DEVELOPMENT OF TOXICS EMISSION FACTORS FROM SOURCE TESTDATA COLLECTED UNDER THE AIR TOXICS HOT SPOTS PROGRAM

Part IIFinal ReportVolume I

Prepared for

Ralph PropperCalifornia Air Resources Board2020 L StreetSacramento, CA 95812

Prepared by

GE Energy and Environmental Research Corporation18 MasonIrvine, CA 92718

December, 1999

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DISCLAIMER

The statements and conclusions in this report are those of the contractor and notnecessarily those of the California Air Resources Board. The mention of commercial products,their source, or their use in connection with material reported herein is not to be construed asactual or implied endorsement of such products.

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ACKNOWLEDGEMENTS

The success of this program was due in part to the excellent cooperation from all of thedistricts that completed surveys and contributed source test reports. Guidance and test reportswere also provided by California Air Resources Board Technical Support, Monitoring andLaboratory, and Research Divisions. This guidance helped in the development of a set ofprocedures that can be used to develop air toxics emission factors of known accuracy for a widerange of devices.

This report was submitted in fulfillment of Contract No. 96-333 Development of ToxicsEmission Factors from Source Test Data Collected Under the Air Toxics Hot Spots Program byGE Energy and Environmental Research Corporation under the sponsorship of the California AirResources Board. Work was completed as of October 1999.

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TABLE OF CONTENTS

DISCLAIMER................................................................................................................................. iABSTRACT ................................................................................................................................... iiACKNOWLEDGEMENTS .......................................................................................................... iiiTABLE OF CONTENTS.............................................................................................................. ivLIST OF TABLES......................................................................................................................... viACRONYMS................................................................................................................................ vii1.0 INTRODUCTION ............................................................................................................. 12.0 DATA COLLECTION....................................................................................................... 3

2.1 Districts................................................................................................................................32.2 Chrome Plating Tests...........................................................................................................4

3.0 SCREENING ...................................................................................................................... 53.1 Procedures............................................................................................................................53.2 Results..................................................................................................................................6

4.0 DETAILED VALIDATION .............................................................................................. 74.1 Procedures............................................................................................................................74.2 Results..................................................................................................................................8

Listing of Tests Reviewed........................................................................................................8Detailed Validation Summary.................................................................................................10Detailed Validation Flags........................................................................................................11

5.0 DATA EXTRACTION.................................................................................................... 166.0 EMISSION FACTORS .................................................................................................... 18

6.1 Design and Operating Parameters ......................................................................................186.2 Normalizing Units..............................................................................................................196.3 Run Specific Method Rating..............................................................................................196.4 Run Specific Emission Factor Calculation .........................................................................216.5 Major and Sub Group Evaluation Parameters....................................................................236.6 Detailed Data Listings........................................................................................................246.7 Outlier Analysis.................................................................................................................256.8 Sub Group Evaluation........................................................................................................26

Asphalt Production - Oil........................................................................................................28Boiler - Fuel Oil......................................................................................................................29Boiler - Refinery Gas .............................................................................................................29Catalytic Reformer.................................................................................................................30Coating, Base/Catalyst/Water Mix.........................................................................................30Coating - Powder....................................................................................................................31Dryer, Pot Ash.......................................................................................................................31Dryer, Sand/Gravel.................................................................................................................31Fluidized Bed Combustion - Biomass....................................................................................32Furnace - Lead........................................................................................................................32

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Heater - Refinery Gas ............................................................................................................33Internal Combustion Engine - Diesel......................................................................................34Internal Combustion Engine - Natural Gas ............................................................................35Incinerator Ð Medical Waste ..................................................................................................36Plating - Anodizing.................................................................................................................37Plating - Decorative................................................................................................................37Plating - Hard .........................................................................................................................38Steam Generator - Natural Gas/CVRG ..................................................................................39Shredding and Delaquering Ð Aluminum ................................................................................39Turbine - Natural Gas ............................................................................................................40

6.9 Sub Group Emission Factor Calculation............................................................................406.10 Sub Group Method and Population Rating ...................................................................416.11 CARB Overall Quality Rating .......................................................................................426.12 EPA Overall Quality Rating...........................................................................................42

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LIST OF TABLES

TABLE 1. PART II DATA COLLECTION SUMMARY.............................................................................. 45TABLE 2. SCREENING RESULTS SUMMARY....................................................................................... 46TABLE 3. PART II DETAILED VALIDATION SOURCE TEST LISTING..................................................... 47TABLE 4. PART II DETAILED VALIDATION FUGITIVE TEST LISTING................................................... 51TABLE 5. DETAILED VALIDATION RESULTS SUMMARY. .................................................................... 53TABLE 6. KEY DESIGN AND OPERATING PARAMETERS.................................................................... 54TABLE 6. KEY DESIGN AND OPERATING PARAMETERS (Continued). .................................................. 55TABLE 6. KEY DESIGN AND OPERATING PARAMETERS (Continued). .................................................. 56TABLE 7. ASSIGNED SOURCE CLASSIFICATION CODES AND EMISSION FACTOR UNITS. .................... 57TABLE 8. LISTING OF SECONDARY AND PRIMARY VALIDATION CHECKS FOR TEST METHODSAPPLICABLE TO PROJECT (a). .......................................................................................................... 61TABLE 9. METHOD RATING SUMMARY. ............................................................................................ 62TABLE 10. MAJOR GROUP AND SUB GROUP EVALUATION PARAMETERS. .......................................... 63TABLE 11. LISTING OF OUTLIERS REMOVED FROM EMISSION FACTOR DEVELOPMENT. ................... 66TABLE 12. POINT SOURCE EMISSION FACTOR GROUPS*. ................................................................. 69TABLE 13. FUGITIVE EMISSION FACTOR GROUPS*. .......................................................................... 73TABLE 14. MEDICAL WASTE INCINERATOR CHARATERISTICS........................................................... 74TABLE 15. CHROME PLATING TEST MAJOR GROUPS AND COMPARISON MATRIX. ............................. 75TABLE 16. SUBSTANCE SPECIFIC UNCERTAINTY AND RELATIVEL STANDARD DEVIATION (a). .......... 77TABLE 17. CARB OVERALL RATING SUMMARY................................................................................... 81TABLE 18. EPA OVERALL RATING THAT WOULD BE ASSIGNED TO EMISSION FACTORS*................... 82TABLE 19. POINT SOURCE EMISSION FACTORS................................................................................ 83TABLE 20. FUGITIVE EMISSION FACTORS........................................................................................185

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ABSTRACT

The California Air Resources Board sponsored a program to develop air toxic emissionfactors from source test data collected under the Air Toxics "Hot Spots" Information andAssessment Act of 1987 (AB2588). Over 1000 source tests have been collected and screened,and a subset of tests was validated in detail. The objective of the screening and detailedvalidation activities was to eliminate data points or sets with significant problems and/orreporting deficiencies. Through this process the best data sets were selected for emission factordevelopment.

Over 3000 emission factors were developed for various source types including asphalt dryers,external combustion units, reciprocating internal combustion engines, turbines, glass and metalfurnaces, polystyrene reactors, coating and plating operations, and fugitives. The substancesquantified include: trace metals; polychlorinated dibenzo[p]dioxins and dibenzofurans; polycyclicaromatic hydrocarbons and other semivolatile organic compounds; benzene, toluene and othervolatile organic compounds; formaldehyde and other aldehydes; and hydrochloric acid. Theemission factor calculation procedures included categorizing each test by design and operatingparameters. Statistics were then applied to determine which parameters had a primary impact onemissions. These primary parameters were used to identify distinct groups of devices. Severalquality ratings were assigned to each emission factor and a graphical user interface (GUI) wasdeveloped to display the emission factors.

As a result of this study, air toxics emission factors have been developed using the best availablesource testing information. These emission factors can be used by facilities to develop moreaccurate and complete emission inventories without additional source testing. This reportdescribes the validation and emission factor development procedures and resulting emissionfactors.

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EXECUTIVE SUMMARY

Beginning in 1993, the California Air Resources Board (CARB) sponsored a program todevelop air toxic emission factors from source test data collected under the Air Toxics "HotSpots" Information and Assessment Act of 1987 (AB2588). During Part I of this effort over 750source tests were collected covering a wide range of devices including asphalt dryers, boilers andheaters, reciprocating internal combustion engines, turbines, glass and metal furnaces,polystyrene reactors, and coating and plating operations. Development of air toxics emissionfactors for petroleum industry combustion sources was conducted under a separate programsupported by the American Petroleum Institute (API) and the Western States PetroleumAssociation (WSPA). To expand the CATEF database, CARB funded a second part of theproject. The primary sources of data were test reports that were not evaluated in Part I thatcontain sufficient documentation to characterize the process, and sampling and analysisprocedures. Part II also includes additional collection of test reports from the districts andchrome plating tests from CARB.

The objective of the data collection phase of the project was to collect all testinginformation generated as a result of the AB2588 process. As a result of the Part I and II datacollection efforts over 1000 tests have been collected from the districts. Several districts,however, did not have sufficient resources to identify if any additional tests had been conductedand/or provide copies of any identified additional test reports.

To develop emission factors based on the best available source tests, a comprehensivedata validation procedure was developed. This procedure identified data points and data setswith significant problems and/or reporting deficiencies in three steps including: screening, detailedvalidation, and outlier analysis.

The following types of information were deemed necessary to develop emission factorsfor this project.

• Measurements of air toxics emissions

• Source classification code (SCC)

• Process rate in units compatible with the SCC

• Laboratory/sample data

• Key parameters specific to the source type

• Number of tests run

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Detailed validation procedures were established to ensure that correct sampling andanalysis procedures were used, to identify significant problems such as high field blanks, checkcalculations, and evaluate the accuracy of the test results. Specific validation procedures weredeveloped for 19 test methods. After the validation activities were completed the emissions datafrom the remaining reports were extracted. This provided yet another quality assurance criterionfor elimination of test report data from consideration and inclusion in the emission factorsestimation process. For each test that was not rejected, 28 different items of information wereextracted.

In summary, the emission factor database contains the information on the following:

• 65 types of Air pollution control device• 65 different ARB ratings• 9 different substance categories• 93 different process materials• 86 source category classifications• 26 standard industrial classification codes• 163 different toxic substances• 43 different source system types.

This development of this information is described in Volume I of this report, which isavailable for public review. Volumes II and III, which are confidential and restricted from publicdistribution, contain a detailed listing of all sources and source categories, substances, test resultsand the results of each level of test report screening. The full database is available in a publicrelease version as a graphical user interface (GUI) for computers operating with the Windows©3.1, 95 and 97 operating systems. Use of the GUI is documented in a separate users manualavailable as a pdf document.

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ACRONYMS

AB2588 Air Toxics ÒHot SpotsÓ Information and Assessment Act of 1987AB AfterburnerAF Air FilterAI Ammonia InjectionAl AluminumAPC Air Pollution ControlAPCS Air Pollution Control SystemATEDS Air Toxic Emission Data SystemBAAQMD Bay Area Air Quality Management DistrictBH BaghouseBTX Benzene, Toluene, and XyleneC CycloneCARB California Air Resources BoardCB Chevron BladeCFS Chemical Fume SuppressantCOC Carbon Monoxide Oxidation CatalystCVAAS Cold Vapor Atomic Absorption SpectrometryCVR Case Vapors RecoveredCr ChromiumCr+6 Chromium HexavalentD M DemisterDMNP Dist Mist NP mist suppressantdscfm Dry Standard Cubic Feet per Minutedscf Dry Standard Cubic FeetGE EER GE Energy and Environmental Research CorporationEF Emission FactorEPA Environmental Protection AgencyESP Electrostatic PrecipitatorF Filter of unknown typeF101 Fumetrol 101F140 Fumetrol 140FB Foam BlanketFBC Fluidized Bed CombustorFF Fabric FilterFI Fume IncineratorFPT Floating Pinched Polypropylene TubesGFAAS Graphite Furnace Atomic Absorption SpectrometryH2S Hydrogen Sulfide

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HCHO FormaldehydeHCl Hydrogen ChlorideHEPA High Efficiency Particulate ArrestingHF Hydrogen FluorideHNO3 Nitric AcidHp Horse PowerH2S Hydrogen SulfideHVLP High Volume Low PressureICAP Inductively Coupled Argon PlasmaICE Internal Combustion EngineIS Internal StandardsLD Laboratory Data or Location DataLI Lime Injectionlbs/MMcf Pounds per Million Cubic Feetlbs/Mgal Pounds per Thousand Gallonslbs/drum Pounds per Drumlbs/gal paint Pounds per Gallon Paintlbs/tons powder Pounds per Tons Powderlbs/lbs production Pounds per Pounds Productionlbs/ton Pounds per Tonlbs/ton coke Pounds per Ton Cokelbs/ton production Pounds per Ton ProductionME Mist EliminatorMMBtu Million British Thermal UnitsMC MulticycloneMMcf Million Cubic FeetMDL Method Detection LimitMgal Thousand Gallonsmg/amp-hr Milligram per Amp-hourmg/kg Milligram per kilogramM M T Multiple Metals TrainM P Mesh PadNi NickelNIOSH National Institute of Occupation Safety and HazardNOx Nitrogen oxidesO2 OxygenPA Paint ArrestorPB PolyballsPBS Packed Bed ScrubberPAH Polycyclic Aromatic HydrocarbonsPCB Polychlorinated Biphenyls

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PCDD Polychlorinated Dibenzo-p-dioxinPCDF Polychlorinated DibenzofuranPE Polyurethaneppbv Parts per Billion VolumePQL Practical Quantitation LimitQA/QC Quality Assurance/Quality ControlRFG Refinery Fuel GasROC Reactive Organic CompoundRSD Relative Standard DeviationS Scrubber of unknown typeSCAQMD South Coast Air Quality Management DistrictSCC Source Classification CodeSCR Selective Catalytic ReductionSD Spray DryerSIC Standard Industrial ClassificationSNCR Selective Non Catalytic ReductionSO2 Sulfur DioxideSVOC Semi-Volatile Organic CompoundsTHC Total HydrocarbonsTi TitaniumTO Thermal Oxidizerug/l Micrograms per litterVC Vinyl ChlorideVOC Volatile Organic CompoundWC Water CurtainWS Wet ScrubberWSN Water Spray NozzleWSPA Western States Petroleum AssociationWT Water Trough

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1.0 INTRODUCTION

In 1993, the California Air Resources Board (CARB) sponsored Part I of a program todevelop air toxic emission factors from source test data collected under the Air Toxics "HotSpots" Information and Assessment Act of 1987 (AB2588). Work for Part I was divided intotwo phases. The objective of Phase I was to collect all source tests prepared for AB2588, screeneach test, conduct a detailed validation on selected tests, develop emission factor calculationprocedures, and conduct a case study. Over 750 source tests were collected covering a widerange of devices including asphalt dryers, boilers and heaters, reciprocating internal combustionengines, turbines, glass and metal furnaces, polystyrene reactors, and coating and platingoperations. During Phase II of Part I, emission factors were calculated from a selection of 177priority tests. The substances quantified include: trace metals; polychlorinateddibenzo[p]dioxins (PCDD) and dibenzofurans (PCDF); polycyclic aromatic hydrocarbons(PAH) and other semivolatile organic compounds (SVOC); benzene, toluene and other volatileorganic compounds (VOC); formaldehyde and other aldehydes; and hydrochloric acid (HCl). Theemission factor calculation procedures included categorizing each test by design and operatingparameters. Statistics were then applied to determine which parameters had a primary impacton emissions. These primary parameters were used to identify distinct groups of devices. Several quality ratings were assigned to each emission factor including the confidence interval,relative standard deviation, population rating, and source test method rating. The emissionfactors developed in Part I are contained in a report titled ÒDevelopment of Toxics EmissionFactors from Source Test Data Collected under the Air Toxics Hot Spots ProgramÓ, April 11,1996. The emission factors are also available in the California Air Toxics Emission Factors(CATEF) graphical user interface (GUI).

Development of air toxics emission factors for petroleum industry combustion sourceswas not funded by CARB during Part I. Instead, CARB agreed to provide the AmericanPetroleum Institute (API) and the Western States Petroleum Association (WSPA) access toAB2588 petroleum industry air toxics source test results to use for the derivation of petroleumindustry emission factors. In return for this access, API and WSPA agreed to use the CARB datavalidation procedures and provide the validated information to CARB for inclusion in theCATEF GUI. The results of this effort are described in the report ÒAir Toxics Emission Factorsfor Combustion Sources using Petroleum Based FuelsÓ released in August of 1998. 39 additionalAB2588 source tests were evaluated as a result of the WSPA/API project.

216 test reports collected in Part I have been examined and used to develop emissionfactors. These tests were selected because they contain information for source types that havemore widespread use and/or higher contributions to overall air toxic emissions. Many of theremaining tests collected in Part I can also be used to develop emission factors. To expand theCATEF database, CARB is funding a second part of the project. The primary sources of dataare test reports that were not evaluated in Part I that contain sufficient documentation tocharacterize the process, and sampling and analysis procedures. Part II also includes additional

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collection of test reports from the districts and chrome plating tests from CARB. The districtdata collection efforts focused on tests conducted since the completion of the Part I datacollection activities. The objectives of this project include:

1) Developing a set of emission factors which can be used by the CARB and theDistricts to check emissions data developed using other estimation techniques;

2) Developing a set of emission factors which can be used by facilities to accuratelyestimate emissions from a variety of source types;

3) Evaluating different devices and control technologies; and

4) Identifying areas where improvements are needed in air toxics inventories andsource test methods.

The Part I data validation and emission factor development procedures was applied to all testreports evaluated in Part II. The Part I graphical user interface (GUI) was revised based on anynew or updated emission factors.

Sections 2 through 5 of this report provide a discussion of the data collection, screening,validation, and data extraction activities for information evaluated and collected in Part II. Thereader is referred to the Part I final report for a discussion of tests collected and evaluated duringPart I. Updated and new emission factors are described and calculated in Section 6.0. Supportingdocumentation on emission factors that are not being revised is provided in the Part I final report. Tables 19 and 20 provides a complete list of emission factors developed in this project (Parts Iand II).

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2.0 DATA COLLECTION

The objective of the data collection phase of the project was to collect all testinginformation generated as a result of the AB2588 process. The reporting phase of theAB2588program includes the preparation of Air Toxic Inventory Reports (ATIRs) which provide airtoxics emissions by process. If source testing was conducted for a process, the results areincluded in the ATIR. The ATIRs are sent to the local air quality management. As a result ofthe Part I and II data collection efforts over 1000 tests have been collected from the districts. Acomplete inventory of the tests collected in Parts I and II of this project is provided inAttachment 2. A summary of the district data collection activities is provided Section 2.1. Chrome plating tests collected from CARB are described in Section 2.2. The Part I datacollection efforts are described in the Part I final report.

2.1 Districts

As described above, source test reports are submitted to the districts with the ATIRs. Thus, copies of the test reports must be requested from the districts. A majority of the testreports submitted to the districts before 1994 were collected as a result of the Part I datacollection activities. The Part II data collection efforts focused on collecting reports submittedafter the Part I activities were completed. In addition, over 100 fugitive test reports identified atthe Santa Barbara and Ventura AQMDs during Part I were collected. Similar to Part I, the Part IIdata collection activities included:

• District survey. The survey was designed to locate additional sources of test data. Eachdistrict was sent a list of test reports collected during Part I of the project. Districts wereasked to provide any test reports not listed.

• District data collection. Data collection teams were sent to the South Coast, SantaBarbara, and Ventura Air Quality Management districts.

As shown in Table 1, only a few of the districts had additional test data. 61 source tests wereobtained from these districts. In addition, 102 analysis of composition tests were collected fromVentura and Santa Barbara. These tests quantify fugitive emissions while source test reportsquantify emissions from point sources. As noted in Table 1, several districts did not havesufficient resources to identify if any additional tests had been conducted and/or provide copiesof any identified additional test reports. Mojave with over 30 additional test reports was themost noteworthy of these districts. Upon further review of MojaveÕs test reports it wasdecided that the reports covered devices that donÕt have widespread use. Thus, additionalprogram resources were not allocated to collect the reports.

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2.2 Chrome Plating Tests

As noted in the previous section, only a few additional source tests have been conducted sincethe Part I data collection activities were completed. As a result, CARB decided to review 86chrome plating test reports that were conducted in California to demonstrate compliance with theNESHAP for hard and decorative electroplating and anodizing operations. CARB providedcopies these reports for review.

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3.0 SCREENING

To develop emission factors based on the best available source tests, a comprehensivedata validation procedure was developed. This procedure identifies data points and data setswith significant problems and/or reporting deficiencies in three steps including: screening, detailedvalidation, and outlier analysis. The primary objective of the screening analysis is to eliminatetest reports that do not provide sufficient process information to develop emission factors. Thesecondary objective of the screening analysis is to determine which tests provide sufficientsupporting information for the detailed validation activities. The detailed validation proceduresare described in Section 4.0 and the outlier analysis is described in Section 6.7. The screeningprocedure and results of the application of this procedure are described in this section.

3.1 Procedures

The following types of information are needed to develop emission factors for thisproject.

• Measurements of air toxics emissions: The focus of this project is on the developmentof air toxics emission factors for substances listed in AB2588.

• Source classification code (SCC): To standardize the categorization of equipment bytheir design and operating characteristics, the EPA and CARB have developed Sourceclassification codes. SCCs are used in this project to allow the users to identify theappropriate emissions factors for their equipment.

• Process rate in units compatible with the SCC: Since an emission factor is typicallynormalized by the process rate, the measurement and reporting of process rates isnecessary for the development of emission factors. In addition, it is essential that theprocess rate be reported in units corresponding to the device SCC, as these units aredesignated by CARB as the appropriate units for emission factors.

• Laboratory/sample data: Laboratory and sample data are necessary for the detailedvalidation process described in Section 4. This process includes checking of testprocedures, calculations, and laboratory results and is critical to the validation of theemission data reported. In addition, without the lab/sample data the calculationscannot be checked.

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• Key parameters specific to the source type: Most device types have one or moreparameters associated with them that could affect emissions. For example, incineratoremissions are impacted by post-combustion air pollution control (APC) device usedsuch as electrostatic precipitators or fabric filters. Tests that do not provide keyparameters are rejected, since their emissions data can not be appropriatelycategorized and evaluated.

• Single run test: To provide an accurate representation of emissions variability CARBtest methods require 3 test runs per condition.

Before beginning the detailed validation process each test was examined for the information listedabove. Any test report missing one or more of the items was rejected. The following sectionprovides results from the screening analysis.

3.2 Results

Table 2 summarizes the results of the screening analysis for the 1041 tests reviewed inParts I and II. Screening results for each test are provided in Attachment 2. Over half of thetests collected did not pass the screening analysis and will not be used for emission factordevelopment. Over half of the tests failing the screening analysis failed because either processrates were not provided or process rates were not provided in the correct units.

Also note that differences in hardware configuration (i.e. the presence of post combustionAPCDs) do not necessarily lead to separate emission factors. In some cases there was nostatistically significant difference between the emissions of certain substances from controlledand uncontrolled devices.

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4.0 DETAILED VALIDATION

The detailed validation procedures include checking to ensure the correct sampling andanalysis procedures were used, qualifying significant problems such as high field blanks, checkingcalculations, and evaluating the accuracy of the test results. The detailed validation proceduresare only applied to those tests passing the screening process described in Section 3. Thefollowing subsections describe the procedures and results of the detailed validation process.

4.1 Procedures

Detailed validation procedures have been developed for all methods needed to quantifythe substances listed in AB 2588 appendix D. Specifically validation procedures have beendeveloped for the following methods:

11 - Hydrogen Sulfide (1983)12 - Inorganic Lead - (March, 1986)15 - Hydrogen Sulfide - (June, 1983)101A - Mercury - (1986)104 - Beryllium - (1986)106 - Vinyl Chloride - (June, 1983)410A/B - Benzene - (March, 1986)421 - Hydrogen Chloride - (January, 1987 and December, 1991)422 - Volatile Halogenated Organics - (January, 1987 and December, 1991)423 - Inorganic Arsenic - (January, 1987)424 - Cadmium - (1987)425 - Total and Hexavalent Chromium - (January, 1987 and September, 1990)428 - PCDD/PCDF and PCB - (March, 1988 and September, 1990)429 - PAH - (September, 1989)430 - Aldehydes - (September, 1989 and December, 1991)433 - Nickel - (1989)436 - Trace Metals - (March, 1991 and 1992)EPA MMT - Trace MetalsEPA 306 - Total and Hexavalent Chromium

Attachment 3 provides validation procedures for each method. These procedures weredeveloped using experience gained conducting air toxic source tests, and reviewing AB 2588 testreports, EPA and CARB test method documentation and CARB method review sheets. Primaryparameters were identified to ensure critical data quality indicators were checked. The primaryparameters provide an overall assessment of data quality but may not provide an indication ofwhy a particular problem occurred. For example, if a method required field, reagent, and methodblanks, only the field blank was considered a primary parameter because it indicates the totalinterference and/or contamination resulting from the field and laboratory activities. However, the

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field blank does not indicate if the contamination resulted from the field and/or laboratoryactivities. For this project, it was more important to evaluate the overall quality of the emissionsdata.

A special note is warranted regarding the results from CARB method 430 fordetermination of aldehydes. Subsequent to the development of this method and its use in thedevelopment of test reports that make up this report, it was found that the method is not reliablefor the determination of acrolein and crotonaldehyde. Specifically, it was found that uponderivatization by 2,4-dinitrophenylhydrazine these compounds decay in solution. Furthermore,many of the emission factors for acrolein are based on non-detect data. Therefore, while emissionfactors are provided for acrolein, the values shown should be used only as indications of possiblelower bounds. This warning does not apply to formaldehyde and acetaldehyde emission factors.

Only those parameters provided in the test reports in the form required by the methodwere checked. For example, if the method required that field blank levels over 20% be flagged,the flags were transferred from the test report to the emission factor database. However, if thefield blank levels were reported but not divided by the sample value, the ratios were notcalculated. Instead a notation was made to indicate that field blanks were collected and analyzedbut the results were not flagged appropriately. The only exceptions to this rule were for CARBMethods 430 and 436. For these two methods, field blank ratios were calculated because mostcontractors did not provide these ratios.

4.2 Results

The results of the detailed validation procedures are described in this section. The firstsubsection lists the source and fugitive tests reviewed. The second subsection summarizes thedetailed validation results. Test-specific detailed validation results are provided in Attachment 2. The final subsection summarizes the detailed validation flags that will be included in thedatabase.

Listing of Tests Reviewed

Tables 3 and 4 list the source and fugitive tests reviewed in Part II using the detailedvalidation procedures described above. Tests reviewed in Part I are provided in Attachment 2and the Part I final report. Table 3 lists the 169 source tests reviewed by Report ID, Device ID,Tests, Device Type, Air Pollution Control System, Fuel, and Material. These parameters aredescribed below:

• Report ID: This is the number that was assigned to a device or similar group of devices ineach document during the initial screening phase. Similar devices all have the same primarycharacteristics such as an internal combustion engine. The report ID is a four-digit numberfollowed by a letter. The four-digit number distinguishes different documents. A unique

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letter is assigned to each device or group of devices in a document. If, for example, adocument contained results for two boilers and an internal combustion engine, the deviceswould be given the same four digit number (####), but each would have its own letteridentifier (e.g., ####A for the two boilers and ####B for the ICE).

• Device ID: This three-digit number is assigned to each device or group of interconnecteddevices upon entry into the database. Some facilities have a group of devices that emit to acommon stack. For example, one facility in the screening database has six steam generatorsexhausting to one stack. These six steam generators would receive a single device ID. Eachengineer entering data had his/her own assigned set so the person responsible for validatingand extracting the results from a particular test could be tracked. In many cases, the reportID and device ID can be used to reference a device or group of interconnected devices. Insome cases, however, a report ID references multiple devices. For example, report ID2431A references 3 devices, device IDs 241 to 243, as shown in Table 3.

• Tests: As mentioned earlier, a test includes the quantification of air toxics and otheremissions from a device or group of interconnected devices operating under one condition. Acondition is defined as set of operating constraints that are fixed during a test. For example,one condition would be a boiler fired on natural gas under normal load. Another conditionmight be the same boiler fired on fuel oil under normal load. In this case, a single device IDwould be assigned and 2 tests would be listed in Table 3.

• Device Type: This field displays the type of device such as internal combustion engine orplating operation.

• Air Pollution Control System: This field displays the type of control system. In some casesthe control system may include multiple air pollution control devices. In these cases, eachdevice is separated by the symbol Ò/Ó.

• Fuel: This field displays the type of fuel consumed during the test. In some cases multiplefuels may have been fired. Each fuel is separated by the symbol Ò/Ó. For some device typessuch as plating operations, fuel type is not applicable and is listed as ÒNoneÓ.

• Material: This field displays the type of material processed during the test. In some casesmultiple materials may have been processed. Each material is separated by the symbol Ò/Ó. For some device types such as internal combustion engines, material type is not applicableand is listed as ÒNoneÓ.

Table 4 lists the 81 fugitive tests reviewed by Report ID, Device ID, Tests, Device Type,and Material. Definitions for these parameters are the same as those listed above.

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Detailed Validation Summary

Table 5 summarizes common problems found in the detailed validation analysis andproblems that resulted in test data being rejected. Detailed validation results for each test areprovided in Attachment 2 and validation flags are presented in the next subsection. Briefdescriptions of each detailed validation note listed in Table 5 are provided below.

• Dioxins/Furans and PAH sampled using a single train. Initially, as per CARB instructions,the results from these reports were not reviewed or extracted. However, after data validationoperations revealed that many of the dioxin/PAH tests were sampled using a single train,CARB reconsidered its initial position, and all results were validated, checked, and extractedas reported. All tests that used combined sampling and analysis for Dioxin and PAH werenoted in the database.

• Separate front/back-half analyses were conducted for CARB 436. The results were notvalidated or extracted per the CARBÕs instructions.

• Used outdated method without CARB approval. For one test, the November 1990 draft ofCARB 436 was used to quantify metals. Since the test was conducted in June of 1991, theMarch 1991 version of CARB 436 should have been used. Since approval was not grantedby the CARB to use the November 1990 version, the results were not validated or extracted.

• CARB 421 sampling was not isokinetic and stack temp < 250F . When the stack temperature isbelow 250 oF, Method 421 requires that isokinetic sampling be conducted. 3 tests did not useisokinetic sampling even though the stack temperature was less than 250 oF. As required byCARB, the results were neither reviewed nor extracted.

• Naphthalene analyzed by CARB 410 . Since naphthalene was quantified using an incorrectmethod these results were not validated or extracted.

• Nonisokinetic sampling CARB 429 . The sampling methodology for 3 tests was modified fornon-isokinetic testing by eliminating the glass nozzle and probe from the sampling train. Thesetests were conducted using a 3/8-inch diameter glass probe placed in the center of the exhauststack. The glass probe was connected directly to a Teflon sample line. No mention of CARBapproval was given for these modifications. The results were validated, extracted, and noted inthe database.

• A full set of internal standards not used for method 429. CARB Method 429 requiresspiking of 14 internal standards into each sample. 60 tests did not spike all 14 standards. Instead, most spiked and reported recoveries for about half of them. The results werevalidated and extracted and noted in the database.

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• All sampling was done non-isokinetically. For a single test, CARB methods 421, 425, 428,429, and 436 were all conducted non-isokinetically. Consequently, the results were neithervalidated nor extracted.

• Mercury not tested by CVAAS. CARB Method 436 specifies the use of CVAAS toquantify Mercury. For a single test this method was not used and the results were rejected.

• Did not use correct impingers for metals train. Two tests did not use the specified number ofimpingers for CARB Method 436 and the results were rejected as specified by the method.

Results of the calculation checks for both Parts I and II are given by device in Attachment2. Most of the calculation errors for both Parts I and II occurred for CARB Method 430. Specifically contractors did not provide the reporting limit when the sample to blank ratio wasless than 5. The results for these reports were not corrected and are noted in the database.

Detailed Validation Flags

After all the tests results were validated and extracted, the method validation sheets werecompiled and the validation flags were entered into a database. The validation flags were thencondensed and exported to a spreadsheet for tabular summation. The results of the Part II detaileddata validation are summarized in the tables located in Attachment 4. Results from the Part Idetailed validation are provided in the Part I final report. Attachment 4 contains one table permethod. Each test method has a set of validation parameters that are used to verify propersampling and analytical procedures. These parameters are organized into sections by type ofsampling or analytical check. The sections are in boldface and shaded gray in the tables. Adetailed review of a source test report can produce three basic responses with the correspondingflag notations for each validation parameter:

• Pass: A blank cell in the table

• Insufficient information to report a parameter: R, V, N, P, RN, PN

• Fail: Y, RF, PF

Consider Method 436 (1992) as an example. This method is applicable to thedetermination of trace metal emissions from stationary sources, and requires some of the morecomplex validation parameter checks. The table shows a total of 13 stacks (Stack IDs: 21310,23010, 23310, 23510, 24710, 25910, 26010, 26110, 26210, 26310, 26410, 27910, and 43610)were sampled and analyzed using this method. The first three digits of the stack ID are the deviceID and the last two digits identify each stack on the device. The stack ID is used in Attachment 4because some devices have multiple stacks. Each of these stacks may have been tested andtherefore validation was conducted on each stack. The following is a brief explanation of eachnotation with an example.

R This notation is used when it cannot be determined whether the parameter was conducted ornot. It could not be determined whether field reagent blanks were collected once per testfor four stacks (21310, 23310, 23510, and 26210).

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V If values were not provided for a parameter, this notation is used. Three stacks (23010,23510, and 24710) show values were not provided for pre-test leak rate.

N This notation is used when a parameter was not conducted. Pre- and/or post-test meter γwere not conducted for one stack (43610).

P This notation is used specifically for the Pitot tube semi-annual calibration sheet parameter.The validation sheet asks if the semi-annual calibration sheet is included in the report. Fourstacks (21310, 23310, 24710, and 27910) failed to do so.

RN* Similar to the V notation, but applied to more detailed parameters that require runquantification. One pre-test leak rate could not be checked for one stack (21310).

PN* Again, similar to the V notation, but applied to more detailed parameters that require runand substance quantification. One stack (23510) shows that values for fifteen matrix spikerecoveries could not be checked.

Y This notation is used when a parameter was conducted and failed. One stack (24710) failedto conduct at least 3 sampling runs.

RF* Similar to the Y notation, but applied to more detailed parameters that require runquantification. One stack (23010) reported isokinetic variation failure for one run.

PF* Again, similar to the Y notation, but applied to more detailed parameters that require runand substance quantification. For one stack (25910), it shows the sample/field ratio is lessthan 5 for eighteen points.

* Numbers before these notations represent how many times a parameter failed or could notbe checked.

