Ha 00 000• m U

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION V

DATE: MAR 2 9 1988

SUBJECT: Data Assessment Request •; l > ' i " '

r No man Niedergang, Chief &&**££ &U4*~*^CERCLA Enforcement Section - .....

•J-.^.-L."Curt is R o s s , Director f-- ------ '"

TO; Central Regional Laboratory

At tached please find a data package (s ) generated for an enforcements i te for your review/assessment.

Si te Name:

Phone:

Enforcement Category: PRP-lead PRP-oversight Fund-lead

State-lead Others

Data Generated By:(Analyt ical Lab) CLP Lab? Org Y_*fN _ ; Inorg Y_*^ N _ ; Dioxin Y _ N

Preliminary PRP-Data />. //>Assessment Done By:

Rev iew Request for the Following Parameter Groups and for the IndicatedPercentage of the Data:

ORGANICS ^SAMPLE INORGANICS ISANPLE OTHERS

// VOCs /## % // Metals °k Dioxin _ %_ _ _(I B/N/A f/ff % // CN to? % _ SAS _ %ft Pest/PCBs /%?% _ _ _ %

Requested Due Date: 30 days _ 21 days is 14 days _ other

Other Information:

Unit Chief frgf^ £ft 3>'2?>-3?

cc: Soo Hong, CES To be CRL Date In >, -*•/ /• 'Conpleted CES Requested Due Dateby CRL : CRL COTmitt^rTJye^Date

Signa ture '

EPA Region 5 Records Ctr.

209187

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION V

DATE: MAR 2 9 1988

SUBJECT: Data Assessment Request

Niedergang, ChiefCERCLA Enforcement Section

^

ur-Curt is R o s s , Director

TO: Central Regional Laboratory

At tached p lease find a data package(s) generated for an enforcements i te for your review/assessment.

Site Name:

CES RPK: Phone:

Enforcement Category: PRP-lead

State-lead

PRP-oversight

Others

Fund-lead

Data Genera ted By: _(Analyt ical Lab) CLP Lab? Org Y_*,fN _ ; Inorg

Preliminary PRP-DataAssessment Done By:

N _ ; Dioxin Y

Review Request for the Following Parameter Groups and for the IndicatedPercentage of the Data:

ISAMPLE ORGANICS ISAMPLE INORGANICS ISANPLE OTHERS

////

VOCs /## %B/N/A ffff %Pest/PCBs

////

MetalsCN

Dioxin _ %SAS _ %

%

Requested Due Date:

Other Information:

30 days _ 21 days <s 14 days _ other

/J

Unit Chief Pft

cc: Soo Hong, CES To be CRL Date In * *••{?:_Completed CES Requested Due Dateby CRL : CRL Comni1tte<rv^Date

Signature

EP» (REV

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION V

SL3JEC

0

' k£~ jjlfsv*^. {sr&w<

IVC C0444- C^T^C

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DATE :

rUNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION V

SUBJECT: Review of Region V CLP DataReceived for Review on

FROM: Curtis Ross, Director (5SCRL) '/X-rx'l .'•'-<• - /.-Central Regional Laboratory '>' '

TO: Data User: s /'•'<'•* • ,;

We have reviewed the data for the following case(s).

SITE NAME: • / -,.••', SMO case No.No. of ~ D.U./Activity

EPA Data Set No. Samples: Numbers

CRL No.

SMO Traffic No. _Mrs. Required

CLP Laboratory: _ for Review:

Fol lowing are our f indings:

?md¥> r * "i-t*,for- r?£c£t/e<L i-xaf

( ) Data are acceptable for use.( vj Data are acceptable for use with qualifications noted above.( ) Data are preliminary - pending verification by Contractor Laboratory.( ) Data are unacceptable.

cc: Duane Geuder, Quality Assurance Officer, EPA Support ServicesJames Petty, Chief Quality Assurance Research, EMSL, Las Vegas

EPA FORM 1320-6 (Rev. 5/87)

PAGE t OFDATA QUAL IF IERS

Con t rac to r : | Case /.^ ,5^

» is a sum^a-j of the out-of-control audits and the possible e f f e c t on thedata for mis c a s e :

/i~ff

'/

3.

/? ' -V

l/&fjt ft- 1 1 fi-*tJ fell fiKct

Reviewed by:

Phone:

Date:

PAGE _v3 OF _£

DATA QUALIF IERS

C o n t - a c t o - : _ | C f l S t > ;

;

Belo» is a sum^a-jr of the out-of-control audits and the possible e f fec t on thedata fo r th is c a s e :

77" -S i/ ('vaVcxfet/ Ps-fz-ei/f £> d£ /,'& (%-<=&&/ tfi&b I) 062X2* A

6", /

I/A ft

Reviewed by:

Phone: ( «-.frg ^ >5rT3

Date:

DATA QUALIFIERSPAGE J£ OF %

Com -act 0-: Case

I

Bplo» is a su"v.a-.> of the out-of-control audits and the possible effect on thedata for t h i s case;

ct'

7>'

*>*s/

7

/

Reviewed by:

Phone:Date:

^ -

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS

VOLATILE HSL COMPOUNDSC A S E / S A S * X5 -T/: <l- CONTRACTOR

f

I nst -uTiert * foilDATE. ;i ;ML :

