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1
Curriculum Vitae
Dr. Julio Lloret Fillol
Number of pages: 20
Section A - Short Curriculum Vitae
o Academic Career; Position & Short Visits. Fellowships & Awards
o Publications summary
Section B - Summary of the early achievements track-record
Section C - Extend Curriculum Vitae
o C.1.- List of Publications
o C.2.- List of participation in research projects
o C.3.- List of invited conferences, meetings and workshops
o C.4.- Patents
o C.5.- List of professional activities
o C.6.- Detailed independent research
2
Section A - Short Curriculum Vitae
Dr. Julio Lloret Fillol (18/03/1977) Researcher ID: A-3102-2009
Current Position
ICREA Research Professor and Research Group Leader at the
Institute of Chemical Research of Catalonia ICIQ (Tenure-Track).
e-mail: [email protected]
Web site: http://www.iciq.org/research/research_group/dr-julio-lloret-fillol/
Education
26-05-2006 European Ph.D. in Chemistry with Excellent Cum Laude, Univ. of Valencia
(Spain). Ph.D. Supervisors: Prof. P. Lahuerta and Prof. J. Peréz-Prieto
06-2001 Bachelor in Chemistry, Univ. of Valencia (Spain)
01-2001 / 06-2001 Erasmus programme, the highest mark, Univ. of Loughborough (UK)
Position
Since 11 - 2015 ICREA Research Professor
Since 11 - 2014 Research Group Leader at the Institute of Chemical Research of Catalonia (ICIQ)
01-2014 - 10-2014 Young Research Group Leader at the Institut the Química Computational i Càtalisi
04-2010 - 10-2014 Independent research leader as Ramón y Cajal (2009-program) at the Univ. of Girona,
Spain (Since 32 years old).
04-2008 / 03-2010 Marie Curie IEF, Univ. of Heidelberg, Germany (Prof. L. H. Gade)
12-2006 / 04-2008 Post-Doc MEyC, Univ. of Heidelberg, Germany (Prof. L. H. Gade)
07-2006 / 12-2006 Post-Doc, Univ. of Valencia, Spain (Prof. M. Ubeda)
01-2002 / 06-2006 Ph.D. student, Univ. of Valencia, Spain.
08-2001 / 12-2001 Univ. of Würzburg, Germany (contracted by SFB347 and BASF) (Prof. H. Werner)
01-2001 / 06-2001 Undergraduate student, Univ. of Loughborough, Erasmus program, UK (Prof. J. Parr)
Short Visits
07-2013 / 08-2013 University of Minnesota. Visiting professor, EEUU (Host: Prof. Dr. L. Que)
10-2006 / 11-2006 Universitat Rovira i Virgili. Visiting professor, Spain (Host: Dr. J. Carbó)
07-2005 / 09-2005 Univ. of Heidelberg, as visiting student, Germany (Prof. L. H. Gade)
06-2004 / 08-2004 Univ. of Joensuu, as visiting student, Finland (Prof. T.A.Pakkanen & P. Hirva)
07-2003 / 08-2003 Max-Plank-Institut für Kohlenforschung, Germany (Prof. L. Gooβen)
04-2002 Univ. Autónoma de Barcelona, Spain (Prof. A. Lledós)
Fellowships and Awards
2019 Thieme Chemistry Journals Award
2017 Young Academy of Europe
2015 Young Researcher Award 2015 (under the 40’s) of the RSEQ
2015 ERC-Consolidation Grant GREENLIGHT_REDCAT (1.999.063 €)
2014 Young Researcher Award 2014 (under the 40’s) of the Organometallic Group of the RSEQ
2014 Positive evaluation in the Spanish Tenure Track Program I3.
2014 Shortlisted for the Chem Soc Rev Emerging Investigator Lectureship 2014
2013 I passed the 1st stage of the 2013-ERC Starting Grant (Interviewed in Brussels)
2013 Qualified as “professor agregat” by “Agència per a la Qualitat del Sistema Universitari Cat.”
2010 Marie Curie Reintegration Grant. WaterSplit (FP7-268445) Total Score: 91.4 over 100.
3
2009 Ramón y Cajal Program (Spanish Tenure Track Program) (MICINN-RYC-2009-0540).
Highly competitive, only <7% program success. Awarded within the top 10.
2007 Marie Curie IEF for career development. CHIRGOLD - Researcher Score: 4.6 over 5.
2006 Post-Doctoral Fellowship Grant from MEyC Spanish Government. (declined after 1 year)
2006 Ph.D. Fellowship Mobility Grant from MEyC, Univ. of Heidelberg (Prof. L. H. Gade)
2004 Ph.D. Fellowship Mobility Grant from MEyC, Univ. of Joensuu (Prof. T.A. Pakkanen)
2002 MEyC Ph.D. Fellowship Grant of the Spanish Government
2002 Ph.D. Fellowship Grant “Fundación Jose y Ana Royo” (declined after 1 year)
2001 Erasmus Fellowship Grant from MEyC, Univ. of Loughborough, UK
2001 Collaboration Grant from MEyC, Spanish government at Univ. of Valencia, Spain
Supervisions and Commissions
Supervision of Graduate Students Fellows
2010 – 2014
As an independent
researcher (at Univ.
of Girona, Spain)
- Supervised 4 Ph.D. students: Mr. Z. Codolá, Mr. F. Acuña, Mr. G. Sabeña,
Mr. A. Call.
- 7 Master Students: Research work on catalysis at Univ. of Girona: Mr. Z.
Codolá (2010), Mr. F. Acuña (2011), Mr. G. Sabenya (2011) and Mr. A. Call
(2011). Supervisor of the master research work on Data mining and
knowledge discovery of Mr. R. Eduart (2012) at Univ. of Buenos Aires.
Supervisor of the Master research work on Computational chemistry and
Catalysis of Ms. C. Casadevall and C. Vignatti (2013).
Zoel Codolà, my first Ph.D. student, has been awarded with the prestigious European Young Chemists
Award 2014. He also had been awarded with a Principe de Asturias Fellowship and had the highest mark
in the Master Defence of his promotion and received the highest Ph.D. mark.
Arnau Call and Ferran Acuña have been awarded with an FPU and FI fellowships, respectively. Both
received the highest Ph.D. mark.
Carla Casadevall has had the highest Master thesis mark of her promotion.
2015 – 2018
At ICIQ
- 8 PhD students under supervision: Mrs. C. Casadevall (4th y), Mr. M.
Claros (3rd y), Mr. K. Michaliszyn (3rd y), Mr. S. Fernandez (2nd y), and Mr. J.
Aragó (2nd year), Mrs. G. Dubed Bandomo (1st y), Mrs. P. David (0 y) and
Mrs. P. Gutierrez (0 y).
