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DETAILS OF GREEN BELT DEVELOPMENT - UPL...DETAILS OF GREEN BELT DEVELOPMENT For the period January – 12 to June - 12 1. No. of trees planted before January -12 inside the company

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  • DETAILS OF GREEN BELT DEVELOPMENT

    For the period January – 12 to June - 12

    1. No. of trees planted before January -12 inside the company premises =

    39106 in 20.5 acre.

    2. During the above mentioned period:

    -No. of trees planted inside company premises = 189 in 0.25 acre area. -Total Trees survived inside company: 189

    3. Total trees available inside company: 39295

    4. Total area covered : 20.75 acre

    5. Total trees per Ha: 4734

  • EXPENDITURE ON POLUTION CONTROL MEASURE FOR THE PERIOD JANUARY – 12 TO JUNE – 12

    A) Operating cost for Air Pollution Control Equipment's

    Sr. No. Plant Pollution Control Equipment Expense

    1 PCL3 Scrubbers 511961

    2 POCL3 Scrubbers 72917

    3 Caustic – Chlorine Hypo Scrubber 10289274

    4 Caustic – Chlorine Caustic Scrubber 317940

    5 White Phosphorus Venture Scrubber 0

    6 PCl5 Scrubbers 2002517

    7 Mancozeb Scrubbers 4998392

    Total cost for operating Air Pollution Control equipment is Rs. 18193001

    B) Operating cost for Water Pollution Control Equipment's

    Sr. No. Plant Pollution Control Equipment Expense

    1 Caustic – Chlorine ETP 1068192

    2 PCL3 & POCl3 Plant Scrubber Effluent 722808

    3 Power Plant ETP 288832

    4 White Phosphorus ETP 0

    5 Central ETP ETP 122460

    6 RO RO 1548320

    7 1 MLD ETP (C-Tech) ETP 9241782

    8 MEE MEE 33053352

    Total cost for operating Water Pollution Control equipment is Rs. 46045745

    C) Operational cost for solid waste disposal

    Rs. 9881271 (This includes transferring cost from plant to our internal solid waste storage and

    from our site to TSDF, BEIL, Ankleshwar)

  • Summary of Stack Monitoring Parameters:

    Stacks Pollutants Limit Average Maximum Minimum

    Power Plant HRSG Stack NOX 50 ppm 28.8 39.7 19.6

    Caustic Scrubber WAD 56-TPD Plant HCl 20 mg/Nm3 7.9 10.8 5.9

    Caustic Scrubber WAD 100-TPD Plant Cl2 9 mg/Nm

    3 1.7 1.7 1.7

    HCl 20 mg/Nm3 6.4 8.5 4.8

    Caustic Scrubber of HCl Furness 100-TPD Plant HCl 20 mg/Nm3 13.8 16.7 10.9

    Caustic Scrubber of Phosphorus Oxy-Chloride

    Plant Distillation Column HCl 20 mg/Nm

    3 6.0 9.7 4.1

    Caustic Scrubber of Distillation Section of PCl3

    Plant

    HCl 20 mg/Nm3 7.7 10.2 4.4

    PCl3 9 mg/Nm3 0.8 1.2 0.5

    Caustic Scrubber of Storage Tank & Drum Filling

    Section of PCl3 Plant

    HCl 20 mg/Nm3 5.6 7.8 3.2

    PCl3 9 mg/Nm3 0.5 0.8 0.2

    Water Scrubber + Alkali Scrubber of Reactor PCl5

    Plant

    Cl2 9 mg/Nm3 1.1 1.6 0.4

    HCl 20 mg/Nm3 14.3 18.3 11.1

    Alkali Scrubber of Mancozeb Plant Reactor D-14

    New EDA Scrubber

    H2S 45 mg/Nm3 17.9 19.8 15.2

    CS2 180 mg/Nm3 127.6 176.0 81.4

    Water Scrubber of Wet Spray Dryer of Mancozeb

    Plant PM 20 mg/Nm

    3 16.5 18.6 14.2

    Bag Filter of RVDF of Mancozeb Plant PM 20 mg/Nm3 13.7 17.0 10.2

    TPPI - Thermic Fluid Heater

    PM 150 mg/Nm3 50.7 66.5 38.4

    SO2 100 ppm 9.8 13.4 7.4

    NOX 50 ppm 12.4 17.1 9.5

    TPPI -Water Scrubber + Ventury Scrubber of Tri-

    Phenyl Phosphite Plant Rector(C-2102) HCl 20 mg/Nm

    3 8.3 11.4 5.9

    TPPI -Water Scrubber + Ventury Scrubber of Tri-

    Phenyl Phosphite Plant Rector(C-2002A) HCl 20 mg/Nm

    3 8.4 10.1 7.0

    TPPI -Water Scrubber + Ventury Scrubber of Tri-

    Phenyl Phosphite Plant Rector(C-2020) HCl 20 mg/Nm

    3 7.3 7.3 7.3

  • Summary of Ambient Monitoring Parameters:

    Pollutants Limit Average Maximum Minimum

    PM10 100 µg/m3 68.5 84.2 56.2

    PM2.5 60 µg/m3 43.1 47.6 38.6

    SOX 80 µg/m3 17.4 25.8 12.4

    NOX 80 µg/m3 23.4 32.3 14.8

    HCl 200 µg/m3 35.9 54.9 7.6

    Cl2 100 µg/m3 4.7 4.7 4.7

    NH3 400 µg/m3 BDL BDL BDL

    HF 160 µg/m3 BDL BDL BDL

    H2S 500 µg/m3 BDL BDL BDL

    CS2 2000 µg/m3 177.3 306.0 84.6

    HC 160 µg/m3 BDL BDL BDL

    P2O5 70 µg/m3 BDL BDL BDL

    Summary of Effluent Parameters:

    Parameters Limits 3rd Party Results NCTL Results

    Average Maximum Minimum Average Maximum Minimum

    pH 6.5-8.5 -- -- 8 7 -- 8.86 6.84

    COD (mg/L) 100 mg/L 89 129 40 116 208 48

    SS (mg/L) 100 mg/L 52 78 12 48 218 21

    Ammonical

    Nitrogen (mg/L) 50 mg/L 12 18 1 13 20 6

  • UNITED PHOSPHORUS LTD., UNIT NO. 5

    JHAGADIA

    STATUS CUM COMPLIANCE REPORT FOR ENV. CLEARANCE NO. J – 11011/325/2006 – IA II (I) DTD. 25TH JULY, 2007 FOR VARIOUS PRODUCTS.

    Sr.

    No.

    Condition Status

    1 The ministry of Environment & forest has examined the

    proposal. It is noted that the proposal is for expansion of

    Unit – V at Jhagadia Gujarat. The expansion project

    comprise of addition of new units for producing Pesticide

    Intermediate & Technical Products and expansion of

    existing Chlor-alkali & Captive Power Plants. Company

    proposes to produce the following Pesticides

    Intermediate Products, Technical Grade Pesticide

    Products along with their By – Products

    Noted and complied.

    Company has started

    manufacturing of Mancozeb

    and Pendimethyline

    Sr.

    No.

