ISSN 0300-9246 JCDTBi(4) 591-856(1983)

JOURNAL OF THE CHEMICAL SOCIETY

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Dalton Transactions Inorganic Chemistry including bioinorganic, organometa I Iic, and solid-state chemistry, and chemically significant spectroscopy

CONTENTS

Thermodynamics of extraction equilibria. Part 6. A further study of the method for determination of equilibrium constants of extraction processes Djordje M. Petkovik

Triorganotin and triorganolead derivatives of N-acetylamino-acids Gerd Rae, Friedo Huber, Hans Preut, Arturo Silvestri, and Renato Barbieri

Nuclear magnetic resonance studies of transition-metal complexes of ethylenediamine-NNN’N’-tetramethylphosphonate in aqueous solution John Oakes and Edward G. Smith

Crown ethers as second-sphere ligands. The interactions of transition-metal ammines with 18-crown-6 and dibenzo-18- crown-6 Howard M. Colquhoun, David F. Lewis, J. Fraser Stoddart, and David J. Williams

Matrix isolation studies of the bonding of acetyl groups in the co-ordinatively unsaturated species acetyltetracar- bonylmanganese and acetylmonocarbonyI(q-cyclopentadieny1)iron Ramli B. Hitam, Ramaier Narayanaswamy, and Antony J. Rest

The preparation and crystal structure of the 3 : 1 adduct of antimony trifluoride and antimony pentafluoride containing the (Sb3FB+)a, cation W. A. Shantha Nandana, Jack Passmore, D. C. Neil Swindells, Peter Taylor, Peter S. White, and John E. Vekris

Aspects of the inorganic chemistry of rubber vulcanisation. Part 4. Dialkyl- and diaryl-dithiophosphate and -dithio- phosphinate complexes of zinc : phosphorus-31 nuclear magnetic resonance spectral studies and structures of “Me4]- [Zn(SzP(OC6H4Me-p)2}3] and [NEt4][Zn(S2PPh2)3] Jon A. McCleverty, Rick S. 2. Kowalski, Neil A. Bailey, Robert Mulvaney, and Dona1 A. O’Cleirigh

The ultra-violet photoelectron spectra of gas-phase and condensed bismuth halides and antimony trifluoride Igor Novak and Anthony W. Potts

Spectroscopic studies on Cz hydrocarbon fragments. Part 1. Vibrational studies of cluster-bound vinyl and vinylidene ligands John Evans and Gregory S. McNulty

An extended X-ray absorption fine structure study of penta-amminecopper(i1) bis(tetrafluorob0rate) : evidence for five equal bond lengths Lucilla Alagna, Tommaso Prosperi, Anthony A. G. Todinson, and Gilbert0 Vlaic

Crevice co-ordination: binding of a ligand molecule in a molecular crevice. Crystal and molecular structures of p-oxo- p-pyridine-p-sulphido-bis[(OO’-di-isopropyl phosphorodithioato)oxomolybdenum(v)] and poxo-p-pyridazine-p-sul- phido-bis[(OO’-di-isopropyl phosphorodithioato)oxomolybdenum(v)] Michael G. B. Drew, Pablo J. Baricelli, Philip C. H. Mitchell, and Alan R. Read

Crystal and molecular structure and magnetic properties of a tetrameric copper(iI) complex with 3-hydroxy-Q-[4’-(3’’,4”- dichlorophenyl)-4’-hydroxy-2’-azabut- 1 ’-en-1 ’-yl]-5-hydroxymethyl-2-methylpyridine (HzL2), [(CUL~)~]-~CH,OH Leonhard Walz, Helmut Paulus, Wolfgang Haase, Harald Langhof, and F’rancoise Nepveu

Alkenyl derivatives of the metals. Oxidative addition to intermediate tin(rr) alkenyls; isolation, and crystal and mole- cular structure of n-butyltris(triphenyletheny1)t in(w) Christine J. Cardin, David J. Cardin, Reginald J. Norton, Hans E. Parge, and Kenneth W. Muir

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CONTENTS

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72 1

729

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737

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779

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Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromium Christine J. Cardin, David J. Cardin, John M. Kelly, Reginald J. Norton, Abhijit Roy, Brian J. Hathaway, and Trevor J. King

Chirality recognition of a clay surface modified by an optically active metal chelate Akihiko Yamagishi