The following is a list summarizing the validation tables for each method. The list containsthose parameters that were flagged for 50% or more of the devices in each table unless noted. Byfar, the most prevalent types of flags found in the tables are those associated with reporting. Still,there are plenty of failures that are noteworthy, but they are much less frequent. Note primaryvalidation parameters are underlined and failures are in Italics. For more details on specificparameter failures, please see the tables in Attachment 4.

Method 11 (1983): Insufficient reporting - Reagent blank not conducted daily Insufficient reporting - Iodine solution not used

Method 12 (1986): Insufficient reporting - Swirl checkInsufficient reporting - Semi-annual pitot tube calibrationInsufficient reporting - Field reagent blank not conducted on 2 filters and0.1N HNO3 Insufficient reporting - Atomic absorption spectrometry not usedInsufficient reporting - Atomic absorption spectrometry not conducted intriplicate

Method 15 (1983): None

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Method 101A (1986): Insufficient reporting - Swirl checkInsufficient reporting - Dry gas meter pre- and post-checkInsufficient reporting - Semi-annual pitot tube calibrationInsufficient reporting - Filter temperatureFailure - Field reagent blank not used to correct samples Failure - Combined analysis not used

Method 104 (1986): Insufficient reporting - Swirl checkInsufficient reporting - Method 1 not usedInsufficient reporting - Nozzle size checkInsufficient reporting - Flow rate checkInsufficient reporting - Field reagent blank not conducted for acetone Failure - Atomic absorption spectrometry not used

Method 106 (1983): Failure - GC/FID not usedInsufficient reporting - GC/FID not usedInsufficient reporting - 3-point calibration curve not conducted daily orbefore and after test

Method 306 (1990): Insufficient reporting - Swirl check

Method 410A (1986): Insufficient reporting - Leak check

Method 421 (1987): Insufficient reporting - Swirl checkInsufficient reporting - Nozzle size checkInsufficient reporting - Semi-annual pitot tube calibrationInsufficient reporting - Field reagent blank not conducted one per test Insufficient reporting - Lab spike not conducted for 10% of samples Insufficient reporting - Duplicate not conducted for each sample

Method 421 (1991): Insufficient reporting - Swirl checkInsufficient reporting - Water not used as impinger solutionInsufficient reporting - Lab spike not conducted prior, daily, and after every40 samples

Method 422 (1987): None

Method 422 (1991): Insufficient reporting - Leak checkInsufficient reporting - Field spike not collected once per source

Method 423 (1987): Insufficient reporting - Filter temperatureInsufficient reporting - Flow rate checkInsufficient reporting - Combined analysis not used

Method 424 (1987): Insufficient reporting - Swirl checkInsufficient reporting - Nozzle size checkInsufficient reporting - Field reagent blank not conducted for two filters and0.1N HNO3 Insufficient reporting - Atomic absorption spectrometry not conducted intriplicate

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Method 425 (1987): Insufficient reporting - Swirl checkInsufficient reporting - Method 1 not usedInsufficient reporting - Dry gas meter pre- and post-checkInsufficient reporting - Semi-annual pitot tube calibrationInsufficient reporting - Matrix spike not conducted once per test forHexavalent Chromium Insufficient reporting - Matrix spike percent recovery for HexavalentChromium >10% Insufficient reporting - Matrix spike not conducted daily for TotalChromium Insufficient reporting - Duplicates not conducted for every 10 samples forTotal Chromium

Method 425 (1990): Insufficient reporting - Probe proof not conducted per probe Insufficient reporting - Matrix spike not conducted once per test forHexavalent Chromium

Method 428 (1988): Insufficient reporting - Swirl checkInsufficient reporting - Nozzle size checkInsufficient reporting - Surrogate standards percent recovery Insufficient reporting - Laboratory control spike percent accuracy Failure - Internal standards percent recovery Insufficient reporting - Internal standards percent recovery

Method 428 (1990): Insufficient reporting - Swirl checkInsufficient reporting - Surrogate standards percent recovery Insufficient reporting - Laboratory control spike percent accuracy Insufficient reporting - Internal standards percent recovery

Method 429 (1989): Insufficient reporting - Swirl checkInsufficient reporting - Surrogate standards not conducted once per test Insufficient reporting - Laboratory control spike percent accuracy Insufficient reporting - Internal standards not conducted once per run

Method 430 (1989): Insufficient reporting - Indication of leaksInsufficient reporting - Matrix spike not conducted per test

Method 430 (1991): Insufficient reporting - Calibration check for each rotometerInsufficient reporting - Indication of leaksInsufficient reporting - Sampling dates not within 2 days of reagent blankcheck

Method 433 (1989): Insufficient reporting - Swirl checkInsufficient reporting - Nozzle size checkInsufficient reporting - Field reagent blank not conducted for two filters and0.1N HNO3

EPA MMT (1989): Insufficient reporting - Duplicates percent difference (ICAP) Insufficient reporting - Duplicates not conducted per run (CVAAS)

Method 436 (1992): Insufficient reporting - Swirl checkFailure - Sample/field blank ratio < 5 Insufficient reporting - Duplicates percent difference (ICAP)

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SCAQMD 207.1 (1990):Insufficient reporting - Swirl check

Lastly, the tables in Attachment 4 do not specify validation results for individual hazardous airpollutants. Consequently, one cannot determine if any one substance failed method parametersmore than others did by using these tables alone. Attachment 5, however, contains a table thatprovides such information. The table lists how many times a particular substance failed avalidation parameter. It includes the Method, Version (Year), Failed Check, Substance, andCount. The table presents results for both isokinetic and non-isokinetic trains.

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5.0 DATA EXTRACTION

Data extraction is the process of entering design and operating information, and emissionresults into a database. After the validation activities were completed as described in Section 4.0,the emissions data were extracted. If a critical validation parameter was not satisfied for amethod, such as analyzing the front- and back-half component of a CARB 436 train, theemissions data for the method were not extracted. If several methods were not suitable forextraction in a single test report, the complete test report was rejected. If the test report did notprovide sufficient information to develop emission factors, it also was rejected. For each testthat was not rejected, the following information was extracted.

Device Information1.) Source classification code (SCC)2.) Standard industrial code (SIC)3.) Control device type4.) Fuel type or material processed5.) Capacity6.) Company7.) Location8.) Report DateSample and Analysis Procedures1.) Sampling method2.) Analysis method3.) Contractor4.) Detection limit based oon MDL or PQLRun Information1.) Process rate and unit (must be appropriate for emission factor development)2.) Site run ID3.) Date of Run4.) Fuel/Material type burned/used during test5.) Description of operation during test6.) Stack flow rate (dscfm)7.) Stack moisture (%)8.) Stack temperature (F)9.) Stack oxygen (%)Emission Information1.) Substance2.) Detection indicator (Detected or Not Detected)3.) Data quality flags4.) Concentration value and unit5.) Emission rate value and unit6.) Emission factor value and unit

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In some instances SCCs were not provided. In these cases SCCs were assigned if a clear categorydefinition was available in the CARB listing. There were some instances where the SCC listingwas not sufficient to distinguish between different types of equipment. For example, natural gasfired turbines have an SCC of 20200203 regardless of whether they are equipped with postcombustion APCDs. Subgroups were developed to account for this following the guidelinesdescribed in Section 6.8. To summarize, however, no subgroups were specified in cases where theresult provided no improvement in data quality. This includes cases where the subgroup wouldhave too few members, or where the subgroup results were not statistically different from theSCC group as a whole.

Similarly, there were instances where emission data were valid but no SCC was available. Anexample would be field gas fired engines, for which the SCC for natural gas was assumed. In thesecases an SCC was assigned as long as the emissions data from the unit were representative of theSCC group to which they were assigned, and as long as there were not enough units to define asubgroup. In future compilations these units may be reassigned as more data becomes availableand if test results from additional units are incorporated.

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6.0 EMISSION FACTORS

A procedure was developed to provide emission factors of known quality for a widerange of air toxics and source types. This procedure considers the design and operation of thesources, process stream characteristics, data quality, source population size, and emission factorvariability. The procedure includes the following steps:

¥ Identify Design and Operating Parameters¥ Identify Normalizing Units¥ Assign Run Specific Method Ratings¥ Calculate Run Specific Emission Factors¥ Identify Major and Sub Group Evaluation Parameters¥ Compile Detailed Data Listings¥ Conduct Outlier Analysis¥ Identify Sub Groups¥ Calculate Emission Factors for each Sub Group¥ Assign Sub Group Method and Population Ratings¥ Assign CARB Overall Quality Rating¥ Assign EPA Overall Quality Rating

Each of these steps is discussed below. The discussion includes a brief background, whichdescribes why the step is needed and the approach used. The background is followed by apresentation of the results of applying the subject step to the data.

6.1 Design and Operating Parameters

Background. To develop emission factors, sources must be grouped by their design andoperating characteristics. Ideally, emissions from devices in each group should be similar or havelow variability when normalized. To define design and operating parameters, a literature reviewwas conducted. AP-42 was one of the best sources of information identified. In addition to AP-42, EER used its experience in past programs such as the WSPA air toxic emission factor projectto define design and operating parameters. Table 6 lists key parameters which may affectemissions from asphalt production, cement kilns, glass manufacturer, metal furnaces, polystyrenemanufacture, chrome plating, surface coating, external combustion, internal combustion, gasturbines, and fugitives.

Results. Few reports contained all of the information listed in Table 6. Basic systemtype, feed material or fuel, and air pollution control system type were available for most sources. Unit capacity and manufacturer were available for approximately half the sources. Someinformation was available for metal furnace type and surface coating spray method.

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6.2 Normalizing Units

Background. An emission factor characterizes air toxic emissions as a ratio of theamount of pollutant released to a process-released parameter. Emission factors are typicallyexpressed in terms of mass of emission per mass or volume of fuel or material fed or productproduced. Thus, the emission rate is normalized by the production rate or by the feed rate offuel or material. This method of normalizing assumes that emissions are directly proportional toproduction rate or fuel or material feed rate. Based on established procedure, normalizing unitswere assigned based on the source classification codes (SCC).

Results. The first step in determining the appropriate normalizing units is to assignSCCs. Using a SCC look-up table from the ARB and descriptions provided in the test reports,SCCs were assigned for each test. Table 7 lists the SCCs assigned. For several tests, no SCCwas available which adequately described the test. For example, several of the reciprocatinginternal combustion engines and one gas turbine were fired on field gas. For these sources, anatural gas SCC was used. In addition, one steam generator, and one heater fired natural andprocess gas simultaneously. SCCs were available for natural gas and process gas separately. However, a SCC was not available for simultaneous burning of natural and process gas. Therefore, both SCCs were used to describe the source in the database. Several of the turbinesalso fired multiple fuels simultaneously. SCCs describing each applicable fuel were listed in thedatabase. For the internal combustion engines and heaters, additional SCCs must be requestedfrom the EPA. The required normalizing units for each SCC also are provided in Table 7. Emission factors have been expressed in these units.

6.3 Run Specific Method Rating

Background. To compare and evaluate test results, it is important to denote the testmethods that were used and the level of documentation that was provided. Various systems havebeen developed to categorize test methods and the level of documentation. For example, the EPAdeveloped the system described below.

EPA Method Rating

A When tests are performed by a sound methodology and are reported in enoughdetail for adequate validation.

B When tests are performed by a generally sound methodology but lack enoughdetail for adequate validation.

C When tests are based on an untested or new methodology or are lacking asignificant amount of background data.

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D When tests are based on a generally unacceptable method but the method mayprovide an order-of-magnitude value for the source.

U Unrateable.

The EPA method rating were used for the Factor Information Retrieval (FIRE) systemthat includes criteria and air toxic emission factors. For the CARB emission factor project theEPA system was modified to distinguish between EPA and CARB methods as well as testswhich provide sufficient documentation and those that do not. The method rating system usedfor CARB emission factor project is described below.

CARB Method Rating

A Test was performed using a new or old CARB methodology and sufficientdocumentation was provided to validate the results.

B Test was performed using a new or old EPA methodology and sufficientdocumentation was provided to validate the results.

C Test was performed using a new or old CARB methodology and insufficientdocumentation was provided to validate the results.

D Test was performed using a new or old EPA methodology and insufficientdocumentation was provided to validate the results.

E An assumption was made in the emission factor calculation that couldsignificantly affect the accuracy of the results. Methods that do not havevalidation check procedures also were rated under this category.

F Emission data is unacceptable for inclusion in emission factor database. If asampling problem or process upset occurred which significantly impacted theemission results, the emission results were excluded from emission factorcalculations. A statistical test was used to identify outliers as described in section6.7.

**It should be noted that the EPA methods are not considered inferior. However, themajority of the test methods were CARBÕs because the Hot Spots programmandated them. An EPA method could be used if there was no correspondingCARB test method or if the source asked for an equivalency determination. CARB and EPA test methods are different in many cases and can lead to differentresults. CARB test methods were rated higher than EPAÕs to provide consistenttest result comparisons.

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A test received an A or B (C or D) rating if a specified number of primary validationparameters could be checked. Primary validation parameters are those that indicate overallcontamination, poor recovery, and imprecision. Primary parameters are identified in Table 8 forCARB and EPA methods. The table also provides the number of primary parameters permethod and the number of primary parameters required to determine if sufficient documentationwas provided. The number of parameters required to determine if sufficient documentation wasprovided was based on the following criteria.

Primary Parameters Sufficient Documentation if0 to 2 0 Missing3 to 4 1 or fewer Missing5 to 6 2 or fewer Missing

Results. Table 9 summarizes the ratings by method. The table lists the number of timesthe method was used for the tests extracted and validated during this project. Several methodsincluding EPA 420.1, EPA M5, EPA 30, NIOSH 1612, SCAQMD 205.1, SCAQMD 25.1, andSCAQMD 5.2 received E ratings because no validation check procedures have been developed. These methods were only used for 26 tests and cover a small fraction of the data reviewed duringthis project. 36 E ratings were assigned because an assumption was made in the emission factorcalculation that could significantly affect the accuracy of the results. These assumptions arediscussed in Section 6.4. Data from 12 tests were identified as outliers and received F ratings asdescribed in Section 6.7.

Sixty-five tests received G method ratings. A method rating of G was assigned when asubstance was quantified using two test methods. In the validation process for the Multi-MetalSampling Train (MMT), CARB required that one metal be sampled using one of the CARBmetal specific sampling trains including CARB 101A, 104, 12, 423 or 433. The metal specificsampling train and MMT results were then compared. This process resulted in replicate resultsfor one metal each time the MMT was used. For this project, the MMT results were usedinstead of the metal specific sampling train results as specified by CARBÕs Monitoring andLaboratory Division.

6.4 Run Specific Emission Factor Calculation

Background. A source test usually includes three runs per sample method. Emissionfactors must be calculated from each of these runs. Once appropriate groups have been defined(see Sections 6.5 and 6.8), run emission factors from one or more source tests are averagedtogether. In general, emission factors are calculated on a run basis using feed or production ratesand air toxic emission rates. For combustion sources, when feed rates are not available, F-Factorscan be used in combination with the stack oxygen and air toxic emission concentration using thefollowing equation.

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EF = FF*HV*(21/(21-02))*C

For Gas Fired:

EF = Emission Factor, lb/MMcfFF = Fuel F-Factor, dscf @ No Excess Air/MMBtuHV = Fuel Heating Value, MMBtu/MMcfO2 = Stack OxygenC = Substance Concentration, lb/dscf @ Stack Oxygen

For Liquid Fired:

EF = Emission Factor, lb/MgalFF = Fuel F-Factor, dscf @ No Excess Air/MMBtuHV = Fuel Heating Value, MMBtu/MgalO2 = Stack OxygenC = Substance Concentration, lb/dscf @ Stack Oxygen

For Solid Fired:

EF = Emission Factor, lb/tonFF = Fuel F-Factor, dscf @ No Excess Air/MMBtuHV = Fuel Heating Value, MMBtu/tonO2 = Stack OxygenC = Substance Concentration, lb/dscf @ Stack Oxygen

Results. Run specific emission factors were calculated for each source in the appropriateunit (see Table 7). For several sources, default parameters were used or other assumptions weremade to calculate emission factors because the appropriate data were not provided in the sourcetest report. These assumptions are described below.

AssumedDensity (D): For several tests a density was required to convert the process rate

into the appropriate normalizing parameter. For example, theemission factor may have been lbs/Mgal and the feed rate wasprovided in lbs/hr. For these sources a density was required toconvert the mass feed rate to a volume feed rate. When the feedmaterial was well characterized, the method rating was not changedto E. For example, distilled fired turbines were not rated as E butcoating operations were when a density was not provided.

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AssumedHeating Value (H): Three sources required that a heating value be assumed to calculate

the emission factor. All of these sources were fired on wellcharacterized fuels and since it is suspected that the heating valuewill not vary significantly, no revision of method rating wasrequired.

AssumedFeed EqualsProducts (FEP): Four sources required the assumption that feed equals production.

Emission factors for cement kilns, glass furnaces, and asphaltproduction must be expressed in lbs per ton production. The testreports for these sources only provided the feed rate of rawmaterials. To calculate the emission factor, the production rate wasassumed to equal to the feed rate and a method rating of E wasassigned.

AssumedOxygen: For device 140 an oxygen was not available for the VOC sampling.

The oxygen level was assumed to be equal to the reading from othermeasurement methods and the method rating was set to E.

6.5 Major and Sub Group Evaluation Parameters

Background. A key step in the emission factor development process is to identifydevices which have similar designs and operation. The design and operating parameters selectedto categorize the devices should impact air toxic emissions. If the parameters are definedappropriately and correct normalizing units are assigned, emission factors developed for eachgroup of devices will be distinctive and will have low variability. These emission factors can beused to accurately assess emissions from similar devices. The first step in the categorizationprocess is to divide the sources into major groups based on their primary design characteristics. Primary design characteristics are those parameters that are known to impact emissions such asbasic system and feed type. For this study, emission data from different major groups were notcombined when calculating emission factors.

The second step in the grouping process is to identify if any such groups are presentwithin each major group. Sub group identification is based on an evaluation of secondary designand operating parameters. Before sub groups can be established, secondary design and operatingparameters must be identified, detailed data listings must be prepared, and ouliers must beidentified and eliminated from the analysis if sampling problems occurred. In addition , guidelinesand statistical tests should be established to determine if sub groups are needed and appropriate. Secondary design and operating parameters are discussed and listed in this section. Detailed data

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listings are described in Section 6.6. The outliers analysis is discussed in Section 6.7 andguidelines for establishing sub groups are presented in Section 6.8.

Results. Major groups have been identified for all devices as shown in Table 10. Eachrow of data describes a different major group. The first column of this table lists the majorgroups. Secondary parameters, which were considered when developing sub groups, are listed inthe ÒSub Group Parameters EvaluatedÓ column. For example, APC system and SCC wereevaluated for the major group Asphalt Prod., Diesel. The number of tests passing the detailedvalidation activities for Parts I and II are listed in the ÒTestsÓ column. The total number of testsavailable for emission factor development is provided in the ÒTotalÓ column.

For some of the major groups, no sub group development is possible for one or morereasons. In addition, some of the sub group analyses from Part I do not need to be updatedbecause no additional tests were collected or evaluated. These differences are distinguished inTable 10 by dividing the major groups into six sections including:

1. Part II Sub group Analysis Ð New and Updated Major Groups2. Part I Sub group Analysis Ð No Additional Data Collected or Evaluated3. No Sub group Analysis Ð No Difference in Design/Operation4. No Sub group Analysis Ð No Difference in Samples5. No Sub group Analysis Ð Single Test6. No Sub group Analysis Ð Process Rate Not Available in Correct Units

Those major groups, which will be updated or are new are listed in the Part II Sub groupAnalysis section of Table 10. The sub group analysis for these major groups is provided inSection 6.8. Major groups, which will not be updated are listed in the Part I Sub group Analysissection of Table 10. The sub group analysis for these major groups is provided in Section 6.8 ofthe Part I final report and is not repeated in this report. Sections 3 to 6 of Table 10 list majorgroups were no sub group development is possible because no difference in design/operation orsamples was found, single test, or the process rate was not available in the correct units.

6.6 Detailed Data Listings

Background. To investigate the impact of secondary design and operating parametersand evaluate outliers, lists of emission factors, design and operating parameters and data qualityparameters must be compiled. These lists are used to identify trends and as inputs to thestatistical evaluation procedures.

Results. The comparison parameters listed in Table 10 and normalized emissions datafor new and updated emission factors (see Section 1 of Table 10) were compiled into 18 tables,one for each device type. Each of these tables was sorted by major group, category, substance,and normalized emissions. The number and type of design and operating parameters listed

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dependent on the device type. For example, fuel type, SCC, strokes per cycle, capacity,condition, APC system, manufacturer, stack oxygen, and stack flow were listed for internalcombustion engines. Because the detailed data listings contain confidential information they havenot been provided in this report.

6.7 Outliner Analysis

Background. Before establishing sub groups outliers must be identified and evaluated. Ifan outlier results from a calculation or data entry error it can be corrected. Outliers resulting fromsampling and analysis problems may be eliminated from data analysis activities. There are manyapproaches for identifying and handling outliers. For this study, the outlier analysis wasconducted in two steps as described below.

i.) Conduct an outlier analysis per substance per test and per substance per majorgroup. The Dixon test was used to identify outliers per substance per test andper substance per major group. To use the Dixon test, a group of data is selectedand sorted from lowest to highest emissions. Then the high and low points areexamined statistically in relation to the other points in the data set. The test willidentify if the high and low points are outliers at a prescribed level of confidence. For this study the confidence level was 95%. It should be noted that whenapplying the Dixxon test to samples with three points many outliers are identifiedwhere two of the points in the data set have approximately equal values and thirdpoint is slightly higher. This commonly occurs when two points are not detectedand the third point is detected. For this analysis, if the other two points in a dataset had similar values and the outlier was within 1.2 order of magnitude of theirvalue, no other checks or action was taken. These values were accepted as beingwithin the expected precision of the test method.

ii.) Evaluate outlier points identified in Step I to determine if sampling problems,calculation errors, and process upsets occurred. Outliers with calculation errorswere corrected and outliers with sampling problems were assigned a method ratingof F for unacceptable. Emissions with method ratings of F were not used todevelop emission factors. Outliers were not eliminated unless a sampling orprocess problem occurred. A major component of the outlier evaluation isproblems found during the detailed validation of the test reports. The flagsdescribed in Attachment 3 indicate these problems.

Results. The statistical test described in Step (I) yielded 402 outliers by device andsubstance groupings and 641 outliers by major group and substance groupings. Combining thetwo analyses, the total number of outliers for the project is 830. As described in Step (ii) eachoutlier was examined to determine if any calculation errors, sampling problems, and processupsets occurred. As shown in Table 11, 108 of the 830 outliers identified had calculation errors,

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sampling problems or process upsets. Only outliers with calculation errors, sampling problemsor process upsets are shown in Table 11. The outliers are classified by major group, device ID,run ID, category, and substance. If the outlier was identified by the major group or deviceanalysis this is indicated in the ÒStatistical Outliner EvaluationÓ columns. Results of the detailedoutlier review are provided in the ÒRepot Review ResultsÓ columns. Additional information onthe detailed review is provided in the ÒCommentÓ column. All outliers with calculation errorswere corrected and included in the database. Outliers with process or method problems wererejected and not included in the emission factor analysis.

6.8 Sub Group Evaluation

Background. Sub groups may be developed for major groups with two or more sources.Major groups are discussed and identified in Section 6.5. As the number of sources increases thepotential for sub group development also increases. Sub groups are developed when a secondarydesign or operating parameter is identified which impacts emissions. Engineering judgement andstatistical analysis can be used to determine if the secondary parameters have a significant impacton emissions. If a secondary parameters doe impact emissions, sub groups are establishedresulting in lower emissions variability than present across the major group.

If the statistical analysis contradicts commonly accepted knowledge about emissionbehavior, sub groups should not be developed. For example, in Part I the APC system,comparison for natural gas fired asphalt production devices indicated wet scrubbers havesignificantly lower chromium emissions and lower emissions of most other metals than fabricfilters. This results was nor expected since fabric filters control particulate matter better thanwet scrubbers. The control of most metals correlates with particulate matter control. It is likelythat another parameter such as the concentration of metals in the feed or differences in systemconfiguration is responsible for the observed difference and not the APC system. Sinceadditional investigation of the test results did not results did not explain the differences and theAPC system was not responsible, no sub groups were developed.

In cases where a secondary parameter impacts one substance but not another, the datafor both substances could be segregated into different sub groups. Another approach would be tosegregate the data for the substance that was not impacted. This approach can generate a largenumber of sub groups with high variability. To reduce the number of sub groups and thevariability of emissions data in each sub group, sub groups were identified in this project usingthe following two step process.

i.) Identify which secondary parameters (comparison parameters) identified in Table 9impact the emissions data by reviewing data listings and using the t-Test. The t-Testuses the t distribution to determine if two samples are from the same population whenthe variances are unknown but equal. The test is applicable to samples containing lessthan 30 data points. A sample is a group of data with a distinct value or range of values

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of the secondary parameter considered. If the t-Test indicated that two samples are notfrom the same population, the secondary parameter that the sample were grouped b y hasa significant impact on emissions. It should be noted that the t-Test was only used tosupport the development of sub groups. In no case was the t-Test used to blindlydevelop sub groups. Before developing sub groups the results of the t-Test wereexamined to ensure they were reasonable based on engineering judgement.

ii.) Segregate tests in each major group onto sub groups based on the those secondaryparameters identified in step I which impact the emissions data. Results from one devicewere not split into different sub groups. This approach is appropriate when a substanceis impacted by the secondary parameters and when it is not impacted.

It should be noted that when a secondary parameter was found to have a significant impact onemissions and a source in the major group was missing information on the parameter, the sourcewas eliminated from the emission factor development process. For example, in Part I it wasfound that strokes per cycle, 2 or 4, is a key parameter for reciprocating internal combustionengines (ICE). Four natural gas reciprocating ICE tests did not specify the strokes per cycle sothey were eliminated. A sub group for sources with unknown strokes per cycle was notdeveloped because the emission factors could not be applied to any source.

Results. The results of the statistical analysis described in Step (I) above for the majorgroups identified in Section 1 of Table 10 are provided in Attachment 6. Section 1 of Table 10lists new or updated major groups with two or more tests. Statistical analyses for major groupswhich donÕt include new data (see Section 2 of Table 10) are provided the Part I final report. Subgroups cannot be developed for those major groups shown in Sections 3 through 6 of Table 10for the following reasons: no difference in design/operation, no difference in samples, single test,or process rate not available in correct units. For these major groups all of the test data aresimply averaged by major group and substance as described in Section 6.9. The remainder of thissection described sub group development for those major groups listed in Section 1 of Table 10.

Attachment 6 includes a series of similar tables containing the results of the t-Testevaluation of each sub group evaluation parameter listed in Section 1 of Table 10. The tables inAttachment 6 are listed below.

Table A6-1. Source Classification Code Comparison.Table A6-2. Air Pollution Control System Comparison.Table A6-3. Reciprocating Internal Combustion Engine Strokes per Cycle Comparison.Table A6-4. Reciprocating Internal Combustion Engine Oxygen Comparison.Table A6-5. External Combustion Burner Type Comparison.Table A6-6. External Combustion Excess Air Comparison.Table A6-7. Gas Turbine Duct Burner Comparison.Table A6-8. Chrome Plating APC System Comparison.

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Table A6-9. Reciprocating Internal Combustion Engine Size Comparison.Table A6-10. Oil Fired Asphalt Production Contractor Comparison.Table A6-11. Fluidized Bed Combustion Fuel Type Comparison.Table A6-12. Coating, Dryer and Incinerator Material Comparison.Table A6-13. External Combustion Burner Type and Excess Air Comparison.Table A6-14. Reciprocating Internal Combustion Engine Strokes per Cycle and Oxygen

Comparison.Table A6-15. Reciprocating Internal Combustion Engine Strokes per Cycle and Size

Comparison.Table A6-16. Reciprocating Internal Combustion Engine Strokes per Cycle, Oxygen and

Size Comparison.

Each of these tables includes a description of the data sets being compared, number of points,average, standard deviation, and detection limit ratio (detect ratio). The detection ratio is theratio of the sum of detected values to the sum of detected and non-detected values. A detect ratioof one indicated that all of the data was detected. A detect ratio of zero indicated that all of thedata was not detected. If the difference between the data sets being compared is significant basedon the t-Test, a ÒYesÓ is provided in the last column of the table. If the difference is significantand the detection ratio of the higher data set is greater than zero, the higher data set is underlined. If the sample sizes are too small for statistical comparison, i.e. one run per data set only, anÒNAÓ is given in the last column and none of the data sets are shaded or underlined.

Each section below provides a brief description of the sub group analysis for the majorgroups listed in Section 1 of Table 10. A list of final sub groups is provided in Table 12 for pointsource major groups. Table 13 provides a list of sub groups for fugitive major groups. It shouldbe noted that Tables 12 and 13 provide all sub groups developed in Parts I and II. The subgroups in each major groups are compared statistically in Attachment 7.

Asphalt Production Ð Oil

Number of Tests Ð 4Rejected Tests Ð All data from 158, PAH data only from 214 and 215Significant Parameters Ð NoneSub Groups - None

Comments Ð The comparison of contractor A and B data indicated that emissionsquantified in contractor A tests are in general higher and in many cases significantly higher thanthe contractor B. Many of the contractor A data points are non detects and the detection limitsare much higher than contractor B. In particular, contract A PAH results for non detected are upto three orders of magnitude higher because LRMS was used instead of HRMS. Because of theuncertainty of the contractor A data. All data for test 158 were eliminated and all PAH data fromtests 214 and 215 were eliminated. The only difference between the remaining tests is two tests

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were conducted on a unit equipped with a baghouse and one test was conducted on a wetscrubber. The baghouse and wet scrubber emissions are similar as indicted by the statisticalanalysis. Thus, no sub groups will be developed.

Boiler Ð Fuel Oil

Number of Tests- 14Rejected Tests Ð 1 (Fuel type not specified)Significant Parameters Ð SCC (Electric Generation or Industrial)Sub Groups Ð 2

Comments Ð Two new tests have been added to this major group bringing the total oftests to 14. One of the sources has a fabric filter and the rest are uncontrolled. The source with afabric filter has the highest emissions. In addition, most of the data for this source are notdetected and the specific fuel type is not identified. For these reasons, device 102 was eliminatedfrom the emission factor development process. Examination of the data listing and SCCcomparison indicates that the electric generation sources generally have lower emissions than theindustrial type sources. This may indicate a relation between source size and emissions since theelectric generation sources are larger than the industrial sources. Two sub groups will bedeveloped, one for electric generation and one for industrial.

Boiler Ð Refinery Gas

Number of Tests Ð 7Rejected Tests Ð PAH data for Report 2599B, E, G, HSignificant Parameters Ð Excess Air (>100% and <100%)Sub groups Ð 2

Comments Ð Based on a review of the boiler detailed data listing it was found that PAHData from tests in Document 2599 are two to three orders of magnitude higher than the othertests. Several reasons for the difference include: LRMS was used yielding high detection limits,none of the required internal standards were used in the analytical procedures, and high levels ofcontaminated were found in many samples. The omission of the required internal standards is amajor failure and can impact the emissions results significantly. Because one of the objectives ofthis project is to develop accurate emission factors, PAH data from document 2599 wereeliminated from the emissions factor development procedures.

The statistical analysis of boilers included a comparison of post-combustion air pollutioncontrol devices, excess air, burner type, and excess air/burner type. Statistical analyses for theseparameters are provided in Attachment 6 of Volume 2. Observations from the comparisons areprovided below:

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¥ The post-combustion air pollution control system type comparison did not indicate any significant differences.

¥ From the detailed data listing it was observed that sources with high excess air have higher emissions. The excess air levels for five of the boilers ranged from 10 to 77%. Oneof the boilers had excess air levels ranging from 100 to 240. To determine if thedifferences observed in the detailed data listing were significant, data sets with excess air<100% were compared to data sets with excess air >100%. Five of Twenty Two organicHAP comparisons indicated that sources with excess air levels >100% have higheremissions. None of the comparisons indicated that sources with excess air levels <100%have higher emissions.

¥ The burner type comparison does not indicate any significant differences.

¥ The burner type and excess air comparison did not indicate any significant differences.

Based on the above observations sub groups for boilers with excess air >100% and<100% will be developed.

Catalytic Reformer

Number of Tests Ð 2Rejected Tests Ð 0Significant Parameters Ð APC SystemSub Groups Ð 2

Comments Ð Controlled and uncontrolled tests were conducted on a single catalyticreformer unit (CRU). The CRU has an activated carbon (AC) control system. Dioxins andFurans were the only air toxics quantified during the tests. A review of the APC system,comparison indicates that the AC system reduced 1 dioxin and 2 furans by about a half order ofmagnitude. Emissions of the other 22 congeners were not significantly different. Even thoughmost dioxin and furan congeners did not differ significantly, sub groups for controlled anduncontrolled emissions will be developed for CRUs.

Coating, Base/Catalyst/Water Mix

Number of Tests Ð 4Rejected Tests Ð 0Significant Parameters Ð Paint Type (Distinguished by Chromium Content)

- APC System (S or AF)Sub groups Ð 3

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Comments Ð This major group includes test results from 4 coating operations. 3 unitshave air filters (Afs) and 1 unit has a scrubber (S). All 4 coating operations use water basedpaints. 2 of the units use paints with 26 wt% Cr and 2 use paints with 5.25 wt% Cr. Thestatistical comparisons indicate that the paints with 26 wt% Cr have higher emissions of bothTotal and Hexavalent Chromium. The scrubber also has higher emissions of both Total andHexavalent Chromium than the air filter. Therefore, the emissions data will be divided intogroups by paint Chromium content and APC system.

Coating Ð Powder

Number of Tests Ð 8Rejected Tests Ð 0Significant Parameters Ð Powder Type (Distinguished by Chromium Content)

- APC system (None or AF)Sub groups Ð 8

Comments Ð No statistical comparison can be made because only one run was conductedper test condition for all but one test. However, the data clearly shows a dependence ofchromium emissions on the percent of chromium in the feed. The higher the chromium content ofthe feed the higher the emissions. It also appears that controlled sources have lower emissions.

Dryer, Pot Ash

Number of Tests - 2Rejected Tests Ð 0Significant Parameters Ð APC System and FeedSub groups Ð 2

Comments Ð This major group includes two tests. One test was conducted on a sulfateof potash dryer controlled by a baghouse. The other test was conducted on a potash dryercontrolled by a scrubber. Emissions from the sulfate of potash dryer are significantly higher thanemissions from the potash dryer. Therefore, two sub groups will be developed.