    Products By Products

    Quantity in MT/Month Quantity in MT/Month

    Items Existing Capacity

    Additional

    Capacity Overall

    capacity

    after

    expansion

    Items Existing

    capacity

    Additional

    capacity

    Overall

    capacity

    after

    expansi

    on

    1 Triphenyl

    Phosphite

    300 - 300 HCl

    (30%)

    353 - 353

    2 Phosphorus Trichloride

    2250 - 2250 - - - -

    3 2,4Di Chloropheno

    l

    166 - 166 Mix

    Chloro

    phenol

    15 - 15

    HCl

    (30%)

    250 - 250

    4 Phosphorus Oxychloride

    150 - 150 - - - -

    5 Phosphorus 900 - 900 Ferrous Phospho

    rus

    150 - 150

    Calcium Silicate

    6000 - 6000

    6 Phosphorus Acid

    150 - 150 HCl(30%)

    600 - 600

    7 Trinonyl Phenyl

    Phosphite

    100 - 100

    8 Phenyl Di Iso Decyl

    Phosphite

    100 - 100

    9 Amino Tri 200 - 200

  • Methylene

    Phosphoric

    Acid

    10 Ethylene Diamine

    Tetra

    Phosphoric

    Acid

    100 - 100

    11 Phosphorus Penta

    Chloride

    150 150

    DVACl Plant

    12 DVACl - 300 300 Spent Sulphuric Acid

    - 900 900

    POCl3 - 400 400

    HCL (28%)

    - 490 490

    Sodium Sulphite

    (20%)

    - 1200 1200

    Pesticides Intermediat

    e Products –

    Multi

    Product

    Plant

    13 N – Alkylated

    Xyledene

    - 300 300 Pera Toluene

    Sulphoni

    c Acid

    (PTSA)

    - 94 94

    OR

    HRT Ketone - 200 200

    OR

    2 – Ethyl 6 – Methyl – n –

    n Aniline

    - 300 300

    OR

    MPBAL - 300 300

    Caustic Chlorine

    Plant

    14 Caustic Soda Lye

    48% (On

    100 % Basis)

    4680 10500 15180 Sodium Hypochl

    orite

    225 525 750

    15 Chlorine 3972 8537 12509 - - - -

    16 Hydrogen 225 263 488 - - - -

    17 Hydrochloric Acid

    (30%)

    1200 2625 3825 - - - -

    Power Plant

    18 Electrical Power

    50

    MW/Hrs

    37.6

    MW/Hrs.

    87.6

    MW/Hrs.

    Steam 30 MT

    / Hrs.

    - 30

    MT/Hrs

    Pesticides Technical

    Products

  • 19 Glyphosate - 1000 1000

    20 Pendimethylene

    - 200 200

    21 Tebuconazole

    - 200 200

    22 Metalochlor - 200 200

    23 Aceflorfen - 500 500 Acetic Acid

    (80%)

    - 1185 1185

    24 Mancozeb - 4000 4000 Sodium Sulphat

    e 96% /

    Sodium

    Sulphat

    e

    Solution

    - 4092/

    15680

    4092/

    15680

    25 Acephate - 800 800 Ammonium

    Acetate

    - 464 464

    26 Cypermethrin

    - 500 500

    27 Permethrin - 300 300 HCl (30%)

    - 94.8 94.8

    Pesticides Formulation

    28 Isopropyl Amine Salt

    of

    Glyphosate

    (liq) –

    Formulation

    (Kl/Month)

    - 2600 2600

    29 Ammonium Salt of

    Glyphosate

    (liq) –

    Formulation

    (Kl/Month)

    - 2600 2600

    30 Sodium Salt of

    Aceflorofen

    Formulation

    - 1500 1500

    CS2 (Carbon Disulfide)

    Plant

    31 Carbon Disulfide

    - 3000 3000

    MnSO4 (Manganese

    Sulfate)

    Plant

    32 MnSO4 (31%)

    - 10000 10000

  • 2 The unit already has 50 MW CPP and additional 37.5 MW CPP is proposal

    to be added. Cooling Towers/ N2 Plant, Compressor, chilling unit,

    Biological ET, DM plant, Fire Fighting System etc. shall be added. Total

    cost of the expansion is Rs. 473.74 Crores and recurring cost will be Rs.

    07.00 Crores. The company has total 8,85,601 sq m (218 acres) of land

    and the proposed expansion project will be in the existing premises. Out

    of this, about 91,655 sq m is covered as green belt and greenery and an

    additional agricultural or forest land is involved in the project site and no

    eco-sensitive zone is involved in 7 km area of the project site. However,

    about 21 Reserve Forests exist with 10 to 24 km from the site.

    Noted

    3 The project activities are listed at 4(c) and 5(b) in the schedule of the

    EIA Notification, 2006 and are of ‘A’ category. The project is submitted

    under the EIA Notification, 2006 for evaluation of the completeness of

    Draft EIA/EMP and for additional TORs, if any, as per Para 2.2.1(b) of

    the Ministry. The Interim Operational Guidelines dated 13th October

    2006 issued by the Ministry, The additional information as desired by

    the committee were submitted by the proponent, since the proposed

    project is industrial area, it would not need Public Consultation as per

    Para 7(i) III, Stage (3) (b) – public construction of EIA Notification

    2006.

    -

    4 Based on the information provided, the Ministry of Environment and

    Forests hereby accords environmental clearance to above project under

    the provisions of EIA Notification dated 14th September 2006 subject

    to the compliance of the following specific and General conditions:

    -

    5 SPECIFIC CONDITIONS: I The gaseous emissions (SO2, NOx, HCl, Cl2, CH4, P2O5, DMS, H2S, HC,

    PCl3, NH4, CS2 AND CO, HC and RSPM from various process units shall

    conform to the standards prescribed by the concerned authorities from

    time to time. At no time, the emission levels shall go beyond the stipulated

    standards. In the event of failure of pollution control system(s) adopted

    by the unit, the respective unit shall not be restarted until the control

    measures are rectified to achieve the desired efficiency.

    Noted and

    complied. We have

    regular monitoring

    internally and

    externally .All

    parameters are

    well within the

    limit.

    II New standards for pesticides unit, as proposed by the CPCB under the

    E(P) A, 1986 shall be followed by the Unit.

    Noted and

    complied.

    III Three new boilers shall be based on Imported Coal/Lignite/ RDF (pellets

    or fluff). Fuel for other boilers and D.G. Sets will be Natural Gas, HSD

    and FO.

    Noted

    IV Natural Gas, H2 and Cl2 shall be transported through pipelines. Present

    transportation mode of hazardous Chemicals by road shall be switched

    over to railway line as soon as it is laid down. All Transportation of

    Hazardous Chemicals shall be as per the MVA, 1989

    Noted

  • V 23 additional Stacks shall be provided for dispersion of gaseous emissions.

    The height of these shall be as per the Prescribed Stack Height rules

    and CPCB guidelines. For process emissions like HCl, Cl2, SO2, PCl3, CS2

    etc. Scrubbers shall be provided with each reactor for quenching. Waste

    air de-chlorination system shall be provided in the Caustic chlorine Plant,

    Vent gases from 2, 4-Dichloro Phenol shall be subjected to two-stage

    absorption consisting of DM water and caustic jet. For Chlorine, 2 stages

    Scrubber with recovery of Sodium Hypo shall be provided.

    Noted and

    complied.

    Scrubbers

    provided for

    Mancozeb plant to

    control process

    emissions.

    VI Water/ Alkali Two stage Scrubber systems, Mist Eliminator with Koch

    filter and Vet Scrubber with Mist Eliminator shall be installed for the

    boilers. Thermic Fluid heater, D.G.Sets, The scrubbed water shall be sent

    to ETP for further treatment.

    Complied

    VII Flare system shall be provided for burning of contaminated H2 and Fume

    incinerator shall be provided for decomposition of contaminated air/gas

    from the plant.

    Noted

    VIII For CPP, ESP will be provided which will meet SPM limits with in 50

    mg/nm3.

    Noted

    IX All liquid row material shall be stored in storage Tanks and Drums Complied

    X Regular monitoring for SO2, NOx, HCl, Cl2,, CH4, P2O5, DMS, H2S, HC,

    PCl3, NH3, CS2 and VOC along with SPM and RSPM in the ambient air at

    carious probable locations in the plant shall be carried out.

    Complied. Company

    have regular

    monitoring

    internally and

    externally . All

    parameters are

    well within limits.

    XI The location if ambient air quality monitoring station shall be reviewed in

    consultation with the State Pollution Control Board (SPCB) and additional

    stations shall be installed, if required in the downwind direction as well as

    where maximum ground level concentration are anticipated.

    Noted and

    complied.

    XII Use if toxic solvent like Methylene Chloride (MC) etc. shall be minimized

    to the extent possible. Benzene shall not be used as solvent and no

    odorous compounds/ gas like Mercaptans or Hydrogen Sulfide shall be

    used or formed in any of reactions at the site.