A fluorine-19 nuclear magnetic resonance study of the strong hydrogen bond between aliphatic diols or acids and alkali metal fluorides Jack M. Miller, Ravendran K. Kanippayoor, and James H. Clark

Mechanisms of reduction of trans-cyclohexane-l,2-diamine-NN~'N'-tetra-acetatomanganate(1n) by hydrazine, hydroxylamine, and substituted benzene-l,2-diols Patrizia Arselli and Edoardo Mentasti

Preparation and crystal structure of diaquabis(l,2-naphthoquinone-2-oximato-ON)dioxouranium(v1)--trichloro- methane (1 /2) and aquabis( 1,2-naphthoquinone-l-oximato-ON)(triphenylphosphine oxide)dioxouranium(vI) Rodolfo Graziani, Umberto Casellato, Pietro A. Vigato, Sergio Tamburini, and Maurizio Vidali

Spin density and structure of aquabis(2,2'-bipyridine)di-~-hydroxo-sulphatodicopper(11) tetrahydrate at 4.2 K Brian N. Figgis, Ronald Mason, Andrew R. P. Smith, Joseph N. Varghese, and Geoffrey A. Williams

Preparation, crystal structure, and spectroscopic studies of [NPrn412[(PhS)CuS2MoS2] and [NPrn4I2[(PhS)CuS2MoS2Cu- (SPh)], containing benzenethiolatocopper(1)-tetrathiomolybdate(v1) complex anions Stephen R. Acott, C. David Gamer, John R. Nicholson, and William Clegg

Investigation into aroylhydrazones as chelating agents. Part 3. Synthesis and spectroscopic characterization of com- plexes of Mn", Co", Ni", Cu", and Zn" with 2,6-diacetylpyridine bis(benzoy1hydrazone) and X-ray structure of aquachloro[2,6-diacetylpyridine bis(benzoylhydrazone)]manganese(i~) chloride Carlo Lorenzini, Corrado Pelizzi, Giancarlo Pelizzi, and Giovanni Predieri

The fluxionality of (2)-6,6,6-tripheny1-6-stannahexa-1,3-diene : evidence for symmetry-allowed suprafacial [ 1,5]-shifts in an organometallic compound Michael J. Hails, Brian E. Mann, and Catriona M. Spencer

Thermodynamics of the complex formation between thorium(1v) and some polydentate ligands in aqueous solution Plinio Di Bernado, Albert0 Cassol, Giuliana Tomat, Arturo Bismondo, and Luciano Magon

Electron spin resonance spectra of reduced [Fe2S2(SC6H4Y-p),I2- (Y = C1, H, or Me) complexes and their selenium- ligated homologues Peter Beardwood and John F. Gibson

Kinetics and mechanism of hydrogen peroxide oxidation by silver(ii1) in aqueous alkaline media Edward T. Borish and Louis J. Kirschenbaum

Photoelectron spectra of the phospha-alkynes: 3,3-dimethyl-l-phosphabutyne BUT-P and phenylphosphaethyne, PhCIP James C. T. R. Burckett-St. Laurent, Michael A. King, Harold W. Kroto, John F. Nixon, and Roger J. Suffolk

Electron, infrared, and resonance-Raman spectra of linear-chain mixed-valence complexes of platinum with 1,2- diaminopropane Robin J. H. Clark and Mohamedally Kurmoo

Solid-state properties of materials of the type Cs4MX6 (where M = Sn or Pb and X = C1 or Br) Robert H. Andrews, Stephen J. Clark, John D. Donaldson, (in part) John C. Dewan, and Jack Silver

Precipitation within unilamellar vesicles. Part 2. Membrane control of ion transport Stephen Mann, Matthew J. Kime, R. George Ratcliffe, and Robert J. P. Williams

The cis effect of phosphines and phosphites in the reactions of chloro( 1,2-diaminoethane)phosphine- and chloro( 1,2- diamin0ethane)trimethyl phosphite-platinum(i1) cations with nucleophiles Giuliano Annibale, Luciano Canovese, Lucio Cattalini, Giampaolo Marangoni, Gianni Michelon, and Martin L. Tobe

Iridium nitrosyl complexes of 9,lO-phenanthrenequinone di-imine. Crystal structure of [Ir(NO){ HNCI4H8N(PPh3))- (PPh,)][PF,], a species containing a phosphazene-imido-ligand Paolo Dapporto, Gianfranco Denti, Giuliano Dolcetti, and Mauro Ghedini

Synthesis of 1-oxidopyridinium-2-thiolato- and pyridine-2-thiolato-complexes of nickel, palladium, and platinum Jack L. Davidson, Peter N. Preston, and Maria V. Russo

Formation of new halogeno mixed-metal clusters by oxidative addition of triphenylphosphinegold(1) halides to [ R U ~ C ( C O ) ~ ~ ] : crystal and molecular structures of [RU~C(CO),~{~-AU(PP~,)}C~] and [RU~C(CO),~{~AU(PP~, ) ) - (p-Br)]

Pentakis(methoxycarbony1)cyclopentadiene chemistry. Part 4. Some silver(1) complexes : crystal and molecular struc- tures of [(Ag[Cs(C02Me)s](OH2)>,].1 .5nH20, [{Ag[Cs(C0,Me)s](PPh3)}2], and [Ag{Cs(C02Me)s}(PPh3)2] Michael I. Bruce, Michael L. Williams, Brian W. Skelton, and Allan H. White

Pentakis(methoxycarbony1)cyclopentadiene chemistry. Part 5. Preparation and crystal and molecular structures of [Au{CS(C02Me),}(PPh3)] and [AU(PP~~)~][C~(CO~M~)~]-M~OH Michael I. Bruce, Jennifer K. Walton, Brian W. Skelton, and Allan H. White

Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, JosC Puga, and Kenton H. Whitmire

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CONTENTS

815

823

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835

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84 I

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Pentakis(methoxycarbony1)cyclopentadiene chemistry. Part 6. Some first-row transition-metal derivatives : crystal and molecular structures of [Fe(CS(C02Me)5}2(MeOH)2], [CO{C~(CO~M~)~}~(OH~)~] , and [CU{C~(CO~M~)~}~(M~OH)~] Michael I. Bruce, Jennifer K. Walton, Michael L. Williams, Jennifer M. Patrick, Brian W. Skelton, and Allan H. White

X-Ray crystal and molecular structure of cis(”’), truns(OO‘)-bis(2-aminoethanolato)-cis-dichloroplatinum(~v) dihydrate. The relationship of anti-tumour activity to ring closure Reiko Kuroda, Stephen Neidle, Ismail M. Ismail, and Peter J. Sadler

Reactions of acetylenes with noble-metal carbonyl halides. Part 6. Carbonyl insertion to give cyclic organo-carbene

complexes of platinum(I1) : synthesis and X-ray structure of cis-[Pt-kC(CO2Et)=C(l?h)C(CO2Et)=C(Ph)O}(PPh3)CI2] Franco Canziani, Franco Galimberti, Luigi Garlaschelli, Maria Carlotta Malatesta, Albert0 Albinati, and Fabio Ganazzoli

The molecular structure of germyl monothioacetate in the gas phase, determined by electron diffraction E. A. V’ Ebsworth, Christopher M. Huntley, and David W. H. Rankin

Notes

Novel synthesis of tris(acetylacetonato)iron(in) Mihir K. Chaudhuri and Soumitra K. Ghosh

Crystal and molecular structure of a new eight-membered tetraphospha-macrocycle, (-PCPh=CMeCMe=d-), Jean Fischer, Andre Mitschler, Francois Mathey, and Francois Mercier

Structural characterization of a binuclear tin adduct : p-[ 1,2-bis(diphenylarsoryl)ethane-O : 0’1-bis(chlorotriphenylt in) Corrado Pelizzi and Giancarlo Pelizzi

Matrix isolation studies on alkali metal arsenates : the characterisation of molecular CsAsO, J. Steven Ogden, Timothy J. Sibley, and Stephen J. Williams

Preparation and X-ray crystal structure of [(OC)3Mo(P2[MeNC(0)NMe]2]3Mo(CO)3] Herbert W. Roesky, Djamm- schid Amirzadeh-Asl, William Clegg, Mathias Noltemeyer, and George M. Sheldrick

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AUTHOR INDEX

Acott, S. R., 713 Alagna, L., 645 Albinati, A., 827 Amirzadeh-Asl, D., 855 Andrews, R. H., 767 Annibale, G., 775 Arselli, P., 689 Bailey, N. A., 627 Barbieri, R., 595 Baricelli, P. J., 649 Beardwood, P., 737 Bismondo, A., 733 Borish, E. T., 749 Bruce, M. I., 799, 809, 815 Burckett -St. Laurent,

J. C. T. R., 755 Canovese, L., 775 Canziani, F., 827 Cardin, C. J., 665, 671 Cardin, D. J., 665, 671 Casellato, U., 697 Cassol, A., 733 Cattalini, L., 775 Chaudhuri, M. K., 839 Clark, J. H., 683 Clark, R. J. H., 761 Clark, S. J., 767 Clegg, W., 713, 855 Colquhoun, H. M., 607 Dapporto, P., 779 Davidson, J. L., 783 Denti, G., 779 Dewan, J. C., 767 Di Bernado, P., 733 Dolcetti, G., 779 Donaldson, J. D., 767 Drew, M. G. B., 649 Ebsworth, E. A. V., 835 Evans, J., 639

Figgis, B. N., 703 Fischer, J., 841 Galimberti, F., 827 Ganazzoli, F., 827 Garlaschelli, L., 827 Garner, C. D., 713 Ghedini, M., 779 Ghosh, S. K., 839 Gibson, J. F., 737 Graziani, R., 697 Haase, W., 657 Hails, M. J., 729 Hathaway, B. J., 671 Hitam, R. B., 615 Huber, F., 595 Huntley, C. M., 835 Ismail, I. M., 823 Johnson, B. F. G., 787 Kanippayoor, R. K., 683 Kelly, J. M., 671 Kime, M. J., 771 King, M. A., 755 King, T. J., 671 Kirschenbaum, L. J., 749 Kowalski, R. S. Z., 627 Kroto, H. W., 755 Kurmoo, M., 761 Kuroda, R., 823 Langhof, H., 657 Lewis, D. F., 607 Lewis, J., 787 Lorenzini, C., 721 Magon, L., 733 Malatesta, M. C., 827 Mann, B. E., 729 Mann, S., 771 Marangoni, G., 775 Mason, R., 703 Mathey, F., 841

McCleverty, J. A., 627 McNulty, G. S., 639 Mentasti, E., 689 Mercier, F., 841 Michelon, G., 775 Miller, J. M., 683 Mitchell, P. C. H., 649 Mitschler, A., 841 Muir, K. W., 665 Mulvaney, R., 627 Nandana, W. A. S., 619 Narayanaswamy, R., 615 Neidle, S., 823 Nepveu, F., 657 Nicholls, J. N., 787 Nicholson, J. R., 713 Nixon, J. F., 755 Noltemeyer, M., 855 Norton, R. J., 665, 671 Novak, I., 635 Oakes, J., 601 O’Cleirigh, D. A., 627 Ogden, J. S., 851 Parge, H. E., 665 Passmore, J., 619 Patrick, J. M., 815 Paulus, H., 657 Pelizzi, C., 721, 847 Pelizzi, G., 721, 847 PetkoviC, D. M., 591 Potts, A. W., 635 Predieri, G., 721 Preston, P. N., 783 Preut, H., 595 Prosperi, T., 645 Puga, J., 787 Rankin, D. W. H., 835 Ratcliffe, R. G., 771 Read, A. R., 649

Rest, A. J., 615 Roesky, H. W., 855 Roge, G., 595 Roy, A., 671 Russo, M. V., 783 Sadler, P. J., 823 Sheldrick, G. M., 855 Sibley, T. J., 851 Silver, J., 767 Silvestri, A., 595 Skelton, B. W., 799, 809, 815 Smith, A. R. P., 703 Smith, E. G., 601 Spencer, C. M., 729 Stoddart, J. F., 607 Suffolk, R. J., 755 Swindells, D. C. N., 619 Tamburini, S., 697 Taylor, P., 619 Tobe, M., 775 Tomat, G., 733 Tomlinson, A. A. G., 645 Varghese, J. N., 703 Vekris, J. E., 619 Vidali, M., 697 Vigato, P. A., 697 Vlaic, G., 645 Walton, J. K., 809, 815 Walz, L., 657 White, A. H., 799, 8W, 815 White, P. S., 619 Whitmire, K. H., 787 Williams, D. J., 607 Williams, G. A., 703 Williams, M. L., 799, 815 Williams, R. J. P., 771 Williams, S. J., 851 Yamagishi, A., 679

NOTE: An asterisk in the heading of each paper indicates the author who is to receive any correspondence.

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