Upload
phuongkq832
View
25
Download
0
Embed Size (px)
Citation preview
5/12/2018 Calcium Bicarbonate - slidepdf.com
http://slidepdf.com/reader/full/calcium-bicarbonate 1/3
Baking soda is sodium bicarbonate, or more correctly named, sodium hydrogen
carbonate:
Calcium bicarbonate (Ca(HCO3)2), also called calcium hydrogen carbonate, does notrefer to a known solid compound; it exists only in aqueous solution containing the ions
calcium (Ca2+), dissolved carbon dioxide (CO2), bicarbonate (HCO3–), and carbonate
(CO32–). The relative concentrations of these carbon-containing species depend on the pH; bicarbonate predominates within the range 6.36-10.25 in fresh water.
Attempts to prepare compounds such as calcium bicarbonate by evaporating its solution
to dryness invariably yield the solid carbonate instead: Ca(HCO3)2(aq) → CO2(g) +H2O(l) + CaCO3(s).
If you need this product, then you would have to buy it as a solution. And even then I am
not sure that you could buy it.
--
Calcium bicarbonate (Ca(HCO3)2), also called calcium hydrogencarbonate, does not
refer to a known solid compound; it exists only in aqueous solution containing thecalcium (Ca2+), bicarbonate (HCO3 – ), and carbonate (CO3
2– ) ions, together with dissolved
carbon dioxide (CO2). The relative concentrations of these carbon-containing speciesdepend on the pH; bicarbonate predominates within the range 6.36-10.25 in fresh water.
All waters in contact with the atmosphere absorb carbon dioxide, and as these waters
come into contact with rocks and sediments they acquire metal ions, most commonly
calcium and magnesium, so most natural waters that come from streams, lakes, andespecially wells, can be regarded as dilute solutions of these bicarbonates. These hard
waters tend to form carbonate scale in pipes and boilers and they react with soaps to form
an undesirable scum.
Attempts to prepare compounds such as calcium bicarbonate by evaporating its solutionto dryness invariably yield the solid carbonate instead: Ca(HCO3)2(aq) → CO2(g) +
H2O(l) + CaCO3(s). Very few solid bicarbonates other than those of the alkali metals and
ammonium ion are known to exist.
The above reaction is very important to the formation of stalactites, stalagmites, columns,and other speleothems within caves and, for that matter, in the formation of the caves
themselves. As water containing carbon dioxide (including extra CO2 acquired from soil
organisms) passes through limestone or other calcium carbonate containing minerals, itdissolves part of the calcium carbonate and hence becomes richer in bicarbonate. As the
groundwater enters the cave, the excess carbon dioxide is released from the solution of the bicarbonate, causing the much less soluble calcium carbonate to be deposited.
Dissolved carbon dioxide (CO2) in rainwater (H2O) reacts with limestone, calciumcarbonate (CaCO3) to form soluble calcium bicarbonate (Ca(HCO3)2). This soluble
compound is then washed away with the rainwater. This is form of weathering is called
'Carbonation'.
5/12/2018 Calcium Bicarbonate - slidepdf.com
http://slidepdf.com/reader/full/calcium-bicarbonate 2/3