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CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
1
CEMENT FACTORIES, AIR POLLUTION
AND
CONSEQUENCES
SYED SANA MEHRAJ
AND
Dr. G.A BHAT
Department of Environmental Science & Centre of research for development, University of
Kashmir, Jammu and Kashmir, India, 190006
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
2
CONTENTS
C. No`s Description Page No.s
Preface &
Acknowledgement
3-5
1. Introduction 6-18
2. Cement factories
and
cement manufacturing
19-29
3. Pollutants from cement
factories
30-36
4. Consequences of cement
pollution
37-52
5. Photo gallery
53-60
6. Summary 61-64
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
3
PREFACE
The fact that air pollution is hazardous to human health is well
known. WHO estimates that, worldwide, at least two million people
every year die prematurely due to health effects caused by a lack of
clean air? Air is the basic necessity of human life but the quality of
air is deteriorating continuously and it is being constantly polluted
from different sources. One of the major sources of air pollution are
automobiles and industries, as per estimates vehicular pollution is
the primary cause of air pollution in urban areas (60%), followed by
industries (20-30%). Cement industry is one of the most important
industries involved in air pollution. The aerial discharge of cement
factories consist of Particulate matter, Sulphur dioxide and Nitrogen
oxides producing continuous visible clouds which ultimately settle on
the vegetation, soil and effects whole biotic life around, as a result
the whole ecosystem around the cement factory is subjected to
extraordinary stress and abuse. This book provides an insite into the
process of cement manufacturing, various types of pollutants which
are released from these factories and their immediate and long term
impacts. As whole process of cement manufacturing, involves
release of enormous pollutants need is to strictly and sustainably
regulate its manufacturing, distribution and use especially in
residential and biodiversity rich areas, so that human lives may not
be lost at the name of so called development.
Syed Sana Mehraj
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
4
ACKNOWLEDGEMENTS
To start with I bow in reverence to Almighty Allah, all praise
to almighty Allah, the cherisher and the sustainer of the universe
who gave me enough courage and patience and by whose mercy
and blessings I was able to complete this book. It gives me
immense pleasure to express my deep sense of gratitude and
indebtness to my ideal supervisor Prof. G .A. Bhat, who‟s friendly
spirit, intellectual guidance, kind supervision, valuable suggestions,
deep concern and constructive criticism provoked like a beckon in
making the present task possible.
I also wish to express deep sense of profound gratitude to Prof. A.
N. Kamili (Head, department of Environmental science), Prof. A. R
Yousuf, Prof. A. K. Pandita my worthy teachers. I am especially
thankful to Mrs. Shazia Bashir Panzoo and Dr. Arifat Jan for
providing necessary help and suggestions in carrying out the task. I
take the opportunity to extend my sincere thanks to Ms.Taseen Gul,
Ms. Raihana Maqbool and Ms. Quassin Basharat (Department of
Bio- technology, University of Kashmir).
I hold extreme gratification for my colleagues, and all staff members
at the Department of Environmental Science and CORD, University
of Kashmir for their constant support and help.
I am thankful to my research team and friends for their support
and help.
I wish to express my deep and sincere thanks to my uncle Syed
Shafat Hussain Rufaie for always being there for providing me
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
5
necessary help and support whenever i need. My special
appreciation and thanks go to Syed Majid Mehraj Balkhi, who
helped me in completing this task and Syed Henah Mehraj Balkhi,
Ph.d research scholar, department of biotechnology, Kashmir
University, who helped me extensively during the preparation of this
book. Last but not least, for being there, whenever I needed them, I
convey my immense gratitude to my family especially my father
Syed Mehraj u din Balkhi and my dearest mother. They have been
long a source of inspiration and motivation force for me to undertake
the present endeavor.
Syed Sana Mehraj
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
7
The modernization and industrialization of developing
countries has led to the increased use of fossil fuels and their
derivatives. As such, developing countries are confronted with the
great challenge of controlling the atmospheric pollution, especially in
the rapidly growing urban centres. Air pollution is an important
problem in industrial areas which may have an adverse effect on the
health of the population. Air pollution is due to the discharge of toxic
fumes, gases, smoke and dusts into the atmosphere (Park and
Park, 1985).
Concern about air pollution in urban regions is receiving
increasingly importance worldwide, especially pollution by gaseous
and particulate trace metals (Azad and Kitada, 1998; Salam et al.,
2003; Begum et al., 2004; and Cachier et al., 2005). A great deal of
attention has focused on particulate matter (PM) pollution, due to
their severe health effects, especially fine particles. Several
epidemiological studies have indicated a strong association between
elevated concentrations of inhalable particles (PM10 and PM2.5) and
increased mortality and morbidity (Perez and Reyes, 2002; Lin and
Lee, 2004; Namdeo and Bell, 2005). Particulate matter pollution in
the atmosphere primarily consists of micron and sub-micron
particles from anthropogenic and natural sources. The
characterization of fine particles has become an important priority of
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
8
regulators, and researchers due to their potential impact on health,
climate, global warming, and long- range transport (Dockery et al.,
1993; IPCC, 2001).
Numerous studies and the lack of effective policies reveal that air
pollution continues to threaten public health (Cropper et al., 1860;
Medina et al., 2009). Studies of long- term exposure to air pollution
(especially particles) suggest an increased risk of chronic respiratory
illness (Schwartz, 1994; Pope et al., 1995; Dockery and Pope, 1994)
and of developing various types of cancers (Hemminki and
Pershagen, 1994; Knox and Gilman, 1997; Nyberg et al. 2000). In
an apparently worst case scenario carried out on the WHO data
sets, (Kunzll et al., 2000) found that 6% of the deaths in Austria,
France, and Switzerland might be associated with exposure of the
population to particulate air pollution. Major air pollution problems
are occurring at urban and industrial centers, increasing pollution
levels however can also be observed at remote sites as a
consequence of agricultural practices and mineral mining and
processing. Motor vehicle traffic is the main contributor of
deterioration of air quality in the urban centers. The high average of
fleet, poor fuel quality, insufficient car maintenance and high
concentration of vehicles in the areas with inadequate infrastructure
all contribute to the high pollutant load. Other important pollutant
sources are industrial activities including cement industry.
As we know India is one of the leading developing
countries that have undergone rapid industrialization in the few
decades of near past. India today is among first ten industrialized
countries of the world (Sharma, 2004). Besides steel and power the
cement production of India is recognized as one of the most
important industries. The consumption pattern of cement often
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
9
denotes economic development of any nation. The rapid and unsafe
growth of various industries during the last 50 years has, however,
resulted in remarkable deterioration of the environment.
Environment is a major issue which confronts industry
and business in today‟s world on daily basis. Different industrial
activities are degrading various environmental components like
water, air, soil and vegetation (Dolgner et al., 1983; Sai et al., 1987;
Mishra, 1991; Murugesan et al., 2004; Kumar et al., 2008). Cement
industry is one of the 17 most polluting industries listed by the
central pollution control board. It is the major source of particulate
matter, SOx, NOx and CO2 emissions. Cement dust contains heavy
metals like chromium, nickel, cobalt, lead and mercury pollutants
hazardous to the biotic environment with impact for vegetation,
human health, animal health and ecosystem (Baby et al. 2008). The
cement industry is involved in the development of structures in this
advanced and modern world because it is the basic ingredient of
concrete used in constructing modern edifices and structures. In
fact, life without cement in this 21st century is inconceivable.
Cement, however, generates dust during its production (Meo, 2004).
Cement is a fine, gray or white powder which is largely made up of
Cement Kiln Dust (CKD), a by-product of the final cement product,
usually stored as wastes in open-pits and landfills. Exposure to
cement dust for a short period may not cause serious problem,
however prolonged exposure can cause serious irreversible damage
to plants and animals (Heather, 2003).Cement dust of sufficient
quantities have been reported to dissolve leaf tissues (TRF, 2008).
Other reported effects of cement dust on plants include reduced
growth, reduced chlorophyll, clogged stomata in leaves, cell
metabolism disruption, interrupt absorption of light and diffusion of
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
10
gases, lowering starch formation, reducing fruit setting (Lerman,
1972), inducing premature leaf fall and leading to stunted growth
(Darley, 1966) thus causing suppression in plants and in animals it
leads to various respiratory and hematological disease, cancers, eye
defects and genetic problems (Iqbal and Shafug, 2001; Meo, 2004;
Mohammed and Sambo, 2008; Ogunbileje and Akinosun,
2011).Besides gaseous and particulate pollutants there are also
enhanced levels of toxic heavy metals in the environment of cement
factory likely cobalt, lead, chromium, nickel, mercury (Baby et al.,
2008) posing very potential hazard for all living organisms (Lewis
and Mcintosh, 1989). Increased concentrations of the above
pollutants cause progressive reduction in the photosynthetic ability
of leaves, mainly a reduction in growth and productivity of plants
(Larcher, 1995).
