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Demonstrating Geological Carbon Demonstrating Geological Carbon Sequestration in the Mt. Simon Sandstone Sequestration in the Mt. Simon Sandstone
of the Illinois Basinof the Illinois Basinpresented bypresented by
Robert J. FinleyRobert J. FinleyIllinois State Geological SurveyIllinois State Geological Survey
March 6, 2008March 6, 2008Indiana Center for CoalIndiana Center for CoalTechnology ResearchTechnology Research
Midwest Geological Midwest Geological Sequestration ConsortiumSequestration Consortium
www.sequestration.orgwww.sequestration.org
Descriptor - include initials /org#/date
Field Validation Tests and Large-Scale Deployment Tests
24
Large scale
Phase II
Phase III
What are we doing?What are we doing?
A collaboration of ADM, the Midwest A collaboration of ADM, the Midwest Geological Sequestration Consortium, Geological Sequestration Consortium, Schlumberger Carbon Services, and other Schlumberger Carbon Services, and other subcontractors plans to inject 1 million subcontractors plans to inject 1 million metric tons of carbon dioxide at a depth of metric tons of carbon dioxide at a depth of 7,500 +/7,500 +/-- ft to test ft to test geological carbon geological carbon sequestrationsequestration
Why are we doing this?Why are we doing this?
Global climate change:Global climate change: role of increased role of increased concentration of manconcentration of man--made greenhouse gases, made greenhouse gases, primarily carbon dioxide (COprimarily carbon dioxide (CO22), ), Carbon management strategies:Carbon management strategies: return of COreturn of CO22derived from fossil fuel use to subsurface derived from fossil fuel use to subsurface reservoirs: reservoirs: geological carbon sequestrationgeological carbon sequestrationLargeLarge--scale testing:scale testing: necessary to verify that necessary to verify that sequestration is safe and effective, as we expect sequestration is safe and effective, as we expect it to beit to be
Who are the players?Who are the players?The Illinois State Geological Survey (ISGS) leads The Illinois State Geological Survey (ISGS) leads a research consortium of the Illinois, Indiana, and a research consortium of the Illinois, Indiana, and Kentucky geological surveys (Kentucky geological surveys (Midwest Geological Midwest Geological Sequestration ConsortiumSequestration Consortium), in place since 2003, ), in place since 2003, to assess the geological carbon sequestration to assess the geological carbon sequestration potential of the Illinois Basinpotential of the Illinois BasinNational Energy Technology Laboratory, Office of National Energy Technology Laboratory, Office of Fossil Energy, leads for the Fossil Energy, leads for the U.S. Department of U.S. Department of EnergyEnergySchlumberger Carbon ServicesSchlumberger Carbon Services provides worldprovides world--class innovative technologies for subsurface class innovative technologies for subsurface reservoir characterization and monitoring reservoir characterization and monitoring
How did we get to this point?How did we get to this point?
ISGS work from 2003ISGS work from 2003--05 showed high potential in 05 showed high potential in the the Illinois BasinIllinois Basin for geological carbon for geological carbon sequestrationsequestrationSmallSmall--scale COscale CO2 2 injection tests underway, 2005injection tests underway, 2005--09, mostly in oil fields09, mostly in oil fieldsDOE desired largeDOE desired large--scale testing to begin before scale testing to begin before 2009; required major source of CO2009; required major source of CO22 and a and a suitable site in close proximitysuitable site in close proximityDiscussions with ADM began in December 06Discussions with ADM began in December 06Proposal submitted May 07; funded December 07Proposal submitted May 07; funded December 07
Illinois BasinIllinois Basin
NN--S Cross Section of CoalS Cross Section of Coal--bearing Strata in Illinoisbearing Strata in Illinois
By Christopher Korose, Jamie McBeth, and Colin Treworgy, ISGS
Mt. Simon SandstoneEau Claire Shale
Illinois Basin Stratigraphic
ColumnMaquoketa Shale
New Albany Shale
Mississippian sandstone and carbonate oil reservoirs
St. Peter Sandstone
Pennsylvanian coal seams
from Leetaru, 2004
Illinois Basin Stratigraphic Column
Sequestration CapacitiesSequestration Capacities**
Seven major coal seams: 2.3Seven major coal seams: 2.3--3.3 billion tonnes3.3 billion tonnes6.7 trillion ft6.7 trillion ft3 3 incremental methane(?)incremental methane(?)
