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Design and Correction of optical Systems
Part 2: Materials
Summer term 2012
Herbert Gross
1
Part 2: Materials - Contents
2.1 Introduction
2.2 Dispersion
2.3 Transmission
2.4 Glasses
2.5 Plastics
2.6 Crystals
2.7 Liquids and Gases
2.8 Metals
Overview
� Important types of optical materials:
1. Glasses
2. Crystals
3. Liquids
4. Plastics, cement
5. Gases
6. Metals
� Optical parameters for characterization of materials
1. Refractive index, spectral resolved n(λ)
2. Spectral transmission T(λ)
3. Reflectivity R
4. Absorption
5. Anisotropy, index gradient, eigenfluorescence,…
� Important non-optical parameters
1. Thermal expansion coefficient
2. Hardness
3. Chemical properties (resistence,…)
Dispersion
n(λλλλ)
ni(λλλλ)
λλλλo
normal normalanomal
λλλλ
n
� Dispersion:
Refractive index changes with wavelength
� Normale dispersion: larger index n for shorter wavelengths,
Ray bending of blue rays stonger than red
�Notice:
Diffraction dispersion is anomalous
with dn/dλ > 0
The different sign allows for chromatic
correction in diffractive elements.
( ) ( )21 λλ nnn −=∆
d n
d λ< 0
Important Test Wavelengths
λλλλ in [nm] Name Color Element
248.3 UV Hg
280.4 UV Hg
296.7278 UV Hg
312.5663 UV Hg
334.1478 UV Hg
365.0146 i UV Hg
404.6561 h violett Hg
435.8343 g blau Hg
479.9914 F' blau Cd
486.1327 F blau H
546.0740 e grün Hg
587.5618 d gelb He
589.2938 D gelb Na
632.8 HeNe-Laser
643.8469 C' rot Cd
656.2725 C rot H
706.5188 r rot He
852.11 s IR Cä
1013.98 t IR Hg
1060.0 Nd:YAG-Laser
Spectral Lines
Selected atomic lines of the sun spectrum used for test purposes
λ λ λ λ [nm]400 450 500 550 600 650 700 750
K H G F E D12
C AB
h g fe d c b12a
Chromatical Evaluation of Optical Systems
� Chromatical performance evaluation of optical systems:
Usage of one main (central) wavelength and two secondary wavelenghts
� Additional definition of wvalengths at the boundaries of the used spectral range, e.g.
- one further wavelength near to the UV edge (g, i)
- one further wavelength near to the IR-edge (s,t)
Main wavelength 1st secondary wavelength 2nd secondary wavelength
e 546.07 green F' 480.0 bue C' 643.8 red
d 587.56 yellow F 486.1 blue C 656.3 red
Dispersion
� Description of dispersion:
Abbe number
� Visual range of wavelengths:
� Typical range of glasses
νe = 20 ...120
� Two fundamental types of glass:
Crone glasses:
n small, ν large
Flint glasses
n large, ν small
( )( )
ν λλ
=−
−
n
n nF C
1
' '
νe
e
F C
n
n n=
−
−
1
' '
Dispersion
Material with different dispersion values:
� Different curvature of the dispersion curve
� Stronger change of index over wavelength for large dispersion
� Inversion of index sequence at the boundaries of the spectrum possible
refractive index n
F6
SK18A
