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8/14/2019 COMPARATIVE EVALUATION OF EURASIAN NATURAL CHLORIDE-SULPHATE WATERS.ppt
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COMPARATIVE EVALUATION OF
EURASIAN NATURAL CHLORIDE-
SULPHATE WATERS`
COMPOSITION BY MEANS OF
MATHEMATICAL MODEL FOR
MINERAL WATERS`CLASSIFICATION
* Kornilov, N.I., ** Surdu O., *** Kornilova, E.N.,* Domnitsky D.A. **Surdu T-V
Stavropol State Agrarian University, Stavropol, Russia
** Ovidius University, Constanta, Romania,
*** OAO "Stavropol Elektronproekt", Stavropol, Russia
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Aims of the study
toestablish a quantitative dependences
connecting composition and properties of the
regional Eurasian mineral water on the basis
of a mathematical model;
to assess the composition of some mineral
waters, brine lakes, squeezed waters,
medicinal mud/clay/sediments in Russia andRomania.
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Materials
samples of chloride-sulphate mineral waters,
mud/clay/peat, from Russia, Romania,Germany, France, Italy, Spain, Ukraine and
other countries of the Eurasian continent
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1. Methods of work
statistical methods of the linear regressionequation
analytical dependences that connect characteristicindicatorsof the mineral waters structure ( , B, )
to independent variables of ionic composition andconcentration (total salinity, ionic composition, acid-base balance, conductivity and some othercharacteristics)
characteristic indicators", calculated from experimental data,refers to those functions of the system, through which, or
through whose derivatives, can expresses in explicit form thecomposition and mass properties of water-salt systems
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1.1. Parameters for the
mathematical description of
structure of water-salt systems
- the total mineralization of water
(g/dm3).- the gram-equivalent of a salt system
of mineral water, g/eqv
Cn -concentration of salts in solution(eqv/dm3)
M
nCM
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Whereratioof equivalent anions cloride and sulphate
functionof one variable
24SO
Cl
X
X
presented in the form of the equationwhere aand bare constants corresponding to mineral water
chloride-sulfate type
b)2
4
SOX
ClX
a(
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1.2.character ist ic indicator
well-definedvalue of the salt solution and depends
on: the natureof dissolved salts, the composition
and concentrationof ions, forming a salt solution
the dilutionof the solution with a given value ofdemineralized water does not change its value
Solutions of different concentrations with similar
values of belong to the same subgroup (class)
of water. Solutions with close relation of constitute a
certain class of mineralized water
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2. Results and Discussion2.1. Standard chloride-sulfate waters of
Russia The natural mineral waters of the chloride-sulfate
type included in the GOST R are water solutions ofchloride and sulfate saltsof sodium, magnesium andcalcium, the total content of which in solution is upto 90 eqv% or more
Processing array values in total mineralization andion composition was carried out on mean values ofthe variables listed in GOST R, subject to the
material balance of the anions Cl-, SO42-, HCO3-andcationsCa 2+, Mg 2+, Na+and K+, forming a saltysolution of mineral waters.