Metal toxicity in plants has been reported by various
authors (Bollard and Butler, 1966; Brown and Jones, 1975; Foy et
al., 1978; Chidambaram et al., 2009). Heavy metal pollutants are
stable in the environment but highly toxic to biological organisms
(Zou et al., 2006; Levent et al., 2009). Among the heavy metals,
Mercury, lead, nickel, chromium are most dangerous heavy metals
released by cement factories (Kumar et al., 2008) and is responsible
for causing various biochemical changes which also includes
cytotoxic and mutagenic effects (Ritambhara et al., 2010 and
Yahaya et al., 2012) such as chromosomal aberrations, stickiness,
c-mitosis, chromosomal bridge, chromosome fragmentation, vagrant
chromosomes, DNA fragmentation etc in various plants as well as in
humans.
Blooming of cement factories has resulted in the
environmental deterioration and in turn degrades the human health
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
11
status in whole world. Studies have shown adverse respiratory
health effects in the people exposed to cement dust, exemplified in
increased frequency of respiratory problems (Al-Neaimi et al.,
2001).It has also been revealed that people of cement dust zone are
badly affected by respiratory problems, gastro intestinal diseases
etc. (Adak et al., 2007). Several studies have also demonstrated
linkages between cement dust exposure, chronic impairment of lung
function and respiratory symptoms in human population. Cement
dust irritates the skin (Ikli et al., 2003). Its deposition in the
respiratory tract causes a basic reaction leading to increased pH
values that irritates the exposed mucous membranes (Zeleke et al.,
2010). Numerous studies and the lack of effective policies reveal
that air pollution continues to threaten public health. Studies of long
– term exposure to air pollution (especially particles) suggest an
increased risk of chronic respiratory illness (Schwartz, 1994;
Sivicommar et al., 2001). Besides health, cement factories are
deteriorating environment as shown by studies. The exhaust gases
and particulate matters of the dust exhausted from cement plants
are released to air and degrading air quality and thus creates
considerable environmental pollution (Adak et al., 2007). Since early
1980s, it has become clear that air pollution affects the health of
human beings and animals (Parada et al., 1987), damages
vegetation, soils and deteriorates materials and generally affects not
only the large metropolitan areas but also the medium sized urban
areas. Air pollution has a great impact on human health, climate
change, agriculture and natural ecosystem (Molina et al., 2004)
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
12
References
Adak, M. D., Adak, S. and Purohit K. M. 2007. Ambient air quality
and health hazards near min-cement plants. Pollution
Research 26(3): 361- 364.
Al-Neaimi, Y. I., Gomes, J. and Lloyd, O. L. 2001. "Respiratory
illnesses and ventilatory function among workers at a cement
factory in a rapidly developing country." Occupational
Medicine, 51(6): 367-373.
Azad, A.K. and Kitada, T.1998. Characteristics of the air pollution in
the city of Dhaka, Bangladesh in winter. Atmos.Environ., 32:
1991-2005.
Baby, S., Singh, N. A., Shrivastava, P., Nath, S. R., Kumar, S. S.,
Singh,D. and Vivek, K. 2008."Impact of dust emission on plant
vegetation of vicinity of cement plant." Environmental
Engineering and Management Journal 7(1): 31-35.
Begum, B.A., Kim, E., Biswas, S.K. and Hopk, P.K. 2004.
Investigation of sources of atmospheric aerosol at urban and
semi urban in Bangladesh. Atmos. Environ., (38): 3025-3038.
Bollard, E. G. and Butler, G. W. 1966. Mineral nutrition of plants.
Annu. Rev. Plant Physiol., 17:77-112.
Brown, J. C. and Jones, W. E. 1975. Heavy metal toxicity in plants.
I.A. crisis in embryo. Commun. Soil Sci. Plant Anal., 6: 421-
438.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
13
Cachier, H., Aulagnier, F., Sarda, R., Gautier, F., Masclet, P. and
Besombes, J.L.2005. The ESCOMPTE experiment: 108 Air.
Qual. Atmos. Health, (1): 101-109.
Chidambaram, A., Sundaramoorthy, P., Murugan, A., Sankar, K.,
Ganesh, B. L. 2009. Chromium induced cytotoxicity in
blackgram (Vigna mungo L.) Iran. J. Environ. Health Sci. Eng.,
6 (1): 17-22.
Cropper, M.L., Simon, N.B., Alberine, A. and Sharma, P.K. 1860.The
health effects of air pollution in Delhi, India.
Darley, E.F.1996. Studies of the effect of cement kiln dust on
vegetation. Journal of the air pollution control association,
(16):145-150.
Dockery, D.W. and Pope, C.A. 1993. Acute respiratory effects of
particulate air pollution. Animal Review of Public Health 1(5):
107 -132.
Dockery, D.W. and Pope, C.A. 1994. Acute respiratory effects of
particulate air pollution. Animal Review of Public Health 1(5):
107 -132.
Dolgner,R., Brockhaus, A., Ewers, U., Weigand, H., Majewski, F. and
Soddemann, H.1983. Repeated surveillance of exposure to
thallium in a population living in the vicinity of a cement plant
emitting dust containing thallium. Int. Arch. Occup. Environ.
Health, (52):79-94.
Foy, C. D., Chaney, R. L. and White, M. C. 1978. The physiology of
metal toxicity in plants. Annu. Rev. Plant Physiol., 29: 511-566.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
14
Hemminki, K. and Pershagen, G. 1999. Cancer risk of air pollution:
Epidermological evidence. Environmental Health Perspectives,
102 (suppl.4), 187-192.
Ikli,B.I., Demir, T.A., Urer, S.M., Beker, A., Akar, T. and Kalyoncu, C.
2003. Effects of chroniuum exposure from a cement factory.
Environmental Research (9):113-118.
Iqbal, Z.Muhammad. and Shafiq, Muhammad.2001. Effect of cement
dust pollution on the growth of some plant species. Turk.
Journal Bot. (25): 19-24.
IPCC (International Panel on Climate Change) 2001.The third
assessment report of working group I of the
intergovernmental panel on climate change. Technical
summary. IPCC Shanghai.
Knox, E. G. and Gilman, E.A. 1997. Hazard proximities of childhood
cancers in Great Britain from 1953-1980.Journal of
Epidermology and community Health, (51): 151-159.
Kumar, S. S., Singh, N. A.,Kumar, V., Sunisha, B., Preeti, S., Deepali,
S. and Nath, S. R., 2008. Impact of dust emission on plant
vegetation in the vicinity of cement plant." Environmental
Engineering and Management Journal 7(1): 31-35.
Kunzall, N., Kalser, R., Medina, S., Studnicka, M., Chanel, O. and
Filliger, P. 2000. Public heath impact of outdoor and traffic-
related air pollution: A European assessment. The Lancet,
(356): 795-801.
Larcher, W. 1995. Physiological plant ecology: Ecophysiology and
stress physiology of functional groups. Into plant morphology,
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
15
physiology and pathology. Ph.D Dissertation University of
California, Riverside.
Lerman, S. 1972. Cement kiln dust and the bean plant (phaseolus
vulgaris L. Black Valentioe Var): In dep. invest.
Levent, K. I., Okan, A. and Cuneyt, A. K. 2009. Genotoxic effects of
industrial wastewater on Allium cepa L. Afr. J. Biotech., 9:
1919-1923.
Lin, J. and Lee, L.C. 2004. Characterization of the concentration and
distribution of urban submicron PM10 aerosol particles. Atmos.
Environ., (38): 469-475.
Medina, S. and Tertre, A.L. and Saklad, M. 2009. The Apheis project:
Air pollution and Health- AEuropean information system. Air.
Qual. Atmos. Health, (2): 185-198.
Mishra, G. P. 1991. "Impact of industrial pollution from a cement
factory on water quality parameters at Kymore."Environment &
Ecology 9(4): 876-880.
