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NitrilesQ 0520 DOI: 10.1002/chin.201045068
An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Ni-triles. — The tandem reaction includes a TBAB-catalyzed substitution using sodium azide and the following oxidative rearrangement with DDQ as an oxidant. Excellent functional group tolerance is shown. The reaction can be scaled up. — (ZHOU, W.; XU, J.; ZHANG, L.; JIAO*, N.; Org. Lett. 12 (2010) 12, 2888-2891, DOI:10.1021/ol101094u ; State Key Lab. Nat. Biomimetic Drugs, Sch. Pharm. Sci., Peking Univ., Beijing 100083, Peop. Rep. China; Eng.) — R. Steudel
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ChemInform 2010, 41, issue 45 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
www.cheminform.wiley-vch.de
ChemInform 2010, 41, issue 45 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
