63
CATHODIC PROTECTION SYSTEM DESIGN Presented By DENIS L ROSSI P.E. CORROSION ENGINEER New England C P Inc.

Corrosion Testing d Rossi Cathodic

Embed Size (px)

DESCRIPTION

Public Domain Materials

Citation preview

Page 1: Corrosion Testing d Rossi Cathodic

CATHODIC PROTECTIONSYSTEM DESIGN

• Presented ByDENIS L ROSSI P.E.

• CORROSION ENGINEER• New England C P Inc.

Page 2: Corrosion Testing d Rossi Cathodic

Corrosion Fundamentals

Page 3: Corrosion Testing d Rossi Cathodic

What is corrosion?

It is defined as the degradation or deterioration of a material,usually a metal, due to a reaction with its environment.

What does that mean???

Page 4: Corrosion Testing d Rossi Cathodic
Page 5: Corrosion Testing d Rossi Cathodic

Corrosion is a natural process. Metals don’t like being metals, they prefer remaining as ores.In the process of converting ores into metals, energy is added in the form of heat, this places the metal into a high-energy state.It is this energy that is given off from the metal, as the metal isreturning to an ore, lower-energy state, is what we call corrosion.

Page 6: Corrosion Testing d Rossi Cathodic

Steel - Rust to Rust

Pipe

Mine Steel Mill

Refining

Bridge

Underground Pipeline

Iron Ore

Rust

IronOxide

Page 7: Corrosion Testing d Rossi Cathodic

Components of a corrosion cell

• Anode – Metal loss or corrosion occurs at the anode

• Cathode– Little or no corrosion occurs at the cathode

• Return Circuit/Metallic Path– Provides a path for electrons to flow, between the anode and cathode

• Electrolyte– Ionized solution capable of conducting electricity

Page 8: Corrosion Testing d Rossi Cathodic

Corrosion of Metals

Current Flow

Current FlowCathode Anode

Electrolyte

Page 9: Corrosion Testing d Rossi Cathodic

Practical corrosion cell

• Anode – bare steel gas service• Cathode – cast iron gas main• Electrolyte – soil that main and service

are buried in• Return path – service tee threaded into

gas main

Page 10: Corrosion Testing d Rossi Cathodic

WIRE(CONDUCTOR)

CARBON ROD(CATHODE)

+0.30mV

ZINC CASE(ANODE)-1.10mV

MOIST PASTE(ELECTROLYTE)

Page 11: Corrosion Testing d Rossi Cathodic

Copper Water Line-(Cathode)

Steel Gas Service (Anode)

Steel Gas Main –(Anode)

CI Water Main(Cathode)

Steel Distribution System – No Insulators ( i = Current Flow)

Appliance-(External Connection)

Soil (Electrolyte)

i

i

ii

i

Page 12: Corrosion Testing d Rossi Cathodic

Copper Water Line

Steel Gas Service

Steel Gas Main

CI Water Main

Steel Distribution System – Insulators

insulator

insulator

Page 13: Corrosion Testing d Rossi Cathodic

PRACTICAL GALVANIC SERIESMaterial Potential*

Pure Magnesium -1.75

Magnesium Alloy -1.60

Zinc -1.10

Aluminum Alloy -1.00

Cadmium -0.80

Mild Steel (New) -0.70

Mild Steel (Old) -0.50

Cast Iron -0.50

Stainless Steel -0.50 to + 0.10

Copper, Brass, Bronze -0.20

Titanium -0.20

Gold +0.20

Carbon, Graphite, Coke +0.30

* Potentials With Respect to Saturated Cu-CuSO4 Electrode

Page 14: Corrosion Testing d Rossi Cathodic

Factors causing corrosion on a pipeline

• Dissimilar metals– Galvanic corrosion

• Brass valve or copper pipe connected to carbon steel pipe• Old carbon steel pipe connected to new steel pipe

• Dissimilar Soils– Varying oxygen content– Varying resistivities

• Mechanical Stresses– Bending and Gouges– Cutting of threads

• Stray Currents

Page 15: Corrosion Testing d Rossi Cathodic

Brass Valve(Cathode)- 300mV

Iron Pipe(Anode)- 500mV

Iron Pipe(Anode)- 500mV

Coupling to Dissimilar Metals

Page 16: Corrosion Testing d Rossi Cathodic
Page 17: Corrosion Testing d Rossi Cathodic

Corrosion

Steel

Copper

Anodic Area (corrosion)

Cathodic Area (protection)

Page 18: Corrosion Testing d Rossi Cathodic
Page 19: Corrosion Testing d Rossi Cathodic
Page 20: Corrosion Testing d Rossi Cathodic

