation with KMnO4 12 Chlorine demand of a water sample

13 Conversion of benzoic acid into its anilide derivative and its crystalisation

14 Purification of organic compounds by crystalisation and sublication (one each )

15 Application of XRD for study of adsorption

16 Preparation of tris ethylene diammine nickel (II ) thiosulphate

17 Separation and identification of two metal ions by column chromatography

Unit -V a) Green chemistry Introduction , significance of green chemistry, issues related to chemical reactions, parameters for

b) Biotechnology

Unit-VI Waste treatments

( Any 13 experiments of the above )

Note – practical examination will be for four hours and students will perform TWO experiments

Reference Books 1 Instrumental methods of chemical analysis -B.K.Sharma , Goel publ. ) 2 Handbook of industrial chemistry --James Kent (CBS Publication) 3 Biotechnology --B.D.Singh( Kalyani publication) 4 Engineering Chemistry --S.S.Dara

5. Inorganic chemistry---J D Lee (ELBS) 6. Inorganic chemistry –Huheey 7 Inorganic chemistry ----Cotton, Wilkinson

8 Spectroscopy ---Kalsi

Unit-I Basics concepts of heat transfer

The relation of heat transfer with thermodynamics, conduction heat transfer, convection heat transfer, radiation heat transfer, Thermal conductivity, thermal insulation, units and dimensions.

Unit-II Heat conduction

General differential equation of conduction, Steady state heat conduction through a plane slab, composite slab, hollow cylinder, composite cylinder and hollow sphere. Contact resistance, heat transfer between surfaces and surrounding, critical thickness of insulation. Heat transfer through extended surfaces of uniform cross section.

Unit-III Convection heat transfer

Convection without phase change:

Natural and forced convection, principal heat balance equation in laminar flow Empirical equations for convection heat transfer in turbulent flow through tubes, through annulus and over a flat plate. Dimensional analysis, dimensional groups used in heat transfer

Convection with phase change:

Condensation: Modes and features, Nusselt’s equation, condensation on vertical and horizontal plate

Boiling: Pool boiling of saturated liquid, types of boiling, concept of critical heat flux

Unit-IV Radiation

Thermal radiation, black body radiation, properties of radiation, laws of radiation. The radiation shape factor, various cases of radiation between two surfaces, radiation shields

Unit-V Heat Exchangers

Basic types of heat exchangers, overall heat transfer coefficient, fouling factor. Double pipe heat exchanger design by LMTD and effectiveness-NTU methods calculations of overall heat transfer coefficient and area), Shell and tube heat exchangers

HEAT TRANSFER

Unit-VI Evaporation

Introduction, types of evaporators, material and energy balance, boiling point elevation, capacity and economy, multiple effect evaporators

Practical:

1. Heat conduction

2. Natural convection

3. Thermal radiation-determination of emissivity

4. Double pipe heat exchanger

5. Shell and tube heat exchanger

6. Plate Heat exchanger

8. Heat transfer in agitated vessels

9. Double effect evaporator

10. Open pan evaporator

11. Heat pipe demonstrator

12. Fluidized bed heat transfer

Reference Books:

1. J P Holman, “Heat Transfer” 9th edition, Tata McGraw Hill Publications, New Delhi (2004)

2. Frank Kreith, Mark Bohn, “Principles of Heat Transfer” 5th edition, PWS Publishing company, Boston (1997)

3. S. P. Sukhatme, “A Textbook on Heat Transfer”, 4th ed, Universities Press (India),., 2005

4. D. Q. Kern, “Process Heat Transfer”, 11th ed., Tata Mc Graw Hill Publication, New Delhi

5. Bird R.B., Stewart W.E., Lightfoot E.N. “Transport phenomena” 2ed., Wiley Publications,2002

Unit 1. Basic Principles of design:

Design Factors, Design procedure, Codes and Standards, Optimization,Design Loads, Combined Loading in Equipments, Concept of Stress and Strain, Types of Stress and Strain Curves for Ductile and Brittle Materials, Factor of Safety, Young’s Modulus, Stress Concentration, Fatigue, Creep, Endurance Limit, Poisson’s Ratio, Shear Modulus, Resilience, Toughness, Mass Moment of Inertia, Polar Moment of Inertia, Section Modulus, Correlation between Torque and Power

2. Basic Principles of Strength of Material

Bending Stress and Shear Stress, Torsional Shear Stress, Variation of Bending and Shear Stress across the Section, Shear Force and Bending Moment Diagram for Simply- supported and Cantilever Beams, Principle Stresses and Planes, Theories of Failure.

3. Design of Machine elements:

a) Direct, Torsional and Bending Stresses in Shaft, Design of Shaft subject to

Bending, Twisting and a combination of Bending and Twisting,

b) Keys and Couplings: Types of Keys and Couplings, Design of a Sunk Key,

Effect of Keyways, Requirement of a good Shaft Coupling, Design of

Flanged Coupling and Muff Coupling. 4. Design of Machine Elements

a) Belts and Pulleys - Selection of Belt Drive, Types of Flat and V- belt

Drives, Types of Belts and Pulleys, Working Stresses in Belts, Velocity

Ratio, Slip and Creep of the Belt, Length of Belt Drives, Ratio of Driving

Tension for Flat and V-belt Drives condition for Transmission of Maximum

Power.

b) Types of Bearings, Classification of Bearings, Sliding Contact Bearing,

Rolling Contact Bearing, Application / Properties of Lubricants, Sliding and

Rolling Contact Bearings, Sommeteld Number, Design Procedure for

PRINCIPLES OF DESIGN

Journal Bearing, Dynamic Load Rating for Rolling Contact Bearing, Life of a

Bearing, Reliability of a Bearing.

5. Design of Joints

Types of Joints: Welded and Pipe Joints, Cotter and Knuckle Joints, Types of Pipe and Welded Joints, Design of Circular Pipe Joints and Flanged Pipe Joint, Strength of Transverse and Parallel Fillet Joints.

6. Piping, Valves and Pumps :

Pipes and Piping Joints, Stress in Pipes, Design of Pipes, Pipe Sizing for Flow of Liquids and Gasses, Classification of Valves and Pumps and their selection criteria, Sizing of Control Valves, Valve Characteristics, Characteristic Curves for Pumps, NPSH calculation for pumps,.

Term Work 1. Assembly drawings of valves. 2. Assembly drawings of pumps. 3. P & I Draigm. 4. Design of shaft, key, coupling, pulley. 5. AUTOCAD assignment on A4 sheets

Sectional drawing of assemblies of components with the help of AUTOCAD Components: Knuckle joints flange coupling, stuffing box, cotter Joints etc.

Reference Books:

1.Coulson & Richardson's Chemical Engineering, Vol 6, 4/e, R K Sinnot, Butterworth -Hienemann, MA

2.Strength of Material, Andrew Pytel & Ferdinando L Singer, Addision-Wesley Inc., Massachusetts

3.A Textbook of Machine Design, R S Khurmi & J K Gupta, Eurasia Publishing House

1) Introduction to chemical engineering thermodynamic and first law: The scope of thermodynamics, fundamental and derived quantities, first law of thermodynamics: Formation of 1st law of thermodynamics, state and path functions,

4) Second law of thermodynamics: Carnot cycle, entropy, mathematical statement of 2nd law, statement of 3rd law. (9 lectures)

Reference Books:

1) Introduction to Chemical Engineering Thermodynamics: J. M. Smith & H. C. Vanness 2) Principles of Chemical Equilibrium : Kenneth Denbigh 3) Chemical Engineering Thermodynamics : B. F. Dodge 4) Chemical Engineering Thermodynamics : T. E. Daubert 5) Thermodynamics for Chemists: Glasstone S. 6) Thermodynamics for Chemical Engineers: Weber and Meissner 7) Chemical and Process Thermodynamics: B. G. Kyle 8) Molecular Thermodynamic: Praunitz 9) Chemical Engineering Thermodynamics: Narayanan 10) Chemical Engineering thermodynamics: Y.V.C. Rao

Chemical Engineering Thermodynamics-I

thermodynamic systems, steady state flow system, phase rule, reversible process heat capacity.

2) Volumetric properties of pure fluids: The P.V.T. behavior of pure substance, the viral equation, the ideal gas, the constant volume, constant pressure, adiabatic, polytrophic processes, real gas, applications of Viral equation, critical properties, Vander Wall equation, Benedict- Webb – Rubin equation, Redlich –Kwong equation.

3) Heat effects: sensible heat effects, temperature dependence of heat capacity, standard heat of reaction, standard heat of formation, standard heat of combustion, temperature dependence of ∆H0, heat effects of industrial reactions.

5) Thermodynamic properties of Fluids: Maxwell relationships, residual properties, residual properties by equations of state, two-phase systems, Clausius- Clapeyron equation, type of thermodynamic diagram, availability.

6) Refrigeration: Refrigeration cycle (p-v, t-s, h-s, and h-x diagrams) for vapor compression and Adsorption refrigeration systems, Evaluation of COP, duty and load of such cycles, heat pumps, liquefaction.

Particle size and shape, Mixtures of particles, Determination of particle size, Standard screen series, screen analysis, Screen effectiveness and capacity, Industrial screening equipments.

Crushing efficiency, energy requirements calculations by using different crushing laws, Size reduction equipments: Primary crushers, secondary crushers, Intermediate & fine grinders, Ultra fine grinders, Cutting machines, Open circuit & Closed circuit grinding.

Storage of solids, characteristics of Bulk solids. Conveyors: Working principles, Construction, Advantages, Disadvantages and design calculation of Screw conveyors, Belt Conveyors, Chain & Flight conveyors, Bucket elevators, Pneumatic conveyors.

Filter media and filter aids, classification of filtration, pressure drop through filter cake, filter medium resistance, specific cake resistance, Continuous Filtration, Washing and dewatering of filter cakes, Centrifugal filtration.

a. Motion of particles in liquid, drag force, drag coefficients

b. Gravity settling method: Terminal velocity, Stoke’s law and Newton’s law, free settling, sink and float method, differential settling.

c. Sedimentation and thickening: Batch sedimentation, equipments for sedimentation, Kynch theory of sedimentation, calculation of area and depth of continuous thickeners, batch thickeners, and continuous thickeners.

d. Fluidization: flow through packed beds, characteristics of fluidized systems, minimum fluidization velocity, types of fluidization, applications of fluidization technique, spouted beds and fixed bed.

Mechanical Operations

1. Particle Technology and size reduction:

2. Handling And Transport of Solids:

Necessity of mixing & agitation in chemical industries, Types of Impellers & propellers, Different flow patterns in mixing, Calculation of power requirement of mixing equipment, Mixing equipment of pastes & viscous material, Solid – Solid Mixing, Agitator selection.

3. Mixing and Agitation:

4. Filtration:

5. Fluid – Solid systems:

6. Benefication Operations, Mineral dressing and centrifugal settling operations:

Froth flotation, magnetic separator, scrubbers, fiber and fabric filter, and electrostatic precipitators. Mineral jig, cyclone separator, hydro cyclone types and centrifuges, centrifugal clarifier.

Reference Books

1. McCabe W. L. &Smith J.C. “Unit Operations in Chemical Engineering”. McGraw Hill Publications.

2. Coulson J. M. & Richardson J.F. “Chemical Engineering Vol. 2”, Pergamon Press. 3. Badger W. L & Banchero J.T. “Introduction to Chemical Engineering”, McGraw Hill

Publications. 4. Foust A. S “Principles of Unit Operation”. 5. George G. Brown, “Unit operations”, CBS publishers and distributors.

List of Practical

Minimum numbers of Experiments to be performed for the term work eight out of the following list.

1. To determine effectiveness of given set of standard screen. 2. To determine energy consumption and crushing law constants for jaw crusher. 3. To determine Critical speed of Ball mill & Average particle size of the product obtained

in ball mill OR Average particle size of product obtained in Bhrustone mill. 4. To determine mixing Index of a mixture in Ribbon Blender. OR To determine mixing

Index of mixture in Sigma Mixer. 5. To determine filter medium resistance and cake resistance by using Vacuum Leaf filter. 6. To determine filter medium resistance and cake resistance by using Plate & frame Filter

Press OR by using centrifuge machine. 7. To determine area of batch thickener by conducting batch sedimentation test. 8. To determine minimum fluidization Velocity & to verify Ergun’s Equation. 9. To determine separation efficiency by using froth flotation cell. 10. To determine separation efficiency by using magnetic separator. 11. To determine efficiency of Cyclone separator. 12. Any one Experiment based on the syllabus of subject Mechanical Operation.

_______________________________________________________________________________________________

Topics to be covered at the time of practicals:

1. General purpose Machine Tools. 2. Joining Processes. 3. Pattern making and Foundry.

List of Practicals:

1. One job on lathe with taper turning thread cutting, drilling. 2. One job on lathe + milling machine – keyway cutting, gear cutting etc. 3. One job of welding. 4. One job of pattern making and foundry – one simple job of non- ferrous material.

A record of the work performed should be presented in the form of a journal based on topics under (A) and the jobs completed under practicals (B).

Reference Books:

Hajra Choudhary; Workshop Technology; Vol. I & II

Workshop Practice

Industrial training shall be as per norms of the institute. The list of industries where students can undergo training will be approved and published by the department. Period of training will be during vacation without affecting regular class work/examination. During the training, the student shall study/analyze the operation/process/design or the complete industry in detail. They shall submit a report in detail identifying the problems with their suggestion for solution and conclusions to the department through the faculty coordinator assigned for the same at the end of the training period. The minimum duration of industrial training is 1-2 weeks. A committee consisting of two faculty of the department will carry out assessment of the training. Students shall make a presentation before the committee.

Industrial Training I

(To be evaluated in Fifth Semester)

Code No.

Subject Teaching Scheme Examination Scheme Total Theory Practical TW/

Drawing Paper Practical Oral TW

4

100 100

3

2

100

25 125

4

2

100

50 150

3

100 100

4 50 50

Subject Code No.