Molina, L.T., Molina, M.J., Slott, R., Kolb, C.E., Gbor, P.K. and Meng,
F. 2004. Air quality in selected megacities. Crit Rev., 10
(suppl).
Molina, M.J., Molina, L.T. 2004. Megacities and atmosphere pollution.
J . Air Wastage Manage Assoc., (54): 644-680.
Mohammed, A. K. and Sambo, A. B. 2008. Haematological
assessment of the nile Tilapia Oreochromis niloticus exposed
to sub-lethal concentrations of portland cement powder in
solution. Int. J. Zool. Res., 4: 48-52.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
16
Murugesan, M., Sivakumar, A., Jayanthi, N. and Manonmani, K.
2004. "Effect of cement dust pollution o physiological and
biochemical activities of certain plants." Pollution Research
23(2): 375-378.
Namdeo,A.and Bell, M.C. 2005. Characteristics and health
implications of fine and coarse particulates at roadside, urban
backgroung and rural sites in UK. Environ. Int., (31): 565-573.
Nyberg, F., Gustavsson, P., Jarup, L., Bellander, T., Berglind, N. and
Jacobsson, R. 2000. Urban air pollution and lung cancer in
Stockholm. Epidermology,11(5): 487-495.
Ogunbileje, J. O. and Akinosun, O. M. 2011. Biochemical and
haematological profile in Nigerian cement factory workers.
Res. J. Environ. Toxicol., 5: 133-140.
Parada, R. Gonzalez, S. and Berggvist, E. 1987. Industrial pollution
with copper and other metals in a beef cattle ranch. Veterinary
and Human Toxiciology (29): 122-26.
Park, J.E. and Park, K.1985. Preventive and social medicine.
Banarsidas Bhanot (Publishers), Napier town, Jabalpur,
India.
Perez, P. and Reyes, J. 2002. Prediction of maximum of 24- h
average of PM10 concentrations 30 –h in advance in
Santiago, Chile. Atmos. Environ., (36): 4555- 4561.
Pope, C.A., Thun, M.J., Namboodiri, M.M., Dockery, D.W., Evans,
J.S. and Speizer, F.E. 1995. Particulate air pollution as
predictor of mortality in a prospective-study of adults.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
17
American Journal of Respiratory and Critical Care Medicine,
151: 669-674.
Ritambhara, T. and Kumar, G. 2010. Genetic loss through heavy
metal induced chromosomal stickiness in Grass pea. Plant
Genetics Laboratory, Department of Botany, University of
Allahabad, Allahabad-211002, India.
Salam, A., Bauer, H., Kassin, K., Ullah, S.M. and Puxbaum, H. 2003.
Aerosol chemical characteristics of a mega-city in southeast
Asia (Dhaka, Bangladesh).Atmos. Environ., (3): 2517-2528.
Sai, V. S., Mishra, M. P. and Mishra, G. P. 1987. "Effect of cement
dust pollution on trees and agricultural crops." Asian
Environment 9(1): 11-14.
Schwartz, J. 1994. Air pollution and daily mortality: A review and meta
analysis. Environmental Research, (64): 36-52.
Sivicommar, R., Jayabalou, R., Subrahmanyam, Y.V., Jothikumar, N.
and Swarnalatha, S. 2001. Air pollution in stone crushing
industry and associated health effect. Indian journal of
environmental health, (4):169-73.
Sharma, P. D. 2004. Ecology and Environmental science. Rastogi
publications, New Delhi (10th Edition).
TRF, 2008. Air pollution effects: Effects on forests, trees and plants.
Tropical Rain Forest.
Yahaya, T. Okpuzor, J. and Oladele, E. O. 2012. Investigation of
Cytotoxicity and Mutagenicity of Cement Dust Using Allium
cepa Test, Res. J. Mutagenesis, 1: 10-18.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
18
Zeleke, Z., Moen, B. and Bratveit, M. 2010. "Cement dust exposure
and acute lung function: A cross shift study." BMC Pulmonary
Medicine 10(1): 19.
Zou. J. H., Wang. M., Jiang .W. S. and Liu, D. H. 2006. Effects of
hexavalent chromium (VI) on root growth and cell division in
root tip cells of Amaranthus viridis, L. Pak. J. Bot., 38(3): 673-
681.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
19
CHAPTER II
CEMENT FACTORIES
AND
CEMENT MANUFACTURING
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
20
Cement industry is one of the most basic industries
involved in the development of a country. Cement is the most widely
used building material throughout the world. With the increase in
demand for cement in India too the numbers of factories are
increasing each year and both consumption and production of
cement has increased greatly in recent years. The cement industry
has been recognized to be playing a vital role in the imbalances of
the environment and producing air pollution hazards. The industry
releases huge amounts of cement dust into the atmosphere which
settle on the surrounding areas forming a hard crust and causes
various adverse impacts.
India is the second largest producer of cement after
China. The production process for cement consists of drying,
grinding and mixing limestone and additives like bauxite and iron ore
into a powder known as “raw meal”. The raw meal is then heated
and burned in a pre-heater and kiln and then cooled in an air cooling
system to form a semi-finished product, known as a clinker. Clinker
(95%) is cooled by air and subsequently ground with gypsum (5%)
to form Ordinary Portland Cement (OPC). Other forms of cement
require increased blending with other raw materials. Blending of
clinker with other materials helps to impart key characteristics to
cement, which eventually govern its end use. There are two general
processes for producing clinker i.e. a dry process and a wet
process. The basic differences between these processes are the
form in which the raw meal is fed into the kiln, and the amount of
energy consumed in each of the processes. In the dry process, the
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
21
raw meal is fed into the kiln in the form of a dry powder resulting in
energy saving, whereas in the wet process the raw meal is fed into
the kiln in the form of slurry. There is a semi-dry processing, which
consumes more energy than the dry process but lesser than the wet
process. Majority of Cement plants are dry process plants.
Limestone is crushed to a uniform and usable size, blended with
certain additives (such as iron ore and bauxite) and discharged on a
vertical roller mill, where the raw materials are ground to fine
powder. An electrostatic precipitator de-dusts the raw mill gases and
collects the raw meal for a series of further stages of blending. The
homogenized raw meal thus extracted is pumped to the top of a pre-
heater by air lift pumps. In the pre-heaters the material is heated to
750°C. Subsequently, the raw meal undergoes a process of
calcination in a pre-calcinator (in which the carbonates present are
reduced to oxides) and is then fed to the kiln. The remaining
calcination and clinkerization reactions are completed in the kiln
where the temperature is raised to between 1,450°C and 1,500°C.
The clinker formed is cooled and conveyed to the clinker silo from
where it is extracted and transported to the cement mills for
producing cement. For producing OPC, clinker and gypsum are
used and for producing Portland Pozzolana Cement (PPC), clinker,
gypsum and fly ash are used. In the production of Portland Blast
Furnace Stag Cement (PSC), granulated blast furnace slag from
steel plants is added to clinker. The main raw material used over
here for cement industry includes limestone (CaCO3), clay,
sandstone (SiO2), bauxite (N2O3) and gypsum (Ca2SO4.2H2O) and
involves the release of various particulates, dust, gases and heavy
metals. The whole process can be summarized in the following
flowchart (Figure 1):
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
22
Figure 1: Source: JK Cements LTD
Grinding
Crushing
Mining (Limestone)
Marketting
Packing
Cement Storage
Cement Grinding
Clinker Storage
Pre-Heating /Pre-Calciner
(Clinkerization)
Blending and Storage
Raw
Meal
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
23
Cement manufacture has caused environmental impacts
at all stages of the process in the area. These include emissions of
airborne pollution in the form of dust, gases, noise and vibration
when operating machinery and during blasting in quarries, and
damage to countryside from quarrying. Equipment to reduce dust
emissions during quarrying and manufacture of cement should have
been widely used, and equipment to trap and separate exhaust
gases should have come into increased use.
Unplanned discharges of atmospheric pollutants
influenced by intense industrialization, population explosion and
urbanization result in injury and damage. The intensity and nature of
the damage is a function of the concentration of the pollutant and
the duration of exposure (dose). This has immediate (acute) and
long (chronic) effects on the quantity and quality of agricultural
products (Shaibu -Imodagbe, 1991). Based on the properties of
these pollutants, the resulting effects on the receptor may cause
biochemical and physiological modifications/alterations at the
cellular level as well as whole plant, animal and ecosystem. These
may cause significant changes in agricultural output. The first
argument advanced by the cement industry was that the industry did
not emit any pollutants at all and that what is added by the cement
plants to the environment is only dust and nothing beyond that. The
truth shockingly is otherwise. Almost all the manufacturing units of a
cement factory e.g., raw mill, kiln, coal mill, cement mill are point
sources of pollution emission. In addition some other activities
associated with post-manufacturing stages like open air handling,
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
24
loading and unloading etc. result in leakage of dust into the
environment, which are called fugitive sources of emissions.
