Combustion in Rotary Kilns & Precalciners, New Targets and Solutions

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  • Fives Pillard 1

    COMBUSTION IN ROTARY KILNS& PRECALCINERS

    NEW TARGETS AND SOLUTIONS

    Fives Driving Progress

  • Fives Pillard 2

    Brief overview of Fives Pillard, Marseilles, France...

    J.C.P.

  • 3Fives Pillard

    Kiln burner concepts of the 90's

    BURNERS WITH AXIAL & RADIAL

    CHANNELSADJUSTABLE AT SITE

    The ROTAFLAM burner

    FIXED BURNER HIGH IMPULSE

    LIMITING MISTAKES OF OPERATORS

    The traditional burner

    versus

    (+) Can be tuned to each kiln at site

    (-) Difficult to adjustComplexHeavy

    The two concepts have been applied for over 15 years,both have shown their limits none is a clear winner.

    NEW PATENTSDE 3933050C2 of Oct. 4, 1989EP 90.430017.5 of Sept.14,1990

    (+) Avoid mistakes ofoperators

    (-) Damages on refractoriesHigh NOx emissionLimited adjustmentsSticking on tips

  • 4Fives Pillard

    New (priority) millennium targets

    Target YearAssess burner operation in a kiln, using Fluent CFD softwareCement kiln simulations1 1999

    Develop the use of Alternative Solid Fuels (A.S.F.) in EuropePowders (animal, biomass, urban) and "Fluff"

    Decrease the running costs of European Cement PlantsBy conversion to high % of A.S.F.

    Put Clinker quality as a priority(+) The Sulphur cycle must be improved

    Address new Sustainable development requirementsReducing CO and NOx emission AT STACK

    2001-

    2005Simplify burners use : the NOVAFLAM burnerImprove precalciners / Urea Ammonia injection

    2000-

    2004

    2 2002

    3 2003

    4

    5

    6 2005Control combustion in real time

  • Fives Pillard 5

    Target 1:

    Assess burner operation in a kiln,using Fluent CFD software

  • 6Fives Pillard

    First cement kiln simulations (with Fluent CFD software)

    The Fluent CFD tool allows to compare burner tip geometries

    Stream lines around flames

    Question : Are there big recirculation areas inside the kiln ?

    Answer : NoExtract from competitor article

    UNTRUE

    High intensity flameLong lazy flame

    Question : Can we evaluate the influenceof flame intensity on theclinker bed ?

    Answer : Yes

    Bad air distribution(white cement)

    Improved

    Question : What is the influence of airdistribution ?

    Answer : essentialMUST be optimized first

  • Fives Pillard 7

    Target 2:

    Develop the use of A.S.F. in Europe

  • 8Fives Pillard

    A.S.F.: how to improve the combustion of fluff ?

    First dispersor New dispersor (2005)

    NEW PATENTSFR 9808254 of June 24, 1998EP 99.430010.1 of June 23, 1999

    ; A fast dispersion into the flameA new "fluff dispersor" has been developed

    Fluff being heterogeneous, its combustion requires:

    Suction of secondary air Radiation on clinker

    ; An acceleration of the combustion, by SLOT EFFECT, enabling

    to Adapt the amount of Hot Secondary Air(H.S.A.) introduced in the flame

    And, - as a consequence- , to affect the flame temperature

    Few H.S.A. in flame,SOFT FLAME

    Fast/high H.S.A. in flame,HIGH INTENSITY FLAME

  • Fives Pillard 9

    Target 3:

    Decrease the running cost of European Cement Plants by conversion to high % of A.S.F.

