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2008 Thioethers Q 0580 Alkynes as Masked Ylides: Gold-Catalyzed Intermolecular Reactions of Propar- gylic Carboxylates with Sulfides. — The in situ generation of sulfur ylides by the Au-catalyzed rearrangement of propargylic carboxylates in the presence of sulfides gives access to novel highly functionalized materials. — (DAVIES*, P. W.; ALBRECHT, S. J.-C.; Chem. Commun. (Cambridge) 2008, 2, 238-240; Sch. Chem., Univ. Birmingham, Edgbaston, Birmingham B15 2TT, UK; Eng.) — M. Paetzel 21- 082

ChemInform Abstract: Alkynes as Masked Ylides: Gold-Catalyzed Intermolecular Reactions of Propargylic Carboxylates with Sulfides

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2008

ThioethersQ 0580 Alkynes as Masked Ylides: Gold-Catalyzed Intermolecular Reactions of Propar-

gylic Carboxylates with Sulfides. — The in situ generation of sulfur ylides by the Au-catalyzed rearrangement of propargylic carboxylates in the presence of sulfides gives access to novel highly functionalized materials. — (DAVIES*, P. W.; ALBRECHT, S. J.-C.; Chem. Commun. (Cambridge) 2008, 2, 238-240; Sch. Chem., Univ. Birmingham, Edgbaston, Birmingham B15 2TT, UK; Eng.) — M. Paetzel

21- 082