Emissions of Carbon dioxide take place during cement
manufacturing due to decarbonisation of Calcium carbonate and
Magnesium carbonate and burning of fossil fuels. Oxidation of
Sulphur in fuel generates SOx (Sulphur dioxides) and combination of
Oxygen and Nitrogen at high temperature in the burning zone
generates Nitrogen oxides. The cement manufacturing processes
thus result in release/ emission of following pollutants:
Criteria Air Contaminants (CAC):
Particulate matter (Suspended and Respirable),
Nitrogen oxides, Sulphur oxides, Carbon monoxide, Volatile organic
compounds (VOC) and Green House Gases (GHG). Other
substances include: Acidic compounds, Heavy metals – Cadmium,
Lead, Mercury and Nickel. It is due to emission of such and other
lethal pollutants that the cement industry finds place in the red
category club i.e. the most polluting industry (Ministry of
Environment and Forest, Government of India and Central Pollution
Control Board).
Blooming of cement factories has resulted in the
environmental deterioration and in turn degrades the human health
status in whole world. Studies have shown adverse respiratory
health effects in the people exposed to cement dust, exemplified in
increased frequency of respiratory problems (Al-Neaimi et al., 2001).
It has also been revealed that people of cement dust zone are badly
affected by respiratory problems, gastro intestinal diseases etc.
(Adak et al., 2007). Several studies have also demonstrated
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
25
linkages between cement dust exposure, chronic impairment of lung
function and respiratory symptoms in human population. Cement
dust irritates the skin (Ikli et al., 2003). Its deposition in the
respiratory tract causes a basic reaction leading to increased pH
values that irritates the exposed mucous membranes (Zeleke et al.,
2010). Numerous studies and the lack of effective policies reveal
that air pollution continues to threaten public health. Studies of long
– term exposure to air pollution (especially particles) suggest an
increased risk of chronic respiratory illness (Schwartz, 1994;
Sivicommar et al., 2001). Besides health, cement factories are
deteriorating environment as shown by studies. The exhaust gases
and particulate matters of the dust exhausted from cement plants
are released to air and degrading air quality and thus creates
considerable environmental pollution (Adak et al., 2007). Since early
1980s, it has become clear that air pollution affects the health of
human beings and animals (Parada et al., 1987), damages
vegetation, soils and deteriorates materials and generally affects not
only the large metropolitan areas but also the medium sized urban
areas. Air pollution has a great impact on human health, climate
change, agriculture and natural ecosystem (Molina et al., 2004).
The impacts of cement industry are countless and it even did not
spare humans from its deteriorating impacts and have adversely
impacted human health in the area. Exposure to cement pollution
has been linked to a number of different health outcomes, starting
from modest transient changes in the respiratory tract and impaired
pulmonary function, continuing to restricted activity/reduced
performance, emergency room visits and hospital admissions and to
mortality (Schuhmacher et al., 2004; Aydin et al., 2010; Zeleke et al.,
2010; Vestbo et al., 1900). There is also increasing evidence for
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
26
adverse effects of cement pollution not only on the respiratory
system, but also on the cardiovascular system (Dockery, 1993). The
most severe effects in terms of the overall health burden include a
significant reduction in life expectancy of the average population by
a month or more ( Samet et al., 2000), which is linked to the long-
term exposure to high levels of air pollution with PM from these
cement industries(Sheppard, 1990; Pope and Dockey., 2006; Grau,
2009)). Besides human health air pollutants have shown more
adverse impacts on livestock (Schwabe, 1984) effecting gross
domestic product (GDP) of the precious wealth of livestock in form
of cattle-buffalo, sheep, goats, poultry etc. The cattle and poultry
amongst all the livestock are considered the most important tool for
the development of the rural economy. The various diseases such
as respiratory infections and various other pollution related problems
are arising among livestock at an alarming rate in the areas.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
27
References
Adak, M. D., Adak, S. and Purohit K. M. 2007. Ambient air quality
and health hazards near min-cement plants. Pollution
Research 26(3): 361- 364.
Al-Neaimi, Y. I., Gomes, J. and Lloyd, O. L. 2001. "Respiratory
illnesses and ventilatory function among workers at a cement
factory in a rapidly developing country." Occupational
Medicine, 51(6): 367.
Aydin, S., Aydin, S., Croteau, G., Sahin, I. and Citil, C. 2010.
"Ghrelin, Nitrite and Paraoxonase/Arylesterase.
Concentrations in Cement Plant Workers." Journal of Medical
Biochemistry 29(2): 78-83.
Dockery, D.W. and Pope, C.A. 1993. Acute respiratory effects of
particulate air pollution. Animal Review of Public Health 1(5):
107 -132.
Grau, L. P.2009. The urban health effects and impact of anthrogenic
and natural air pollution.
Ikli,B.I., Demir, T.A., Urer, S.M., Beker, A., Akar, T. and Kalyoncu,
C. 2003. Effects of chroniuum exposure from a cement factory.
Environmental Research (9):113-118.
Molina, L.T., Molina, M.J., Slott, R., Kolb, C.E., Gbor, P.K. and
Meng, F. 2004. Air quality in selected megacities. Crit Rev., 10
(suppl).
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
28
Parada, R. Gonzalez, S. and Berggvist, E. 1987. Industrial pollution
with copper and other metals in a beef cattle ranch. Veterinary
and Human Toxiciology (29): 122-26
Pope,C.A. and Dockery, W.D. (2006) Health effects of fine
particulate air pollution. Air and waste manage assoc.
(56):709-742.
Samet, J.M., Dominici, F., Zeger, S.L., Schwartz, J. and Dockery, D.
W. 2000. The National Morbidity, Mortality, and Air Pollution
Study. Part I: Methods and Methodologic Issues. Health
Effects Institute Research Report (94), Part I.
Schwabe, C.W.1984. Veterinary Medicine and Human Health. 3rd
edn. Baltimore/London, William and Wilkins, 562-77.
Schwartz, J. 1994. Air pollution and daily mortality: A review and
meta analysis. Environmental Research, (64): 36-52
Schuhmacher, M., Domingo, J. L. and Garreta, J. 2004. "Pollutants
emitted by a cement plant: health risks for the population living
in the neighborhood." Environmental Research (9) 52: 198-
206.
Sheppard, D. Hughson, W.G. and Shellito, J.1990. Occupational
lung diseases. In: Joseph La Dou, Occupational Medicine,
USA, Appleton and Lange: 221-236.
Sivicommar, R., Jayabalou, R., Subrahmanyam, Y.V., Jothikumar, N.
and Swarnalatha, S. 2001. Air pollution in stone crushing
industry and associated health effect. Indian journal of
environmental health, (4):169-73.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
29
Vestbo, J. and Rasmussen, F. V. 1990. "Long-term exposure to
cement dust and later hospitalization due to respiratory
disease. "International Archives of Occupational and
Environmental Health 62(3): 217-220.
Zeleke, Z., Moen, B. and Bratveit, M. 2010. "Cement dust exposure
and acute lung function: A cross shift study." BMC Pulmonary
Medicine 10(1): 19.
Zeyde, K., Zeleke, E.M., Bente. And Magni, B. 2010. Cement dust
exposure and acute lung function. Across shift study, BMC,
Pulmonary Medicine (10): 19.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
31
Three criteria air pollutants are released to the air during
cement manufacturing which includes particulate matter (PM),
nitrogen oxides (NOX) and sulfur dioxide (SO2) which can be
categorised into two headings:
1) Particulates
2) Gaseous pollutants
Particulates
Particulate air pollution is a complex mixture of small
and large particles of varying origin and chemical composition.
Larger particles, ranging from about 2.5 microns to 100 microns in
diameter, usually comprise smoke and dust from industrial
processes, agriculture, construction, and road traffic, as well as plant
pollen and other natural sources. Smaller particles those less than
2.5 microns in diameter generally come from combustion of fossil
fuels. These particles include soot from vehicle exhaust, which is
often coated with various chemical contaminants or metals, and fine
sulfate and nitrate aerosols that form when SO2 and nitrogen oxides
condense in the atmosphere. The largest source of fine particles is
industries, but auto and diesel exhaust are also prime contributors,
especially along busy transportation corridors.