Mature oil reservoirs: 140Mature oil reservoirs: 140--440 million tonnes440 million tonnes860860--1,300 million barrels incremental oil1,300 million barrels incremental oil
St. Peter Sandstone: 1.6St. Peter Sandstone: 1.6--6.4 billion tonnes6.4 billion tonnesMt. Simon SandstoneMt. Simon Sandstone: : 2727--109 billion109 billion tonnestonnes
*DOE, 2007, Carbon Sequestration Atlasof the United States and Canada
Mt. Simon Sandstone Mt. Simon Sandstone ReservoirReservoir
4,143 ft
8,467 ft
• Mt. Simon Sandstone is used for natural gas storage in Champaign County, IL at 4,000 to 4,200 ft
• Mt. Simon core has been recovered from a few deep exploration wells
A Model for Mt. Simon Sandstone A Model for Mt. Simon Sandstone Deposition: Alluvial Fans in Death ValleyDeposition: Alluvial Fans in Death Valley
From Leetaru, 2008
ADM GeophysicsADM Geophysics
SITE
October 07
N
ADM Test SiteADM Test Site
AA Dehydration/ Dehydration/ compression compression facility locationfacility locationBB Pipeline routePipeline routeCC Injection well Injection well sitesiteDD Potential Potential verification well verification well sitessitesFF Anaerobic Anaerobic wastewater wastewater treatment facilitytreatment facility
F
~ 3/4 mile
A
B
C
D
D
Sand grain
Pore space
CO2 Storage in Sandstone Reservoir Pore Space
Pin head
Reservoir Caprock (shale seal)Reservoir Caprock (shale seal)
Pin head
Plume Monitoring StrategiesPlume Monitoring StrategiesPosition of COPosition of CO22 plume based on repeat surface plume based on repeat surface and downhole geophysics similar to Sleipner and downhole geophysics similar to Sleipner project in Norway and Frio Brine Pilot near project in Norway and Frio Brine Pilot near HoustonHouston
1994 1995 2001
Sleipner 4D Geophysics
Frio Brine Pilot
Daley et al, 2007CO2 response
Simulation of COSimulation of CO22 injection into Mt. Simon at ADM Siteinjection into Mt. Simon at ADM Site
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50
Gas saturation
1,700
68
440
68
3.6
220
7.0
210
Permeability
7000
7200
7400
7600
7800
8000
8200
1/3 million tonnes/yr for 3years, 1 yr of injection
1/3 million tonnes/yr for 3years, 2 yrs of injection
1/3 million tonnes/yr for 3years, 3 yrs of injection
10 years shut in after3 yrs of injection
100 years shut in after3 yrs of injection
Sonic porosity
Dept
h
Injection well Injection well Injection well Injection wellInjection well
Weaber–Horn (Loudon)
High Perm Layer (8) Injection Only
o 0.05 0.1 0.15 0.2 0.25
500 ft
Surface Surface Monitoring of Monitoring of Air and Soil Air and Soil
for COfor CO22
UGA Laboratory for Environmental Physics
IR Gas Analyzer
Sonic anemometer
from Oldenburg, LBNL
Groundwater and CO2 flow and transport
Shallow Groundwater MonitoringShallow Groundwater Monitoring
Wells drilled andperiodically
sampled
Preliminary COPreliminary CO22 Process Flow DiagramProcess Flow Diagramfor ADM Sitefor ADM Site
InputWet at 14.5 psia
OutputDry at ~1,300-1,500 psia
from Trimeric Corporation
What are the project outcomes?What are the project outcomes?
