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Descriptive Mineralogy Native Elements: Pure elements that occur as minerals

Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

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Page 1: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Descriptive Mineralogy

Native Elements:Pure elements that occur

as minerals

Page 2: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Classification of the Minerals• Non-Silicates

– Native Elements– Halides– Sulfides– Oxides– Hydroxides– Carbonates– Sulfates– Phosphates

• Silicates– Orthosilicates– Sorosilicates– Cyclosilicates– Chain Silicates– Layer Silicates– Tektosilicates

Page 3: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements

Page 4: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Metals

• Fe, Co, Ni: Meteorites• Platinum Group: (Ru, Rh, Pd, Os, Ir, Pt):

Mafic Igneous Rocks• Coinage metals: Cu, Ag, Au

– Cu, Ag: Supergene Enrichments (SulfideOxidation)

– Au: Low Temperature Hydrothermal, Placer

Page 5: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Iron: Meteorites

Page 6: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Iron: MeteoritesWidmanstätten Pattern

Page 7: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Iron-Nickel Phase Diagram

Page 8: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Platinum Group MetalsRu, Rh, Pd, Os, Ir, Pt

• Strongly siderophile elements• Enriched in Fe meteorites• Found in layered mafic intrusions

– Bushvelt Complex (South Africa)– Stillwater Complex (Montana)– Skaergaard Complex (Greenland)

Page 9: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated
Page 10: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated
Page 11: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Bushvelt: Layered Gabbroic Intrusion

Page 12: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Bushvelt: Layered Gabbroic Intrusion

Page 13: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Skaergaard: Layered Gabbroic Intrusion

Page 14: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Skaergaard: Layered Gabbroic Intrusion

Page 15: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Skaergaard: Layered Gabbroic Intrusion

Page 16: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Cu, Ag, Au• Cu and Ag: Supergene Enrichment

– Oxidation of Cu, Ag sulfides inunsaturated zone

– Precipitation of metal, oxides andcarbonates at water table

• Ag and Au: hydrothermal– Native metals and tellurides

• Au: placer– oxidized hydrothermal

Page 17: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Supergene Copper

Page 18: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Hydrothermal Silver

Page 19: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Hydrothermal Gold

Page 20: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Hydrothermal Gold

Page 21: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: non metals

• Carbon:– Graphite: Metamorphic Rocks– Diamond: Kimberlites

• Sulfur (+Se):– Salt Domes (Sulfate reduction),– Volcanos (H2S oxidation)

• Tellurium (Te) Tellurideoxidation

Page 22: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Carbon

• Graphite (Low Pressure)– Metamorphosed Organic-rich sediments

• Diamond (High Pressure >100km)– Kimberlites– Placers from kimberlites

Page 23: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated
Page 24: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Diamond

Page 25: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Diamond

Page 26: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated
Page 27: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Kimberley Mine 1875

Page 28: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements: Sulfur

• Fumaroles (Volcanic hydrothermal vents)– Oxidation of H2S

• Salt dome cap rocks– Sulfate reduction by petroleum

Page 29: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Fumarole Sulfur: Nysseros

Page 30: Descriptive Mineralogy Native Elementscribme.com/cu/data/Geology/Minerology/Lectures/14Natives.pdf• Cu and Ag: Supergene Enrichment – Oxidation of Cu, Ag sulfides in unsaturated

Native Elements