The health effects of particulates are strongly linked to
particle size. Small particles, such as those from fossil fuel
combustion, are likely to be most dangerous, because they can be
inhaled deeply into the lungs, settling in areas where the body‟s
natural clearance mechanisms can‟t remove them. The constituents
in small particulates also tend to be more chemically active and may
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
32
be acidic as well and therefore more damaging. Numerous studies
associate particulate pollution with acute changes in lung function
and respiratory illness (Douglas et.al 1996., USEPA, 1996), resulting
in increased hospital admissions for respiratory disease and heart
disease, school and job absences from respiratory infections, or
aggravation of chronic conditions such as asthma and bronchitis
(Deborah,1996).
Numerous studies suggest that health effects can occur
at particulate levels that are at or below the levels permitted under
national and international air quality standards. In fact, according to
the WHO and other organizations, no evidence so far shows there is
a threshold below which particle pollution does not induce any
adverse health effects, especially for the more susceptible
populations.
Table 1: Particulate size varies with the type of particulate from
different sources:
S. No Particulate type
Diameter References
11
Cement Dust
80-90% greater than 30 um
Darley (1966)
22
Motor Vehicles
0.01-5000um Nimaniya et.al (1971)
33
Urban road dust
3-100um Thompson et.al (1984)
44
Fly Ash 1-2000um Kragickova and Mejstrick (1984)
55
Coal Dust 3-100um Rao (1971)
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
33
Gaseous pollutants
Gaseous pollutants have major negative impacts on
health. They also play an important role in environmental changes in
atmospheric chemistry. SO2 and NO2 form acids through different
chemical reactions in the atmosphere, and these acids are
subsequently deposited on land and ocean surfaces as acid rain. It
is anticipated that the increasing load of atmosphere sulfur dioxide
(SO2), nitrogen dioxide (NO2), carbon dioxide (CO2), carbon
monoxide (CO), and ozone (O3) will contribute to global climate
change, consequently, it is necessary to quantify the emission in the
very near future. The combustion of fuels at high temperatures in
cement kilns results in the release of NOX emissions, which causes
various health adverse health effects. In SO2 emissions from cement
plants result from the combustion of sulfur-bearing compounds in
coal, oil, and petroleum coke, and from the processing of pyrite and
sulfur in raw materials. Cement manufacturing releases carbon
dioxide (green house gas) in the atmosphere both directly when
calcium carbonate is heated, producing lime and carbon dioxide,
and also indirectly through the use of energy if its production
involves the emission of carbon dioxide. The cement industry is the
second largest CO2 emitting industry behind power generation. The
cement industry produces about 5% of global man made CO2
emissions, of which 50% is from the chemical process, and 40%
from burning fuel. The amount of CO2 emitted by the cement
industry is nearly 900kg of CO2 for every1000 kg of cement
produced. The high proposition of CO2 produced in the chemical
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
34
reactions leads to large decrease in mass in the conservation from
lime stone to cement. So, to reduce the transport of heavier raw
materials and to minimize the associated costs, it is more
economical for cement plants to be closer to the lime stone quarries
rather than to the consumer centres. Besides particulates and
gaseous pollutants many other pollutants are also released from
cement factories which include toxic heavy metals
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
35
References
Darley, E.F. 1996. Studies of the effect of cement kiln dust on
vegetation. Journal of the air pollution control association,
(16):145-150.
Deborah, S. 1996. Breathtaking: Premature Mortality Due to
Particulate Air Pollution in 239 American Cities, Natural
Resources Defense Council, New York, p. 14-15.
Douglas and Dockery, 1996. “Health Effects of Acid Aerosols on
North American Children: Respiratory
Symptoms,” Environmental Health Perspectives, Vol.
(104), No. 5, p. 503.
Kragickova, A. and Majestrik, V.1984. The effect of fly ash and
particles on the plugging of stomata. Environmental pollution
(36):83-93.
Ninomiya,J.S.,Bergman, W. and Simpson, B.H.1971. Automotive
particulates emission in England and W.T. Berry, eds.
Proceedings of the second International clear air congress.
Academic press, New York, 663-671.
Rao, D.N.1971. A study of the air pollution problem due to coal
unloading in Varanasi, India. In: H.M England and W.T.
Berry, eds. Proceedings of the second International clear
air congress. Academic press, New York, 273-276.
Thompson,J.R., Mueller, P.W., Fluciger, W.and Rutter,A.J. 1984.
The effect of dust on photosynthesis and its significance for
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
36
roadside plants. Environmental pollution (series A) (34):171-
190.
U.S. Environmental Protection Agency (USEPA), 1996. Office of Air
Quality Planning and Standards, Review of National
Ambient Air Quality Standards for Particulate Matter: Policy
Assessment of Scientific and Technical Information, Report
No. EPA-452/R-96-013 (USEPA, Washington, D.C, V-2-V-
24, V-27-V-28, V-71.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
38
The aerodynamic diameter of cement particles makes it a
potential health hazard, as these are respirable in size and reaches
in internal organs particularly lungs leading to occupational lung
diseases. This size distribution would make the trachea-bronchial
respiratory zone, the primary target of cement deposition. The main
route of entry of cement dust particles in the body is the respiratory
tract and/ or the gastrointestinal tract by inhalation or swallowing
respectively (Green, 1970). Both routes, especially the respiratory
tract are exposed to numerous potentially harmful substances in the
cement mill environment. Besides cement dust various gaseous
pollutants are also contributed by cement factories which cause
pollution and ultimately affect human health.
The various organ systems which get affected because of cement
factories include:
Respiratory system: In respiratory system, these causes lungs
cough and phlegm production, chest tightness, impairment of lung
function, obstructive and restrictive lung diseases, Pleural
thickening, fibrosis, emphysema, lung nodulation, pneumoconiosis
and carcinoma of lung
Gastro intestinal system: Oral cavity, mechanical trauma, mucosal
inflammation, loss of tooth surface, periodontal diseases, dental
caries, dental abrasion, liver diffuse, swelling and proliferation of
sinusoidal (hepatic) lining cells, sarcoid type granulomas,
perisinusoidal and portal fibrosis and hepatic lesions is caused in the
gastro intestinal system.
Stomach: In stomach it causes stomach ache and cancer.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
39
Central nervous system (brain): Usually causes headache and
fatigue.
Lymphatic system: Spleen diminished lymphatic tissue and splenic
lesions.
Other affects includes affect in eyes, skin and bones. Irritation in
eyes, running eyes and conjunctivitis, skin irritation, itching, skin boil
and burn, osteonecrosis, lesion of humerus, thinning of the cortex
and reduction of epiphyseal cartilage.
Allergic reactions that interfere with breathing: Allergic reactions
which create many breathing problems, from simple runny noses to
life-threatening respiratory arrest. The immune system's abnormal
response to harmless allergens unleashes histamines and other
substances that work to restore equilibrium .The side effects of this
process result in respiratory and other allergy symptoms.
Complications can occur in people with extreme sensitivities to the
allergenic proteins in some pollen, foods, household pollutants,
animal secretions and other substances. Pre-existing respiratory
conditions also contribute to the severity of allergic effects on the
respiratory system.
Chronic bronchitis: Bronchitis is an infection of the bronchial tree.
The bronchial tree is made up of the tubes that carry air into the
lungs. When these tubes get infected, they swell and mucus forms.
This makes it hard for a person to breathe. The person may cough
up mucus and many wheeze.
Asthma: Asthma (AZ-ma) is a condition in which the airflow in and
out of the lungs may be partially blocked by swelling, muscle
squeezing, and mucus in the lower airways. These episodes of
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
40
partial blockage, called asthma "fares" or "attacks," can be triggered
by dust, pollutants, smoke, allergies, cold air, or infections.
Emphysema: In emphysema the alveolar tissue is partially
destroyed and the remaining alveoli are weakened and enlarge. The
bronchioles collapse on exhalation, trapping air in the alveoli. Over
time this process impairs the ability to exchange particulate matter
oxygen and carbon dioxide with the circulatory system, leading to
breathing difficulties; Emphysema is a noncontiguous disease that
results from multiple factors, including a genetic predisposition to the
condition, smog, cigarette smoke, and infection.