- 3 Master Students: Research work on computational chemistry at Univ. of
Girona: Mr. S. Fernandez (2017), Mr. Master BIST: M. Bueno (2018). Master
URV on catalysis Mr. L. Montiel (2018).
Sergio Fernandez has had the highest Master thesis mark of his promotion and awarded with an FPU
Teaching Activities
2010 – 2013 Lecturer of Inorganic Chemistry in the Chemistry Department. Teaching background
on “Materials Science” subject. (30 h)
2013 – 2019 Lecturer of Master of Computational Chemistry and Catalysis of the Department of
Chemistry at Girona University. Teaching background on “Catalysis apply to the
energy production” subject (30 h)
2013.10 Lecturer on the postgraduate program of the Univ. Nacional Autónoma de Mexico.
“Catalysis apply for the energy production” (4.5 h)
4
Commissions of Trust
• Member of Ph.D. thesis jury on seven occasions (Girona, Barcelona, 2xMadrid, Castellon, and
Perugia (Italy, 2014) and Stockholm (Sweden, June 2014).
• Reviewer of scientific journals such as Nat. Chem., J. Am. Chem. Soc, ACIE among others.
• Regular reviewer of the Petroleum Research Foundation, Spanish national basic research program,
and FET-open Horizon 2020. Marie Skłodowska-Curie actions – Individual Fellowships (H2020-
MSCA-IF-2014), among other agencies
ORGANIZACION CONGRESOS
2015 – 3- 6-Nov. XII Simposio de Investigadores Jóvenes, Barcelona, Spain. Member of the organization and scientific
committee.
2018 – 30 Jul – 4 – Aug 43nd International Conference on Coordination Chemistry" in Sendai (Japan). Symposium S33
Functional hybrid materials for catalytic energy conversion, Organizer
2018 – 18-19-Oct. 2nd Trans Pyrenean Meeting in Catalysis (TraPCat2), Tarragona, Spain. Organizer
During my PostDoc (at University of Heidelberg, Germany)
• PhD advisor of Mr. A. Kruckenberg, Mr. P. Scherl and advisor for diplomarbeiten Mr. Achim
Kruckenberg, Mr. Peter Scherl and Mr. Christoph Rettenmeier (Univ. of Heidelberg, Germany).
• Assistant professor in“Anorganisch-Chemisches Forschungspraktikum” (4 undergrad student’s, total of
60 days).
Memberships of Scientific Societies
• Partner member of the WG3 CARISMA COST ACTION and CHAOS ACTION
• Member of the “Real Sociedad Española de Química” (RSEQ, since 2003) and of the American Chemical
Society (ACS, since 2009)
Major Collaborations Active
- Collaborations in Europe
Prof. Dr. M. Beller (LIKAT at the Univ. of Rostock), Prof. Dr. Beatriz Royo (ITQB at the Univ. Nova de
Lisboa), Dr W. R. Browne (Univ. of Groningen), Prof. Dr. Julia Pérez-Prieto (Univ. of Valencia), Prof. Dr.
Lutz Hans Gade (Univ. of Heidelberg), Dr. Miquel Costas (Univ. of Girona), Dr. Josep M. Lluis (Univ. of
Girona), Dr. Ruben Mas (Univ. Autonoma de Madrid), Prof. Dr. George JP Britovsek (Imperial College,
London), Dr. Olaf Rüdinger (Max Plank Institute Mulheim, Germany).
- Collaborations with the rest of the world
Prof. Dr. L. Que (Univ. of Minnessota), Prof. Dr. E. Münck (Carnegie Mellon University), Prof. Dr. G
Ghirlanda (Arizona State University).
5
Publications summary
During my scientific carrier, I have produced over
74 scientific publications in the most prestigious
international journals, three book chapters and
around 80 communications in international forums
and conferences. I have been invited to give
lectures over 60 times. Among all of them, I want
to remark the talks in the University of Michigan,
Arizona, and Minnesota (about top 20 USA
universities in the Shanghai ranking) and the
International School of Organometallic Chemistry.
My research has also delivered in 6 Spanish/International patents. Since April-2010 I have published as an
independent researcher a collection of papers in top international peer-reviewed journals: 1 x Nat. Chem.
2011, 807-813 (>460 cites indexed in crossref and highlighted), 2 x Nature Communication, 2 x ACIE.
(one VIP), 6 x J. Am Chem. Soc, 9 x Chem. Eur. J. (one Frontispiece), 2 Chem Sci (one cover picture), 3
Chem. Commun. (one cover picture) among others.
According to the ISI Web of Knowledge, I have over 2300 citations with a google scholar h index of 27.
Since 2010, I have supervised 4 Ph.D. thesis and currently are ongoing eight more.
Selected Publications as the corresponding author derived from the PI independent research work
1) “Efficient Water Oxidation Catalysts Based on Readily Available Iron Coordination Complexes” J.
Lloret-Fillol et al. - Nature Chem. 2011, 807-813 (>460 citations, crossref).
2) “Electronic Effects in Iron-Catalyzed Water Oxidation” - Chem. Eur. J. 2013, 19, 8042. (70 c.)
3). “Highly Effective Water Oxidation Catalysis with Ir Complexes”- Chem.Eur.J.2013, 19, 7203. (59c.)
4). “Triggering the generation of an iron(IV)-oxo compound and its reactivity towards sulfides by RuII
photocatalysis.” J. Am. Chem. Soc, 2014, 136, 4624. (37 c.)
5) “Photo- and electro-catalytic H2 production by new 1st-row transition metal complexes based on an
aminopyridine pentadentate ligand” - Chem. Eur. J. 2014, 20, 6171-6183. (43 c.)
6) “Evidence for an Oxygen Evolution Fe-O-Ce Intermediate in iron-Cat.WO” - Nature Comm.
01/2015; 6:5865. (40 c.)
7) “Cobalt-Copper Dual Light-Driven Catalytic Reduction of Aldehydes and Aromatic Ketones in
Aqueous Media.” Chem. Sci., 2017, 8, 4739
Cover picture
Highlighted in Chemistry World from RSC and ChemistryViews from Wiley
Most downloaded articles of 2017: Energy and Catalysis
8) “Understanding Light-driven H2 Evolution through the Electronic Tuning of Aminopyridine Cobalt
Complexes.” Chem Sci., 2018, 9, 2609.
Editors’ Choice Collection.
Collection to celebrate our diverse and global authorship.
9) “A Highly Active N-heterocyclic Carbene MnI Electrocatalyst for CO2 Reduction.” Angew. Chem.,
2018, 57, 4603.