Subject Teaching Scheme Examination Scheme Total Theory Practical TW/

Drawing Paper Practical Oral TW

4

4

100

50

150

3 2 100

50

25 175

3

2

100

50 150

(to be evaluated in Seventh Semester)

-

Total 18 8 4 500 100 100 50 750

BCE-501 Chemical Engineering Mathematics

BCE-502 Mass Transfer I 4 2 100 50 25 175

Subject

Semester-V

Semester-VI

50 50

Total 18 10 500 50 50 150 750

BCE-503 Industrial Organization & mgmt

BCE-504 Chemical Process Technology

BCE-505 Chemical Engineering Thermodynamics II

BCE-506 Computer Aided Chemical Engineering I

BCE-507 Industrial Training I (Evaluation)

BCE-601 Chemical Reaction Engineering I

BCE-602 Transport Phenomena 4 100 100 BCE-603 Chemical Engineering

Design I BCE-604 Mass Transfer II 4 2 100 50 150 BCE-605 Process

Instrumentation & Control

BCE-606 Seminar 2 25 25 Industrial Training II

Chemical Engineering Mathematics

________________________________________________________________________ Unit 1: Error and Roots of Equation Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods: Error Definition, Round of Error, Error Propagation, Total Numerical Error Bracketing method: Graphical, Bisection, False-Position. Open Method: Single variable Newton Raphson, Multi-Variable Newton Raphson, Secant, Multiple roots. Roots of Polynomial: Muller, Baristow Unit 2: Linear Algebraic Equation Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods Naïve Gauss Elimination, Gauss-Jordon Elimination, LU Decomposition, Tridiagonal Systems (Thomas Algorithm), Cholesky decomposition, Gauss Seidel and Relaxation Methods. Eigen values and Eigen Vectors of Matrices: Faddeev-Leverrier, Power and Householder and Givens Method Unit 3: Regression Analysis and Interpolation Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods Linear Regression, Polynomial Regression, Multiple Linear regression, Non-linear regression, Newton’s Interpolation, Newton’s Divided Difference Interpolation Polynomial, Lagrangian Interpolation. Statistical Analysis: Orthogonal Collocation, Surface Responce Numerical Integration: Trapezoidal method, Simpson 1/3rd rule, Simpson 3/8th rule Unit 4: Ordinary Differential Equation: Initial Value Problems

Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods Euler’s method, Modified Euler’s method, 2nd order Runge Kutta Method, 4th order Runge-Kutta method, Systems Equation Ordinary Differential Equation: Boundary Value Problems Polynomial method, Power method, Finite Difference Technique, Orthogonal Collation Finite Element, Galerkin Finite Element method Unit 5: Partial Differential Equation Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods Elliptical Equation, Control Volume Approach, Heat Conduction Equation, Explicit method, Implicit method, Crank Nicolson method, Finite Difference method, Galerkin Finite Element Unit 6: Optimization

Problems based on Process Calculation, Fluid Flow operation and Heat Transfer to be solved using following methods Basic concept of optimization and formulation, Nature of optimization Unconstraint One Dimension Methods: Newton’s Method, Quadratic Interpolation, Cubic Interpolation Unconstraint Multiple Variable: Random search, Grid search, Simplex search, Quasi-Newton method

References

1. Steven C Chapra, Raymond P Canale, ‘Numerical Methods for Engineers’, 5th Edition, Tata McGraw-Hill Publishing Company Limited, New Dehli, 2007

2. Santosh K Gupta, ‘Numerical Methods for Engineers’, New Age International Publishers Limited, 1995

3. Thomas F Edgar, David M Himmeblau, Leon S Lason, ‘Optimization of Chemical Processes’, 2nd Edition, Mc-Graw Hill Publication, 2002

4. S. Balgurusamy, ‘Numerical methods’, Tata McGraw Hill Publication, New Dehli, 2008

5. Curtise F Gerald, Patrick O Wheatley, ‘Applied Numerical Analysis’, 6th Edition, Pearson Education Asia, 2002.

Mass Transfer I _______________________________________________________________________________________________Unit 1: Introduction General principles of Mass Transfer, classification of Mass Transfer Operations, choice of separation method, methods of conducting mass transfer operations, design principles. Diffusion Mass Transfer Molecular Diffusion in gases and liquids, diffusivities of gases and liquids, types of diffusion, Fick’s and Maxwell law of diffusion, diffusion in solids, unsteady state mass transfer. Unit 2:

Mass transfer Coefficients in laminar flow and turbulent flow, theories of Mass transfer, mass, heat and momentum transfer analogies. Inter-phase mass transfer, equilibrium in mass transfer, the two resistance theory, continuous cocurrent, countercurrent and crosscurrent processes, cascades. Unit 3: Gas Absorption Mechanism of gas absorption, equilibrium in gas absorption, application of mass transfer theories to absorption, absorption in wetted wall columns, values of transfer coefficient, absorption in packed tower and spray tower, calculation of HETP, HTU, NTU, calculation of height of packed and spray tower. Absorption in tray towers, absorption and stripping factors, tray efficiencies, calculation of number of trays for absorption, absorption with chemical reaction. Unit 4: Humidification and Dehumidification Principles, vapour-liquid equilibria, enthalpy of pure substances, basic definition of all humidification terms, wet bulb temperature relation, psychrometric chart, Lewis relation, methods of humidification and dehumidification, equipment like cooling towers, tray towers, spray chambers, spray ponds, cooling tower design – HTU, NTU concept, calculation of height of cooling tower. Unit 5: Equipment for gas liquid operation Gas dispersal equipment – bubble columns, mechanically agitated vessels, tray towers. Liquid dispersal equipment – Venturi scrubbers, wetted wall columns, spray towers, packed columns Unit 6 : Drying Principles, equilibrium in drying, type of moisture binding, mechanism of batch drying, continuous drying, time required for drying, mechanism of moisture movement in solid, design principles of tray dryer, rotary dryer, drum dryer, spray dryer, fluidized bed and spouted bed dryer, pneumatic dryer and vacuum dryer.

Reference books :

1) Mass Transfer Operations – Treybal R.E., McGraw Hill 2) Chemical Engineering, Vol I & II – Coulson J.M. and |Richardson J.F.,

McGraw Hill 3) Principles of Unit Operations in Chemical Engineering, Foust A.S. 4) Separation Techniques – King C.J. 5) Design of Equilibrium Stage Processes - Smith B.D. 6) Unit Operations of Chemical Engineering, McCabe W.L. and Smith J.C. ,

McGraw Hill List of Practicals

1) Tray Dryer – To calculate rate of Drying 2) Rotary Dryer – To study the Characteristics of Rotary Dryer 3) Spray Dryer – To study the design and Operating Principles of Spray Dryer 4) Fluidized Bed Dryer – To study the characteristics of Fluidized bed Dryer 5) Liquid Diffusion – To calculate the Diffusion Coefficient for a liquid –liquid

system 6) Winkelmann’s method – To find the diffusion Coefficient of vapour in still air 7) Enhancement Factor – To find the enhancement factor for absorption with and

without chemical reaction 8) Mass transfer Coefficient – To determine the Mass Transfer Coefficient for

Absorption in a Packed Tower 9) Cooling Tower– To study the characteristics 10) Humidifier and Dehumidifier – To study the Characteristics 11) Interphase Mass Transfer Coefficient – To calculate the individual and overall

Mass Transfer Coefficient 12) Wetted Wall Column – To find the mass transfer coefficient in a wetted wall

Column

Note On Term Work :

• Minimum number of experiments – 8 • Minimum number of assignments – 2 ( out of remaining experiments) • Besides experimental work, evaluation of term work should be done through

periodic tests • Record of assessment of practical should be maintained on continuous basis

Unit 1:

1) Management for Business and Industry-C.S. George Jr. 2) Principles of management- Knoots and O.Donnell. 3) Business Organization and management- M.C. Shulka

Industrial Organization And Management

Management Science: Management, its growth, concepts of administration and management of organization. Definition of management, functions, authority and responsibility. Unity of command and direction Decision making in management by objectives. Business Organization: Different forms of organization, their formation and working, Different organization structure- line organization, functional organization, line and staff organization. Unit 2: Personnel Management: Manpower planning, sources of recruitment, selection and training of staff. Job evaluation, merit rating, performance appraisal, wage administration and system, of wage payment, incentive, motivations, industrial fatigue, Trade unions – industrial relations. Unit 3: Purchase and stores management: Concepts of quotation, tenders and comparative statement, inspection and quality control, Inventory, carrying cost and fixed cost of inventory, examples of cost of Inventory, Stores management, functions of storekeeper, methods of inventory : LIFO, FIFO. Unit 4: Marketing management: Concepts of selling, marketing, definition of marketing, market research and of pricing, penetration, pricing, skimming pricing, distribution of product, advertising and promotion. Unit 5: Export and import management: Concepts of international trade, duties, antidumping duty, cost involved in exporting a product, pricing of export product. Government aids for export promotion, export houses, export promotion counsel, MODVAT, patent and patent rights. Quality Management: TQM, quality circles, ISO systems. Unit 6: Management Laws: Concepts of contract act, offer, and acceptance, types of contracts, Void contract, concept pf guarantee and warranty. Introduction of MRTP and FERA. Work study: Work Measurement, motion and time study flow process chart, flow diagram, sio chart, string chart, therbligs. Practicles: Reference Books

i) Chlor – Alkali Industry: Production of Soda Ash, NaOH and Chlorine ii) Sea Chemicals: Sodium – Magnesium compounds, Different methods for

different salt recovery. iii) Electrolytic Industry: Production of Aluminium, Magnesium.

Nitrate. ii) Phosphorous Industry: Production of Phosphoric acid, single and triple

Super Phosphate, Ammonium Phosphate. iii) Sulphur Industry: Production of Sulphur, Sulphuric acid, Ammonium

i) Sugar – Starch Industry: Production of Sugar, Starch Derivatives ii) Paper and Pulp Industry: Kraft Pulp Process, Sulphite Pulp Process,

Production of Paper. iii) Fermentation Industry: Production of Ethyl Alcohol, Absolute Alcohol.

Coke Oven – Construction, Working and Applications. ii) Oils and Fats : Basic Chemistry, Solvent Extraction Process,

Hydrogenation of Oil, Interesterification. iii) Soaps and Detergents: Chemistry- Cleaning Action, Production of Soap,

Natural Glycerin, Production of Detergents, Applications iv) Bio Pharmaceutical Industry: Production of Penicillin, Antibiotics.

Characteristics of Refineries- Refinery operations, Pyrolysis, Cracking, Reforming, Polymerization, Alkylation, Hydroalkylation, Isomerization, Hydrogenation.

Hydrocarbons ii) C2 Compounds: Production of Ethylene and Acetylene- Steam Cracking of

Hydrocarbons, Ethylene Dichloride, Vinyl Chloride

Chemical Process Technology

Unit I: Basic Concepts: The process study should contain raw materials, flow diagram, detailed process description, major engineering problems, advantages and disadvantages of the process and product applications. Unit Operations, Unit Processes, Schematic representation and applications for unit operations and unit processes. Chlor- Alkali And Elctrolytic Industry, Sea Chemicals:

Unit II: Nitro- Phosphorous Industry And Sulphur Industry: i) Nitrogen Industry: Production of Ammonia, Nitric acid, Urea, Ammonium

Sulphate. Unit III: Sugar- Starch, Paper – Pulp And Fermentation Industry

Unit IV: Natural Chemicals: i) Coal Chemicals: Destructive Distillation of Coal, Types of Carbonization,

Unit V: Industrial Gases And Petroleum Industry: i) Industrial Gases: Producer gas, Fuel Cell, Natural Gas, Water gas ii) Petroleum Industry: History of Production of Crude Petroleum,

Unit VI: Petrochemical Industry: i) C1 Compounds: Production of Methanol, Formaldehyde, and Halogenated

iii) C3 Compounds: Production of Propylene by Indirect Hydration, Acetone, Cumene

iv) Aromatic Compounds: Production of Phenol, Phthalic Anhydride, and Styrene

References:

1. Chemical Technology Vol. I, II, III, IV Chemical Engg. IIT Madras 2. Outlines of Chemical Technology, Dryden 3. Unit Processes in Organic Synthesis, Groggins P., McGraw Hill. 4. Chemical Process Industries, Shreeve R.N., McGraw Hill. 5. Industrial Chemicals, Feith – Keys and Clerk.

Term work/ Practical:

1. Heat and Mass balance calculations of any two processes using simulator like Preparation of Ketone, Ester.

2. Process flow sheets drawing of any two processes using CAD. 3. Industrial Visit to Inorganic compound manufacturing unit 4. Industrial Visit to Organic compound manufacturing unit 5. Preparation of soap, 6. Liquid Detergent 7. copper pigment, 8. Phenol formaldehyde resin, 9. Sodium Phenolate, 10. Barium sulphate, 11. Alcohol using fermentation

Unit: 1 Solution Thermodynamics: Fundamental property relations, chemical potential, effect of T and P on chemical potential, criteria for phase equilibrium, partial properties, ideal gas mixtures, fugacity and fugacity coefficients for pure species, for species in solution, generalized correlations, ideal solutions. (7lectures) Unit 2: Solution Thermodynamic applications: excess properties, VLE data- fugacity, activity coefficients, excess Gibb’s energy, Margules equation, van Laar equation, property changes of mixing. (7lectures) Unit : 3: Vapor – liquid equilibrium : The nature of equilibrium, criteria of equilibrium, effect of T and P on VLE, azeotropes, the phase rule, Duhem’s theorem, Raoult’s law, VLE by modified Raoult’s law, dew point and bubble point calculations, VLE from K-value correlations, Flash calculations (8 lectures) Unit: 4: Phase Equilibria: Equilibrium and stability, liquid -liquid equilibrium, solid- liquid equilibrium, osmotic equilibrium and osmotic pressure, thermodynamic consistency. (8 lectures) Unit 5: Chemical Reaction Equilibria: The reaction coordinates, Application of the criteria for equilibrium to chemical reactions, the standard Gibbs free energy change and the equilibrium constant, effect temperatureon equilibrium constant, evaluation of the equilibrium constant (7lectures) Unit 6: Equilibrium constant: relation of equilibrium constant to composition, calculation of equilibrium conversion for single reaction. The phase rule and Duhem’s theorem for reacting systems, multireaction Equilibria

Reference Books: 1) Introduction to Chemical Engineering Thermodynamics: J. M. Smith & H. C.

Vanness 2) Principles of Chemical Equilibrium : Kenneth Denbigh 3) Chemical Engineering Thermodynamics : B. F. Dodge 4) Chemical Engineering Thermodynamics : T. E. Daubert 5) Thermodynamics for Chemists : Glasstone S. 6) Thermodynamics for Chemical Engineers: Weber and Meissner 7) Chemical and Process Thermodynamics: B. G. Kyle 8) Molecular Thermodynamics: Praunitz 9) Chemical Engineering Thermodynamics : Narayanans

Chemical Engineering Thermodynamics II

Minimum 12 practical and a compulsory home paper Applications of Numerical Techniques in Chemical Engineering to be evaluated by following methods: Topics may include but are not restricted to: 1. Eigen values and Eigen vector computations for Level Control Applications. 2. Applications of Vectors to problems in Fluid Mechanics, Continuity equations, Stream lines, Equations of motion, Bernoulli’s equations. 3. Numerical interpolation 4. Numerical integration. 5. Integration of ODE – Equation for Batch Reactions. 6. Numerical differentiation. 7. Root-finding method – two non linear equations. 8. Linear programming for solving Liquid Level in Tank model. 9. Data fitting. 10. Process calculation using MS-EXCEL. 11. Application of neural networks. 12. Fuzzy logic applications. 13. Application of support vector machines. 14. Design Algorithms 15. Non-linear optimization methods-Interacting and non interacting systems 16. Regression Analysis.

Home paper for each student or group of students is compulsory. (A paper written by a student may be five to six pages in double spacing, a few figures may get added.)

Computer Aided Chemical Engineering – I.

Industrial Training I

_______________________________________________________________________________________________ Evaluation of Industrial training carried out by students after Semester IV is to be evaluated.

Reference: 1) Chemical Reaction Engineering: Levenspile O. 2) Chemical Engineering Kinetics: Smith J., 3) Elements of Chemical Reaction Engineering: H. Scott, Fogler.

Experiments: Minimum of ten experiments should be performed. Suggested list is as below

1) Study of first order reaction.

SEMESTER VI

Chemical Reaction Engineering –I

Unit: 1 Kinetics of Homogeneous Reactions: Defining a rate equation and its representation, single and multiple reactions, elementary and non elementary reactions, molecularity and order of reactions, kinetic models for non-elementary reactions, searching mechanism, rate controlling step. Unit: 2: Analysis and interpretation of Batch Reactor data: Constant volume batch reactor, integral and differential methods of analysis, variable volume batch reactor, integral and differential methods of analysis. Unit: 3: Reactor Design: Introduction, conversion of mass in reactors, performance equation for ideal stirred tank reactor, tubular flow reactor, batch reactor, space time and space velocity. Isothermal Reactors for single Reactions: Batch reactor, mixed versus plug flow reactors and second order reactions, graphical comparison, multiple reactor system, plug flow reactors in series & / or in parallel, equal size mixed reactors in series, reactors of different types in series, reactors of different types in series, recycle reaction (flow, batch), auto-catalytic reaction, non- steady flow semi-batch reactors. Unit: 4: Multiple reactions: Parallel and series reactions, performance of various ideal reactors, qualitative and quantitative discussion for multiple reactions, instantaneous and overall fractional yield. Unit: 5: Temperature and pressure effects: Temperature dependency from Arrhenius law, thermodynamics, collision theory, transition state theory, comparison of theories, rate of reactions predicted by theories, single reactions: heat of reaction from thermodynamics, equilibrium constants from thermodynamics, graphical design procedure, heat effects, adiabatic operations, non adiabatic operations.

Unit: 6: Deviations from Ideal Reactor: Self mixing of a single fluid & two miscible units. Residence time distribution, F,C,E, curve and relation between them. Models for non-ideal reactions, dispersion model, tanks in series model segregated flow model.

2) Inversion of sucrose 3) Study of pseudo first order reaction. Acid catalysed hydrolysis of methyl acetate 4) Study of a second order reaction – Saponification of ethyl acetate. 5) Determination of Arrhenius parameters 6) Study of homogeneous catalytic reaction, decomposition of hydrogen peroxide,

acid catalysed ester hydrolysis. 7) Batch fermentation of sucrose using invertase 8) Study of PFR 9) Study of CSTR 10) Study of CSTR combination in first order reactions 11) Study of F & C curves in CSTR 12) Study of F & C curves in Helical coil reactor 13) Study of PFR & CSTR combination in second order reaction

15

1. Introduction of viscosity and mechanism of momentum transport: Newton’s law of viscosity, Newtonian – Non-Newtonian fluids, pressure and temperature dependence of viscosity, theory of viscosity of gases and liquids.

2. Velocity distribution in laminar flow: Shell momentum balances of a) Flow of falling film b) Flow through the circular tube c) Flow through an annulus d) Creeping flow around a solid sphere e) Adjacent flow of two immiscible fluids

3. Equations of change for isothermal system a) the equation of continuity b) the equation of motion c) equation of change in curvilinear coordinate d) use of equation of change to set up steady flow problem e) equation of mechanical energy f) dimensional analysis of equation of change

4. Velocity distribution in turbulent flow: a) fluctuations and time smoothing quantities b) time smoothing of the equation of change for an incompressible

fluid c) semi empirical expression for the Reynolds

5. Interphase transport in isothermal system: a) defining friction factors b) friction factors for flow in tube, around spheres packed column

6. Macroscopic balances for Isothermal systems: a) the macroscopic mass, momentum and mechanical energy

balances b) estimation of the friction loss c) use of the macroscopic balances to set up steady flow problems.

Unit 3 & 4: Energy Transport: 18 hrs 1. The introduction of thermal conductivity and mechanism of energy

transport: Fourier’s law of heat conduction, temperature and pressure dependence of thermal conductivity in gases and liquids 2. Temperature distribution in solids and in laminar flow:

a) shell energy balance, boundary conditions b) heat conduction with electrical heat source c) heat conduction with a nuclear heat source d) heat conduction with a viscous heat source e) Heat conduction through composite walls. Addition of resistance

Transport Phenomena Unit 1 & 2: Momentum Transport:

f) forced and free convection g) heat conduction in a cooling fin

3. Temperature distribution in turbulent flow a) temperature fluctuations and time smoothed temperature b) time smoothing the energy equation c) semi empirical expressions for turbulent energy flux

4. Interphase transport in non- isothermal system a) definition of the heat transfer coefficients b) heat transfer coefficient for forced convection in tubes c) heat transfer coefficient for forced convection around submerged

objects d) heat transfer coefficients for forced convection through packed

beds e) heat transfer coefficients for free convection

Definitions of concentrations, velocities and mass fluxes, Fick’s law of diffusion, temperature and pressure dependence of mass diffusivity.

2. Concentration distribution in solids and in laminar flow: a) shell mass balances, boundary conditions b) diffusion through stagnant gas film c) diffusion with heterogeneous chemical reaction d) diffusion with homogeneous chemical reaction e) diffusion in falling liquid film: forced convection mass transfer

3. Concentration distribution in turbulent flow: a) concentration and the time smoothed concentrations b) time smoothing of the equation of continuity

a) definition of binary mass transfer coefficient in one phase b) co-relation of binary mass transfer coefficient in one phase at low mass

transfer rates c) co-relation of binary mass transfer coefficient in two phases at low mass

transfer rates d) definition of transfer coefficient for high mass transfer rates

Reference: 1. Transport Phenomena, Bird R. B., Stewart and Lightfoot, John Wiley & Sons 2. Momentum heat and mass transfer, Bennett C. O. Mayors. 3. Analysis heat and mass transfer, Eckert Erg and Brake R. M. 4. Fundamentals of momentum, heat and mass transfer, James Welty, Charles Wicks 5. “Energy Mass and Momentum transport phenomena in continua”, Slattery J. C.

Unit 5: Mass Transport: 1. Introduction of diffusivity and mechanism of mass transport:

Unit 6: 1. Simultaneous & Analogy momentum, heat and mass transfer. 2. Interphase transport in multi component system:

Chemical Engineering Design - I

Unit 1: Material Specifications- types of materials and their basic characteristics, Plastics as MOC for chemical plants, Materials for specific environments like high temperature, low temperature, corrosive services, Indian standards on materials Equipment Fabrication and Testing- Post weld heat treatment, inspection and non destructive testing of equipment, pressure tests, radiography tests, dye penetration tests, Freon test, magnetic test, Ultrasonic test Optimization techniques Unit 2: Pressure Vessels- Proportioning of pressure vessels, selection of L/D ratio, optimum proportions. Design of unfired pressure vessels: Types of pressure vessels, codes and standards for pressure vessels (IS: 2825; 1969), Pressure vessels subjected to internal pressure: Complete design as per IS: 2825: 1969 involving

1) Shells: cylindrical, spherical 2) Selection and design of various heads Pressure vessels subjected to external pressure: Design of shell, heads, stiffening rings as per IS: 2825; 1969 Flanges and Nozzles- Classification of flanges, types of flanges, Gasket - types, selection, and design, Bolt design and selection, flange thickness Nozzle reinforcement, design of compensation Unit: 3 High Pressure Vessels- Materials of construction, stresses in thick cylinder, pre-stressing of thick walled vessels, monoblock, multilayer, Autofrettage, shrink fitted shell, ribbon and wire wound vessel, Analysis and design of high pressure vessels including shell and head along with the stress distribution. Storage Vessels: Study of various types of storage vessels and applications, Atmospheric vessels, vessels for storing volatile and nonvolatile liquids, storage of gases, Losses in storage vessels, Various types of roofs used for storage vessels, manholes, nozzles and mountings. Design of cylindrical storage vessels as per IS: 803; should include base plates, shell plates, roof plates, wind girders, curb angles for self supporting and column supported roofs. Design of rectangular tanks as per IS: 804. Unit: 4 Design of Tall Vessels- Stresses in the shell of a tall vertical vessel, and period of vibration, Vessel Supports- Introduction and classification of supports, design of skirt supports considering stresses due to dead weight, wind load, seismic load, design of base plate, skirt bearing plate, anchor bolts, bolting chairs and skirt shell plates Design of saddle supports, ring stiffeners Unit: 5 Heat Exchangers- Codes and standards for heat exchangers, Shell and tube heat exchanger- General design considerations- LMTD correction factor, fluid allocation,

above mentioned equipments. b) Minimum four assignments using AutoCAD.

fluid velocities, stream temperatures, pressure drop, Shell side and tube side heat transfer coefficients Mechanical design of shell and tube heat exchanger- thickness of shell and shell cover, channel cover, tube sheet, size and number of tie rods and spacers Design of double pipe heat exchanger, Unit: 6 Design of Heat exchange equipments- Evaporators- Classification, criteria for selection, design Condensers-Heat transfer fundamentals, condensation outside horizontal tubes, condensation inside and outside vertical tubes, condensation inside horizontal tubes, condensation of steam, mean temperature difference, condensation of mixtures, pressure drop in condensers Reboilers and vaporizers - types, selection, boiling heat transfer fundamentals, estimation of boiling heat transfer coefficients, pool boiling, convective boiling, design of forced circulation reboilers, thermosyphon reboilers, and kettle reboilers Plate heat exchanger- Advantages, disadvantages, design procedure, temperature correction factor, heat transfer coefficients, pressure drop References: 1. “Process equipment design” by L.E. Brownell and E. Young, John Wiley, New York, 1963. 2. “Introduction to Chemical Equipment Design” by B.C. Bhattacharya C.B.S. Publications. 3. “Process Equipment Design” by M.V. Joshi, Mcmillan India. 4. “Chemical Engineering Vol. 6” by J.M. Coulson, J.F. Richardson and R.K. Sinott, Pergamon Press. 5. “Applied Process Design for Chemical and Petrochemical Plants” vol 1 and 2, Ludwig E.E., Gulf publishing company, Texas. 6. “Indian standards Institution” code for unfired pressure vessels, IS - 2825 7. “Chemical Process Equipment-Selection and design” Walas S.M. Butterworth Heinamen, McGraw Hill book company, New York 8. “Chemical Engineering volume 2” by J.M. Coulson, J.F. Richardson, and R.K. Sinott Pergamon Press. Term Work : a) Minimum four number of assignment related to Design and Drawing on

Mass Transfer II

Unit 1: Distillation Vapour – liquid equilibria for ideal and non-ideal systems, relative volatility, ideal solutions, azeotropes, positive and negative deviations from ideality, multi component system, methods of distillation - differential , flash, azeotropic, extractive, low pressure, steam distillation, batch rectification. Unit: 2 Continuous rectification for binary system, multistage (tray) towers, Lewis Sorrel, McCabe Thiele, and Ponchon Savarit methods for multistage operations, tray efficiencies, concept of reflux, mnimum reflux ratio, optimumreflux, total reflux, Fenske’s equation, reboilers, use of open steam, rectification of azeotropic mixtures. Partial and total Condensers, cold reflux, Fenske-Underwood equation, packed towers for distillation, NTU, HTU, HETP concept and calculations, concept of multicomponent distillation, distillation column internals. Unit: 3 Liquid-Liquid Extraction Ternary liquid equilibria, single stage extraction, multistage crosscurrent, countercurrent and cocurrent extraction, calculations based on triangular diagrams, x – y co – ordinates and solvent free basis. Continuous countercurrent extraction with reflux, total reflux, stage efficiency, continuous contact extraction in packed towers, HTU and NTU concept, types of extractors – stage type and differential type. Unit 4: Solid – Liquid Extraction (Leaching): Leaching equipment – continuous counter current leaching, ideal stage equilibrium, operating time, constant and variable underflow, number of ideal stages, stage efficiencies. Calculation of single stage and multistage leaching processes. Unit 5: Adsorption and Ion Exchange: Adsorption – Basic Principle and Equilibria in adsorption. Single gases and vapors – Adsorption of liquids. Types of adsorption – Physical and Chemical Adsorption Isotherms- Langmuir and Freundlich. Introduction to pressure Swing Adsorption (PSA), and Temperature Swing Adsorption (TSA). Equipments: Continuous Contact: steady state –moving bed Adsorbers. Ion Exchange- Principles of Ion Exchange, Techniques and applications, Equilibria and rate of ion exchange, equipments. Unit 6: Crystallisation & Novel Techniques: Principle rate of crystal growth, population balance and size distribution, calacultion of yield, enthalpy balances, equipment. Membrane separation techniques- Ultra filtration. Nanofiltration, reverse osmosis, Rate based processes such as diffusion coefficient based inert gas generation from air by carbon molecular sieves.

List of Practicals Any eight practicals to be conducted out of the following:

1. Simple Distillation 2. Total Reflux 3. Steam Distillation 4. Equilibrium Diagram for Liquid – Liquid Extraction 5. Characterization of Spray Extraction Column 6. York Schibel Column 7. Distillation using Sieve Plate, Bubble Cap Column 8. Batch/ Continuous Leaching 9. Process of Crystallization and its Characteristics 10. Batch Crystallization 11. Ion Exchange Term work will be based on the conduct of above practical.

Reference Books:

1. Treybal R.E. “Mass Transfer Operation” 2. Richardson J. F. and Coulson J.M. “ Chemical Engineering”, Vol. I , II 3. Foust A.S., “ Principles of Unit Operations” 4. Henley E. J. and Seader H.K. “Stage wise Process Design” , McGraw Hill 5. Smith B.D., “ Design of Equilibrium Stage Process”. 6. McCabe and Smith, “ Unit Operations in Chemical Engineering” 7. King C. J. “ Separation Processes”, McGraw Hill 8. A.L. Lyderson, “ Mass Transfer in Engineering Practices”, John Wiley.

21

Process Instrumentation And Control

---------------------------------------------------------------------------------------------------- Unit 1: Fundamentals of Process Instrumentation (PI): Need and scope of process instrumentation, classification of process variables, measurement problem analysis, basic measurement terms, Functional elements of instruments, static and dynamic characteristics of measuring instruments (zeroth, first, and second-order instruments/ systems), measurement system configuration, transducer elements (types and classification). Intermediate elements: Instrument amplifiers, compensators, differential and integrator elements, signal conditioners (signal generation and processing), filtering and signal analysis, data acquisition and conversion (ADC, DAC), digital signal transmission and processing (serial communication, telemetry), Indicating and recording elements, Microprocessors , microcontrollers, personal computer (PC) based instrumentation systems (virtual instrumentation using soft wares like Lab view) , input-output (I/O) devices and displays, calibration of instruments. Unit 2: Temperature, Pressure, and Strain Measuring Instruments: Temperature measuring instruments: Introduction, classification, temperature scales (units), mechanical temperature sensors (filled- system thermometers, expansion thermometers), electrical temperature sensors (RTD, thermistors, thermocouples), radiation sensors (optical and radiation), solid-state sensors, quartz sensors, calibration methods (comparison and fixed point). Pressure and strain measuring instruments: Introduction, classification, low , medium, and high pressure measuring instruments, pressure scales (units), manometers, elastic element pressure gauges with pressure equations (using bourdon tube, diaphragms, capsule, and bellows), transduction/ electrical sensors with pressure equations (based on variable capacitance, resistance, and inductance/reluctance-LVDT), force- balance transducers along with mathematical equations, solid-state devices, thin-film transducers, digital transducers, piezoelectric transducers ,vibrating element sensors, pressure multiplexer, calibration of pressure sensors using dead- weight tester. Mechanical, optical, and electrical strain gauges. Unit 3: Level and Flow Measuring Instruments: Level measuring instruments: Introduction, classification, direct methods (point contact methods, sight or gauge glass methods, buoyancy methods using floats and displacers), indirect methods (hydrostatic pressure methods, capacitance methods, radiation methods, ultrasonic methods , weighing method, sonic methods), solid level measurement. Flow measuring instruments: Introduction, classification (rate of flow and total flow meters), pressure head- type flow meters (orifice plate, venturi tube, flow nozzle, pitot tube), variable- area flowmeters (rotameters), electromagnetic, mechanical (positive

displacement and turbine- type), anemometer, ultrasonic- type, vortex- flow type, thermal- type, laser anemometers ,mass flow meters(cover mathematical treatment for all the sensors). Unit 4: Instrumental Methods of Chemical Analysis Introduction, classification, basic components of analytical instruments, measurements used Absorption and emission spectrometric methods: ultraviolet (UV), visible , and infrared (IR) spectroscopy, atomic absorption spectroscopy (AAS), mass spectroscopy, refractometry Chromatographic methods: gas chromatography (GC), liquid chromatography (LC), high performance liquid chromatography (HPLC). Electrochemical methods: measurement of Ph, colourimetric, conductometric, potentiometric. Process instruments and automatic on-line analysis Unit 5: Fundamentals of Process Dynamics (P.D.): Introduction to process dynamics (P.D.), mathematical tools for process control (Laplace transform, complex numbers), ideal forcing functions, control-relevant theoretical process modeling, transfer function and state-space models, poles and zeros of transfer function and their effect on dynamic response, block diagram representation, studying dynamic behavior of linear time invariant (LTI) systems, dynamic behavior of pure gain, pure capacitive, first- order, second-order systems, dead- time systems (derive differential equation model, transfer function, response to standard test signals and response characteristics along with physical examples), process identification using step response data . Unit 6: Feedback Control Systems Introduction to feedback control system (FBCS), classification of process variables, selection of controlled variable (CV), manipulated variables (MV), disturbance or load variables (DV), block diagram with essential variables and instrument elements, derivation of closed- loop transfer function for servo and regulator operations, classical feedback controllers -ON-OFF, P, PI, PD, PID (control equation/ law/ algorithm, tuning parameters, open-loop response characteristics along with effect of tuning parameters), simple control performance measures (rise time, overshoot, decay ratio, offset), closed- loop response characteristics of first- and second- order processes with classical controllers. Industrial process control Systems: Control system symbols used in process and instrumentation (P&ID) diagrams and drawings, basic regulatory control loops for controlling temperature of liquid heated in stirred-tank heater using electrical (or steam) heating, pressure of air/ gas in pressure vessel, level of liquid inside surge vessel, flow of liquid in pipe line. Single-loop controllers for surge vessel level control, reactors (batch and CSTR), heat exchangers, distillation column, pumps, compressors.

Reference books: 1. Instrument Engineers’ Handbook (Process Measurement)- Bella G. Liptak, Elsevier 2. Instrument Engineers’ Handbook (Process Control)- Bella G. Liptak, Elsevier 3. Instrumentation devices and systems- Rangan, Sharma, Mani, Tata McGraw Hill Publishing Co. Ltd. 4 .Instrumental methods of analysis – Willard, Merritt, Dean, Settle, CBS Publishers and Distributors 5. Instrumental approach to Chemical Analysis- Shrivastava, Jain, S. Chand and Co. 6. Handbook of Analytical Instruments- Khandpur, Tata McGraw Hill Publishing Co. Ltd. 7. Process Control- Bequette, PHI publications 8. Chemical process control- Stephanopoulos, PHI publications 9. Process Dynamics and Control- Seborg, Edgar, Mellichamp- John Wiley and sons Inc. Practicals:

1. Calibration and characteristics of temperature sensors 2. Calibration and characteristics of pressure sensors 3. Calibration and characteristics of level sensors 4. Calibration and characteristics of flow sensors 5. Instrumental methods of chemical analysis using GC, HPLC, AAS, UV

spectrophotometer, refractometer, pH meter, conductivity meter, etc. 6. Dynamic behavior of first- order systems 7. Dynamic behavior of second- order systems

Characteristics of ON-OFF, P, PI, PD, PID controllers applied to temperature, pressure, level, flow processes

Seminar _______________________________________________________________________________________________ The mini project may be a review of literature of specific phenomena/new process. Working model to demonstrate the principal, alternatively a small experimentation to investigate chemical engineering data/unit process/ unit operation. Based on this study focused report should be submitted.

25

_______________________________________________________________________________________________Industrial training shall be as per norms of the institute. The list of industries where students can undergo training will be approved and published by the department. Period of training will be during vacation without affecting regular class work/examination. During the training, the student shall study/analyze the operation/process/design or the complete industry in detail. They shall submit a report in detail identifying the problems with their suggestion for solution and conclusions to the department through the faculty coordinator assigned for the same at the end of the training period. The minimum duration of industrial training is 1-2 weeks. A committee consisting of two faculty of the department will carry out assessment of the training. Students shall make a presentation before the committee.

Industrial Training II

Code No.

Subject Teaching Scheme Examination Scheme Total Theory Practical TW/

Drawing Paper Practical Oral TW

Control 4 2 100 50 150

4

100 100

3

2

100 50

150

4

50 50

50 50

Code No.

Subject Teaching Scheme Examination Scheme Total Theory Practical TW/

Drawing Paper Practical Oral TW

Simulation 4 2 100 50 50 200

4 4 100 50

50 200

List of elective subjects: Subject Code No Elective I

Subject Code No Elective II

Environmental Engineering Chemical Process Synthesis Membrane Technology Advanced Materials Bioprocess Engineering Polymer Technology Corrosion Engineering Piping Design & Engineering

Advance Separation Processes

Petroleum Refining

Semester - VII Subject

Semester – VIII Subject

BCE-704 Chemical Reaction Engineering II

BCE-705 Chemical Engineering Design II

BCE-706 Computer Aided Chemical Engineering II

BCE-707 Industrial Training II (Evaluation)

BCE-708 Project 2 - Total 19 6 6 500 50 150 50 750

BCE-804 Process Engineering Costing & Plant Design

BCE-805 Project 6 50 100 150 Total 16 2 10 400 150 200 750

BCE-701 Elective – I 4 2 100 50 150 BCE-702 Elective- II 4 100 100 BCE-703 Process Dynamics and

BCE-701 BCE-702

BCE-801 Elective – III 4 100 100 BCE-802 Elective – IV 4 100 100 BCE-803 Process Modeling and

Subject Code No Elective III

Subject Code No Elective IV

Artificial Intelligence In Chemical Engineering Standardization and Quality Assurance in Chemical Process Industry

Energy Conservation In Chemical Process Industries Catalysis Chemical Process Safety Nanotechnology Food Technology Fuel Cell Technology

Petrochemical Engineering

Computer Aided Process Control

Open Elective*

BCE-802BCE-801

ELECTIVE-I

ENVIRONMENTAL ENGINEERING

Unit – I: Introduction An overview of environmental engineering, pollution of air, water and soil, impact of population growth on environment, environmental impact of thermal, hydro and nuclear energy, chemical pollution, solid wastes, prevention and control of environmental pollution, water and air pollution laws and standards, clean development mechanisms (CDM), Kyoto Protocol. Unit – II: Air Pollution- Sources, Effects and Measurement Definition of air pollution, sources scales of concentration and classification of air pollutants. Effects of air pollutants on human health, plants, animals, materials, Economic effects of air pollution, Sampling and measurement of air pollutants, Air pollution control standards: WHO, BIS, MPCB, CPCB. Unit – III: Air Pollution Control Methods and Equipment Particulate pollution: cleaning methods, collection efficiency, particulate collection systems, Basic design and operating principles of settling chamber, cyclone separator, fabric filter, electrostatic precipitator. Operating principles of spray tower, centrifugal scrubber, venturi scrubber. Selection of particulate collector. Gaseous pollution: Principles of control by absorption, adsorption, combustion or catalytic oxidation, removal of SOx, NOx. Numerical problems based on the theory. Unit – IV: Water Pollution Domestic and industrial wastewater, types, sources and effects of water pollutants. Waste water characteristics–DO, BOD, COD, TOC, total suspended solids, colour and odour, bacteriological quality, oxygen deficit, determination of BOD constants. Water quality standards: ICMR, WHO, MPCB and CPCB Unit – V: Wastewater Treatment Principles of primary treatment and secondary treatment, process design and basic operating principles of activated sludge (suspended growth) process, sludge treatment and disposal, trickling filter. Advanced methods of waste water treatment: UASB, photo catalytic reactors, wet-air oxidation, and biosorption. Unit – VI: Tertiary Water Treatment and Solid Waste Management: Tertiary treatment: disinfection by chlorine, ozone and hydrogen peroxide, UV rays, recovery of materials from process effluents, micro-screening, biological nitrification and denitrification, granular medium filtration. Land Pollution: Sources and classification of solid wastes, disposal methods, incineration, composting, recovery and recycling.

Seminars: Seminar should be based on theory. Students may undertake studies in design and development, analysis, synthesis, construction and fabrication of equipments, treatment plants. Critical review on product or system, generation of new concept, idea and improvement in existing process related to the subject. Visits to wastewater Treatment plant, Common Effluent Treatment Plant, Solid Waste Management Sites etc. should be arranged Term work should be based on the technical report on these studies carried out by individual or a small group of students. Modern audio-visual techniques may be used at the time of presentation. References:

1. Rao C.S. “Environmental Pollution Control Engineering”, Wiley Eastern Publications.

2. Metcalf and Eddy “Wastewater Engineering”, Tata McGraw Hill Publishers. 3. Mahajan S.P. “Pollution Control in Process Industry”, Tata McGraw Hill

Publishers 4. MyCock “Handbook of Air Pollution”. 5. Flagan R.C. and Seinfield J.H. “Fundamentals of Air Pollution Engineering” 6. Peavy H.S. and Rowe D.R. and Tchobanoglous G. “Environmental Engineering” 7. Martin Crowford “ Air Pollution Control theory” 8. Stern “Air Pollution”, Vol.-I and Vol.-II. 9. G.Kiely, Environmental Engineering, McGraw Hill 1997.