A largeA large--scale scale injection of 1 million tons of COinjection of 1 million tons of CO22successfully demonstrated and associated safety, successfully demonstrated and associated safety, efficiency, and effectiveness requirements metefficiency, and effectiveness requirements metVolume Volume sufficient to monitor geophysically;sufficient to monitor geophysically;dehydration/compression equipment scalable to IGCCdehydration/compression equipment scalable to IGCCA A process model establishedprocess model established for equipment, permitting, for equipment, permitting, injection, environmental monitoring, and outcome injection, environmental monitoring, and outcome assessment that will support energy facility assessment that will support energy facility development with integrated carbon sequestration in development with integrated carbon sequestration in the Illinois Basin, nationally, and globallythe Illinois Basin, nationally, and globallyAn An ““activeactive”” geological site modelgeological site model developed and developed and continually updated as new data are acquiredcontinually updated as new data are acquired
What is the project schedule?What is the project schedule?■■ The project was funded December 18, 2007The project was funded December 18, 2007
■■ Baseline environmental activities to begin spring 08Baseline environmental activities to begin spring 08
■■ Preliminary UIC permit planned for May 08Preliminary UIC permit planned for May 08
■■ Injection well drilling: start June 08; ~68 days to drillInjection well drilling: start June 08; ~68 days to drill
■■ UIC Completion Report based on well dataUIC Completion Report based on well data
■■ Final functional testing of compression, pipeline, and Final functional testing of compression, pipeline, and wellhead initiated in fall 09wellhead initiated in fall 09
■■ Injection would occur from December 2009 Injection would occur from December 2009 –– December December 20122012
■■ Verification wells would be drilled ~winter 2011 and Verification wells would be drilled ~winter 2011 and ~summer 2012 (if second well funded)~summer 2012 (if second well funded)
■■ Environmental monitoring through December 2014Environmental monitoring through December 2014
24
Schlumberger Private
Schlumberger Carbon Services
Commercial Scale Storage Timeline with Cost & Uncertainty
Performance & Risk(Functions) Capacity, Injectivity, Containment >>>> (Stakes) HSE, Cost, Image
Uncertainty
Possible site Probable site Appoved site
Time
Tota
l cos
t & u
ncer
tain
ty
1 yr 2-3 yrs 5-7yrs
High
Low
Prelim.study
30 yrs
Total cost
ConstructionIncludes time
for plant construction
ConstructionIncludes time
for plant construction
Detailedcharacterization
Detailedcharacterization
Data acquisition
Data acquisition
Authorization
DesignDesign
Model driven Monitoringplan
Monitoringplan
50 yrs 100+
$5-$10 / ton
Closure
Equalization
Long termEnvironmentalmonitoring
Long termEnvironmentalmonitoring
Living model
Prediction
Model update
Injection &monitoring
Injection &monitoring
25
Schlumberger Private
Schlumberger Carbon Services
Commercial Scale Storage Timeline with Cost & Uncertaintyand Cost Estimates for Site Selection and Development
Performance & Risk(Functions) Capacity, Injectivity, Containment >>>> (Stakes) HSE, Cost, Image
Uncertainty
Possible site Probable site Appoved site
Time
Tota
l cos
t & u
ncer
tain
ty
1 yr 2-3 yrs 5-7yrs
High
Low
Prelim.study
30 yrs
Total cost
ConstructionIncludes time
for plant construction
ConstructionIncludes time
for plant construction
Detailedcharacterization
Detailedcharacterization
Data acquisition
Data acquisition
Authorization
DesignDesign
Model driven Monitoringplan
Monitoringplan
50 yrs 100+
$5-$10 / ton
Closure
Equalization
Long termEnvironmentalmonitoring
Long termEnvironmentalmonitoring
Living model
Prediction
Model update
Injection &monitoring
Injection &monitoring
$14-22 million
26
Schlumberger Private
Schlumberger Carbon Services
Commercial Scale Storage Timeline with Cost & Uncertaintyand Cost Estimates for Site Selection and Development
Performance & Risk(Functions) Capacity, Injectivity, Containment >>>> (Stakes) HSE, Cost, Image
Uncertainty
Possible site Probable site Appoved site
Time
Tota
l cos
t & u
ncer
tain
ty
1 yr 2-3 yrs 5-7yrs
High
Low
Prelim.study
30 yrs
Total cost
ConstructionIncludes time