C h 1 o " ome t n a n eIBromo^ e t h a n eV ^ n y l Ch lo r ideChi o 'oethanpM e t h y l p n e C h l o r i d eA c e t o n eCa"bo r P)i sul f i ae1,1-Picr o r o e t n a n e1 , ! -P~ chl c roe t neneT r a ^ s - l ^ - D ^ c h l o-oetheneC h ' r-e'o-r-Z-rvta^nr1 j?-?"1 e n ! o~oet r ' a n e] ,1 , 1 -T r - i c h l c-oet naneC a " ^ c ^ Te fac h l o " ' de 1v i n y i A c e t a t eP-o~: ;; cM o-o^etha- .e1 ,? - r~ c»- . lo "C""cpa n e

|Tra n s- l ,3-^ ich l o'^p-qp_eneTr - ^ c^ lo -oethe ieD-; bro~o;hl Drome th.a^e] ,1 ,?-T - - (c ' " ; o-oetnanpB e - z e ' - e 'c~ s - 1 , 3 -? - ct-. ' io-or'oppr.e2 - C r ' c"o?*. r-»1 v ' n v let terE - ? ~ - ^ ; --d-*et - . 1 - P - P e - t a n r n e? - k ' e>a i j - elet "e : r > i c -oetheie!,! ,? ,? -Tet -a :n1 oroethaneT &1 ur^c

Cnlo 'cr ie^.zeneEthjl De rzeneSt v "e1".?ir.-^yleneO/p -Xy lene

A F F E C T E DSAM-lES:

Rev1 ewe -' iI n i t i a l s / T a t e : LA//I

J

1 ','

Ini

•2J '/R^

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* These flags should he applied to the analytes on the sample data sheets.

OF

CAS['SAS * /

UN1TEO STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS

Wf* WK) SEM1VOLATILE HSL COMPOUNDS

3 - £. CONTRACTOR

J P S t -u-v-t * (»/•>••) 1

D'*E 'T ]M L :

Phenolb1 S ( -_?- f* l 9 "c>eth_ v l )Ether2 -Ch lo -o r K ~- r " !

1 ,3-n ich i o-ehen:pnp1 ,4-Di chl o-obenzene ^8en;yl A l c o h o l1 ,2-P' ch l o -obenzene2-Met P V 1 phenol 1b" s i. 2 -ch i cro1 sop'opyl 1 EtherA-Met^ylpneno^i

N-N- foso-f"! - n - P r o c v l a~- neHe^ach l o 'oe tnsne

| N ~ t " 0 b e i ~ z e r i eI sor."?"on-e2-N' t -or-e1- :^2 ,a-?--e: r v i r ' -e^c 1

B?" r r~ : A c ^ cI b~ s '. 2-C r^l O 'De thoxV^Methane

2 ,--T • c ^ l o'ophenol1 ,2 ,4 -Tr ' . ch lo roben?eneN = ; K t h a l ene£-Cr 1 o-oan- ' 1 - jneH e * 2 c h l o "o i>^ tad i enei-Cr l oro-3-Meth j l phenol2 - M e t - v 1 r>ar h t na le ie^ ? ' 3 . ^ : o ~ o c y c 1 o p e n t a ^ ' e ^ e2.1- ^ - T " l C h 1 ; C i " O C ^ 6 n c " 1

? _ , - _ , ? - - T - - i c n l oror^enr l2 - T r ' c -D-ap ' - . t na l ener - > ' " i r o 3 " " l " n eD'r .eth_yl Prt D e l a t eAce^ar1"1 ! "~ v 1 ene3 - f > - troa1"! 1 •> neA c e n a , v r t ^ e n e2, A - D - n- 1 rophenol4-r,-' t -op^enolDi Senzo f u -an

A F F E C T E DS A M P L E S :

Rev 'ewe" ^In i t ia ls /Da te : ^l!'/ <

Hj. 'f i^sy• /( f /

Inn

RF

:i. . L

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.. CaVs-7tRSD

*?.£>

•

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*

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RF

. Cc

t"

I .*

* These flags should be applied to the analytes on the sample data sheets. 8/87

PAGE OF _£_

CASE/SAS f

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIEKS

SEMIVOLATILE HSL COMPOUNDSPage 2

i "3 U CONTRACTOR (I L-/l'"/ 'L -

Instrument * .•- c -' /D A T E / T I M E :

2j4-D"initrotol uene2 f6-Di nitrotol ueneDiethylphtnalate4-Chl oropheny 1-pnenyletherFluorene4-N-" t roani 1 i ne4 J6-D ini t ro-2-Methyl phenolN-Ni t rosodipheny l ami ne4-BromDpheny l -phenv l etherH e x a c h l o robenzeneP e n t a c n l o r o p h e n o lPhenant hreneA n t h r a c e n eD'-n-Bj t v l p ' - tna l a teFl uo-anthe' .ePy reneButv l benzvlp.hthal a teB e n z o ( a ) A . n t n r a c e n eb < s ( ? - E t h v l h e x y l ) P n thai ateCh-yseneD ' - n - O c t v l Ph tha la teB e n z o ( D ) F l u o r a n t h e n eB e n z o [ < ^ F l u o " a n t h e n eB e r z o ! a }'T y - e n eI n d e n o ' 1 , 2 f 3 - c c N P y - e n eDi 5enz f a ,h i A n t n - a c e n eE e " z o '. - , r , - ' P e " v 1 e " c

Init. Cal .-•-•A-/r'7RF• 'f/

'•'<\

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1RSD *

Cont. Cal .ij-itft //'C^RF

< v''

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ID- V. 7

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RF tu •

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RF ID-

*

Cont. Cal .!1

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1

ID • 111111I111111

1 111Ii

111

SEE PA2E 1 FO^ AFFECTED SAMPLES.

* These flags should be applied to the analytes on the sample data sheets.

Reviewer's Initials/Date:8/8'

Case:

Contractor:

TENTATIVELY IDENTIFIED COHPOUKDSMATCH ASSESSMENT

BOH: Reviewer should note directljr on Organic Anal/sis Data Sheet (OACS). those Hatches that In his opinion (based on contract criteria] areunreasonable.

CRITERIA

(1) Relative Intensities of major Ions (>!ffl) reference spectrumshould be present In the sample spectrum.

(2) Relative intensities of major Ions 1n sample spectrum shouldagree to within 20S of reference spectrun intensities.