Lung cancer: Studies of the American Cancer Society cohort
directly link the particulate exposure to with lung cancer. For
example, if the concentration of particles in the air increases by only
1%, the risk of developing a lung cancer increases by 14% (Pope et
al, 2002 and Kweskhi et al, 2004). Further, it has been established
that particle size matters, as ultrafine particles penetrate further into
the lungs (Valavinidis, 2008).
Pneumonia: Pneumonia is an inflammation and infection of the
lungs. Although pneumonia is special concern for older people and
those with chronic illnesses, it can also strike young, healthy people
as well. In infectious pneumonia, bacteria, viruses, fungi or other
organisms attack the lungs, leading to inflammation that makes it
hard to breathe. Pneumonia can affect one or both lungs. Infection
of both lungs is referred to as double pneumonia.
Tuberculosis: Tuberculosis is caused by a bacterium that attacks
the lungs and sometimes other body tissues as well. If infections in
the lungs are left un-treated, the disease destroys lung tissue. In the
past, antibiotics have con-trolled tuberculosis, but recently, new
antibiotic-resistant strains of the tuberculosis bacterium have
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
41
evolved. These new strains now pose a significant public health
problem.
Cough: A cough is a sudden and often repetitively occurring reflex
which helps to clear the large breathing passages from secretions,
irritants, foreign particles and microbes. The cough reflex consists of
three phases: an inhalation, a forced exhalation against a closed
glottis, and a violent release of air from the lungs following opening
of the glottis, usually accompanied by a distinctive sounds (Chung
and Pavord, 2008).Coughing can happen voluntarily as well as
involuntarily. Coughing may be caused by air pollution including
tobacco smoke, particulate matter, irritant gases, and dampness in
the home (Goldsobel and Chipps, 2010). The human health effects
of poor air quality are far reaching, but principally affect the body's
respiratory system and the cardiovascular system.
Wheezing: Wheezing is a high-pitched whistling sound during
breathing. It occurs when air flows through narrowed breathing
tubes. There may be various causes of wheezing such as asthma,
bronchitis, breathing of any foreign substance or dust etc (David
et.al, 2010).
Besides humans, cement affects directly the quality of
soil, as it adds number of harmful substances to it. Although, the
basic constituents of cement dust are calcium (CaCO3), silicon
(SiO2), aluminum (Al2O3), ferric and manganese oxides (Akpan et
al., 2011) its production produces known toxic, carcinogenic and
mutagenic substances, such as particulate matters, sulfur dioxide,
nitrogen dioxide, volatile compounds, long lived dioxins and heavy
metals (Davidovits, 1994). The calcinations and burning processes
of cement production produce poisonous gases that cause injuries
to plants and animals (Abimbola et al., 2007; Gbadebo and Bankole,
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
42
2007). Cement dust causes numerous hazards to the biotic
environment, which have adverse effects and toxicological risks for
vegetation, animal health and ecosystems (Shukla et al., 1990;
Armolaitis et al., 1996; Sivicommar et al., 2001; Schwartz, 1994;
Adak et al., 2007) Plant growth parameters, yield and yield
components of crops can be considerably influenced by excessive
metal accumulation in soil (Lerman, 1972). The particles of cement
deposits are quite alkaline making soils of neighborhood alkaline
and changing its other properties which in turn affects vegetation
growth, decreases chlorophyll content thus decreasing
photosynthesis rate as chlorophyll pigments are essential
component for photosynthesis, decreasing respiration rate, reducing
transpiration and thus growth rate (Borka et al., 1978; Sai et al.,
1987; Shukla et al., 1990; Asubiojo et al., 1991; Iqbal and Shafiq,
2001; Ade-Ademilua and Umebese, 2007; Nanos et al., 2007). Jan
and Bhat, 2006; Rafiq et al., 2008; Jan, 2009 studied the impacts of
cement pollution on morphology of Saffron plant and its productivity.
One of the important aspects is decrease in chlorophyll content. A
decrease in chlorophyll has been used as an indicator of an air
pollution injury (Gibbert, 1968).Decrease in chlorophyll „a‟
chlorophyll „b‟ and Total chlorophyll content in fresh tissues of
affected leaves might be due to chloroplast damage by incorporation
of cement dust into foliar tissue. Similar observation have also been
made by Pandey et al. (1998, 1999) with stone crusher dust and by
Lerman (1972); Singh and Rao (1968); Pandey and Singh (1990)
and by Pandey et al. (1998) with cement dust. Agarwal and Tiwari
(1997) are of the opinion that the alkaline conditions caused by
solubilisation of dust in cell cap may be responsible for chlorophyll
degradation vis–a-vis photosynthetic efficiency. However, Mengel
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
43
and Kirby (1983); Hewitt (1983) indicated that decrease in
chlorophyll is due to induced Iron deficiency caused in excess of
Calcium supply. A number of workers have reported the similar
results (Borka,1980; Lerman, 1972) has suggested that continuous
application of cement clogs the stomata, and thus interfering with
gaseous exchange. This may lead to increased leaf temperatures
which may retard the chlorophyll synthesis (Mark, 1963; Singh and
Rao, 1981). Chlorophyll may be destroyed in cells under cement
cover (Bredemann, 1992; Panjenkemp, 1961; Samdor, 1973;
Klinesek, 1970; Borka, 1978). Reduction in chlorophyll content in
the cement affected plants and in the leaves can be attributed to
the effect of Nitrogen oxides and Sulphur dioxide released from the
factory as the pollutants. The appreciable reduction in chlorophyll
contents in Sulphur dioxide treated plants were also noticed by
some other workers like (Chand and Kumar, 1987; Kumar and
Pandey, 1985).
Besides morphological and physiological changes in
plants there also occur biochemical changes because of cement
dust such as decrease in protein contents , change in proline level,
total free amino acids, reducing sugars, abnormality during mitosis,
chromosomal breakages etc (Kaushik, 1996). Besides gaseous and
particulate pollutants there are also enhanced levels of other
elements (metals and non- metals) in cement dust which cause
numerous effects on plant which includes decrease in yield, seed
germination, leaf area and water content of the leaves (Hasan et al.,
2011). Among the elements most toxic are heavy metals, as cement
dust contains a number of heavy metals such as Mercury, lead,
nickel, chromium etc. These cause cytogenic as well as mutagenic
effects such as decrease in plant growth, low pollen fertility,
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
44
decrease in seed yield, decrease in total protein levels,
chromosomal stickness in meiosis phase, c-mitosis, chromosomal
bridge, chromosome fragmentation, vagrant chromosomes, bi-
nucleus chromosomes and multi-polar anaphase and DNA
fragmentation (Abdul, 2010; Ritambhara et al., 2010; Yahaya et al.,
2012).Among heavy metals Mercury plays an essential role.
Mercury is a typical toxic metal pollutant. Bioaccumulation of
mercury in plants and its entry into the food chain resulting in long
term health hazards is of major concern. Since the beginning of the
industrial era, anthropogenic adulteration of the atmosphere,
increased mining, high rate containing mercury in the industries are
some of the sources of mercury, creating a vitiated environment.
The uptake and accumulation of chemicals by plants may prove to
be the most important aspect of chemical pollution dynamics
(Mohapatra, 1989). It is interesting to note that the elements like
mercury are easily absorbed by the plants than the other elements
(Pendias and Pendias, 1989).The higher concentration of mercury is
due to the mercury released from the factory kiln and preheating/
precalcining operations which gets accumulated in the nearest area
of the factory. Mercury is introduced into the kiln with raw materials
(90% of the material input) and to a minor extent with fuels, such as
coal and oil which are used to provide energy for calcinations. It is
also reported that the hypogeal parts accumulated comparatively
lesser amounts of mercury than the epigeal parts in plant (Jan and
Bhat, 2008). Mobility of heavy metal mercury has been
demonstrated by a members of workers, Furgusson (1984)
correlated the transportation system through the xylem and phloem
and transpiration intensity which significantly influence its
accumulation. Mercury mobility to Peterson, (1984) appeared to be
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
45
greater when it entered the plant through the stem or leaf .The metal
entry into plants through the leaves is more significant for pollution
elements because of aerosol deposits (Furgusson, 1984). A number
of reports revealed that the accumulated levels in plants are
influenced by their distance from the source of the metal (Steinnes,
1987) and also seasonal effect (Chaney et al., 1984).