10) “Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts
by Deuteration of Oxidation Sensitive Sites.” J. Am. Chem. Soc. 141, 323
Five patents:
WO/2013/004874, WO/2014/076340, ES2440896B1 and WO2015059337A1
6
Section B - Summary of the achievements track-record as an independent researcher
Dr. Julio Lloret Fillol has started a new research group at the ICIQ since November of 2014. Currently, the
working research group is mainly formed by:
Prof. LLORET FILLOL JULIO 20825037D Principal Researcher - CELEX-ICIQ-ICREA
CASADEVALL SERRANO CARLA Ph.D. Student; FPU
CLAROS MIGUEL Ph.D. Student; CELLEX-ICIQ
Michaliszyn Klaudia Ph.D. Student; ERC
Fernandez Sergio Ph.D. Student; FPU
Aragó Jordi Ph.D. Student; FPI
Dubed Bandomo Geyla Caridad Ph.D. Student; ERC
Pascual David Ph.D. Student; ERC
Gutierrez Luis Ph.D. Student; ERC
Dr Noufal Kandoth Juan de la cierva
Dr Federico Franco COFUND EU-ICIQ-IPMP; ERC
Dr Sekhar Mondal Suvendu COFUND EU-ICIQ-IPMP; ERC
Dr. Bucci Alberto A-LEAF
Dr. Martin Vlad ERC
The research lines of the group at the ICIQ are devoted to providing further understanding on mechanism
principles participating in artificial photosynthetic schemes and develop systems for the synthesis of fine
chemicals:
1) Reductive chemistry for the synthesis of fine chemicals and fuels.
I have been awarded with a Consolidator Grant of the European Research Council to develop this project.
a. Water Reduction (WR): We have identified new highly efficient cobalt molecular water reduction
catalysts that operate in both photo- and electrochemical (J. Lloret and co. Chem. Eur. J. 2014, 20,
6171) conditions, with improved performances through electronic tuning of the ligand (> 8500 TON
and 52000 TON/h). We have also unequivocally identified the metal protonation as the rate
determining step of the light-driven H2 evolution mechanism (Chem. Sci., 2018, 9, 2609. This article
is part of the themed collections: Editors’ Choice Collection, Collection to celebrate our diverse and
global authorship). We have taken advantage of the ligand platform versatility to study the effect of
secondary effects in catalysis by developing artificial metalloenzymes. Interesting enough, the
catalytic performance improved upon catalyst encapsulation in streptavidin. We suggested that the
protein pocket aid the delivery of protons over the catalytic center.
b. CO2 Reduction Catalysis (RC): We have also studied the CO2 reduction activity for the same cobalt
complexes and studied the mechanism of action (Under preparation). On the other hand, and in
collaboration with Prof. B. Royo (ITQB, Nova University of Lisbon) we have developed the first
purely organometallic Mn complexes for CO2 reduction. The systems reveal an extraordinary
electrocatalytic CO2 reduction activity even in the absence of protons. Mechanistic insights reveal
proposed intermediates in CO2 reduction such as [Mn(CO)4] [M-OCOH] and [M-H] (Angew. Chem.
Int. Ed. 2018, 57, 4603).
c. Modify electrodes with COFs: We have developed new COFs based on the {Mn(CO)3} motive
characterized by 13C-NMR, IR and EXAFS, with high catalytic activity and good selectivity for CO2
reduction to CO at low overpotential in water at pH 7.5.
d. Reactivity of organometallic complexes: We are also exploring the reactivity of 1st-row transition
metal complexes based on the tripodal C3‐Symmetric HTIM(PR2)3 family of ligands (Eur. J. Inorg.
Chem. 2018, 23, 2612; Cover picture; ICIQ special issue). The systems are catalytically active and
selective for the hydroboration of CO2 to formic acid. Moreover, the nickel derivates are highly active
and selective for the hydrogenation of N-heterocycles.
e. Towards Light-driven Water Reduction Catalysis; Beyond Artificial Photosynthesis: Same cobalt
complexes developed for WR are also active catalyst for the reduction of ketones to alcohols using
7
water as a source of H2 and light as the driving source (A. Call and J. Lloret-Fillol Chem Sci, 2017,
8, 4739 (Cover picture) and Chem. Commun. 2018, 9643).
2) Oxidation Chemistry; Water Oxidation Catalysts (WOC).
Water is the most appealing global-scale source of electrons that can be used to store energy into chemical
bonds. However, it is also considered one of the bottlenecks for the development of artificial photosynthesis.
WO needs to be catalyzed in order to proceed at low energy barriers and practical reaction rates. Intermediates
involved in water oxidation are highly unstable, and their characterization is still very challenging (CCR 2017,
334, 2 and book chapters 2018-2019, CV publications 73-74).
a. Well-defined Iron Complexes for WO: in collaboration with Dr. M. Costas: We have discovered
highly efficient homogeneous iron catalysts for WO (Lloret et al. Nat. Chem. 2011, 807-813). These
findings constitute a breakthrough in the field of WOC. Further studies allowed me to suggest two
new intermediates in WO and organic oxidation a FeV=O (Chem. Eur. J. 2012, 18, 13269) and a rare
{Fe-O-Ce} intermediate (Chem. Eur. J. 2013, 19, 8042, Highlighted in Angewandte Chemie and as
Frontispiece). Theoretical studies, carried out in my group, aid me to unravel the mechanism of WO
catalyzed by non-heme iron complexes, the ligand role, and the requirements to develop active
catalysts for WO (Chem. Eur. J. 2014, 20, 5696 and Inorg. Chem. 2014, 53, 5474-5485). Recently, I
have finally characterized the proposed exotic {Fe-O-Ce} intermediate (resonance Raman, EXAFS,
high-field EPR, and Mössbauer) in collaboration with Prof. L. Que and Prof. E. Münck. The discovery
of this heterometallic complex opens the possibility to study in detail the role of the Lewis acid in the
O-O bond formation reaction, mimicking the PSII. (Nature Commun. 2015 NCOMMS-14-03271A)
These results call the attention of Prof. K. Morokuma among others, which embarked in studying
theoretical aspects of the reaction. Also, I have led to the discovery of the reactivity enhancement (100
fold) of an oxo-iron(IV) towards oxygen atom transfer reactions by photochemical irradiation, J.
Lloret-Fillol, and co. JACS 2014 136, 4624. We have also improved 10-fold the water oxidation
catalysts by deuteration of oxidation-sensitive sites. More importantly, this provides the strongest
evidence of a molecular system in the literature (JACS 2019, 141, 323).
b. Well-defined Ruthenium Complexes for WO: We have elucidated the WO mechanism for
homologous Ru complexes (Chem. Eur. J. 2016, 22, 20111). Among the most challenging are the
intermediates located after the O-O bond formation event, which is irreversible and usually the rate
determining step. For this reason, there is no clear experimental information of the reactivity nor the
intermediates after the O-O bond formation event. Fortunately, we have obtained a full
characterization and reactivity of an intermediate located after the O-O bond formation. The
characterized intermediate is better described as a RuIV-peroxo species using spectroscopic (L-edge
XAS, Raman) and spectrometric studies in combination with theoretical calculations (Manuscript in
preparation).
c. Materials. Molecular complexes are convenient platforms for study mechanism of water oxidation.
