1997 alkylation, arylation, dealkylation, dearylation, C-acylation, olefination

alkylation, arylation, dealkylation, dearylation, C-acylation, olefinationO 0280

32 - 043Nucleophilc Introduction of Fluorinated Alkyl Groups into Aldehydesand Ketones Using the Corresponding Alkyl Halide with Samar-ium(II) Iodide. — SmI2 is found to induce the nucleophilic introductionof fluorinated alkyl halides into aldehydes and ketones, opening a new route toorganofluorine compounds. — (YOSHIDA, M.; SUZUKI, D.; IYODA, M.; J.Chem. Soc., Perkin Trans. 1 (1997) 5, 643-648; Dep. Chem., Fac. Sci., TokyoMetrop. Univ., Hachioji, Tokyo 192-03, Japan; EN)

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