Cement dust causes numerous hazards to the biotic
environment, which have adverse effects and toxicological risks for
vegetation, animal health and ecosystems (Shukla et al., 1990;
Armolaitis et al., 1996; Sivicommar et al., 2001; Schwartz, 1994;
Adak et al., 2007) Plant growth parameters, yield and yield
components of crops can be considerably influenced by excessive
metal accumulation in soil (Lerman, 1972).
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
46
References
Abdul, G. 2010. Toxic effects of heavy metals on plant growth and
metal accumulation in maize (Zea mays L.), Iranian J.
Toxi., 3.
Abimbola, A. F., Kehinde, P. O. O. and Olatunji, A.S. 2007. The
sagamu cement factory, SW Nigeria: Is the dust generated a
potential health hazard. Environ. Geochem. Health, 29: 163-
167.
Ade-Ademilua, O. E. and Umebese, C. E. 2007. The growth of
Phaseolus vulgaris L. (Leguminosae) in a cement site rich
in heavy metals. Pak. J. Biol. Sci., 10: 182-185.
Adak, M. D., Adak, S. and Purohit K. M. 2007. Ambient air quality
and health hazards near min-cement plants. Pollution
Research 26(3): 361- 364.
Agarwal, S and Tiwari, A. 1997. Observations on Kiln dust pollution
in Patrapali region Raigrh (M.P.). Flora and Fauna. 3(2):
131-133.
Akpan, I. O., Amodu, A. E. and Akpan, A. E. 2011. An assessment of
the major elemental composition and concentration in
limestones samples from Yandev and Odukpani areas of
Nigeria using nuclear techniques. J. Environ. Sci. Technol.,
4: 332-339.
Armolaitis, K. E., Vaichis, M. V., Kuchialaricheno, L. and Raguotis,
A. O. 1996. Influence of cement mill emission on physico-
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
47
chemical properties of forest soils near the mill. Europ. Soil
Scien., 28: 212-220.
Asubiojo, O. I., Aina, P. O., Oluwole, A. F., Arshed, W., Akanle, O.
A. and Spyrou, N. M. 1991. Effects of cement production on
the elemental composition of soils in the neighbourhood of
two cement factories. Water Air Soil Pollut., 819–828.
Borka, G., Lsaszar, E. and Melnar, A. 1978. The effect of cement
factory dust on the development, growth and some
important metabolic processes of wheat cultivars. Botan.
Kozlemenyek, 65(4): 233-238.
Bredemann, G. 1992. Botanische Unttersuschungen bei
Reuchschaden. In Entstehung, Erkennung and Beurteilung
van Rauchschden ed. By E. Haselhoff, G. Bredemann and
W. Haselhoff, 285-392. Berlin, Gebr. Borhtraegen Verl.
Chand, S. and.Kumar, N. 1987. Ecological aspects of Oryza sativa,
Linn, IR-8 in relation to SO2 gas. Journ. Uni. Kuwait (Sci.) 8,
229-234.
Chaney, R.L., Strrett, S.B. and Mickle, H.N. 1984. In Proc. Symp.
Heavy Metals in Urban soils (ed. Preer, J.R.) Univ. Dist.
Columbia, Washington, , pp. 37-84.
Chung, K. F., Pavord, I. D. April 2008. "Prevalence, pathogenesis,
and causes of chronic cough". Lancet 371 (9621):1364–74.
David, Z, M,D. and David, R. E. 2010. Previously reviewed by Neil
K.Kaneshiro, MD, MHA, Clinical Assistant Professor of
Pediatrics, University of Washington School of Medicine,
Medline plus.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
48
Davidovits, J. 1994. Global warming impact on the cement and
aggregate industries. World Resour. Rev., 6: 263-278.
Furgusson , J.E., 1984. Sci. Total Environ., 50, 1-5.
Gbadebo, A. M. and Bankole, O. D. 2007. Analysis of potentially
toxic metals in airborne cement dust around sagamu,
Southwestern Nigeria. J. App. Sci., 7: 35-40.
Gibbert, O.L. 1968. Bryophytes as indicators of air pollution in the
Tyne Valley-New Phytol 67: 15-36.
Green, G.M. 1970. The J. Burns Amberson lecture. In defense of
lung. Am. Rev. Rep. Dis.102: 691-703.
Hasan et al., 2011. Effect of kiln dust from a cement factory on
growth of Vicia faba L. J. Environ. Bio., 32.
Hewitt, E.J. 1983. Diagnosis of mineral disorders in plants, vol. H,
M,S,O, Lendon, p: 54-110.
Iqbal, Z.Muhammad. and Shafiq, Muhammad.2001. Effect of cement
dust pollution on the growth of some plant species. Turk.
Journal Bot. (25): 19-24.
Jan, A. and Bhat, G. A. 2006. Impact of cement dust on the
morphology of Saffron (Crocus sativus) and three species of
horticultural trees. J. Res. and Dev., 6, 129-133.
Jan, A. 2009. Impact of cement dust pollution on agricultural crops
with special reference to Saffron cultivation in Pampore
area. Ph.D Thesis submitted to University of Kashmir.
Kaushik, G. C. 1996. Cytotoxicity of cement kiln dust on mitosis of
root tip cells in Vicia faba. J. Ecotoxi. and Environ. Monit.,
6(1): 53-57.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
49
Klinesek, P. 1976. Investigation on the effect of cement dust on
some common trees and shrubs. Kertgazdasag, 8/3(1): 71-
76.
Krewski D, Burnett R, Jerrett M, Pope CA, Rainham D, Calle E,
Thurston G., Thun M. 2004. Mortality and long-term
exposure to ambient air pollution: ongoing analyses based
on the American Cancer Society cohort". J. Toxicol.
Environ. Health A (68)13–14.
Kumar, S. S., Singh, N. A., Kumar, V., Sunisha, B., Preeti, S.,
Deepali, S. and Nath, S. R. 2008. Impact of dust emission
on plant vegetation in the vicinity of cement plant. J.
Environ. Engin. and Manage., 7(1): 31-35.
Lerman, S. 1972. Cement kiln dust and the bean plant (phaseolus
vulgaris L. Black Valentioe Var): In dep. invest.
Mark, L.T. 1963. Temperature inhibition of carotene synthesis in
tomato. Bot. Gaz., 124, 180-5.
Mengel, A. and Kirby.C. 1983. The qualitative analysis of chlorophyll
in plant extracts. Photochemical and Photobiology, 2, 241-3.
Mohapatra, A., 1989. Curr.Sci., 806-807.
Nanos, G. D and Ilias, F. I. 2007. Effects of inert dust on olive (Olea
europaea L.) leaf physiological parameters. Environ. Sci.
and Poll. Res. Intern., 14: 212-214.
Pandey, D.D. and Simba, A.K. 1990. Effect of cement kiln dust
pollution on certain parameters of maize crops and soils.
Ind. J. Envt. Health. 17: 114-120.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
50
Pandey, D.D. and Singh, A.K. 1990. Effect of cement dust on
chlorophyll in wheat leaf. Environm. and Ecol., 8: 461-463.
Pandey, D.D.; Sinha, A.K. and Kumar, P. 1998. Impact of stone
crusher dust pollution on Cicer arietinum. Biojournal, Vol. 10
(No.1. and 2): 105-110.
Panjenkemp, H. 1961. Einwirkung des Zementofenstaubes duf
pflanze and tiere. Zem-kalk-Gips, 14: 88-95.
Pendias, A. and Pendias, H. 1989.Trace Elements in soils and
plants, CRC press, Cleveland, Ohio.
Peterson, P.J., Benson, L.M. and Zicve, R., 1984. Effects of trace on
plant function, Applied Science Publishers, pp. 279-342.
Pope, C.A., Burnett, R.T., Thun, M.J., Calle, E.E., Krewski, D., Ito,
K., Thurston, G.D. 2002. "Lung cancer, cardiopulmonary
mortality, and long-term exposure to fine particulate air
pollution". Journal of the American Medical
Association 287 (9): 1132–1141.
Rafiq, S. K., Ganai, B. A. and Bhat, G. A. 2008. Impact of automobile
emissions on the productivity of Crocus sativus L. Inter. J.
Environ. Res., 2(4): 1735-6865.
Ritambhara, T. and Kumar, G. 2010. Genetic loss through heavy
metal induced chromosomal stickiness in Grass pea. Plant
Genetics Laboratory, Department of Botany, University of
Allahabad, Allahabad-211002, India.