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M
MMineralization and ions composition of the reference mineral
chloride-sulphate waters of Russia
Title of waterMineralization ,
(g/dl)
Ion composition of water, mg-eqv/dl
HCO3- SO4
2- CI- Ca2+ Mg2+ Na+ + K+
1 Kashinskaja 2,825 0,76 35,43 7,13 20 10,28 13,04
2 Uglichskaja 4,094 1,56 45,31 15,49 14,59 10,79 36,98
3 Bujskaja 11,945 0,81 133,26 45,74 20 18,51 141,3
4 Igevskaja 4,350 3,28 46,88 16,90 20 18,57 28,78
5 Irkutskaja 2,050 4,67 17,71 9,30 13 8,23 9,78
6 Lipezkij bjuvet 3,301 4,32 27,21 17,81 3,75 2,06 43,48
7 Anapskaja 3,067 7,79 21,88 15,49 1,21 3,98 39,97
8 Lisogorskaja 18,165 7,7 159,9 118,9 65,8 195,7
9 Don 2,850 5,74 21,35 16,90 8,25 9,98 25,67
10 Nigne-Ivkinskaja 7,598 1,46 59,37 60,83 25 20,27 76,09
11 Ergeninskaja 5,700 6,56 40,62 42,25 27,5 12,34 50
12 Novo-Igevskaja 15,420 0,82 99,38 144,93 30 8,64 206,52
13 Kaspij 6,416 13,75 27,67 56,65 0,42 1,03 95,65
14 Solvichegodskaja 8,850 0,82 43,75 94,37 2,5 8,23 123,9
15 Hilovskaja 3,535 2,36 17,21 39,84 18,75 14,40 26,09
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Quant i ty o f general min eral izat ion , ratio and
characteristic indicators of composition ,Band of the
reference mineral chloride-sulphate waters of Russia
Title of water(g/dl)
CI
-/ XSO4
2-(g/eqv)
(g2 / eqv2)
(g2 / eqv2)
1 Kashinskaja 2,825 0,201 65,21 2126 10580
2 Uglichskaja 4,094 0,342 65,65 2155 6320
3 Bujskaja 11,945 0,345 66,43 2207 6396
4 Igevskaja 4,350 0,360 64,92 2107 5854
5 Irkutskaja 2,050 0,525 65,39 2138 4072
6 Lipezkij bjuvet 3,301 0,654 66,97 2243 3429
7 Anapskaja 3,067 0,708 67,87 2306 3257
8 Lisogorskaja 18,165 0,744 63,40 2010 2701
9 Don 2,850 0,791 64,78 2099 2653
10 Nigne-Ivkinskaja 7,598 1,024 62,45 1950 1904
11 Ergeninskaja 5,700 1,040 63,61 2023 1945
12 Novo-Igevskaja 15,420 1,458 62,91 1979 1357
13 Kaspij 6,416 2,047 65,42 2140 1045
14 Solvichegodskaja 8,850 2,157 61,54 1894 878
15 Hilovskaja 3,535 2,315 59,50 1770 765
24SO
Cl
XX
M
M
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2. Results and Discussion2.1. Standard chloride-sulfate waters of
Russia Mathematical treatment of the values of the characteristic
parameter , allowed obtaining an analytical expression
for the function lnin the form of a linear regression
equation:
ln )]XX
[ln(f24SO
Cl
=
24SO
ClX
X
7,6302 1,0511
r = 0,9974 where: r - correlation coefficient.
ln
=
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2. Results and Discussion
2.1. Standard chloride-sulfate waters of Russia.Graphic dependence of function ln = f [ln(CI- / XSO4 2- )]for standard chloride-sulfate mineral water of Russia
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2. Results and Discussion2.2. Eurasian regional chloride-sulfate water
Title of water (g/dl)
CI
-
/ XSO4
2-(g/eqv)
(g2 / eqv2)
1 2 3 4 5 6
1 Acqua de Cavabaa (Spain) 86,550 0,061 71,20 41550
2 Batalinskay (Ru) 20,949 0,131 65,82 16540
3 Rubeg (Ru) 7,982 0,197 65,28 10820
4 Lake B. Solenoje-mud (Ru) 243,68 0,201 65,13 10550
5 Lake Sengileevskoje (Ru) 0,234 0,204 65,21 11570
6Kissinger Bitterwasser Heilwasser
(G)34,890 0,234 60,32 7770
7 Staroeletskaja (Ru) 4,110 0,256 68,94 9280
8Slanic Moldova 8-bis
(Romania)0,193 0,263 65,87 8250
9 Nickolina Balka (Ru) 10,052 0,356 61,54 5719
10 Lake M. Solenoje (Ru) 145,65 0,426 63,26 4697