Basic Corrosion Cell

Earth (Electrolyte)Corrosion Current

Return PathCorroding Area Protected Area

Anodic Area Cathodic Area

Page 21: Corrosion Testing d Rossi Cathodic

Oxygen Concentration Corrosion Cell

More Oxygen - Cathodic - Protected

Less Oxygen - Anodic - CorrodingUndisturbed Earth

Corrosion Currents Pipe

Backfill

Page 22: Corrosion Testing d Rossi Cathodic

Oxygen ConcentrationCorrosion Cell

Corrosion Currents

RockAnodic Area

Cathodic Areas

Anodic Area

Pipe

Wood Bed Block

Page 23: Corrosion Testing d Rossi Cathodic

Scarred/Damaged Surface Corrosion

Threads, scratches and dents are anodicto undisturbed surfaces along the pipe.

Page 24: Corrosion Testing d Rossi Cathodic
Page 25: Corrosion Testing d Rossi Cathodic

Dissimilar Soils

Corrosion

Anodic Area Cathodic Area

Soil (Low concentration of Salts)Soil (High concentration of Salts)

Page 26: Corrosion Testing d Rossi Cathodic

Cathodic Protection Rectifier

Anode Groundbed

Gas Pipeline

Water Pipeline

(-)

(+)

Current Discharge(Corrosion)

Current Discharge(Corrosion)

Stray Current Due to Impressed Current Cathodic Protection System

Page 27: Corrosion Testing d Rossi Cathodic

Corrosion Current vs Metal Loss

• Metal loss is directly proportional to corrosion current

• 1 amp per year = 20 pounds of steel lost• Larger area of steel exposed - more

current required for cathodic protection• For given current - faster wall

penetration at smaller exposed surface area

Page 28: Corrosion Testing d Rossi Cathodic

Stray Current

Page 29: Corrosion Testing d Rossi Cathodic

SummarySummary

•Corrosion Cell*Anode*Cathode*Electrolyte*Metallic Connection

Page 30: Corrosion Testing d Rossi Cathodic

Rules & Regulations

• Department of Transportation– Part 192

• Operations And Maintenance Manual

Page 31: Corrosion Testing d Rossi Cathodic
Page 32: Corrosion Testing d Rossi Cathodic
Page 33: Corrosion Testing d Rossi Cathodic
Page 34: Corrosion Testing d Rossi Cathodic

What Has to be Cathodically Protected ?

•All steel pipe installed after 1971 must be protected from external corrosion.

•Regardless of size•Regardless of Length

•What does that mean ? •All new steel pipe MUST have:

Page 35: Corrosion Testing d Rossi Cathodic

Protective Coating•Applied on a properly applied surface•Have sufficient adhesion to the pipe•Sufficient strength to resist cracking•Have sufficient strength to resist damage due handling and soil stress.

•Compatible with cathodic protection currents•Coatings must also be:

•Inspected for damage prior to lowering in the ditch•Must be protected from damage from adverse ditch conditions.•Precautions must be taken to protect coated pipe that is to be installed by boring.

Page 36: Corrosion Testing d Rossi Cathodic

Cathodic Protection

• Provide a level of cathodic protection for the entire length of the underground structure.

• Cathodic protection levels must be controlled so as not to damage coatings.

Page 37: Corrosion Testing d Rossi Cathodic

Electrical Isolation

• Insulating devices must be installed on the steel pipe so as to facilitate electrical isolation.• Mains – @ Tie-ins and crossings with other

utilities• Services - @ the main and the service riser• Casings – insulated from the carrier unless both

carrier and casing are cathodically protected as a single unit.

Page 38: Corrosion Testing d Rossi Cathodic

Test Leads and Boxes• Test leads must be securely attached and minimize

stress concentration on the pipe.• All test lead connections at the pipe must be

coated.• Test leads must extend out of the test box by at

least 18”.• Test box locations and dimensions will be

indicated on the design drawings.• Test leads will be connected as required.

Page 39: Corrosion Testing d Rossi Cathodic

Pipe installed prior to 1971

• Bare or coated steel pipe determined to be in areas of continuing corrosion must be cathodically protected.

• Hot Spot Protection.

Page 40: Corrosion Testing d Rossi Cathodic

Atmospheric Corrosion• Pipelines that are exposed to the atmosphere

must be cleaned and either coated or jacketed with a material suitable for the prevention of atmospheric corrosion.

• Steel service risers and meter installations must be coated to the outlet side of the meter bar.