  • 10Fives Pillard

    The ROTAFLAM Version 2 with SLOT EFFECT

    allowed for a huge increase of A.S.F. use (%)

    (A.S.F.) Alternative Solid FuelsEnd user Kiln (tpd)

    % Heat release Type

    HOLCIM HOVER, Germany DRY 3200 75 Fluff + Animal meal ROTAFLAM V2

    HEIDELBERGER LENGFURT, Germany DRY 2500 80 Fluff + Animal meal + Solvents ROTAFLAM V2

    HEIDELBERGER SCHELKLINGEN, Germany DRY 2500 75 Fluff+ Dry sewage sludge ROTAFLAM V2

    ROHRDORF, Germany SEMI WET 3000 80 Tetrapack, Plastic ROTAFLAM

    WITTEKIND, Germany DRY 2500 52 Bram ROTAFLAM V2

    DYCKERHOFF, DEUNA, Germany DRY 3000 50 Fluff + Plastic ROTAFLAM

    HOLCIM ECLEPENS, Switzerland DRY 2000 30 Sawdust + Animal meal ROTAFLAM V2

    Burner

  • 11Fives Pillard

    The ROTAFLAM Version 2 with SLOT EFFECT

    Focus on Holcim plant, Hver (G) : Clinker quality improved and Fluff consumption increased

    up to 75 %, i.e. 13 tons/hr

    NEW PATENTSFR 0705305 of July 20, 2007EP 08.160478.7 of July 16, 2008

  • Fives Pillard 12

    Target 4:

    Put Clinker quality as a PRIORITY

    Fives

  • 13Fives Pillard

    Clinker quality & Sulphur cycle

    The ROTAFLAM Version 2 with "SLOT EFFECT improves the clinker quality and impedes the Sulphur cycle formation, thanks to:

    No contact between flame and the clinker bed

    Low diameter "cigar" shaped flame in the kiln axis

    High intensity flame (DRY PROCESS), softer (WET)

    End user Main fuel Kiln (tpd) Former burner New burner Improvement

    TIANRUI RUIZHOU, China High ash coal 6000 ROTAFLAM 14 Mpa,production increase by 3,5 %

    HOLCIM, Sri Lanka Coal + sawdust 900 ROTAFLAM 30 Mpa

  • Fives Pillard 14

    Target 5:

    Address New Sustainable development requirements

  • 15Fives Pillard

    Sustainable development : a struggle against pollutants

    NEW PATENT: EP 04.290293.2 of Feb.4, 2004

    CO and NOx reduction at stack needs FIRST to limit them AT KILN INLET !

    Patented concept: Low NOx Tips, joint development between Italcementi & Fives Pillard(Grant awarded from the European Community) :

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    ORIGINAL

    1ST LOW NOX

    TIP

    2ND LOW NOX TIP

    NOx AT KILN INLET

    DIFFERENTBURNER TIPS

    First tests at ITALCEMENTI's SARCHE plant (It) (1997-2001), confirmed in ITALCEMENTI's BRONI plant (It) (2002-2004) tests led to developing special LOW NOx tips.

  • 16Fives Pillard

    Sustainable development : a struggle against pollutants

    Low NOx tips have proven sizeable benefits

    End User Kiln (tpd) Main fuel NOx at kiln inlet@ 10% O2 dry Improvements (NOx reduction, capacity)ITALCEMENTI SALERNO, Italy 1400 Petcoke 1020 Increase production from 1300 to 1400 tpd. in a narrow furnace

    ITALCEMENTI BRONI, Italy 730 Petcoke 775 NOx reduction -46% compared with previous ITC burner

    ITALCEMENTI SARCHE, Italy 800 Petcoke 1020 NOx reduction -29% compared with the Monochannel burner in narrow furnace -

    ITALCEMENTI SCAFA, Italy 950 Petcoke 1063 NOx reduction -26% compared to the previous ROTAFLAM

    ITALCEMENTI CALUSCO, Italy 4000 Petcoke 510 Good performances - fully satisfied (new plant)

    CALCIA VILLIERS, France 1200 Coal 880 Kiln more stable and use of a higher LSF meal with same NOx emission

    CCB GAURIN, Belgium 1650 Petcoke 755 NOx reduction -30% compared to the previous ROTAFLAM

    HOLCIM MERONE, Italy 2300 Petcoke 730 NOx reduction -27 % compared to the previous ROTAFLAM

    ITALCEMENTI COLLEFERO, Italy 2300 Petcoke 920 NOx reduction -17% compared to FLS and no hot spot

    ITALCEMENTI VASSILIKO, Cyprus 6000 Coal Under com.

  • 17Fives Pillard

    Prediction software for NOx emissions at kiln inlet

    Coal concentration

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    The Fives Pillard NOx ROTA software allows to separate the influencing factors of NOx emission.The use of computerized multi points measurements is mandatory.

    Influencing factors:0

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    Specific heat per m3 Material flow density

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    Burner swirl

    The 800 mg/Nm3@10%O2 target at kiln inlet is achievable !

  • Fives Pillard 18

    Target 6:

    Simplify burner use : the NOVAFLAM burner

    Improve Precalciners / Urea Ammonia injection

    Control combustion in real time

  • 19Fives Pillard

    The NOVAFLAM burner : a simplified use

    From the ROTAFLAM to the NOVAFLAM burner

    ROTAFLAM NOVAFLAMROTAFLAM Version2Burners with axial & swirl channels adjustable at site

    Tailor-made" engineered designAllows much more simple adjustmentsAddition of "slot effect"

    Main features :

    S.A.S. (single air supply) as standard

    D.A.S. (double air supply) only for special applications,for example : LOW NOx application

    burner tips engineered according to process data

    NEW PATENTSEP 06.778673.1 of June 26,2006EP 07.290663.9 of May 23, 2007FR0852836 of April 28, 2008FR2009/050593 of April 07, 2009

  • 20Fives Pillard

    The NOVAFLAM burner : Input data for engineering

    Process data (incl. kiln geometry); Dry or wet process, and L of kiln; Burner heat release without safety margin; LSF of raw material, sulphur content; Secondary air temperature, type of cooler, position of tip in kiln; List of fuels, concentration in conveying lines, % of each, volatiles, granulometry, sulphur content; Carriage: Can the burner be in the kiln axis ?

    Running data; Past experience with the kiln (difficulties, rings, other); Priority targets (Increase prod ? Improve clinker quality ? Sulphur cycle problems ? Decrease NOx ?

    Increase A.S.F. %?)

    Absolutely avoid a burner oversizing

  • 21Fives Pillard

    The NOVAFLAM burner : technical design choices

    primary air outletInfluence of increasing SWIRL

    Flame OK

    primary air outletMax velocity for 250 mb fan pressure

    Max velocity # 100 m/sUnacce

    ptable

    primary air outletInfluence of increasing SWIRL

    Flame OK Flame OK

    primary air outletMax velocity for 250 mb fan pressure

    Max velocity # 250 m/s

    SINGLE or DOUBLE primary air outlet ?

    SINGLE

    DOUBLE

    SINGLE

    DOUBLE Adopted!

    LOW SWIRL

    LOW SWIRL

    HIGH SWIRL

    HIGH SWIRL

    Unacce

    ptable

    Adopted!

    A DOUBLE primary air outlet is mandatory

  • 22Fives Pillard

    The NOVAFLAM burner : references

    ASFEnd user Main fuel Kiln (tpd) % Heat release TypeKOHAT CEMENT, Pakistan GAS / COAL DRY 6700 0 - Successfully commissioned by customer , satisfiedGHARIBWAL CEMENT, Pakistan GAS / COAL DRY 6700 0 - Successfully commissioned by customer , satisfied

    HEBEI, Kuishan, China COAL DRY 5500 0 - Very satisfied, high clinker quality & production

