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Carboxylic amidesQ 0490 DOI: 10.1002/chin.201106087

Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation. — The process can be applied to the formation of various amides, sulfonamides and carboxylic acids/esters. In the case of amine (XIV) and tBuOH, thermolytic cleavage of the -tBu groups takes place. — (ROBERTS*, B.; LIPTROT, D.; ALCARAZ, L.; LUKER, T.; STOCKS, M. J.; Org. Lett. 12 (2010) 19, 4280-4283, http://dx.doi.org/10.1021/ol1016965 ; AstraZeneca R&D Charnwood, Loughborough, Leicestershire LE11 5RH, UK; Eng.) — R. Simon

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ChemInform 2011, 42, issue 06 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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ChemInform 2011, 42, issue 06 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim