Corr Shield Nt 4292

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SAFETY DATA SHEET Version: 6.0

Effective date: 12/03/2012

Previous Date: 23/12/2009

CORRSHIELD NT4292Section 1: Identification of the substance/mixture and of the company/undertaking

Product identifier CORRSHIELD NT4292

Version number 6.0

Revision date 12/03/2012

Supersedes date 23/12/2009

Relevant identified uses of the substance or mixture and uses advised against

Identified uses Corrosion inhibitor

Uses advised against None known.

GE Water & Process Technologies BVBA

Toekomstlaan 54

Industriepark Wolfstee

2200 HERENTALS

tel : +32 14 / 25 91 11

fax : +32 14 / 25 91 12

e-mail : [email protected]

Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa, Israel (Europe and Englishlanguage speaking countries):+44(0)1235 239670

Middle East & Africa (speaking Arabic):+44(0)1235 239671

Official advisory body :

ANTIGIFCENTRUM

Bruynstraat 1

B-1120 BRUSSEL

+ 32 70 245 245

Details of the supplier of the safety data sheet

Section 2: Hazards identification

Classification of the substance or mixture

Classification according to Directive 67/548/EEC or 1999/45/EC as amended

Classification O;R8, T;R25, N;R50

Hazard summary

Physical hazards Contact with combustible material may cause fire.

Health hazards Toxic if swallowed.

Environmental hazards Very toxic to aquatic organisms.

Label elementsLabel according to Directive 67/548/EEC or 1999/45/EC as amended

Contains: Sodium nitrite

Material name: CORRSHIELD NT4292 Page: 1 / 9






CORRSHIELD NT4292

Toxic Oxidising Dangerous for theenvironment

R-phrases R25 Toxic if swallowed.R8 Contact with combustible material may cause fire.R50 Very toxic to aquatic organisms.

S-phrases S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where

possible).S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

Supplemental label information Not applicable.

Other hazards Not assigned.

Section 3: Composition/information on ingredients

Mixtures

Chemical description Sodium nitrite, aqueous solution

Chemical name NotesINDEX No.REACH Registration No.CAS-No. / EC No.%

Classification: DSD: O;R8, T;R25, N;R50

Ox. Sol. 3;H272, Acute Tox. 3;H301, Aquatic Acute 1;H400CLP:

007-010-00-401-2119471836-277632-00-0

231-555-9

>= 25Sodium nitrite

The classification of the above substance(s) is given, including the symbol letters and R phrases which are assigned in accordance with theirphysicochemical, health and environmental hazards. Please refer to section 16 (Relevant R phrases, used in sections 2 and 3 of this SDS),where the full text of each relevant R phrase is listed.

Section 4: First aid measures

Description of first aid measures

Inhalation Remove to fresh air.

Skin contact Wash with water.

Eye contact Flush immediately with plenty of running water.

Ingestion First rinse mouth with water.Immediately give 1-2 glasses of water, if victim is fully conscious.Do NOT induce vomiting!Seek medical attention.

Most important symptoms and

effects, both acute and delayedNot available.

Indication of any immediate

medical attention and special

treatment needed

Not available.

Section 5: Firefighting measures

Extinguishing media

Suitable extinguishing media Flood with water.Use of CO2 or foam may not be effective.

Unsuitable extinguishing

mediaNot available.







CORRSHIELD NT4292Special hazards arising from the

substance or mixtureOxides of nitrogen evolved in fire.

Advice for firefighters

Special protective equipment

for firefightersSelf contained breathing apparatus. (CEN : EN 137)Protective clothing (CEN : EN 469)Protective gloves (CEN : EN 659)Helmet (CEN : EN 443)

Special firefighting

proceduresUse standard firefighting procedures and consider the hazards of other involved materials.Prevent spillage and fire-fighting water from entering in public sewers or the immediate environment.

Section 6: Accidental release measures

Personal precautions, protective equipment and emergency proceduresFor non-emergency

personnelWear protective clothing, gloves and safety goggles.

For emergency responders Use personal protection recommended in Section 8 of the MSDS.

Environmental precautions Prevent from entering sewers or the immediate environment.Do not empty into drains, dispose of this material and its container to hazardous or special wastecollection point.

Methods and material for

containment and cleaning upAbsorb onto inert material and dispose of according to Hazardous Waste Regulations.

Reference to other sections Please refer also to section no. 8 'Exposure controls' for further information.

Section 7: Handling and storage

Precautions for safe handling Contains an oxidiser.Avoid all contact with reducing agents, oils, greases, organics and acids.

Conditions for safe storage,

including any incompatibilitiesKeep away from oxidisable and combustible materials.Store containers closed when not in use.

Specific end use(s) Only for professional and industrial users

Shelf life 720 days

Section 8: Exposure controls/personal protection

Control parameters

Occupational exposure limits No exposure limits noted for the ingredient(s).

Biological limit values No biological exposure limits noted for the ingredient(s).

Recommended monitoringprocedures

Not available.

Exposure controls

Appropriate engineering controls Ensure good ventilation.

Individual protection measures, such as personal protective equipment

Eye/face protection Splash proof chemical goggles.CEN : EN 166

Skin protection

- Hand protection Neoprene gloves (Protection against unintentional short-term contact)CEN : EN 374-1/2/3; EN 420

- Other Protective clothing.CEN : EN 340; EN 369; EN 465

Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2CEN : EN 140; EN 143; EN 149

Thermal hazards Not available.







CORRSHIELD NT4292Environmental exposure controls Prevent from entering in public sewers or the immediate environment.Do not empty into drains, dispose of this material and its container to hazardous or special wastecollection point.

Section 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance

Colour Yellow

Physical state Liquid

Odour Mild

Odour threshold Not available.pH (concentrated product) 8,4

Melting point/freezing point < -20 °C

Boiling point, initial boiling point,

and boiling range

104 °C

Flash point > 100 °C Pensky Martens (CC)

Evaporation rate No information available.

Flammability (solid, gas) Not available.

Flammability limit - lower (%) Not available.

Flammability limit - upper (%) Not available.

Vapour pressure 18 Approximate (mmHg) at 21°C

Vapour density < 1 (Air = 1)

Relative density 1,29

Solubility (water) Completely soluble

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not applicable.

Decomposition temperature Not available.

Viscosity No information available.

Explosive properties Not applicable.

Oxidizing properties Not applicable.

Other data

Shelf life 720 days

Other information No relevant additional information available.

Section 10: Stability and reactivity

Reactivity Not available.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous reactions Not applicable.

Conditions to avoid No special requirement.

Incompatible materials Avoid contact with strong reducing agents.Avoid contact with combustible materials.

Do not mix with nitrosating agents (forms nitrosamines).Avoid contact with strong acids.

Hazardous decomposition

productsOxides of nitrogen evolved in fire.







CORRSHIELD NT4292Section 11: Toxicological information

Information on toxicological effects

Product Test results

CORRSHIELD NT4292 (Mixture) Dermal LD50 rabbit: > 2000 mg/kg (estimated value)

Oral LD50 rat: 213 mg/kg (estimated value)

Components Test results

Sodium nitrite (7632-00-0) Acute Inhalation LC50 Rat: 5,5 mg/l 4 Hours

Acute Oral LD50 Mouse: 175 mg/kg

Acute Oral LD50 Rabbit: 186 mg/kg

Acute Oral LD50 Rat: 85 mg/kg

Acute Other LD50 Mouse: 158 mg/kg

Acute Other LD50 Rat: 65 mg/kg

Acute toxicity Toxic if swallowed.

Skin corrosion/irritation Not classified.

Respiratory sensitisation Not classified.

Specific target organ toxicity

- repeated exposure

Not classified.

Specific target organ toxicity

- single exposure

Not classified.

Carcinogenicity Not classified.

Germ cell mutagenicity Not classified.

Reproductive toxicity Not classified.

Information on likely routes of exposure

Ingestion Causes nausea, dizziness and/or vomiting.May cause stomach pain, cramps and/or diahrroea.May cause coughing, breathing difficulties, or shortness of breath.Danger of serious damage to health by prolonged exposure if swallowed .

Inhalation May cause irritation to respiratory organs.

Skin contact Prolonged or repeated contact may cause transient irritation.

Eye contact Prolonged or repeated contact may cause transient irritation.

Symptoms Not available.

Mixture versus substance

informationNone known.

Other information Not available.

Section 12: Ecological information

Toxicity

Product Test results

LC50 Daphnia magna: 470 mg/l 96 hourCORRSHIELD NT4292 (Mixture)

LC50 Fathead minnow: 930 mg/l 96 hour

NOEL Daphnia magna: 310 mg/l 96 hour

NOEL Fathead minnow: 620 mg/l 96 hour


EC50 Greasyback shrimp (Metapenaeus ensis): 16,14 - 26,61 mg/l48 hours

Sodium nitrite (7632-00-0)







CORRSHIELD NT4292


LC50 Channel catfish (Ictalurus punctatus): 0,048 mg/l 96 hoursSodium nitrite (7632-00-0)

LC50 Fish: 0,56 - 1,78 mg/l 96 hour

Persistence and degradability

This product, being inorganic, has no TOC, BOD.

- COD (mgO2/g) 92 (calculated data)

Bioaccumulative potential Not available.

Mobility in soil Not available.

Results of PBT and

vPvB assessment

Not available.

Other adverse effects Not available.

Environmental fate -

Partition coefficient

Not available.

Summary Very toxic to aquatic organisms.The evaluation of environmental hazards is based on the concentration limits as set out in directive1999/45/EC.

Section 13: Disposal considerations

Waste treatment methodsContaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 1015 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not otherwisespecified.15 01 Packaging (including separately collected municipal packaging waste).15 01 10 Packaging containing residues of or contaminated by dangerous substances.Depending on the origin and state of the waste, other EWC numbers may be applicable too.

Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 0316 Wastes not otherwise specified in the list.16 03 Off-specification batches and unused products.16 03 03 Inorganic wastes containing dangerous substances.Depending on the origin and state of the waste, other EWC numbers may be applicable too.

Section 14: Transport information

ADR

UN3099UN number

Oxidizing liquid, toxic, n.o.s. (Sodium nitrite Mixture)UN proper shipping name

5.1Transport hazard class(es)

6.1Subsidiary class(es)

IIIPacking group

YesEnvironmental hazards

(E)Tunnel restriction code

Not available.Special precautions for user

RID

UN3099UN number









CORRSHIELD NT42926.1Subsidiary class(es)

IIIPacking group



ADN

UN3099UN number




IIIPacking group



IATA

UN3099UN number




IIIPacking group



IMDG

UN3099UN number




IIIPacking group


F-A, S-QEmS No.


ADR RID ADN IATA IMDG

Transport in bulk according to

Annex II of MARPOL 73/78 and the

IBC Code

No information available.

Section 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulations

Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex INot listed.

Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex II

Not listed.







CORRSHIELD NT4292Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I

Not listed.

Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1

Not listed.


Not listed.


Not listed.

Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V

Not listed.

Directive 96/61/EC concerning integrated pollution prevention and control (IPPC): Article 15, European Pollution Emission Registery

(EPER)

Not listed.

Regulation (EC) No. 1907/2006, Article 59(1). Candidate List

Not listed.

National regulations Not available.

Inventory status

Country(s) or region Inventory name On inventory (yes/no)*

YesEurope European Inventory of Existing Commercial Chemical Substances(EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

Chemical safety assessment Not available.

Section 16: Other information

List of abbreviations CAS: Chemical Abstract Service Registration NumberEC-No: European Commission NumberCLP: Regulation on classification, labeling and packaging of substances and mixturesDSD: Dangerous Substances DirectiveCEN: European Committee for StandardisationTWA: Time Weighted AverageSTEL: Short Term Exposure LimitLD50: Lethal Dose, 50%LC50: Lethal Concentration, 50%EC50: Effect Concentration, 50%NOEL: No Observed Effect Level

COD: Chemical Oxygen DemandBOD: Biochemical Oxygen DemandTOC: Total Organic CarbonADR: European Agreement concerning the International Carriage of Dangerous Goods by RoadADN: European Agreement concerning the International Carriage of Dangerous Goods by InlandWaterwaysIATA: International Air Transport AssociationIMDG: International Maritime Dangerous Goods CodeRID: International Rule for Transport of Dangerous Substances by Railway

References Safety data sheets of raw materials.

Information on evaluation

method leading to the

classification of mixture

The health and environmental hazards of this mixture are assessed by applying the conventionalmethods as described in Annex II and III to Directive 1999/45/EC.

Full text of any statements orR-phrases and H-phrases under

Sections 2 to 15

R8 Contact with combustible material may cause fire.R25 Toxic if swallowed.R50 Very toxic to aquatic organisms.

H272 - May intensify fire; oxidiser.H301 - Toxic if swallowed.H400 - Very toxic to aquatic life.







CORRSHIELD NT4292Revision information This document has undergone significant changes and should be reviewed in its entirety.

Training information Provide training on safe handling while considering the type of application and exposure scenarios.

Based on EC Directive /

Regulations1999/45/EC2001/118/EC2004/73/EC(EC) No 1907/2006 (REACH)(EC) No 453/2010

Further information Correction in Section: 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15.16


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Corr Shield Nt 4292