Dryer, Sand/Gravel

Number of Tests Ð 2Rejected Tests Ð 0Significant Parameters Ð APC System, MaterialsSub groups Ð 2

Comments Ð This major group includes two tests at sand/gravel facilities. One facilityhas a Baghouse (BH) and the other uses a Caustic Scrubber (CS). The facility with the CS also

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blends contaminated soils with the raw materials. No statistical comparisons could be conductedsince the facilities did not quantify any of the same substances. Since the controls and materialsare significantly different, sub groups will be developed for each facility.

Fluidized Bed Combustion Ð Biomass

Number of Tests Ð 4Rejected Tests Ð 0Significant Parameters Ð Waste Type (Agricultural Waste, Agricultural/Urban Wood Waste,

Urban Wood Waste, Saw Mill Wood Waste)Sub groups Ð 4

Comments Ð Emissions test results from one Fluidized Bed Combustion (FBC) unit havebeen added to this major group in Part II. The FBC unit was tested while firing a 50/50 mix ofagricultural waste and urban wood waste and while firing just urban wood waste. Each of thefour tests in this major group were conducted while firing different types of biomass including:

¥ Agricultural Waste¥ Agricultural/Urban Wood Waste¥ Urban Wood Waste¥ Saw Mill Wood Waste

Two of the units tested had fabric filters and one unit had an ESP.

Statistical comparisons of the biomass types and particulate control systems areprovided in Attachment 6. Only one significant difference was found in over 40 comparisons forthe particulate control systems. When comparing the type of biomass burned, numeroussignificant differences were found. This indicated that the composition of the biomass burnedhas a significant impact on emissions. Many of the biomass type comparisons indicated that thetests conducted while firing agricultural waste or a combination of agricultural waste and urbanwood waste have higher emissions. Sub groups will be developed based on the type of biomassfired. Therefore, each sub group will have a single test.

Furnace Ð Lead

Number of Tests Ð 4Rejected Tests Ð 0Significant Parameters Ð SCCSub groups Ð 2

Comments Ð This major group includes tests conducted on 4 lead melting pots at abattery component processing facility. Each melting pot includes a baghouse to control

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particulate emissions. Three of the melting pots produce molten lead and one pot produces leadoxide. No statistical comparisons were conducted for this major group because the normalizingunit for the pots producing molten lead is different than the normalizing unit for the melting potproducing lead oxide. Therefore, sub groups were developed for the two processes (i.e.,production of lead and production of lead oxide). No difference in the design/operation of thethree lead melting pots was found in the report so emissions data from these tests will beincluded in a single sub group.

Heater Ð Refinery Gas

Number of Tests Ð 25Rejected Tests Ð PAH data for Reports 2599A, B, C, D, NSignificant Parameters Ð Excess Air (>100% and <100%)Sub groups Ð 2

Comments Ð Based on a review of the heater detailed data listing it was found that PAHdata from tests in Document 2599 are two to three orders of magnitude higher than the othertests. PAH data from Document 2599 are significantly higher. Several reasons for the differenceinclude: LRMS was used yielding high detection limits, none of the required internal standardswere used in the analytical procedures, and high levels of contaminates were found in manysamples. The omission of the required internal standards is a major failure and can impact theemission results significantly. Because one of the objectives of this project is to develop accurateemission factors, PAH data from document 2599 were eliminated from the emission factordevelopment procedures.

The statistical analysis of heaters included a comparison of post-combustion air pollution controldevices, excess air, burner type, and excess air burner type. Statistical analyses for theseparameters are provided in Attachment 6. Observations from the comparisons are providedbelow:

¥ The comparison of post-combustion air pollution control devices indicated severalsignificant differences. Most of the differences were detected for metals. Since thecontrols used including SCR and DeNOx are not expected to impact metals emissions, sosub groups were developed.

¥ From the detailed data listing it was observed that sources with high excess air havehigher emissions. The excess air level for 20 of the heaters ranged from 9 to 80%. Two ofthe heaters had excess air levels ranging from 111 to 224. To determine if the differencesobserved in the detailed data listing were significant, data sets with excess air <100% werecompared to data sets with excess air >100%. Twenty of Thirty organic HAP

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comparisons indicated that sources with excess air levels >100% have higher emissions.None of the comparisons indicated that sources with excess air levels <100% have higheremissions.

¥ Only two organic substances (Fluoranthene and Pyrene) of 24 indicate LNBs havesignificantly higher emissions than CBs. If burner type was a key parameter it shouldimpact the emissions of other organics significantly.

¥ When grouping by burner type and excess air, four significant differences are found. Two of these are likely a result of excess air levels and not the burner type. Theremaining two significant differences are the same ones discussed in the burner typecomparison above. These comparisons indicate that LNB have higher emissions. However, only two organics indicate that LNBs have higher emissions. If LNBs did havea significant impact on organic emissions it is expected that more substances would beimpacted.

Based on the above observations sub groups for heaters with excess air >100% and<100% will be developed.

Internal Combustion Engine Ð Diesel

Number of Tests Ð 10Rejected Tests Ð 0Significant Parameters Ð SCC (Electric Generation, Industrial or Commercial/Institutional)

- Oxygen Level (<13% or >13%)Sub groups Ð 5

Comments Ð Two additional units have been added to this major group in Part II. Oneunit was tested for ammonia emissions and the other unit was tested for PAH and formaldehydeemissions. The ammonia test is the first in the Diesel fired Internal Combustion Engine group.

In part I it was found that sources with a stack oxygen content greater than 13% havehigher emissions than sources with oxygen <13%. In addition, it was found that emissions fromcommercial engines are lowest and electric generation engines are highest. Industrial engines haveemissions between commercial and electric generation sources. This relation between source typeand emissions may also be related to stack oxygen content since all of the electric generationsources have higher stack oxygen contents and all of the commercial sources have lower stackoxygen contents. The industrial sources are split roughly between high and low stack oxygenunits. The new unit which was tested for PAH and formaldehyde emissions supports both thePart I observations on stack oxygen content and source type. Therefore, the same sub groups areproposed for Part II. Statistical comparisons of SCC, stack oxygen, and source size are providedin Attachment 6.

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Internal Combustion Engine Ð Natural Gas

Number of Tests Ð 25Rejected Tests Ð 4 (Strokes per cycle not specified)Significant Parameters Ð Strokes (2 or 4)

- Oxygen (Rich or Lean)- Capacity (>650 Hp or <650 Hp)- APC System (None or NSCC)

Sub groups Ð 5

Comments Ð Three additional units have been added to this major group in Part II. Eachof the units was tested for formaldehyde and two units were tested for benzene. Additionalbenzene, toluene, and xylene test results were added to Device ID 171. Two of the units beingadded to the database for this major group have non-selective catalytic converters (NSCC). Noneof the Part I units have post combustion controls.

Due to the larger sample size of the natural gas fired internal combustion engine majorgroup, several secondary parameters were considered including APC system, strokes per cycle,rich or lean combustion, and source size. The statistical analysis of each of these parameters isprovided in Attachment 6. Observations from the statistical analysis and detailed data listing areprovided below.

¥ As noted previously two of the units added in Part II have NSCC. The statisticalcomparison of these units without post combustion controls indicates that NSCCprovides lower emissions of both benzene and formaldehyde. Formaldehyde emissionsare significantly lower.

¥ A comprehensive comparison of 2 and 4 stroke engines is not possible since most of theunits in the database are 4 stroke engines. The statistical comparison of 2 and 4 strokeengines did not indicate any significant differences. However, since the analysis for fieldgas engines (see Part I final report) and theory indicates the engine configuration isimportant, the engines were divided into 2 and 4 stroke sub groups. The number ofstrokes per cycle could not be verified for four devices (156, 168, 169, 170). Thesedevices were eliminated from the analysis and will not be included in the emissions factordevelopment procedure. Only source 156 has a significant quantity of data.

¥ For the 4 stroke engines, the statistical comparisons indicated that sources with oxygenless than 2% (rich burn) have significantly higher emissions of many organics includingPAHs than sources with oxygen greater than 2% (lean burn). Formaldehyde emissionsare significantly higher for lean burn sources. No comparison of emissions from 2 strokelean and rich burn engines was possible since all of the 2 stroke engines were lean burn.

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¥ For the 4 stroke lean burn engines, 13 of 22 statistical comparisons indicated that sourceswith <650 Hp have significantly higher emissions than sources with >650 Hp. Thesecomparisons included a range of organics including PAHs, aldehydes, benzene andtoluene. The impact of size could not be evaluated for 4 stroke rich burn since all 4 strokerich burn engines were <650 Hp.

Based on the above discussion, tests in the natural gas fired internal combustion enginemajor groups will be divided into sub groups by post combustion air pollution control system,strokes per cycle, rich or lean combustion, and source size.

Incinerator Ð Medical Waste

Number of Tests Ð 6Rejected Tests Ð 3 (Missing Key Parameters)Significant Parameters Ð Waste, Manufacturer, APC SystemSub groups Ð 3

Comments Ð Six medical waste incinerators are included in this major group. Thecharacteristics of these incinerators are provided in Table 14. Five of the incinerators have twochambers and no post combustion controls. One incinerator has a scrubber and the number ofchambers was not specified. None of the reports provided comprehensive design and operatingdata. Where available, the incinerator manufacturer and stack oxygen have been listed in Table14. The waste type descriptions have been listed directly from the reports. No additional wastecharacteristics are provided in the reports.

A comparison of incinerator emissions by APC system is provided in Attachment 6. Asshown in Table 14, HCl is the only substance, which can be compared by APC system TheAPC system comparison indicates that the scrubber has significantly lower HCl emissions. Thedifference in HCl emissions may also result partly from differences in the chlorine contents of thewastes burned. No information on waste chlorine content is provided in the reports.

Attachment 6 also includes a comparison of incinerator emissions by waste type. Dioxin/furan, PAH, hexavalent chromium, and formaldehyde emissions from systems withoutpost combustion controls are compared. The HCl waste type comparison is most likelydetermined by the post combustion controls of the systems being compared. The dioxin/furancomparison indicates that the system which burns infectuous waste (Device ID 227) hassignificantly higher emissions than the systems which burn animal bedding (Device ID 226) andpathological waste (Device ID 208). The observed difference in emissions may also be a result ofthe incinerator design and operation. The infectious waste incinerator is an Incinomite with astack temperature ranging from 457 to 502 and the incinerators with lower dioxin/furanemissions are manufactured by Ecolair and ThermTech. Both of these incinerators have higher

37

stack temperatures as shown in Table 14. The comparisons for PAH and formaldehydeemissions cannot be evaluated statistically because the sample sized are less than 3.

As described above the incinerators compared have a wide range of designs andoperation. Each incinerator has a unique configuration and waste composition. As a result, noneof the data will be combined. Instead, a separate group will be developed for each system. Inorder for these emissions factors to be applied to other systems some basic information must beavailable including manufacturer, waste type, and post combustion air pollution control system. Three of the tests (Device Ids 208, 226, and 227) provide this necessary information and will bedeveloped into emission factors. Data from tests 245, 246, and 283 donÕt provide all of thenecessary process characteristics. Therefore, these tests will be rejected and not included onfactors. It should be noted that the tests, which will be developed into emission factors, donÕtcontain comprehensive details on the process design/operation or waste characteristics. As aresult, these emissions factors have high uncertainty.

Plating Ð Anodizing

Number of Tests Ð 6Rejected Tests Ð 0Significant Parameters Ð APC System

(Control systems with filter, controls systems without filter)Sub groups Ð2

Comments Ð The anodizing operating data set includes 5 tests. As with the hard platingdata sets few operational parameters were available. Al of the test were conducted on controlledunits. The controls range from a wet scrubber to a mist eliminator/wet scrubber/HEPAcombination. Only one of the tests was conducted on a system with a filter. The total chromiumresults for this test are lower than other tests which do not have filters. It should also be notedthat all test results for the system with a filter were not detected. If more sensitive techniqueswere used it is likely that the filter results would be lower. In addition, because of the lowsensitivity of the filter test, the hexavalent chromium results are higher than total chromiumresults. Statistical comparisons of the different systems are provided in Attachment 6. Thesecomparisons are not very reliable since the anodizing data sets are small consisting of 1 to 2 testseach.

Based on the observations described above, two sub groups will be developed foranodizing operations including sub groups for devices with and without filters.

Plating Ð Decorative

Number of Tests Ð 2Rejected Tests Ð 0

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Significant Parameters Ð APC System (Control systems with filter, controls systems without filter)

Sub group Ð 2

Comments Ð The decorative plating operation data set is very limited with only twotests. As shown in Table 15, one test was conducted on a system with a wet scrubber and theother on a system with a mist eliminator, mist suppressant, and HEPA. Emissions from theHEPA system are orders of magnitude lower than the system with a wet scrubber. The wetscrubber hexavalent chromium emissions are the highest of any plating operation including hardand anodizing operations. In addition, the wet scrubber hexavalent chromium emissions were notdetected indicating a low sensitivity analysis technique and/or short sample time.

Based on the observations described above, two sub groups will be developed fordecorative plating operations including sub groups for devices with and without filter. Emissionsdata for the sub group without a filter are considered very unreliable because low sensitivitytechniques were used.

Plating Ð Hard

Number of Tests Ð 41Rejected Tests Ð 1Significant Parameters Ð APC System

(Control systems with filter, controls systems with filter, uncontrolled units)

Sub groups Ð 3

Discussion Ð The hard plating data set includes 41 tests quantifying hexavalent and totalchromium emissions. While this is a large data set there are also 27 different air pollution controlsystem configurations as shown in Table 15. In addition, most tests did not provide informationon other potentially important parameters including amount of work, chemical or electrochemicalactivity, the strength and temperature of solution, and current densities. As a result of the widerange of control configurations and incomplete process descriptions it is difficult to identify theimpact of specific control devices on emissions.

All of the tests except one had some type of control installed. The control devices canbe segregated into four groups, mainly wet scrubber, chemical fume suppressants, misteliminators, and filters. As shown in Table 15, most of the hard plating devices have wetscrubbers. The specific type of scrubber was not specified for 10 of the tests. Several chemicalfume suppressants were used including Fumetrol 101, Fumetrol 140, foam blankets, andpolypropylene balls. The mist eliminators included mesh-pad and Chevron-blade and most ofthe filters were HEPAÕs.

39

Examining the emissions data in the detailed data listing (see Section 6.6), no cleardifferences were found between devices with and without wet scrubbers, chemical fumesuppressants, or mist eliminators. However, the detailed data listing shows that many of thelowest emitting devices had filters. The observation from the detailed data listing that airpollution control systems with filters have lower emissions is quantified statistically inAttachment 6. Attachment 6 provides a statistical comparison of both total and hexavalentchromium emissions by air pollution control system. The different control systems aredistinguished by the presence of wet scrubbers, chemical fume suppressants, mist eliminators,and/or filters. Specific types of control are not compared such as F101 vs. F140 or HEPA vs.MP because this would yield small samples for comparison. Comparisons of samples with 1test are not generally considered reliable. The comparisons for hard plating operations show thatair pollution control systems with filters have statistically lower emissions. In only 6comparisons did control systems with filters have statistically higher emissions. However,control systems without filters had statistically higher emissions in 62 comparisons.

Based on the discussion above three sub groups have been developed including systemswith filters, systems without filters, and systems without controls. The first two sub groups arethe same as those developed in Part I. The uncontrolled category is new.

Steam Generator Ð Natural Gas/CVRB

Number of Tests Ð 5Rejected Tests Ð 0Significant Parameters Ð NoneSub groups Ð 1

Comments Ð All sources in this category have low excess air and no post-combustioncontrols, so no comparison of the impact of these parameters was made. For naphthalene,conventional burners had higher emissions than low-NOx burners. Since this comparison wasbased on single source data sets and no other comparisons indicate conventional burners havehigher emissions, sub groups based on burner type were not established.Shredding and Delaquering Ð Aluminum

Number of Tests Ð 2Rejected Tests Ð 0Significant Parameters Ð APC SystemSub groups Ð 2

Comments Ð This major group includes two shredding and delaquering units. One unithas a venturi scrubber (VS) and the other has a baghouse (BH) to control particulate emissions. Dioxins and furans were quantified on the unit with a VS and metals on the unit with a BH. Astatistical evaluation was not conducted because the same substances were not quantified on the

40

both units. Since metals and dioxins/furans could be impacted by the type of particulate controlinstalled, sub groups were developed for each unit.

Turbines Ð Natural Gas

Number of Tests Ð 16Rejected Tests Ð 0Significant Parameters Ð SCC (Cogeneration or Noncongeneration)Sub groups Ð 2

Comments Ð Seven additional turbines have been added as a results of the Part IIactivities. Three of these turbines have heat recovery steam generators and are classified ascogeneration operations. Duct burners, cogeneration and post combustion air pollution controlswere the sub group parameters investigated for this major group. Statistical comparisons of theseparameters are provided in Attachment 6. The comparison of post combustion air pollutioncontrol systems indicated that systems with SCR/COC had significantly higher emissions ofsome organics than systems without any post combustion controls. The observed difference islikely a result of another difference in design or operation.

The comparison of emissions from systems with and without cogeneration indicates thatcogeneration systems have lower organic emissions. This is consistent with the Part I analysis. Reviewing the data it was found that systems with cogeneration have lower stack oxygen and aregenerally larger than systems without cogeneration. These factors may contribute to the lowerorganic emissions observed in the statistical comparisons.

Emissions from systems with and without duct burners also were compared. Ductburners are sometimes added to cogeneration systems to add supplement heat to the turbineexhaust before the heat recovery steam generator. No significant differences were found.

Based on the above discussion, sub groups will be developed for systems with andwithout cogeneration.6.9 Sub Group Emission Factor Calculation

Background. Once sub groups have been established, run specific emission factors mustbe averaged for each substance in each sub group. For this project, the run specific emissionfactors were averaged arithmetically. It should be noted that most tests included three runs. Therefore, if a sub group included two tests the corresponding six run emission factors would beaveraged. In addition to the arithmetic average, several statistics were calculated including theuncertainty, relative standard deviation, number of sources, detection ratio, and median, maximumand minimum emissions factors. The detect ratio is defined as the ratio of the sum of all of thedata was detected. A detect ratio of zero indicates all of the data was not detected. The relativestandard deviation and uncertainty are indicator of the precision and accuracy of the emissions

41

factors. The relative standard deviation is calculated as 100 times the standard deviation dividedby the arithmetic average. The uncertainty is calculated as 100 times the 95% confidence intervaldivided by the arithmetic average. Ideally the relative standard deviation and uncertainty shouldbe zero.

Results. Tables 19 and 20 list emission factors and corresponding sample statistics forpoint and fugitive sources, respectively. One set of emission factors is given per major and subgroup. Descriptions of the major and sub groups are provided in Tables 12 and 13. The relativestandard deviation and uncertainty information in Table 19 and 20 are summarized in Table 16for each substance. The average relative standard deviation is 56% (42% Median) and the averageuncertainty is 108% (Median 73%). To reduce these values would require additional sub groups. However, no additional sub groups were found. It should also be noted that creating additionalsub groups reduces the size of the sample that reduces the representativeness of the emissionfactors.

6.10 Sub Group Method and Population Rating

Background. Once the emission factors have been calculate it is important to assignquality ratings to each emission factors. Several ratings can be assigned to each emission factorincluding method and population ratings. The method rating describes the test method that wasused and the level of supporting document provided. The method rating used for this project isdescribed in Section 6.3. It should be noted that the method rating is assigned on a run basis. When the runs are averaged together to calculate emissions factors for each substance in each subgroup, the method rating must also be averaged. For example, if an average emissions factor wasderived from one A rated run and one C rated run, B would be the resulting method rating.

The second rating is used to describe how well emissions can be estimated from theentire pool of sources. To provide an accurate estimate of emissions from the source pool, anemission factor should be derived from many randomly chosen facilities in the industrypopulation. For this study, one of the following population ratings was assigned to eachemission factor.

1 - Source test data taken from many randomly chosen facilities in the industrypopulation (5 or more sources).

2 - Source test data taken from a reasonable number of facilities (3 to 4 sources).3 - Source test data taken from a small number of facilities, and there may be reason

to suspect that the facilities do not represent a random sample of the industry (<3sources).

Population ratings were assigned based on a recommendation from the California Air ResourcesBoard. This recommendation was to assign the population rating based on the number of sourcesas described above.

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Results. Average method ratings are provided in Tables 19 and 20 for each emissionfactor. The method rating is the first character of the ARB rating. The population ratings arealso provided in Tables 19 and 20. The second character of the ARB rating is the populationrating.

6.11 CARB Overall Quality Rating

Background. Several indicators of data quality have been assigned to each emissionfactor. These indicators include the method rating, population rating, and indicators of variabilitysuch as the relative standard deviation and uncertainty. To summarize all of these indicators, asingle CARB overall rating was developed. The CARB overall rating has the format Òxy-vnÓwhere ÒxÓ is the method rating, ÒyÓ is the population rating, and ÒnÓ is the order of magnitudedifference between the minimum and maximum emission factors for each substance in each subgroup. It should be noted that if the emission factor was developed from a single run, n was setto Ò-Ò.

Results. CARB overall ratings are provided in the ÒARB RatingÓ column of Tables 19and 20 for each emission factor. The number of emission factors with each CARB overall ratingare provided in Table 17. It should be noted that the EPA methods are not considered inferior. However, the Hot Spots Program mandated that an EPA method could be used only if there wasno corresponding CARB test method or if the source asked for an equivalency determination. CARB and EPA test methods are different in many cases and can lead to different results. CARB test methods were rated higher than the EPAÕs to provide consistent test resultcomparisons.

6.12 EPA Overall Quality Rating

Rating. Similar to the CARB overall quality rating, the EPA has developed an overallquality rating used to designate the quality of each emission factor. This rating termed Òfactorquality ratingÓ by the EPA considers the type of method used, level of supportingdocumentation available, and how well the population is represented. The EPA assigns factorquality ratings of A, B, C, D, and E as described below.

EPA Factor Quality Rating or Overall Quality Rating

A Excellent. Factors developed only from A-rated source test data taken from manyrandomly chosen facilities in the industry population. The source category isspecific enough to minimize variability within the source population.

B Above average. Developed only from A-rated test data from a reasonable numberof facilities. Although no specific bias is evident, it is not clear if the facilities

43

tested represent a random sample of the industry. AS with the A rating, thesource is specific enough to minimize variability within the source population.

C Average. Developed from A- and B-rated test data from a reasonable number offacilities. Although no specific bias is evident, it is not clear if the facilities testedrepresent a random sample of the industry. As with the A rating, the sourcecategory is specific enough to minimize variability within the source population.

D Below average. Developed from A- and B-rated test data from a small number offacilities, and there may be reason to suspect that these facilities do not representa random sample of the industry. There also may be evident of variability withinthe source population.

E Poor. The emission factor was developed from C- and D-rated test data, and theremay be reason to suspect that the facilities tested do not represent a randomsample of the industry. There also may be evident within the source categorypopulation.

EPA A through D test data/method ratings used to assign EPA factor quality factorquality are listed and described below

EPA Test Data Rating or Method Rating

A When tests are performed by a sound methodology and are reported in enoughdetail for adequate validation.

B When tests are performed by a generally sound methodology but lack enoughdetail for adequate validation.

C When tests are based on an untested or new methodology or are lacking asignificantly amount of background data.

D When tests are based on a generally unacceptable method but the method mayprovide an order-of-magnitude value for the source.

Results. To allow comparison of the quality of CARB and EPA emission factors on asimilar basis, EPA overall quality ratings or factor quality ratings were assigned to each CARBemission factor using the criteria provided in Table 18. The number of CARB emission factorswith each EPA overall rating is provided within parentheses in Table 18. The EPA overallratings shown in Table 18 were assigned for this project and are not official EPA ratings.

The definitions of the CARB and EPA method ratings provided in Tables 17 and 18 aredifferent. The CARB method rating system was developed to distinguish between tests

44

conducted using EPA and CARB methods as well as tests that provide and do not providesufficient documentation. The EPA method rating system does not identify the local, state orfederal government agency that developed the test method. The CARB system does not denotetests based on untested/new methodologies or tests based on generally unacceptable order ofmagnitude methods (see EPA method ratings C and D). A CARB method rating for tests basedon generally unacceptable order of magnitude methods is not needed, because these tests were notincluded in the CARB database.

To assign EPA overall quality ratings as described in the background section above,various terms such as many randomly chosen facilities, reasonable number of facilities, and smallnumber of facilities had to be defined. In addition since EPA method ratings must be assigned toassign EPA overall quality ratings, EPA method rating terms such as sound methodology,adequate validation, and untested/new methodology were defined. Each EPA term along with theCARB definition used for this project is provided below.

EPA Term CARB Definition1. Many Randomly/Chosen Facilities 5 or more Sources2. Reasonable Number of Facilities 3 to 4 Sources3. Small Number of Facilities <3 Sources4. Sound Methodology Current EPA or CRB Method5. Adequate Validation Adequate Validation if Specified Number of

Primary Validation. Parameters could bechecked (see Section 6.3)

6. Untested/New Methodology Old versions of CARB or EPA testmethods.

The CARB definitions were applied to assign EPA method and overall quality ratings.

45

TABLE 1. PART II DATA COLLECTION SUMMARY.

District Number of Comment

Tests

Tests Collected During Part II

Amador 0 No additional tests identified

Butte 1

North Coast 1

Placer 0 No additional tests identified

San Joaquin 2

Santa Barbara 76 8 Source and 68 Fugitive tests

South Coast 39

Ventura 43 9 Source and 34 Fugitive Tests

Tehema 1

Tuolumne 0 No additional tests identified

Tests Not Collected During Part II

Bay Area 2 No response

Lassen 2 ARB has two pooled test plans

Mojave 36 Move tests for unique devices and would not havegeneral applicability

Sacramento 6 No response

San Diego ? No response

Shasta 10 ARB has ten pooled test plans

46

TABLE 2. SCREENING RESULTS SUMMARY.

Screening Check Number of Tests Failing Screening Check

Part I Part II Project

No Air Toxic Measurements 4 76 80

SCC Could Not be Assigned 0 33 33

Process Rate Not Available 302 69 371

No Laboratory or Sample DataProvided

0 29 29

Key Design and OperatingParameters not Provided

0 39 39

Single Run Test 0 34 34

Duplicate Reports 9 21 30

Wrong Method Used 0 1 1

Total 315 302 617

47

TABLE 3. PART II DETAILED VALIDATION SOURCE TEST LISTING.

ReportID

DeviceID

Tests Device Type Air PollutionControl System

Fuel Material

2524A 234 1 Anodizing tank ? None Aluminum2364A 214 1 Asphalt production C/BH Back-up oil Aggregate/asphalt2365A 215 1 Asphalt production C/BH Back-up oil Rocks/sand/

petroleum2194A 216 1 Asphalt production FF ? Asphalt2193A 217 1 Asphalt production FI Natural Gas Flux2099A Rev 1 Asphalt production, crusher None Aggregate2304D 280 1 Batteries, Cast on strap line FI None Batteries2304B 281 1 Batteries, Grid casting ? None Grids2304A 282 1 Batteries, Post pour ? None Batteries2512A 201 1 Boiler LI/SNCR Wood/biomass None2095A 218 1 Boiler ? Coal/natural gas None2600A 261 1 Boiler None Refinery fuel gas None2623A 279 1 Boiler AI/LI/B Coal/coke None2599B 505 1 Boiler SCR Refinery fuel gas None2599E 508 1 Boiler None Refinery fuel gas None2599G 642 1 Boiler None Refinery fuel gas None2599H 643 1 Boiler None Refinery fuel gas None2487A 645 1 Boiler ? Fuel oil no. 6 None2599F 646 1 Boiler None Refinery fuel gas None2333A 209 1 Coating operation AF None Poly-amide paint2334A 210 1 Coating operation ? None Barium chromate

primer2197A 211 1 Coating operation ? None Acrylic enamel

systems2529B 252 1 Coating operation ? None Ni/Al thermal

spray powder2609A 270 1 Coating operation FI None Water reducible

paint2610A 273 1 Coating operation FI None Solvent reducible

paint2620A 278 1 Coating operation S None Water reducible

paint2160A Rev 1 Coating operation ? None Paint2605A 263 1 Cogeneration unit SCR/AI/COC/HPC Natural gas/refinery

gasNone

2607E 271 1 Cogeneration unit SCR/COC Natural gas/refinerygas/butane

None

2607F 272 1 Cogeneration unit SCR/COC Natural gas/refinerygas

None

2118A 212 1 Dehydrator C Natural gas Sludge2630A 289 1 Dehydrator None Natural gas Glycol2575A 205 1 Dryer C/BH ? Fiberboard2353A 249 1 Dryer BH Diesel Specialty sand2082A 250 1 Dryer ? ? Pot ash2085A 251 1 Dryer BH ? Sulfate of pot ash2317A 203 1 Flare None Landfill gas None2350A 213 1 Flare None Landfill gas None

48

TABLE 3. PART II DETAILED VALIDATION SOURCE TEST LISTING.

ReportID

DeviceID

Tests Device Type Air PollutionControl System

Fuel Material

2624A 284 1 Flare None Landfill gas None2602A 260 1 Fluid Catalytic Cracking

Unit? Refinery fuel gas Oils

2204A Rev 1 Air analysis at landfill None Landfill gas2206A Rev 1 Air analysis at landfill None Landfill gas2010A 223 1 Furnace, Carbon ? ? Precarbonized

rayon2016A 219 1 Furnace, melting pot ? Natural gas Lead2016A 220 1 Furnace, melting pot ? Natural gas Lead2016A 221 1 Furnace, melting pot ? Natural gas Lead2016A 222 1 Furnace, melting pot ? Natural gas Lead2531A 200 1 Furnace, Metal None Fuel oil no. 6 Metal2131A ** 1 Furnace, Steel BH ? Steel2488A 224 1 Heater None Natural gas None2117A 225 1 Heater SCR Refinery fuel gas None2601A 259 1 Heater None Refinery fuel gas None2604A 262 1 Heater None Refinery fuel gas None2605B 264 1 Heater SCR/AI/COC/HPC Refinery fuel gas None2607A 265 1 Heater None Refinery fuel gas None2607B 266 1 Heater None Refinery fuel gas None2607C 267 1 Heater None Refinery fuel gas None2607D 268 1 Heater None Refinery fuel gas None2607G 269 1 Heater None Refinery fuel gas None2598A 436 1 Heater Thermal DeNOx Refinery fuel gas None2599A 437 1 Heater SCR Refinery fuel gas None2599N 438 1 Heater SCR Refinery fuel gas None2300A 439 1 Heater None Refinery fuel gas None2300A 440 1 Heater None Refinery fuel gas None2300A 441 1 Heater None Refinery fuel gas None2300A 442 1 Heater None Refinery fuel gas None2300A 443 1 Heater None Refinery fuel gas None2599A 444 2 Heater None Refinery fuel gas None2124A 445 3 Heater None Refinery fuel gas None2599C 506 1 Heater None Refinery fuel gas None2599D 507 1 Heater None Refinery fuel gas None2599B 509 1 Heater None Refinery fuel gas None2103A 244 1 Incinerator None Natural gas Infectuous waste2558A 208 1 Incinerator, Onsite ? Gas Pathological

waste2422A 226 1 Incinerator, Onsite ? ? Animal bedding2103A 227 1 Incinerator, Onsite None Natural gas Infectious waste2410A 228 1 Incinerator, Onsite SCR Waste gas ?2543A 229 1 Incinerator, Onsite ? ? Coffee beans2542A 230 1 Incinerator, Onsite ? Diesel Waste explosives2398A 245 1 Incinerator, Onsite ? Natural gas Human carcasses2398B 246 1 Incinerator, Onsite ? Natural gas Animal carcasses2152A 247 1 Incinerator, Onsite ? Propane Bodies2152A 248 1 Incinerator, Onsite ? Propane Bodies2199A 283 1 Incinerator, Onsite S Natural gas ?

49

TABLE 3. PART II DETAILED VALIDATION SOURCE TEST LISTING.

ReportID

DeviceID

Tests Device Type Air PollutionControl System

Fuel Material

2185A 232 1 Kiln CS ? 60% blue shalepetroleum hydro

2395A 238 1 Oven ? ? Coating ofelectric motorwires

2097A 237 1 Oven, Curing ? Natural gas Abrasive cuttingtools

2191A Rev 1 Oven, Conventional air ? ? Bread2187A Rev 1 Oven, Conventional air ? ? Bread2456A 239 1 Plating operation PBS None Chromic acid2430A 240 1 Plating operation DM/PB/F101 None Chromic acid2431A 241 1 Plating operation DM/S/PB/F101 None Chromic acid2431A 242 1 Plating operation DM/S/PB/F101 None Chromic acid2431A 243 1 Plating operation DM/S/PB/F101 None Chromic acid2626A 286 1 Plating operation S None Chromic acid2847A, 286 1 Plating operation S None Chromic acid2878A2866A, 455 1 Plating operation S None Chromic acid2802A2819A 456 1 Plating operation S None Chromic acid2816A 457 1 Plating operation DM/PBS/HEPA None Chromic acid2832A 458 1 Plating operation DM/S None Chromic acid2874A 459 1 Plating operation DM/S/F140 None Chromic acid2841A 460 1 Plating operation DM/PBS/PB/F101 None Chromic acid2870A, 461 1 Plating operation DM/PBS/FB/PB None Chromic acid2849A2837A 462 1 Plating operation F140 None Chromic acid2868A 463 1 Plating operation DM/PB/HEPA None Chromic acid2883A 464 1 Plating operation DM/PBS/HEPA None Chromic acid2875A 465 1 Plating operation PBS None Chromic acid2852A 466 1 Plating operation F140 None Chromic acid2850A 467 1 Plating operation DM/S/F101/F140/

MPNone Chromic acid

2850A 468 1 Plating operation DM/S/F101/PB/MP None Chromic acid2848A 469 1 Plating operation PBS/F101/PB None Chromic acid2815A 470 1 Plating operation DM/DMNP/HEPA None Chromic acid2814A 471 1 Plating operation DM/HEPA None Chromic acid? 472 1 Plating operation DM/HEPA None Chromic acid? 473 1 Plating operation DM/HEPA None Chromic acid2865A 474 1 Plating operation S/FPT None Chromic acid2800A 475 1 Plating operation PBS/FB None Chromic acid2867A 476 1 Plating operation DM/S None Chromic acid2823A 477 1 Plating operation S/F None Chromic acid2813A, 478 1 Plating operation DM/PBS/PB None Chromic acid2879A2805A 479 1 Plating operation PBS/DM None Chromic acid2575B 206 1 Presser None None Fiberboard2492A 446 1 Reboiler None None Triethylene

Glycol2492B 447 1 Reboiler None None Ethylene Glycol

50

TABLE 3. PART II DETAILED VALIDATION SOURCE TEST LISTING.