for plant construction
ConstructionIncludes time
for plant construction
Detailedcharacterization
Detailedcharacterization
Data acquisition
Data acquisition
Authorization
DesignDesign
Model driven Monitoringplan
Monitoringplan
50 yrs 100+
$5-$10 / ton
Closure
Equalization
Long termEnvironmentalmonitoring
Long termEnvironmentalmonitoring
Living model
Prediction
Model update
Injection &monitoring
Injection &monitoring
$14-22 million
2 Wells and MonitoringSetup - Two Year Effort$15-20 million
27
Schlumberger Private
Schlumberger Carbon Services
Commercial Scale Storage Timeline with Cost & Uncertaintyand Cost Estimates for Site Selection and Development
Performance & Risk(Functions) Capacity, Injectivity, Containment >>>> (Stakes) HSE, Cost, Image
Uncertainty
Possible site Probable site Appoved site
Time
Tota
l cos
t & u
ncer
tain
ty
1 yr 2-3 yrs 5-7yrs
High
Low
Prelim.study
30 yrs
Total cost
ConstructionIncludes time
for plant construction
ConstructionIncludes time
for plant construction
Detailedcharacterization
Detailedcharacterization
Data acquisition
Data acquisition
Authorization
DesignDesign
Model driven Monitoringplan
Monitoringplan
50 yrs 100+
$5-$10 / ton
Closure
Equalization
Long termEnvironmentalmonitoring
Long termEnvironmentalmonitoring
Living model
Prediction
Model update
Injection &monitoring
Injection &monitoring
$14-22 million
2 Wells and MonitoringSetup - Two Year Effort$15-20 million
Early Monitoring$1.5-4 million/yr
Midwest GeologicalMidwest GeologicalSequestration ConsortiumSequestration Consortiumwww.sequestration.orgwww.sequestration.org
Midwest Midwest Regional Regional Carbon Carbon
Sequestration Sequestration PartnershipPartnership
The three The three MRCSPMRCSP’’ss Phase II tests evaluate geologic regionsPhase II tests evaluate geologic regions
Appalachian BasinAppalachian Basin
Cincinnati ArchCincinnati Arch
Michigan BasinMichigan Basin
Appalachian Basin Site Appalachian Basin Site –– FirstEnergyFirstEnergy
PowerspanPowerspan ECO ECO Pilot PlantPilot Plant
R. E. Burger Power PlantDepth (ft bgs)
0
1,000
2,000
3,000
4,000
5,000
6,000
7,000
8,000
9,000
10,000
11,000
12,000
13,000
Injection TestWell
Power Plant
Storage Formation
Seismic Survey, July 2006
8000 Foot Test Well, January, 2007
0
1,000
2,000
3,000
4,000
5,000
6,000
7,000
8,000
9,000
10,000
Depth (ft bgs)
Injection TestWell
Antrim Gas Well
Monitoring Well
Niagara EOR WellsCO Pipeline2Gas Processing Plant
Target Storage Formation
Michigan Basin Site
5000 Foot Deep Test WellNovember 2006
Existing EOR Infrastructure
Saline Injection Target
Cincinnati Arch Site Cincinnati Arch Site –– Duke EnergyDuke Energy
East Bend StationEast Bend Station
Injection Target, Mt. Simon
Seismic SurveyOctober, 2006
Test WellFall 2007
Experience with MRCSP and other projects has demonstrated Experience with MRCSP and other projects has demonstrated the value of site specific data from test wells.the value of site specific data from test wells.
COCO22 Storage Modeling ProcessStorage Modeling ProcessConceptualizeConceptualize--characterizecharacterize--DesignDesign--MonitorMonitor--CalibrateCalibrate--validatevalidate
Preliminary Modeling Based on Regional Data
Site Drilling and Testing Site Specific Modeling
Example‐MRCSP Michigan Basin State‐Charlton 30/31 Field Test Site
MMV is an MMV is an important part of important part of all field projects.all field projects.
Monitoring, Measuring and Verification (MMV)Monitoring, Measuring and Verification (MMV)
Depth (ft bgs)
0
1,000
2,000
3,000
4,000
Storage Formation
Injection TestWell
Depth (ft bgs)
0
1,000
2,000
3,000
4,000
Storage Formation
Depth (ft bgs)
0
1,000
2,000
3,000
4,000
Storage Formation
Injection TestWell
Na
Ca K
90
10
90
80
20
80
70
30
70
60
40
60
50
50
50
40
60
40
30
70
30
20
80
20
10
90
10
Brine Chemistry andFluid Sampling
Wireline, Coring and Mechanical Integrity
System Monitoring
3650
3700
3750
3800
3850
3900
3950
0 20 40 60 80 100
Time (Days)
Pres
sure
(PSI
)
0
20
40
60
80
100
120
140
Tem
pera
ture
(*F)
Multi‐level Monitoring
1460
1480
1500
1520
1540
1560
1580
1600
1620
0 10 20 30 40 50 60 70
Days
Pre
ssur
e (P
SI)
Pressure1Pressure2Pressure3Pressure4
60
65
70
75
80
85
90
95
0 10 20 30 40 50 60 70
Days
Tem
pera
ture
(F)
Temp1Temp2Temp3Temp4
Pressure Temperature
Deep MonitoringWell
Cross‐well or3D Seismic
Surface Flux and Soil Gas Probes
Borehole Tiltmeters