λλλλ
1.675
1.7
1.65
1.625
1.60.5 0.75 1.0 1.25 1.751.5 2.0
Dispersion Equation
� Experimental determination of
refractive indices for discrete
wavelengths
� Fit of model based or empirical
dispersion function
� Interpolation for desired wavelength
� Types of dispersion formulas:
1. Empirical, no extrapolation
allowed
2. Based on physical oscillator
model, extrapolation possible
in certain rangeλλλλ
n
400 600 800 1000 1200 1400 1600 1800 2000 2200 24001.48
1.49
1.5
1.51
1.52
1.53
1.54
measured data points
model curve of dispersion
∑−
+=j j
j
o
knn
22
22
ωω
Dispersion Formulas
� Schott formula
empirical
� Sellmeier
Based on oscillator model
� Bausch-Lomb
empirical
� Herzberger
Based on oscillator model
� Hartmann
Based on oscillator model
n a a a a a ao= + + + + +− − − −1
2
2
2
3
4
4
6
5
8λ λ λ λ λ
n A B C( )λλ
λ λ
λ
λ λ= +
−+
−
2
212
2
222
n A B CD E
Fo
o
( )
( )
λ λ λλ
λ
λ λλ
λ λ
= + + + +
− +−
2 4
2
2
2 22
2 2
( )mmit
aaaan
o
oo
o
µλ
λλλλλλ
168.0
)(222
3
22
22
1
=
−+
−++=
λλλ
−+
−+=
5
4
3
1)(a
a
a
aan o
Relative Partial Dispersion
� Relative partial dispersion :
Change of dispersion slope with λ
� Definition of local slope for selected
wavelengths relative to secondary
colors
� Special selections for characteristic
ranges of the visible spectrum
λ = 656 / 1014 nm far IR
λ = 656 / 852 nm near IR
λ = 486 / 546 nm blue edge of VIS
λ = 435 / 486 nm near UV
λ = 365 / 435 nm far UV
( ) ( )P
n n
n nF C
λ λ
λ λ1 2
1 2=
−
−' '
λλλλ
n
400 600 800 1000700500 900 1100
e : 546 nm
main color
F' : 480 nm
1. secondarycolor
g : 435 nmUV edge
C' : 644 nm
s : 852 nm
IR edge
t : 1014 nm
IR edge
C : 656 nmF : 486 nm
d : 588 nm
i : 365 nm
UV edge
i - g
F - C
C - s
C - t
F - e
g - F
2. secondarycolor
1.48
1.49
1.5
1.51
1.52
1.53
1.54
n(λλλλ)
Relative Partial Dispersion
� Typical behavior of glasses:
Flint (e.g. SF9) glasses have stronger dispersion than crown glasses (e.g. LaK21)
� Larger difference of refractive index over the visible spectrum
λλλλ
dn/dλλλλ
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1-0.7
-0.6
-0.5
-0.4
-0.3
-0.2
-0.1
0
SF9
LaK21
∆∆∆∆nSF9
∆∆∆∆nLaK21
Normal Line
� The relative partial dispersion changes approximately linear with the dispersion for glasses
� Nearly all glasses are located on the normal line in a P-ν-diagram
� Glasses apart from the normal line shows anomalous partial dispersion
these material are important for chromatical correction of higher order
2,12,12,1 λλλλλλ ν baP d +⋅=
21212121 λλλλλλλλ ν PbaP d ∆++⋅=
Normal Line
Pg,F
0.5000
0.5375
0.5750
0.6125
0.6500
90 80 70 60 50 40 30 20
F2
F5
K7
K10
LAFN7
LAKN13
LAKL12
LASFN9
SF1
SF10
SF11
SF14
SF15
SF2
SF4
SF5
SF56A
SF57
SF66
SF6
SFL57
SK51
BASF51
KZFSN5
KZFSN4
LF5
LLF1
N-BAF3
N-BAF4
N-BAF10
N-BAF51N-BAF52
N-BAK1
N-BAK2
N-BAK4