However, their instability against oxidative damage challenges their technological application. On the
other hand, mix metal oxides (MM’Ox) are extremely robust materials. However, their understanding
is more challenging. In this regard, we are developing synthetic protocols to control wet synthesis
MM’Ox that gives highly active materials which can also serve as model systems for study.
3) Computational Mechanistic Investigation.
We have usually combined experimental and theoretical studies (in collaboration with J. M. Lluis at
UdG) to understand the reaction mechanisms better. Just an example of operative pathways in Ag
catalyzed cross-coupling reactions (Nature Commun 2014).
4) Development of Hight Throughput Experimental Techniques.
In other to accelerate the development of light-driven methodologies we have developed parallel
screening platforms of 24 and 48 reactions under temperature (-80 to 120 ºC) and light intensity control.
A new design provides an anaerobic environment which allows for low-temperature studies. The
irradiation is homogeneous in all reaction positions with a standard deviation lower than 2.5 %. The
system can be calibrated with a convenient toolkit to control all different variables precisely.
8
Section C - Extended Curriculum Vitae
C.1. List of Publications since 2010, (* Corresponding author)
2019
77.- “Advances in the Electrochemical Catalytic Reduction of CO2 with Metal Complexes” Federico
Franco, Sergio Fernandez, Julio Lloret-Fillol* Current Opinion In Electrochemistry -Organic and
Molecular Electrochemistry (2019) – Edited by Marc Robert, 2019 In press
76.- “Water Oxidation Catalysis with Well-defined Molecular Iron Complexes” Carla Casadevall,
Alberto Bucci, Miquel Costas,* Julio Lloret-Fillol* Advances in Inorganic Chemistry V 74 on Water
Oxidation Catalysis– Edited by Rudi van Eldik and Colin Hubbard, 2019 In press
75.- “Water Oxidation Catalyzed by First Row Transition Metal Complexes.” Julio Lloret-Fillol,* Miquel
Costas,* Advances in Organometallic Chemistry– Edited by Pedro Perez , 2019 In press
74.- “Visible Light Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes” M.
Claros, F. Ungeheuer, F. Franco, V. Martin-Diaconescu, A. Casitas,* J. Lloret-Fillol,* Angew. Chem.
Int. Ed. 2019, DOI: 10.1002/anie.201812702
73.- “Catalytic water oxidation: Water Oxidation to O2 Mediated by 3d Transition Metal Complexes.”
Zoel Codolà, Julio Lloret-Fillol,* Miquel Costas,* in “Non-Noble Metal Catalysis: Molecular
Approaches and Reactions” John Wiley & Sons, 2019 Edited by Bert Klein Gebbink and Marc-Etienne
Moret.
72.- Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation
Catalysts by Deuteration of Oxidation Sensitive Sites Zoel Codolà, Ilaria Gamba, Ferran Acuña,
Carla Casadevall, Martin Clémancey, Jean-Marc Latour,Josep M. Luis, Julio Lloret-Fillol* and Miquel
Costas* J. Am. Chem. Soc. 2019, 141, 323.
2018
71.- Enhance and Control of the Selectivity in Light-driven Ketone versus Water Reduction Using
Aminopyridine Cobalt Complexes Arnau Call, and Julio Lloret-Fillol* Chem. Commun. 2018, 9643
70.- Manganese N-Heterocyclic Carbene Complexes for Catalytic Reduction of Carbonyl Groups with
Silanes Mara F. Pinto, Federico Franco, Julio Lloret-Fillol, Beatriz Royo,* ChemCatChem 2018, 10,
2734
Cover Picture
69.- Synthesis and Reactivity of Copper(I) Complexes based on C3-Symmetric Tripodal HTIM(PR2)3
Ligands Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch,
Julio Lloret-Fillol* Eur. J. Inorg. Chem. 2018, 2612
Cover Picture
68.- Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate
Ruixi Fan, Joan Serrano-Plana, Williamson N. Oloo, Apparao Draksharapu, Anna Company, Margarida
Borrell, Julio Lloret-Fillol, Yisong Guo,* Emile Bominaar,* Lawrence Que Jr.,* Miquel Costas,*
Eckard Münck,* J. Am. Chem. Soc., 2018, 140, 3916
67.- A Highly Active N-heterocyclic Carbene MnI Electrocatalyst for CO2 Reduction Federico Franco,
Mara F. Pinto, Beatriz Royo,* and Julio Lloret-Fillol* Angew. Chem., 2018, 57, 4603
9
66.- Understanding Light-driven H2 Evolution through the Electronic Tuning of Aminopyridine
Cobalt Complexes Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernandez, Maria Gonzalez,
Julia Perez-Prieto, Josep M. Luis, Julio Lloret-Fillol,* Chem Sci., 2018, 9, 2609
This article is part of the themed collections:
▪ Editors’ Choice Collection.
▪ Collection to celebrate our diverse and global authorship.
65.- Modified High Surface Carbon Fiber Electrode as Efficient Electro-Organocatalytic Material for
Hydrogen Production Octavio Gonzalez del Moral, Arnau Call, Federico Franco, Jose Antonio Nieto-
Rodríguez, María Frias, Sergio Díaz-Tendero, Jose Aleman, Jose L. G. Fierro, Miquel Costas, Julio
Lloret-Fillol, Rubén Mas-Ballesté* Chem. Eur. J., 2018, 24, 3305
64.- Design of Zn-, Cu- and Fe-BPA complexes confined in a self-assembled nanocage via bipyridine
anchoring Cédric Colomban, Vlad Martin-Diaconescu, Teodor Parella, Sébastien Goeb, Cristina
García-Simón, Julio Lloret-Fillol, Miquel Costas, and Xavi Ribas Inorg Chem., 2018, 57, 3529
2017
63.- Cobalt-Copper Dual Light-Driven Catalytic Reduction of Aldehydes and Aromatic Ketones in
Aqueous Media Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, and Julio Lloret-
Fillol* Chem. Sci. 2017, 8, 4739
Cover Picture
Most downloaded articles of 2017: Energy and Catalysis
62.- Making and Breaking of the O-O Bond at Iron Complexes Gerard Sabenya, Laura Lázaro, Ilaria
Gamba, Vlad Martin-Diaconescu,* Erik Andris, Thomas Weyhermüller, Frank Neese,* Jana Roithova,*
Eckhard Bill,* Julio Lloret-Fillol,* Miquel Costas.* J. Am. Chem. Soc., 2017, 139, 9168
61.- Making and Breaking of the O-O Bond at Iron Complexes Ilaria Gamba, Zoel Codolà, Julio Lloret-
Fillol,* Miquel Costas,* Coordination Chemistry Reviews 2017, 334, 2
2016
60.- Nuevas estrategias para la conversión de la energía solar en enlaces químicos Zoel Codolà, Arnau
Call, Ferran Acuña-Pares, Julio Lloret Fillol* Anales 2016, 112, 133
59.- Spectroscopic, electrochemical and computational characterization of Ru species involved in
catalytic water oxidation. Evidence for [RuV(O)(Py2Metacn)] intermediate, Carla Casadevall, Zoel
Codola, Miquel Costas, Julio Lloret-Fillol* Chem. Eur. J. 2016, 22, 10111
58.- Water oxidation: High five iron, Julio Lloret-Fillol, Miquel Costas Nature Energy 2016, 137,
10.1038/nenergy.2016.23
2015
57.- Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2-O Bond Forming Reactions, J. Serra, C.