ReportID

DeviceID

Tests Device Type Air PollutionControl System

Fuel Material

2460B 169 1 Reciprocating ICE None Natural gas None2460B 170 1 Reciprocating ICE None Natural gas None2460B 171 1 Reciprocating ICE None Natural gas None2436A 231 1 Reciprocating ICE None Diesel None2616A 274 1 Reciprocating ICE NSCR Natural gas None2616B 275 1 Reciprocating ICE NSCR Natural gas None2629A 288 1 Reciprocating ICE SCR/AI Diesel None2355A 448 1 Reciprocating ICE None Natural gas None2404A Rev 5 Reciprocating ICE ? Landfill gas None2631A 290 1 Rotary kiln WS Natural gas ?2005A 235 1 Shredding and delaquering BH None Aluminum2072A 236 1 Shredding and delaquering S None Aluminum2324A 233 1 Delaquering ? None Aluminum2407A 511 2 Steam generator None Natural/CVR gas None2407A 512 1 Steam generator None Natural/CVR gas None2407A 513 1 Steam generator None Natural/CVR gas None2502A 253 1 Thermal oxidizer ? Natural gas ?2009A 254 1 Turbine None Natural gas None2009A 255 1 Turbine None Natural gas None2102B 256 1 Turbine None Natural gas None2102B 257 1 Turbine None Natural gas None2130A 258 1 Turbine None Natural gas None2627A 287 1 Turbine SI/AI/SCR Natural gas None2459A 449 1 Turbine SCR Natural gas None2599K 451 1 Turbine SCR/COC RFG/NG None2599K 452 1 Turbine SCR/COC RFG/NG None2599J 510 2 Turbine SCR/COC NG/LPG/RFG None2599I 644 1 Turbine COC Refinery fuel gas None2477A Rev 2 Turbine ? Natural gas None2575B 207 1 Unloader None None Fiberboard

** Data not extracted for this device (see Attachment 2 for additional details).

51

TABLE 4. PART II DETAILED VALIDATION FUGITIVE TEST LISTING.

Report ID Device ID Tests Device Type Material Used

2643A 301 1 Abrasive blasting Dust2642A 319 1 Aeration basin Wastewater2654A 349 1 Asphalt production, rock pile Dust2655A 350 1 Asphalt production, rock pile Dust2644A 296 1 Asphalt production, various Rock plant mine feed2644A 297 1 Asphalt production, various Specialty mine feed2642A 321 1 DAF tank Wastewater2652A 308 1 Flanges Crude oil2638A 298 1 Flanges Field gas2646A 314 1 Flanges Field gas2663A 324 1 Fugitives, misc. Casing gas/natural gas2663A 325 1 Fugitives, misc. Casing gas/natural gas2663A 327 1 Fugitives, misc. Crude oil2663A 328 1 Fugitives, misc. Diesel2663A 329 1 Fugitives, misc. Lube oil2663A 330 1 Fugitives, misc. Lube oil2665A 340 1 Fugitives, misc. Lube oil2661A 332 1 Fugitives, misc. Sour water2646A 312 1 Gas plant Field gas2661A 331 1 Gas processing Fuel gas2656A 334 1 Gas processing Fuel gas2665A 339 1 Gas processing Fuel gas2664A 343 1 Gas processing Fuel gas2664A 348 1 Gas processing Fuel gas2666A 370 1 Gas processing Produced gas2666A 371 1 Gas processing Produced gas2666A 372 1 Gas processing Produced gas2666A 373 1 Gas processing Produced gas2642A 317 1 Headworks Wastewater2639A 307 1 Main trap Produced gas2642A 318 1 Primary sedimentation tank Wastewater2642A 320 1 Solids odor processing Sludge2638A 300 1 Internal combustion engine Diesel2662A 355 1 Internal combustion engine Lube oil/diesel2640A 293 1 Tank headspace Crude oil2640A 295 1 Tank headspace Crude oil2641A 305 1 Tank headspace Crude oil2639A 306 1 Tank headspace Crude oil2648A 313 1 Tank headspace Crude oil2646A 315 1 Tank headspace Crude oil2646A 316 1 Tank headspace Crude oil2664A 341 1 Tank headspace Crude oil2664A 344 1 Tank headspace Crude oil2664A 345 1 Tank headspace Crude oil2666A 356 1 Tank headspace Crude oil2666A 358 1 Tank headspace Crude oil2666A 360 1 Tank headspace Crude oil

52

TABLE 4. PART II DETAILED VALIDATION FUGITIVE TEST LISTING.

Report ID Device ID Tests Device Type Material Used2666A 364 1 Tank headspace Crude oil2666A 366 1 Tank headspace Crude oil2666A 368 1 Tank headspace Crude oil2666A 374 1 Tank headspace Crude oil2656A 335 1 Tank headspace Diluent2664A 346 1 Tank headspace Distillate oil2640A 292 1 Tank headspace Produced water2640A 294 1 Tank headspace Produced water2638A 299 1 Tank headspace Produced water2646A 309 1 Tank headspace Produced water2646A 310 1 Tank headspace Produced water2646A 311 1 Tank headspace Produced water2663A 326 1 Tank headspace Produced water2666A 365 1 Tank headspace Produced water2666A 367 1 Tank headspace Produced water2665A 337 1 Tank headspace Wastewater2665A 338 1 Tank headspace Wastewater2664A 342 1 Tank headspace Wastewater2664A 347 1 Tank headspace Wastewater2666A 357 1 Tank liquid Produced water2666A 359 1 Tank liquid Produced water2666A 361 1 Tank liquid Produced water2666A 363 1 Tank liquid Produced water2666A 369 1 Tank liquid Produced water2666A 375 1 Tank liquid Produced water2661A 333 1 Truck loading Sulfur2643A 302 1 Turbine Jp-42643A 303 1 Turbine Jp-52643A 304 1 Turbine/RICE Diesel2662A 351 1 Wastewater treatment Wastewater2662A 352 1 Wastewater treatment Wastewater2662A 353 1 Wastewater treatment Wastewater2662A 354 1 Wastewater treatment Wastewater

53

TABLE 5. DETAILED VALIDATION RESULTS SUMMARY.

Detailed Validation Note Status Number of Tests FailingValidation Check

Part I Part II Project

Dioxin/PAH samples using a singletrain

Note 7 1 8

Separate front/backhalf analysisconducted for CARB 436

Reject 2 1 3

Used outdated method without CARBapproval

Reject 1 0 1

Method 421 sampling was not isokineticand stack temp < 250F

Reject 3 0 3

Naphthalene analyzed by method 410 Reject 14 0 14Nonisokinetic sampling method 429 Note 3 0 3Full set of internal standards not usedfor method 429

Note 40 20 60

All sampling done non-isokinetically Reject 1 1 1Mercury not tested by CVAAS Reject 0 1 1Did not use correct impingers for metalstrain

Reject 0 2 2

Failed swirl check Reject 0 1 1Total 71 27 97

54

TABLE 6. KEY DESIGN AND OPERATING PARAMETERS.

Asphalt Production¥ type of production process X conventional or drum mix¥ methods of recycling, if any¥ production rate¥ plant capacity¥ gas flow rate¥ existence of scavenger system¥ temperature of asphaltic cement and aggregate in pug mill¥ type of fuel¥ type of air pollution control device, if any

Cement Kilns¥ type of production process X wet or dry¥ use of preheater or precalciner¥ existence of an alkali bypass stack¥ production rate¥ plant capacity¥ type of fuel¥ type of air pollution control device, if any

Glass Manufacturing¥ type of glass being manufactured X soda-lime, lead, fused silica, etc.¥ type of grease and oil lubricant used on machinery in forming and

finishing phase¥ frequency and magnitude of glass gobs contacting machine lubricant¥ type of fuel¥ type of air pollution control device, if any

Metal Furnaces¥ type of metal being processed¥ quality of scrap (i.e. dirt, oil, and moisture laden)¥ level and type of scrap preparation and treatment X solvent degreasing,

heat, etc.¥ process used to charge and melt metal X batch or continuous¥ type of furnace X electric arc, induction, reverberatory, etc.¥ whether furnace is open or closed system¥ if open, number of process phases I which the furnace doors and lids are

open X charging, backcharging, alloying, tapping, etc.¥ type of cover fluxes and demagging agents used¥ type of fuel¥ type of air pollution control device, if any

55

Polystyrene Manufacturing¥ type of polystyrene being manufactured X high-impact or expandable¥ grade of polystyrene being produced (i.e., lower molecular weights)¥ type of production process X batch¥ the polymerization technique X bulk, solution, suspension, or emulsion¥ operating characteristics of the vacuum devolatilizer condenser¥ type of vacuum system used to collect condensate X steam ejectors or

vacuum pumps• condenser coolant operating temperature• type of air pollution control device, if any

Chrome Plating Operations• type of cleaning process utilizing prior to electroplating X wire brushing,

electrocleaning, or pickling• type of solvents used during cleaning of work piece• purpose of electroplating X decorative, hard-plating or anodizing• efficiency of electroplating process (i.e. % of current used for actual

electroplating as opposed to electrolysis)• type of air pollution control device, if any

Surface Coating Operations• type of coating operation X toll or captive• coating application procedures X conventional spray, airless spray, roller,

dip, etc.• coating formulations (i.e., solvent-based, waterborne, powder)• amount of volatile matter in the coating• type of add-on emission controls, if any

External Combustion• type of unit – boiler, process heater, fluidized bed, steam generator• configuration of unit – direct fire, tangential, turbo, wall fired, spreader,

pulverized, circulating• type of fuel• capacity and load – MMBtu/hr, Mwe• manufacturer• burner type – low NOx, conventional• air preheat• NOx control – flue gas recirculation, staged combustion, water injection,

steam injection• operating parameters – combustion temperature, residence time, oxygen• type of add-on emission controls, if any

Internal Combustion Engines• manufacturer• type of fuel• capacity and lead – bhp

56

• ignition – spark ignition or compression ignition• injection – direct injection or indirect injection• rich or lean operation• strokes – 2 or 4• compression ratio• NOx control – exhaust gas recirculation, turbo charge, water injection,

charge cooling, ignition retard, injection retard, steam injection• engine speed, rpm• type of add-on emission controls, if any

Turbines• manufacturer• type of fuel• capacity and lead – Mwe• NOx control – exhaust gas recirculation, water injection, steam injection• compression ratio• engine speed, rpm• type of add-on emission controls, if any

Fugitives• component type – tank, valves, flanges, pump seals, compressor seals,

open-ended lines, safety relief devices, drains, rock pile, etc.• tank type , if applicable – open top, fixed-roof, external floating-roof,

internal floating roof• material type – light liquid, heavy liquid, gas-vapor, hydrogen, diesel,

crude oil, gasoline, aggregate, etc.

57

TABLE 7. ASSIGNED SOURCE CLASSIFICATION CODES AND EMISSION FACTOR UNITS.

SCC Description 1 Description 2 Description 3 Description 4 Unit10100217 External Combustion

BoilerElectric Generation Bituminous coal Atm fluid bed combustion lb/Tons burned

10100222 External CombustionBoiler

Electric Generation Subbituminus coal Pulverized coal dry bottom lb/Tons burned

10100401 External CombustionBoiler

Electric Generation Residual oil No 6 Oil Normal Firing lb/1000 gallons burned

10100501 External CombustionBoiler

Electric Generation Distillate Oil No 1 and No 2 oil lb/1000 gallons burned

10100601 External CombustionBoiler

Electric Generation Natural gas >100 MMBtu/hr lb/Million cubic feet burned

10100801 External CombustionBoiler

Electric Generation Coke All boiler sizes lb/Tons burned

10100903 External CombustionBoiler

Electric Generation Wood/bark waste Wood boiler lb/Tons burned

10200401 External CombustionBoiler

Industrial Residual oil No 6 Oil lb/1000 gallons burned

10200402 External CombustionBoiler

Industrial Residual oil 10-100 MMBtu/hr lb/1000 gallons burned

10200403 External CombustionBoiler

Industrial Residual oil < 10 MMBtu/hr lb/1000 gallons burned

10200501 External CombustionBoiler

Industrial Distillate Oil No 1 and No 2 oil lb/1000 gallons burned

10200701 External CombustionBoiler

Industrial Process gas Petroleum refinery lb/Million cubic feet burned

10200802 External CombustionBoiler

Industrial Coke All boiler sizes lb/Tons burned

10300501 External CombustionBoiler

Commercial/Institutional Distillate Oil No 1 and No 2 oil lb/1000 gallons burned

10300811 External CombustionBoiler

Commercial/Institutional Landfill gas Boiler lb/Million cubic feet burned

20100101 Internal CombustionEngine

Electric Generation Dist.Oil/Diesel Turbine lb/1000 gallons burned

20100102 Internal CombustionEngine

Electric Generation Dist.Oil/Diesel Reciprocating lb/1000 gallons burned

20100201 Internal CombustionEngine

Electric Generation Natural gas Turbine lb/Million cubic feet burned

58

TABLE 7. ASSIGNED SOURCE CLASSIFICATION CODES AND EMISSION FACTOR UNITS.

SCC Description 1 Description 2 Description 3 Description 4 Unit20100202 Internal Combustion

EngineElectric Generation Natural gas Reciprocating lb/Million cubic feet burned

20100301 Internal CombustionEngine

Electric Generation Diesel Reciprocating lb/1000 gallons burned

20100801 Internal CombustionEngine

Electric Generation Landfill gas Turbine lb/Million cubic feet burned

20100802 Internal CombustionEngine

Electric Generation Landfill gas Reciprocating lb/Million cubic feet burned

20200102 Internal CombustionEngine

Industrial Dist.Oil/Diesel Reciprocating lb/1000 gallons burned

20200103 Internal CombustionEngine

Industrial Dist.Oil/Diesel Turbine-cogeneration lb/1000 gallons burned

20200201 Internal CombustionEngine

Industrial Natural gas Turbine lb/Million cubic feet burned

20200202 Internal CombustionEngine

Industrial Natural gas Reciprocating lb/Million cubic feet burned

20200203 Internal CombustionEngine

Industrial Natural gas Turbine-cogenertn lb/Million cubic feet burned

20200252 Internal CombustionEngine

Industrial Natural gas 2-cycle lean burn lb/Million cubic feet burned

20200254 Internal CombustionEngine

Industrial Natural gas 4-cycle lean burn lb/Million cubic feet burned

20200701 Internal CombustionEngine

Industrial Process gas Turbine lb/Million cubic feet burned

20200705 Internal CombustionEngine

Industrial Refinery gas Turbine lb/Million cubic feet burned

20201013 Internal CombustionEngine

Industrial Liq petroleum gas LPG:turbine:cogeneration lb/1000 gallons burned

20300101 Internal CombustionEngine

Commercial/Institutional Dist.Oil/Diesel Reciprocating lb/1000 gallons burned

30101817 Chemical Manufacturing Plastics Production Polystyrene General lb/Tons product30101818 Chemical Manufacturing Plastics Production Polystyrene Reactor lb/Tons product30102431 Chemical Manufacturing Plastics Production Synthetic organic fiber Heat treat furnace:carbonization lb/Tons of material30200201 Food/Agriculture Coffee Roasting Roaster Direct fired lb/Tons green beans30300926 Primary Metals Iron and Steel Misc processes Electric Induction furnace lb/Tons produced

59

TABLE 7. ASSIGNED SOURCE CLASSIFICATION CODES AND EMISSION FACTOR UNITS.

SCC Description 1 Description 2 Description 3 Description 4 Unit30400101 Secondary Metals Secondary Aluminum Sweating furnace lb/Tons produced30400103 Secondary Metals Secondary Aluminum Smelting furnace Reverberatory lb/Tons metal produced30400107 Secondary Metals Secondary Aluminum Hot dross process lb/Tons metal produced30400108 Secondary Metals Secondary Aluminum Crushing/screenng lb/Tons metal produced30400199 Secondary Metals Secondary Aluminum Not classified Other lb/Tons produced30400224 Secondary Metals Secondary Copper Electric induction furnace Brass/bronze charge lb/Tons of charge30400401 Secondary Metals Secondary Lead Kettle refining Pot furnace lb/Tons metal charged30400408 Secondary Metals Secondary Lead Barton process Oxidation kettle lb/Tons lead oxide produced30400505 Electrical Equipment Lead Battery Manufacturing Entire process Total lb/1000 batteries produced30400522 Electrical Equipment Lead Battery Manufacturing Grid casting lb/Tons processed30500205 Petroleum Industry Asphalt Concrete Drum dryer Hot asphalt plant lb/Tons of asphalt30500211 Petroleum Industry Asphalt Concrete Rotary dryer conventional Plant w/cyclone lb/Tons produced30500214 Petroleum Industry Asphalt Concrete Truck load-out lb/Tons loaded30500606 Mineral Products Cement Manufacturing Dry process Kilns lb/Tons cement produced30501402 Mineral Products Glass Manufacturing Container glass Melting furnace lb/Ton of glass produced30501403 Mineral Products Glass Manufacturing Flat glass Melting furnace lb/Ton of glass produced30501622 Mineral Products Lime Manufacturing Calcining Coal rotary preheat kiln lb/Lb/ton of lime manfactrd30502201 Mining Operations Nonmetallic Mineral Potash production Mine-grind/dry lb/Tons ore30502508 Mining Operations Nonmetallic Mineral Sand/gravel Dryer lb/Tons product produced30503605 Mineral Products Nonmetallic Mineral Bonded abrasives manufacturing Firing or curing lb/Tons processed30505001 Mineral Products Nonmetallic Mineral Asphalt processing Blowing lb/Tons asphalt processed30600105 Petroleum Industry Petroleum Refining Process heaters Natural gas-fired lb/Million cubic feet burned30600106 Petroleum Industry Petroleum Refining Process heaters Process gas-fired lb/Million cubic feet burned30600201 Petroleum Industry Petroleum Refining Catalytic crackng Fluid catalytic cracker lb/1000 barrels fresh feed30601101 Petroleum Industry Petroleum Refining Asphalt blowing General lb/Tons of asphalt produced30601401 Petroleum Industry Petroleum Refining Petroleum coke Calciner lb/Tons raw coke processed30601601 Petroleum Industry Petroleum Refining Catalytic reforming General lb/1000 bbls crude feed30609904 Petroleum Industry Petroleum Refining Incinerators Process gas lb/Million cubic feet burned30700402 Pulp and Paper Pulpboard Fiberboard General lb/Tons finished product30901006 Fabricated Metals Electroplating Entire process Chrome mg/amp-hr30902501 Fabricated Metals Drums/Barrels Drum cleaning Drum burning lb/Drums burned30904010 Fabricated Metals Metal Deposition Thermal spray of Powdered metal lb/Tons sprayed metal

consum

60

TABLE 7. ASSIGNED SOURCE CLASSIFICATION CODES AND EMISSION FACTOR UNITS.

SCC Description 1 Description 2 Description 3 Description 4 Unit30904020 Fabricated Metals Metal Deposition Plasma arc spray Of powdered metal lb/Tons sprayed metal

consum31000301 Oil and Gas Production Natural Gas Production Glycol dehydrator Reboiler still vent lb/Million cubic feet burned31000304 Oil and Gas Production Natural Gas Production Glycol dehydrator Ethyl glycol:General lb/Million cubic feet burned31000403 Oil and Gas Production Fuel-Fired Equipment Process heaters Crude oil lb/1000 gallons burned31000404 Oil and Gas Production Fuel-Fired Equipment Process heaters Natural gas lb/Million cubic feet burned31000413 Oil and Gas Production Fuel-Fired Equipment Steam generators Crude oil lb/1000 gallons burned31000414 Oil and Gas Production Fuel-Fired Equipment Steam generators Natural gas lb/Million cubic feet burned31000415 Oil and Gas Production Fuel-Fired Equipment Steam generators Process gas lb/Million cubic feet burned31307001 Electrical Equipment Windings Reclaimation Incinerator oven Single chamber lb/Tons charged31502101 Miscellaneous Industries Health Care Crematory stack lb/Bodies40200110 Organic Solvent Surface Coating Paint-general Solvent-base coating lb/Gallons coating40200210 Organic Solvent Surface Coating Paint-general Water-base coating lb/Gallons coating40200610 Organic Solvent Surface Coating Primer General lb/Gallons coating50100506 Solid Waste Disposal Government Other incinerator Sludge lb/Tons dry sludge50200504 Solid Waste Disposal Commercial/Institutional Medical waste incinerator lb/Tons burned50300205 Solid Waste Disposal Industrial Open burning Rocket propellant lb/Tons of fuel50300601 Solid Waste Disposal Industrial Landfill dump Waste gas flare lb/Million cubic feet burned

61

TABLE 8. LISTING OF SECONDARY AND PRIMARY VALIDATION CHECKS FOR TEST METHODS APPLICABLE TO PROJECT (a).

CHECK 11 12 15 101A 104 106 410 421 421 422 422 423 424 425 425 428 428 429 430 430 433 EPA EPA 43683 86 83 86 86 83 86 87 91 87 91 87 87 87 90 88 90 89 89 91 89 Meta

ls306 91,92

SAMPLE LOCATIONSwirl Check S S S S S S S S S S S S S S S SStack Size S S S S S S S S S S S S S S S SNumber of Sample Points S S S S S S S S S S S S S S S S

SAMPLING EQUIPMENTNozzle Size Check S S S S S S S S S S S S S S S SField Gas Dry Meter Calibration S S S S S S S S S S S S S S S S S SPitot Tube Semi-Annual Calibration S S S S S S S S S S S S S S S STedlar Bag Contamination Check P P P

SAMPLING PROCEDURESNumber of Sample Runs S S S S S S SLength of Sample Time S S S SLeak Check S S S S S S S S S S S S S S S S S S S S S S SSample Line Loss SIsokinetic Variation S S S S S S S S S S S S S S S SField Reagent Blank P P P P P P P P P P P P PField Blank P P P P P P P PField Spike PSurrogate Recovery P P PProbe Proof PFilter Temperature S SFlow Rate Level S S S S SSample Date PCorrect Impinger Solutions S S S S S S S

ANALYSISCorrect Method Used S S S S S S S S S S S S S S S SExtraction Date P P PAnalysis Date P P P P P P P P P3-Point Calibration SMatrix Spike Recovery P P P P P P PLab Spike Recovery P PLab Control Spike Recovery P P PInternal Standard Recovery P P PDuplicate Percent Difference P P P P P P P PSeparate Impinger Analysis S

PRIMARY PARAMETER SUMMARYSufficient Documentation 1 1 0 1 1 1 2 2 2 2 3 1 1 2 3 3 3 4 3 3 1 2 3 3Total 1 1 0 1 1 1 2 3 3 2 5 1 1 3 4 4 4 6 4 5 1 3 4 5

P - Primary validation parameter.S - Secondary validation parameter.Blank - Check not applicable for method.(a) - Table described in Section 6.3 Background

62

TABLE 9. METHOD RATING SUMMARY.

Sample Method Version Substance Number of Tests at Method RatingA B C D E F G

CARB 101A 86 Mercury 6 - - 2CARB 104 86 Beryllium 1 - 3 - 7CARB 106 83 Vinyl Chloride 7 - -CARB 11 83 Hydrogen Sulfide 7 - 44 -CARB 12 86 Lead 4 - 4 - 1 5CARB 15 83 Hydrogen Sulfide 22 - -CARB 410A 86 BTX 76 - 70 - 3CARB 410B 86 BTX 24 - 17 -CARB 421 87 HCl 3 - 21 - 1 1

91 HCl 5 - 6 -CARB 422 87 VOC 15 - 6 -

91 VOC 8 - 5 -CARB 423 87 Arsenic 6 - 1 - 1 8CARB 424 87 Cadmium 1 - 1 - 7CARB 425 87 Chromium (Hex) 12 - 12 - 1

90 Chromium (Hex) 26 - 66 - 16CARB 426 87 Cyanide - - 4CARB 428 88 Dioxin & Furan 4 - 4 - 1

90 Dioxin & Furan 17 - 4 - 1 2CARB 429 89 PAH 74 - 70 - 3 6CARB 430 89 Aldehydes 78 - 65 - 4 1

91 Aldehydes 32 - 21 -CARB 433 89 Nickel 1 - 2 - 13CARB 436 92 Trace Metals 15 - 18 - 1 12EPA MMT 89 Trace Metals - 9 - 53 3 2 10BAAQMD ST1B 82 Ammonia - 9 - 1SCAQMD 207.1 90 Ammonia - 11 -EPA 306 90 Chromium (Hex) - 15 -EPA 420.1 Phenol - a - a 1EPA M5 Chloride and Fluoride - a - a 2 1EPA 30 86 BTX - a - a 16NIOSH 1612 Propylene Oxide - a - a 1SCAQMD 205.1 Chromium (Hex) - a - a 4SCAQMD 25.1 Ethylbenzene & Styrene - a - a 1SCAQMD 5.2 Particulate - a - a 1

- Does not applya - no validation conducted

63

TABLE 10. MAJOR GROUP AND SUB GROUP EVALUATION PARAMETERS.

Major Group Sub Group Parameters Evaluated TestsPart I Part II Total

Section 1Part II Sub group Analysis Ð New and Updated Major Groups*

Asphalt Prod., Oil APC System, Contractor 2 2 4Boiler, Fuel Oil SCC 12 2 14Boiler, Ref. Gas APC System, Excess Air, Burner Type 7 7Catalytic Reformer APC System 2 2Coating, Base/Catalyst/Water Mix APC System, Paint Cr Content 4 4Coating, Powder APC System, Powder Cr Content, SCC 7 1 8Dryer, Pot ash APC System, Material 2 2Dryer, Sand/Gravel APC System, Fuel Type 2 2FBC, Biomass APC System, Fuel Type 2 2 4Furnace, Lead SCC 4 4Heater, Ref. Gas APC System, Excess Air, Burner Type 25 25RICE, Diesel SCC, Capacity, Oxygen 8 2 10RICE, Natural Gas APC System, Strokes per Cycle, Capacity, Oxygen 22 3 25Incinerator, Medical Waste APC System, Waste Type 6 6Plating, Anodizing APC System 3 3 6Plating, Decorative APC System 2 2Plating, Hard APC System 8 33 41Plating, Hard/Anodizing APC System 3 3Steam Generator, Natural/CVR Gas APC System, Excess Air, Burner Type 2 3 5Shredding and Delaquering, Aluminum APC System 2 2Turbine, Natural Gas APC System, SCC, Duct Burners 9 7 16

Section 2Part I Sub group Analysis Ð No Additional Data Collected or Evaluated**

Asphalt Prod., Diesel APC System, SCC 4 4Asphalt Prod., Natural Gas APC System, SCC 5 5Boiler, Distillate SCC 7 7Coating, Green PE APC System, Spray Method 5 5Coating, Green Primer APC System, Spray Method 8 8FBC, Coal APC System 6 6Furnace, Aluminum APC System, Furnace Type 7 7Furnace, Glass APC System, SCC 4 4RICE, Field Gas Strokes per Cycle, Capacity, Oxygen 6 6Steam Generator, Crude Oil APC System, Load, Burner Type 3 3Turbine, Distillate SCC 5 5

Section 3No Sub group Analysis - No Difference in Design/Operation

Boiler, Natural Gas None 3 3Cement Kiln, Coal None 2 2Crematory None 2 2FBC, Coke None 2 2Heater, Natural Gas None 1 1 2ICE, Landfill Gas None 2 2PM, Reactor None 2 2PM, Storage Silo None 3 3

64

TABLE 10. MAJOR GROUP AND SUB GROUP EVALUATION PARAMETERS.

Major Group Sub Group Parameters Evaluated TestsPart I Part II Total

SG, Natural Gas None 1 1 2Turbine, Natural/Ref. Gas None 5 5

Section 4No Sub group Analysis - No Difference in Samples

Abrasive Blasting, Dust None 2 2Asphalt Prod., Dust None 4 4Composition, Crude oil None 2 2Composition, Diesel None 4 4Composition, Lube Oil None 3 3Composition, Produced water None 7 7Composition, Wastewater None 4 4Flanges, Field gas None 2 2Flare, Landfill gas None 4 4Fugitives, Casing/Natural Gas None 2 2Gas Processing, Fuel Gas None 5 5Gas Processing, Produced Gas None 4 4Tank, Crude oil None 18 18Tank, Produced water None 8 8Tank, Wastewater None 4 4

Section 5No Sub group Analysis - Single Test

Aeration Basin, Wastewater None 1 1Asphalt Prod., Blowing None 1 1Asphalt Prod., Truck Load None 1 1Battery Prod., Grids None 1 1Battery Prod., Post Pour None 1 1Battery Prod., Strap Line None 1 1Boiler, Coal/Natural Gas None 1 1Boiler, Coke/Coal None 1 1Boiler, Landfill Gas None 1 1Boiler, Wood None 1 1Cement Kiln, Coal/Coke None 1 1Coating, Base/Catalyst/Solvent Mix None 1 1Coating, Yellow PE None 1 1Coke Calcining None 1 1Composition, Jp-4 None 1 1Composition, Jp-5 None 1 1Composition, Lube oil/Diesel None 1 1Composition, Sour Water None 1 1DAF Tank, Wastewater None 1 1Dehydrator, Sludge None 1 1Delaquering, Aluminum None 1 1Drum Burning Furnace None 1 1Dryer, Fiberboard None 1 1FCCU, Refinery gas None 1 1Flanges, Crude oil None 1 1Fugitive, Sulfur None 1 1

65

TABLE 10. MAJOR GROUP AND SUB GROUP EVALUATION PARAMETERS.

Major Group Sub Group Parameters Evaluated TestsPart I Part II Total

Furnace, Alloy Stock None 1 1Furnace, Brass/Bronze None 1 1Furnace, Carbonization None 1 1Gas Processing, Field gas None 1 1Headworks, Wastewater None 1 1Heater, Natural/Ref. Gas None 1 1Heater, Oil None 1 1Incinerator, Waste explosives None 1 1Incinerator, Waste Gas None 1 1Main Trap, Produced Gas None 1 1Oven, Curing Tools None 1 1Oven, Wire Coatings None 1 1PM, Devolatizer None 1 1PM, Extruder None 1 1PM, Mix Tank None 1 1Preheater Kiln, Coal None 1 1Presser, Fiberboard None 1 1PST, Wastewater None 1 1Reboiler, Ethylene Glycol None 1 1Reboiler, Triethylene Glycol None 1 1Roaster, Green beans None 1 1Solids odor processing, Sludge None 1 1Tank, Diluent None 1 1Tank, Distillate oil None 1 1Turbine, Field Gas None 1 1Turbine, Landfill Gas None 1 1Turbine, Natural/Ref. Gas/Butane None 1 1Turbine, Natural/Ref./LP Gas None 1 1Turbine, Ref. Gas None 1 1Unloader, Fiberboard None 1 1

Section 6No Sub group Analysis - Process Rate Not Available in Correct Unit

Asphalt Blowing None 2 2

*See Section 6.8 for sub group analysis**See Section 6.8 of Part I report for sub group analysis

66

TABLE 11. LISTING OF OUTLIERS REMOVED FROM EMISSION FACTOR DEVELOPMENT.

Major Group DeviceID

Run ID Category Substance Statistical OutlierEvaluation

Report ReviewResults

Comment

MajorGroup

Test Calculation

Process

Method

Asphalt Prod., Diesel 105 105C1R8 Metals Cadmium y x x r 8Asphalt Prod., Diesel 105 105C1R8 Metals Copper y x x r 8Asphalt Prod., Diesel 105 105C1R9 Metals Cadmium y x x r 8Asphalt Prod., Natural Gas 103 103C1S1 PAH Benzo(a)anthracene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Benzo(a)pyrene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Benzo(b)fluoranthene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Benzo(g,h,i)perylene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Benzo(k)fluoranthene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Chrysene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Dibenz(a,h)anthracene y x x r 2Asphalt Prod., Natural Gas 103 103C1S1 PAH Indeno(1,2,3-cd)pyrene y x x r 2Asphalt Prod., Oil 158 158C1R3 Metals Arsenic y x r x 9Asphalt Prod., Oil 158 158C1R3 Metals Lead y x r x 9Asphalt Prod., Oil 158 158C1R6 Metals Zinc y x r x 9Asphalt Prod., Oil 215 215C1R2 Metals Zinc y y c x x cBoiler, Distillate 161 161C1R3 SVOC 2-Chloronaphthalene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Acenaphthene y x x r 5Boiler, Distillate 161 161C1R3 PAH Acenaphthylene y x x r 5Boiler, Distillate 161 161C1R3 PAH Anthracene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Benzo(a)pyrene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Benzo(b)fluoranthene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Benzo(e)pyrene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Benzo(g,h,i)perylene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Benzo(k)fluoranthene y x x r 5Boiler, Distillate 161 161C1R3 PAH Dibenz(a,h)anthracene y y x x r 5Boiler, Distillate 161 161C1R3 PAH Fluorene y x x r 5Boiler, Distillate 161 161C1R3 PAH Indeno(1,2,3-cd)pyrene y y x x r 5Boiler, Distillate 161 161C1R3 SVOC Perylene y y x x r 5Boiler, Distillate 181 181C1R3 PAH Acenaphthene y x r x 6Boiler, Distillate 181 181C1R3 PAH Acenaphthylene y x r x 6,10Boiler, Distillate 181 181C1R3 PAH Benzo(a)anthracene y y x r x 6Boiler, Distillate 181 181C1R3 PAH Chrysene y x r x 6Boiler, Distillate 181 181C1R3 PAH Fluoranthene y x r x 6,10Boiler, Distillate 181 181C1R3 PAH Fluorene y y x r x 6Boiler, Distillate 181 181C1R3 PAH Naphthalene y x r x 6Boiler, Distillate 181 181C1R3 PAH Phenanthrene y y x r x 6Boiler, Distillate 181 181C1R3 PAH Pyrene y x r x 6,10Boiler, Fuel Oil 102 102C1R2 PAH Acenaphthene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Acenaphthylene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Anthracene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Benzo(a)anthracene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Benzo(a)pyrene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Benzo(b)fluoranthene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Benzo(g,h,i)perylene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Benzo(k)fluoranthene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Chrysene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Dibenz(a,h)anthracene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Fluoranthene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Fluorene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Indeno(1,2,3-cd)pyrene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Phenanthrene y y x x r 1Boiler, Fuel Oil 102 102C1R2 PAH Pyrene y y x x r 1

67

TABLE 11. LISTING OF OUTLIERS REMOVED FROM EMISSION FACTOR DEVELOPMENT.