    Noted

    XIII Bioassay test and toxicity index shall be carried out regularly. Complied

    XIV All the storage tanks shall be under negative pressure to avoid any

    leakages. Breathers, N2 blanketing and condensers will be provided for all

    the storage tanks. Closed handling systems for chemicals and solvents will

    be provided. Magnetic seals will be provided for pumps/agitators for

    reactors for reduction of fugitive emission, Chilled Brine based

    condensers shall be used to prevent VOC emission. Solvent traps shall be

    installed wherever necessary.

    Complied

    XV All venting equipment shall have vapour recovery system. All the pumps

    and other equipment’s where there is a likelihood of HC leakages shall be

    provided with Leak Detection and Repair (LDAR) system and LEL

    indicators and Hydrocarbon detectors. Provision for immediate isolation

    of such equipment, in case of a leakage will also be made. The company

    shall provide a well defined Leak Detection and Repair (LDAR) programme

    for quantification and control of fugitive emissions. The detectors

    sensitivity will be in ppm levels.

    Complied

  • XVI Spent solvents shall be recovered as possible & solvent recovery shall be

    further increased from the present 95% to at least 98% percent.

    Solvent vapours emitted during purification process from purification

    tanks as fugitive emissions shall be reduced as far as possible.

    Noted and

    complied.

    XVII Portable monitoring instruments for all relevant gases like Chlorine and

    Ammonia shall be provided.

    Complied. Chlorine

    sensors are

    provided.

    XVIII Fugitive emissions in the work zone environment, product, raw materials

    storage area shall be regularly monitored for all relevant parameters. The

    emissions shall conform to the limits imposed by the State Pollution

    Boards/Central Pollution Control Board.

    Complied.

    Online sensors are

    provided for

    monitoring Fugitive

    emissions like

    Chlorine, H2S etc.

    XIX No ground water shall be used for the project. Water requirement will not

    exceed 10,000 m3/day, which will be met through GIDC Water supply.

    Complied. Our

    water consumption

    is well within the

    limit.

    XX Daily waste water generation will not exceed to 4,575 m3/day. The whole

    waste water shall be treated in the proposed two ETPs. One Effluent

    Treatment Plant shall consist of primary, secondary and tertiary

    treatment units for the proposed Pesticide, CS2 and MnSO4 Plants. The

    inorganic stream shall be sent to CETP after the primary treatment. The

    Biodegradable stream shall be treated up to tertiary treatment. High

    TDS and low COD stream shall taken to MEE System and High Organic

    (high COD) stream will be incinerated. The final treated effluent will be

    collected in collection sump and discharged through GIDC drainage line.

    The effluent generated from the proposed 350 TPD Caustic Chlorine and

    enhanced CPP which will be modified. The effluent generated from the

    proposed pesticides in the proposed ETP. The treated effluent shall be

    sent to CETP of BEAIL for final discharge into the deep sea through

    closed pipeline. No free solvent shall go to the ETP.

    Complied.

    Effluent treatment

    plant consisting

    primary, Secondary

    and tertiary

    treatment.

    Augmented the

    treatment system

    with Hypo

    treatment to meet

    the Ammonical

    Nitrogen

    XXI Hazardous / Solid Waste generated shall be as per the list and quantities

    submitted to this Ministry as per the letter no. UJH/PRO/17/2007 dated

    14th May 2007. On-site Incinerator shall be installed to incinerate

    incinerable waste. Otherwise the waste shall de sent to the Common

    Incinerator of BEIL. Land fillable waste shall be sent to BEIL-TSDF.

    Complied.

    We have taken

    membership of

    BEIL and sending

    material to BEIL

    regularly.

    XXII Emissions from the incinerator shall be the prescribed norms for the

    incinerators. Monitoring Protocol as prescribed in these standards shall

    be followed.

    Noted

    XXIII Fly ash generated from the CPP will be utilized for Brick manufacturing

    and for Cement manufacturing as per the Fly Ash Utilisation Notification.

    Noted

    XXIV All safety measures suggested in the letter no. UJH/PRO/17/2007 dated

    14th May 2007 for the solvent and reactants storage shall be

    implemented

    Noted & complied

    XV The company shall undertake following Waste Minimization measures.

    A Metering and control of quantities of active ingredients to minimize

    waste.

    Noted and

    complied

  • B Reuse of by-products from the process as raw materials or as raw

    material substitutes in other processes.

    Complied

    C Use of automated filling to minimize spillage. Complied

    D Use of “Close Feed” system into batch reactors. Complied

    E Venting equipment through vapour recovery system. Complied

    F Use of high pressure hoses for equipment clearing to reduce wastewater

    generation.

    Noted

    G The project authorities shall strictly comply with the provisions made in

    Manufacture, Storage and Import of Hazardous Chemicals Rules, 1989 as

    amended in 2000 for handling of hazardous chemicals. Necessary

    approvals from Chief Controller of Explosives must be obtained before

    commissioning of the expansion project. Requisite On-Site and Off-Site

    Disaster Management Plans will be prepared and implemented. Regular

    mock drills shall be carried out for both On-Site and Off-Sit plans.

    Noted

    H The company shall develop rain water harvesting structures to harvest

    the run off water for recharge of ground water.

    Noted

    I Minimum 25% of the total area shall be developed as green belt as per the

    CPCB guidelines. Additional 1,12,091 sq.m shall be developed as green belt.

    Noted

    J Occupational health surveillance of the workers shall be done on a regular

    basis and records maintained as per the Factories Act.

    Complied

    K Training shall be impaired to all employees on safety and health aspects of

    chemicals handling. As informed to the Ministry. OHSAS 18001 shall be

    continued. Pre employment and routine periodical medical examinations for

    all employees shall be undertaken on regular basis. Training to all

    employees on handling of chemicals shall be imported.

    Complied

    L Usage of PPEs by all employees/ workers shall be ensured. Complied

    M The company shall strictly follow all the recommendations mentioned in

    the Charter on Corporate Responsibility for Environmental Protection

    (CREP).

    Complied

    N The company shall harvest surface as well as rainwater from the rooftops

    of the buildings proposed in the expansion project and storm water drains

    to recharge the ground water and use the same water for various

    activities of the project to conserve fresh water.

    Noted

    O All the recommendations made by the consultants in respect of

    environmental management and risk mitigation measures relating to the

    project shall be implemented.

    Complied

    P The company shall undertake all relevant measures as indicated during the

    Public Hearing for improving the Socio-economic conditions of the

    surrounding area. CSR activities will be undertaken by involving local

    villages and administration.

    Complied

    Q The company shall undertake eco-developmental measures including

    community welfare measures in the project area for the overall

    improvement of the environment. The eco-development plan should be

    submitted to the SPCB within three months of receipt of this letter for

    approval.

    Noted

    GENERAL CONDITIONS

    I The project authorities shall strictly adhere to the stipulations made by

    the State Pollution Control Board.

    Complied

  • II No further expansion or modifications in the plant shall be carried out

    without prior approval of the Ministry of Environment and Forests. In

    case of deviations or alterations in the project proposal from those

    submitted to this Ministry for clearance, a fresh reference shall be made

    to the Ministry to assess the adequacy of conditions imposed and to odd

    additional environmental protection measures required, if any.

    Noted and

    complied.

    We have obtained

    Consent to

    Establish (NOC)

    from GPCB for

    products mix

    change and applied

    for Consent to

    operate(CC&A) .

    NOC copy is

    attached in

    Annexure -1 for

    your ready

    reference.

    III At no time, the emissions shall exceed the prescribed limits. In the event

    of failure of any pollution control system adopted by the unit, the unit

    shall be immediately put out of operation and shall not be restarted until

    the desired efficiency has been achieved.

    Noted and

    Complied.

    IV The project authorities shall strictly comply with the rules and

    regulations under Manufacture, Storage and Import of Hazardous

    Chemicals Rules, 1989 as amended in October, 1994 and January, 2000.

    Authorization from the SPCB shall be obtained for collection, treatment,

    storage, and disposal of hazardous wastes.

    Complied

    V The over all noise levels in and around the plant area shall be kept well

    within the standards by providing noise control measures including

    acoustic hoods, silencers, enclosures etc. on all sources of noise

    generation. The ambient noise levels shall conform to the standards

    prescribed under Environment (protection) Act,1986 Rules, 1989 viz. 75

    dBA (day time) and 70 dBA (night time).