(3) Molecular Ions present In reference spectrum should be presentIn sample spectrum.

(4) Ions present in sample spectrum, but not in reference spectrumshould be reviewed for possible background contamination orpresence of coeluting Interferences.

(5) Ions present in reference spectrum, but not in the samplespectrum should be reviewed for possible subtraction from thesample spectrum because of background contamination or caelut-ing interferences.

(6] If, in the reviewer's opinion, no valid identification canbe made the compound should be labelled as 'unknown' and theInitials and date of the reviewer placed on the OAOS.

PAGE 1 OFUNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION V

DATE:

SUBJECT: Review of Region V CLP DataReceived for Review on

FROM. Curtis Ross, Director (5SCRL)Central Regional Laboratory

T0: Data User: "

We have reviewed the data for the following case(s).

SITE NAME; ^ -~ <?'''-- SMO Case No. I $S~£^ sot-1** 766'No. of ^ D.U./Activity

EPA Data Set No. Samples: ¥\ J Numbers

CRL No.

SMO Traffic No.Hrs. Required

CLP Laboratory: Cp~ 0 w' < .U f f°r Review:

Following are Our findings:

.. - 3

n,r~ UUA <m~c( Sj-~~,'-l'UA , tc^ U - - / - i ^ t f / V 5 M ,

-i-v- <

tTV-r-

are acceptable for use.^7Data are acceptable for use with qualifications referenced above.

See Data Qualifier sheets and Calibration Outlier forms for flags andadditional comments.

( ) Data are preliminary - pending verification by Contractor Laboratory.See Case Summary above.

( ) Data are unacceptable.

cc: Carl a Dempsey.CLP Quality Assurance Officer, Analytical Operations BranchJames Petty, Chief Quality Assurance Research, EMSL, Las Vegas

EPA FORM lj»-i (BEV >7»|

_

PAGE 2- OF / 3DATA QUALIF IERS

Cont-actc- : C r . - . • > , . , ,-,Lj I Case / 7 L-

Belo*. is a sum-a-^ of the out-of-control audi ts and the possible e f fec t on thedata for this c a s e :

4 M' 5(Tl L-. /)I

' ~~t -r K-<_ ->

' " ' - • • i j

5 .e — i /• t/tx4 Cctl, ~L{A J - I L ^ -Cot l< *>r^± ct ri<c.

^ - U'6 /-V rJ^J'tL

<: T ^?r;^\ frx / o, g<^ ff/.-n fn »- , ^^? "i f- J

i . v v /"l/t" ^ Q ' C . - * - ^ s i-l ; u V _ i. i t .

-ft 1

LA'' 4 ^ ^7 S ^A ; - (yc7/^ 5 c. ,a AO c,

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of Ii-. . ^

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-t-Q,

C- vx 5 / L ^ / in -rr/ . r . ,

!/ '( ./ .4 ^^-^1^-. t'Vtt ^ /^ v i / ^1 ^ t-' a c^: cy

c\ J <-/ - D,- n&E-i • r f r /wi^f u,-\\u-f /-.+ I>L1 u t U ' C ^ J-^-i+isi^ -f^L. h.^.

Reviewed by: '"t'

Phone: _

Date: S

PAGE 3 OF I 5DATA QUALIFIERS

Contractor; Case

'? D If-

•* is a sum-a-y of the out-of-control audits and the possible effect on thedata for tnis case:

$i'<-~. C^ i.^'c.1 i lA* I

)c. "h

' -/- ^

,-)f^r

... t" fc

II. ~ 6 a- / ? 'j.-.. fr- S (— f'c,'

I ' -; y- > f. A C.' . 0

Reviewed by:

Phone:Date:

/>- 7?

CASE/SAS #

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION V'X CALIBRATION OUTLIERS

VOLATILE HSL COMPOUNDS

PAGE OF ]

CONTRACTOR

I ns t r umen t * oo ( cf

D A T E / T I M E :

Chl o-onetnaneBro" io^ethaneV - " v l C h l o - ' d eC n l o r o e t n a n e

|Me thy lene Ch lo r ideAcetoneCa 'Dcn m s u l f i d e1 ,1-D? chl o roethane1 , 1-0' ch l o roe theneT r a r s - l , 2 - D ' c h l o r o e t h e n eC h l o - o * o - m2-B ' j t a n onp1_,2-D' cnl o r o e t h a n e1 ,1 ,1 -Tr i ch lo roe thaneC a - D c n T e t r a c n l o - ' d eV i n y i A c e t a t e3ro~:.^* chl oro~>ethane1 ,2-D' ch1c-G"opane

| T r a " s - l , 3 - D i c h l o r o p r o p e n eT r - cr lo -oe theneD' bro-cchl oror.e tnane1 ,1 , ? - T r ^ c n l o roe tnaneB e - z e " ^ eC ' s - l , 3 - D i c h l o r o c r o p ? n e2 - C n l o " o e : n y l v iny l etherB-Q-Df ; - "i - w et~. 1 -2-De". tanoneZ - H e x a ^ o - eT e t r a c n 1 c 'oethgne1,1 ,2, 2-Tefachl oroethaneTo 1 ueneChl o -ohenzeneEthyl DenzeneS t v - e ^ em - X y eneo / p - X y l e n e

A F F E C T E DS A M P L E S :

Rev i ewe"' s /

-

Init. Ca ./i>/ryTiF

lf>(Y

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%R50

if.' -^

5

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RF XD

1

.41 V

/ •AMie> $51.) T

.