N-BALF4
N-BALF5
N-BK10
N-F2
N-KF9
N-BASF2
N-BASF64
N-BK7
N-FK5
N-FK51N-PK52
N-PSK57
N-PSK58
N-K5
N-KZFS2
N-KZFS4
N-KZFS11
N-KZFS12
N-LAF28
N-LAF2
N-LAF21N-LAF32
N-LAF34
N-LAF35
N-LAF36
N-LAF7
N-LAF3
N-LAF33
N-LAK10
N-LAK22
N-LAK7
N-LAK8
N-LAK9
N-LAK12
N-LAK14
N-LAK21
N-LAK33
N-LAK34
N-LASF30
N-LASF31
N-LASF35
N-LASF36
N-LASF40
N-LASF41
N-LASF43
N-LASF44
N-LASF45
N-LASF46
N-PK51
N-PSK3
N-SF1
N-SF4
N-SF5
N-SF6
N-SF8
N-SF10
N-SF15
N-SF19
N-SF56
N-SF57
N-SF64
N-SK10
N-SK11
N-SK14
N-SK15
N-SK16
N-SK18N-SK2
N-SK4
N-SK5
N-SSK2
N-SSK5
N-SSK8
N-ZK7
N-PSK53
N-PSK3
N-LF5
N-LLF1
N-LLF6
BK7G18
BK7G25
K5G20
BAK1G12
SK4G13
SK5G06
SK10G10
SSK5G06
LAK9G15
LF5G15
F2G12
SF5G10
SF6G05
SF8G07
KZFS4G20
GG375G34
νννν
normal
line
Transmission
� Internal transmission:
only volume absorption, without losses at the interfaces
� Typical characterization:
transmission of a plate with finite width 25 mm
calculation of the transmission of a sample
with arbitrary thickness
� Glasses: strong edge at the UV side
� Definition of edge position
1. 50% value
2. mean value of 20% and 80% value
d
in
outd e
I
IT
⋅−== α
( ) mm
d
mmd TT 2525
=
λλλλ
T
200 400 500 600 700 8000
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
50 % -
Definition
20 / 80 % -
Definition
Transmission
� Typical transmission of glass
� Three ranges:
1. steep UV edge
2. high transmission
plateau in the visible
3. slow edge towards
the IR
λλλλ inµµµµm
T (d=10mm)
UV-edgeionization
of the
atoms
IR-edgeabsorption
by residualwater
window withtransmission T > 0.99
0.50 1.51.0 2 2.50.90
0.925
0.975
0.95
1.0
NIRVIS
Transmission
� Absolute transmission of a sample,
Only energy in-out-ratio
Losses at the interfaces (Fresnel) are incorporated
� Internal transmission of a sample,
only volume losses, interface efects removed
0I
IT =
0i
i
I
IT =
I(x)
x
Io
Iio
IIi
n
Transmission: Glasses
� Transmission of
glasses
� plate with thickness
d = 10 mm
in mλλλλµµµµ
T (d=10mm)
TiF6
KzFSN4
LaK33
BK7
LaF2
SK4
FK52
Transmission: IR- and UV Materials
Transmission of UV- and IR-materials (with Fresnel losses at interfaces)
T
Log λ λ λ λ
in µ µ µ µm
ZnS3mm
IRG 5 mm
Suprasil 3mm
CdTe
4mm
ZnSe
3mm
Ge
3mm
GaAs
3mm
IRG 1002mm
100
50
0
visualrange
infrared
3 - 5infrared
8 - 12
0.1
Glass
� Glass blocks
� Striae in glass
Ref: P. Hartmann / Schott
Glass Diagram 2010
� Usual representation of
glasses:
diagram of refractive index
vs dispersion n(ν)
� Left to right:
Increasing dispersion
decreasing Abbe number
Glass Diagram: Changes of Numbers
Ref: P. Hartmann / Schott
Data Sheet
Glass:
LAFN7
Part 1
Data Sheet
Glass:
LAFN7
Part 2
Ranges of the Glass Diagram
Crown glasses
ν
νe e
e e
für n
für n
> <
> >
54 7 16028
49 7 16028
. .
. .
Flint glasses
ν
νe e
e e
für n
für n
< <
< >
54 7 16028
49 7 16028
. .
. .