Major Group DeviceID

Run ID Category Substance Statistical OutlierEvaluation

Report ReviewResults

Comment

MajorGroup

Test Calculation

Process

Method

Boiler, Ref. Gas 646 646C1R3 Metals Beryllium y y x r x 17Boiler, Ref. Gas 646 646C1R3 Metals Copper y y x r x 17Boiler, Ref. Gas 646 646C1R3 Metals Lead y y x r x 17Boiler, Ref. Gas 646 646C1R3 Metals Manganese y x r x 17Boiler, Ref. Gas 646 646C1R3 Metals Nickel y y x r x 17Dryer, Pot ash 251 251C1R3 VOC Trichloroethene y c x x cFBC, Coal 431 431C1R1 Dioxin/Furan Dioxin:5D 12378 y x x r 11FBC, Coal 431 431C1R1 Dioxin/Furan Dioxin:6D 123678 y x x r 11FBC, Coal 431 431C1R2 Dioxin/Furan Dioxin:4D 2378 y x x r 11FBC, Coal 431 431C1R2 Dioxin/Furan Dioxin:5D 12378 y x x r 11FBC, Coal 431 431C1R2 Dioxin/Furan Dioxin:6D 123678 y x x r 11FBC, Coal 431 431C1R2 Dioxin/Furan Dioxin:7D 1234678 y x x r 11FCCU, Refinery gas 260 260C1R2 PAH Fluorene y y c x x cFurnace, Lead 219 219C1R3 Metals Antimony y c x x cHeater, Ref. Gas 225 225C1R2 PAH Acenaphthylene y x x r 21Heater, Ref. Gas 264 264C1R2 PAH Fluorene y c x x cHeater, Ref. Gas 266 266C1R3 VOC Benzene y c x x cHeater, Ref. Gas 445 445C3R2 PAH Acenaphthene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Acenaphthylene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Anthracene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Benzo(a)anthracene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Benzo(a)pyrene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Benzo(b)fluoranthene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Benzo(g,h,i)perylene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Benzo(k)fluoranthene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Chrysene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Dibenz(a,h)anthracene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Fluoranthene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Fluorene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Indeno(1,2,3-cd)pyrene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Naphthalene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Phenanthrene y x x r 12Heater, Ref. Gas 445 445C3R2 PAH Pyrene y x x r 12ICE, Landfill Gas 133 133C1R2 PAH Anthracene y c x x cIncinerator, Medical Waste 226 226C1R2 Dioxin/Furan Furan:5F 23478 y x ? x 20Oven, Wire Coatings 238 238C1R3 PAH Fluorene y y c x x cOven, Wire Coatings 238 238C1R3 VOC Formaldehyde y y c x x cPlating, Anodizing 421 421C1R4 Metals Chromium (Total) y x ? x 23Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:4D 2378 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:5D 12378 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:6D 123478 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:6D 123678 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:6D 123789 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:6D Total y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Dioxin:8D y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:5F 12378 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:5F 23478 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:6F 123478 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:6F 123678 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:6F 123789 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:6F 234678 y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:6F Total y y x x r 25Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:7F 1234789 y y x x r 25

68

TABLE 11. LISTING OF OUTLIERS REMOVED FROM EMISSION FACTOR DEVELOPMENT.

Major Group DeviceID

Run ID Category Substance Statistical OutlierEvaluation

Report ReviewResults

Comment

MajorGroup

Test Calculation

Process

Method

Shredding and Delaquering, Aluminum 236 236C1R1 Dioxin/Furan Furan:8F y y x x r 25Turbine, Natural Gas 141 141C1R1 VOC Formaldehyde y x x r 3Turbine, Natural/Ref. Gas 263 263C1R1 Metals Manganese y y x x ? 22

y - outlier as identified by statistical analysisr - rejected from emission factor developmentx - passed checkc - data corrected1 Ð Due to matrix interference the detection limit for Run 2 from the samples taken when the unit was fired on oil was high.2 Ð Higher detection limits for tests 11 and 12 resulted from analytical interferenceÕs associated with the sample matrices.3 Ð First run contaminated during extended leak check.5 - Do to matrix interference the detection limit for Run 3 was two orders of magnitude higher than Runs 1 and 2.6 Ð Incomplete combustion during boiler shutdown and startup may be the cause for the relatively high PAH results for Run 3.8 Ð Blank quantities greater than sample quantities.9 Ð Constant clogging of pitot tube lines and filters, interruptions of plant operations, power failures encountered during sampling.10 Ð Boiler shutdown and startup may be cause of relatively high PAH results for Run 3.11 Ð Low recoveries of internal standard due to sample matrix.12 Ð Samples appear to be contaminated. Sample extraction produced a sticky organic material that was unlike other sample extracts.17 Ð Process unit upset during MMT run 3.20 Ð Flow disturbance and low afterburner temperature.21 Ð Low flow rates resulted in higher DL.22 Ð Residual manganese contamination in impingers.23 Ð Results of all four tests indicated that scrubber was not performing properly.25 Ð Break in sample train during the test.

69

TABLE 12. POINT SOURCE EMISSION FACTOR GROUPS*.

Major Group SubGroup

Fuel/Material SCC APC System Other

Asphalt Prod., Blowing 1 Natural gas/Flux 30505001 FI NoneAsphalt Prod., Diesel 1 Diesel/Aggregate 30500211 C/FF NoneAsphalt Prod., Diesel 2 Diesel/Aggregate 30500205 FF NoneAsphalt Prod., Diesel 3 Diesel/Aggregate 30500205 WS NoneAsphalt Prod., Natural Gas 1 Natural gas/Aggregate 30500211 C/FF NoneAsphalt Prod., Natural Gas 1 Natural gas/Aggregate 30500211 C/WS NoneAsphalt Prod., Oil 1 Back-up oil/Aggregate 30500211 C/BH NoneAsphalt Prod., Oil 1 Process oil 70/Aggregate 30500211 C/WS NoneAsphalt Prod., Truck Load 1 Asphalt 30500214 FF NoneBattery Prod., Grids 1 Grids 30400522 NONE NoneBattery Prod., Post Pour 1 Batteries 30400505 NONE NoneBattery Prod., Strap Line 1 Batteries 30400505 NONE NoneBoiler, Coal/Natural Gas 1 Coal/Natural gas 10100222 NONE NoneBoiler, Coke/Coal 1 Coke/Coal 10200802 LI/AI/B NoneBoiler, Distillate 1 Diesel 10200501 NONE NoneBoiler, Distillate 1 Diesel 10300501 NONE NoneBoiler, Fuel Oil 1 No. 6 Fuel oil 10100401 NONE NoneBoiler, Fuel Oil 2 No. 6 Fuel oil 10200401 NONE NoneBoiler, Fuel Oil 2 No. 6 Fuel oil 10200402 NONE NoneBoiler, Fuel Oil 2 No. 6 Fuel oil 10200403 NONE NoneBoiler, Fuel Oil 2 Residual fuel 10200401 NONE NoneBoiler, Landfill Gas 1 Landfill gas 10300811 NONE NoneBoiler, Natural Gas 1 Natural gas 10100601 NONE NoneBoiler, Ref. Gas 1 Refinery gas 10200701 NONE EA<100%Boiler, Ref. Gas 1 Refinery gas 10200701 SCR EA<100%Boiler, Ref. Gas 2 Refinery gas 10200701 NONE EA>100%Boiler, Wood 1 Wood 10100903 ESP/MC NoneCatalytic Reformer 1 Naphtas 30601601 NONE NoneCatalytic Reformer 2 Naphtas 30601601 AC NoneCement Kiln, Coal 1 Coal/Raw Materials 30500606 FF NoneCement Kiln, Coal/Coke 1 Coal/Coke/Raw Materials 30500606 FF NoneCoating, Base/Catalyst/ SolventMix

1 Solvent reducible paint 40200110 FF HVLP Spray Gun

Coating, Base/Catalyst/ WaterMix

1 5.25% Cr 40200210 AF ?

Coating, Base/Catalyst/ WaterMix

1 5.25% Cr 40200210 AF HVLP Spray Gun

Coating, Base/Catalyst/ WaterMix

2 26% Cr 40200210 AF HVLP Spray Gun

Coating, Base/Catalyst/ WaterMix

3 26% Cr 40200210 S ?

Coating, Green PE 1 15% Cr 40200110 BF HVLP Spray GunCoating, Green PE 2 15% Cr 40200110 PA HVLP Spray GunCoating, Green PE 3 15% Cr 40200110 WC HVLP Spray GunCoating, Green PE 4 15% Cr 40200110 WT HVLP Spray GunCoating, Green Primer 1 25-35% Chromate 40200610 BF HVLP Spray GunCoating, Green Primer 2 25-35% Chromate 40200610 PA HVLP Spray GunCoating, Green Primer 3 25-35% Chromate 40200610 WC ConventionalCoating, Green Primer 4 25-35% Chromate 40200610 WC HVLP Spray GunCoating, Green Primer 5 25-35% Chromate 40200610 WSN ConventionalCoating, Green Primer 6 25-35% Chromate 40200610 WT HVLP Spray GunCoating, Powder 1 75% Cr3C2, 20% NiCr, 5% Cr 30904020 NONE ConventionalCoating, Powder 2 87% Al2O3, 13% TiO2 30904020 NONE ConventionalCoating, Powder 3 70% Ni, 4% Cr 30904020 AF ConventionalCoating, Powder 4 49% Ni, 44% Cr 30904020 AF ConventionalCoating, Powder 5 4% Ni, 96% Al 30904020 AF Conventional

70

TABLE 12. POINT SOURCE EMISSION FACTOR GROUPS*.

Major Group SubGroup

Fuel/Material SCC APC System Other

Coating, Powder 6 80% Ni, 20%Cr 30904020 NONE ConventionalCoating, Powder 7 100% Chromium Oxide 30904020 NONE ConventionalCoating, Powder 8 8.5% Cr 30904010 NONE ?Coating, Yellow PE 1 30% Lead Chromate 40200110 BF ConventionalCoke Calcining 1 Natural gas/Coke 30601401 SD/FF NoneCrematory 1 Propane/Bodies 31502101 NONE NoneDehydrator, Sludge 1 Natural gas/Sludge 50100506 C NoneDelaquering, Aluminum 1 Aluminum 30400101 NONE NoneDrum Burning Furnace 1 Drums 30902501 AB NoneDryer, Fiberboard 1 Fiberboard 30700402 C/BH NoneDryer, Pot ash 1 Pot ash 30502201 S NoneDryer, Pot ash 2 Sulfate of potash 30502201 BH NoneDryer, Sand/Gravel 1 Natural gas/Blue shale/ Total

petroleum hydrocarbon30502508 CS None

Dryer, Sand/Gravel 2 Diesel/Specialty sand 30502508 BH NoneFBC, Biomass 1 Saw mill wood waste 10100903 AI/C/ESP NoneFBC, Biomass 2 Agricultural waste 10100903 AI/C/FF NoneFBC, Biomass 3 Agricultural/Urban wood waste 10100903 LI/SNCR/C/FF NoneFBC, Biomass 4 Urban wood waste 10100903 LI/SNCR/C/FF NoneFBC, Coal 1 Coal 10100217 LI/AI/C/FF NoneFBC, Coal 1 Coal 10100217 LI/AI/FF/ESP NoneFBC, Coke 1 Coke 10100801 LI/AI/C/FF NoneFCCU, Refinery gas 1 Refinery gas/Oils 30600201 ESP/COB NoneFlare, Landfill gas 1 Landfill gas 50300601 NONE NoneFurnace, Alloy Stock 1 Alloy stock 30300926 NONE Electric InductionFurnace, Aluminum 1 Aluminum 30400107 FF DrossFurnace, Aluminum 2 Aluminum 30400199 NONE Melting PotFurnace, Aluminum 3 Aluminum 30400103 FF ReverberatoryFurnace, Aluminum 4 Aluminum 30400103 NONE ReverberatoryFurnace, Brass/Bronze 1 Brass/Bronze ingot 30400224 FF Electric InductionFurnace, Carbonization 1 Precarbonized rayon 30102431 NONE NoneFurnace, Glass 1 Raw Materials 30501402 FF NoneFurnace, Glass 2 Raw Materials 30501402 NONE NoneFurnace, Glass 2 Raw Materials 30501403 NONE NoneFurnace, Lead 1 Lead 30400401 FF Melting PotFurnace, Lead 2 Lead 30400408 FF Melting PotHeater, Natural Gas 1 Natural gas 31000404 NONE NoneHeater, Natural/Ref. Gas 1 Natural gas/Refinery gas 30600105/30600106 NONE NoneHeater, Oil 1 Pipeline oil 31000403 NONE NoneHeater, Ref. Gas 1 Refinery gas 30600106 DeNOx EA<100%Heater, Ref. Gas 1 Refinery gas 30600106 NONE EA<100%Heater, Ref. Gas 1 Refinery gas 30600106 SCR EA<100%Heater, Ref. Gas 2 Refinery gas 30600106 NONE EA>100%Heater, Ref. Gas 2 Refinery gas 30600106 SCR EA>100%ICE, Diesel 1 Diesel 20200102 NONE O2<13%ICE, Diesel 2 Diesel 20300101 NONE O2<13%ICE, Diesel 3 Diesel 20100102 NONE O2>13%ICE, Diesel 4 Diesel 20200102 NONE O2>13%ICE, Diesel 5 Diesel 20100102 SCR/AI O2<13%ICE, Field Gas 1 Field gas 20200202 NONE 4S/Lean/<650HpICE, Field Gas 2 Field gas 20200252 NONE 2S/Lean/<650HpICE, Field Gas 4 Field gas 20200254 NONE 4S/Rich/<650HpICE, Field Gas 5 Field gas 20200252 NONE 2S/Lean/>650HpICE, Landfill Gas 1 Landfill gas 20100802 NONE NoneICE, Natural Gas 1 Natural gas 20200202 NONE 4S/Lean/<650HpICE, Natural Gas 2 Natural gas 20200254 NONE 4S/Rich/<650HpICE, Natural Gas 3 Natural gas 20200202 NONE 4S/Lean/>650Hp

71

TABLE 12. POINT SOURCE EMISSION FACTOR GROUPS*.

Major Group SubGroup

Fuel/Material SCC APC System Other

ICE, Natural Gas 4 Natural gas 20200252 NONE 2S/Lean/>650HpICE, Natural Gas 5 Natural gas 20100202 NSCR 4S/Rich/<650HpIncinerator, Medical Waste 1 Natural gas/Pathological waste 50200504 NONE EcolairIncinerator, Medical Waste 2 Animal bedding 50200504 NONE Therm-Tech,

PU250Incinerator, Medical Waste 3 Natural gas/Infectious waste 50200504 NONE Incinomite, 80DSIncinerator, Waste explosives 1 Diesel/Waste explosives 50300205 NONE NoneIncinerator, Waste Gas 1 Waste gas 30609904 SCR NoneOven, Curing Tools 1 Natural gas/Abrasive cutting tools 30503605 NONE NoneOven, Wire Coatings 1 Coatings of electric motor

winding wires31307001 NONE None

Plating, Anodizing 1 Chromic acid 30901006 DM NonePlating, Anodizing 1 Chromic acid 30901006 DM/PB/F101 NonePlating, Anodizing 1 Chromic acid 30901006 DM/S/PB/F101 NonePlating, Anodizing 1 Chromic acid 30901006 WS NonePlating, Anodizing 2 Chromic acid 30901006 DM/WS/HEPA NonePlating, Decorative 1 Chromic acid 30901006 PBS NonePlating, Decorative 2 Chromic acid 30901006 DM/DMNP/HEPA NonePlating, Hard 1 Chromic acid 30901006 DM NonePlating, Hard 1 Chromic acid 30901006 DM/PB NonePlating, Hard 1 Chromic acid 30901006 DM/PBS NonePlating, Hard 1 Chromic acid 30901006 DM/PBS/FB/PB NonePlating, Hard 1 Chromic acid 30901006 DM/PBS/PB NonePlating, Hard 1 Chromic acid 30901006 DM/PBS/PB/F101 NonePlating, Hard 1 Chromic acid 30901006 DM/S NonePlating, Hard 1 Chromic acid 30901006 DM/S/F140 NonePlating, Hard 1 Chromic acid 30901006 DM/S/PB/F101 NonePlating, Hard 1 Chromic acid 30901006 DM/WS/PB NonePlating, Hard 1 Chromic acid 30901006 F140 NonePlating, Hard 1 Chromic acid 30901006 FB NonePlating, Hard 1 Chromic acid 30901006 FB/PB NonePlating, Hard 1 Chromic acid 30901006 PBS NonePlating, Hard 1 Chromic acid 30901006 PBS/F101/PB NonePlating, Hard 1 Chromic acid 30901006 PBS/FB NonePlating, Hard 1 Chromic acid 30901006 S NonePlating, Hard 1 Chromic acid 30901006 S/FPT NonePlating, Hard 1 Chromic acid 30901006 WS NonePlating, Hard 2 Chromic acid 30901006 DM/HEPA NonePlating, Hard 2 Chromic acid 30901006 DM/PB/HEPA NonePlating, Hard 2 Chromic acid 30901006 DM/PBS/HEPA NonePlating, Hard 2 Chromic acid 30901006 DM/S/F101/PB/MP NonePlating, Hard 2 Chromic acid 30901006 DM/S/F140/F101/M

PNone

Plating, Hard 2 Chromic acid 30901006 DM/WS/HEPA NonePlating, Hard 2 Chromic acid 30901006 S/F NonePlating, Hard 3 Chromic acid 30901006 NONE NonePlating, Hard/Anodizing 1 Chromic acid 30901006 DM/S NonePlating, Hard/Anodizing 1 Chromic acid 30901006 S NonePM, Devolatizer 1 Styrene monomer 30101818 ESP NonePM, Extruder 1 Styrene monomer 30101818 ESP NonePM, Mix Tank 1 Styrene monomer 30101818 ESP NonePM, Reactor 1 Styrene monomer 30101818 ESP NonePM, Storage Silo 1 Styrene monomer 30101817 NONE NonePreheater Kiln, Coal 1 Coal/Raw Materials 30501622 C/FF NonePresser, Fiberboard 1 Fiberboard 30700402 NONE NoneReboiler, Ethylene Glycol 1 Ethylene glycol 31000304 NONE NoneReboiler, Triethylene Glycol 1 Triethylene glycol 31000301 NONE NoneRoaster, Green beans 1 Green beans 30200201 AB NoneSG, Crude Oil 1 Crude oil 31000413 NONE NoneSG, Crude Oil 1 Crude oil 31000413 SO2 Scrub None

72

TABLE 12. POINT SOURCE EMISSION FACTOR GROUPS*.

Major Group SubGroup

Fuel/Material SCC APC System Other

SG, Natural Gas 1 Natural gas 31000414 NONE NoneSG, Natural/CVR Gas 1 Natural gas/CVR gas 31000414/31000415 NONE NoneShredding and Delaquering,Aluminum

1 Aluminum 30400101/30400108 BH None

Shredding and Delaquering,Aluminum

2 Aluminum 30400101/30400108 VS None

Turbine, Distillate 1 Diesel 20100101 NONE NoneTurbine, Distillate 1 No. 2 Distillate oil 20100101 NONE NoneTurbine, Distillate 2 No. 2 Distillate oil 20200103 NONE NoneTurbine, Field Gas 1 Field gas 20200203 NONE NoneTurbine, Landfill Gas 1 Landfill gas 20100801 NONE NoneTurbine, Natural Gas 1 Natural gas 20100201 NONE NoneTurbine, Natural Gas 1 Natural gas 20200201 NONE NoneTurbine, Natural Gas 2 Natural gas 20200203 AI/SCR NoneTurbine, Natural Gas 2 Natural gas 20200203 COC NoneTurbine, Natural Gas 2 Natural gas 20200203 COC/SCR NoneTurbine, Natural Gas 2 Natural gas 20200203 NONE NoneTurbine, Natural Gas 2 Natural gas 20200203 SCR NoneTurbine, Natural/Ref. Gas 1 Natural gas/Refinery gas 20200203/20200705 SCR/AI/COC NoneTurbine, Natural/Ref. Gas 1 Natural gas/Refinery gas 20200203/20200705 SCR/COC NoneTurbine, Natural/Ref. Gas/Butane

1 Natural gas/Refinery gas/ Butane 20200203/20200705 SCR/COC None

Turbine, Natural/Ref./ LP Gas 1 Natural/LP/Refinery gas 20200203/20200705/20201013

SCR/COC None

Turbine, Ref. Gas 1 Refinery gas 20200701 COC NoneUnloader, Fiberboard 1 Fiberboard 30700402 NONE None

*Emission factors in sets not separated by lines are the same.

73

TABLE 13. FUGITIVE EMISSION FACTOR GROUPS*.

Major Group Sub Group Fuel/Material

Abrasive Blasting, Dust 1 Dust

Aeration Basin, Wastewater 1 Wastewater

Asphalt Prod., Dust 1 DustAsphalt Prod., Dust 1 Rock plant mine feedAsphalt Prod., Dust 1 Specialty mine feed

Composition, Crude oil 1 Crude oil

Composition, Diesel 1 Diesel

Composition, Jp-4 1 Jp-4

Composition, Jp-5 1 Jp-5

Composition, Lube Oil 1 Lube oil

Composition, Produced water 1 Produced water

Composition, Sour Water 1 Sour water

Composition, Wastewater 1 Wastewater

DAF Tank, Wastewater 1 Wastewater

Flanges, Crude oil 1 Crude oil

Flanges, Field gas 1 Field gas

Fugitive, Sulfur 1 Sulfur

Fugitives, Casing/Natural Gas 1 Casing gas/Natural gas

Gas Processing, Field gas 1 Field gas

Gas Processing, Fuel Gas 1 Fuel gas

Gas Processing, Produced Gas 1 Produced gas

Headworks, Wastewater 1 Wastewater

Main Trap, Produced Gas 1 Produced gas

PST, Wastewater 1 Wastewater

Solids odor processing, Sludge 1 Sludge

Tank, Crude oil 1 Crude oil

Tank, Diluent 1 Diluent

Tank, Distillate oil 1 Distillate oil

Tank, Produced water 1 Produced water

Tank, Wastewater 1 Wastewater

*Emission factors in sets not separated by lines are the same.

74

TABLE 14. MEDICAL WASTE INCINERATOR CHARATERISTICS.

APCSystem

Substances QuantifiedDeviceID

Chambers Manu-facturer

StackTemperature,F

Waste

VOC Dioxin/Furan

PAH Metals HCl

208 2 Ecolair 1740 to 1840 HospitalPathological

None Y

226 2 Therm Tech 1330 Animal BeddingInfectious

None Y

227 2 Incinomite 457 to 502 Hospital Infectious None Y Y Y245 2 ? 490 to 670 Human Carcasses None Y Y Y246 2 ? ? Animal Carcasses None Y283 ? ? 401 to 420 Pathological S Y

75

TABLE 15. CHROME PLATING TEST MAJOR GROUPS AND COMPARISON MATRIX.

Major Group Condition ID

APCS Type Wet Scrubber Chemical FumeSuppressant

Mist Eliminator Filter

Used Type Used Type Used Type Used Type

Plating, Anodizing 240C1 DM/PB/F101 N NA Y PB/F101 Y Mesh Pad N NAPlating, Anodizing 241C1 DM/S/PB/F101 Y ? Y PB/F101 Y ? N NAPlating, Anodizing 420C1 WS Y ? N NA N NA N NAPlating, Anodizing 421C1 WS Y ? N NA N NA N NAPlating, Anodizing 620C1 DM/WS/HEPA Y ? N NA Y ? Y HEPA

Plating, Decorative 239C1 PBS Y PBS N NA N NA N NAPlating, Decorative 470C1 DM/DMNP/HEPA N NA Y DMNP Y Mesh-Pad Y HEPA

Plating, Hard 242C1 DM/S/PB/F101 Y ? Y PB/F101 Y ? N NAPlating, Hard 243C1 DM/S/PB/F101 Y ? Y PB/F101 Y ? N NAPlating, Hard 432C1 WS Y ? N NA N NA N NAPlating, Hard 455C1 S Y ? N NA N NA N NAPlating, Hard 455C2 S Y ? N NA N NA N NAPlating, Hard 456C1 S Y ? N NA N NA N NAPlating, Hard 457C1 DM/PBS/HEPA Y PBS N NA Y Mesh-Pad Y HEPAPlating, Hard 459C1 DM/S/F140 Y ? Y F140 Y ? N NAPlating, Hard 460C1 DM/PBS/PB/F101 Y PBS Y PB/F101 Y ? N NAPlating, Hard 461C1 None N NA N NA N NA N NAPlating, Hard 461C2 FB/PB N NA Y FB/PB N NA N NAPlating, Hard 461C3 F140 N NA Y F140 N NA N NAPlating, Hard 461C4 F140 N NA Y F140 N NA N NAPlating, Hard 461C1 DM/PBS Y PBS N NA Y Chevron Blade N NAPlating, Hard 461C2 DM/PBS/FB/PB Y PBS Y FB/PB Y Chevron Blade N NAPlating, Hard 462C1 F140 N NA Y F140 N NA N NAPlating, Hard 463C1 DM/PB/HEPA N NA Y PB Y Mesh-Pad Y HEPAPlating, Hard 464C1 DM/PBS/HEPA Y PBS N NA Y ? Y HEPAPlating, Hard 465C1 PBS Y PBS N NA N NA N NAPlating, Hard 466C1 F140 N NA Y F140 N NA N NAPlating, Hard 467C1 DM/S/F140/F101/MP Y ? Y F140/F101 Y Chevron Blades Y MPPlating, Hard 468C1 DM/S/F101/PB/MP Y ? Y F101/PB Y Chevron Blades Y MPPlating, Hard 469C1 PBS/F101/PB Y PBS Y F101/PB N NA N NA

76

TABLE 15. CHROME PLATING TEST MAJOR GROUPS AND COMPARISON MATRIX.

Major Group Condition ID

APCS Type Wet Scrubber Chemical FumeSuppressant

Mist Eliminator Filter

Used Type Used Type Used Type Used Type

Plating, Hard 471C1 DM/HEPA N NA N NA Y Mesh-Pad Y HEPAPlating, Hard 472C1 DM/HEPA N NA N NA Y Chevron Blade/Mesh-

PadY HEPA

Plating, Hard 473C1 DM/HEPA N NA N NA Y Chevron Blade/Mesh-Pad

Y HEPA

Plating, Hard 474C1 S/FPT Y ? Y FPT N NA N NAPlating, Hard 475C1 PBS/FB Y PBS Y FB N NA N NAPlating, Hard 475C1 FB N NA Y FB N NA N NAPlating, Hard 476C1 DM/S Y ? N NA Y ? N NAPlating, Hard 477C1 S/F Y ? N NA N NA Y ?Plating, Hard 478C1 DM/PBS/PB Y PBS Y PB Y Chevron Blade N NAPlating, Hard 478C2 DM/PBS/PB Y PBS Y PB Y Chevron Blade N NAPlating, Hard 608C1 DM/PB N NA Y PB Y ? N NAPlating, Hard 608C2 DM N NA N NA Y ? N NAPlating, Hard 609C1 DM/WS/PB Y ? Y PB Y ? N NAPlating, Hard 609C2 DM/WS/PB Y ? Y PB Y ? N NAPlating, Hard 610C1 WS Y ? N NA N NA N NAPlating, Hard 621C1 DM/WS/HEPA Y ? N NA Y ? Y HEPAPlating, Hard 622C1 DM/WS/HEPA Y ? N NA Y ? Y HEPA

Plating, Hard/Anodizing 286C1 S Y ? N NA N NA N NAPlating, Hard/Anodizing 286C2 S Y ? N NA N NA N NAPlating, Hard/Anodizing 458C1 DM/S Y ? N NA Y ? N NA

77

TABLE 16. SUBSTANCE SPECIFIC UNCERTAINTY AND RELATIVEL STANDARD DEVIATION (a).

Category Substance Relative Standard Deviation,%

Uncertainty, %

Mean Minimum Maximum Mean Minimum MaximumDioxin/Furan Dioxin/Furan:Total 51.98 25.72 76.58 129.13 63.89 190.24Dioxin/Furan Dioxin:4D 2378 47.52 2.18 132.12 127.15 19.20 739.14Dioxin/Furan Dioxin:4D Other 96.53 96.53 96.53 239.78 239.78 239.78Dioxin/Furan Dioxin:4D Total 71.07 7.73 170.56 184.01 19.20 660.69Dioxin/Furan Dioxin:5D 12378 56.02 3.45 142.30 142.00 19.20 495.15Dioxin/Furan Dioxin:5D Other 23.10 23.10 23.10 57.39 57.39 57.39Dioxin/Furan Dioxin:5D Total 84.17 4.41 234.95 214.84 19.20 950.95Dioxin/Furan Dioxin:6D 123478 63.24 3.45 228.39 161.58 27.75 863.71Dioxin/Furan Dioxin:6D 123678 57.23 3.44 147.43 157.65 19.20 906.40Dioxin/Furan Dioxin:6D 123789 62.79 3.44 228.54 163.70 30.93 1004.66Dioxin/Furan Dioxin:6D Other 44.09 44.09 44.09 109.53 109.53 109.53Dioxin/Furan Dioxin:6D Total 69.51 3.44 192.58 177.39 19.20 828.76Dioxin/Furan Dioxin:7D 1234678 56.63 2.98 127.05 148.04 7.40 695.61Dioxin/Furan Dioxin:7D Other 38.24 38.24 38.24 95.00 95.00 95.00Dioxin/Furan Dioxin:7D Total 62.69 7.73 169.01 160.20 19.20 640.39Dioxin/Furan Dioxin:8D 45.07 3.43 156.83 102.82 19.20 240.35Dioxin/Furan Furan:4F 2378 69.37 4.11 172.39 181.25 11.60 871.51Dioxin/Furan Furan:4F Other 47.70 47.70 47.70 118.50 118.50 118.50Dioxin/Furan Furan:4F Total 68.54 4.67 166.84 190.43 11.60 942.19Dioxin/Furan Furan:5F 12378 61.85 3.21 176.54 157.63 19.20 810.37Dioxin/Furan Furan:5F 23478 65.11 1.79 168.14 173.12 16.04 1027.87Dioxin/Furan Furan:5F Other 42.57 42.57 42.57 105.75 105.75 105.75Dioxin/Furan Furan:5F Total 72.27 7.73 164.68 203.47 19.20 1216.63Dioxin/Furan Furan:6F 123478 65.25 1.38 171.12 168.45 3.44 894.48Dioxin/Furan Furan:6F 123678 61.35 1.38 166.91 160.35 3.44 917.96Dioxin/Furan Furan:6F 123789 57.43 1.17 174.85 151.23 10.54 874.59Dioxin/Furan Furan:6F 234678 63.29 2.55 158.52 165.96 6.33 881.45Dioxin/Furan Furan:6F Other 49.18 49.18 49.18 122.18 122.18 122.18Dioxin/Furan Furan:6F Total 71.22 1.42 164.18 186.23 12.78 951.60Dioxin/Furan Furan:7F 1234678 67.19 4.63 167.38 176.48 11.50 881.77Dioxin/Furan Furan:7F 1234789 70.16 0.68 195.12 187.71 6.12 1103.37Dioxin/Furan Furan:7F Other 0.00 0.00 0.00 0.00 0.00 0.00Dioxin/Furan Furan:7F Total 65.78 4.47 167.80 174.80 19.20 940.90Dioxin/Furan Furan:8F 65.15 1.67 215.22 150.32 4.15 421.74Halogens HCl 48.79 7.47 98.79 150.34 18.55 799.00Halogens HF 69.20 31.61 122.53 328.15 33.18 1100.90Metals Aluminum 162.18 162.18 162.18 402.88 402.88 402.88Metals Antimony 36.29 2.18 129.46 50.96 5.42 206.81Metals Arsenic 45.00 0.00 175.03 96.21 0.00 592.95Metals Barium 45.38 0.00 125.06 92.74 0.00 232.35Metals Beryllium 36.51 0.00 245.64 79.52 0.00 870.80Metals Cadmium 59.85 0.00 313.81 126.98 0.00 900.98Metals Chromium (Hex) 45.43 0.00 177.44 80.18 0.00 514.08Metals Chromium (Total) 41.04 0.00 167.83 76.96 0.00 601.87Metals Cobalt 38.66 0.00 105.93 210.80 0.00 951.78Metals Copper 44.40 0.00 140.67 98.24 0.00 502.34

78

TABLE 16. SUBSTANCE SPECIFIC UNCERTAINTY AND RELATIVEL STANDARD DEVIATION (a).

Category Substance Relative Standard Deviation,%

Uncertainty, %

Mean Minimum Maximum Mean Minimum MaximumMetals Iron 38.81 38.81 38.81 96.40 96.40 96.40Metals Lead 49.25 0.00 223.04 94.19 0.00 484.67Metals Magnesium 17.62 0.00 52.85 43.77 0.00 131.30Metals Manganese 79.76 0.00 366.37 143.88 0.00 421.86Metals Mercury 59.32 0.00 180.99 95.18 0.00 370.24Metals Molybdenum 32.98 32.98 32.98 81.93 81.93 81.93Metals Nickel 59.04 0.00 207.41 128.56 0.00 819.37Metals Phosphorus 34.46 0.00 102.29 62.90 0.00 198.16Metals Selenium 51.12 0.00 285.39 93.69 0.00 1179.04Metals Silver 51.08 0.00 144.07 125.99 0.00 722.28Metals Strontium 2.51 2.51 2.51 6.24 6.24 6.24Metals Thallium 40.48 2.18 117.46 53.62 5.42 136.34Metals Vanadium 60.74 60.74 60.74 150.89 150.89 150.89Metals Zinc 64.02 0.00 262.73 147.59 0.00 1233.82PAH Acenaphthene 75.25 0.00 215.25 123.72 0.00 584.68PAH Acenaphthylene 80.11 0.00 223.79 130.52 0.00 530.66PAH Anthracene 65.89 0.00 216.17 123.10 0.00 1222.55PAH Benzo(a)anthracene 67.27 0.00 353.09 95.93 0.00 411.28PAH Benzo(a)pyrene 64.71 0.00 478.22 108.29 0.00 956.35PAH Benzo(b)fluoranthene 68.58 0.00 424.05 110.62 0.00 397.22PAH Benzo(b+k)fluoranthene 38.40 1.90 99.78 37.18 4.71 83.96PAH Benzo(e)pyrene 48.45 5.04 129.80 104.01 12.52 322.44PAH Benzo(g,h,i)perylene 56.23 0.00 217.33 84.59 0.00 349.14PAH Benzo(k)fluoranthene 64.39 0.00 417.90 94.30 0.00 287.83PAH Chrysene 61.42 0.00 215.17 90.71 0.00 361.90PAH Dibenz(a,h)anthracene 54.60 0.00 339.62 72.67 0.00 407.84PAH Fluoranthene 63.29 0.00 258.95 96.69 0.00 385.95PAH Fluorene 67.54 0.00 214.54 113.98 0.00 610.07PAH Indeno(1,2,3-cd)pyrene 63.72 0.00 475.63 85.05 0.00 394.25PAH Naphthalene 71.35 0.00 271.16 103.36 0.00 360.49PAH Phenanthrene 65.63 0.00 208.44 104.87 0.00 415.55PAH Pyrene 69.06 0.00 276.89 108.67 0.00 360.26PCB PCB:Decachlorinated biphenyls 27.15 3.02 45.99 67.44 7.51 114.25PCB PCB:Dichlorinated biphenyls 51.50 3.02 83.34 127.94 7.51 207.03PCB PCB:Heptachlorinated biphenyls 45.29 3.02 151.05 112.52 7.51 375.22PCB PCB:Hexachlorinated biphenyls 48.14 4.02 137.80 119.59 9.99 342.32PCB PCB:Monochlorinated biphenyls 37.03 3.02 102.83 91.99 7.51 255.45PCB PCB:Nonachlorinated biphenyls 30.62 3.02 53.68 76.06 7.51 133.36PCB PCB:Octachlorinated biphenyls 27.45 3.02 73.64 68.19 7.51 182.94PCB PCB:Pentachlorinated biphenyls 39.97 3.02 74.51 99.30 7.51 185.10PCB PCB:Tetrachlorinated biphenyls 41.86 3.02 108.25 103.99 7.51 268.90PCB PCB:Trichlorinated biphenyls 47.36 3.02 103.57 117.64 7.51 257.28Particulate Particulate 70.16 59.15 81.16 116.06 85.18 146.94SVOC 1,2-Dichlorobenzene 7.55 0.00 20.87 18.75 0.00 51.84SVOC 2-Chloronaphthalene 64.04 2.15 172.55 140.18 19.32 428.63

79

TABLE 16. SUBSTANCE SPECIFIC UNCERTAINTY AND RELATIVEL STANDARD DEVIATION (a).