ELECTIVE-I

Unit I:. Introduction: Separation processes, introduction to membrane processes, history, definition of a membrane, membrane processes. Materials and Material Properties: Introduction, polymers, stereoisomerism, chain flexibility, molecular weight, chain interactions, state of the polymer, effect of polymeric structure on Tg, glass transition temperature depression, Unit II. Preparation of Synthetic Membranes: Introduction, preparation of synthetic membranes, phase inversion membranes, preparation technique for immersion precipitation, preparation technique for composite membranes, Unit IV. Characterization of Membranes: Introduction, membrane characterization, characterization of porous membranes, characterization of ionic membranes, characterization of non porous membranes. Unit V . Transport in Membranes: Introduction, driving forces, non equilibrium thermodynamics, transport through porous, non porous, and ion exchange membranes. Membrane Processes: Introduction, osmosis, Pressure driven membrane processes, concentration driven membranane electrically driven processes, membrane reactors. Unit VI . Polarization phenomenon and fouling: introduction, concentration polarization, turbulence promoters, pressure drop, gel layer model, osmotic pressure model, boundary layer resistance model, concentration polarization in diffusive membrane separations and electro dialysis, membrane fouling, methods to reduce fouling, compaction. Module and process design: Introduction, plate and frame model, spiral wound module, tubular module, capillary module, hollow fiber model, comparison of module configurations. Texts 1) M.H.V. Mulder, Membrane Separations. Kluwer Publictions References: 2). S.P. Nunes, and K.V. Peinemann, membrane Technology in the chemical industry, Wiley-VCH. 3) R. Rautanbach and R.Albrecht, Membrane Process, John Wiley & Sons. 4). R.Y.M. Huang, Perevoparation Membrane Separation Processes, Elsevier. 5). J.G. Crespo, K.W. Boddekes, Membrane Processes in Separation and Purification, Kluwer Academic Publications. 6). Larry Ricci and the staff of chemical engineering separation techniques, Mc Graw Hill publications. Seminars: Seminar should be based on theory. Students may undertake studies in design of equipment, treatment plants. Plant visits may be encouraged. Term work should be based on the technical report on these studies carried out by individual or a small group of students. Modern audio-visual techniques may be used at the time of presentation.

MEMBRANE TECHNOLOGY

ELECTIVE-I

BIOPROCESS ENGINEERING

Unit I: Introduction to biomass Bio-chemicals: Introduction to structure of cells, important cell of types, growth of microbial cells. Bio-chemicals: Primary, secondary, tertiary structure of biomacromolecules such as lipids, sugars and polysaccharides, nucleotides, RNA, DNA, amino acids, proteins, hybrid biochemical etc interactions of these molecules, structure and functions of biomembranes, Osmoregulations interacting toxins. Unit II: Applications of Bioprocesses in Chemical Industry: Discuss manufacturing process for major products produced by biochemical reactions such as penicillin, vitamins A, alcohol, acetic acid and vinegar, acetone, lactic acid, citric acid, wine, proteins. Aerobic and anaerobic waste-watr treatment. Unit III: Kinetics of Enzyme catalyzed reactions: Enzyme substrate complex and enzyme action with example from industrial enzymes, simple enzyme, kinetics with one and two substrate. Michaelis-Menten kinetics. Models of enzymes kinetics with brief introduction, substrate activation and inhibition. Multiple substrates reacting on a single enzyme. Protein denaturation by chemical agent and heat. Numerical problems based on theory. Unit IV: Applied Enzyme Catalysis: Kinetics of substrate utilization, production formation and biomass production in cell cultures. Cell in cell culture system. Computer application for kinetics developments. Numerical problems based on theory. Unit V: Transport Phenomena in bioprocess system: Modification in the design and analysis of chemical reactor as biological reactors. Computerized simulation of bioreactor. Fed batch reactor, CSTR plug flow reactors, Reactor dynamics, reactor with non-ideal mixing sterilization of reactors, immobilized biocatalyst, multiphase bioreactors, fermentation technology. Unit VI: Product recovery operations and Bioprocess economics: Dialysis, Reverse osmosis, ultra-filtration, and Micro-filtration, Chromatography, electrophoresis, electro dialysis, crystallization and drying. Bioprocess economics.

Seminars: Seminar should be based on theory. Students may undertake studies in design of equipment, treatment plants. Plant visits may be encouraged. Term work should be based on the technical report on these studies carried out by individual or a small group of students. Modern audio-visual techniques may be used at the time of presentation. References:

1 Bailey, James E Ollis, Davis F: “Biochemical Engineering”, McGraw Hill. 2 Aiba A-Humphery A.E., Mills N.F., “Biochemical Engineering”, Academic Press. 3 Atkinson B.,” Biochemical Reactors”, Pion Ltd. London. 4 Ghosh T.K., et. Al., “Advances in Biochemical Engineering”, Vol.1/3, Springer

Verlag 1971-74 5 Biochemical and Biological Engineering science, Vol. 1 and 2. 6 Wingard L.B., “Enzyme Engineering”, Fr. Interscience N.Y. 1972. 7 Shular and Kargi “Bioprocess Engineering” Prantice-Hall 2nd Ed. 2003.

ELECTIVE-I

CORROSION ENGINEERING

Unit I: Introduction and Scope: Corrosion: Definition, wet and dry corrosion, mechanism, electro-chemical principles and aspects of corrosion, Faradays laws, specific conduction, specific resistance, transport no. mobility etc. Various forms of corrosion, a brief review of corrosion. Rate expressions. Thermodynamic aspects of corrosion, equlibrium potential, Narnst equation for electrode potential. EMF series, overvoltage, application of Nernst equation to corrosion reactions, calculation of corrosion rates. Unit II: Polarisation and corrosion potentials: Reference electrodes for corrosion measurements, types of polarisation, concentration, activation and resistance polarisations, Tafel equation, Tafel constant, Evans Diagrams. Anodic control, cathodic control, mixed control. Pourbaix-diagram for Fe -H2O system. Unit III: Galvanic corrosion, uniform attack, pitting corrosion, dezincification, cavitation, erosion, fretting corrosion, intergranular and stress corrosion cracking. Remedial measures for the above. Unit IV: High temperature oxidation, Pilling Bedworth ratio, mechanisms of Oxidation, corrosion, testing procedures and evaluation: Corrosion of iron and steel in Aqueous media, Effect of velocity, temperature and composition of media. Unit V: Prevention techniques, modification of the material by alloying, appropriate heat treatment. Chemical and Mechanical methods of surface treatment coatings - metallic, non-metallic linings, cathodic protection, passivity and anodic protection. Text Books: 1. Corrosion Engineering by Fortana and Greena. 2. Corrosion and Corrosion Control, H.H. Uhllg. Reference Books: 1. Electrochemistry by Samuel Glasstone. Seminars: Seminar should be based on theory. Students may undertake studies in design of equipment, treatment plants. Plant visits may be encouraged. Term work should be based on the technical report on these studies carried out by individual or a small group of students. Modern audio-visual techniques may be used at the time of presentation.

ELECTIVE-II

1. Chemical Process Design, Robin Smith. 2. Conceptual Design of Chemical Process-James Douglas 3. Unit process in organic synthesis –P.H. Grogins

CHEMICAL PROCESS SYNTHESIS

Unit I: Introduction Of Chemical Process Design: Introduction, Approach to Process Development, Development of New Process, Different Considerations, development of Particular Process, Overall Process design, Hierarchy of Process Design, Onion Model, Approach to Process Design. Unit II: Choice Of Reactor: Reaction Path, Types of Reaction Systems, Reactor Performance, Idealized Reactor Models, Reactor Concentration, Temperature, Pressure, Phase, Catalyst )Unit III: Choice Of Separator: Separation of Heterogeneous Mixtures, Separations of Homogeneous Mixtures, Distillation, Azeotropic Distillation, Absorption, Evaporation, Drying etc. Unit IV: Distillation Sequencing: Distillation Sequencing using simple columns, Heat Integration of Sequences of Simple Distillation Columns, Distillation Sequencing using thermal coupling, Optimization of Reducible Structure .Unit V : Heat Exchanger Network And Utilities: Energy Targets, Composite Curves, Heat Recovery Pinch, Threshold Problems, Problem Table Algorithm, Process Constraints, Utility Selection, Furnaces, Combined Heat and Power, Integration of Heat Pump, Integration of Refrigeration Cycles, Overall Heat Exchanger Network and Utilities . Unit VI: Safety And Health Considerations: Fire, Explosion, Toxic Release, Intensification of hazardous Materials, Attenuation of Hazardous Materials, Quantitive Measures of Inherent Safety, Overall Safety and Health Considerations. References:

ELECTIVE-II

References

1. Richorson R.W., Modern Ceramic Engineering, (Marcel Dekker) 2. Composites , Chawala K.K. 3. FRP Technology, Weatherhead. 4. Engg. Polymers, Dyson R.W. 5. Polymers of high technology, electronics and photonics, Bowden M.J & Tumber S.R.

ADVANCED MATERIALS

Unit I: Advanced Metallic Systems. Steels for special applications, Austempered Ductile Iron.

Unit II: Advanced Polymeric Materials. New polymeric materials such as Kevlar, Nomex, UHMWPE and Fiber Technology.

Unit III: Advanced Ceramic Materials. Advanced powder synthesis techniques. Advanced processing methods. Microstructural design and grain boundary engineering. Case studies.

Unit IV: Introduction to Composite Materials, Factors influencing the properties of composite materials like fiber parameter, matrix, interface & molding methods . Phase selection criteria. Reinforcing mechanisms. Interfaces, advantages and disadvantages. Polymer Composites. Reinforcing and matrix materials. Prepregs. Fiber winding techniques. Fabrication techniques. Laminates. Mechanical behaviour, etc.

Unit V: Metal Composites. Types of reinforcement. Chemical compatibility. Fabrication processes. Mechanical behaviour and properties. Ceramic Composites. Matrices and reinforcement. Why to reinforce ceramics. Fabrication methods. Crack propagation and mechanical behaviour.

Unit VI: Carbon composites, their properties, fabrication methods and their applications. Ablative polymers, their applications, air craft materials, Introduction to Nanomaterials. Synthesis & Characterization of nanomaterial, application of nanomaterials with special reference to Chemical Engineering.

ELECTIVE-II

1. Principals of Polymerization, Odion G.G., MaGraw Hill. 2. Text Book of Polymer Science, Billmer F.W, John Wiley & Sons. 3. Polymer Science, Gowarikar et al. 4. Text Book of Polymer Science, F. Rodrigues. 5. Polymer Science & Technology, Fried J.R., PHI. 6. Rubber Technology & Manufacturing, Blow C.M., Hepbun C. 7. Synthetic Rubbers Chemistry & Technology, D.C. Blackly. 8. Plastics by Brydson.

POLYMER TECHNOLOGY

Unit – I Introduction and Classification of Polymers. Thermosets, Thermoplastics, Linear Branch, Cross Linked Polymers. Factors influencing the polymer properties. Unit – II Addition & Condensation polymers, Polymerization Techinques, Bulk Solution Suspension, Emulsion, Interfacial Polymerization with their merits & Demerits. Unit – III Molecular Weights, Mn, Mw, Mv, Polydispersity Index. Different Methods of determination of Molecular weight. Effect of Molecular weight on Engg. Properties of Polymers, Numerical based on theory. Unit – IV Kinetics of free radical polyumerization (initiation propagation & termination.) Chain transfer agents. Kinetic of Step growth polymerization. Copolymers & its Kinetics Coordination Polymerization. Unit – V Polymer additives, compounding. Fillers plastisizers lubricants colourants UV stabilizers, fire retardants, antioxidants. Different moulding methods of polymers. Unit – VI Manufacturing of typical polymers with flow-sheet diagrams, their properties & applications : PE, PP, PS, PPO, Teflon Polyesters, Nylons, Kevlar, Nomex. Thermosets like Epoxies, unsaturated polyesters, phenolics, vinyl esters, cynate esters etc.Elastomers like natural rubber, butyl, neoprene, Bunas Silicons, Thiokol etc. Numerical/Problems based on Theory References:

ELECTIVE-II

PIPING DESIGN AND ENGINEERING

Unit I: Line sizing and optimization A brief revision covering friction factor, pressure drop for flow of non-compressible and compressible fluids, (Newtonian Fluids), pipe sizing, economic velocity. Pipe line networks and their analysis for flow in branches, restriction orifice sizing. Non-Newtonian fluids – types with examples, pressure drop calculations for Non-Newtonian fluids.

Unit II : Materials for Piping system Desirable properties of piping materials, materials for low, normal and high temperature services, materials for corrosion resistance. Common ASTM and IS specifications for: Seamless / ERW pipes, pipe fittings, flanges, and fasteners, materials for valves. Gaskets: Functions and properties, types of gaskets and their selection. Unit III: Types of Valves, Control Valves, Safety Valves, Constructional features, Criteria for selection. Piping components. Safety valves and other pressure relieving devices, constructional features, selection criteria.

Unit IV: Piping System Design Two phase flow, types of two phase flow, two phase flow as encountered in piping for steam, distillation column, related aspects of two phase flow such as pressure drop, vibrations. Important system characteristics and design principles related to steam flow at high and low pressures. Calculations for line sizing, steam traps, P.R.V. & condensive systems. Design principles and line sizing for vacuum pipelines, slurry pipelines, surge drums and flare stacks, vacuum devices including ejector system. Classification of pumps, compressors, fans and blowers. Considerations governing pump selection, analysis of system and pump characteristics in connection with series, parallel flow, minimum flow and equalizing lines, NPSH, allowable nozzle loads in various codes. Design principles and line sizing of pneumatic conveying of solids, components of conveying systems, dust and fume extraction systems principles. Unit V : Piping Layouts Introduction to P & I Diagrams, Process flow diagrams, standard symbols and notations. Introduction to various facilities required guidelines for Plot Plan / Plant Layout. Introduction to equipment layout, piping layout, piping isometrics and bill of material (Material take off exercise). Typical piping system layout considerations for following systems:

(i) Distillation systems and heat exchangers (ii) Reactors (iii) Pipe racks (iv) Storage tanks (v) Pumps

Unit VI: (Thermal Insulation for Piping) / Costing of Piping Purposes of Thermal Insulation. Principles of conductive and convective heat transfer to the extent of application to heat loss / gain through bare pipe surfaces. Critical thickness of insulation, estimating thickness of insulation, optimum thickness of insulation. Insulation for hot and cold materials and their important properties, insulation material selection criteria, typical insulation specification – hot and cold materials.