1

^fl/^iafotrvilae-rii

1

* RF t: «

1

t I

t

These flags should be applied to the analytes on the sample data sheets,

e/87

ft- P V7 70 5

CASE/SAS *

STATES ENVIRONMENTAL PROTECTION AGENCY REGION V766 S~i CALIBRATION OUTLIERS

PAGE ^OF /

VOLATILE HSL COMPOUNDSCONTRACTOR

I nst , ruT>ent * o o ( £fD A T E / T I M E :

Cn oro-ietnaneBromn-iet haneV i n y l Chl ori deCn lo roe tnaneMetnylene Cn lo r ideA c e t o n eC a - o c n Pnsu l f i ce

I ni t . Ca .Vii/W

RF

.LW

1 ,1-Di chl o roe thane \I.Hoi\ ,1-Di cnl o roe theneT r a n s - 1 ,2-D1 chl o roethene \\TYChl o ro f or~2 -B - tanone 10,0151 ,2-D1 cnl o roe tnane1,1,1 - T r i c h l o r o e t h a ^ eC a - D o n T e t r a c h l o r ' d eV i n v 1 A c e t a t e

.Vfy'39r

X R S D *

•^

Cont. C a l . Cont . C a l . Cont . C a l . Con t . C a l .

'/»i, iwi 116. v'ivRF %D • RF

,tvo|

;.iJ?

.vic

,01}

.^*7

3."3-;-' cnl oro-ethane1_,2-D'; cn lo rc"o~a~eT -a°s- l ,3 -D icn lo roDroneneTr i cn l o -oe tneneD' D-o-ocnloror .e tnane

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1 ,1 , 2 - T r i c n l c roe tnane

B e - z e - ec - s-1 , 3 -D i ch lo -o : -op?ne2-C r o " o e t n v l v i ny le ther5-O- j f c - r r ,

1

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2 - ^ ' e * 2 " l C " e ttt). jo1? .ovi i-rtf T .svflii. 71 ^T e t " a c n 1 c 'oe thenel_Jl_,2_J_2-Te* -a cnl o roe thaneT o : u e n eCn 1 o "0^en^e r eEthy l te rze ieStvenem-Xy 1 eneo / p - X y l ene

A F F E C T E DS A M P L E S :

Revi ewe*1 sIn i t ia ls /Hate: ^^Sf^^

-

t/6/fcO/i-l5Pttjtfre'Ow/a-fc

c>/vr^i '

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[//«!"!/ - t

These flags should be applied to the analytes on the sample data sheets.

fi/87

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION V^ 0 6- 16*^^ CALIBRATION OUTLIERS

PAGE OF

CASE/SAS 0VOLATILE HSL COMPOUNDS

CONTRACTOR

I -stru- ie- t *D A T E / T I M E :

Chl o"on-,e tnaneBro"io~et ha neV - r y l C n l o - i c eChl c r o e t n a n eMethy l ene C n l o " i d eA c e t o n eC a - D c n pi-! sal f i de1 ,1-D1 Chl o r o e t h a n e1 ,1 -Tn chl o -oe theneT r a n s - 1,2-D1 chl or oetheneCh 1 ore f or-2 - B ^ t a - o n p1 , 2 - D - c h l o r o e t n a n e!_,! j l -T r i chl o roe thaneC a r b c n Tet racn 1 o"deV - ' n y l A c e t a t e3"o~:- ' chl oroiethane1 j 2 - D - chl c -OD 'opa -eT r a - s - l , 3 - 0 i c h l o-oj>ropeneTn cnl o -oetne ieD is ro^och lo ro r .e tha -e1 ,1 , 2 - T r i c h l c r o e tnaneB e n z e n ec1 s-1 ,3-D' i ch lo"0"-op?ne2 - C h l o r o e t h y l v i n y l e t h e rB-O-n fc " "- - w et " , 1 -2 - D e- . tanone2 - ^ e x a - o - eTe fach l c ' oe thenel J l J 2 J 2-Te t "ach l o roe thaneT o ! ueneChl o-c t ienzeneE t hy 1 D e r. zeneStvenem-x.y 1 eneo / p - X y l ene

AFFECTEDS A M P L E S :

R e v i e w e " ' sIn i t i a l s /na te : lw >/-/ v^

Im

•2/>/Rh

ken

t. Ca

rvIRSO

•

*

Coni

RF'

0,0 /S'

.

i;f?//<;u/ftK/Ftl

.. c c'i uto

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. Cc

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s .

*

Con1

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0.*

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HF

. Cal .

%3 i *

* These flags should be applied to the analytes on the sample data sheets.

fi/87

PAGE

Gt.S;-,\ V -7/G

CASE /S AS *

UN1TEO STATES ENVIRONMENTAL PROTECTION AGENCY REGION V, -,, • -^ CALIBRATION OUTLIERSj>l~ 76t) J~~ SEMIVOLATILE HSL COMPOUNOS

OF

, ,6 J- CONTRACTOR _ (f

Inst ru"ient * 0 o\(0

D A T E ' T I M E :

Phenolb i s ( -2 -Ch l oroethyl )Ether2-Ch 1 orophr-- 11 , 3 - D i c h i o r o h e n ; e n ?1,4-Dichl orobenzeneBenzyl A lcoho l1 ,2-Dich lorobenzene2-Methy 1 phenolb i s (2 - ch l o "o i sop ropy 1 )Ether4-MethylphenolN-Ni t " O S O - O i - n - P r o p y l am- neHexach l oroetnaneN- t robenzeneIsophorone2-Ni t ropnenol2 ,4-r i imetnyl phenolBe -zc i c A c H db- s (2-Chl o 'oe thoxy )Met nane2,4-D ich lo ropheno l1 ,2 ,4 -T r i ch lo rooenzeneNaphtha l ene4-Chl o roa n - 1 " neHexach l orobutadiene4-Chloro- 3- Methyl phenol2-Methy 1 naphtha! eneH e x a c h l o - o c y d o p e n t a d i e n e2 ,^ ,6 -Tr ich lo ropne n c l2J4_ !5-T,- icnlorophenol2-Chl o ronapn tna l enet-N"; t roan- 1 - neDinethjl Ph tha la teAcenaph thy lene3-Ni troani 1 ineAcenaphthene2,4-Di nitrophenol4-N-' tropheno!Dibenzofuran

A F F E C T E OSAMPLES:

Reviewe*Init ials/Date: 7'1 - w -r/>/V/

-"

Ini 1

v*RF

^.^7

/,VJ(

,toe

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. Cc

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.