    Complied

    VI The project proponent shall also comply with all the environmental

    protection measures and safeguards recommended in the EIA/EMP

    report.

    Complied

    VII A separate Environmental Management Cell equipped with full fledged

    laboratory facilities shall be set up to carry out the Environmental

    Management and Monitoring functions.

    Complied

    VIII The project authorities shall earmark separate funds of Rs. 43.09 Crores

    to implement the conditions stipulated by the Ministry of Environment

    and Forests as well as the State Government along with the

    implementation schedule for all the conditions stipulated herein. Rs. 07.00

    crores will be the annual recurring expenditure for environmental

    protection measures. The funds so provided shall not be diverted for any

    other purpose.

    Noted and being

    complied

    IX The implementation of the project vis-à-vis environmental action plans

    shall be monitored by the concerned Regional Office of the Ministry /

    SPCB / CPCB. A six monthly compliance status report shall be submitted

    to monitoring agencies.

    Complied

  • X The project proponent shall inform the public that the project has been

    accorded environmental clearance by the Ministry and copies of the

    clearance letter are available with the SPCB/Committee and may also be

    advertised within seven days from the date of issue of the clearance

    letter at least in two local newspapers that are widely circulated in the

    region of which one shall be in the vernacular language of the locality

    concerned and a copy of the same shall be forwarded to the concerned

    Regional Office of the Ministry.

    Complied

    XI The project authorities shall inform the Regional Office as well as the

    Ministry, the date of financial closure and final approval of the project by

    the concerned authorities and the date of start of the project.

    Complied

    XII The Ministry may revoke the right to stipulated additional conditions, if

    found necessary. The company in a time bound manner will implement

    these conditions.

    Noted

    XIII The above conditions will be enforced, inter-alia under the provisions of

    the Water (Prevention & Control of Pollution) Act, 1981, the Environment

    (Protection) Act, 1986 Hazardous Waste (Management and Handling)

    Rules, 2003 and the Public Liability Insurance Act, 1991 along with their

    amendments rules.

    Noted

  • UNITED PHOSPHORUS LTD., UNIT NO. 5 JHAGADIA

    STATUS CUM COMPLIANCE REPORT FOR ENV. CLEARANCE NO. J-

    11011/42/95-A.II (1), DTD. 17TH. MAY, 1996 OF 100 TPD CHLOR-ALKALI PLANT

    Sr. No.

    Condition Status

    1 To adhere GPCB and state Govt. stipulation Complied as per CCA No. 10067 Dated 25th February 2008 valid up to 18.12.2012

    2 To intimate MoEF about any project coming up in the premises

    Complied. As and when new projects are coming up, we will intimate MOEF. We have obtained Consent to Establish (NOC) from GPCB for products mix change and applied for Consent to operate(CC&A) . NOC copy is attached in Annexure -1 for your ready reference.

    3 Gaseous (CL2, SO2, Nox, HC) and particulate emission from the various process vents and storage tanks should conform to the standards.

    Complied Parameters are within limits.

    4 Three AAQ to install • Stack emission to monitor regularly

    • To submit AAQ + Stack report to MoEF once in six

    month with statistical analysis and interpretation

    • 3 AAQ installed for monitoring of PM10,PM2.5, SO2,NOX & CL2.

    • CL2,HCl Monitored in Hypo & HCl stacks

    • Results are being submitted in half yearly reports. It is well within stipulated norms.

    5 Fugitive emission monitoring and data recorded Chlorine sensor is to be installed in the chlorine

    storage area at lower level between the tanks

    16 Cl2 sensors at strategic locations & monitored on DCS.

    6 • Liquid effluents coming out of the plants should be confirmed to the standard prescribed by the GPCB

    • Recycling and reuse of the treated waste water should be maximized

    • Complied • Steam condensate of

    Caustic Evaporation reused in Brine make up & Cooling tower make up

    7 • Adequate measures for the control noise levels below 85dB.

    • Employees to be provided with PPE.

    • Engineering Control measures to reduce noise

    • Monitoring done monthly. Range is from 70 to 75dB

    • Ear muffs & ear plugs are provided to the person working in high noise area like H2 compressor, & air compressor

    • Acoustic enclosures provided

  • 8 Occupational health surveillance program with respect to exposure to chlorine, thermal stresses and noise pollution.

    Complied. We are doing half yearly

    medical check up. We are also doing full body medical check up by external expert agency once in two years. All records are maintained

    9 • Green belt of adequate width & density covering 25 acres of land should be developed

    • Treated effluent to be used for green belt development

    • Complied • Presently we have about

    39295 trees • Sewage water is used for

    gardening

    10 • Educate the neighboring people for accidental release of chlorine

    • To install wind sock • Necessary approval from CCE & Chief Inspector of

    Factories

    • Complied. • Disclosure of Information

    on Cl2 to general public is given in book let thriceand also conducted awareness program in the year 1999 & 2005

    • We have installed 14wind socks inside the factory

    • Obtained CCE approval

    for CL2 Storage, filling in toners, hydro testing. Also for H2 filling & storage.

    • Maps of plant approved & inspected by Chief Inspector of Factories(Director – Industrial Safety & Health, Gujarat State)

    11 Hazardous waste handling as per rules 1989 Complied Yearly return submission is

    done for solid waste generation & disposal to GPCB

    12 To follow hazardous chemicals Mfg./Storage/Handling / import Rules1989-1994

    Complied. MSIHC guidelines followed

    for e.g On site emergency plan, MSDS etc.

    13 To set up laboratory for collection & analysis of sample

    Complied Laboratory is in operation &

    regular analysis is being done for waste water, stacks & ambient air, ground water etc.

  • 14 Set up Environment management cell Internal Environment management cell comprising of Unit Head, plant head, SHE Head & Corporate Environmenthead is in operation for close monitoring. The environment cell verifies environmental performance and involves in environmental audit

    15 • Funds earmarked during project for Env. protection • Year wise expenditure to be submitted to MoEF

    • Complied. • Project has been

    commissioned since 1997 with compliance of all environment related protection

    • Statement of expenditure submitted half yearly.

    16 Six monthly - Half yearly report submission to MoEF • Being submitted regularly

  • UNITED PHOSPHORUS LTD., UNIT NO. 5 JHAGADIA

    STATUS CUM COMPLIANCE REPORT FOR ENV. CLEARANCE NO.

    J.13011/26/96-1A.II, DTD. 24TH. DEC., 1996 OF 50 MW COMBINED CYCLE CO. GENERATION POWER PLANT.

    Sr. Sr. Sr. Sr. No.No.No.No.

    ConditionConditionConditionCondition StatusStatusStatusStatus

    1 All the conditions stipulated in the GPCB NOC No. PC/NOC/-BRCH-1611/9518 should be implemented

    Complied for effluent quantity & quality norms

    2 An area of 103 acres only to be acquired for power plant including green belt development

    Complied. Power plant is included in the area of 103 acres

    3 Three stack of height 30m, 35m, 7m for Gas Turbine, HRSG, DG sets should be installed

    Installed & commissioned

    4 Ambient air quality should be regularly monitored and results should be submitted to the MoEF every six months

    We are submitting results half yearly to MOEF along with Half yearly EC compliance report.

    5 Sulfur content in Naphtha should not exceed 0.15%

    Condition is not applicable now as we have switched over from Naphtha to Natural Gas from June 2002 and consent has been obtained

    6 Nox control system should be installed to ensure that Nox emission should not exceed 50 ppm

    Nox is well within norms.

    7 To use effluent for green belt development It is being used

    8 Water used for plant should be restricted to 6480 KL/Day

    It ranges from 1200 to 1500 KL/Day

    9 • Adequate measured for Noise control below -85 dB

    • To give PPE to employees

    • Enclosures provided to control noise

    • People use ear muffs & ear plugs

    10 Green belt development @ 1500-2000 trees / hectares

    Presently we have about 39295trees in 20.75 Acres.

    11 Land fill site provided No solid waste generation from power plant. Power Plant fuel is Natural Gas.

    12 To build thermal proof wall between Naphtha tanks and switch yard

    Not applicable as we have switched over from Naphtha to Natural Gas.