J. Whiteoak, F. Acuña-Parés, M. Font, J. M. Luis, J. LloretFillol and Xavi Ribas,* J. Am. Chem. Soc.
2015, 137, 13389
56.- Non-heme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and their Reactivities
Towards Hydrogen- and Oxygen-Atom Transfer Reactions, M. Mitra, H. Nimir, S. Demeshko, S.
Bhat, M. Haukka, J. Lloret-Fillol, G. C. Lisensky, F. Meyer, A. A. Shteinman, W. R. Browne, D. A.
Hrovat, M. G. Richmond, M. Costas, and E. Nordlander* Inorg. Chem. 2015 , 54, 7152
55.- Non-heme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and their Reactivities
Towards Hydrogen- and Oxygen-Atom Transfer Reactions, Teresa Corona, Florian F Pfaff, Ferran
10
Acuña‐Parés, Apparao Draksharapu, Christopher J Whiteoak, Vlad Martin‐Diaconescu, Julio
Lloret‐Fillol, Wesley R Browne, Kallol Ray, Anna Company* Chem. Eur. J. 2015, 21, 15029
54.- H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2
Azin Hassanpour, Ferran Acuña-Parés, Josep M Luis, Olaf Cusso, Silvia Morales de la Rosa, José
Miguel Campos-Martín, Jose LG Fierro, Miquel Costas, Julio Lloret-Fillol, Rubén Mas-Ballesté Chem.
Commun 2015, 51, 14992
53.- Evidence for an Oxygen Evolving Fe–O–Ce Intermediate in Iron-Catalysed Water Oxidation Zoel
Codolà, Laura Gómez, Scott T. Kleespies, Lawrence Que, Jr.,* Miquel Costas* and Julio Lloret-Fillol*
Nature Communications 01/2015, 6:5865
52.- Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Co-Ligands in H2O2
Activation for Asymmetric Epoxidation of a-Alkyl-Substituted Styrenes, O. Cusso, X. Ribas, J.
Lloret-Fillol, and M. Costas* Angew. Chem Int Ed. 2015, 54, 2729
Very Important Paper
2014
51.- Observació directa de cicles redox de Ag (I)/Ag (III) de dos electrons en catàlisi de
funcionalització d’halurs d’aril Marc Font, Ferran Acuña-Parés, Teodor Parella, Jordi Serra, Josep M
Luis, Julio Lloret-Fillol, Miquel Costas, Xavi Ribas Revista de la Societat Catalana de Química 2014
13:40.
50.- Direct observation of two-electron Ag(I)/Ag(III) redox chemistry in silver-catalyzed aryl halide
functionalizations Marc Font, Ferran Acuña-Parés, Teodor Parella, Jordi Serra, Josep M. Luis, Julio
Lloret-Fillol, Miquel Costas, Xavi Ribas* Nature Communications 2014 5:4373
49.- Aryl-Copper(III)-acetylides as key intermediates in Csp2-Csp model couplings under mild
conditions Mireia Rovira, Marc Font, Ferran Acuña-Parés, Teodor Parella, Josep M. Luis, Julio Lloret-
Fillol, Xavi Ribas* Chem. Eur. J. 2014, 20, 10005
48.- Light-Driven Hydrogen Generation: Efficient Copper-Based Water Reduction Catalysts Henrik
Junge, Zoel Codolà, Anja Kammer, Nils Rockstroh, Shu-Ping Luo, Michael Karnahl, Marga-Martina
Pohl, Sebastian Wohlrab, Julio Lloret-Fillol, Miquel Costas, and Matthias Beller* Journal of Molecular
Catalysis A: Chemical 2014, 395, 449
47.- Theoretical Study of the Water Oxidation Mechanism with Non-heme Iron Complexes. Evidence
that the FeIV(O) Species Cannot React with the Water Molecule to Form the O-O Bond Ferran
Acuña-Parés, Miquel Costas, Josep M. Luis* and Julio Lloret-Fillol* Inorg. Chem. 2014, 53, 5474
46.- Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging
Oxidative Transformations Zoel Codolà, Julio Lloret-Fillol,* Miquel Costas* Book Chapter in
Progress in Inorganic Chemistry 2014, 447-532
45.- Photo- and electro-catalytic H2 production by new 1st row transition metal complexes based on
an aminopyridine pentadentate ligand Arnau Call, Zoel Codolà, F. Acuña-Pares Julio Lloret-Fillol*
Chem. Eur. J.. 2014, 20, 6171
44.- Triggering the generation of an iron(IV)-oxo compound and its reactivity towards sulfides by RuII
photocatalysis Anna Company,* María González-Béjar, Gerard Sabeña, Laura Gómez, Miquel
Costas,* Julia Pérez-Prieto* Julio Lloret-Fillol* J. Am. Chem. Soc. 2014, 4624-4533
43.- Comprehensive Coordination Chemistry III; Small molecule models for non-prophyrinic iron
and manganese oxygenases Anna Company,* Julio Lloret Fillol,* Miquel Costas*, Elsevier, 2014,
V3.18, 487-564.
42.- Unraveling the mechanism of water oxidation catalyzed by non-heme iron complexes F. Acuña-
11
Pares, Z. Codolà, M. Costas, J.M Luis,* J.Lloret-Fillol,* Chem. Eur. J. 2014, 20, 5696
41.- Evidence that Steric Factors Modulate Reactivity of Tautomeric Iron-Oxo Species in
Stereospecific Alkane C-H Hydroxylation Mainak Mitra, Julio Lloret-Fillol, Matti Haukka, Miquel
Costas,* Ebbe Nordlander* Chem. Commun., 2014, 50, 1408 – 1410
2013
40 Highly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine
Manganese Catalysts Olaf Cussó, Isaac Garcia-Bosch, David Font, Xavi Ribas, Julio Lloret-Fillol,
Miquel Costas* Org. Lett. 2013, 15, 6158-6161
39.- Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-Heme Iron
Catalysts Ofal Cusso, Isaac Garcia-Bosch, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas* J. Am.