11 Nezlobinskaja (Ru) 2,980 0,454 73,93 6071
12 Krakowianka (Pol) 2,714 0,460 65,71 4693
13 Feodosiiskaja (Ukr) 3,957 0,540 59,7 4067
14Lake B. Tambykan, (mud mortars)
(Ru)17,724 0,543 62,52 3643
15 Lake B. Tambykan (Ru) 22,982 0,547 62,90 3573
M
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2. Results and Discussion2.2. Eurasian regional chloride-sulfate water
Title of water(g/dl)
CI
-/ XSO4
2-(g/eqv)
(g2 / eqv2)
16 Dax (France) 0,987 0,575 67,13 3940
17 Slanic-Moldova, 5 (Rom) 0,658 3300
18 Lake Techirghiol (mud mortars), (Rom) 75,346 2,107 60,64 873
19 Kaspij Sea (Ru) 10,547 2,300 59,44 768
20 Antonius Heilwasser (G) 2,136 2,331 66,08 937
21 Press water of dark-grey clay, sample 10 (Ru) 15,499 4,091 62,40 476
22 Lake Techirghiol (Rom) 73,238 4,320 58,90 402
23 Kujalnik 6 (Ukr) 3,197 5,348 62,67 367
24 Maxbrunner Heilwasser (Ger) 6,926 5,889 66,15 372
25 Black Sea (Ru) 16,031 6,572 58,82 263
26 Witjaevskij Liman (Ru) 70,579 8,442 57,79 198
27 Thermal Baths Scrajo (Italy) 14,159 8,877 61,29 212
28 Press water of dark-grey clay, sample .11 (Ru) 17,382 9,364 59,53 189
29 World`s Ocean 35,080 9,745 58,01 173
30 Lake Solenoe (Ru) 79,988 12,657 57,47 131
31 Lake Golybitskoe (Ru) 26,250 23,528 58,83 74
M
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-4 -3 -2 -1 0 1 2 3 4
ln (XCI-/ XSO2-4)
4
5
6
7
8
9
10
11
ln
Lake (mud mortars)B. TambykanLakeB.Tambykan
Aqua de cavabana
Batalinskay
Lake B. SolenojeLake Sengileevskoje
Kissinger Bitterwasser Heilwasser
StaroeletskajaSlanic-Moldova, N8 bis
Nickolina BalkaLake M.Solenoje
Nezlobinskaja
Krakowianka
Slanic-Moldova, N5
Lake Golubitskoe
Lake Solenoe
Lake Techirhiol, mud mortars
Kaspij Sea
Antonius Heilwasser
World's Ocean
Lake TechirghiolKujalnik N6
Maxbrunner Heilwasser
Black Sea
Witjaevskij Liman
Thermal Baths ScrajoPress water of dark-gray clay number 11.
Press water of dark-grey clay number 10
FeodosiiskajaDax
2. Results and Discussion
2.2. Eurasian regional chloride-sulfate water
Graphic dependence of the function ln = f [ln(CI-/ XSO42-)]
for the Eurasian regional mineral waters
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2. Results and Discussion2.3. Comparative estimate of the Eurasian regional
and standard water Russia chloride-sulphate type
The coefficients A, Dand r for the Eurasian regional
and standard mineral waters Russia chloride-sulfate type
Mineral
waters
Coefficients Correlation coefficient
r D
The reference waters of
Russia
2059 1,0511 0,9974
The Eurasianregionalwaters
2025 1,0549 0,9987
Association of the
reference watersof
Russia and Eurasia
regional waters
2040 1,0572 0,9986
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2. Results and Discussion2.3. Comparative estimate of the Eurasian regional
and standard water Russia chloride-sulfate type
Statistical analysis of the data showed that in allcases r = 0,997 - 0,999, and the error of calculationsdoes not exceed the stdv 5% (level of confidenceinterval).
Analysis of numerical datafor characteristic index ,showed that natural mineral waters of differentsources of the Eurasian continent, irrespective of theirgeographical location, form a class of waters with
similar ionic composition, which shows the unity of thegenesis and metamorphism of hydro mineralresources (mineral waters and mud).