    13 Sludge from common sludge tank to be incinerated and disposed in the land fill site

    No such sludge is generated which requires incinerator

    14 Full cooperation should be extended to the statutory authority during their visit

    Noted the point

    15 Funds earmarked for Env. protection during project

    Project has been commissioned since 1997 with compliance of all environment related protection

  • 16 Environment monitoring committee should be constitute

    As our plant is commissioned since long Internal Environment management cell comprising of Unit Head, plant head, SHE Head & Corporate Environment head is in operation for close monitoring.

    After implementation of the project, we have constituted a monitoring committee and the last meeting was conducted in September - 2002

    We have carried out a meeting involving various stakeholders including the monitoring members in September 2005 in connection with information on the change over of fuel from naphtha to natural gas as we are working on CDM project.

    17 Any deviation or alternation in project need fresh reference to the ministry

    There was no deviation during project. However subsequently raw material change from Naphtha to Natural Gas in 2002

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Effluent Sample Analysis Report

    Report No. ME-BH-0333-120113-SA-UPL-5-JH Date: 13.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Industrial Effluent/Grab

    Sample Collectedby

    Laboratory

    Sampling Location ETP Outlet (Treated Effluent)

    Sample Quantity/Packing

    20 L X 1 No. PVC Can

    Date of Sampling 04.01.2012 Date of Receipt of Sample

    07.01.2012

    Sampling Procedure

    IS:3025(Part I) 1987 RA1998

    Date of Start of Analysis

    09.01.2012 Date of Completion of Analysis

    12.01.2012

    Sr. No.

    Parameters Unit Results GPCB LIMIT

    Method Reference

    1. pH - 7.12 5.5 to 8.5 APHA, 21st Ed., 2005, 4500 - H+

    2. Temperature oC 26.0 40 oC IS 3025, Part 9:1983, RA 2002

    3. Colour Hazen 10.0 100 APHA, 21st Ed., 2005, 2120 – B,C

    4. Total Residual Chlorine

    mg/L N.D 1.0 IS-3025, Part 26:1986, RA 2003 Eds 2.1(2004-02)

    5. Total Dissolved Solids (TDS)

    mg/L 9964 2100 APHA, 21st Ed., 2005, 2540 - C

    6. Total Suspended Solids (TSS)

    mg/L 12.0 100 APHA, 21st Ed., 2005, 2540 - D

    7. Oil and Grease mg/L

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Report No. ME-BH-0333-120131-SA-UPL-5-JH Cont… 22. Copper as Cu mg/L < 0.03 2.0 APHA, 21st Ed., 2005, 3500-Cu - B

    23. Chromium Hexavalent as Cr6+

    mg/L < 0.02 0.1 APHA, 21st Ed., 2005, 3500-Cr - B

    24. Total Chromium as Cr

    mg/L < 0.02 2.0 APHA, 21st Ed., 2005, 3111 – B

    25. Mercury as Hg mg/L < 0.0008 0.01 APHA, 21st Ed., 2005, 3112 – B

    26. Arsenic as As mg/L 0.011 0.2 IS 3025, Part 37:1988, RA 2003

    27. Cadmium as Cd mg/L 0.019 2.0 APHA, 21st Ed., 2005, 3111 – B

    28. Total Heavy Metal mg/L < 2 7.0 By Calculation

    29. Percentage Sodium (% Na)

    % 93.4 60 MERI HANDBOOK

    Remarks: N.D. – Not Detectable

    .----------------------------------------------------------End------------------------------------------ for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY ---------------- ---------------------------------------------------------------------

    Note: 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the

    laboratory.

    Page 2 of 2

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0337-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Power Plant Turbine Stack 2. Power Plant HRSG Stack Sample Quantity/Packing

    50 mL X 2 No. PVC Bottle and 1 X 1 No. Thimble

    Date of Sampling 05.01.2012 Date of Receipt of Sample

    10.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis

    11.01.2012 Date of Completion of Analysis

    16.01.2012

    Stack No. 1 2

    Stack attached to Power Plant Turbine Stack Power Plant HRSG Stack

    Material of construction M.S. M.S.

    Stack height above ground level (Meter) 30.0 35.0

    Stack diameter(Meter) 3.0 3.0

    Stack shape at top Round Round

    Type of fuel N.G. N.G.

    Flue gas Temperature (0C) Not 135

    Flue gas Velocity (m/sec) In 14.1

    Total gas quantity (Nm3/hr) Operation 262066

    Parameter Unit Results GPCB Limit Method Reference

    Particulate Matter mg/Nm3 -- BDL 150 IS 11255 (Part 1):1985 RA-2003

    Sulphur Dioxide (SO2) ppm -- BDL 100 IS 11255 (Part 2):1985 RA -2003

    Oxides of Nitrogen (NOx) ppm -- 29.2 50 IS 11255 (Part 7):2005

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0342-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Stack Emission Sample Collectedby Laboratory

    Sampling Location 1. Caustic Scrubber WAD 56-TPD Plant 2. Caustic Scrubber WAD 100-TPD Plant 3. Caustic Scrubber HCl Furness 56-TPD Plant 4. Caustic Scrubber HCl Furness 100-TPD Plant

    Sample Quantity/Packing

    50 mL X 3 No; 100mL X 3No. PVC Bottle

    Date of Sampling

    06.01.2012 Date of Receipt of Sample

    10.01.2012

    Sampling Procedure As per IS: 11255 and IS: 5182

    Date of Start of Analysis

    11.01.2012 Date of Completion of Analysis

    16.01.2012

    Stack No. 1 2 3 4

    Stack attached to

    Caustic Scrubber of WAD 56-TPD Plant

    Caustic Scrubber of WAD 100-TPD Plant

    Caustic Scrubber of HCl Furness 56-TPD Plant

    Caustic Scrubber of HCl Furness 100-TPD Plant

    Material of construction H.D.P.E. H.D.P.E. F.R.P. F.R.P.

    Stack height above ground level (Meter) 30 30 30 30

    Stack diameter(Meter) 0.2 0.15 0.15 0.25

    Stack shape at top Round Round Round Round

    Type of fuel Process

    Scrubber Process

    Scrubber Process

    Scrubber Process

    Scrubber

    Flue gas Temperature (0C) 30 30 Not 45

    Flue gas Velocity (m/sec) 4.6 8.1 In 5.6

    Total gas quantity (Nm3/hr) 512 507 Operation 927

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL -- BDL 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 10.8 5.2 -- 14.8 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0338-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Di-Choloro Phenol Plant 2. Phosphorus Oxi-Chloride Plant 3. Phosphorus Acid Plant

    Sample Quantity/Packing

    50 mL X 1 No. PVC Bottle

    Date of Sampling 05.01.2012 Date of Receipt of Sample

    10.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis

    11.01.2012 Date of Completion of Analysis

    16.01.2012

    Stack No. 1 2 3

    Stack attached to

    Water & Caustic Scrubber of DCP Plant Reactor

    Caustic Scrubber of Phosphorus Oxy-Chloride Plant Distillation Column

    Water & Caustic Scrubber OR Ventury Scrubber of H3PO4 Scrubber Reactor

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.15 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process Scrubber Process

    Scrubber Process

    Scrubber

    Flue gas Temperature (0C) Not 30 Not

    Flue gas Velocity (m/sec) In -- In

    Total gas quantity (Nm3/hr) Operation -- Operation

    Parameter Unit Results GPCB Limit

    Method Reference

    Sulphur Dioxide (SO2)

    mg/Nm3 -- -- -- 40 IS 11255 (Part 2):1985 RA -2003 Oxides of Nitrogen (NOx) mg/Nm

    3 -- -- -- 25 IS 11255 (Part 7):2005

    Chlorine (Cl2) mg/Nm3 -- -- -- 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 -- 6.4 -- 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laborator

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0339-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location

    1. Caustic Scrubber of Distillation Section of PCl3 Plant

    2. Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    3. Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Sample Quantity/Packing

    50 mL X 5 No; 100mL X 3 No. PVC Bottle

    Date of Sampling 05.01.2012 Date of Receipt of Sample

    10.01.2012

    Sampling Procedure As per IS: 11255 and OSHA: 6402

    Date of Start of Analysis

    11.01.2012 Date of Completion of Analysis

    16.01.2012

    Stack No. 1 2 3

    Stack attached to

    Caustic Scrubber of Distillation Section of PCl3 Plant

    Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.2 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process