Chem. Soc. 2013, 135, 14871
38.- Zirconium Hydrazides as Metallanitrene Synthons: Release of Molecular N2 from a
Hydrazinediido Complex Induced by Oxidative N-N-Bond Cleavage Thorsten Gehrmann, Julio
Lloret Fillol, Heike Herrmann, Hubert Wadepohl and Lutz H. Gade,* Organometallics 2013, 23, 3877-
3889
37.- Oxidation of anticancer Pt(II) monodentate phosphine complexes. Towards stable but active
Pt(IV) prodrugs M. Ángeles Medranoa, A. Álvarez-Valdés, J. Perles, J. Lloret-Fillol, S. Muñoz-
Galván, A. Carnero, C. Navarro-Ranninger, A. G. Quiroga.* Chem. Commun., 2013, 49, 4806
36.- Highly Effective Water Oxidation Catalysis with Iridium Complexes through the use of NaIO4,
Zoel Codolà; João M. S. Cardoso; Beatriz Royo; Miquel Costas; Julio Lloret-Fillol* Chem. Eur. J.
2013, 19, 7203-7213
35.- Electronic Effects on Water Oxidation Iron Catalysts Zoel Codolá, Isaac Garcia, Irene Prat, Miquel
Costas* and Julio Lloret Fillol,* Chem. Eur. J. 2013, 8042–8047
2012
34.- Iron Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation with a Single Electron
Oxidant and Water as Oxygen Atom Source Isaac García-Bosch, Zoel Codolà, Irene Prat, Xavi
Ribas, Julio Lloret-Fillol,* Miquel Costas* Chem. Eur. J. 2012, 18, 13269
33.- Synthesis, Characterization and Thermal Rearrangement of Zirconium Tetraazadienyl and
Pentaazadienyl Complexes. Thorsten Gehrmann, Julio Lloret Fillol, Hubert Wadepohl and Lutz H.
Gade* Organometallics 2012, 31, 4504
32.- Domino Reaction Cascades With and Without Bifurcations of Zirconium Hydrazinediido
Complexes with Alkynes Thorsten Gehrmann, Solveig A. Scholl, Julio Lloret Fillol, Hubert
Wadepohl, and Lutz H. Gade* Chem. Eur. J. 2012, 18, 3925 – 3941.
31.- The More Gold – The More Enantioselective: Cyclohydroaminations of γ-Allenyl Sulfonamides
with Mono-, Bis- and Trisphospholane Gold(I) Catalysts Lara-Isabel Rodríguez, Torsten Roth, Julio
Lloret Fillol, Hubert Wadepohl, Lutz H. Gade* Chem. Eur. J. 2012, 18, 3721 – 3728
30.- Alkane C-H Oxidation Catalyzed by Transition Metal Complexes. A. Company,* Julio Lloret,* L.
Gómez,* M. Costas,* Alkane C-H Oxidation Catalyzed by Transition Metal Complexes. Netherlands
Springer Science & Business Media. ISBN: 978-90-481-3697-1. 2012, 142-228
2011
29.- Efficient Water Oxidation Catalysts Based on Readily Available Iron Coordination Complexes.
Julio Lloret Fillol,* Zoel Codolà, Isaac Garcia-Bosch, Laura Gómez, Juan José Pla, Miquel Costas,*
12
Nat. Chem. 2011, 807-813
Identified as Highly Cited Paper by ISI, Highlighted by Nachrichten aus der Chemie,
2011, 59, p.1030, as one of the most important achievements in the chemistry of 2011.
28.- Stitching Phospholanes Together Piece by Piece: New Modular Di- and Tridentate
Stereodirecting Ligands. Julio Lloret Fillol, Achim Kruckenberg, Peter Scherl, Hubert Wadepohl,
Lutz H. Gade* Chem. Eur. J. 2011, 17, 14047-14062.
27.- Zirconium-Catalyzed Multistep Reaction Sequences of Hydrazines with Alkynes: A Non-Fischer
Type Pathway to Indoles. Thorsten Gehrmann, Julio Lloret Fillol, Solveig Scholl, Hubert Wadepohl,
Lutz H. Gade* Angew. Chem., Int. Ed. 2011, 50, 5757
C.2. List of participation in research projects
14.- Light-driven Reductive Chemistry for Solar-Fuels and Solar-Chemicals. (2017 SGR 1647) (2017-
2020) PI. Julio Lloret-Fillol (22.240 EUR).
13.- Reduciones Quimicas Mediadas Por La Luz. De Combustibles A Compuestos Solares. (Ministerio
de Economía Y Competencia, CTQ2016-80038-R) (2017-2020) PI. Julio Lloret-Fillol, (70.000 EUR +
FPI; a 4 y PhD fellowship).
12.- An Artificial Leaf: a photo-electro-catalytic cell from earth-abundant materials for sustainable
solar production of CO2-based chemicals and fuels (HORIZON-2020 - FET Proactive 732840 A-
LEAF) (2017-2020) Coordinator. Jose Ramón Galan Mascaros, (7.980.861 EUR)
11.- Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts
and Light-driven Water Reduction as a Source of Reductive Equivalents (ERC-2014-CoG 648304)
(2015-2020) PI. Dr. Julio Lloret Fillol (1.999.063 EUR)
10.- Study of intermediates in catalytic H2 generation with cobalt complexes based on tacn (Diamon
and Electra SINCROTRONS), 2015, measurements and travel expenses, PI: Dr. Julio Lloret-Fillol
9.- Well-Defined Iron Catalysts for Challenging Tasks (Fundação para a Ciência e a Tecnologia,
PTDC/QEQ-QIN/0565/2012) (2013-2015) PI. Dr. Beatriz Royo (148.000 EUR)
8.- Modular Ligands for water splitting (Marie Curie Reintegration Grant, FP7-PEOPLE-2010-RG FP7-
268445) PI Dr. Julio Lloret Fillol (2011/7 – 2014/7) (45.000 EUR)
7.- Design of stereoselective organometallic catalysts base on adaptable ligands through modular and
secondary interactions (Univ. of Girona). MEyC Ramón y Cajal RYC-2009-05409 P.I.: Dr. Julio
Lloret Fillol. (15.000 € + 180.000 € (salary)).
6.- Diseño bioinspirado de catalizadores para la oxidación de enlaces C-H, C=C y agua (Ministerio de
Economia y Competencia CTQ2012-37420-C02-01) PI. Dr. Miquel costas (2013 – 2015) (196.000
EUR + a fellowship PhD)
5- Supramolecular Chemistry applied to the Design, Synthesis and Evaluation of Bioactive
Compounds of Anti-inflammatory, Anti-tumour or Anti-parasitic Action (SUPRAMED)
(CONSOLIDER- CSD2010-00065) PI. Prof. Enrique Víctor García-España Mon; PI(Girona): Dr.