Two major families of glass types, depending on chemical ingredients:
1. Crown:
Low index, low dispersion
2. Flint:
High index, high dispersion
n
80 70 60 50 40 30 2025354555657585
1.45
1.50
1.55
1.60
1.65
1.70
1.75
1.80
1.85
1.90
1.95
2.00
LaK
LaSF
SF
TiSF
TiF
BaSF
F
LF
LLF
BaLF
LaF
PSK
PK
FK TiK
BKK
SK
BaK
SSK
KF
crown glass
flint
glass
BaF
Chemical Glass Families
Abbr. Name Abbr. Name
Crownglasses
K Kron
Flintglasses
F Flint
BaK Baritkron BaF Baritflint
BaLK Baritleichtkron BaLF Baritleichtflint
BK Borkron BaSF Baritschwerflint
ZK Zinkkron LLF Doppelleichtflint
SK Schwerkron KF Kronflint
SSK Doppelschwerkron KzF Kurzflint
FK Fluorkron LaF Lanthanflint
TiK Tiefkron LaSF Lanthanschwerflint
PK Phosphatkron LF Leichtflint
PSK Phosphatschwerkron SF Schwerflint
LaK Lanthankron TiF Tiefflint
TiSF Schwertiefflint
KzFS Kurzschwerflint
Available Ranges in the Glass Diagram
νννν
n
20 30 40 50 60 70 80 90 1001.4
1.5
1.6
1.7
1.8
1.9
2
20 30 40 50 60 70 80 90 1001.4
1.5
1.6
1.7
1.8
1.9
2
Schott Ohara
� Nearly equal area in the glass diagramm with available materials for all vendors
� No options with Index / dispersion
1. high / high
2. low / low
Plastics
Material Index at 546 nm
Abbenumber
MaxTemp
Therm expan10-6 K-1
Scatterin %
Trans.3mm,
Densityg/cm3
PMMA - Polymethyl-Methacrylat 1.49280 57 90 65 2 92 1.19
PC - Polycarbonat - Makrolon, Lexan 1.59037 30 120 69 4 87 1.20
CR39 - DEGBAC - Gießharz 1.5011 57.8 100 120 1 1.32
PS - Polystyrol 1.590 30.8 80 70 3 89 1.06
DPSC - Diphenyl-sulfidcarbonat 1.612 26.0
CMMA 1.50 56.0
Styrol, SAN 1.566 34.7 95 65 4 90 1.09
SMA 1.585 31.3
SMMA 1.568 33.5
FMS 1.508 34.0
SCMA 1.535 42.5
COC 1.533 56.0
MR8 1.60 42.0
Plastic Materials
Plastics in the
n - ν - diagram
90 80 70 60 50 40 30 20
1.40
1.45
1.50
1.55
1.60
1.65
1.70
1.75
1.80
1.85
1.90
1.95
2.00
refractiveindex n
Abbe number νννν
10
PMMA
CR39o
o
o
o
SAN
PS oPC
CMMAo
o COC oSCMA
oFMS
oSMMA
oSMA
DPSC
o
oMR8
plastics
anorganic
glasses
Properties of Plastic Materials
1. Stress induced birefringence during processing
2. Generation of local inhomogenieties of the refractive index in die casting
3. Water intake (swelling) : change of shape (up to 4%) and decrease in the refractive index
4. Electro-static charge
5. Aging due to cold forming, polymerization, opalescence, yellowing
6. Strong thermal variation of the refractive index
7. Limiting temperature (above the transition temperature the material is destroyed)
100 ... 120 °C
8. For an increased abrasive hardness and for the prevention from charging and
swelling ,special coatings may have to be applied.