    YANBU, Saudi Arabia HEAVY FUEL OIL DRY 11000 0 - Not yet startedFUCHUAN, China HIGH ASH COAL / OIL DRY 5500 0 - Not yet startedCHIFENG YUANHANG, China HIGH ASH COAL / OIL DRY 2900 0 - StartedXIBEI CHANGYE, China HIGH ASH COAL / OIL DRY 4500 0 - Not yet startedLUOYANG TONGLI, China HIGH ASH COAL / OIL DRY 5500 0 - StartedXING KUANG CEMENT, China HIGH ASH COAL / OIL DRY 5500 0 - Not yet startedZAOZHUANG JINQAO, China HIGH ASH COAL / OIL DRY 6000 0 - Not yet startedDANGOTE CEMENT LINES 1 & 2, Nigeria HFO/GAS/COAL DRY 6000 0 - Not yet startedLARESTAN CEMENT, Iran HFO/GAS DRY 3300 0 - Not yet startedBAOARE CEMENT, Chad HFO DRY 800 0 - Not yet startedMCE CEMENT, Ethiopia HFO/GAS/COAL DRY 3000 0 - Not yet startedWUAN XINFENG CEMENT, China HIGH ASH COAL / OIL DRY 6000 0 - Not yet startedXUZHOU LONGHAN CEMENT, China HIGH ASH COAL / OIL DRY 5500 0 - Not yet startedFURONG JUNLIAN CEMENT, China HIGH ASH COAL / OIL DRY 5500 0 - Not yet startedQUINLIANSHAN MINE CEMENT, China HIGH ASH COAL / OIL DRY 2500 0 - Not yet startedTPI POLENE KILNS 1,2 & 3, Thailand COAL / FLUFF (RDF) / OIL DRY 10000 0 - Not yet startedEL NAHDA CEMENT CO., Egypt HFO/GAS DRY 7000 0 - Not yet startedCAMCE KANT LINES 1 TO 5, Kyrkystan HFO/GAS/COAL DRY 720 0 - Not yet startedCAMCE KANT LINES 6 & 7, Kyrkystan HFO/GAS/COAL DRY 504 0 - Not yet startedHENAN YONGAN CEMENT, Chine HIGH ASH COAL / OIL DRY 5800 0 - Not yet startedQUINLIANSHAN YONGDENG CEMENT, Chine HIGH ASH COAL / OIL DRY 5500 0 - Not yet startedZAOZHUANG WOFENG, Chine HIGH ASH COAL / OIL DRY 5800 0 - Not yet startedQUYANG JINYU CEMENT, Chine HIGH ASH COAL / OIL DRY 5800 0 - Not yet startedNANJING HOPE, Ethiopia HFO DRY 1700 0 - Not yet started

    HOLCIM LUMBRES, France PETCOKE WET 800 30 Sawdust+ Animal meal Commissioned by customer, satisfied, sawdust flow x 2HOLCIM DANNES, France PETCOKE SEMI DRY 1200 50 Sawdust+ Animal meal Very satisfied, 70 % more sawdust (5 t/hr)SHANDONG DONGHUA, China COAL DRY 5500 0 - Very satisfied, high clinker quality & productionBEIJING LIMA, China COAL DRY 5000 0 - Very satisfied, high clinker quality with low LHV coal

    GUANGZHOU, China COAL DRY 4000 20 Plastic chips Commissioning scheduled on June 2009SHANDONG QUANXING, China COAL DRY 3200 0 - Commissioning scheduled on June 2009AHLIA CEMENT, Lybia HFO/GAS DRY 3000 0 - Not yet startedCBMI AL BADIA, Syria COAL/PETCOKE DRY 5500 0 - Not yet startedVICAT KAZAKHSTAN, Kazakhstan COAL DRY 3000 0 - Not yet startedHOLCIM, OBOURG PLANT, Belgium PETCOKE WET 3000 50 Schiste / Sludge / Sawdust Commissioning scheduled on July2009

    User feedback

  • 23Fives Pillard

    The NOVAFLAM burner : references

    ; Simplicity of adjustment confirmed.

    ; Intense flame, low with low primary air pressure (< 250 mbar), confirmed.

    HOLCIM LUMBRES opinion: "Replacing the previous burner by the NOVAFLAM has allowed us to increase the % total kiln energy amount from impregnated sawdust from 11% in 2007 to 20% in 2008Furthermore, the NOVAFLAM is very simple to use

    HOLCIM DANNES opinion: "The total substitution rate has increased by 70%... The flame is strong and intense even with pressure from 160 to 180 mbar the operators highly appreciate the burner flexibility and the simplicity of the adjustments"

  • 24Fives Pillard

    The NOVAFLAM burner : a shorter Return on Investment

    RUNNING COSTS INSTALLATION COSTS

    KILN PRODUCTION EXISTING CARRIAGE

    Stability increased

    Production increased (typically 2-4%)

    A low quality coal can be used

    Recovered

    USE OF HIGH A.S.F. % EXISTING P.A. FAN

    Cancelling fuel costs Recovered

    Huge savings! Minimized!