1. Piping Design Handbook by John J. Mcketta, by Marcel Dekker, Inc, New York. 2. Process plant layout and piping design by Ed Bausbacher & Roger Hunt (PTK

Prentice Hall Publication) 3. Piping Handbook Edited by Mohinder Nayyar 4. Pipe Drafting and Design by Roy A Parisher & Robert A. Rhea.

ASME Codes 31

References:

ELECTIVE-II

1) Mulder M. “Basic Principles of Membrane Technology”, Luksvar Academic. 2) Richardson – Coulson “Chemical Engineering Vol- 3 “, Pargmon. 3) Treybal,” Mass transfer Operations”, Mc GRaw Hill Publication. 4) Rousseau, “Handbook of Separation Process Technology”, Wiley –Interscience. 5) M.N. Sasteri, “Separation Methods” , Himalaya Publishing House. 6) Schweitzer, “Separation Techniques for chemical engineers”, Mc Graw – Hill

Publications. 7) King C. J. Separation Techniques.

ADVANCED SEPARATION PROCESSESS

UNIT I: General Principle, Temperature swing adsorption (TSA) Pressure swing adsorption (PSA), Liquid Chromatography processes- basic concepts, phenomena and their characterization, Chromatography options, separation systems, characteristics of solids and their selection for various applications, column design and filling, applications of chromatography in separation of enzymes and proteins, industrial examples. UNITII: Membrane Separation Process: Introduction, Principle classification, types of membranes, mechanisms of separation in MF,UF,RO, dialysis, electro dialysis, pervaporation, gas permeation,fouling,liquid emulsion membranes, industrial applications. UNIT III: Reactive Separations Separation based on reversible chemical complexation, reactive distillation, reactive extraction, reactive crystallization. UNIT IV: Bubble and Foam Separations: Foam formation, Collapse and drainage phenomena, and equipments, adsorption properties of foams, modes of operation of foam fractionation equipments, principle of froth flotation, properties of foam related to flotation operation, design and development of flotation equipment, applications to protein and enzyme separation and waste water treatment. UNIT V :Zone electrophoresis, Zone refining, Molecular sieves, Adductive crystallization. UNIT VI : Ultra centrifugation, recoil methods, Exchange reactions, ring oven technology, Selection of separation processes with case studies. References :

ELECTIVE-II

References: 1. Gary J H, Handwerk G E, ‘Petroleum refining’. 2. Speight J G, ‘The Chemistry and technology of petroleum’ 3. Myers, ‘Handbook of Petroleum Processing’.

PETROLEUM REFINING

Unit I. Petroleum composition, specifications of petroleum and some petroleum products such as LPG, Gasoline, Kerosene, Diesel oil and Engine oil. Unit II. Pre- refining operations such as, Settling, Moisture removal, Storage, Heating through exchangers and pipe seal heaters, Atmospheric distillation, Vacuum distillation. Unit III. Significant conversion units such as, Reforming, Cat-Cracking, Hydro-cracking and coking. Unit IV. Refining of petroleum products such as Acid refining, Chemical refining, Hydro-refining, HDS, HDM, HAD. Unit V. Blending, Additives, Storage of products, Transportation, Safety norms, House keeping, Marketing of petroleum and petroleum products. Unit VI. Recent trends in petroleum in terms of Distillation, Packing materials, Catalyst , etc.

PROCESS DYNAMICS & CONTROL

Unit1: Dynamic Behavior of Complicated Processes: Brief review of dynamic behavior of low-order simple processes (such as- pure capacitive, pure gain, first-order, and second order systems, dead-time systems), Dynamic behavior of systems with zeros, lead- lag systems, inverse response systems, Process identification using impulse, and frequency- response techniques. Unit 2: Stability analysis and design of single-loop feedback control systems: Brief review of single-loop feedback control systems and classical controllers, Stability analysis of feedback control systems using Routh- Hurwitz, root locus, and frequency- response techniques (Bode and Nyquist plots only). Simple and time-integral performance criteria for feedback control systems, design of feedback control systems using root locus and frequency response techniques, open and closed-loop methods of tuning of classical controllers, Unit 3: Design of Complex Control Systems: Design of controllers with difficult dynamics such as large time-delay systems, inverse- response systems.Analysis and design of control systems with multiple loops (cascade, selective, split range control systems).Analysis and design of advanced control systems (feedforward, ratio, adaptive and inferential control systems) Unit 4: Control of Multivariable Systems: (restricted to maximum third-order systems only) Introduction to multivariable systems, transfer function and state-space models, poles and zeros of multivariable systems, multiple single- loop controllers for multivariable systems, interaction analysis and loop pairing using the Relative Gain Array (RGA) method, decoupling, design of decouplers. Unit 5: Digital and Computer- based Control Systems: Sampling of continuous signals to discrete- time signals, reconstruction of continuous- time signals from discrete- time signals using hold elements, Digital approximation of classical controllers. Role of digital computer in process control as process interface for data acquisition and control, Centralized control systems, supervisory control systems (SCADA), microcomputer- based control systems (PLC, DCS) Unit 6: Introduction to Plant wide Control: Issues in plant wide control, process design and process control, internal feedback of material and energy, design of plant wide control systems for the plants involving reactors, flash unit, etc., effect of control structure on closed- loop performance. Recommended Books: 1. Instrument Engineers’ Handbook (Process Measurement)- Bella G. Liptak, Elsevier 2. Instrument Engineers’ Handbook (Process Control)- Bella G. Liptak, Elsevier 3. Instrumentation devices and systems- Rangan, Sharma, Mani, Tata McGraw Hill

Publishing Co. Ltd. 4 .Instrumental methods of analysis – Willard, Merritt, Dean, Settle, CBS Publishers and Distributors 5. Instrumental approach to Chemical Analysis- Shrivastava, Jain, S. Chand and Co. 6. Handbook of Analytical Instruments- Khandpur, Tata McGraw Hill Publishing Co. Ltd. 7. Process Control- Bequette, PHI publications 8. Chemical process control- Stephanopoulos, PHI publications 9. Process Dynamics and Control- Seborg, Edgar, Mellichamp- John Wiley and sons Inc. 10. Computer-based Industrial Control-Krishna Kant, PHI publications LIST OF PRACTICALS (Perform minimum 08 experiments from the following list)

1 .Characteristics of single-loop and advanced control systems such as cascade, ratio, split- range, feed forward control

2Multivariable/ multi process control systems 2. Study of plant wide control systems using dynamic simulators such as

UniSim, gPROMS, Hysis, etc. 4.MATLAB and SIMULINK exercises( using Control System Toolbox and System Identification toolboxes) on

3. Study of dynamic behavior of systems using LTI viewer 4. Comparison of open-loop and closed-loop response characteristics of

processes using different types of classical controllers 5. Root locus and frequency response design of control systems/

compensators using SISO design tool 6. Process identification using System Identification Toolbox 7. Simulation of control systems using SIMULINK

5. Study of computer-based control systems such as Centralized, Supervisory, SCADA, DCS, PLC

References: 1) Chemical Reaction Engineering: Levenspile O. 2) Chemical Engineering Kinetics: Smith J. 3) Chemical and Catalytic Reaction Engineering- Carberry & Verma. 4) Elements of Chemical Reaction Engineering: H. Scott Fogler. 5) Principles of Reaction Engineering: Dawande, Denett publications. 6) Heterogeneous Reactions: Analysis Examples and reactor Design. Vol.1 & 2-

Doraiswamy L.K. and Sharma M.M. 7) An Introduction to Chemical Reaction Kinetics & Reactor Design.-C.G.Hill.

CHEMICAL REACTION ENGINEERING - II

Unit I : Heterogeneous Reactions: Types, rates, contacting patterns. Fluid – Particle reactions: Selection of model Unreacted core model, progressive conversion model, Rate of reaction for shrinking spherical particles. Application to design. Fluidized bed with entrainment. Unit II Fluid – Fluid Reaction: Rate equation for reaction, kinetic regimes, slurry reaction kinetics, Aerobic fermentation. Application to Tower design, Mixer settler, Semi batch contacting pattern. Unit III: Adsorption: Surface chemistry and adsorption. Isotherms, Determination of surface area by BET method. Catalysis: Determination of surface area, void volume and solid density, pore-volume distribution, catalyst selection, preparation of catalyst and its deactivation, poisoning and regeneration. Nature and mechanism of catalytic reactions Unit IV: Diffusion in porous catalyst: Gaseous diffusion in single cylindrical pore. Diffusion in liquids in porous catalyst, surface diffusion. Mass transfer with reaction. Effectiveness factor, Experimental and calculated effectiveness factor, selectivity’s for porous catalysts, rate and mechanism of deactivation Unit V: Solid- catalyzed Reaction: Rate equation (For all resistances) experimental methods for finding rates, Determining controlling resistances and rate equation, product distribution. Unit VI: Design: Introduction to design of Staged adiabatic reactors, fluidized bed reactor, slurry reactor, bubble, column reactor, fermentors (As multiphase reactors) Enzyme catalyzed reactions: Introduction to Michaelis –Menten kinetics, inhibition.

CHEMICAL ENGINEERING DESIGN – II

_________________________________________________________ Unit I: Agitators and Reaction vessels- Study of various types of agitators , their selection , applications , baffling , power systems which includes twisting moment , equivalent bending moment, design of blades . Reaction vessels- Introduction ,classification , heating systems , design of vessels, study and design of various types of jackets like plain, half coil, channel, limpet oil. Study and design of internal coil reaction vessels, Heat transfer coefficients in coils Unit II: Design of distillation column-Design variables in distillation, design methods for binary systems, plate efficiency, approximate column sizing , plate contactors, plate hydraulic design. Unit III: Packed columns-Choices of plates or packing, packed column design procedure, packed bed height (Distillation and absorption), HTU, Cornell’s method, onda’s method, column diameter, column internals, wetting rates, column auxiliaries. Unit IV: Auxiliary process vessels: Study of auxiliary process vessels such as reflux drum, knockout drum, liquid-liquid and gas-liquid separators, entrainment separators, oil water separator, Decanter, gravity separator. Safety devices used in process industries, Introduction to design and engineering software. Unit V: Piping Design A brief revision covering friction factor, pressure drop for flow of non-compressible and compressible fluids, (Newtonian Fluids), pipe sizing, economic velocity. Pipe line networks and their analysis for flow in branches, restriction orifice sizing. Non-Newtonian fluids – types with examples, pressure drop calculations for Non-Newtonian fluids. Pipe line design on fluid dynamic parameter Unit VI: Materials for Piping system Desirable properties of piping materials, materials for low, normal and high temperature services, materials for corrosion resistance. Common ASTM and IS specifications for: Seamless / ERW pipes, pipe fittings, flanges, and fasteners, materials for valves. Gaskets: Functions and properties, types of gaskets and their selection. Term work: Process and Mechanical design and drawing of any Six equipments from unit 1 to 4 which should include at least two sheets based on AUTOCAD/Autodesk or design software.

References: 1. “Process equipment design” by L.E. Brownell and E. Young, John Wiley, New York, 1963. 2. “Introduction to Chemical Equipment Design” by B.C. Bhattacharya C.B.S. Publications. 3. “Process Equipment Design” by M.V. Joshi, McMillan India. 4. “Chemical Engineering Vol. 6” by J.M. Coulson, J.F. Richardson, and R.K. Sinott, Pergamon Press. 5. “Chemical Engineering volume 2” by J.M. Coulson, J.F. Richardson, and R.K. Sinott Pergamon Press. 6. “Mixing theories and practices” by Uhl V.W. and Grey J.B. Academic Press, New York, 1967. 7. “Mass Transfer Operations” by Treyball R.E., McGraw Hill, New York. 8. “Chemical Process Equipment-Selection and design” Walas S.M. , Butter worth Heinamer, McGraw Hill book company, New York. 9. “Indian standards Institution” code for shell and tube heat exchangers, IS – 4503 10 “Applied Process Design for Chemical and Petrochemical Plants” vol 1 and 2, Ludwig E.E., Gulf publishing co. publishing company, Texas. 11. Pipe Drafting and Design by Roy A Parisher & Robert A. Rhea. ASME Codes 31 12. Hydraulics and Fluid Mechanics by Modi and Seth. 13. Fluid mechanics and Hydraulic Machines by Dr. R. K. Bansal

Minimum 10 Practical and a compulsory home paper.

1) Steady state flow sheet synthesis. a) Flash Operation b) Reaction Synthesis c) Heat Exchangers d) Two Stage Compression

2. Dynamic flow sheet synthesis.

a) Application of Controllers b) Controller Tuning 3. Advanced method of optimization (e.g.: sequential quadratic programming)

4. AI methods (e.g.: XLISP program), 5. Expert system simulation (e.g.: PROLOG based program) 6. Advanced numerical method – finite difference methods

7. Finite Element Methods and Analysis 8. Basics of Computational Fluid Dynamics 9. Data modeling using support Vector Machines. 10. HAZOP and HAZAN analysis-Case Study 11. Heuristic and Separation Synthesis 12. Plant Scale up calculations for a process. 13. Computer program for Design of reactor/ Heat Exchangers. Distillation Column/ or any Chemical equipment by any language.

Home paper for each student or group of students is compulsory. A paper written by a student may be ten to fifteen pages in double spacing; a few figures may get added.

