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Demonstration of Semiconducting Polymers for Microsprings
Lilit Abramyan
IMSURE Fellow
Mentors:
John LaRue (MAE)
Richard Nelson (EECS)
Polymers
Low cost Easy processing Excellent thermal stability Flexibility
Conducting Polymers
LEDs Transistors Optical devices Micro-electro-mechanical systems
Drug deliveryDLP (Digital Light Processing)
Motivation
Plate
F(mechanical)
F(electrical)
Anchor
Spring
Electrode
Projection lens
Black hole absorption
http://www.dlp.com/tech/what.aspx
Image by Chang-hsiu Chen
Plans
Thin films Electrical properties Equivalent circuit Surface morphology Young’s modulus
Background Information
PEDOT poly(3,4-ethylenedioxythiophene) Good conductor Insoluble
PSS poly(styrenesulfonate) Makes dispersion with PEDOT in water
PVA (polyvinyl alcohol) Adds viscosity Better mechanical properties
Solutions
PEDOT:PSS Baytron P
(manufacturer-prepared) – conducting polymer
NMP (N-Methyl-2-pyrrolidone) – conductivity enhancement
Silquest – durability
Isopropanol – reduce surface energy
Dynol 604 – wetting agent
Solutions (cont.)
Two separate solutions – PEDOT & PVA
Mix at different weight percentages
Fabrication of Samples
Spin coat onto Silicon and glass Silver epoxy contacts
Resistance & Conductivity
L
AR
1
ρ=resistivity
R=resistance
A=cross-sectional area
L=length
σ=conductivity
Thickness - profilometer
Lower percentage of PEDOT→ More PVA→ More viscous→ Thicker films
L
Transient Response
Pulse testing
Sample on Silicon Sample on Glass
Initial Simulation Model
R1
21
C3
1 2
R3
21
R2
21
C2
1 2
ImpedanceNyquist Plot
Phase vs. Frequency
Equivalent Circuit (Final Simulation Model)
C p1 2
R 421
R 221
C 11 2
C 31 2
R 121
R 321
C 21 2
Impedance spectroscopy model
SEM (Scanning Electron Microscope) Images
100% PEDOT
On glass
80% PEDOT
On glass
50% PEDOT On silicon
Soaked in water
Resonant Frequency & Young’s Modulus Vibrometer at Polytec
(http://www.polytec.com)
Acknowledgements
John LaRue Richard Nelson Allen Kine Chang-hsiu Chen Said Shokair Urop & IM-SURE National Science Foundation