9. During the cooling process significant changes occur in the volume caused by shrinking.
There are two different types of plastics
a. thermosets, shrinking 0.4%...0.7%
b. thermoplasts, shrinking 4%...14%
Usage of Plastics in Optical Systems
� Most attractive use of plastics: Consumer optics
- benefit of light weight
- critical cost
- high number of pieces
� Advantages for special components due to manufacturing technique:
- complex surface shapes, arrays, aspheres
- for injection moulding cost of complex shape only for master piece
� Typical products with plastics components:
- Eye glasses
- binoculars
- photographic lenses
- pic-up objective lenses
- illumination systems
Plastics vs Glass Materials
property unit range plastics range glass
refractive index n 1.49 ...1.61 1.44...1.95
dispersion ν 25...57 20...90
uniformity of the refractive index 10-3
...10-4
10-4
...10-6
temperature dependence of the refractive index 10-6*K
-1 -100...-160 -10...+10
Vickers hardness N/mm2 120...190 3000...7000
thermal expansion 10-6*grd
-1 70...100 5...10
thermal conductivity Wm-1grd-1
0.15...0.23 0.5...1.4
internal transmission in the green range 0.97...0.993 0.999
stress - optical coefficient 10-12
Pa-1
40 3
stress- birefringence 5*10-5
...10-3
0
density g/cm3 1.05...1.32 2.3...6.2
water intake % 0.1...0.8 0
Comparison plastics with glasses
UV- and IR - Materials
material refractive
index λλλλ-range (µµµµm) UV IR νννν P
MgF2 1.389 0.12 - 9.0 • •
ZnS 2.25 0.4 - 14.5 • 12.831 0.271
CaF2, calcium fluoride 1.42 0.12 - 11.5 • • 47.53 0.397
ZnSe 2.44 0.5 - 22.0 • 34.20 0.291
MgO 1.69...1.737 0.28 - 9.5 • 53.4
CdTe 2.70 0.9 - 31.0 •
diamond 2.3757 0.25...3.7, 6.0... • (•) 2387 0.469
germanium 4.003 2.0...15 • 701.42 0.556
silicon 3.433 1.2...15 • 420.16 0.523
BaF2 1.474 0.18...12 • • 81.7 0.651
SiO2 , quartz 1.544 0.15...4.0 • (•) 69.9 0.653
Al2O3 , sapphire 1.769 0.17...5.5 • (•) 6.626 0.650
IR - Materials
name composition application toxity processing
germanium Ge 5 can be processed very well
gallium arsenide GaAs 2 toxic
silicon Si 5 high tool wear
zink sulfide ZnS 4 can be processed very well
zink selenide ZnSe 4 slightly toxic can be processed very well
sapphire Al2O3 3
IG2 / AMTIR-1 Ge33As12Se55 3 toxic
IG3 Ge30As13Se32Te25 3 toxic
IG4 Ge10As40Se50 3 toxic
IG5 / AMTIR-3 Ge28Sb12Se60 4 slightly toxic can be processed well
IG6 As40Se60 3 toxic
GASIR1 Ge22As20Se58 3 toxic
GASIR2 Ge20Sb15Se65 3 slightly toxic
calcium fluoride CaF2 3
barium fluoride BaF2 3
lithium fluoride LiF 3
sodium chloride NaCl 2
sodium fluoride NaF 2
potassium bromide KBr 2
potassium chloride KCl 2
potassium iodide KJ 2
KRS 5 TlBr-TlJ 2 toxic
KRS 6 TlBr-TlCl 2 slightly toxic
thallium bromide TlBr 1
thallium iodide TlJ 1
Gases
� Refractive indices near to 1
� Definition of indices relative to vacuum
(usual glasses: relative to air)
� Strong changes of the index with temeprature and pressure
� Examples
( )T
T
p
pnn 0
0
011 ⋅⋅−+=
medium ne ννννe
Air 1.000293246 89.68
Argon 1.00028314 80.90
Chlorine 1.0007840 56.40
Helium 1.00003495 194.17
Ammonia 1.000379 47.38
carbon dioxyde 1.0004506 77.82
oxygen 1.00027227 71.09
nitrogen 1.00029914 89.83
steam 1.0002527 66.50
hydrogen 1.00013937 77.00
Refractive Index of Air
� Empirical formula for the refracdtive index of air at normal pressure as a function of
- wavelength λ in µm
- temprature T in °C
(n-1) 10-6
T = 70 °
T = 50 °
T = 20 °
in mλ µ
[ ]( )2000367.0101803.0476.1
036.26810142
6 −⋅−⋅
++⋅+= −
Tnλλ
Refractive Index of Air
� Formula of Edlen:
Refractive index of air as a function of
