2001 dehalogenation

dehalogenationO 0236

08 - 070Rapid and Efficient Palladium Catalyzed Reduction of Aryl Halidesby Triethylsilane under Microwave Irradiation. — Triethylsilanein the presence of catalytic amounts of palladium chloride is an efficient andselective system for reductive dehalogenation of aryl halides under microwaveirradiation. The new dehalogenation method is compatible with a variety offunctional groups such as ketone, ester, or nitro groups. — (VILLEMIN,DIDIER; NECHAB, BELKACEM; J. Chem. Res., Synop. (2000) 9, 432-434;Ec. Natl. Super. Ing., CNRS, Inst. Sci. Matiere Rayonnem., Univ. Caen,F-14050 Caen, Fr.; EN)

1