Category Substance Relative Standard Deviation,%

Uncertainty, %

Mean Minimum Maximum Mean Minimum MaximumSVOC 2-Methylnaphthalene 47.68 1.42 161.60 80.37 3.53 340.46SVOC Benzaldehyde 29.96 6.29 63.37 74.41 15.64 157.41SVOC Ethylbenzene 45.26 0.00 158.91 132.79 0.00 1111.79SVOC Perylene 45.20 1.39 206.85 88.24 3.45 277.26SVOC Phenol 64.67 0.00 131.32 94.36 0.00 326.21VOC 1,1,1-Trichloroethane 53.15 0.00 176.12 89.51 0.00 417.61VOC 1,1,2,2-Tetrachloroethane 39.11 0.00 151.38 43.21 0.00 202.41VOC 1,1,2-Trichloroethane 29.01 0.00 151.38 18.12 0.00 52.45VOC 1,1-Dichloroethane 52.39 0.00 151.38 63.24 0.00 252.61VOC 1,1-Dichloroethene 37.86 0.00 151.38 40.10 0.00 183.75VOC 1,2,4-Trichlorobenzene 0.00 0.00 0.00 0.00 0.00 0.00VOC 1,2-Dichloroethane 31.89 0.00 165.26 31.83 0.00 210.90VOC 1,2-Dichloroethene 53.92 0.00 193.02 34.44 0.00 81.51VOC 1,2-Dichloropropane 38.84 0.00 151.38 42.56 0.00 198.48VOC 1,3-Butadiene 19.36 0.00 93.74 22.16 0.00 98.38VOC 1,4-Dioxane 136.33 136.33 136.33 169.27 169.27 169.27VOC 2-Chloroethyl Vinyl Ether 84.27 10.77 157.76 40.71 26.77 54.66VOC 2-Hexanone 40.82 0.00 151.38 20.51 0.00 52.45VOC 4-Methyl-2-pentanone 51.09 0.00 153.27 17.70 0.00 53.11VOC Acetaldehyde 67.17 0.98 299.45 110.77 2.44 913.65VOC Acetone 61.92 0.00 197.73 83.38 0.00 420.56VOC Acetonitrile 169.52 169.52 169.52 121.27 121.27 121.27VOC Acrolein 58.49 0.00 244.16 70.28 0.00 270.34VOC Acrylonitrile 139.60 127.82 151.38 105.58 52.45 158.71VOC Ammonia 32.61 0.00 120.14 111.76 0.00 1079.44VOC Benzene 44.31 0.00 305.12 67.91 0.00 1150.72VOC Bromodichloromethane 29.01 0.00 151.38 18.12 0.00 52.45VOC Bromoform 29.01 0.00 151.38 18.12 0.00 52.45VOC Bromomethane 29.01 0.00 151.38 18.12 0.00 52.45VOC Carbon Tetrachloride 17.84 0.00 151.38 16.23 0.00 58.57VOC Carbon disulfide 52.22 0.00 159.16 76.90 0.00 395.38VOC Carbonyl Sulfide 6.19 0.41 14.76 15.37 1.02 36.66VOC Chlorobenzene 36.82 0.00 174.73 83.77 0.00 423.54VOC Chloroethane 29.01 0.00 151.38 18.12 0.00 52.45VOC Chloroform 24.39 0.00 150.55 37.75 0.00 313.43VOC Chloromethane 38.05 0.00 151.38 40.59 0.00 186.67VOC Cyanide 25.54 14.40 51.60 63.44 35.77 128.18VOC Dibromochloromethane 29.01 0.00 151.38 18.12 0.00 52.45VOC Dichlorodifluoromethane 50.46 0.00 151.38 17.48 0.00 52.45VOC Dichloromethane 117.53 106.38 126.63 242.89 116.39 314.58VOC Diochloromethane 49.80 49.80 49.80 123.72 123.72 123.72VOC Ethylene dibromide 1.55 1.55 1.55 1.63 1.63 1.63VOC Ethylene dichloride 1.55 1.55 1.55 1.63 1.63 1.63VOC Formaldehyde 74.18 0.95 351.67 111.15 2.37 1220.79VOC Freon 11 1.21 0.00 4.83 1.92 0.00 7.69VOC Freon 113 0.00 0.00 0.00 0.00 0.00 0.00

80

TABLE 16. SUBSTANCE SPECIFIC UNCERTAINTY AND RELATIVEL STANDARD DEVIATION (a).

Category Substance Relative Standard Deviation,%

Uncertainty, %

Mean Minimum Maximum Mean Minimum MaximumVOC Hexane 21.29 9.06 41.69 52.89 22.51 103.55VOC Hydrogen Sulfide 50.78 0.00 184.09 172.47 0.00 1214.14VOC Methyl Chloroform 34.12 0.90 80.11 46.45 2.23 84.07VOC Methyl Ethyl Ketone 77.21 0.00 149.96 138.37 0.00 365.24VOC Methylene Chloride 38.46 0.00 240.78 40.74 0.00 130.44VOC Perchloroethylene 1.22 0.90 1.55 1.93 1.63 2.23VOC Propylene 44.09 0.00 185.03 46.80 0.00 166.68VOC Propylene Oxide 20.56 20.56 20.56 51.07 51.07 51.07VOC Styrene 59.70 0.00 169.06 220.29 0.00 1194.21VOC Tetrachloroethene 22.30 0.00 147.49 24.46 0.00 110.47VOC Toluene 53.18 0.00 213.61 90.81 0.00 892.12VOC Trichloroethene 38.32 0.00 171.84 49.01 0.00 262.46VOC Trichloroethylene 1.55 1.55 1.55 1.63 1.63 1.63VOC Trichlorofluoromethane 23.16 0.00 151.38 17.08 0.00 52.45VOC Vinyl Acetate 34.36 0.00 135.67 12.86 0.00 47.01VOC Vinyl Chloride 27.47 0.00 151.38 37.12 0.00 183.32VOC Xylene (Total) 49.21 0.00 165.99 87.91 0.00 412.34VOC Xylene (m) 21.86 6.19 37.54 54.32 15.38 93.25VOC Xylene (m,p) 38.84 0.00 151.73 94.62 0.00 1103.06VOC Xylene (o) 35.68 0.00 289.29 74.95 0.00 975.12VOC Xylene (p) 17.71 7.10 28.33 44.00 17.63 70.38VOC cis-1,2-Dichloroethene 0.00 0.00 0.00 0.00 0.00 0.00VOC cis-1,3-Dichloropropene 50.46 0.00 151.38 17.48 0.00 52.45VOC p-Dichlorobenzene 25.28 3.76 89.83 40.22 5.98 142.94VOC trans-1,2-Dichloroethene 0.00 0.00 0.00 0.00 0.00 0.00VOC trans-1,3-Dichloropropene 50.46 0.00 151.38 17.48 0.00 52.45

(a) Table described in Section 6.9 Results.

81

TABLE 17. CARB OVERALL RATING SUMMARY.

Population RatingCARB Method Rating Order ofMagnitudeDifference

1. Many randomfacilities (5 ormore sources)

2. Reasonablenumber of facilities

(3 to 4 sources)

3. Small numberof facilities (<3

sources)

- 80 4 12 10401 18 16 2502 14 42 443 8 4 174 2 25 1

A. Test was performed using anew or old CARBmethodology and sufficientdocumentation was provided tovalidate the results.

6 1- 30 3 4 771 11 45 542 61 33 213 20 6 134 18 5 25 1

B. Test was performed using anew or old EPA methodologyand sufficient documentationwas provided to validate theresults.

6 1- 1390 12 5791 4 36 1282 6 11 253 7 2 5

C. Test was performed using anew or old CARBmethodology and insufficientdocumentation was provided tovalidate the results.

4 6- 540 18 1231 4 21 592 4 6 27

D. Test was performed using anew or old EPA methodologyand insufficient documentationwas provided to validate theresults. 3 1 3 4

0 1021 25

E. An assumption was made in theemission factor calculation thatcould significantly affect theaccuracy of the results.

2 1 2

vN - N is the order of magnitude difference between minimum and maximum.() - Number of emission factors

82

TABLE 18. EPA OVERALL RATING THAT WOULD BE ASSIGNED TO EMISSION FACTORS*

EPA Method Rating Population Rating1. Many random

facilities [5 or moresources]

2. Reasonablenumber of

facilities [3 to 4sources]

3. Small number offacilities [<3

sources]

A Current EPA orCARB methodwith supportingdocumentation

A (26) B (19)

B Current EPA orCARB method nosupportingdocumentation

C (32)

D (859)

C Old EPA orCARB methodwith and withoutsupportingdocumentation

NR(395)

D Order ofmagnitude method

E (1944)

NR - Not rated in EPA system() - Number of emission factors*EPA overall ratings shown were assigned for this project and are not official EPAratings.

83

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Blowing 1 VOC Hydrogen Sulfide C3-v2 4.26E-04 1.26E-05 1.26E-03 1.09E-05 lbs/ton processed 1 168.44 418.44 0.98

Asphalt Prod., Diesel 1 Metals Arsenic C3-v0 2.73E-07 2.71E-07 2.77E-07 2.70E-07 lbs/ton production 1 1.44 3.58 0.00

Asphalt Prod., Diesel 1 Metals Beryllium C3-v0 5.45E-07 5.42E-07 5.54E-07 5.39E-07 lbs/ton production 1 1.44 3.58 0.00

Asphalt Prod., Diesel 1 Metals Cadmium C3-v- 1.62E-06 1.62E-06 1.62E-06 1.62E-06 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 1 Metals Chromium (Hex) C3-v0 3.61E-07 3.67E-07 5.17E-07 2.00E-07 lbs/ton production 1 43.92 109.11 1.00

Asphalt Prod., Diesel 1 Metals Chromium (Total) C3-v0 1.96E-06 1.40E-06 3.41E-06 1.07E-06 lbs/ton production 1 64.78 160.93 1.00

Asphalt Prod., Diesel 1 Metals Copper C3-v0 1.50E-06 1.50E-06 1.66E-06 1.35E-06 lbs/ton production 1 14.76 132.64 1.00

Asphalt Prod., Diesel 1 Metals Lead C3-v0 2.01E-06 2.17E-06 2.77E-06 1.08E-06 lbs/ton production 1 42.76 106.22 1.00

Asphalt Prod., Diesel 1 Metals Manganese C3-v0 1.24E-05 1.36E-05 1.61E-05 7.55E-06 lbs/ton production 1 35.33 87.76 1.00

Asphalt Prod., Diesel 1 Metals Mercury C3-v0 4.88E-08 5.93E-08 7.05E-08 1.66E-08 lbs/ton production 1 58.25 144.70 0.52

Asphalt Prod., Diesel 1 Metals Nickel C3-v0 2.73E-06 2.71E-06 2.77E-06 2.70E-06 lbs/ton production 1 1.44 3.58 0.00

Asphalt Prod., Diesel 1 Metals Selenium C3-v0 2.73E-07 2.71E-07 2.77E-07 2.70E-07 lbs/ton production 1 1.44 3.58 0.00

Asphalt Prod., Diesel 1 Metals Zinc C3-v0 1.82E-05 1.66E-05 2.44E-05 1.35E-05 lbs/ton production 1 30.95 76.88 1.00

Asphalt Prod., Diesel 1 PAH Acenaphthene A3-v1 4.80E-07 3.42E-07 9.53E-07 1.45E-07 lbs/ton production 1 87.81 218.12 1.00

Asphalt Prod., Diesel 1 PAH Acenaphthylene A3-v1 3.36E-07 2.70E-07 6.35E-07 1.03E-07 lbs/ton production 1 80.92 201.01 1.00

Asphalt Prod., Diesel 1 PAH Anthracene A3-v0 3.21E-08 3.49E-08 3.79E-08 2.34E-08 lbs/ton production 1 23.94 59.48 1.00

Asphalt Prod., Diesel 1 PAH Benzo(a)anthracene A3-v0 6.12E-08 4.86E-08 9.00E-08 4.48E-08 lbs/ton production 1 41.00 101.85 1.00

Asphalt Prod., Diesel 1 PAH Benzo(a)pyrene A3-v0 2.79E-09 2.21E-09 4.45E-09 1.73E-09 lbs/ton production 1 51.96 129.08 1.00

Asphalt Prod., Diesel 1 PAH Benzo(b)fluoranthene A3-v0 1.39E-08 8.64E-09 2.49E-08 8.28E-09 lbs/ton production 1 68.08 169.13 1.00

Asphalt Prod., Diesel 1 PAH Benzo(g,h,i)perylene A3-v0 1.90E-09 1.72E-09 2.65E-09 1.33E-09 lbs/ton production 1 35.53 88.26 0.23

Asphalt Prod., Diesel 1 PAH Benzo(k)fluoranthene A3-v0 5.13E-09 3.60E-09 8.47E-09 3.31E-09 lbs/ton production 1 56.56 140.50 1.00

Asphalt Prod., Diesel 1 PAH Chrysene A3-v0 2.70E-08 2.34E-08 4.08E-08 1.69E-08 lbs/ton production 1 45.67 113.46 1.00

Asphalt Prod., Diesel 1 PAH Dibenz(a,h)anthracene A3-v0 1.76E-09 1.72E-09 2.65E-09 9.00E-10 lbs/ton production 1 49.76 123.60 0.00

Asphalt Prod., Diesel 1 PAH Fluoranthene A3-v0 2.17E-07 2.24E-07 2.28E-07 1.98E-07 lbs/ton production 1 7.51 18.66 1.00

Asphalt Prod., Diesel 1 PAH Fluorene A3-v0 8.83E-07 8.10E-07 1.22E-06 6.21E-07 lbs/ton production 1 34.56 85.85 1.00

Asphalt Prod., Diesel 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.06E-09 1.80E-09 2.65E-09 1.72E-09 lbs/ton production 1 24.92 61.89 0.29

Asphalt Prod., Diesel 1 PAH Naphthalene A3-v0 4.75E-05 3.42E-05 7.94E-05 2.88E-05 lbs/ton production 1 58.62 145.61 1.00

Asphalt Prod., Diesel 1 PAH Phenanthrene A3-v0 6.27E-07 6.55E-07 8.47E-07 3.78E-07 lbs/ton production 1 37.64 93.51 1.00

84

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Diesel 1 PAH Pyrene A3-v0 1.66E-07 1.66E-07 1.75E-07 1.58E-07 lbs/ton production 1 4.94 12.28 1.00

Asphalt Prod., Diesel 1 VOC Benzene C3-v0 1.56E-02 1.50E-02 1.74E-02 1.43E-02 lbs/ton production 1 10.42 25.88 1.00

Asphalt Prod., Diesel 1 VOC Formaldehyde A3-v0 1.32E-04 1.15E-04 1.98E-04 8.28E-05 lbs/ton production 1 44.97 111.70 1.00

Asphalt Prod., Diesel 2 Metals Arsenic E3-v0 6.60E-08 4.59E-08 1.20E-07 3.19E-08 lbs/ton production 1 71.88 178.55 1.00

Asphalt Prod., Diesel 2 Metals Beryllium E3-v0 1.50E-07 1.53E-07 1.63E-07 1.35E-07 lbs/ton production 1 9.49 23.57 0.00

Asphalt Prod., Diesel 2 Metals Cadmium E3-v0 1.38E-07 1.59E-07 1.63E-07 9.29E-08 lbs/ton production 1 28.37 70.48 0.78

Asphalt Prod., Diesel 2 Metals Chromium (Hex) E3-v0 8.56E-08 7.92E-08 1.20E-07 5.79E-08 lbs/ton production 1 36.68 91.13 1.00

Asphalt Prod., Diesel 2 Metals Chromium (Total) E3-v0 5.23E-07 3.27E-07 9.15E-07 3.26E-07 lbs/ton production 1 65.04 161.56 1.00

Asphalt Prod., Diesel 2 Metals Copper E3-v0 1.12E-06 1.09E-06 1.45E-06 8.17E-07 lbs/ton production 1 28.16 69.96 1.00

Asphalt Prod., Diesel 2 Metals Lead E3-v0 2.27E-06 1.45E-06 4.04E-06 1.31E-06 lbs/ton production 1 67.86 168.57 1.00

Asphalt Prod., Diesel 2 Metals Manganese E3-v0 9.11E-07 9.29E-07 1.08E-06 7.21E-07 lbs/ton production 1 19.99 49.66 1.00

Asphalt Prod., Diesel 2 Metals Mercury E3-v0 7.06E-07 7.10E-07 7.83E-07 6.25E-07 lbs/ton production 1 11.21 27.84 0.00

Asphalt Prod., Diesel 2 Metals Nickel E3-v0 5.35E-07 4.23E-07 7.65E-07 4.16E-07 lbs/ton production 1 37.34 92.75 1.00

Asphalt Prod., Diesel 2 Metals Selenium E3-v0 1.16E-06 9.29E-07 1.75E-06 8.17E-07 lbs/ton production 1 43.59 108.29 0.50

Asphalt Prod., Diesel 2 Metals Zinc E3-v1 6.71E-06 3.55E-06 1.39E-05 2.62E-06 lbs/ton production 1 93.70 232.75 1.00

Asphalt Prod., Diesel 2 PAH Acenaphthene E3-v0 2.11E-08 2.33E-08 3.06E-08 9.31E-09 lbs/ton production 1 51.40 127.67 1.00

Asphalt Prod., Diesel 2 PAH Acenaphthylene E3-v1 2.04E-08 1.30E-08 4.19E-08 6.37E-09 lbs/ton production 1 92.51 229.80 1.00

Asphalt Prod., Diesel 2 PAH Anthracene E3-v0 1.68E-08 1.44E-08 2.53E-08 1.08E-08 lbs/ton production 1 44.86 111.43 1.00

Asphalt Prod., Diesel 2 PAH Benzo(a)anthracene E3-v0 6.41E-09 6.03E-09 9.14E-09 4.07E-09 lbs/ton production 1 39.88 99.08 1.00

Asphalt Prod., Diesel 2 PAH Benzo(a)pyrene E3-v0 3.13E-10 3.38E-10 3.49E-10 2.53E-10 lbs/ton production 1 16.87 41.91 1.00

Asphalt Prod., Diesel 2 PAH Benzo(b)fluoranthene E3-v1 4.39E-09 7.84E-10 1.18E-08 5.68E-10 lbs/ton production 1 146.56 364.08 1.00

Asphalt Prod., Diesel 2 PAH Benzo(g,h,i)perylene E3-v0 5.03E-10 5.07E-10 5.32E-10 4.71E-10 lbs/ton production 1 6.16 15.30 1.00

Asphalt Prod., Diesel 2 PAH Benzo(k)fluoranthene E3-v1 1.13E-09 3.97E-10 2.63E-09 3.49E-10 lbs/ton production 1 115.87 287.83 1.00

Asphalt Prod., Diesel 2 PAH Chrysene E3-v0 1.25E-09 1.10E-09 1.67E-09 9.80E-10 lbs/ton production 1 29.45 73.16 1.00

Asphalt Prod., Diesel 2 PAH Dibenz(a,h)anthracene E3-v0 1.90E-10 1.32E-10 3.15E-10 1.24E-10 lbs/ton production 1 56.78 141.05 0.00

Asphalt Prod., Diesel 2 PAH Fluoranthene E3-v0 8.67E-08 7.84E-08 1.29E-07 5.27E-08 lbs/ton production 1 44.76 111.18 1.00

Asphalt Prod., Diesel 2 PAH Fluorene E3-v1 2.78E-07 2.74E-07 4.73E-07 8.82E-08 lbs/ton production 1 69.13 171.72 1.00

Asphalt Prod., Diesel 2 PAH Indeno(1,2,3-cd)pyrene E3-v0 3.00E-10 2.99E-10 3.06E-10 2.95E-10 lbs/ton production 1 2.01 4.99 1.00

85

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Diesel 2 PAH Naphthalene E3-v0 1.08E-05 1.30E-05 1.40E-05 5.39E-06 lbs/ton production 1 43.57 108.24 1.00

Asphalt Prod., Diesel 2 PAH Phenanthrene E3-v0 7.23E-07 6.03E-07 1.08E-06 4.90E-07 lbs/ton production 1 42.95 106.70 1.00

Asphalt Prod., Diesel 2 PAH Pyrene E3-v0 5.99E-08 5.88E-08 8.60E-08 3.49E-08 lbs/ton production 1 42.66 105.97 1.00

Asphalt Prod., Diesel 2 VOC Benzene E3-v0 1.04E-03 1.04E-03 1.09E-03 1.00E-03 lbs/ton production 1 4.45 11.06 0.00

Asphalt Prod., Diesel 2 VOC Formaldehyde E3-v0 2.43E-04 2.20E-04 3.30E-04 1.80E-04 lbs/ton production 1 31.80 79.00 1.00

Asphalt Prod., Diesel 3 Metals Arsenic D3-v- 8.02E-06 8.02E-06 8.02E-06 8.02E-06 lbs/ton production 1 0.00 0.00 0.00

Asphalt Prod., Diesel 3 Metals Beryllium D3-v- 4.01E-06 4.01E-06 4.01E-06 4.01E-06 lbs/ton production 1 0.00 0.00 0.00

Asphalt Prod., Diesel 3 Metals Cadmium D3-v- 4.41E-05 4.41E-05 4.41E-05 4.41E-05 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Chromium (Total) D3-v- 8.42E-05 8.42E-05 8.42E-05 8.42E-05 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Copper D3-v- 1.32E-04 1.32E-04 1.32E-04 1.32E-04 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Lead D3-v- 2.19E-03 2.19E-03 2.19E-03 2.19E-03 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Manganese D3-v- 1.64E-03 1.64E-03 1.64E-03 1.64E-03 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Mercury D3-v- 8.02E-07 8.02E-07 8.02E-07 8.02E-07 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 Metals Nickel D3-v- 3.81E-04 3.81E-04 3.81E-04 3.81E-04 lbs/ton production 1 0.00 0.00 0.00

Asphalt Prod., Diesel 3 Metals Selenium D3-v- 8.02E-06 8.02E-06 8.02E-06 8.02E-06 lbs/ton production 1 0.00 0.00 0.00

Asphalt Prod., Diesel 3 Metals Zinc D3-v- 4.62E-03 4.62E-03 4.62E-03 4.62E-03 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Diesel 3 VOC Benzene C3-v- 3.05E-04 3.05E-04 3.05E-04 3.05E-04 lbs/ton production 1 0.00 0.00 1.00

Asphalt Prod., Natural Gas 1 Metals Arsenic C2-v1 6.69E-07 6.13E-07 2.00E-06 1.05E-07 lbs/ton production 3 90.07 69.24 0.00

Asphalt Prod., Natural Gas 1 Metals Beryllium C2-v1 8.32E-07 9.08E-07 2.00E-06 2.11E-07 lbs/ton production 3 74.61 57.35 0.00

Asphalt Prod., Natural Gas 1 Metals Cadmium C2-v1 1.78E-06 9.44E-07 7.99E-06 4.21E-07 lbs/ton production 3 133.47 102.59 0.79

Asphalt Prod., Natural Gas 1 Metals Chromium (Hex) C2-v1 4.47E-07 3.05E-07 1.07E-06 3.33E-08 lbs/ton production 3 94.43 72.58 0.27

Asphalt Prod., Natural Gas 1 Metals Chromium (Total) C2-v0 9.92E-07 1.04E-06 1.55E-06 4.25E-07 lbs/ton production 3 37.04 28.47 0.67

Asphalt Prod., Natural Gas 1 Metals Copper C2-v0 3.27E-06 3.37E-06 4.88E-06 1.23E-06 lbs/ton production 3 40.05 30.78 0.72

Asphalt Prod., Natural Gas 1 Metals Lead C2-v1 4.36E-06 1.52E-06 2.10E-05 6.84E-07 lbs/ton production 3 152.51 117.23 1.00

Asphalt Prod., Natural Gas 1 Metals Manganese C2-v1 2.00E-05 2.16E-05 4.46E-05 1.89E-06 lbs/ton production 3 68.58 52.71 1.00

Asphalt Prod., Natural Gas 1 Metals Mercury C2-v2 1.08E-05 3.39E-06 3.06E-05 3.08E-07 lbs/ton production 3 115.28 88.61 1.00

Asphalt Prod., Natural Gas 1 Metals Nickel C2-v1 3.63E-06 2.05E-06 1.02E-05 7.98E-07 lbs/ton production 3 89.63 68.90 0.00

Asphalt Prod., Natural Gas 1 Metals Selenium C2-v1 6.68E-07 6.13E-07 1.99E-06 1.05E-07 lbs/ton production 3 89.94 69.13 0.00

86

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Natural Gas 1 Metals Zinc C2-v0 1.30E-05 1.24E-05 2.56E-05 6.35E-06 lbs/ton production 3 46.31 35.60 1.00

Asphalt Prod., Natural Gas 1 PAH Acenaphthene B2-v3 6.40E-07 5.72E-07 1.23E-06 8.14E-10 lbs/ton production 3 63.77 49.02 1.00

Asphalt Prod., Natural Gas 1 PAH Acenaphthylene B2-v4 1.53E-06 2.14E-07 1.06E-05 3.70E-10 lbs/ton production 3 223.79 172.02 1.00

Asphalt Prod., Natural Gas 1 PAH Anthracene B2-v3 1.88E-07 9.45E-08 9.67E-07 4.14E-10 lbs/ton production 3 161.11 123.84 1.00

Asphalt Prod., Natural Gas 1 PAH Benzo(a)anthracene B2-v1 9.64E-09 1.03E-08 1.57E-08 3.70E-10 lbs/ton production 3 48.74 45.08 0.99

Asphalt Prod., Natural Gas 1 PAH Benzo(a)pyrene B2-v0 1.04E-09 1.04E-09 1.63E-09 3.70E-10 lbs/ton production 3 43.99 40.68 0.32

Asphalt Prod., Natural Gas 1 PAH Benzo(b)fluoranthene B2-v1 1.48E-09 5.31E-10 3.73E-09 2.44E-10 lbs/ton production 3 98.97 91.53 0.87

Asphalt Prod., Natural Gas 1 PAH Benzo(e)pyrene C3-v0 3.83E-09 3.94E-09 4.14E-09 3.41E-09 lbs/ton production 1 9.79 24.32 1.00

Asphalt Prod., Natural Gas 1 PAH Benzo(g,h,i)perylene B2-v1 1.29E-09 1.27E-09 2.04E-09 3.70E-10 lbs/ton production 3 40.72 37.66 0.54

Asphalt Prod., Natural Gas 1 PAH Benzo(k)fluoranthene B2-v1 2.34E-09 1.55E-09 4.36E-09 3.70E-10 lbs/ton production 3 71.96 66.55 0.75

Asphalt Prod., Natural Gas 1 PAH Chrysene B2-v1 1.55E-09 1.55E-09 3.22E-09 3.70E-10 lbs/ton production 3 57.18 52.88 0.62

Asphalt Prod., Natural Gas 1 PAH Dibenz(a,h)anthracene B2-v1 9.84E-10 1.04E-09 1.77E-09 3.22E-10 lbs/ton production 3 56.93 52.65 0.36

Asphalt Prod., Natural Gas 1 PAH Fluoranthene B2-v4 4.56E-07 7.46E-08 3.60E-06 5.99E-10 lbs/ton production 3 258.95 199.04 1.00

Asphalt Prod., Natural Gas 1 PAH Fluorene B2-v3 1.72E-06 2.07E-06 2.65E-06 2.96E-09 lbs/ton production 3 51.74 39.77 1.00

Asphalt Prod., Natural Gas 1 PAH Indeno(1,2,3-cd)pyrene B2-v1 1.16E-09 1.04E-09 2.18E-09 3.70E-10 lbs/ton production 3 49.04 45.35 0.49

Asphalt Prod., Natural Gas 1 PAH Naphthalene B2-v2 2.48E-05 1.56E-05 6.46E-05 5.48E-07 lbs/ton production 3 96.39 74.09 1.00

Asphalt Prod., Natural Gas 1 PAH Phenanthrene B2-v3 2.45E-06 1.91E-06 7.75E-06 6.81E-09 lbs/ton production 3 87.68 67.40 1.00

Asphalt Prod., Natural Gas 1 PAH Pyrene B2-v4 8.39E-07 6.14E-08 7.04E-06 8.14E-10 lbs/ton production 3 276.89 212.84 1.00

Asphalt Prod., Natural Gas 1 SVOC Ethylbenzene C3-v0 2.74E-05 2.70E-05 3.34E-05 2.17E-05 lbs/ton production 1 21.36 53.06 1.00

Asphalt Prod., Natural Gas 1 VOC Acetaldehyde C3-v0 5.32E-05 5.80E-05 6.39E-05 3.77E-05 lbs/ton production 1 25.80 64.08 1.00

Asphalt Prod., Natural Gas 1 VOC Benzene C2-v1 8.98E-05 1.94E-05 3.32E-04 1.03E-05 lbs/ton production 3 135.22 103.94 1.00

Asphalt Prod., Natural Gas 1 VOC Formaldehyde B2-v2 2.57E-04 3.89E-05 7.86E-04 1.00E-05 lbs/ton production 3 136.38 104.83 1.00

Asphalt Prod., Natural Gas 1 VOC Hydrogen Sulfide C3-v0 7.34E-04 7.25E-04 8.95E-04 5.82E-04 lbs/ton production 1 21.36 53.06 0.00

Asphalt Prod., Natural Gas 1 VOC Methyl Chloroform C3-v0 2.87E-06 2.83E-06 3.50E-06 2.27E-06 lbs/ton production 1 21.36 53.06 0.67

Asphalt Prod., Natural Gas 1 VOC Toluene C3-v0 4.32E-05 4.50E-05 5.31E-05 3.14E-05 lbs/ton production 1 25.40 63.09 1.00

Asphalt Prod., Natural Gas 1 VOC Xylene (Total) C3-v0 4.26E-05 4.05E-05 5.28E-05 3.43E-05 lbs/ton production 1 22.09 54.87 1.00

Asphalt Prod., Oil 1 Metals Arsenic D2-v0 3.46E-06 4.23E-06 4.54E-06 1.16E-06 lbs/ton production 3 39.33 32.88 0.42

Asphalt Prod., Oil 1 Metals Beryllium D2-v0 3.95E-07 4.23E-07 4.43E-07 2.95E-07 lbs/ton production 3 14.50 12.12 0.00

87

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Oil 1 Metals Cadmium D2-v1 7.70E-07 7.46E-07 1.89E-06 1.93E-07 lbs/ton production 3 69.07 57.75 0.31

Asphalt Prod., Oil 1 Metals Chromium (Hex) B2-v1 4.30E-07 4.97E-07 7.88E-07 8.24E-08 lbs/ton production 3 67.14 56.13 0.09

Asphalt Prod., Oil 1 Metals Chromium (Total) B2-v2 1.05E-05 9.12E-06 2.32E-05 2.82E-07 lbs/ton production 3 73.72 61.63 1.00

Asphalt Prod., Oil 1 Metals Copper D2-v0 7.19E-06 8.03E-06 1.13E-05 2.71E-06 lbs/ton production 3 39.46 32.99 1.00

Asphalt Prod., Oil 1 Metals Lead D2-v1 2.87E-06 2.11E-06 7.41E-06 7.74E-07 lbs/ton production 3 73.29 61.27 1.00

Asphalt Prod., Oil 1 Metals Manganese D2-v2 6.54E-05 4.53E-05 2.01E-04 2.78E-06 lbs/ton production 3 116.45 97.36 1.00

Asphalt Prod., Oil 1 Metals Mercury D2-v2 4.92E-06 5.37E-06 1.35E-05 2.95E-08 lbs/ton production 3 87.70 73.32 1.00

Asphalt Prod., Oil 1 Metals Nickel D2-v2 1.27E-04 1.14E-05 4.81E-04 5.16E-06 lbs/ton production 3 170.66 142.68 1.00

Asphalt Prod., Oil 1 Metals Selenium D2-v1 2.92E-06 3.53E-06 6.59E-06 1.93E-07 lbs/ton production 3 84.49 70.64 0.28

Asphalt Prod., Oil 1 Metals Zinc D2-v1 1.11E-04 3.55E-05 3.79E-04 1.55E-05 lbs/ton production 3 116.70 97.56 1.00

Asphalt Prod., Oil 1 PAH Acenaphthene A3-v0 3.06E-07 3.06E-07 3.87E-07 2.23E-07 lbs/ton production 1 26.85 66.69 1.00

Asphalt Prod., Oil 1 PAH Acenaphthylene A3-v0 5.26E-07 4.46E-07 7.91E-07 3.42E-07 lbs/ton production 1 44.58 110.75 1.00

Asphalt Prod., Oil 1 PAH Anthracene A3-v0 5.74E-08 5.65E-08 7.56E-08 4.02E-08 lbs/ton production 1 30.91 76.78 1.00

