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2001 diastereoselective syntheses, enantioselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism) O 0031 46 - 031 Chiral S,S-Donor Ligands in Palladium-Catalyzed Allylic Alkyla- tion. — Chiral dithioethers are investigated for the first time as ligands in Pd-catalyzed asymmetric allylic alkylation. Enantioselectivities obtained with ligands (I) and (IIb) range from 13 to 42%. — (GOMEZ, MONTSERRAT; ET AL.; Tetrahedron: Asymmetry 12 (2001) 10, 1469-1474; Dep. Quim. Inorg., Univ. Barcelona, E-08028 Barcelona, Spain; EN) 1

ChemInform Abstract: Chiral S,S-Donor Ligands in Palladium-Catalyzed Allylic Alkylation

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2001 diastereoselective syntheses, enantioselective syntheses

diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)O 0031

46 - 031Chiral S,S-Donor Ligands in Palladium-Catalyzed Allylic Alkyla-tion. — Chiral dithioethers are investigated for the first time as ligands inPd-catalyzed asymmetric allylic alkylation. Enantioselectivities obtained withligands (I) and (IIb) range from 13 to 42%. — (GOMEZ, MONTSERRAT;ET AL.; Tetrahedron: Asymmetry 12 (2001) 10, 1469-1474; Dep. Quim. Inorg.,Univ. Barcelona, E-08028 Barcelona, Spain; EN)

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