    Scrubber Storage Scrubber

    Process Scrubber

    Flue gas Temperature (0C) 30 30 30

    Flue gas Velocity (m/sec) -- -- --

    Total gas quantity (Nm3/hr) -- -- --

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL 1.6 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 4.4 4.9 17.6 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Phosphorus Tri-Chloride Vapours (PCl3) mg/Nm

    3 0.8 BDL -- 9 OSHA Method No.6402, 1985

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Ambient Air Quality Monitoring Report Report No.: ME-BH-0334-120113-SA-UPL-5-JH Date: 13.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Ambient Air Sample Collected by Laboratory

    Sampling Location Nr. U.G.Tank Sample Quantity/Packing

    30 mL X 8 No; 100mL x 1 No. PVC Bottle, 1 No. Filter Paper and 2L X 1 No. Bladder

    Date of Sampling 04.01.2012 Date of Receipt of Sample

    07.01.2012

    Sampling Procedure As per CPCB Guidelines and IS: 5182

    Date of Start of Analysis

    09.01.2012 Date of Completion of Analysis

    12.01.2012

    Meteorological Data/ Environmental Conditions

    Avg. Wind Velocity km/hr

    Prominent Wind Direction Relative Humidity

    (%) Temperature

    (0C)

    3.9 NE - SW Max Min Max Min 54 31 30 11

    Location Nr. U.G.Tank Duration of Survey 24 hrs

    Sr. No.

    Parameter Result Unit GPCB Limit

    Method Reference

    1. Respirable Suspended Particulate Matter (RSPM)

    58.4 µg/m3 100 CPCB Guidelines

    2. Oxides of Sulphur (SOx) 12.36 µg/m3 80 CPCB Guidelines

    3. Oxides of Nitrogen (NOx) 14.8 µg/m3 80 CPCB Guidelines

    4. Hydro Chloride Vapour (HCl) 36.7 µg/m3 200 Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    5. Chlorine (Cl2) BDL µg/m3 100 IS 5182 (Part 19):1982, RA 2003

    6. Ammonia (NH3) BDL µg/m3 400 APHA Method No. 401, 2nd Edition

    7. Hydrogen Flouride (HF) BDL µg/m3 160 IS 5182, Part 13:1991

    8. Hydrogen Sulphide (H2S) BDL µg/m3 500 IS 5182, Part 7:1999

    9. Carbon Di-Sulphide (CS2) 247 µg/m3 2000 IS 5182 Part 20 1999

    10. Hydrocarbon (H.C.) BDL µg/m3 160 IS 5182, Part 17:1979

    11. Phosphorus Pent-oxide Fumes (P2O5) BDL µg/m3 70 APHA 25ST Edition 4500, P - D

    Remarks : BDL – Below Detectable Limit

    ----------------------------------------------------------End------------------------------------------ for Mahabal Enviro Engineers Pvt. Ltd. Harish Mendhi Technical Manager AUTHORISED SIGNATORY

    ---------------- --------------------------------------------------------------------- Note: 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Noise Level Monitoring Report

    Report No.: ME-BH-0340-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT – 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Noise Level Sample Collected by

    Laboratory

    Sampling Location As mentioned bellow Sample Quantity/ Packing

    Not Applicable

    Date of Sampling 05.01.2012 Date of Receipt of Sample

    Not Applicable

    Sampling Procedure

    Noise Level Meter

    Location Unit Results Norms

    dB(A) Leq DAY NIGHT

    Fencing Wall East Side (Nr. C-Tech. ETP)

    dB(A) Leq

    74.5 71.2

    Day(06.00-22.00) – 75

    Night(22.00-06.00) - 70

    Fencing Wall North Side (Nr. Raise Plant)

    67.9 64.9

    Fencing Wall South Side (Nr. Secondary Brine)

    74.1 70.3

    Fencing Wall West Side (Nr. Salt Yard)

    66.3 60.1

    --------------------------------------------End------------------------------------- For Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY

    ------------------------------------------------------------------------------------------------------- Note: 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Noise Level Monitoring Report

    Report No.: ME-BH-0341-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Noise Level Sample Collected by

    Laboratory

    Sampling Location As mentioned bellow Sample Quantity/ Packing

    Not Applicable

    Date of Sampling 05.01.2012 Date of Receipt of Sample

    Not Applicable

    Sampling Procedure

    Noise Level Meter

    Location Unit Results Norms

    dB(A) Leq DAY NIGHT

    Primary Brine

    dB(A) Leq

    78.5 73.4

    TLV - 90

    Secondary Brine 77.1 71.2

    H2 Compressor 86.2 80.1

    Cl2 Compressor 87.3 83.9

    Utility Block – Mechanical 95.5 97.3

    WP-CO Pump 65.3 62.5

    Power Plant GT 85.8 85.7

    Utility – MNZ 89.1 87.6

    D – 14 Tank- MNZ 80.2 79.1

    SPD-Panel Room – MNZ 73.4 73.1

    Security Gate 75.1 71.4

    1 MLD ETP– C-Tech Blowers 78.2 74.5

    Belt Filter Vacuum Pump - MNZ 87.4 83.2

    --------------------------------------------End------------------------------------- For Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY

    ------------------------------------------------------------------------------------------------------- Note: 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0342-120118-SA-UPL-5-JH Date: 18.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Alkali Scrubber of Mancozeb Plant Reactor D-14

    2. Water Scrubber of Wet Spray Dryer of Mancozeb Plant

    3. Bag Filter of RVDF of Mancozeb Plant

    Sample Quantity/Packing 1 X 1 No. Thimble

    Date of Sampling 06.01.2012 Date of Receipt of Sample

    10.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis

    11.01.2012 Date of Completion of Analysis

    16.01.2012

    Stack No. 1 2 3

    Stack attached to Alkali Scrubber of Mancozeb Plant Reactor D-14 New EDA Scruber

    Water Scrubber of Wet Spray Dryer of Mancozeb Plant

    Bag Filter of RVDF of Mancozeb Plant

    Material of construction S.S. M.S. M.S.

    Stack height above ground level (Meter) 30.0 30.0 35.0

    Stack diameter(Meter) 0.1 1.8 0.2

    Stack shape at top Round Round Round

    Type of fuel Process Scrubber Process Stack Process Stack

    Flue gas Temperature (0C) Not 59 Not

    Flue gas Velocity (m/sec) In 8.7 In

    Total gas quantity (Nm3/hr) Operation 72143 Operation

    Parameter Unit Results GPCB Limit

    Method Reference

    Particulate Matter

    mg/Nm3 -- 18.6 -- 20 IS 11255 (Part 1):1985 RA-2003 Hydrogen Sulphide (H2S)

    mg/Nm3 -- -- -- 45 IS 11255 (Part 4):1985 RA-2003 Carbon Di-Sulphide (CS2)

    mg/Nm3 -- -- -- 180 IS 11255 (Part 4):1985 RA -2003

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0354-120130-SA-UPL-5-JH Date: 30.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Power Plant Turbine Stack 2. Power Plant HRSG Stack Sample Quantity/Packing

    50 mL X 2 No. PVC Bottle and 1 X 1 No. Thimble

    Date of Sampling 20.01.2012 Date of Receipt of Sample 24.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis 24.01.2012

    Date of Completion of Analysis 28.01.2012

    Stack No. 1 2

    Stack attached to Power Plant Turbine Stack Power Plant HRSG Stack

    Material of construction M.S. M.S.

    Stack height above ground level (Meter) 30.0 35.0

    Stack diameter(Meter) 3.0 3.0

    Stack shape at top Round Round

    Type of fuel N.G. N.G.