COMPUTER AIDED CHEMICAL ENGINEERING II

Industrial Training II _______________________________________________________________________________________________ Evaluation of Industrial training carried out by students after Semester VI is to be evaluated.

Students will be allotted project either individually or in groups. Each project will have one guide from the faculty. Students may be encouraged to choose co-guide from the industry, wherever possible. The aim of the project work is to evaluate the quality and competence developed by the students implementing theoretical concepts learned, in terms of technical report / presentation. The students may encourage to do Plant Design Project. In case of Plant Design Project, the report must consist of the following chapters:

1. Introduction (including market report) 2. Process Selection 3. Material and Energy Balance 4. Sizing and detailed design of major equipment/s 5. Thermodynamics and Kinetics 6. Instrumentation & Process Control 7. Plant Layout 8. Waste Treatment & Safety aspects 9. Cost Analysis 10. References

In case of strictly research or more practical project, the report must consist of the following chapters:

1. Abstract 2. Aim and Objectives 3. Introduction/background 4. Literature Review 5. Methodology 6. Results 7. Discussion 8. Conclusion and recommendations

References Appendices

In case of Modeling and Simulation Project, for example “Modeling and Simulation of Trickle Bed Reactor”, the report may consist of the following chapters:

1. Introduction 2. Literature Review 3. Trickle Bed Reactor 4. Hydrodesulphurization 5. Modeling of Trickle Bed Reactor

PROJECT

6. Simulation of Trickle Bed Reactor 7. Sensitivity Analysis 8. Conclusion & recommendations

Nomenclature References Appendices

The actual contents of the project report may be decided by the faculty guide. Students should guide to refer chemical abstracts/engineering abstracts, national/international journals to know about the latest field.

ELECTIVE-III

B.E. CHEMICAL (SEMESTER VIII)

ARTIFICIAL INTELLIGENCE IN CHEMICAL ENGINEERING

Introduction, Scope, historical perspective; Implication of AI applied to problems in engineering analysis and design; Formal concepts in design, knowledge representation and data bases; Coupled symbolic and numerical computation; Qualitative reasoning, uncertainly, truth maintenance; Integrated compute aided engineering. Knowledge based process control; Adaptive and learning systems; Applications of Neural Networks; Fuzzy logic and genetic algorithms; AI oriented languages and architechtures. Expert systems design and development; ES tools and techniques Applications in various chemical and bio – Chemical processes. TEXT BOOK 1 Artificial intelligence in chemical engineering by Quantrille

ELECTIVE-III

1. Energy Outlook: Introduction, Scope of the Problem, Thermodynamic Efficiencies, The Fundamental Strategy. The Second Law of Thermodynamics Revisited: Difference between Laws, Definitions : Available Energy, Availability, and Energy, Available Energy and Fuel. Characterizing Energy Use: Understanding Energy use, Missing Data, An Illustrative Onsite Audit, An illustrative Steam Power Balance 2. Optimum performance of Existing Facilities: Principle 1 – Minimise Waste, Combustion Principles, Illustrative Problems – Combustion Efficiency, Steam Trap Principles, Principle 2 – Manage Energy Use Effectively, Facilities Improvement - An Overall Site Approach, Utilising the Energy Audit, Overall Site Interactions, Cogeneration, Total Site Cogeneration Potential, Illustrative Problem: Maximum Potential Fuel Utilisation, The Linear Programming Approach .Methodology of Thermodynamic Analysis: General Considerations, Introduction, Sign Conventions, Detailed Procedures, Illustrative Examples. 3. Detailed Thermodynamic Analysis of Common Unit Operations: Introduction, Heat Exchange, Expansion - Pressure Letdown ∆P, Mixing, Distillation – A Combination of Simple Processes, Combustion Air Preheating. Use of Thermodynamic Analysis to Improve Energy Efficiency: Introduction, Overall Strategy, Reducing available Energy (Work) Losses, Accepting “Inevitable” Inefficiencies, Optimisation through Lost Work Analysis, Research Guidance. Thermodynamics and Economics: Capital–Cost Relationships, Background Information, The Entire Plant Energy System Is Pertinent, Investment Optimisation, Defining the Limits of Current Technology, Fundamental Process Improvements. 4. Systematic Design Methods: Introduction, Process Synthesis, Applications to Cogeneration Systems, Thermo economics, Systematic Optimisation. Guidelines and Recommendations for improving process conditions: Introduction, Chemical Reactions, Separations, Heat Transfer, Process Machinery, System Interactions and Economics, A Checklist of Energy Conservation Items, Shortcomings of Guidelines. 5. Energy Conservation Measures: Introduction, Management Systems for Energy Conservation, Energy Audits and Energy Monitoring, Combined heat and power generation: Introduction, Technology of CHP Systems, Balancing Heat and Power Loads, Economic Incentives for Further CHP systems, Technical Potential for Further CHP systems, Good Housekeeping (Minor) Conservation Measures Heat Recovery: Introduction, Heat Transfer Equipment, Heat Exchanger Networks, Heat Recovery from Waste Fuels, Heat Exchanger Fouling, Heat Pumps.Power recovery: Power recovery from pressure reduction of process fluids, Power recovery from low grade waste heat.

ENERGY CONSERVATION IN CHEMICAL PROCESS INDUSTRIES

Energy Conservation Measures: Thermodynamics of Separation Processes, Methods for reducing energy consumption in distillation, Established Approaches to Energy Conservation in drying, Energy Conservation in Evaporation, Energy Conservation in Mixing, Energy Conservation in Comminution, Role of Equipment Manufacturers 6. Process Design: Introduction, Product Substitution, Process Routes, Thermodynamic (Second law) analysis of processes, Miscellaneous design methods, Effect of energy conservation measures on reliability and control of processes, Batch processes, Mature Processes. Economic Assessment of Energy Conservation Measures, Potential for Future Energy Savings: Potential savings through good house keeping (minor) measures, Potential savings through major measures and in the long term. Texts/ references: 1 Energy Conservation in the Process Industries by W.F. Kenny, Academic Press, INC. 2 Energy Conservation in the Chemical and Process Industries by Colin D.Grant, Published by The Institution of Chemical Engineers, London 3 Energy Management Handbook by Wayne C.Turner, The Fairmount Press, INC. 4 Principles of Waste Heat Recovery by Robert Goldstick, Albert Thumann, The Fairmount Press, INC. 5 The Efficient Use of Energy, General Editor I.G.C.Dryden, IPC Science and Technology Press, Guildford, Surrey, England. 6.Sukhatme S. P., “Solar Energy”, Tata McGraw Hill, New Delhi. 7.Diwakar Rao P. L., “Energy Conservation Handbook,” Utility Publication Ltd., Jan 1988. 8. Douglas C, “Energy Technology Handbook”, McGraw Hill. 9. Kern D. C. , ‘Process Heat Transfer’, McGraw Hill Publications

ELECTIVE-III

Unit I: Concepts and definition, safety culture, storage of dangerous materials, Plant layout Safety systems, OSHA incidence rate, FAR, FR, The accident Process: Initiation, Propagation, and Termination, Toxicology: Ingestion, Inhalation, Injection, Dermal Absorption, Dose versus response curves, Relative toxicity, Threshold Limit Values.

applications, Prentice Hall, Inc, 1990. 2. P. P. Leos, Loss prevention in process Industries, Vol 1 and 2 Butterworth, 1983 3. R. W. King and J. Magid, Industrial Hazards and Safety Handbook, Butterworth,

1982 4. Khulman, Introduction of Safety Science, TUV Rheinland, 1986 5. W. E. Baker, Explosion, hazards and Evaluation, Elsevier, Amsterdam, 1983 6. O. P. Kharbanda and E. A. Stallworthy, Management of Disasters and How to

Prevent Them. Grower 1986

CHEMICAL PROCESS SAFETY

Unit II: Industrial Hygiene: Government regulations, Identification, Evaluation: Evaluating Exposures to volatile toxicants by monitoring, evaluating worker Exposures to dusts, evaluating worker exposures to noise, Estimating worker exposures to toxic vapors. Unit III: Technology and process selection, scale of disaster, Fire triangle, Distinction between fires and explosion, Definitions of Ignition, Autoignition temperature, fire point, flammability limits, Mechanical explosion Deflagration and detonation, Confined explosion, Unconfined explosion, Vapors cloud explosions, Boiling liquid expanding vapor explosion (BLEVE), Dust explosion, shock wave, Flammability characteristics of liquids and vapors, Minimum oxygen concentration (MOC) and Inerting. Unit IV:Control of toxic chemicals, Storage and handling of flammable and toxic chemical, Runway reactions, Relief system risk and hazards management, Design to prevent Fires and Explosions: Inerting, static Electricity, Explosion proof equipment and Instrument, Ventilation, sprinkler systems and Miscellaneous Design for preventing Fires and Explosion. UnitV: Hazards Identification: Process hazards checklists, Hazard Surveys, Hazard and Operability Studies (HAZOP), Safety reviews.Risk Assessment: Review of probability Theory, Interaction between process units, Revealed and unrevealed failure, probability of coincidence, Event trees and Fault trees. Unit VI: Safety versus production, Hazard models and risk data. Tackling disasters, plan for emergency. Risk management routines, Emergency shutdown systems, Role of computers in safety, Prevention of hazard human element, Technology and process selection. References 1. Daniel A. Crowl and Joseph F. Louvar, Chemical Process Safety: Fundamentals with

ELECTIVE-III

Delhi, Kanishka Publishers. 7) Fellows P. , Ellis H., 1990 – Food Processing Technology Principles and Practice

–New York 8) Considine D. M., Food and Food Production Encyclopedia, VNR New York

1982.

FOOD TECHNOLOGY

Unit I: Introduction and Basic Principles: Importance of food Industry in India, Current status of various food products from cereals, dairy, edible oil, fruits, vegetables and beverages. Physical, chemical, biological, nutritional, sensory characteristics of food. Unit II: Post Harvesting operations and storage: Storage of solid foods, Cleaning (wet and dry), sorting by shape, size, colour, weight, grading and peeling, Equipment for storage of solids, bins, silos, controlled atmosphere storage for food grains and vegetables and fruits. Principles involved in degradation and prevention Unit III: Treatment of milk before storage, effect of pasteurization, heat sterilization, In-container sterilization, storage of oils, filtration, free fatty acids removal, foots and other impurities. Unit IV: Processing of fruits for manufacture of Jams, Jellies, operations and equipments involved. Manufacture of Pickles, Squashes, and beverages, preservatives used in food processing. Unit V: Processing of food grains, Theory of size reduction equipments and effect of size reduction on foods, evaporation extrusion, hot air dehydration, baking, roasting and hot oil frying Theory, equipments, applications and effect on food materials for Freezing / Freeze drying and Freeze concentration Unit VI:Post Processing operations: Coating or enrobing operations, equipment and applications, theory of food packaging, types of packaging materials and packaging operations, filing and sealing of rigid and semi-rigid containers. Materials for handling the food items. Temper evident containers. References: 1) Matz S. A. : Bakery Technology & Engineering, AVI Publishing, 1960. 2) Shapton & Shapton, Safe Processing of Foods 3) Weiser, Mountney, Gould, Practical Food Microbiology and Technology. 4) Charm S. E. Fundamentals of food Engineering, AVI, 1963. 5) Hall, Farral, Rippen, Encyclopedia of food Engineering, AVI 1970. 6) Mirajkar M, Menon- Food Science and Processing Technology Vol I & II New

ELECTIVE-IV

Practices, Second Edition, ASQ Chemical and Process Industries Division,

Standardization and Quality Assurance in Chemical Process Industry

Unit I: Utility of standard; Standards for material consumption; Standards for equipment; Standards for manual work; Standards for financial returns, Qualitative standards. Unit II: Approach to standardization, Objective of the system, Idealized model for national standard system, Case studies of national standards systems. Unit III :Inspection and Quality Control:- Objective, Function of inspection, Elements of quality, Objective of statistical quality control; Function of S. Q. C; Control charts, Concept of sampling; Concept of zero defects. [8] Unit IV :Study of different standards followed by the chemical industry. Unit V: Role of technology transfer in standardization; Modern trends in standardization. References: 1) AIChE Journals/ 2) Quality Control Journals 3) Indian Standards Book 4) Quality Assurance for the Chemical Process Industries: A Manual of Good

ELECTIVE-IV

1. Smith J.M.: “Chemical Engineering Kinetics”, 3rd Edition, McGraw Hill 2. Satterfield Charles N.: Heterogeneous Catalysis in Industrial Practices, McGraw-

Hill International Editions, 2nd Edition 1993. 3. Bailey James, Davis Ollis: “Biochemical Engineering”, McGraw Hill 4. Wingard L.B.: Enzyme Engineering, Fr. InterScience, N.Y. 1972. 5. Carberry J. J.: Chemical and Catalytic Reaction Engineering, McGraw Hill, New

York, 1976.