*

* These flags should be applied to the analytes on the sample data sheets. 8/87

PAGE

CASE/SAS f

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION V,-,,*% ^ CALIBRATION OUTLIEKS

[VOLATILE HSL COMPOUNDSPage 2i } rc- CONTRACTOR c U-

Instrument * c. ;• , C-D A T E / T l M t :

2,4-Dirntrotoluene2.6-DinnrotolueneDiethylpnthalate4 -Chl orophen_yl-phenyl etherFl uo'ene4-Ni t noa^1 1 1 ne4j6-P^ nnro- 2-Methy 1 phenolN-fp t rosod ipneny l a^i ne4-p To-1 DphenyJ-phenvl etherh e x a r h l o~obe rzeneP e " t 3 c h l o*"0phenolPneijnth-eneAnt n-a:eneD~ -n-B-t v l p~*. re I a teFl u:-a-t > . t f - . < rP y - e n eB ^ t y ^ e " ? \ ^ p ' - t h a l a t eB e n z o ; a A n t h r a c e n eb - s ( ? - E t h v ' h e x y l ) P n t h a ! a r eL> - v s e r r[>- _ r , -C' : t vl Pht hsl ateB e ' r c . r '' F i uC 'antne 'es e r z c . * ^ luO"e r the".eB r ' 2 C c ' - v - e ' . r

I r "f " : I ,? ? - c c ^ - y re^eL" De r 2 a , " ' -n- r -a :e "eB e ' 2 : ' c , n . - > c.:-, ^ e - c

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SEE PAGE 1 FOK AFFECTED SAMPLES.

These flag"; s ho-lc be applied to the analytes on the sample data sheets,

Rev;ewe"'s Initials/Date:8/67

P^PV^/7c

CASE/SAS #

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS

SEMIVOLATILE HSL COMPOUNDS(Page 1)

(e "1_ CONTRACTOR (: ? „ - ,

PAGE OF

Instrument * Ooj- (DATE 'TIME :

Phenolb-.s(-2-Chloroethyl )Ether2-Chlorop*cT i1 ,3-Oich torohe'ze^e1,4-Dichl orobenzeneBenzvl Alcohol1 ,2-bichloroben2ene2-Methy 1 phenolbi s(2-ch loroisopropyl )Ether4-Methyl phenolN-N-. troso-D-i-n-PropylamineHexachl oroethaneN-itrobenzeneIsopho-one2-NUrophenol2 4-rM methyl p he~olBenzoi c Ac i db^si. 2-Chl o"oethoxy)Me thane2 ,4-Di chl orophenol1,2,4-Tricnl orobenzeneNaphtha 1 ene4-Chl OToani 1 i neHexachl o-ooutadiene4-Chl o "0-3- Methyl phenol2-Methy 1 naphthal eneHexachl orocyclopentadi ene2, 4, 6-Tr-! chl orophenol2,4,5-Tricnl orophenol2-ChloTonaphthalene2-N i troan- } • neDimethyl PhtnalateAcenaphthy 1 ene3-Ni troan-' 1 1 neAcenaphthene2,4-Di nnrophenol4-Ni trophenolDibenzofuran

AFFECTEDSAMPLES:

Reviewe- ^-/Initials/Date: "ty (^J ^ A/V

miK/£

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li

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These flags should be applied to the analytes on the sample data sheets, 8/87

PAGE OF

C A S E / S A S *

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLlEKS

u SEM3VOLAT1LE HSL COMPOUNDS, ^,, P«9e 2

CONTRACTOR Co-

Instrument * <>«>.(D A T E / T I M E :

?j4-Dini t rDtol uene2,6-DTn t roto l ueneDiethylphthatate4-Chlorophenyl-phenyletherFluo-ene4-M 1 -oar-"! i np4j_6-r>i nnro- 2-Methy IphenolN-N->t rosodipheny 1 a™ ne4-B-om?phenyl-phenvletnerh e x a c h l c-p;>e r.zenePe- tacHo-opneno lPnenanth-eneArt h-a:eneD- -n -B - t v l cK* .n = } e:eFT u : -a - t ' , e - .< rP v -eneB- i t y lne-zy " p^ the l ateBe- 'Zo ! a ' A n t n - a c e n eb - s ! ? - E t h y l h e x y l J P n t h a l a T pLr ~ v se r t -n-.r._(i :» vi pn tha la teB e ' : o ' r ^ F 1 u o - a -.t n e n eBe r. z P ., « ' r 1 u o " a r t he neBt r 2 J e '. r v "e-'r

Ir"f :• 1 ,2 , 3- cc 1 - y~eneL' De r 2 a ,r • -- t n -a :eneB e ' 2 ? 'c ,h . - ' C-.; - \ ' P - C

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SEE PAH 1 FOr; A F F E C T E D SAMPLES.

* Tnese flag* s KD-la be appVIed to the analytes on the sample data sheets.