Asphalt Prod., Oil 1 PAH Benzo(a)anthracene A3-v0 1.11E-08 1.21E-08 1.26E-08 8.65E-09 lbs/ton production 1 19.27 47.88 1.00

Asphalt Prod., Oil 1 PAH Benzo(a)pyrene A3-v1 1.84E-09 8.07E-10 3.96E-09 7.44E-10 lbs/ton production 1 100.13 248.75 0.72

Asphalt Prod., Oil 1 PAH Benzo(b)fluoranthene A3-v0 2.10E-09 1.98E-09 2.38E-09 1.94E-09 lbs/ton production 1 11.66 28.96 1.00

Asphalt Prod., Oil 1 PAH Benzo(g,h,i)perylene A3-v0 1.20E-09 1.32E-09 1.37E-09 9.01E-10 lbs/ton production 1 21.64 53.76 0.75

Asphalt Prod., Oil 1 PAH Benzo(k)fluoranthene A3-v0 8.17E-10 8.07E-10 9.01E-10 7.44E-10 lbs/ton production 1 9.64 23.94 0.00

Asphalt Prod., Oil 1 PAH Chrysene A3-v0 8.17E-10 8.07E-10 9.01E-10 7.44E-10 lbs/ton production 1 9.64 23.94 0.00

Asphalt Prod., Oil 1 PAH Dibenz(a,h)anthracene A3-v0 8.17E-10 8.07E-10 9.01E-10 7.44E-10 lbs/ton production 1 9.64 23.94 0.00

Asphalt Prod., Oil 1 PAH Fluoranthene A3-v0 3.57E-08 3.39E-08 4.61E-08 2.70E-08 lbs/ton production 1 27.14 67.42 1.00

Asphalt Prod., Oil 1 PAH Fluorene A3-v0 6.58E-07 7.02E-07 8.39E-07 4.32E-07 lbs/ton production 1 31.54 78.35 1.00

Asphalt Prod., Oil 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 8.17E-10 8.07E-10 9.01E-10 7.44E-10 lbs/ton production 1 9.64 23.94 0.00

Asphalt Prod., Oil 1 PAH Naphthalene A3-v0 3.08E-05 2.98E-05 3.39E-05 2.88E-05 lbs/ton production 1 8.75 21.73 1.00

Asphalt Prod., Oil 1 PAH Phenanthrene A3-v0 6.64E-07 6.62E-07 8.83E-07 4.46E-07 lbs/ton production 1 32.86 81.64 1.00

Asphalt Prod., Oil 1 PAH Pyrene A3-v0 5.62E-08 4.52E-08 8.18E-08 4.14E-08 lbs/ton production 1 39.77 98.80 1.00

Asphalt Prod., Oil 1 VOC Benzene B2-v1 3.34E-04 4.09E-04 6.06E-04 4.69E-05 lbs/ton production 3 71.38 59.68 1.00

Asphalt Prod., Oil 1 VOC Formaldehyde B2-v1 3.92E-04 2.51E-04 1.06E-03 5.23E-05 lbs/ton production 3 96.46 80.64 1.00

88

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Asphalt Prod., Truck Load 1 VOC Hydrogen Sulfide C3-v0 1.13E-01 1.05E-01 1.34E-01 9.90E-02 lbs/ton charged 1 16.63 41.30 1.00

Battery Prod., Grids 1 Metals Arsenic A3-v0 1.13E-03 1.13E-03 1.13E-03 1.13E-03 lbs/ton processed 1 0.00 0.00 0.00

Battery Prod., Grids 1 Metals Lead C3-v0 6.59E-03 6.46E-03 7.98E-03 5.32E-03 lbs/ton processed 1 20.26 50.33 1.00

Battery Prod., Post Pour 1 Metals Lead C3-v1 8.27E-03 4.77E-03 1.77E-02 2.39E-03 lbs/MBatteries 1 99.31 246.71 1.00

Battery Prod., Strap Line 1 Metals Lead C3-v0 1.31E-02 8.43E-03 2.39E-02 7.02E-03 lbs/MBatteries 1 71.34 177.22 1.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 3.34E-10 3.28E-10 4.27E-10 2.46E-10 lbs/ton 1 27.13 67.38 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:4D Total A3-v0 3.34E-10 3.28E-10 4.27E-10 2.46E-10 lbs/ton 1 27.13 67.38 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:5D Total A3-v0 4.79E-10 3.37E-10 8.54E-10 2.46E-10 lbs/ton 1 68.34 169.77 0.59

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:6D 123478 A3-v1 1.56E-10 1.70E-10 2.70E-10 2.63E-11 lbs/ton 1 78.79 195.72 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 2.82E-10 2.63E-10 3.37E-10 2.46E-10 lbs/ton 1 17.20 42.72 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:6D Total A3-v0 2.82E-10 2.63E-10 3.37E-10 2.46E-10 lbs/ton 1 17.20 42.72 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 5.12E-10 5.03E-10 6.07E-10 4.26E-10 lbs/ton 1 17.80 44.21 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:7D Total A3-v0 4.52E-10 5.03E-10 6.07E-10 2.46E-10 lbs/ton 1 41.07 102.01 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Dioxin:8D A3-v0 6.03E-09 6.50E-09 7.42E-09 4.16E-09 lbs/ton 1 27.92 69.35 1.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:4F 2378 A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:4F Total A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:5F 12378 A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:5F 23478 A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:5F Total A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:6F 123478 A3-v0 1.71E-10 1.70E-10 1.73E-10 1.69E-10 lbs/ton 1 1.38 3.44 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:6F 123678 A3-v0 1.71E-10 1.70E-10 1.73E-10 1.69E-10 lbs/ton 1 1.38 3.44 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:6F 123789 A3-v0 2.82E-10 2.63E-10 3.37E-10 2.46E-10 lbs/ton 1 17.20 42.72 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:6F 234678 A3-v0 2.34E-10 2.63E-10 2.70E-10 1.70E-10 lbs/ton 1 23.71 58.91 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:6F Total A3-v0 2.03E-10 1.70E-10 2.70E-10 1.69E-10 lbs/ton 1 28.61 71.07 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:7F 1234678 A3-v0 2.60E-10 2.63E-10 2.70E-10 2.46E-10 lbs/ton 1 4.63 11.50 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:7F 1234789 A3-v0 3.93E-10 4.16E-10 4.27E-10 3.36E-10 lbs/ton 1 12.65 31.43 0.00

89

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:7F Total A3-v0 3.04E-10 3.28E-10 3.37E-10 2.46E-10 lbs/ton 1 16.48 40.93 0.00

Boiler, Coal/Natural Gas 1 Dioxin/Furan Furan:8F A3-v0 8.61E-10 8.54E-10 8.77E-10 8.51E-10 lbs/ton 1 1.67 4.15 0.00

Boiler, Coal/Natural Gas 1 Metals Arsenic A3-v0 4.11E-05 3.39E-05 6.12E-05 2.84E-05 lbs/ton 1 42.73 106.16 0.00

Boiler, Coal/Natural Gas 1 Metals Barium C3-v0 1.39E-03 1.65E-03 1.69E-03 8.31E-04 lbs/ton 1 34.86 86.60 0.00

Boiler, Coal/Natural Gas 1 Metals Beryllium C3-v0 2.78E-05 3.30E-05 3.36E-05 1.67E-05 lbs/ton 1 34.64 86.05 0.00

Boiler, Coal/Natural Gas 1 Metals Cadmium C3-v0 4.39E-05 4.30E-05 5.22E-05 3.65E-05 lbs/ton 1 17.96 44.61 1.00

Boiler, Coal/Natural Gas 1 Metals Chromium (Total) C3-v0 1.56E-04 1.65E-04 2.19E-04 8.31E-05 lbs/ton 1 43.98 109.25 0.65

Boiler, Coal/Natural Gas 1 Metals Cobalt C3-v0 2.78E-04 3.30E-04 3.37E-04 1.66E-04 lbs/ton 1 34.84 86.55 0.00

Boiler, Coal/Natural Gas 1 Metals Copper C3-v0 6.95E-04 8.26E-04 8.43E-04 4.15E-04 lbs/ton 1 34.86 86.59 0.00

Boiler, Coal/Natural Gas 1 Metals Lead C3-v0 2.22E-04 2.70E-04 3.14E-04 8.31E-05 lbs/ton 1 55.12 136.93 0.88

Boiler, Coal/Natural Gas 1 Metals Magnesium C3-v0 1.02E-03 1.19E-03 1.45E-03 4.15E-04 lbs/ton 1 52.85 131.30 1.00

Boiler, Coal/Natural Gas 1 Metals Manganese C3-v0 4.17E-04 4.96E-04 5.06E-04 2.49E-04 lbs/ton 1 34.87 86.62 0.00

Boiler, Coal/Natural Gas 1 Metals Mercury A3-v0 1.61E-05 1.33E-05 2.40E-05 1.09E-05 lbs/ton 1 43.48 108.00 0.00

Boiler, Coal/Natural Gas 1 Metals Nickel C3-v0 1.39E-04 1.65E-04 1.69E-04 8.31E-05 lbs/ton 1 34.81 86.48 0.00

Boiler, Coal/Natural Gas 1 Metals Selenium A3-v1 1.75E-04 2.19E-04 2.78E-04 2.84E-05 lbs/ton 1 74.56 185.22 0.95

Boiler, Coal/Natural Gas 1 Metals Zinc C3-v0 2.45E-03 2.81E-03 3.37E-03 1.16E-03 lbs/ton 1 46.90 116.50 1.00

Boiler, Coal/Natural Gas 1 PAH Acenaphthene C3-v0 8.98E-08 8.98E-08 1.10E-07 6.97E-08 lbs/ton 1 31.55 283.46 0.00

Boiler, Coal/Natural Gas 1 PAH Acenaphthylene C3-v1 6.88E-07 6.97E-07 1.16E-06 2.06E-07 lbs/ton 1 69.35 172.28 0.90

Boiler, Coal/Natural Gas 1 PAH Anthracene C3-v0 1.45E-07 1.27E-07 2.24E-07 8.32E-08 lbs/ton 1 49.79 123.70 0.00

Boiler, Coal/Natural Gas 1 PAH Benzo(a)anthracene C3-v0 7.19E-08 7.19E-08 8.76E-08 5.62E-08 lbs/ton 1 30.80 276.71 0.00

Boiler, Coal/Natural Gas 1 PAH Benzo(a)pyrene C3-v0 2.13E-07 2.19E-07 2.91E-07 1.28E-07 lbs/ton 1 38.39 95.37 0.46

Boiler, Coal/Natural Gas 1 PAH Benzo(b)fluoranthene C3-v- 1.21E-07 1.21E-07 1.21E-07 1.21E-07 lbs/ton 1 0.00 0.00 0.00

Boiler, Coal/Natural Gas 1 PAH Benzo(e)pyrene C3-v0 1.59E-07 1.84E-07 1.86E-07 1.06E-07 lbs/ton 1 28.84 71.65 0.00

Boiler, Coal/Natural Gas 1 PAH Benzo(g,h,i)perylene C3-v0 5.85E-07 5.83E-07 7.44E-07 4.27E-07 lbs/ton 1 27.09 67.30 0.00

Boiler, Coal/Natural Gas 1 PAH Benzo(k)fluoranthene C3-v0 1.54E-07 1.75E-07 1.84E-07 1.03E-07 lbs/ton 1 28.59 71.01 0.40

Boiler, Coal/Natural Gas 1 PAH Dibenz(a,h)anthracene C3-v0 8.51E-07 8.74E-07 1.09E-06 5.85E-07 lbs/ton 1 30.03 74.59 0.00

Boiler, Coal/Natural Gas 1 PAH Fluorene C3-v- 2.15E-06 2.15E-06 2.15E-06 2.15E-06 lbs/ton 1 0.00 0.00 1.00

Boiler, Coal/Natural Gas 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 5.18E-07 5.38E-07 6.57E-07 3.60E-07 lbs/ton 1 28.82 71.60 0.00

90

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Coal/Natural Gas 1 PAH Phenanthrene C3-v- 4.03E-06 4.03E-06 4.03E-06 4.03E-06 lbs/ton 1 0.00 0.00 1.00

Boiler, Coal/Natural Gas 1 SVOC 1,2-Dichlorobenzene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 SVOC 2-Chloronaphthalene C3-v0 1.15E-07 1.09E-07 1.41E-07 9.45E-08 lbs/ton 1 20.72 51.47 0.00

Boiler, Coal/Natural Gas 1 SVOC Ethylbenzene A3-v0 7.77E-05 9.31E-05 1.17E-04 2.34E-05 lbs/ton 1 62.34 154.87 1.00

Boiler, Coal/Natural Gas 1 SVOC Perylene C3-v0 2.27E-07 2.46E-07 2.85E-07 1.48E-07 lbs/ton 1 30.99 77.00 0.00

Boiler, Coal/Natural Gas 1 VOC 1,1,1-Trichloroethane A3-v1 1.59E-04 4.92E-05 3.84E-04 4.42E-05 lbs/ton 1 122.37 303.99 1.00

Boiler, Coal/Natural Gas 1 VOC 1,1,2,2-Tetrachloroethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 1,1,2-Trichloroethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 1,1-Dichloroethane A3-v1 2.30E-05 9.63E-06 5.01E-05 9.38E-06 lbs/ton 1 101.69 252.61 0.00

Boiler, Coal/Natural Gas 1 VOC 1,1-Dichloroethene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 1,2-Dichloroethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 1,2-Dichloroethene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 1,2-Dichloropropane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC 2-Chloroethyl Vinyl Ether A3-v0 2.20E-05 2.33E-05 2.34E-05 1.93E-05 lbs/ton 1 10.77 26.77 0.00

Boiler, Coal/Natural Gas 1 VOC 2-Hexanone A3-v0 3.76E-05 3.52E-05 4.28E-05 3.49E-05 lbs/ton 1 11.91 29.58 0.00

Boiler, Coal/Natural Gas 1 VOC Acetone A3-v0 2.22E-03 2.24E-03 2.30E-03 2.11E-03 lbs/ton 1 4.52 11.22 0.34

Boiler, Coal/Natural Gas 1 VOC Benzene A3-v0 9.75E-05 9.15E-05 1.10E-04 9.08E-05 lbs/ton 1 11.32 28.11 1.00

Boiler, Coal/Natural Gas 1 VOC Bromodichloromethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Bromoform A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Bromomethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Carbon disulfide A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Carbon Tetrachloride A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Chlorobenzene A3-v1 5.18E-05 4.46E-05 1.01E-04 9.63E-06 lbs/ton 1 89.25 221.72 0.00

Boiler, Coal/Natural Gas 1 VOC Chloroethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Chloroform A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Chloromethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Dibromochloromethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Dichloromethane A3-v1 3.06E-03 1.08E-03 7.53E-03 5.75E-04 lbs/ton 1 126.63 314.58 1.00

91

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Coal/Natural Gas 1 VOC Formaldehyde A3-v2 4.51E-01 2.50E-01 1.10E+00 9.33E-03 lbs/ton 1 126.38 313.95 1.00

Boiler, Coal/Natural Gas 1 VOC Methyl Ethyl Ketone A3-v0 9.45E-05 7.71E-05 1.50E-04 5.63E-05 lbs/ton 1 52.18 129.63 1.00

Boiler, Coal/Natural Gas 1 VOC Styrene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Tetrachloroethene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Toluene A3-v1 1.05E-03 3.22E-04 2.69E-03 1.45E-04 lbs/ton 1 135.03 335.44 1.00

Boiler, Coal/Natural Gas 1 VOC Trichloroethene A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Trichlorofluoromethane A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Vinyl Acetate A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Vinyl Chloride A3-v0 9.44E-06 9.38E-06 9.63E-06 9.31E-06 lbs/ton 1 1.78 4.42 0.00

Boiler, Coal/Natural Gas 1 VOC Xylene (Total) A3-v0 4.33E-04 5.10E-04 6.52E-04 1.38E-04 lbs/ton 1 61.18 151.98 1.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin/Furan:Total A3-v0 3.09E-10 3.49E-10 3.62E-10 2.18E-10 lbs/ton 1 25.72 63.89 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.53E-11 1.62E-11 1.74E-11 1.23E-11 lbs/ton 1 17.15 42.60 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:4D Total A3-v0 1.53E-11 1.62E-11 1.74E-11 1.23E-11 lbs/ton 1 17.15 42.60 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 1.52E-11 1.59E-11 2.19E-11 7.62E-12 lbs/ton 1 47.38 117.69 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:5D Total A3-v0 1.52E-11 1.59E-11 2.19E-11 7.62E-12 lbs/ton 1 47.38 117.69 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 2.30E-11 2.19E-11 2.68E-11 2.03E-11 lbs/ton 1 14.57 36.20 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 2.24E-11 2.16E-11 2.57E-11 2.00E-11 lbs/ton 1 13.16 32.70 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 2.13E-11 2.05E-11 2.46E-11 1.89E-11 lbs/ton 1 13.84 34.37 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:6D Total A3-v0 3.01E-11 2.68E-11 4.31E-11 2.03E-11 lbs/ton 1 39.08 97.07 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 6.32E-11 6.47E-11 9.40E-11 3.09E-11 lbs/ton 1 50.04 124.29 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:7D Total A3-v0 6.32E-11 6.47E-11 9.40E-11 3.09E-11 lbs/ton 1 50.04 124.29 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Dioxin:8D A3-v0 1.04E-10 1.01E-10 1.41E-10 7.11E-11 lbs/ton 1 33.66 83.61 1.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:4F 2378 A3-v0 8.67E-12 8.68E-12 9.07E-12 8.26E-12 lbs/ton 1 4.67 11.60 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:4F Total A3-v0 8.67E-12 8.68E-12 9.07E-12 8.26E-12 lbs/ton 1 4.67 11.60 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:5F 12378 A3-v0 1.14E-11 9.76E-12 1.72E-11 7.26E-12 lbs/ton 1 45.49 113.00 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:5F 23478 A3-v0 9.15E-12 9.76E-12 1.04E-11 7.26E-12 lbs/ton 1 18.24 45.30 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:5F Total A3-v0 1.14E-11 9.76E-12 1.71E-11 7.26E-12 lbs/ton 1 44.97 111.72 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:6F 123478 A3-v0 9.75E-12 8.32E-12 1.33E-11 7.62E-12 lbs/ton 1 31.75 78.86 0.00

92

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Coke/Coal 1 Dioxin/Furan Furan:6F 123678 A3-v0 8.90E-12 7.26E-12 1.22E-11 7.23E-12 lbs/ton 1 32.23 80.07 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:6F 123789 A3-v0 1.07E-11 8.71E-12 1.47E-11 8.68E-12 lbs/ton 1 32.55 80.86 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:6F 234678 A3-v0 9.26E-12 7.62E-12 1.26E-11 7.59E-12 lbs/ton 1 30.96 76.90 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:6F Total A3-v0 1.08E-11 9.07E-12 1.47E-11 8.68E-12 lbs/ton 1 31.27 77.68 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:7F 1234678 A3-v0 1.70E-11 1.52E-11 2.37E-11 1.19E-11 lbs/ton 1 35.81 88.96 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:7F 1234789 A3-v0 1.29E-11 1.37E-11 1.47E-11 1.02E-11 lbs/ton 1 18.66 46.36 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:7F Total A3-v0 1.76E-11 1.52E-11 2.37E-11 1.37E-11 lbs/ton 1 30.60 76.03 0.00

Boiler, Coke/Coal 1 Dioxin/Furan Furan:8F A3-v0 4.44E-11 3.59E-11 6.15E-11 3.59E-11 lbs/ton 1 33.19 82.44 0.00

Boiler, Coke/Coal 1 Halogens HCl A3-v0 1.47E-01 1.73E-01 1.92E-01 7.47E-02 lbs/ton 1 43.01 106.85 1.00

Boiler, Coke/Coal 1 Metals Arsenic A3-v0 7.14E-06 7.20E-06 7.35E-06 6.86E-06 lbs/ton 1 3.47 8.62 0.66

Boiler, Coke/Coal 1 Metals Beryllium A3-v0 5.20E-07 5.88E-07 6.12E-07 3.61E-07 lbs/ton 1 26.58 66.02 1.00

Boiler, Coke/Coal 1 Metals Cadmium A3-v0 7.14E-07 7.20E-07 7.35E-07 6.86E-07 lbs/ton 1 3.47 8.62 0.00

Boiler, Coke/Coal 1 Metals Chromium (Hex) A3-v0 6.42E-07 6.50E-07 7.71E-07 5.04E-07 lbs/ton 1 20.87 51.84 1.00

Boiler, Coke/Coal 1 Metals Chromium (Total) A3-v0 2.33E-05 2.31E-05 2.42E-05 2.27E-05 lbs/ton 1 3.46 8.60 1.00

Boiler, Coke/Coal 1 Metals Copper A3-v0 1.76E-05 1.65E-05 2.12E-05 1.52E-05 lbs/ton 1 18.03 44.80 1.00

Boiler, Coke/Coal 1 Metals Lead A3-v0 3.66E-06 4.32E-06 4.41E-06 2.24E-06 lbs/ton 1 33.57 83.38 0.60

Boiler, Coke/Coal 1 Metals Manganese A3-v0 5.92E-05 3.96E-05 1.14E-04 2.42E-05 lbs/ton 1 80.97 201.13 1.00

Boiler, Coke/Coal 1 Metals Mercury A3-v0 1.73E-06 1.94E-06 2.09E-06 1.16E-06 lbs/ton 1 29.10 72.29 1.00

Boiler, Coke/Coal 1 Metals Nickel A3-v0 3.92E-04 4.41E-04 4.68E-04 2.67E-04 lbs/ton 1 27.76 68.97 1.00

Boiler, Coke/Coal 1 Metals Selenium A3-v1 2.38E-05 3.48E-05 3.60E-05 7.49E-07 lbs/ton 1 83.92 208.47 0.00

Boiler, Coke/Coal 1 Metals Zinc A3-v0 4.96E-05 5.04E-05 6.61E-05 3.22E-05 lbs/ton 1 34.31 85.23 1.00

Boiler, Coke/Coal 1 PAH Acenaphthene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Acenaphthylene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Anthracene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Benzo(a)anthracene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Benzo(a)pyrene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Benzo(b)fluoranthene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Benzo(e)pyrene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

93

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Coke/Coal 1 PAH Benzo(g,h,i)perylene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Benzo(k)fluoranthene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Chrysene A3-v0 5.32E-08 5.75E-08 7.26E-08 2.94E-08 lbs/ton 1 41.18 102.29 1.00

Boiler, Coke/Coal 1 PAH Dibenz(a,h)anthracene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Fluoranthene A3-v0 4.71E-08 4.67E-08 5.82E-08 3.63E-08 lbs/ton 1 23.24 57.73 1.00

Boiler, Coke/Coal 1 PAH Fluorene A3-v0 1.39E-07 1.37E-07 1.45E-07 1.34E-07 lbs/ton 1 4.23 10.51 0.00

Boiler, Coke/Coal 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 PAH Naphthalene A3-v0 2.09E-06 2.03E-06 2.22E-06 2.01E-06 lbs/ton 1 5.41 13.45 0.00

Boiler, Coke/Coal 1 PAH Phenanthrene A3-v0 7.48E-07 7.26E-07 8.00E-07 7.19E-07 lbs/ton 1 5.99 14.89 0.00

Boiler, Coke/Coal 1 PAH Pyrene A3-v1 1.57E-07 5.09E-08 3.95E-07 2.40E-08 lbs/ton 1 132.12 328.20 0.95

Boiler, Coke/Coal 1 SVOC 2-Methylnaphthalene A3-v0 3.19E-07 3.12E-07 3.42E-07 3.02E-07 lbs/ton 1 6.49 16.13 0.00

Boiler, Coke/Coal 1 SVOC Perylene A3-v0 2.47E-08 2.41E-08 2.62E-08 2.40E-08 lbs/ton 1 5.04 12.52 0.00

Boiler, Coke/Coal 1 VOC Formaldehyde A3-v0 4.78E-03 4.82E-03 5.30E-03 4.22E-03 lbs/ton 1 11.28 28.02 0.66

Boiler, Distillate 1 PAH Acenaphthene B1-v3 2.11E-04 3.77E-05 1.13E-03 5.33E-07 lbs/Mgal 6 184.82 98.49 0.99

Boiler, Distillate 1 PAH Acenaphthylene B1-v2 6.50E-05 2.99E-05 2.38E-04 1.68E-06 lbs/Mgal 7 127.79 65.71 0.76

Boiler, Distillate 1 PAH Anthracene B1-v2 2.39E-05 1.77E-05 8.49E-05 3.56E-07 lbs/Mgal 7 96.51 47.99 0.93

Boiler, Distillate 1 PAH Benzo(a)anthracene B1-v2 1.35E-05 9.21E-06 9.93E-05 3.60E-07 lbs/Mgal 6 167.60 86.17 0.72

Boiler, Distillate 1 PAH Benzo(a)pyrene B1-v2 7.55E-06 4.59E-06 2.20E-05 3.60E-07 lbs/Mgal 7 86.63 43.08 0.09

Boiler, Distillate 1 PAH Benzo(b)fluoranthene B1-v2 6.67E-06 3.69E-06 2.11E-05 3.60E-07 lbs/Mgal 7 97.14 48.31 0.16

Boiler, Distillate 1 PAH Benzo(e)pyrene A3-v0 1.40E-05 1.40E-05 1.52E-05 1.28E-05 lbs/Mgal 1 11.97 107.56 0.00

Boiler, Distillate 1 PAH Benzo(g,h,i)perylene B1-v2 8.50E-06 6.13E-06 2.77E-05 4.62E-07 lbs/Mgal 7 93.25 43.64 0.21

Boiler, Distillate 1 PAH Benzo(k)fluoranthene B1-v3 8.31E-05 4.34E-06 7.03E-04 3.60E-07 lbs/Mgal 7 269.37 133.95 0.95

Boiler, Distillate 1 PAH Chrysene B1-v2 1.28E-05 8.56E-06 1.01E-04 3.60E-07 lbs/Mgal 6 183.62 94.41 0.77

Boiler, Distillate 1 PAH Dibenz(a,h)anthracene B1-v2 6.49E-06 4.58E-06 2.72E-05 3.43E-07 lbs/Mgal 7 114.28 53.48 0.10

Boiler, Distillate 1 PAH Fluoranthene B1-v1 3.32E-05 2.60E-05 7.12E-05 1.64E-06 lbs/Mgal 6 68.49 35.21 0.95

Boiler, Distillate 1 PAH Fluorene B1-v2 1.17E-04 1.33E-04 2.78E-04 2.78E-06 lbs/Mgal 6 70.89 37.78 0.98

Boiler, Distillate 1 PAH Indeno(1,2,3-cd)pyrene B1-v2 6.64E-06 5.82E-06 2.18E-05 3.60E-07 lbs/Mgal 7 86.38 40.43 0.16

Boiler, Distillate 1 PAH Naphthalene B1-v4 3.67E-01 9.84E-04 2.78E+00 6.98E-05 lbs/Mgal 7 246.24 115.24 1.00

94

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Distillate 1 PAH Phenanthrene B1-v2 3.72E-04 3.53E-04 9.80E-04 6.61E-06 lbs/Mgal 7 79.23 39.40 1.00

Boiler, Distillate 1 PAH Pyrene B1-v2 4.08E-05 4.40E-05 1.16E-04 9.95E-07 lbs/Mgal 6 73.28 37.68 0.83

Boiler, Distillate 1 SVOC 2-Chloronaphthalene A3-v0 1.84E-05 1.84E-05 1.86E-05 1.81E-05 lbs/Mgal 1 2.15 19.32 0.00

Boiler, Distillate 1 SVOC 2-Methylnaphthalene A3-v0 1.40E-04 1.23E-04 1.81E-04 1.17E-04 lbs/Mgal 1 24.99 62.08 0.57

Boiler, Distillate 1 SVOC Ethylbenzene C3-v0 1.49E-03 1.55E-03 1.65E-03 1.27E-03 lbs/Mgal 1 13.33 33.12 0.00

Boiler, Distillate 1 SVOC Perylene A3-v0 2.71E-05 2.71E-05 2.90E-05 2.52E-05 lbs/Mgal 1 9.88 88.74 0.00

Boiler, Distillate 1 VOC Benzene C3-v0 2.54E-03 2.62E-03 2.85E-03 2.17E-03 lbs/Mgal 1 13.62 33.84 1.00

Boiler, Distillate 1 VOC Formaldehyde B1-v4 3.49E-01 5.33E-02 1.75E+00 2.20E-04 lbs/Mgal 6 152.43 75.80 1.00

Boiler, Distillate 1 VOC Hexane C3-v0 1.21E-03 1.26E-03 1.34E-03 1.03E-03 lbs/Mgal 1 13.13 32.62 0.00

Boiler, Distillate 1 VOC Propylene C3-v0 1.71E-03 1.78E-03 1.80E-03 1.53E-03 lbs/Mgal 1 8.87 22.03 1.00

Boiler, Distillate 1 VOC Toluene C3-v0 1.50E-03 1.43E-03 1.70E-03 1.35E-03 lbs/Mgal 1 12.35 30.68 0.38

Boiler, Distillate 1 VOC Xylene (Total) C3-v0 1.49E-03 1.55E-03 1.65E-03 1.27E-03 lbs/Mgal 1 13.33 33.12 0.00

Boiler, Fuel Oil 1 Metals Arsenic C2-v1 1.06E-03 1.11E-03 2.20E-03 3.96E-04 lbs/Mgal 3 51.81 39.82 1.00

Boiler, Fuel Oil 1 Metals Beryllium C2-v1 1.48E-05 8.10E-06 4.41E-05 5.83E-06 lbs/Mgal 3 101.51 78.03 0.62

Boiler, Fuel Oil 1 Metals Cadmium C2-v1 2.23E-04 1.24E-04 7.99E-04 6.48E-05 lbs/Mgal 3 103.73 79.73 1.00

Boiler, Fuel Oil 1 Metals Chromium (Hex) A2-v1 1.81E-04 9.22E-05 5.52E-04 5.60E-05 lbs/Mgal 3 95.13 73.13 0.90

Boiler, Fuel Oil 1 Metals Chromium (Total) A2-v0 6.09E-04 5.71E-04 1.01E-03 2.16E-04 lbs/Mgal 3 40.04 30.78 1.00

Boiler, Fuel Oil 1 Metals Copper C2-v1 1.40E-03 1.47E-03 1.99E-03 3.11E-04 lbs/Mgal 3 39.86 30.64 1.00

Boiler, Fuel Oil 1 Metals Lead C2-v1 1.61E-03 1.04E-03 3.79E-03 3.69E-04 lbs/Mgal 3 69.64 53.53 1.00

Boiler, Fuel Oil 1 Metals Manganese C2-v1 1.58E-03 1.38E-03 4.99E-03 5.64E-04 lbs/Mgal 3 86.76 66.69 1.00

Boiler, Fuel Oil 1 Metals Mercury C2-v1 3.06E-03 3.56E-03 5.57E-03 6.38E-04 lbs/Mgal 3 62.32 47.91 0.00

Boiler, Fuel Oil 1 Metals Nickel C2-v2 9.75E-02 8.00E-02 1.83E-01 2.21E-03 lbs/Mgal 3 55.88 42.96 1.00

Boiler, Fuel Oil 1 Metals Selenium C2-v1 9.61E-04 6.30E-04 2.19E-03 2.50E-04 lbs/Mgal 3 69.79 53.65 0.87

Boiler, Fuel Oil 1 Metals Zinc C2-v0 1.41E-02 9.91E-03 2.70E-02 5.70E-03 lbs/Mgal 3 58.53 44.99 1.00

Boiler, Fuel Oil 1 PAH Acenaphthene C2-v2 3.11E-05 1.69E-05 9.76E-05 8.45E-07 lbs/Mgal 4 117.74 74.81 0.99

Boiler, Fuel Oil 1 PAH Acenaphthylene C2-v0 1.08E-06 1.04E-06 1.44E-06 8.41E-07 lbs/Mgal 4 19.30 12.27 0.00

Boiler, Fuel Oil 1 PAH Anthracene C2-v1 2.27E-06 1.83E-06 5.23E-06 8.45E-07 lbs/Mgal 4 68.49 43.52 0.90

Boiler, Fuel Oil 1 PAH Benzo(a)anthracene C2-v1 2.08E-06 1.05E-06 1.30E-05 8.41E-07 lbs/Mgal 4 165.71 105.29 0.52

95

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Fuel Oil 1 PAH Benzo(a)pyrene C2-v0 1.08E-06 1.04E-06 1.44E-06 8.41E-07 lbs/Mgal 4 19.30 12.27 0.00

Boiler, Fuel Oil 1 PAH Benzo(b+k)fluoranthene C2-v1 1.52E-06 1.05E-06 6.30E-06 8.41E-07 lbs/Mgal 4 99.78 63.40 0.34

Boiler, Fuel Oil 1 PAH Benzo(g,h,i)perylene C2-v0 1.29E-06 1.05E-06 3.57E-06 8.41E-07 lbs/Mgal 4 57.64 36.62 0.23

Boiler, Fuel Oil 1 PAH Chrysene C2-v0 1.14E-06 1.05E-06 1.68E-06 8.41E-07 lbs/Mgal 4 23.75 15.09 0.12

Boiler, Fuel Oil 1 PAH Dibenz(a,h)anthracene C2-v0 1.10E-06 1.05E-06 1.44E-06 8.41E-07 lbs/Mgal 4 19.23 12.22 0.09

Boiler, Fuel Oil 1 PAH Fluoranthene C2-v1 3.24E-06 1.66E-06 1.81E-05 8.45E-07 lbs/Mgal 4 148.20 94.16 0.87

Boiler, Fuel Oil 1 PAH Fluorene C2-v1 3.75E-06 3.40E-06 1.34E-05 8.41E-07 lbs/Mgal 4 95.91 60.94 0.90

Boiler, Fuel Oil 1 PAH Indeno(1,2,3-cd)pyrene C2-v0 1.26E-06 1.05E-06 3.19E-06 8.41E-07 lbs/Mgal 4 50.84 32.30 0.21

Boiler, Fuel Oil 1 PAH Naphthalene C2-v1 3.21E-03 1.95E-03 8.49E-03 5.66E-04 lbs/Mgal 4 88.66 56.33 1.00

Boiler, Fuel Oil 1 PAH Phenanthrene C2-v1 7.47E-06 6.32E-06 2.90E-05 8.45E-07 lbs/Mgal 4 102.17 64.92 0.97

Boiler, Fuel Oil 1 PAH Pyrene C2-v1 2.50E-06 1.33E-06 1.34E-05 8.45E-07 lbs/Mgal 4 141.21 89.72 0.78