Page 41: Corrosion Testing d Rossi Cathodic

Other• Exposed Pipe Inspection

– Further Investigation if additional corrosion is evident.

• Inspect coatings for damage• Inspect bare pipe for pitting and uniform wall loss.

• Internal Pipe inspection• Inspection Data to be kept for the LIFE of

the pipe.

Page 42: Corrosion Testing d Rossi Cathodic

Cathodic Protection

Page 43: Corrosion Testing d Rossi Cathodic

Elements of a Corrosion Control System

Coating

Connect to morenegative metal

Limit Area in Contact with Electrolyte

Break electrical pathto what’s not

being protected

Page 44: Corrosion Testing d Rossi Cathodic

Protection of a Pipeline with a Sacrificial Anode

Pipe Ano

de

Current through WirePipe Coating

tCurrent through Soil

Page 45: Corrosion Testing d Rossi Cathodic

Black Wire

Lead Seal

Steel Core

Gypsum Powder

MagnesiumBar

ClothSack

SealingCompound

Magnesium Anode

Note: Anodes should be installed 18” below and 18” to the side of the pipe.The anode should be also be soaked with water before backfilling.Do not carry by the wire.

Page 46: Corrosion Testing d Rossi Cathodic

Sacrificial Magnesium Anode

Page 47: Corrosion Testing d Rossi Cathodic

R

+

-

Rectifier Groundbed

IJ IJ

Rectifier

Anode Groundbed

Page 48: Corrosion Testing d Rossi Cathodic

POLE MOUNTED RECTIFIER

Page 49: Corrosion Testing d Rossi Cathodic

Typical Arrangement of Cathodic Protection For Tanks

Typical Arrangement of Cathodic Protection For Tanks

Rectifier

AnodesTank

Tank

Page 50: Corrosion Testing d Rossi Cathodic

Tidal Zone Cathodic ProtectionTidal Zone Cathodic Protection

MHW

MLW

Steel Pile

Galvanic or ImpressedCurrent Anodes

Tidal Zone

Structure Section

Cathodic Protection is Afforded to Steel in Tidal Zone During Periods of High Tides.

Page 51: Corrosion Testing d Rossi Cathodic

Corrosion Testing

Page 52: Corrosion Testing d Rossi Cathodic

Pipe-to-Soil Potential Test

Test BoxCu/CuSO4 Reference Cell

Multimeter-0.85

Pipe

Pipe Lead

Page 53: Corrosion Testing d Rossi Cathodic

Corrosion Monitoring

• Mains - Once a Year– Ensure Test Box Availabilty

• Services – Once every Ten Years– Ensure Test Wires are Connected

• Rectifiers and Bonds – 2 Months• Record Keeping – For the life of the pipe.

Page 54: Corrosion Testing d Rossi Cathodic

Common Corrosion Problems

Page 55: Corrosion Testing d Rossi Cathodic

Shielding of Cathodic Protection

Wood

Cathodic Protection Current

Corrosion

Anode

Page 56: Corrosion Testing d Rossi Cathodic

SheetingCurrent Pipe

Shielding Of Protective CurrentsShielding Of Protective Currents

Page 57: Corrosion Testing d Rossi Cathodic

Pipe Wall

Backfill

Protected

Coating

Cathodic Protection CurrentProtects Exposed Area

Cathodic Protection Current Does Not ProtectArea Under Disbonded Coating

Coating Disbondment & CP Shielding Coating Disbondment & CP Shielding

Page 58: Corrosion Testing d Rossi Cathodic

Faulty Service Isolators

Page 59: Corrosion Testing d Rossi Cathodic

Mastic Application

MA

STIC

Page 60: Corrosion Testing d Rossi Cathodic

Proper Mastic Application

Wire brush damaged areasApply two thin coats (paint)Let dry between coats (15 min)Let dry before backfilling.

Page 61: Corrosion Testing d Rossi Cathodic

Proper Coating Repairs withCold Applied Tape

Clean pipe with wire brush.Apply primer to clean pipe.Wrap tape around pipe.

Page 62: Corrosion Testing d Rossi Cathodic

Other• Test Wires not connected to anode.• No dielectric union on service entrance or

service regulator vent.• Underground electrical contact with other

metallic structure.• Isolator installed incorrectly or not at all.• Isolator installed and not indicated.• Test boxes paved over.• Telemetry not isolated.

Page 63: Corrosion Testing d Rossi Cathodic

Summary

• Corrosion CellAnodeCathodeElectrolyteMetallic Connection

• Corrosion Control SystemCoating - Mastic and Cold Applied TapeIsolation - Insulating JointsCathodic Protection - Magnesium Anode