- ' s I n i t i a l s / D a t e :8/67

70

CASE/SAS

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS[VOLATILE HSL COMPOUNDS

(Page 1)CONTRACTOR fi i) v

PAGEJj_ OF

Instrument * OO ( S~~

D A T E n I ME :

Phenolb is ( -2 -Ch lo roe thy l )Ether2-Cnl ororhr-.ril ,3 -D ich io roben2e n e1 ,4-Dichl o robe nz eneBenzv l A lcoho l1,2-Dicn lorobenzene2-Methy 1 phenolbi s ( 2 - c h l o-oisopropyl }Ether4 -Methyl phenolN-Ni t roso-Di -n-P ropy 1 am-i neHexach l oroethaneN i t robenzeneI sopho-one2-N^ t rojT'henol2 , 4 - D i m e t h y l p h e n o l

B e n z o i c A c i db ' s ( 2 - C h l o . - o e t h o x y ) Me thane2 ,4-Dichl orophenol1 ,2 ,4-Tr ich l orobenzeneNaphtha lene4-Chl oroani 1 i neH e x a c h l o -obutad iene4-Ch lo ro- 3 -Methyl phenol2-Methy 1 naph tha leneH e x a c h l o - o c v c l o pentad -ene2, 4 ^ 6 - T r i chl pro phenol2 ,4 J 5-Tr icn l oTophenol2-Chl o ronaphtna l eneZ-N- t roan -T - neDinethyl Pntna la teAcenaphthy lene3-Ni troam 1 ineAcenaphthene2,4-Qi n-i trophenol4-Ni trophenolDibenzofuran

A F F E C T E DSAMPLES:

ReviewerInit ials/Date: ^ r/ Ws-v

Ini t . Cal .</faRF

f.rtt

/.fcrs

.fc>0

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l.^to

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11

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* These flags should be applied to the analytes on the sample data sheets, 8/87

PAGE l>- OF

C A S E / S A S

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION V~u*t- 7//01 CALIBRATION OUTLlEKS•Jlr /w» • SEMIVOLATILE HSL COMPOUNDS

Page 2' ~\ TL- V CONTRACTOR Cc ^ f^ U

Instrument $ c - I ^DATE / T l Mt :

2_,4-D^nitrotoluene2,6-D' innrotolueneDiethy\p_nthalate4-CMoropnenyl-phenvletherFl uo~eneC-Ni \ rpa1^ 1 •> np

4 ,6-D1 n- t -o-2-Methy 1 phenolN-N1 1 rosodi phpny 1 ami ne4 _ B -omophenyl-p hen vl etnerhe x a c h! p-pbe r 'ZpnePe' tac ' - lorophenolPnena^th-eneAnt hra:eneD ' - n - B ^ t v r " t r 2 l e t eFl j : -a"V e' - rp v - e n e5 ^ t y l b e " 2 ^ 1 pht hal a teBe-'zo '. a ^nt h-a:eneb- s : 2 - E t h y l n e x v l ) P n t h a ! a t eL> ' v se r r

r>--r , -Ci ;* . vl Ph tha le teB e ' 2 0 .. : '? 1 uc -en tne -eB e r z o , k i' u o r a " t h e r e

Init. Ca! ./ / A

Rh/

I.KJbBe- 2; c ' - v - e ' rI r " f " j 1 , 2 , 3 - c c i ' y - e h f | /,•»)'L ' D e r 2 a , r - ' " i t h " a c e ' - e -7t?B e ' r r ' c , h . ~ D - : ' \ ' e " c ,v/o

j.y/x7IRSD *

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SEE PA:,E i FOK A F F E C T E D SAMPLES.

* These flag< s Ko-la be a^p'ied to the analytes on the sample data sheets,

Rev'ewe-'s Initial s/Date: 7/CAj l^( Yy8 / 6 -

CASE/SAS *

PAGEj_UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION V

CALIBRATION OUTLIERS ^ 0 L-^ 7C ~J-SEMI VOLATILE HSL COMPOUNDS p |3 p 7 7C-

. n _ . (Page 1)| ') C- L- CONTRACTOR

OF '

,tL

Instrument * Ooo 2.D A T E / T I M E :

Phenolb i s ' - 2 -Ch ]o^oe thy l )Ether2-Chlororh--nr ll ,3 -D ich iorohen2e r i e1 ,4-Di chl orobenzeneBenzyl A l c o h o l1 ,2-bi ch lo robenzene2- Methy l phenolbi s ( 2 - c h loroi sopropyl ) Ether4 -Me thy! phenolN-Ni t roso-Oi-n-Propy l amineHexachl o roe thaneNi t robenzene1 sophorone2-Ni t ropnenol2 ,4-rumethy 1 phenolB e ~ z c i c A c i db i s ( 2 - C h l o T o e t h o x v ) Me thane2 ,4-Di cnl orophenol1, 2, 4-Tr i cnl orobenzeneNaphtha l ene4-Chl oroa°i 1 " neHexach lo robu tad- iene4-Chl or o-3- Methyl phenol2-MethylnaphtnaleneH e x a c h l o - o c y d o p e n t a d - ' e n e2, £ ,6-Tri chl orophenol^j^jS-Tri cnl orophenol2-Chl o ronapn tna l ene2-Nuroan- 1 - neDimethyl Ph tha la teAcenaphthy 1 ene3-M troani 1 ineAcenaphthene2,4-Di ni trophenol4-Ni trophenolDi benzofuran

A F F E C T E DSAMPLES:

Reviewe- / ,Initials/Date: 7)uJ V T1^

( • / / •

Ini t . Cal .IfaRF

.^-^

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Cont. Cal .J/i7 ^RF

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RF 1 W *

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RF

i

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i

11

These flags should be applied to the analytes on the sample data sheets. 8/87

PAGE ( f OF

CASE/SAS *

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTL1EKS

SEMI VOLATILE HSL COMPOUNDS

i i ', • p*9e 2 r\ V' <-••>•- CONTRACTOR t '-"- 0 .