CATALYSIS

Unit I: Introduction to Catalysis. Application to industrial processes – one example each from Inorganic, Fine organic chemical, petroleum refining, petrochemical and biochemical industries.Types of catalysis: Homogeneous Catalysis Unit II: Heterogeneous Catalysis: Introduction, Phase transfer and tri-phase catalysis, liquid – liquid and solid – liquid catalysis, mechanism, engineering problems, mass transfer considerations and reactor types. Unit III: Gas – solid catalytic reactions. Adsorption theories and concept of active site. Adsorption isotherm and Langmuir – Hinshelwood approach. Diffusion effect. Unit IV: Preparation of catalysts – Supported metal and metal oxide catalyst. Major steps involved in catalysts preparation and formation. Physical methods of catalyst characterization for determination of surface area, pore volume and average pore size. BET equation. Unit V: Zeolites – Structural considerations. Templeted molecular sieves, size and shape selectivity, 4 – 5 industrial applications of zeolites. Modification of zeolites.Unit VI: Biocatalysts – enzymes, lipases and microbes as catalysts. Mechanism of participation of enzymes in a few typical reactions. Michaelis – Menten Kinetics, inhibition. Reactions and denaturation of two biopolymers, proteins and nucleic acids: one or two industrial reactions. References:

ELECTIVE-IV

Unit I: Introduction :Introduction to nanotechnology and materials,Nanomaterials, How It All Began: Synthesis of carbon buckyballs ,List of stable carbon allotropes extended,fullerenes, metallofullerenes, solid C60, bucky onions, nanotubes, nanocones Properties of Individual nanoparticles. Methods of synthesis. Carbon nanostructures

Unit II: Synthesis procedures of nanomaterials :Bottom-up vs. top-down , Epitaxial growth ,Self-assembly ,Modelling and Applications Production Techniques of Nanotubes Carbon arc bulk synthesis in presence and absence of catalysts High-purity material (bucky paper) production using Pulsed Laser Vaporization (PLV) of pure and doped graphite High-pressure CO conversion (HIPCO) nanotube synthesis based on Boudoir reaction Chemical Vapor Deposition (CVD) Unit III: Characterizations of nanomaterials :Top down approach Bottom up approach Optical Microscopy, Electron Microscopy,Secondary electron scattering, back scattering, Scanning Probe Microscopes, Focussed Ion Beam Technique,X-ray imaging, SPM-AFM, STM, Optical Microscopy, Electron Microscopy,Secondary electron scattering, back scattering, Scanning Probe Microscopes, Focussed Ion Beam Technique,X-ray imaging, SPM-AFM, STM Unit IV: Semiconductors and Quantom dots :Intrinsic semiconductors, Band gaps, Law of mass action, Mobility of charge carriers Extrinsic semiconductors The p-n junction, Ferromagnetism Energy gaps The nearly free electron model The number of orbitals in a band Electrons and holes, effective masses Review of classical mechanics, de Broglie's hypothesis ,Heisenberg uncertainty principle Pauli exclusion principle Schrödinger's equation Properties of the wave function,Application: quantum well, wire, dot ,Quantum cryptography Unit V: Nano colloids and Chemistry :Surface Tension and Interfacial Tension Surfaces at Equilibrium Surface Tension Measurement, Contact Angles, Colloidal Stability, Electrical Phenomena at Interfaces Van der Waals Forces between Colloidal Particles, photocatalysis Nanostructured materials. Self-assembly and Catalysis. UnitVI: Unit Applications and Safety, Environment:Waste Water Treatment , Nanobiotechnology : Drug Delivery , Nanoclay, Nanocomposites, Surface coatings. Self cleaning Materials, Hydrophobic Nanoparticles. Biological nanomaterials. Nanoelectronics. Nanomachines & nanodevices Societal, Health and Environmental Impacts Commercial Processes for Nanotechnology and Chemical Engineering Applications Nanohydrogel, Photocatalytic reactors, Nanoclay Synthesis , Polymer nanocomposite, Introduction to industries which produces commercial nanomaterials

NANOTECHNOLOGY

Text Book: Introduction to NanoScience, (CRC Press of Taylor and Francis Group LLC), G. Louis

Hornyak, Joydeep Dutta, Harry F. Tibbals and Anil K. Rao, May 2008, 856pp, ISBN-13:

978142004805

ELECTIVE-IV

1. Bokris John O’m, Srinivasan S., “Fuel cells-their electrochemistry”, McGraw Hill 1969.

2. Appleby A.J. Fralkes F. R., “Fuel cell handbook”, Van Nostrand Reinhold 1989.

3. Kordesch Karl, Simader G., “Fuel cells and their applications”, VCH publications 1996.

4. “Fuel cell: a handbook”, U S Department of energy. 5. Leo J.M.J., Blomen, Mugerwa M. N., “Fuel cell systems”, plenum press.

FUEL CELL TECHNOLOGY

Unit I: Fuel cell definitions. Fuel cell types: Proton-exchange membrane, phosphoric acid, molten carbonate, solid oxide ceramic type. Mechanism of power generation and applications. Unit II: Solid –oxide fuel cells (SOFC) basics. Homogeneous solid oxide electrolytes: ionic conductivity, defect structure in ionic solids, defect equilibria, determination of defect concentrations, ionic transference number, temperature dependence of conductivity. Unit III: Heterogeneous solid oxide electrolytes. Ionic conductivity of heterogeneous electrolytes. Classification of two phase composite materials. Models to explain conductivity enhancement in heterogeneous electrolytes. Advantages and drawbacks of solid-oxide fuel cells. Requirements of electrolytes, cathode and anode, interconnection materials. Unit IV: SOFC configurations and performance: Tubular configuration, monolithic SOFC, planer (bipolar plate) design. Manufacturing processes. Unit V: Thermodynamic processes in fuel cells. Operation and performance of SOFC. Multistage oxidation concept. Unit VI: Fuel cell power systems. SOFC integrated power plants: Benefits of pressurization, integrated SOFC/turbine systems, internally reformed SOFC. References

ELECTIVE-IV

1. Petrochemical by Hobson and Pohl 2. Introduction to petrochemical industry and refinery by Speight 3. Outline of chemical industry by Dryden and Gopal Rao

PETROCHEMICAL ENGINEERING

Unit I: Introduction to petrochemical, Petrochemical industry in India, basic raw material for petrochemical synthesis and their sources, preparation of feedstocks for petrochemical production, main building blocks of petrochemical industry Unit II: First generation raw material like olefins, aromatics, naphthenes. Production of aromatics, naphthenes and other hydrocarbon feedstocks Unit III: Production of low molecular weight olefins by hydrocarbon cracking, furnaces, separation techniques and purification Unit IV: Combining olefins and aromatics to produce second generation intermediates such as glycols, amines, acids, ketones that can be used also as solvents and formulating agents Unit V: Polymers: Bulk, engineering and speciality, types of polymerization such as bulk, emulsion and suspension etc, at least two polymeric products and manufacture from each class Unit VI: Integration of refinery and petrochemical plants with power generation, pollution control – norms and methods of elimination, brief description on safety considerations References:

ELECTIVE-IV

1. B.G.Liptak, Instrumentation Engineers Handbook Process Control,3rd Edtion. 2. D.M.Considine, Process Instrument & Control Handbook, McGraw Hill. 3. P. Harriot, Process Control, Tata McGraw Hill publications. 4. Ogata, Modern Control Engineering, PHI publications.

COMPUTER AIDED PROCESS CONTROL

Unit I: Basic Concepts: Role of digital computer in process control, elements of computer control system(block diagram), classification (DDC, supervisory), process control architecture( centralized, distributed, hierarchical), man-machine interface, advantages. Unit II: Multivariable process control(MIMO Control system) Introduction, nature, input-output pairing, interactions, controllability and observability transfer function model, open loop dynamic analysis in state space, transient response and stability, Interaction analysis and loop pairing , RGA and loop pairing, design of non-interacting control loops. Unit III: Digital control: Discretization (sampling) of continuous signals, Reconstruction of continuous signals from their discrete values, Z- transforms, dynamic analysis of discrete time systems(first order dead time, lead/lag systems), digital approximation of classical controllers, digital control algorithms for P, PI, PD & PID controllers, stability & design of digital controllers, self tuning digital control systems, Direct Digital Control (DDC)

Unit IV: Process control Computer Hardware and Software: Organization of general purpose computer, interfaces, communication & networking, data transfer techniques, computer aided process control softwares, real time application softwares, PC based data acquisition systems, real time programming languages, software for modeling & simulation of control systems (MATLAB, SIMULINK, System build, Easy-5, Simmon, Desire) UnitV: Distributed control system and programmable Logic Controllers Introduction to DCS, software configuration, communication, supervisory control. Introduction to microcomputers, Evolution, architecture, basic structure of PLC, programming, ladder diagram, communication and networking, advantages of PLC. Integration of DCS with PLC and computers. Unit VI: Industrial application of digital/ computer control and plant wide control Control system for MIMO system such as- two product distillation column, packed bed reactor, jacketed packed bed reactor, fired heaters, heat exchangers, pumps, compressors. Managing the process control design problem-Definition, sequence of design steps, temporal hierarchy of control structure, process decomposition, integrating of control design methods. References:

5. Stephanopoulos, Chemical Process Control, PHI publications. 6. S.K.Singh, Computer aided process Control, PHI publications. 7. Nise, Control System Engineering. 8. Marlin T. Process Control: Designing process and control systems for dynamic

performance, McGraw-Hill. 9. Ogunaik B.A. and W.H. Ray, Process dynamics, Modeling and control, Oxford

University press, NY, 1994. 10. K.Kaul, Computer Based Industrial Control, PHI Publications.

Unit: VI Applications of modeling and simulation in distillation, Transient analysis of staged absorbers, unsteady state analysis in reactor system, Modeling and simulation of effluent treatment plant, Use of numerical methods to solve different models.

Ten practical will be conducted with the use of mathematical and chemical engineering CAD software’s such as Hysys, ChemCAD, EnviroPro, Mathcad, Matlab etc. Development of programs for numerical methods and process simulation.

References:

1. Luyben W. L., “Process Modeling Simulation and Control for Chemical Engineers”, McGraw Hill, 1988.

2. Davis M. E., “Numerical Methods and Modeling for Chemical Engineers”, Wiley, New York, 1984.

3. Finlayson B. A., “Nonlinear analysis in Chemical Engineering”, McGraw Hill, New York, 1980.

4. Chapra S.C., R.P. Canale, “Numerical Methods for Engineers”, Tata-McGraw Hill Publications

PROCESS MODELING & SIMULATION

Unit: I. Introduction to Modeling: Introduction, definition of Modeling and simulation, different types of models, application of mathematical modeling, scope of coverage. Unit: II Fundamental laws: continuity equation, energy equation, equation of motion, transport equation, equation of state, phase and chemical equilibrium, chemical kinetics. Unit: III Heat Transfer and Other Equipments: Heat exchangers, evaporators, agitated vessels, pressure change equipments, mixing process, fluid – solid operations

Unit: IV Mass Transfer Equipments: flash distillation, differential distillation, continuous binary distillation in tray and packed column, vaporizers, single phase and multiphase separation, multi-component separation, drying equipments, adsorption, absorbers and strippers. Unit: V Reaction Equipments: Batch reactor, Semi batch reactor, Continuous stirred tank reactor, Plug flow reactor, Slurry reactor, Trickle bed reactor, Bubble column reactor, Packed column reactor, Bioreactors, Reactors used in effluent treatments, Fluidized bed reactor.

Practical:

5. Franks R.E.G., “Modeling and Simulation in Chemical Engineering”, Wiely Intrscience, NY

6. John Ingam, Irving J. Dunn., “Chemical Engineering Dynamic Modeling with PC simulation”, VCH Publishers.

7. Kayode Coker A., “Chemical Process Design, Analysis and Simulation”, Gulf Publishing Company.

8. Himmelblau D., K.B. Bischoff, “Process Analysis and Simulation”, John wiely & Sons.

9. Wayne Blackwell, “Chemical Process Design on a Programmable Calculator”, McGraw Hill.

.

Unit I: Process Development: Process selection, study of alternative processes, pilot plant, Scale up methods, Flow sheet preparation, sketching techniques, Equipment numbering, Stream designation, Material and energy balances. Plant Design:Design basis ,Process selection -Selection of equipment, specification and design of equipment’s, material of construction, Plant location, Plant layout and installation, Safety, Start up, Shutdown and Operating guidelines. Unit II:Cost Engineering:Time value of money and equivalence, Interest, cost comparisons by present worth, Annual equivalent cost and capitalised cost methods, Uniform gradient and series.Depreciation, Taxes and Insurances,Nature of depreciation, Methods of determining depreciation, depreciation rates in current Indian situation, Types of taxes and insurance’s, Procedure for cost comparison after taxes. [8] Unit III:Cost Estimation: Types of cost estimation, capital investment cost, fixed capital cost, working capital cost, start-up costs, process equipment cost estimation, cost index, Equipment costs due to inflation, Battery limit investments, estimation of plant cost, Estimation of total product cost, Manufacturing cost, General expenses. Profitability: Criteria of profitability, Payout period, Return on investment, Present value, Cash flow analysis, Alternative investment analysis, Sensitive analysis in project profitability. Unit IV:Economic Optimization and Optimum Design: Nature of optimisation, Uni-variable and multivariable systems, Analytical, graphical and incremental methods of solution, LaGrange multiplier method, Linear programming and dynamic programming establishing optimum conditions, Break even chart for production schedule, Optimum production rates in plant operation, Optimum conditions in batch, cyclic and semicyclic operation, Sensitivity and response analysis. Unit V:Optimisation of Different Process Equipment: Viz., transportation systems, heat exchangers, evaporators, mass transfer equipments and reactors. Determination of height and diameter of different process equipments at conditions of optimum cost .Pinch Technology analysis. Preparation of techno-economic feasibility report. Unit VI: Role of project engineering in project organisation ;Plant location and plant layout; Start up and shut downs of project; Preliminary data for construction projects; Process engineering; Flow diagram, Plot plans, Scheduling the project; Engineering design and drafting. Critical path method (cpm): Events and activities; Network diagramming; Earliest start time and earliest finish time ;latest start time and latest finish time; Float, Advantage of CPM ;Cost to finish he projects earlier than normal cost; Precedence diagramming.

PROCESS ENGINEERING COSTING & PLANT DESIGN

Process flow diagram. Piping and instrumentation diagram. Plant layouts and elevations. Piping GA drawing.

Piping isometrics. 2. Minimum two assignments based on theory to be solved on computer. Reference books 1. Peter S. Max & Timmerhaus, Plant Design and economics for chemical engineers. Mc Graw Hill (2002). 2. Srinath L. S., “PERT AND CPM.” affiliated east press pvt. Ltd., new york (1973) 3. Perry J. H.,”Chemical engineering handbook” 7TH ed. Mc Graw Hill ( 1997). 4. JELLEN F. C., “Cost and optimization in engineering”. Mc Graw Hill (1983).

Programme evaluation and review technique (pert): PERT network and time estimates; Single versus multiple time estimates; Frequency distribution. Practicals: 1.Minimum six drawing of following preferably on Auto CAD/Autodesk.