M. Costas (2011 – 2015) (4.000.000 EUR)
4.- Stereoselective Catalysis (SFB623-B6) PI. Prof. Dr. Lutz H. Gade (2009/2 – 2013/2)
3.- Síntesis, Reactividad y Aplicaciones de Complejos Quirales de Rh(II) Soportados con Ligandos
Quirales de Simetria C2. (CTQ2005-08351) PI. Prof. Pascual Lahuerta Peña (2002 – 2005)
2.- Asymmetric Catalysis Using Threefold Symmetry AC3S (HPRN-CT-2001-00187, European net-
work) PI. Prof. Pascual Lahuerta Peña (2002 – 2006)
13
1.- Síntesis y Estudio de la Actividad Catalítica de Nuevos Catalizadores con Ligandos Quirales,
Pinza y C3. Hetereogenización en Matrices Sólidas. (MAT2002-04421-C02-02, MCYT Spanish
Science and Technology Ministry) PI. Prof. Pascual Lahuerta Peña, Universidad de Valencia (2002 –
2005)
C.3. List of invited conferences, meetings and workshops since 2012
61.- CaixaForum Tarragona Química i energia, les fronteres del segle XXI, Tarragona, (Spain) 2019,
March 5th Julio Lloret Fillol and Anna Company Outreach Lecture
60.- 9th International Conference on Advanced Materials and Nanotechnology (AMN9) Wellington, (New
Zealand) 2019, 13th February From Well-defined Coordination Complexes towards Materials for
Artificial Photosynthesis Julio Lloret Fillol Invited Speaker.
59.- Workshop On: Otago Future Fuels (OFF), Dunedin, (New Zealand) 2019, From Well-defined
Coordination Complexes towards Materials for Artificial Photosynthesis Julio Lloret Fillol Plenary
Lecture
58.- CaixaForum Girona Química i energia, les fronteres del segle XXI, Girona, (Spain) 2019, January 29th
Julio Lloret Fillol and Anna Company Outreach Lecture
57.- Workshop On: Solar Fuel Production Based on Nanostructured Photoelectrodes and Catalysts, Braga,
(Portugal) 2018, From Well-defined Coordination Complexes towards Materials for Artificial
Photosynthesis Julio Lloret Fillol Key Note
56.- VI Workshop on Sustainable Chemistry Tools in Green Chemistry – Castellon – 2018 Design of
Catalytic Systems for Photo- and Electrochemical Transformations. On the way to Renewable Fuels
and Chemicals Julio Lloret Fillol Plenary Lecture
55.- Post-ICCC2018 meeting Fukuoka, (Japan) 2018 Light-Driven Reductive Chemistry for Renewable
Fuels and Chemicals. Julio Lloret Fillol Key Note
54.- Post-ICCC2018 meeting Oita, (Japan) 2018, Water Oxidation Catalysis with Well-defined Fe
Complexes Julio Lloret Fillol Plenary Lecture
53.- ICCC2018 Sendai, (Japan) 2018, Towards Light-Driven Reduction. From Solar Fuels to Solar
Chemicals Julio Lloret Fillol Invited Speaker
52.- BIYSC – Tarragona – ICIQ – 2018 Artificial Photosynthesis, From Solar Fuels to Solar Chemicals.
Julio Lloret Fillol Lecture – outreach activity
51.- Metting ECIR – Barcelona 2018 Mechanistic insights into water and CO2 reduction chemistry by
well-define cobalt complexes Julio Lloret Fillol Invited Speaker
50.- University of Sevilla (Spain) 2018, Towards Light-Driven Reduction. From Solar Fuels to Solar
Chemicals Julio Lloret Fillol Lecture
49.- GDR Solar Fuels, Collège de France – Paris (France) 2018. Light-driven Reductions Using Well-
Defined Coordination Complexes; From Solar Fuels to Solar Chemicals Julio Lloret Fillol Plenary
Lecture
48.- Donostia International Physics Center (DIPC) 25th May – Donostia (Spain) 2018 Light-driven
Reductions Using Well-Defined Coordination Complexes; From Solar Fuels to Solar Chemicals Julio
Lloret Fillol Lecture
14
47.- Girona Seminar (Predictive Catalysis, Transition-Metal Reactivity by Design) 2018, Girona (Spain)
Towards Light-Driven Reduction. From Solar Fuels to Solar Chemicals Julio Lloret Fillol Key Note
46.- Gordon Research Conference; Renewable Energy: Solar Fuels – Ventura (USA) 2018, Isolation and
characterization of an elusive Ru(IV) peroxo: A missing link Julio Lloret Fillol Selected poster for
oral presentation
45.- University of Arizona (USA) 2018, Artificial Photosynthesis from Solar Fuels to Solar Chemicals
Julio Lloret Fillol Lecture
44.- Barluenga Lectureship – Oviedo (Spain) 2017, Light-Driven Reduction Chemistry. From Solar Fuels
to Solar Chemicals. Julio Lloret Fillol Plenary Lecture
43.- ISOC - XI edition of the International School of Organometallic Chemistry Organometallic chemistry,
(Italy) 2017. from theory to applications , Artificial Photosynthesis from Solar Fuels To Solar
Chemicals Julio Lloret Fillol Plenary Lecture
42.- University of Oviedo (Spain) 2017. Water oxidation catalysis with well-defined Fe and Ru complexes
Julio Lloret Fillol Lecture
41.- i-Chat Frascati, Roma (Italy) 2017. Catalytic Light-Driven Reductive Transformations Mediated by
Cobalt Complexes Julio Lloret Fillol Oral Lecture
40.- Universidad de Barcelona (Spain) 2017. Towards Artificial Photosynthetic Schemes for Light-Driven
Transformations Julio Lloret Fillol Lecture
39.- ACS-(San Francisco, USA) 2017. Towards Artificial Photosynthetic Schemes for Light-Driven
Transformations Julio Lloret Fillol Oral Presentation
38.- Regensburg University From Solar Fuels to Solar Chemicals Julio Lloret Fillol Lecture
37.- Tutorial at the Graduate school "Chemical Photocatalysis" at Regensburg University MOLECULAR
CATALYSTS FOR WATER SPLITTING, A technological and scientific perspective Julio Lloret
Fillol Lecture
36.- CAIXAFORUM -2017 Lleida, (Spain) Combustibles solares Carla Casadevall, Julio Lloret-Fillol*
Plenary Leture, Outreach Activity
35.- EUCHEMS-2016 (Sevilla, Spain) Catalytic light-driven reduction of water and organic compounds by
well-defined cobalt complexes, Julio Lloret Fillol Oral Presentation
34.- 2nd International Symposium on Chemical Energy Conversion Processes (ISCECP-2) (Fukuoka,
JAPAN) 2016, Water Oxidation catalysts based on aminopyridine ligands Julio Lloret Fillol Key Note