    Flue gas Temperature (0C) Not 133

    Flue gas Velocity (m/sec) In 13.4

    Total gas quantity (Nm3/hr) Operation 251047

    Parameter Unit Results GPCB Limit Method Reference

    Particulate Matter mg/Nm3 -- BDL 150 IS 11255 (Part 1):1985 RA-2003

    Sulphur Dioxide (SO2) ppm -- BDL 100 IS 11255 (Part 2):1985 RA -2003

    Oxides of Nitrogen (NOx) ppm -- 28.5 50 IS 11255 (Part 7):2005

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0355-120131-SA-UPL-5-JH Date: 30.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Stack Emission Sample Collectedby Laboratory

    Sampling Location 1. Caustic Scrubber WAD 56-TPD Plant 2. Caustic Scrubber WAD 100-TPD Plant 3. Caustic Scrubber HCl Furness 56-TPD Plant 4. Caustic Scrubber HCl Furness 100-TPD Plant

    Sample Quantity/Packing

    50 mL X 3 No; 100mL X 3No. PVC Bottle

    Date of Sampling 20.01.2012 Date of Receipt of Sample 24.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis 24.01.2012

    Date of Completion of Analysis

    28.01.2012

    Stack No. 1 2 3 4

    Stack attached to

    Caustic Scrubber of WAD 56-TPD Plant

    Caustic Scrubber of WAD 100-TPD Plant

    Caustic Scrubber of HCl Furness 56-TPD Plant

    Caustic Scrubber of HCl Furness 100-TPD Plant

    Material of construction H.D.P.E. H.D.P.E. F.R.P. F.R.P.

    Stack height above ground level (Meter) 30 30 30 30

    Stack diameter(Meter) 0.2 0.15 0.15 0.25

    Stack shape at top Round Round Round Round

    Type of fuel Process Scrubber

    Process Scrubber

    Process Scrubber

    Process Scrubber

    Flue gas Temperature (0C) 30 30 Not 42

    Flue gas Velocity (m/sec) 4.6 7.9 In 5.5

    Total gas quantity (Nm3/hr) 512 494 Operation 919

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL -- BDL 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 6.3 4.8 -- 11.3 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0356-120130-SA-UPL-5-JH Date: 30.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Alkali Scrubber of Mancozeb Plant Reactor D-14

    2. Water Scrubber of Wet Spray Dryer of Mancozeb Plant

    3. Bag Filter of RVDF of Mancozeb Plant

    Sample Quantity/Packing 50 ml X 2 No. PVC Bottle

    Date of Sampling 20.01.2012 Date of Receipt of Sample 24.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis 24.01.2012

    Date of Completion of Analysis

    28.01.2012

    Stack No. 1 2 3

    Stack attached to Alkali Scrubber of Mancozeb Plant Reactor D-14 New EDA Scruber

    Water Scrubber of Wet Spray Dryer of Mancozeb Plant

    Bag Filter of RVDF of Mancozeb Plant

    Material of construction S.S. M.S. M.S.

    Stack height above ground level (Meter) 30.0 30.0 35.0

    Stack diameter(Meter) 0.1 1.8 0.2

    Stack shape at top Round Round Round

    Type of fuel Process Scrubber Process Stack Process Stack

    Flue gas Temperature (0C) 28 Not Not

    Flue gas Velocity (m/sec) -- In In

    Total gas quantity (Nm3/hr) -- Operation Operation

    Parameter Unit Results GPCB Limit

    Method Reference

    Particulate Matter

    mg/Nm3 -- -- -- 20 IS 11255 (Part 1):1985 RA-2003 Hydrogen Sulphide (H2S)

    mg/Nm3 BDL -- -- 45 IS 11255 (Part 4):1985 RA-2003 Carbon Di-Sulphide (CS2)

    mg/Nm3 169 -- -- 180 IS 11255 (Part 4):1985 RA -2003

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0357-120131-SA-UPL-5-JH Date: 30.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Di-Choloro Phenol Plant 2. Phosphorus Oxi-Chloride Plant 3. Phosphorus Acid Plant

    Sample Quantity/Packing

    50 mL X 1 No. PVC Bottle

    Date of Sampling 20.01.2012 Date of Receipt of Sample 24.01.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis 24.01.2012

    Date of Completion of Analysis 28.01.2012

    Stack No. 1 2 3

    Stack attached to

    Water & Caustic Scrubber of DCP Plant Reactor

    Caustic Scrubber of Phosphorus Oxy-Chloride Plant Distillation Column

    Water & Caustic Scrubber OR Ventury Scrubber of H3PO4 Scrubber Reactor

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.15 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process Scrubber Process

    Scrubber Process

    Scrubber

    Flue gas Temperature (0C) Not 30 Not

    Flue gas Velocity (m/sec) In -- In

    Total gas quantity (Nm3/hr) Operation -- Operation

    Parameter Unit Results GPCB Limit

    Method Reference

    Sulphur Dioxide (SO2)

    mg/Nm3 -- -- -- 40 IS 11255 (Part 2):1985 RA -2003 Oxides of Nitrogen (NOx) mg/Nm

    3 -- -- -- 25 IS 11255 (Part 7):2005

    Chlorine (Cl2) mg/Nm3 -- -- -- 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 -- 6.4 -- 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0358-120130-SA-UPL-5-JH Date: 30.01.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Stack Emission Sample Collected by Laboratory

    Sampling Location

    1. Caustic Scrubber of Distillation Section of PCl3 Plant

    2. Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    3. Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Sample Quantity/Packing

    50 mL X 5 No; 100mL X 3 No. PVC Bottle

    Date of Sampling 20.01.2012 Date of Receipt of Sample 24.01.2012

    Sampling Procedure

    As per IS: 11255

    Date of Start of Analysis 24.01.2012

    Date of Completion of Analysis 28.01.2012

    Stack No. 1 2 3

    Stack attached to

    Caustic Scrubber of Distillation Section of PCl3 Plant

    Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.2 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process

    Scrubber Storage Scrubber

    Process Scrubber

    Flue gas Temperature (0C) 30 30 30

    Flue gas Velocity (m/sec) -- -- --

    Total gas quantity (Nm3/hr) -- -- --

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL BDL 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 6.2 7.2 13.8 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Phosphorus Tri-Chloride Vapours (PCl3) mg/Nm

    3 0.9 BDL -- 9 OSHA Method No.6402, 1985

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Effluent Sample Analysis Report

    Report No. ME-BH-0362-120225-SA-UPL-5-JH Date: 15.02.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Industrial Effluent/Grab

    Sample Collectedby

    Laboratory

    Sampling Location ETP Outlet (Treated Effluent)

    Sample Quantity/Packing

    20 L X 1 No. PVC Can

    Date of Sampling 06.02.2012 Date of Receipt of Sample

    07.02.2012

    Sampling Procedure

    IS:3025(Part I) 1987 RA1998

    Date of Start of Analysis

    08.02.2012 Date of Completion of Analysis

    13.02.2012

    Sr. No.

    Parameters Unit Results GPCB LIMIT

    Method Reference

    1. pH - 7.45 5.5 to 8.5 APHA, 21st Ed., 2005, 4500 - H+

    2. Temperature oC 26.0 40 oC IS 3025, Part 9:1983, RA 2002

    3. Colour Hazen 65.0 100 APHA, 21st Ed., 2005, 2120 – B,C

    4. Total Residual Chlorine

    mg/L N.D 1.0 IS-3025, Part 26:1986, RA 2003 Eds 2.1(2004-02)

    5. Total Dissolved Solids (TDS)

    mg/L 9290 2100 APHA, 21st Ed., 2005, 2540 - C

    6. Total Suspended Solids (TSS)

    mg/L 45.0 100 APHA, 21st Ed., 2005, 2540 - D

    7. Oil and Grease mg/L

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Report No. ME-BH-0362-120229-SA-UPL-5-JH Cont… 22. Copper as Cu mg/L < 0.03 2.0 APHA, 21st Ed., 2005, 3500-Cu - B

    23. Chromium Hexavalent as Cr6+

    mg/L < 0.02 0.1 APHA, 21st Ed., 2005, 3500-Cr - B

    24. Total Chromium as Cr

    mg/L < 0.02 2.0 APHA, 21st Ed., 2005, 3111 – B

    25. Mercury as Hg mg/L < 0.0008 0.01 APHA, 21st Ed., 2005, 3112 – B

    26. Arsenic as As mg/L 0.009 0.2 IS 3025, Part 37:1988, RA 2003

    27. Cadmium as Cd mg/L 0.007 2.0 APHA, 21st Ed., 2005, 3111 – B

    28. Total Heavy Metal mg/L < 2 7.0 By Calculation

    29. Percentage Sodium (% Na)

    % 90.9 60 MERI HANDBOOK

    Remarks: N.D. – Not detected

    .----------------------------------------------------------End------------------------------------------ for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY ---------------- ---------------------------------------------------------------------

    Note: 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the

    laboratory.