Sai, V. S., Mishra, M. P. and Mishra, G. P. 1987. "Effect of cement
dust pollution on trees and agricultural crops." Asian
Environment 9(1): 11-14.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
51
Samdor, L. 1973. A Naszaly hegy xemeszeti feldrajza xekinterrel a
kialakitasra kerdo porvedo erdosav vendszorre,
Szakdolgozat. Kerteszeti Egyetem, Budapest.
Schwartz, J. 1994. Air pollution and daily mortality: A review and
meta analysis. Environmental Research, (64): 36-52.
Shukla, J. V., Pandey, S. N., Singh, M., Yunus, M., Singh, N. and
Ahmad, T. J. 1990. Effect of cement dust on growth and
yield of Brassica campestris L. Environ. Pol., 66(1): 81-88. .
Singh and Rao, D.N. 1968. Effect of cement dust pollution on soil
properties on wheat plants. Ind. J. Envt. Health. 20: 258-
267.
Singh, S.N. and Rao, D.N. 1981. certain responses of wheat plants
to cement dust pollution. Env. Pollution. Ser. A. 24: 75-81.
Sivicommar, R., Jayabalou, R., Subrahmanyam, Y.V., Jothikumar, N.
and Swarnalatha, S. 2001. Air pollution in stone crushing
industry and associated health effect. Indian journal of
environmental health, (4):169-73.
Steinnes, E., 1987. In lead, Mercury, Calcium and Aresenic in the
Environment (eds Hutchinson, J.C and Mcena, K.M.), Scope
31, Nilcy, New York, , pp. 107-117.
Valavanidis, A., Fiotakis, K. and Vlachogianni, T. 2008. "Airborne
particulate matter and human health: toxicological
assessment and importance of size and composition of
particles for oxidative damage and carcinogenic
mechanisms". J. Environ. Sci. Health C. Environ. Carcinog.
Ecotoxicol. Rev. 26 (4): 339–62.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
52
Yahaya, T. Okpuzor, J. and Oladele, E. O. 2012. Investigation of
Cytotoxicity and Mutagenicity of Cement Dust Using Allium
cepa Test, Res. J. Mutagenesis, 1: 10-18.
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PHOTO GALLERY
Some photo Glimpses
Of pollution from cement factories
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54
Panoramic View of Saifco Cement Factory in Khonmoh,
Jammu and Kashmir, India
Dust and Gas Emission from JK Cements, Khonmoh,
Jammu and Kashmir, India
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55
Huge Gaseous Clouds Emanating from Khrew Cement Factory,
Jammu and Kashmir, India
Dust and Gas Emissions from Khrew, Jammu and Kashmir,
India (JK Cements)
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56
Cement Dust on Wild Fruit Shrub (Rubus viveus)
Cement Dust on Forest Tree (Celtis australis) and the Ground
Herbage on which Cattle Graze
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57
Dust and Gas coming out from the Chimney of the Factory
Cement Dust Settled on the Vehicles
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58
Cement factory of Khrew, Jammu and Kashmir, India
Cement Dust settled on creepers
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
61
Cement is currently the most widely used material
throughout the world. Its production is being recognized to be
playing a hazardous role in the imbalances of the environment and
producing air pollutants. The cement kilns emit enormous amounts
of cement dust into the atmosphere which settle on the soil and
vegetation of landscape. Cement dust is a potential phytotoxic
pollutant in the vicinities of cement producing factories creating
serious pollution problems. Quality of air is vitally important simply
because we can‟t avoid breathing in the air around us. The average
adult breathes in about 20 cubic meters, or 20,000 liters of air a day.
Those who live in urban and sub urban areas should be especially
concerned, since they are exposed to a greater amount of pollutants
coming from automobile traffic, commercial, industrial and
manufacturing facilities, as well as other sources. Air pollutants can
cause a variety of health problems - including breathing problems;
asthma; reduced lung function; lung damage; bronchitis; cancer;
and brain and nervous system damage. Air pollution can also irritate
the eyes, nose and throat, and reduce resistance to colds and other
illnesses. Air pollution can be especially harmful to the very young,
the very old, and those with certain -existing medical conditions. Air
pollution also causes haze and smog, reduces visibility, dirties and
damages buildings and other landmarks, and harms trees, lakes
and animals. It is also responsible for thinning the protective ozone
layer in the upper atmosphere that protects us from harmful
ultraviolet radiation from the sun, and is also contributing to the
phenomenon known as global warming- the steady increase in
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
62
average temperature of the global climate(Environmental
assessment and policy).
The fact that air pollution is hazardous to human health
is well known. WHO estimates that, worldwide, at least two million
people every year die prematurely due to health effects caused by a
lack of clean air? Air is the basic necessity of human life but the
quality of air is deteriorating continuously and it is being constantly
polluted from different sources. One of the major sources of air
pollution are automobiles and industries, as per estimates vehicular
pollution is the primary cause of air pollution in urban areas (60%),
followed by industries (20-30%) in India ( Sivasamy and
Srinivasan,1997). Number of industries in India is increasing with
time so is increase in air pollution. Cement industry is one of the
most important industry in India, as India is the second largest
cement producer in the world, cement consumption in the country
has been growing @ 10% per annum in the last few years and this
growth pattern is expected to be maintained, still country has per
capita consumption about 150 as compared to world average of
about 400 which is a huge gap, so cement production of country is
expected to increase at an alarming rate.
The discharge of cement factories generally consist of
Particulate matter, Sulphur dioxide and Nitrogen oxides producing
continuous visible clouds which ultimately settle on the surroundings
as a result the whole ecosystem around the cement factory is
subjected to extraordinary stress and abuse. Huge clouds of cement
dust have been in generation in the area right from the
establishment of these factories.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
63
Almost all the manufacturing units of a cement factory
e.g., raw mill, kiln, coal mill, cement mill are point sources of
pollution emission. In addition some other activities associated with
post-manufacturing stages like open air handling, loading and
unloading etc. result in leakage of dust into the environment, which
are called fugitive sources of emissions. Emissions of Carbon
dioxide take place during cement manufacturing due to
decarbonisation of Calcium carbonate and Magnesium carbonate
and burning of fossil fuels. Oxidation of Sulphur in fuel generates
SOx (Sulphur dioxides) and combination of Oxygen and Nitrogen at
high temperature in the burning zone generates Nitrogen oxides.
The cement manufacturing processes thus result in release/
emission of following pollutants:
Particulate matter (Respirable and non respirable),
Nitrogen oxides, Sulphur oxides, Carbon monoxide, Volatile organic
compounds (VOC) and Green House Gases (GHG).Other
substances include: Acidic compounds, Heavy metals – Cadmium,
Lead, Mercury and Nickel. It is due to emission of such and other
lethal pollutants that the cement industry finds place in the red
category industry i.e. the most polluting industry (Ministry of
Environment and Forest, Government of India and Central Pollution
Control Board).
Besides all these there are some hidden impacts on the
surrounding community such as the visual blight and resulting drop
in property values, lowering living standard and quality of life, noise
and diesel truck emissions, socio economic degradation, increase in
stress level and many more.Cement industry is a major pollution
problem contributor in terms of dust and particulate matter emitted at
various steps of cement manufacture. Besides particulate matter,
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
64
SO2, NOx, discharge from cement factories generally consists of
heavy metals and dust producing continuous visible clouds which
ultimately settle on the surroundings as a result the whole
ecosystem around the cement factory is subjected to extraordinary
stress and abuse.
Keeping in view the hazards of cement dust it is
recommendable that the cement industry management, their
workers and health officials should work together to adopt scientific
and technical preventive measures, such as well ventilated work
areas and workers should wear appropriate apparel, mask, safety
goggles etc. It is also suggested that cement mill workers must
undergo pre-employment and periodic medical surveillance tests.
These measures would help to identify susceptible workers in due
time and improve the technical preventive measures that will
decrease the risk of occupational hazards in the cement industrial
workers. Tree belts must be established around the newly come up
cement factories. The stack height must be appropriate and air
pollution control devices should be installed and regularly checked.
CEMENT FACTORIES, AIR POLLUTION AND CONSEQUENCES
65
About the Author
Syed Sana Mehraj Balkhi completed her masters
in Environmental sciences from university of Kashmir
in 2010.Pursued her M.Phil. from the same university
on various consequences of cement pollution from
2011- 2013.Presently author is pursuing her Doctoral
degree on cement pollution consequences with special reference
to toxic metals from university of Kashmir
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