33.- CARISMA - COST – Ljubljana (Slovenia) 2016. Spectroscopic, electrochemical and computational
characterization of Ru species involved in catalytic water oxidation Julio Lloret Fillol Key Note
32.- Pacifichem 2015 – Honolulu (USA) 2015, Aminopyridine ligands as platforms for well-defined Water
Oxidation and reduction catalysis Julio Lloret Fillol Invited Speaker
31.- Universidad de Zaragoza (Spain) 2015, Well-Defined Water Oxidation And Light-Driven Reduction
Catalysts Julio Lloret Fillol Lecture
30.- XII Simposium the Jovenes Investigadores Sigma-Aldrich – Barcelona (Spain) 2015, Aminopyridine
ligands as platforms for well-defined Water Oxidation and reduction catalysis Julio Lloret Fillol
Plenary Lecture
29.- Bienal RSEQ – A Coruña 2015. Aminopyridine Ligands as Platforms for Well-Defined Iron Water
Oxidation Catalysts and Light-Driven Cobalt Reduction Catalysts Julio Lloret Fillol Oral
Presentation
28.- Max Planck Institute for Chemical Energy Conversion 2015, Aminopyridine Ligands as Platforms for
Well-Defined Light-Driven Cobalt Reduction and Iron Water Oxidation Catalysts Julio Lloret Fillol
Lecture
15
27.- Ruhr-Universität Bochum, Young researcher talk 2015, Aminopyridine Ligands as Platforms for
Well-Defined Light-Driven Cobalt Reduction and Iron Water Oxidation Catalysts Julio Lloret Fillol
Lecture
26.- CARISMA COST ACTION – Tarragona (Spain) 2015, Homogeneous Iron-Catalysed Water
Oxidation Julio Lloret Fillol Key Note
25.- EUCHEM 2014 – Istanbul (Turkey) 2014, Aminopyridine ligands as platforms for well-defined Water
Oxidation and reduction catalysis Julio Lloret Fillol Invited Speaker
24.- ISAACS13 – Dublin (UK) 2014, Intermediates in Homogeneous Iron-Catalysed Water Oxidation
Julio Lloret Fillol Oral Presentation
23.- University of Lund 2014 (Sweden), Julio Lloret Fillol Homogeneous Water Oxidation Catalysis with
First Row Coordination Complexes Invited Lecture.
22.- NIS-Colloquium, Photo- and electrochemical Cells for Solar Fuels - Torino (Itali) 2014 Water
Oxidation Catalysis with Nonheme Iron Complexes, Julio Lloret Fillol Invited Lecture
21.- COST ACTION CM1205 CARISMA, Utrecht 2013 (Netherlass) Julio Lloret Fillol. Homogeneous
Water Oxidation Catalysis with Iron Coordination Complexes. Invited Speaker.
20.- Graduate Course at Universidad Nacional Autónoma de Mexico (UNAM, Mexico) 2013 “Catálisis
aplicada a la producción de energía” Oct. 21 - 23 of 2013 (4.5 h) Julio Lloret Fillol Lecture
19.- University of Michigan 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis
with Iron Coordination Complexes. Invited Speaker.
18.- Utah State University 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis with
Iron Coordination Complexes. Invited Speaker.
17.- University of Minnesota 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis
with Iron Coordination Complexes. Invited Speaker.
16.- SiLQCOM 2013 Huatulco (Pacific coast of Oaxaca, Mexico), 13-17 Octubre del 2013 Julio Lloret-
Fillol* “Mechanistic Insight of Homogeneous Water Oxidation Catalysis with Iron Coordination
Complexes” Invited Speaker.
15.- COST action CM1003 Utrecht 2013 (Nederland) Julio Lloret Fillol. Homogeneous Water Oxidation
Catalysis with Iron Coordination Complexes. Oral Contribution.
14.- 1st Workshop on Advanced Materials for Solar Fuels Applications, Castellón, 11 Febrero del 2012,
Julio Lloret-Fillol* “Mechanistic Insight of Homogeneous Water Oxidation Catalysts with Iron
Coordination Complexes” Invited Lecture.
13.- IX Simposio de Investigadores Jóvenes Zaragoza, 7-10 Noviembre del 2012, Julio Lloret-Fillol*
“Mechanistic Insight of Homogeneous Water Oxidation Catalysts with Iron Coordination Complexes”
Oral Presentation.
12.- ADHOC, International Symposium on Activation of Dioxygen & Homogeneous Catalytic Oxidation
Jerusalem, Israel, 2012, 2-7 Sept. Julio Lloret Fillol,* Zoel Codolà, Isaac Garcia-Bosch, Laura
Gómez, Irene Prat and Miquel Costas,* “Homogeneous Water Oxidation Catalysts with Iron
Complexes” Oral Communication
11.- Invited Lecture Madrid 20-Genuary-2012 Julio Lloret Fillol “Efficient Water Oxidation Catalysts
Based on Readily Available Iron Coordination Complexes” Lecture.
C.4. Patents
16
1.- “Procedimiento de oxidación catalítica de agua mediante catalizadores de hierro” Julio Lloret Fillol, Zoel
Codolà, Isaac Garcia-Bosch, Laura Gómez, Juan José Pla, Miquel Costas P1969ES00, 06/07/2011
(International extended, WO/2013/004874.
2.- “Catalizadores para la epoxidación de alquenos“ Olaf Cusso, David Font Gimbernat, Irene Prat Casellas,
Anna Company Casadevall, Laura Gomez Martín, Xavier Ribas Salamaña, Isaac Garcia Bosch, Julio Lloret
Fillol, Miquel Costas Salqueiro, WO/2014/076340, 13/11/2012.
3.- “Compuesto poliamínicos y complejos metálicos que comprenden para su uso como agentes
antiparasitarios“ Xavi Rivas, Miquel Costas, Olaf Cussó, Anna Company, Julio Lloret, Manual Sánchez,
Clotilde Marín, María Jose Rosales, Francisco Olmo, ES2440896B1, 23/11/2013.
4.- “Compuesto metálicos que comprenden compuestos poliamínicos y dichos compuestos para su uso como
agentes antiparasitarios“ Olaf Cusso, Xavi Rivas, Miquel Costas, Olaf Cussó, Anna Company, Julio Lloret,
Manual Sánchez, Clotilde Marín, María Jose Rosales, Francisco Olmo, ES2439397A1 / WO2015059337A1
23/11/2013.
5.- “Un procedimiento de reducción fotocatalítico y una composición catalizadora utilizada en el
procedimiento” J. Lloret Fillol, A. Call Quintana, C. Casadevall Serrano, A. Casitas Montero.
WO/2018/211154 / PCT/ES2017/070314, 16/05/2017
6.- "Process for the activation of chloride organic compounds and a catalytic composition used in the process
Julio Lloret-Fillol, Miquel Claros, Felix Ungeheuer, Alicia Casitas. Submitted as: EP patent application No:
EP18382332.3, application date 15.05.2018