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AminationO 0268 DOI: 10.1002/chin.201029040
Copper-Bipyridine-Catalyzed Enantioselective α-Amination of β-Keto Esters. — Highly enantioselective α-amination of 1-indanone-based β-keto esters with diethyl azodicarboxylate is achieved in the presence of a chiral copper-bipyridine catalyst. Interestingly, β-diketones react with significant lower enantioselectivity under similar conditions. — (GHOSH, S.; NANDAKUMAR, M. V.; KRAUTSCHEID, H.; SCHNEIDER*, C.; Tetrahedron Lett. 51 (2010) 14, 1860-1862; Inst. Org. Chem., Univ. Leipzig, D-04103 Leipzig, Germany; Eng.) — Mais
29- 040
ChemInform 2010, 41, issue 29 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim