C-C bond formationO 0282 DOI: 10.1002/chin.201208048

Chemoselective Transfer of Allyl or Phenyl Group from Allyl(phenyl)germanes in Pd-Catalyzed Reactions with Aryl Halides. — The chemoselective Stille-like syn-thesis of the compounds (III) also gives the homocoupling by-products. The yields of the chemoselective Heck-like reaction to the compounds (V) decrease with the number of allyl groups of the Ge-compounds (I)/(IV) while the isomeric ratios (V)/(VI) remain similar. — (PITTELOUD, J.-P.; LIANG, Y.; WNUK*, S. F.; Chem. Lett. 40 (2011) 9, 967-969, http://dx.doi.org/10.1246/cl.2011.967 ; Dep. Chem. Biochem., Fla. Int. Univ., Miami, FL 33199, USA; Eng.) — C. Gebhardt

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