    Page 2 of 2

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0365-120225-SA-UPL-5-JH Date: 25.02.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Power Plant Turbine Stack 2. Power Plant HRSG Stack Sample Quantity/Packing

    50 mL X 2 No. PVC Bottle and 1 X 1 No. Thimble

    Date of Sampling 13.02.2012 Date of Receipt of Sample

    17.02.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis

    18.02.2012 Date of Completion of Analysis

    23.02.2012

    Stack No. 1 2

    Stack attached to Power Plant Turbine Stack Power Plant HRSG Stack

    Material of construction M.S. M.S.

    Stack height above ground level (Meter) 30.0 35.0

    Stack diameter(Meter) 3.0 3.0

    Stack shape at top Round Round

    Type of fuel N.G. N.G.

    Flue gas Temperature (0C) Not 137

    Flue gas Velocity (m/sec) In 14.4

    Total gas quantity (Nm3/hr) Operation 266336

    Parameter Unit Results GPCB Limit Method Reference

    Particulate Matter mg/Nm3 -- BDL 150 IS 11255 (Part 1):1985 RA-2003

    Sulphur Dioxide (SO2) ppm -- BDL 100 IS 11255 (Part 2):1985 RA -2003

    Oxides of Nitrogen (NOx) ppm -- 31.8 50 IS 11255 (Part 7):2005

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0366-120225-SA-UPL-5-JH Date: 25.02.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type

    Stack Emission Sample Collectedby Laboratory

    Sampling Location 1. Caustic Scrubber WAD 56-TPD Plant 2. Caustic Scrubber WAD 100-TPD Plant 3. Caustic Scrubber HCl Furness 56-TPD Plant 4. Caustic Scrubber HCl Furness 100-TPD Plant

    Sample Quantity/Packing

    50 mL X 3 No; 100mL X 3No. PVC Bottle

    Date of Sampling

    13.02.2012 Date of Receipt of Sample

    17.02.2012

    Sampling Procedure As per IS: 11255 and IS: 5182

    Date of Start of Analysis

    18.02.2012 Date of Completion of Analysis

    23.02.2012

    Stack No. 1 2 3 4

    Stack attached to

    Caustic Scrubber of WAD 56-TPD Plant

    Caustic Scrubber of WAD 100-TPD Plant

    Caustic Scrubber of HCl Furness 56-TPD Plant

    Caustic Scrubber of HCl Furness 100-TPD Plant

    Material of construction H.D.P.E. H.D.P.E. F.R.P. F.R.P.

    Stack height above ground level (Meter) 30 30 30 30

    Stack diameter(Meter) 0.2 0.15 0.15 0.25

    Stack shape at top Round Round Round Round

    Type of fuel Process

    Scrubber Process

    Scrubber Process

    Scrubber Process

    Scrubber

    Flue gas Temperature (0C) 30 30 Not 45

    Flue gas Velocity (m/sec) 4.6 8.1 In 5.6

    Total gas quantity (Nm3/hr) 512 507 Operation 927

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL -- BDL 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 8.4 4.8 -- 12.7 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laboratory.

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0367-120225-SA-UPL-5-JH Date: 25.02.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location 1. Di-Choloro Phenol Plant 2. Phosphorus Oxi-Chloride Plant 3. Phosphorus Acid Plant

    Sample Quantity/Packing

    50 mL X 1 No. PVC Bottle

    Date of Sampling 13.02.2012 Date of Receipt of Sample

    17.02.2012

    Sampling Procedure As per IS: 11255

    Date of Start of Analysis

    18.02.2012 Date of Completion of Analysis

    23.02.2012

    Stack No. 1 2 3

    Stack attached to

    Water & Caustic Scrubber of DCP Plant Reactor

    Caustic Scrubber of Phosphorus Oxy-Chloride Plant Distillation Column

    Water & Caustic Scrubber OR Ventury Scrubber of H3PO4 Scrubber Reactor

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.15 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process Scrubber Process

    Scrubber Process

    Scrubber

    Flue gas Temperature (0C) Not 30 Not

    Flue gas Velocity (m/sec) In -- In

    Total gas quantity (Nm3/hr) Operation -- Operation

    Parameter Unit Results GPCB Limit

    Method Reference

    Sulphur Dioxide (SO2)

    mg/Nm3 -- -- -- 40 IS 11255 (Part 2):1985 RA -2003 Oxides of Nitrogen (NOx) mg/Nm

    3 -- -- -- 25 IS 11255 (Part 7):2005

    Chlorine (Cl2) mg/Nm3 -- -- -- 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 -- 9.7 -- 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, without written approval of the laborator

    Page 1 of 1

  • Mahabal Enviro Engineers Pvt. Ltd. Engineers, Consultants, Environmental Monitoring Laboratory, Contractors

    Plot No. 13/14, Opp. Patel Petrol Pump, Chhindawara Road, Koradi, Dist-Nagpur- 441 111

    Phone: 91-07109-326999, 0712-2612162, Tle Fax: 0712-2612212, E-mail: [email protected]

    QF / 5.10/1 – B Amend. No. 00 Dt. 01.08.2010

    Stack Emission Monitoring Report

    Report No. ME-BH-0368-120225-SA-UPL-5-JH Date: 25.02.2012

    Name and Address of Customer

    United Phosphorus Limited, UNIT-V, 746 & 750, G.I.D.C; Jhagadia, GUJARAT - 393110

    Order Reference No. 4510051816 Dated 19.05.2011

    Sample Description / Type Stack Emission Sample Collected by Laboratory

    Sampling Location

    1. Caustic Scrubber of Distillation Section of PCl3 Plant

    2. Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    3. Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Sample Quantity/Packing

    50 mL X 5 No; 100mL X 3 No. PVC Bottle

    Date of Sampling 13.02.2012 Date of Receipt of Sample

    17.02.2012

    Sampling Procedure As per IS: 11255 and OSHA: 6402

    Date of Start of Analysis

    18.02.2012 Date of Completion of Analysis

    23.02.2012

    Stack No. 1 2 3

    Stack attached to

    Caustic Scrubber of Distillation Section of PCl3 Plant

    Caustic Scrubber of Storage Tank & Drum Filling Section of PCl3 Plant

    Water Scrubber + Alkali Scrubber of Rector PCl5 Plant

    Material of construction H.D.P.E. H.D.P.E. H.D.P.E.

    Stack height above ground level (Meter) 30.0 30.0 30.0

    Stack diameter(Meter) 0.2 0.2 0.15

    Stack shape at top Round Round Round

    Type of fuel Process

    Scrubber Storage Scrubber

    Process Scrubber

    Flue gas Temperature (0C) 30 30 30

    Flue gas Velocity (m/sec) -- -- --

    Total gas quantity (Nm3/hr) -- -- --

    Parameter Unit Results GPCB Limit

    Method Reference

    Chlorine (Cl2) mg/Nm3 BDL BDL 1.6 9 IS 5182 (Part 19):1982, RA 2003

    Hydro Chloride Vapours (HCl) mg/Nm

    3 5.3 3.2 14.9 20

    Jecob M.B. The Analytical Toxicology of Industril Inorganic Poisons-Inter Science Publishers, Newyork, USA-2367

    Phosphorus Tri-Chloride Vapours (PCl3) mg/Nm

    3 0.8 BDL -- 9 OSHA Method No.6402, 1985

    Remarks : BDL – Below Detectable Limit

    --------------------------------------------End------------------------------------- for Mahabal Enviro Engineers Pvt. Ltd.

    Harish Mendhi Technical Manager AUTHORISED SIGNATORY -------------------------------------------------------------------------------------------------------

    Note : 1. The result listed refers only to the tested sample(s) and applicable parameter(s). 2. This report is not to be reproduced except in full, w