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Systematic of Eurasian Mineral chloride-
sulphate waters on the value of the
characteristic indicator
and the ratio
Group
of mineral
waters
Index
subgroup
(classes)
Title of water,
ordinal number
(g/dl)
(g2
/ eqv2
)1 2 3 4 5 6 7
I Sulphate
IAcqua de Cavabaa
(Spain) (1)86,550 0,061 41550
BI Batalinskay (Ru) (2) 20,949 0,131 16540
CI
Rubeg (Ru)( 3) 7,982 0,197 10820
Lake B. Solenoje
(Ru)(4) 243,68 0,201 10550
Kashinskaja (Ru) (5) 2,825 0,201 10580
Lake Sengileevskoje
(Ru)(6)0,234 0,204 11570
M
2
4SO
Cl
X
X
24SO
Cl
XX
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Group
of
mineral
waters
Index
subgroup
(classes)
Title of water,
ordinal number
(g/dl)
(g2 / eqv2)
IIChloride
-sulfate
AII
Kissinger Bitterwasser Heilwasser (G) (7) 34,890 0,234 7770
Staroeletskaja (Ru) (8) 4,110 0,256 9280
Slanic Moldova 8 bis (Rom) (9) 0,193 0,263 8250
BII
Ugeichskaja (Ru) (10) 4,094 0,342 6320
Bujskaja (Ru) (11) 11,945 0,345 6396
Nickolina Balka (Ru) (12) 10,052 0,356 5719
Igevskaja (Ru) (13) 4,350 0,360 5854
CII
Lake M. Solenoje (Ru) (14) 145,65 0,426 4697
Nezlobinskaja (Ru) (15) 2,980 0,454 6071
Krakowianka (Pol) (16) 2,714 0,460 4693
DII
Irkutskaja (Ru) (17) 2,050 0,525 4072
Feodosiiskaja (Ukr) (18) 3,957 0,540 4067
Lake (mud mortans) B. Tambykan (Ru) (19) 17,724 0,543 3643
Lake B. Tambykan (Ru) (20) 22,982 0,547 3573
Dax (France) (21) 0,987 0,575 3940
EIILipezkij bjuvet (Ru) (22) 3,301 0,654 3429
Slanic-Moldova, 5 (Rom) (23) 0,658 3300
FII
Anapskaja (Ru) (24) 3,067 0,708 3257
Lisogorskaja (Ru) (25) 18,165 0,744 2701
Don (Ru) (26) 2,850 0,791 2653
24SO
Cl
X
XM
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Group
of mineral
waters
Index subgroup
(classes)
Title of water,
ordinal number
(g/dl)
(g2 / eqv2)
III Sulfate-
chloride
AIII
Nigne-Ivkinskaja
(Ru) (27)7,599 1,024 1904
Ergeninskaja
(Ru) (28)5,700 1,040 1945
BIII Novo-Igevskaja(Ru) (29) 15,420 1,458 1357
CIII
Kaspij (Ru) (30) 6,416 2,047 1045
(mud mortans),
(Rom) (31)75,346 2,107 873
DIIISolvichegodskaja
(Ru) (32)8,850 2,157 878
EIII
(Ru) (33) 10,547 2,300 768
Hilovskaja (Ru(34) 3,535 2,315 765
Antonius Heilwasser
(Ger) (35) 2,136 2,331 937
M
2
4SO
Cl
X
X
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Group
of mineral
waters
Index
subgroup
(classes)
Title of water,
ordinal number
Mineralization,
(g/dl)
Ratio Characteristic
indicator
,
g2 / eqv2
IV Chloride
AIV
Press water of dark-gray clay,
sample 10 (Ru) (36) 15,499 4,091 476
(Rom) (37)73,238 4,320 402
BIV
Kujalnik 6
(Ukr) (38) 3,197 5,348 367
Maxbrunner Heilwasser (Ger)
(39) 6,926 5,889 372
(Ru) (40) 16,031 6,572 263
DIV
Witjaevskij Liman (Ru) (41)70,579 8,442 198
Thermal Baths Scrajo (42)14,159 8,877 212
Press water of dark-gray clay,
sample 11 (Ru)( 43) 17,382 9,364 189
World`s Ocean ( 44)35,080 9,745 173
EIV (Ru)( 45) 79,988 12,657 131
FIV (Ru)(46) 26,250 23,528 74
M
24SO
Cl
X
X
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3. Conclusion
a) Characteristic parameters , B and with a high
degree of reliabilityallow the identification of watersof
different ionic composition and mineralization,
regardless of geographical coordinatesof the locationof their sources;
b) Characteristic parameters , B and (calculated
from the experimental data of chemical analysis of
water) allow to assess water qualityand can be usedto organize national and pan-European monitoring
systems of natural waters;
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3. Conclusion
)Analytical dependence of the function
ln
= 7,6209
1,0572
allows the quantitative identificationof the
various regional water on their correspondinganalogues of standard mineral waters and
their subsequent certification and
standardization.
2
4SO
Cl
X
X
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