    Payback time of 8 months for the 2 HOLCIM French plants

  • 25Fives Pillard

    The NOVAFLAM burner : a lower Carbon assessment

    CO2 emission ELECTRIC CONSUMPTION

    Concentration can be increasedElectric Consumption: less15%

    Pressure can be reducedFlow reducedElectric Consumption: less 30/40%

    Consumed electricityReduced!

    SPECIFIC CONSUMPTION SOLID FUELCONVEYING LINES

    Reduced (average 3 %)CO2

    USE of higher BIOMASS FUEL % PRIMARY AIR FAN

    CO2

    CO2Reduced!

  • Fives Pillard 26

    Now, what about

    Improving Precalciners

    Control combustion in real time

  • 27Fives Pillard

    Improving Precalciners / Urea Ammonia injection

    The Fluent studies on PRECALCINERS focused on:

    NEW PATENTSEP 06.291903.0 of Dec. 11, 2006FR 06.05355 of June 15, 2006

    NOVAFLAM and NEUTRINOX are complementary

    ; Temperature profiles and recirculation zones; Influence of (preca) burners positioning

    They allow to choose the best Urea/Ammonia injection points to meet NOx limits AT STACK

    Control valve set

    Re-circulation zones

    Levels of injection

    Temperature profile

    Special atomizer

    The NEUTRINOX SNCR system includes : A control valve set Two levels of injectors Special atomizers

    End user NOx at stackmg @10% O2, dryNOx reduction

    %Efficiency

    % Client's feedback

    ITALCEMENTI Salerno, Italy 700 73 83 3 years of operation, easy maintenance, high reliability

    ITALCEMENTI Colleferro line 5, Italy 800 72 46 2 years of operation, easy maintenance, ammonia tests pending

    ITALCEMENTI Colleferro line 6, Italy 1080 60 56 2 years of operation, easy maintenance, ammonia tests pending

    ITALCEMENTI Vibo Valentia, Italy 790 50 30 2 years of operation , modifications for 10% increase efficiency

    HOLCIM Hon Chong, VI 750 50 25 2 years of satisfactory operation

    ITALCEMENTI Vassiliko, Cyprus Target 800 Guaranteed 50 - To be commissioned Dec 2009

  • 28Fives Pillard

    SITE ASSISTANCE SERVICES

    Real-time combustion controls

    Decreasing NOx emission needs an increase of P.C concentration.It is servo-controlled by the line pressure drop.

    NEW PATENTEP 00.401340.5 of May 16,2000

    Enables to control via INTERNET:

    Fives Pillard improved a well-known probe and offers it with

    ,for SO2, NOx, CO, O2 analyzers

    : Our specialists operate worldwide.

    coal/petcoke dosing systems :STAPILDOS

    Burner Management System :ROTASAFE

    sampling probes at kiln inlet :ROTASAMPLER

    : 200 m: 8 kg/Nm3: +/- 1,5 %

    Max length of conveying lineMax coal/petcoke concentrationStability of coal/petcoke flow

    ; Flow rates of each fuel (incl. A.S.F.); Burner adjustments & combustion measurements

  • 29Fives Pillard

    Combustion in rotary kilns & precalciners: conclusions

    The NOVAFLAM burner is simple to adjust

    The NOVAFLAM burner allows: a very high % of Alternative Solid Fuels minimum electric consumption recovering the existing carriage and primary air fan

    The NOVAFLAM LOW-NOx, in association with the NEUTRINOX system, allows to meet emission limits AT STACK

    The Fives Pillard group wants to develop a SPIRIT OF PARTNERSHIP with your Group aiming at proposing the best adequate solutions on a case by case basis.

    We invite you to come and visit us in Marseilles, where all detailed questions will be answered!

  • Fives Pillard 30

    With our warm thanks!All the Fives Pillard Management