T : temperature in °C
p : pressure in torr
x : relative CO2-content
q : partial pressure of water steam
( )[ ]
( )
−⋅⋅−
⋅+
⋅−⋅⋅+⋅⋅
−+
−+⋅⋅−⋅++=
−−
−
2
108
22
8
0384.0802.310
0036610.01
009876.05953.0101
60.93214
/19.38
15518
/1130
233398337.8091100004.05327.011
λ
λλ
qT
Tpp
xn
Liquids
� Examples
� Index of water
λλλλ
n
400 600 800 1000 1200 1400 1600 1800 2000
1.30
1.31
1.32
1.33
1.34
1.35
1.36
200
1.37
medium nd
Ethylalcohol 1.362
Gasoline 1.440
Benzene 1.501
Glycine 1.455
Methyliodide CH2J2 1.742
Carbon sulfate 1.628
Cedar wood oil 1.51
Liquid oxygen 1.221
Liquid hydrogen 1.11
Absorption of Water
� Spectral resolved absorption coefficient of water
Ref: A. Kienle
Technical Liquids
Liquids of the vendor Cargille
020406080100120
νννν-Number
PCs
0,4
0,45
0,5
0,55
0,6
0,65
0,7
0,75
SCHOTT Glasses
Series A
Series AAA
Series AA
Series E
Series I
Series EC31
νννν-Number
Pg,F
0102030405060708090100
Series E
Series I
Series EC31
SCHOTT Glasses
Series A
0,5
0,55
0,6
0,65
0,7
0,75
Abbe normal line
Cements
� Optical cement materials:
- rigid connection of glass components
- typical thickness 0.01 mm without optical
effects
- elasticity for compensation of thermal expansion
differences desired
- typical index n = 1.45…1.55 (epoxy resins)
� Organic cement problems with
- UV transmission
- long term stability
- high energy density
- thermal stability
crown
glassflint
glassn
1.5
1.7
1.6
cement
z
Metals
� Complex refractive index
� Alternative formulation:
attenuation κ
� Relation with conductivity σ
� Typical data of some metals
ir ninn ⋅+=~
( )κ⋅+⋅= inn 1~
( )σνεµω
σπεµ ⋅⋅+⋅=
⋅⋅+⋅= 24~ iin
material n k δδδδ in [µµµµm]
gold 0.402 2.54 0.034
silver 0.129 3.25 0.026
aluminum 0.912 6.56 0.013
tungsten 3.50 2.72 0.032
platinum 2.10 3.67 0.023
silicon 4.12 0.048 1.787
Dispersion of the Refractive Index of Metals
� Typically strong structure of the dispersion
curve with absorption ranges
� Example: Aluminum
� Comparison of different metalsLog λ λ λ λ0.1 µµµµm
10
k
1 µµµµm 10 µµµµm
10-1
10-2
1
n
Vis
λλλλ
R
1 µµµµm500 nm300 nm 2 µµµµm 5 µµµµm
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
10 µµµµm
aluminum, Al
silver, Ag
mercury, Hg
gold, Aucopper, Cu
platinum, Pt
nickel, Ni
chromium, Cr
Summary of Important Topics
� Characterization of optical materials: refractive index n, Abbe number ν (dispersion)
� Abbe number: mean slope of dispersion curve, small ν means large dispersion
� Choice of special wavelengths to describe the dispersion behavior (e.g.: e, F, C)
� Partial dispersion P: more refined description of dispersion: curvature
� Normal glass line: most glasses fulfill P proportional to ν
� Mathematical description of dispersion: Sellmeier formulas, corresponds to modelling
adjacent absorption lines, typically 2-3 terms considered
� Transmission of materials: glasses show UV IR decay, crystals have broader windows
� Glass diagram: n-ν-chart, distinction of
1. crown glasses, n low, ν high, dispersion low
2. flint glasses; n high, ν low, dispersion high
� Plastics materials: for high volume systems, bad performance in comparison to glass
(thermal, index low, straylight, transmission)
� Special behavior, but minor importance in optics: gases, liquids, cements, metals
45
Outlook
Next lecture: Part 3 – Components
Date: Wednesday, 2012-05-02
Contents: 3.1 Lenses - description and parameters
- imaging formulas
3.2 Mirrors
3.3 Prisms - dispersion prims
- reflection prisms
- miscellaneous
3.4 Special components - gratings
- aspheres
- diffractive elements
- taper
- gradient lenses
46