Jns t rumpnt * CG -' )-D A T E / T I M t :

2j4-Difli t roto! uene2,6-D - 'n ' ' t roto lueneDiethyl_p_h thai ate4-Chl orophenyl-phenyl etherFl uo-eie4-N-. t rpa^i 1 1 np^fr-p-i iv t ro-2-Methylj>henolN-Ni t rosoSiphenyl a1""' ne4-Bromophenyl -phe^v le tnerh e « a c r. 1 c -o^enzenePe~t a c ^ l o-ophenplPhenanth-eneAnt h-a:eneD' -n-Bat v 1 rnfal e teF l u : - a - t » . e ' . e 1P y - e n eB ^ t y l b e - z v ' p n t h a l a t eB e n z o : & ( i n thTa :enet r s : 2 - E t * v l h e x v l ) P n t h a l a reL " » - - v s e ' rr>-.r,-v-i:t vl Put hamateB ? ' 2 C . ' : ' F 1 u o - e n t n e n eBe " z c . k 'F 1 uo -a^ theneBr r 2 C e ' F y - e n e

i r"f :• ! _ , ? . 3 - c c ' ! ' yTenej' oe r 2 a ,r ' i-t n - a c e n eB r ' Z P ' c , h . - ' C.:. -, le - c

Inn

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.

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ID

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*

SEE PA>I 1 FOH AFFECTED SAMPLES.

These flag^ s Ko-lc be applied to the analytes on the sample data sheets.

Rev'ewe-'s I n i t i a l s/Date: r/

Contractor: 0 ,• -v, r>± r-U-~- v.

TENTATIVELY IDENTIFIED COMPOUNDSHATCH ASSESSMENT

HOTt: leviewer should note direct!/ en Organic Analysis Data Sheet (OADS).those matches that 1n his opinion (based on contract criteria) ireunreasonable.

CRITERIA

(1) Relative intensities of aujor Ions (>10l) reference spectrumshould be present In the sample spectrum.

(2) Relative Intensities of aajor Ions 1n sample spectrum shouldagree to within 201 of reference spectra Intensities.

(3) Molecular Ions present 1n reference spectrum should be presenttn sample spectrum.

(4) Ions present 1n sample spectrum, but not 1n reference spectrumshould be reviewed for possible background contamination orpresence of coelutlng Interferences.

(5) Ions present 1n reference spectrum, but not in the samplespectrum should be reviewed for possible Subtraction from thesample spectrum because of background contamination or coelut-lng Interferences. •"

(6) If, 1n the reviewer's opinion, no valid Identification canbe made the compound should be labelled as 'unknown' and theInitials and date of the reviewer placed on the OADS.

V

r/w / - ;J --

UNITED S T A G E S ENVIRONMENTAL P R O T E C T I O N A G E N C YREGION V

S . 5 J E C T - . Revev. c f R e g i o n v CL D DataR e c e i v e d f o r Review on

C u r t i s R c s s , Di rec to - ( 5 S C R L !Ce n t r a l R e g i o n a l Labora to ry

c -

D a t a Use - : ." - -" - ,••'

£ , - rev iew: t - e d a t a for t he f o l l o w i n g c a s e j s ) .

Set No.No. ofSamples:

70

c a s e No. °l 2.C 2-D . U . / A c t i v i t y

Numbers

N o .

CL? L a b o r a t o r y ; -T;yt-mA>n

F o l l o w i n g a re our f i n c i - g s :

,H^Sec^'/tk-^

J

Hrs. Requi redfor R e v i e w : _ /_[_

j_L

( ) Data are acceptable for use.( ") Data are acceptable for use with qualifications noted above.( ) Data are preliminary - pending verification by Contractor Laboratory.( ) Data are unacceptable.

cc: Duane Geuder, Quality Assurance Officer, EPA Support ServicesJames Petty, Chief Quality Assurance Research, EMSL, Las Vegas

EPA FORM 1320-6 (Rev. 5/87;

PAGE -z OF ^

DATA QUALIFIERS PJf 4^7 Q

/• -,Cont rac to r : Ri'tf'nVy. £bA^o | C a s e / '~i2.e <LJ

Below is a summary of the out-of-control audits and the possible e f fect on the

data for this case:

AH £' y- - . j /'H-v.y . . a

d tVy, , «^Jo I H

.vr\,y..'^f< CA ,

-

\\r-~^- C <£.*>• + /C^ - V- t C . <^v^~v,J. \cr0 /^,V u o L . ' c U »i N)c*-,V.clv,,U

Ox

• o

CAl, /,rA ^

cld^c ' AV3 <-^A'^v>A V 6. < >lA Q-g^ -ce4fccj-^- - -^M

<jv JJ

A-1 tJet-tLoMloly. )<^ol^ C jU

r

^-' X f^.Ar- ^r^ fL^ bi<^i rf ,

Reviewed by: «

Phone: .''3/^) 353 -

Date: '4 -1>1 '& B

PAGE 3 OFDATA QUALIFIERS

C o n t r a c t o r : |4< 2, I Case

Below is a summary of the out-of-control audits and the possible e f fec t on thedata for this case:

JV^ '/ ^ I.'

• A A- .

"M > A f l h* A o j r-. t-Ji C

0)1- Jr> X

•. £ I ^3 ^ l /. 2- _t«y

it, ,-ccc^cr-e,:, Vc/- jfj'

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Mv,t<--\ /\/fl/A.t-.l<

f t h.iru WA!>>». ( / c /v^«^

UMJlKv O >

id-

Reviewed by:

Phone:

Date:

z.) 3^3 - t Y T

PAGE V OF 7.

DATA QUALIFIERS

4 70Cont rac to r : |^.'ft yvwrv-v £-oA3^ I Case l^^c

Below is a summary of the out-of-control audits and the possible e f fec t on thedata for this case :

i f /vt

TW-

/ ),u. , -j- .fev" -fr-«— . c < - ^ ' l . g

aa^A \

yVi i tA

x i l < - ^ . , /< Oh>j xc, i •<_ . '-' .V.H^^. fv^Su / t.^ f& ,-' fj^ 'h?//Cc^.U|d

I r. c i' "v\ ojV)^w<, , 'JiC.L^o t^eVyiAvtg. . V ' ^ v l -1-U i w > " "*«£., C-hJ o. g «-' ^ vt'd.<_ i Acfc|-c>)a^ A<.r\j j o i-\ i V r » l <a_ , Ac.ru J^ .K Tr .'

