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Chemistry 11
Organic Chemistry Unit Review
Name: Date: Block:
Answer the questions in the space provided.
1. Of the following molecules, choose 2 that best fit each description.
a) Structural Isomers a) A&E _________ , F&G ________
b) Unsaturated Hydrocarbons b) B&F&D ______ , ____________
c) Have the general formula CnH2n+2 c) A&C&E ______ , ____________
d) When water is added, forms an alcohol d) D&F&H ______ , ____________
e) Contain alkyl groups e) A&C ________ , ____________
2. Explain what is wrong with each of the following. If a given name is incorrect, provide the correct name.
a) 2-ethylheptane b) 5-methylhexane
c) d) 2-fluoro-4-hexyne
e)
CH3 C
CH3
CH3
CH3CH C CH2 CH3 CH3 CH2 CH2 CH CH3
CH3
CH2 CH CH2 CH3CH2 CH2
CH2CH2
CH3 CH2 CH CH CH3
A B C
D E
F G
H
2-butene pentane
CH3 CH2 CH CH3
CH3
F
CH3
CH3CH3
= 2,4,6-trimethylbenzene
3. Name the following molecules. a) b) pentane 3-methylheptane c) d) 5-ethyl-3-methyloctane 2,2,4,4-tetramethylpentane e) f) 4-methyl-2-pentene 1-butyne g) h) 3,4-dibromo-2,2-dichloro-5-iodohexane 1-ethylcyclopentane i) j)
3-octene 1,3,5-trichlorobenzene
CH3CH2CH2
CH2 CH3
CH3 CH2 CH2 CH2 CH CH3CH2CH3
CH3 C CH2 C CH3
CH3
CH3
CH3
CH3
CH3 CH CH CH CH3
CH3
CH C CH2
CH3
CH3 C CH CH CH
BrCl
Cl
Br
I
CH3CH2
CH2
CH2
CH
CH2
CH2 CH3
Cl
Cl Cl
CH3 CH2 CH CH2 CH CH2 CH2 CH3
CH3 CH2CH3
CH3 CH2 CH2 CH2
C CCH2 CH3
H
H
4. Draw the structures of the following compounds. a) 3-ethyl-4-methyloctane b) 3-heptyne c) 3,3-diethylpentane d) 1-chloro-3-ethylbenzene e) tetramethylbutane f) 1-chloro-3,4-dimethyl-cyclohexane g) 3-iodo-1-propyne h) dichloromethane i) 3-heptene j) 2-pentene
5. Draw this molecule. 4,4,5-triethyl-2,3,5,6,8,8,-hexamethyl-6,7-dipropyldecane
6. Name the following compound:
CH
C C C C C C C CH3
CH
CH
CH2
CH3
CH3
FCl
Br
Cl
CH3
CH2
CH2
CH3
CH2
CH2
CH3
CH2
CH3
CH3
CH3
CH2
CH3
F
Br
Br
Br
F
7. Draw and name all of the structural isomers of C6H14.
8. Draw and name all of the structural isomers of C5H10.
9. Draw and name as many structural isomers for C4H9OH:
10. Draw and name as many structural isomers for C5H10BrOH:
11. Match the following compounds to their appropriate descriptions. There may be more than one correct answer. 1. ___D, E___ Alcohol
2. ___G___ Carboxylic acid
3. ___C___ Saturated hydrocarbon
4. ___I___ Ketone
5. ___N___ Aromatic ring
6. ___M___ Propyne
7. ___K___ Ether
8. ___L___ Ester
9. ___H___ Aldehyde
10. ___H___ 12 carbons
11. ___N___ Benzene
12. ___C___ Alkane
13. ___B, J___ Alkene
14. ___A, M___ Alkyne
15. A, B, N, M_ Has no isomers
16. ___J___ Diene
17. ___E___ Methanol
18. ___D___ Ethanol
19. ___N___ C6H6
20. ___J___ C6H8
A B C
D E F
G H
C2H2 C2H4 C2H6
CH3 CH2 OH CH3 OH CH2 C OHNH2
O
CH2 C OHCH2
O
CH3
CH2 C CH2CH2
O
CH3 CH2 CH3
CH
O
I J
K L
M N
CH2 C OCH2
O
CH3 CH3CH2 O CH2CH2CH3 CH2 CH3
H C C C H
H
H