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Rhodium(I)-Catalyzed Intramolecular Ene Reaction of Vinylidenecyclopropanes and Alkenes for the Formation of Bicyclo[5.1.0]octylenes. — Acetonitrile plays a crucial role in the reaction medium. In toluene, [2+2]cycloaddition adducts (XII) are formed with moderate yields. — (LI, W.; YUAN, W.; SHI, M.; HERNANDEZ, E.; LI*, G.; Org. Lett. 12 (2010) 1, 64-67; Dep. Chem. Biochem., Tex. Tech. Univ., Lubbock, TX 79409, USA; Eng.) — R. Simon
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ChemInform 2010, 41, issue 23 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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