J. ,'- D-£h lore• ™^™

CO A-S tJSh.VKAf^j ,Vr, A r - tCTK, - dc f ec f

fr^-

i i i'

T"C L.

M x <-

v.^^va

^ tVv^ t-i ft.

*CVX cL J. 'lu f.

Reviewed by:

Phone: Git-l 3S3 -

Date: V~ 2,1

PAGE _£ OF %DATA QUALIFIERS

Contractor :\

Below is a summary of the out-of-control audits and the possible effect on thedata for this case:

^

, /" n ~b 1 c.,

>

Reviewed by:

Phone: (3/2JDate: ^ - Z'

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS

, _ VOLATILE HSL COMPOUNDSCASE/SAS f iicL/32')£t CONTRACTOR M

OF «2

Instrument * -$-CD A T E / T I M E :

Chl orometnaneBromomethaneV i n y l C h l o r - d eChloroetnaneMethylene Ch lor ideA c e t o n eCarbon rnsul f - lde1,1-Dicr . loroetnane1^1-Dichl oroetheneTrans-1 ,2-Dichloroethene 1Chl o~of orm?-6utancnpIj2-Di chl oroethane1 ,1 f l -T r i chl oroethaneCarbo n Te t racH o-ideV i n y l A c e t a t eBro~ D: chl o romethane]^2-r-'chlorop-opaneTrans-1 ,3-Dichl oropropeneTri chl oroetheneD-'bromochl oromethanel_,l j2-T-ichloroethaneBenzeneC" s-1 ,3-Dichloroproppne2-Ch l oroethvl v* nyl etherB-0"?fG-r

C-ye thv l -2 -Pe r . t anone2-HeA.ano- .eTet -ach 1 oroethene1,1 , 2, 2 -Te t rac hi oroethaneTo lueneChl o-obenzeneE t nyl D e r. z e n eStv renein- Xy 1 e r eo /p -Xy lene

A F F E C T E DSAMPLES:

Rev i ewe~ ' iIni t ia ls / D a t e : ^,\/. ^'1VW

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>J(3O

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* These flags should be applied to the analytes on the sample data sheets.

8/87

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION VCALIBRATION OUTLIERS

VOLATILE HSL COMPOUNDS

PAGE_L OF A.

CASE/SAS * cjL 2 7 L CONTRACTOR ///--"

Ins t rument *D A T E ' T I M E :

Chl oromethaneBromomet hane

.Vinyl Ch lo r i deChloroethaneMethyl ene Ch lo - i deAcetoneCa-bo- R i s u l f i d e1 ,1-Dichloroetnane1 , l -P-> chl oroetheneTrans- l ,? -D ic h l o roe theneChl ? TO fo rm?-Butano n P1 ,2-D- Ch loroethane1 ,1 , 1 -Tr i chl oroethaneCarbo p Tet -acr l o-ideV i n y l A c e t a t eBrc~:.- ;cnl oromethanel_,2-r ;-chl o-op-op_areTrans- l ,3 -D ich lo ropropeneTri chl oroetheneDibromochlo-ometnane1 ,1 ,2-T- ich loroethaneBe-zenec ; s - I , 3 - D * c h l o - o p - o p p n e2-Chl o ' oe thy l v i nylethe rB-o-- f c - ~4 - M e t * - > l - 2 - P e r t a n o - . e2 - H e * a n o - eT e t - a c h l oroethenelJ !J2J2-Tet-ac hi oroethaneT o " ueneCnl o "Cbe r ' ZeneE t h y T oe-.zeneStyre r em-Xy 1 ene0 /P -Xy lene

A F F E C T E DSAMPLES:

R e v ^ e w e " ' s ^In i t ia ls / D a t e : -J*^ ^'^ •${

Imi^-23Rh

. .t.V')

fctrtf

VtK

t'J

IT 3

lf.r

f^ -

- ^ '

.. Ca-3b '%RSO

Sl-tf\

^J" 2^

rtlA^H.-2'l •?

-219•Z1^!20 b /-

•zOj, /^2 9 6

•

<<£?*

j

i

7_

<"t"

VS

SA

Coni

Hh

.. C<

to

)l.i

Com

HI-

.. Cc

ID

) .

*

Cont

RF

.. C<

ID

) .

*

Cont

Rh

. Cc

%D 4

I

I

I

I

I

!

* These flags should be applied to the analytes on the sample data sheets,

e/87

Case: JcO 2.

Contractor: H

TENTATIVELY IDENTIFIED COMPOUNDSHATCH ASSESSMENT

iOTE: levlewe- should note direct!/ an Organic Ana7/$1s Data Sheet (OAOS).those matches that 1n his opinion (based on contract criteria) areunreasonable.

CRITERIA

(1) Relative Intensities of aujor Ions (>10l) reference spectrumshould be present 1n the sample spectrum.

(2) Relative Intensities of major ions 1n sample spectrum shouldagree to within *; 201 of reference spectrum Intensities.

(3) Molecular Ions present In reference spectrum should be present<n sarrp'e spectrum.

(4) Ions p-esent In sample spectrum, but not 1n reference spectrut.should be reviewed for possible background contamination orpresence of coelutlng Interferences.

(5) Ions present 1n reference spectrum, but not In the samplespectrum should be reviewed for possible subtraction from thesample spectrum because of background contamination or coelut-lng Interferences. •'

(6) If, <n the reviewer's opinion, no valid Identification canbe made the compound should be labelled as "unknown* and theInitials and date of the reviewer placed on the OADS.