Boiler, Fuel Oil 1 SVOC Benzaldehyde C3-v0 4.14E-03 5.10E-03 5.25E-03 2.06E-03 lbs/Mgal 1 43.45 107.92 0.00

Boiler, Fuel Oil 1 VOC Acetaldehyde C3-v0 5.33E-03 2.93E-03 1.02E-02 2.84E-03 lbs/Mgal 1 79.42 197.30 0.82

Boiler, Fuel Oil 1 VOC Benzene C2-v0 3.49E-04 3.63E-04 3.69E-04 3.15E-04 lbs/Mgal 3 7.29 5.61 0.00

Boiler, Fuel Oil 1 VOC Formaldehyde B2-v2 4.90E-02 4.46E-02 1.50E-01 2.58E-03 lbs/Mgal 3 104.74 80.51 1.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:4D 2378 C3-v0 6.33E-10 5.71E-10 7.83E-10 5.46E-10 lbs/Mgal 1 20.50 50.93 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:4D Total A3-v0 5.87E-09 7.14E-09 7.59E-09 2.87E-09 lbs/Mgal 1 44.44 110.39 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:5D 12378 C3-v0 3.68E-10 2.73E-10 5.71E-10 2.61E-10 lbs/Mgal 1 47.67 118.42 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:5D Total A3-v0 1.19E-08 1.28E-08 1.48E-08 8.11E-09 lbs/Mgal 1 28.95 71.92 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:6D 123478 C3-v0 3.68E-10 2.73E-10 5.71E-10 2.61E-10 lbs/Mgal 1 47.67 118.42 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:6D 123678 C3-v0 3.68E-10 2.73E-10 5.71E-10 2.61E-10 lbs/Mgal 1 47.67 118.42 0.25

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:6D 123789 C3-v0 3.68E-10 2.73E-10 5.71E-10 2.61E-10 lbs/Mgal 1 47.67 118.42 0.25

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:6D Total A3-v0 1.47E-08 1.68E-08 1.87E-08 8.75E-09 lbs/Mgal 1 35.75 88.81 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:7D 1234678 C3-v0 3.12E-09 2.86E-09 5.19E-09 1.30E-09 lbs/Mgal 1 62.77 155.93 1.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:7D Total A3-v0 5.98E-09 4.67E-09 8.61E-09 4.65E-09 lbs/Mgal 1 38.15 94.77 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Dioxin:8D C3-v1 7.50E-08 8.28E-08 1.23E-07 1.93E-08 lbs/Mgal 1 69.66 173.05 1.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:4F 2378 C3-v0 8.16E-10 7.83E-10 1.09E-09 5.71E-10 lbs/Mgal 1 32.18 79.95 1.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:4F Total A3-v0 3.26E-09 2.76E-09 4.49E-09 2.53E-09 lbs/Mgal 1 32.95 81.86 0.00

96

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Fuel Oil 2 Dioxin/Furan Furan:5F 12378 C3-v0 4.59E-10 5.46E-10 5.71E-10 2.61E-10 lbs/Mgal 1 37.52 93.21 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:5F 23478 C3-v0 4.59E-10 5.46E-10 5.71E-10 2.61E-10 lbs/Mgal 1 37.52 93.21 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:5F Total A3-v0 7.02E-09 5.38E-09 1.11E-08 4.60E-09 lbs/Mgal 1 50.45 125.32 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:6F 123478 C3-v0 3.64E-10 2.86E-10 5.46E-10 2.61E-10 lbs/Mgal 1 43.44 107.90 0.50

Boiler, Fuel Oil 2 Dioxin/Furan Furan:6F 123678 C3-v0 2.73E-10 2.73E-10 2.86E-10 2.61E-10 lbs/Mgal 1 4.51 11.20 0.33

Boiler, Fuel Oil 2 Dioxin/Furan Furan:6F 123789 C3-v0 3.68E-10 2.73E-10 5.71E-10 2.61E-10 lbs/Mgal 1 47.67 118.42 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:6F 234678 C3-v0 5.51E-10 5.71E-10 8.20E-10 2.61E-10 lbs/Mgal 1 50.85 126.32 0.50

Boiler, Fuel Oil 2 Dioxin/Furan Furan:6F Total A3-v1 6.51E-09 5.48E-09 1.32E-08 8.65E-10 lbs/Mgal 1 95.60 237.47 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:7F 1234678 C3-v0 1.44E-09 1.14E-09 2.09E-09 1.09E-09 lbs/Mgal 1 38.89 96.62 1.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:7F 1234789 C3-v0 4.64E-10 2.73E-10 8.57E-10 2.61E-10 lbs/Mgal 1 73.43 182.42 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:7F Total A3-v0 3.39E-09 3.19E-09 3.85E-09 3.14E-09 lbs/Mgal 1 11.79 29.30 0.00

Boiler, Fuel Oil 2 Dioxin/Furan Furan:8F C3-v0 7.15E-09 7.14E-09 1.04E-08 3.91E-09 lbs/Mgal 1 45.27 112.46 1.00

Boiler, Fuel Oil 2 Metals Antimony C3-v1 1.09E-03 1.05E-03 2.21E-03 9.53E-05 lbs/Mgal 2 66.08 69.35 0.75

Boiler, Fuel Oil 2 Metals Arsenic C1-v2 5.89E-04 1.85E-04 3.64E-03 1.67E-05 lbs/Mgal 8 142.64 60.23 0.53

Boiler, Fuel Oil 2 Metals Barium C3-v1 1.51E-02 1.82E-02 2.80E-02 9.29E-04 lbs/Mgal 2 76.27 80.04 1.00

Boiler, Fuel Oil 2 Metals Beryllium C1-v2 4.20E-04 3.14E-05 3.35E-03 7.83E-06 lbs/Mgal 8 245.64 106.22 0.94

Boiler, Fuel Oil 2 Metals Cadmium C1-v4 3.43E-03 2.78E-04 5.02E-02 1.70E-06 lbs/Mgal 8 313.81 139.13 0.95

Boiler, Fuel Oil 2 Metals Chromium (Hex) B1-v2 3.50E-04 2.05E-04 1.21E-03 1.86E-05 lbs/Mgal 6 109.67 54.54 0.16

Boiler, Fuel Oil 2 Metals Chromium (Total) B1-v3 1.64E-03 8.97E-04 6.85E-03 3.75E-06 lbs/Mgal 8 119.71 50.55 0.84

Boiler, Fuel Oil 2 Metals Cobalt A3-v0 2.24E-03 2.51E-03 3.33E-03 8.77E-04 lbs/Mgal 1 55.77 138.55 1.00

Boiler, Fuel Oil 2 Metals Copper C1-v1 4.37E-03 1.97E-03 1.95E-02 8.92E-04 lbs/Mgal 8 107.52 45.40 1.00

Boiler, Fuel Oil 2 Metals Lead C1-v3 4.49E-03 6.41E-04 3.62E-02 5.00E-05 lbs/Mgal 8 223.04 94.18 0.87

Boiler, Fuel Oil 2 Metals Manganese C1-v3 4.38E-02 1.53E-03 5.47E-01 1.80E-04 lbs/Mgal 8 317.20 133.94 1.00

Boiler, Fuel Oil 2 Metals Mercury C1-v2 1.93E-04 9.01E-05 1.43E-03 5.22E-06 lbs/Mgal 8 161.66 68.26 0.67

Boiler, Fuel Oil 2 Metals Molybdenum A3-v0 5.13E-03 4.49E-03 7.05E-03 3.86E-03 lbs/Mgal 1 32.98 81.93 1.00

Boiler, Fuel Oil 2 Metals Nickel C1-v3 1.30E-01 2.51E-02 4.70E-01 1.62E-04 lbs/Mgal 8 123.42 52.12 0.99

Boiler, Fuel Oil 2 Metals Phosphorus D3-v0 2.86E-02 2.51E-02 3.74E-02 2.33E-02 lbs/Mgal 1 26.90 66.81 1.00

Boiler, Fuel Oil 2 Metals Selenium C1-v3 3.23E-03 4.00E-04 4.49E-02 2.28E-05 lbs/Mgal 8 285.39 120.51 0.64

97

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Fuel Oil 2 Metals Silver C3-v1 8.09E-04 6.49E-04 1.85E-03 1.49E-04 lbs/Mgal 2 89.08 93.48 0.94

Boiler, Fuel Oil 2 Metals Thallium C3-v1 9.91E-04 1.14E-03 1.86E-03 9.76E-05 lbs/Mgal 2 78.56 82.45 0.00

Boiler, Fuel Oil 2 Metals Vanadium A3-v0 7.68E-02 9.35E-02 1.13E-01 2.41E-02 lbs/Mgal 1 60.74 150.89 1.00

Boiler, Fuel Oil 2 Metals Zinc C1-v3 8.66E-02 2.05E-02 1.09E+00 7.17E-04 lbs/Mgal 8 262.73 110.94 1.00

Boiler, Fuel Oil 2 PAH Acenaphthene B1-v2 2.30E-05 1.95E-06 8.51E-05 3.34E-07 lbs/Mgal 9 137.19 54.27 0.04

Boiler, Fuel Oil 2 PAH Acenaphthylene B1-v3 3.13E-05 1.98E-06 1.83E-04 3.80E-08 lbs/Mgal 9 138.96 54.97 0.24

Boiler, Fuel Oil 2 PAH Anthracene B1-v3 2.32E-05 1.50E-06 8.51E-05 1.85E-08 lbs/Mgal 9 136.48 53.99 0.04

Boiler, Fuel Oil 2 PAH Benzo(a)anthracene B1-v4 2.24E-05 1.26E-06 8.51E-05 5.80E-09 lbs/Mgal 9 142.98 56.56 0.01

Boiler, Fuel Oil 2 PAH Benzo(a)pyrene B1-v3 2.50E-05 2.37E-06 8.51E-05 2.60E-08 lbs/Mgal 9 124.08 49.09 0.11

Boiler, Fuel Oil 2 PAH Benzo(b)fluoranthene B1-v2 2.93E-05 3.46E-06 8.51E-05 3.34E-07 lbs/Mgal 7 113.75 51.78 0.03

Boiler, Fuel Oil 2 PAH Benzo(b+k)fluoranthene C3-v0 1.60E-06 1.11E-06 4.15E-06 8.46E-07 lbs/Mgal 2 80.01 83.96 0.43

Boiler, Fuel Oil 2 PAH Benzo(e)pyrene C3-v1 9.40E-07 7.21E-07 2.66E-06 1.28E-07 lbs/Mgal 2 99.48 104.40 0.00

Boiler, Fuel Oil 2 PAH Benzo(g,h,i)perylene B1-v3 2.29E-05 2.02E-06 8.51E-05 1.45E-07 lbs/Mgal 9 138.79 54.90 0.02

Boiler, Fuel Oil 2 PAH Benzo(k)fluoranthene B1-v4 2.83E-05 7.58E-07 8.51E-05 2.90E-09 lbs/Mgal 7 120.61 54.90 0.00

Boiler, Fuel Oil 2 PAH Chrysene B1-v2 2.56E-05 5.87E-06 8.51E-05 5.45E-07 lbs/Mgal 9 119.24 47.17 0.13

Boiler, Fuel Oil 2 PAH Dibenz(a,h)anthracene B1-v2 2.28E-05 1.50E-06 8.51E-05 2.07E-07 lbs/Mgal 9 139.32 55.11 0.02

Boiler, Fuel Oil 2 PAH Fluoranthene B1-v2 2.78E-05 1.49E-05 9.64E-05 8.46E-07 lbs/Mgal 9 110.81 43.83 0.27

Boiler, Fuel Oil 2 PAH Fluorene B1-v2 3.18E-05 8.18E-06 8.59E-05 8.93E-07 lbs/Mgal 9 104.18 41.21 0.31

Boiler, Fuel Oil 2 PAH Indeno(1,2,3-cd)pyrene B1-v3 2.25E-05 1.26E-06 8.51E-05 1.52E-07 lbs/Mgal 9 141.68 56.05 0.01

Boiler, Fuel Oil 2 PAH Naphthalene B1-v4 4.95E-03 1.28E-04 5.09E-02 8.76E-06 lbs/Mgal 9 271.16 107.27 1.00

Boiler, Fuel Oil 2 PAH Phenanthrene B1-v2 4.38E-05 1.99E-05 3.46E-04 1.94E-06 lbs/Mgal 9 152.14 60.19 0.57

Boiler, Fuel Oil 2 PAH Pyrene B1-v3 2.35E-05 1.92E-06 8.51E-05 1.57E-07 lbs/Mgal 9 133.76 52.91 0.05

Boiler, Fuel Oil 2 SVOC 2-Chloronaphthalene C3-v1 1.53E-07 1.27E-07 3.99E-07 1.63E-08 lbs/Mgal 2 101.95 106.99 0.00

Boiler, Fuel Oil 2 SVOC 2-Methylnaphthalene C3-v1 7.99E-05 5.49E-05 1.94E-04 9.76E-06 lbs/Mgal 2 102.17 107.22 1.00

Boiler, Fuel Oil 2 SVOC Ethylbenzene A3-v1 1.42E-03 1.81E-03 2.14E-03 3.11E-04 lbs/Mgal 1 68.59 170.39 1.00

Boiler, Fuel Oil 2 SVOC Perylene C3-v2 5.13E-07 5.42E-08 2.68E-06 3.77E-08 lbs/Mgal 2 206.85 217.07 0.00

Boiler, Fuel Oil 2 VOC 1,3-Butadiene B3-v1 6.17E-03 5.97E-03 1.18E-02 8.95E-04 lbs/Mgal 2 93.74 98.38 0.00

Boiler, Fuel Oil 2 VOC Acetaldehyde A2-v1 2.31E-03 1.31E-03 5.20E-03 2.80E-04 lbs/Mgal 3 92.98 71.47 0.22

98

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Fuel Oil 2 VOC Acrolein A3-v0 3.52E-03 3.82E-03 5.20E-03 1.43E-03 lbs/Mgal 2 46.55 48.85 0.00

Boiler, Fuel Oil 2 VOC Benzene B1-v3 3.32E-02 4.72E-03 5.17E-01 4.26E-04 lbs/Mgal 8 305.12 123.24 0.95

Boiler, Fuel Oil 2 VOC Chloroform A3-v0 4.96E-03 5.00E-03 5.10E-03 4.78E-03 lbs/Mgal 1 3.26 8.11 0.00

Boiler, Fuel Oil 2 VOC Formaldehyde A1-v3 5.25E-02 7.13E-03 4.92E-01 1.48E-04 lbs/Mgal 7 229.86 104.63 0.96

Boiler, Fuel Oil 2 VOC Propylene A3-v0 2.19E-02 2.21E-02 2.25E-02 2.11E-02 lbs/Mgal 1 3.26 8.11 0.00

Boiler, Fuel Oil 2 VOC Toluene A3-v0 7.30E-03 5.85E-03 1.23E-02 4.68E-03 lbs/Mgal 2 40.73 42.74 0.61

Boiler, Fuel Oil 2 VOC Xylene (Total) A3-v0 9.28E-03 1.09E-02 1.14E-02 2.42E-03 lbs/Mgal 2 37.75 39.62 0.41

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:4D 2378 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:4D Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:5D 12378 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:5D Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:6D 123678 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:6D Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:7D 1234678 C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:7D Total C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Dioxin:8D C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:4F 2378 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:4F Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:5F 12378 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:5F Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:6F 123678 C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:6F Total C3-v0 6.68E-07 6.43E-07 7.27E-07 6.34E-07 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:7F 1234678 C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:7F Total C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Dioxin/Furan Furan:8F C3-v0 1.34E-06 1.29E-06 1.45E-06 1.27E-06 lbs/MMcf 1 7.73 19.20 0.00

Boiler, Landfill Gas 1 Metals Arsenic D3-v0 3.62E-03 3.70E-03 3.94E-03 3.22E-03 lbs/MMcf 1 10.15 25.22 1.00

Boiler, Landfill Gas 1 Metals Beryllium D3-v0 5.33E-04 2.56E-04 1.10E-03 2.43E-04 lbs/MMcf 1 92.06 228.68 0.00

Boiler, Landfill Gas 1 Metals Cadmium D3-v0 5.43E-03 6.42E-03 6.70E-03 3.18E-03 lbs/MMcf 1 35.96 89.34 1.00

99

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Landfill Gas 1 Metals Chromium (Hex) C3-v0 5.20E-04 5.75E-04 7.14E-04 2.71E-04 lbs/MMcf 1 43.50 108.06 0.54

Boiler, Landfill Gas 1 Metals Chromium (Total) D3-v0 3.99E-02 3.53E-02 5.76E-02 2.68E-02 lbs/MMcf 1 39.86 99.01 1.00

Boiler, Landfill Gas 1 Metals Copper D3-v0 6.93E-03 7.22E-03 1.11E-02 2.53E-03 lbs/MMcf 1 61.58 152.96 1.00

Boiler, Landfill Gas 1 Metals Lead D3-v0 5.62E-03 5.71E-03 6.85E-03 4.30E-03 lbs/MMcf 1 22.68 56.35 1.00

Boiler, Landfill Gas 1 Metals Manganese D3-v1 2.06E-01 1.74E-01 3.79E-01 6.62E-02 lbs/MMcf 1 76.90 191.03 1.00

Boiler, Landfill Gas 1 Metals Mercury D3-v0 6.95E-05 6.93E-05 7.86E-05 6.06E-05 lbs/MMcf 1 12.89 32.03 1.00

Boiler, Landfill Gas 1 Metals Nickel D3-v0 6.85E-02 5.29E-02 1.15E-01 3.74E-02 lbs/MMcf 1 60.16 149.45 1.00

Boiler, Landfill Gas 1 Metals Selenium D3-v0 4.95E-04 4.97E-04 5.08E-04 4.81E-04 lbs/MMcf 1 2.73 6.79 0.00

Boiler, Landfill Gas 1 Metals Zinc D3-v0 8.32E-02 8.38E-02 8.84E-02 7.74E-02 lbs/MMcf 1 6.67 16.57 1.00

Boiler, Landfill Gas 1 PAH Acenaphthene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Acenaphthylene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Anthracene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Benzo(a)anthracene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Benzo(a)pyrene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Benzo(b)fluoranthene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Benzo(g,h,i)perylene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Benzo(k)fluoranthene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Chrysene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Dibenz(a,h)anthracene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Fluoranthene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Fluorene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Naphthalene A3-v0 2.17E-01 2.16E-01 2.59E-01 1.76E-01 lbs/MMcf 1 19.13 47.53 1.00

Boiler, Landfill Gas 1 PAH Phenanthrene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 PAH Pyrene A3-v0 4.11E-04 4.15E-04 4.19E-04 4.00E-04 lbs/MMcf 1 2.44 6.06 0.00

Boiler, Landfill Gas 1 VOC Ammonia E3-v0 2.25E+00 2.21E+00 2.35E+00 2.19E+00 lbs/MMcf 1 3.67 9.12 0.00

Boiler, Landfill Gas 1 VOC Formaldehyde C3-v0 1.25E-01 1.22E-01 1.34E-01 1.19E-01 lbs/MMcf 1 6.33 15.72 1.00

Boiler, Natural Gas 1 SVOC Benzaldehyde C3-v0 1.64E-02 1.57E-02 2.72E-02 6.40E-03 lbs/MMcf 1 63.37 157.41 0.00

100

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Natural Gas 1 VOC Acetaldehyde C3-v0 8.87E-03 8.47E-03 1.47E-02 3.46E-03 lbs/MMcf 1 63.37 157.41 0.00

Boiler, Natural Gas 1 VOC Benzene C2-v0 4.31E-03 2.15E-03 8.70E-03 2.07E-03 lbs/MMcf 3 76.41 58.73 0.00

Boiler, Natural Gas 1 VOC Formaldehyde B2-v2 2.21E-01 6.96E-02 6.72E-01 1.22E-02 lbs/MMcf 3 126.05 96.89 1.00

Boiler, Ref. Gas 1 Metals Arsenic D3-v1 7.04E-04 7.65E-04 1.13E-03 2.11E-04 lbs/MMcf 1 66.10 164.21 1.00

Boiler, Ref. Gas 1 Metals Beryllium D3-v0 1.55E-04 1.55E-04 1.56E-04 1.53E-04 lbs/MMcf 1 1.35 12.10 1.00

Boiler, Ref. Gas 1 Metals Cadmium D3-v0 2.38E-03 2.05E-03 3.13E-03 1.98E-03 lbs/MMcf 1 27.01 67.10 1.00

Boiler, Ref. Gas 1 Metals Chromium (Hex) C3-v0 7.70E-03 7.56E-03 1.09E-02 4.67E-03 lbs/MMcf 1 40.17 99.78 0.00

Boiler, Ref. Gas 1 Metals Chromium (Total) C3-v1 1.28E-02 5.43E-03 3.08E-02 2.16E-03 lbs/MMcf 1 122.51 304.34 1.00

Boiler, Ref. Gas 1 Metals Copper D3-v0 6.30E-03 6.30E-03 7.71E-03 4.89E-03 lbs/MMcf 1 31.59 283.84 1.00

Boiler, Ref. Gas 1 Metals Lead D3-v0 2.42E-03 2.42E-03 2.49E-03 2.36E-03 lbs/MMcf 1 3.87 34.76 1.00

Boiler, Ref. Gas 1 Metals Manganese D3-v0 2.39E-03 2.39E-03 3.14E-03 1.64E-03 lbs/MMcf 1 44.52 400.01 1.00

Boiler, Ref. Gas 1 Metals Mercury D3-v0 3.23E-04 3.18E-04 3.82E-04 2.70E-04 lbs/MMcf 1 17.33 43.04 0.00

Boiler, Ref. Gas 1 Metals Nickel D3-v0 5.59E-03 5.59E-03 7.03E-03 4.16E-03 lbs/MMcf 1 36.33 326.44 1.00

Boiler, Ref. Gas 1 Metals Selenium D3-v0 2.06E-03 2.36E-03 2.83E-03 9.79E-04 lbs/MMcf 1 46.79 116.23 0.16

Boiler, Ref. Gas 1 Metals Zinc D3-v2 3.42E+00 3.82E-01 9.78E+00 9.27E-02 lbs/MMcf 1 161.24 400.53 1.00

Boiler, Ref. Gas 1 PAH Acenaphthene A3-v0 5.88E-06 5.75E-06 6.47E-06 5.44E-06 lbs/MMcf 1 8.97 22.29 0.37

Boiler, Ref. Gas 1 PAH Acenaphthylene A3-v0 2.56E-06 2.59E-06 2.59E-06 2.50E-06 lbs/MMcf 1 2.04 5.07 0.00

Boiler, Ref. Gas 1 PAH Anthracene A3-v1 2.28E-05 2.50E-05 3.89E-05 4.40E-06 lbs/MMcf 1 76.23 189.36 1.00

Boiler, Ref. Gas 1 PAH Benzo(a)anthracene A3-v0 1.83E-05 1.79E-05 2.46E-05 1.25E-05 lbs/MMcf 1 33.08 82.19 1.00

Boiler, Ref. Gas 1 PAH Benzo(a)pyrene A3-v0 3.42E-06 3.37E-06 4.40E-06 2.50E-06 lbs/MMcf 1 27.72 68.85 0.76

Boiler, Ref. Gas 1 PAH Benzo(b)fluoranthene A3-v0 6.76E-06 7.24E-06 8.28E-06 4.75E-06 lbs/MMcf 1 26.90 66.83 1.00

Boiler, Ref. Gas 1 PAH Benzo(g,h,i)perylene A3-v0 3.85E-06 3.89E-06 5.17E-06 2.50E-06 lbs/MMcf 1 34.64 86.06 0.78

Boiler, Ref. Gas 1 PAH Benzo(k)fluoranthene A3-v0 2.56E-06 2.59E-06 2.59E-06 2.50E-06 lbs/MMcf 1 2.04 5.07 0.00

Boiler, Ref. Gas 1 PAH Chrysene A3-v0 3.42E-06 2.59E-06 5.17E-06 2.50E-06 lbs/MMcf 1 44.30 110.04 0.50

Boiler, Ref. Gas 1 PAH Dibenz(a,h)anthracene A3-v0 2.56E-06 2.59E-06 2.59E-06 2.50E-06 lbs/MMcf 1 2.04 5.07 0.00

Boiler, Ref. Gas 1 PAH Fluoranthene A3-v0 4.25E-05 3.10E-05 7.24E-05 2.40E-05 lbs/MMcf 1 61.63 153.10 1.00

Boiler, Ref. Gas 1 PAH Fluorene A3-v0 9.78E-06 5.75E-06 1.82E-05 5.44E-06 lbs/MMcf 1 74.23 184.40 1.00

Boiler, Ref. Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.56E-06 2.59E-06 2.59E-06 2.50E-06 lbs/MMcf 1 2.04 5.07 0.00

101

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Ref. Gas 1 PAH Naphthalene A3-v0 2.06E-04 1.94E-04 2.40E-04 1.85E-04 lbs/MMcf 1 14.51 36.05 1.00

Boiler, Ref. Gas 1 PAH Phenanthrene A3-v0 5.64E-05 4.49E-05 8.80E-05 3.62E-05 lbs/MMcf 1 49.24 122.32 1.00

Boiler, Ref. Gas 1 PAH Pyrene A3-v0 5.98E-05 5.17E-05 8.28E-05 4.49E-05 lbs/MMcf 1 33.82 84.01 1.00

Boiler, Ref. Gas 1 SVOC Phenol C2-v1 2.18E-03 8.64E-04 5.66E-03 7.28E-04 lbs/MMcf 4 95.89 60.93 0.85

Boiler, Ref. Gas 1 VOC Acetaldehyde C1-v3 3.97E-03 2.43E-03 1.21E-02 4.92E-06 lbs/MMcf 5 100.80 55.82 1.00

Boiler, Ref. Gas 1 VOC Benzene C1-v2 2.06E-01 6.24E-02 1.40E+00 3.39E-03 lbs/MMcf 5 180.67 96.27 0.80

Boiler, Ref. Gas 1 VOC Formaldehyde C1-v1 1.60E-02 1.41E-02 4.14E-02 3.24E-03 lbs/MMcf 5 62.29 34.50 1.00

Boiler, Ref. Gas 1 VOC Hydrogen Sulfide A1-v1 2.74E-01 2.37E-01 7.15E-01 5.94E-02 lbs/MMcf 5 89.81 47.85 0.00

Boiler, Ref. Gas 1 VOC Toluene E2-v2 8.40E-01 8.35E-02 5.00E+00 4.14E-02 lbs/MMcf 3 189.87 145.94 0.97

Boiler, Ref. Gas 2 Halogens HCl C3-v1 1.60E+00 2.18E+00 2.33E+00 2.83E-01 lbs/MMcf 1 71.40 177.37 0.00

Boiler, Ref. Gas 2 Metals Arsenic A3-v1 3.57E-03 3.13E-03 6.82E-03 7.77E-04 lbs/MMcf 1 85.21 211.66 0.71

Boiler, Ref. Gas 2 Metals Beryllium A3-v0 2.60E-04 2.49E-04 3.18E-04 2.13E-04 lbs/MMcf 1 20.60 51.18 0.00

Boiler, Ref. Gas 2 Metals Cadmium A3-v0 6.60E-04 6.32E-04 8.08E-04 5.40E-04 lbs/MMcf 1 20.62 51.22 0.00

Boiler, Ref. Gas 2 Metals Chromium (Hex) C3-v0 2.38E-04 2.36E-04 3.11E-04 1.67E-04 lbs/MMcf 1 30.14 74.88 0.00

Boiler, Ref. Gas 2 Metals Chromium (Total) C3-v0 2.46E-03 2.50E-03 2.52E-03 2.37E-03 lbs/MMcf 1 3.48 8.63 0.34

Boiler, Ref. Gas 2 Metals Copper A3-v1 5.30E-03 2.49E-03 1.13E-02 2.13E-03 lbs/MMcf 1 97.81 242.98 0.71

Boiler, Ref. Gas 2 Metals Lead A3-v1 3.01E-03 7.51E-04 7.73E-03 5.40E-04 lbs/MMcf 1 136.07 338.03 0.94

Boiler, Ref. Gas 2 Metals Manganese A3-v2 1.43E-01 3.23E-02 3.95E-01 1.08E-03 lbs/MMcf 1 153.34 380.92 1.00

Boiler, Ref. Gas 2 Metals Mercury A3-v0 1.10E-03 1.17E-03 1.35E-03 7.84E-04 lbs/MMcf 1 26.25 65.20 0.00

Boiler, Ref. Gas 2 Metals Nickel A3-v1 1.97E-02 5.02E-03 4.97E-02 4.29E-03 lbs/MMcf 1 132.25 328.53 0.84

Boiler, Ref. Gas 2 Metals Selenium A3-v2 3.30E-01 3.52E-01 6.27E-01 1.22E-02 lbs/MMcf 1 93.23 231.59 1.00

Boiler, Ref. Gas 2 Metals Zinc A3-v1 9.89E-02 1.27E-02 2.78E-01 6.05E-03 lbs/MMcf 1 156.80 389.52 1.00

Boiler, Ref. Gas 2 PAH Acenaphthene A3-v0 1.23E-05 1.49E-05 1.73E-05 4.77E-06 lbs/MMcf 1 53.90 133.88 1.00

Boiler, Ref. Gas 2 PAH Acenaphthylene A3-v1 1.42E-04 1.97E-04 2.23E-04 5.58E-06 lbs/MMcf 1 83.68 207.88 1.00

Boiler, Ref. Gas 2 PAH Anthracene A3-v0 3.49E-05 3.83E-05 4.84E-05 1.79E-05 lbs/MMcf 1 44.52 110.60 1.00

Boiler, Ref. Gas 2 PAH Benzo(a)anthracene A3-v1 1.07E-05 4.42E-06 2.51E-05 2.45E-06 lbs/MMcf 1 117.69 292.36 1.00

Boiler, Ref. Gas 2 PAH Benzo(a)pyrene A3-v0 2.09E-06 2.01E-06 2.27E-06 1.99E-06 lbs/MMcf 1 7.52 18.69 0.00

Boiler, Ref. Gas 2 PAH Benzo(b)fluoranthene A3-v1 1.54E-04 1.25E-04 3.27E-04 9.54E-06 lbs/MMcf 1 104.55 259.72 1.00

102

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Ref. Gas 2 PAH Benzo(e)pyrene A3-v1 2.13E-05 1.77E-05 4.38E-05 2.32E-06 lbs/MMcf 1 98.62 244.99 1.00

Boiler, Ref. Gas 2 PAH Benzo(g,h,i)perylene A3-v0 2.09E-06 2.01E-06 2.27E-06 1.99E-06 lbs/MMcf 1 7.52 18.69 0.00

Boiler, Ref. Gas 2 PAH Benzo(k)fluoranthene A3-v1 3.05E-05 2.94E-05 5.97E-05 2.27E-06 lbs/MMcf 1 94.28 234.20 0.98

Boiler, Ref. Gas 2 PAH Chrysene A3-v1 9.72E-05 6.03E-05 2.14E-04 1.73E-05 lbs/MMcf 1 106.42 264.36 1.00

Boiler, Ref. Gas 2 PAH Dibenz(a,h)anthracene A3-v0 3.02E-06 2.27E-06 4.77E-06 2.01E-06 lbs/MMcf 1 50.49 125.42 0.53

Boiler, Ref. Gas 2 PAH Fluoranthene A3-v0 1.52E-04 1.41E-04 1.83E-04 1.32E-04 lbs/MMcf 1 18.03 44.79 1.00

Boiler, Ref. Gas 2 PAH Fluorene A3-v1 8.29E-05 1.05E-04 1.23E-04 2.14E-05 lbs/MMcf 1 65.17 161.89 1.00

Boiler, Ref. Gas 2 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.86E-06 3.15E-06 9.16E-06 2.27E-06 lbs/MMcf 1 77.12 191.56 0.84

Boiler, Ref. Gas 2 PAH Naphthalene A3-v0 1.55E-03 1.68E-03 1.77E-03 1.19E-03 lbs/MMcf 1 20.04 49.79 0.74

Boiler, Ref. Gas 2 PAH Phenanthrene A3-v0 3.06E-04 3.74E-04 4.08E-04 1.35E-04 lbs/MMcf 1 48.65 120.86 1.00

Boiler, Ref. Gas 2 PAH Pyrene A3-v0 6.66E-05 6.38E-05 7.24E-05 6.36E-05 lbs/MMcf 1 7.59 18.86 1.00

Boiler, Ref. Gas 2 SVOC 2-Methylnaphthalene A3-v0 1.30E-04 1.33E-04 1.55E-04 1.03E-04 lbs/MMcf 1 19.68 48.88 0.74

Boiler, Ref. Gas 2 SVOC Ethylbenzene A3-v0 1.14E-01 1.10E-01 1.21E-01 1.10E-01 lbs/MMcf 1 5.15 12.78 0.00

Boiler, Ref. Gas 2 SVOC Perylene A3-v0 2.09E-06 2.01E-06 2.27E-06 1.99E-06 lbs/MMcf 1 7.52 18.69 0.00

Boiler, Ref. Gas 2 SVOC Phenol A3-v0 2.63E-03 2.61E-03 2.96E-03 2.30E-03 lbs/MMcf 1 12.47 30.97 1.00

Boiler, Ref. Gas 2 VOC 1,1,1-Trichloroethane A3-v0 6.39E-02 6.81E-02 6.81E-02 5.56E-02 lbs/MMcf 1 11.32 28.12 0.00

Boiler, Ref. Gas 2 VOC 1,2-Dichloroethane A3-v0 2.03E+00 2.16E+00 2.16E+00 1.77E+00 lbs/MMcf 1 11.20 27.83 0.00

Boiler, Ref. Gas 2 VOC Acetaldehyde A3-v0 5.75E-01 5.61E-01 6.50E-01 5.14E-01 lbs/MMcf 1 11.99 29.78 1.00

Boiler, Ref. Gas 2 VOC Ammonia B3-v0 3.21E+00 3.37E+00 3.93E+00 2.34E+00 lbs/MMcf 1 25.08 62.29 1.00

Boiler, Ref. Gas 2 VOC Benzene A3-v0 8.38E-02 8.13E-02 8.88E-02 8.13E-02 lbs/MMcf 1 5.16 12.82 0.00

Boiler, Ref. Gas 2 VOC Carbon Tetrachloride A3-v0 1.19E-02 1.27E-02 1.27E-02 1.03E-02 lbs/MMcf 1 11.32 28.11 0.00

Boiler, Ref. Gas 2 VOC Chloroform A3-v0 5.72E-02 6.09E-02 6.09E-02 4.97E-02 lbs/MMcf 1 11.27 28.00 0.00

Boiler, Ref. Gas 2 VOC Cyanide E3-v0 1.25E-02 1.24E-02 1.43E-02 1.07E-02 lbs/MMcf 1 14.40 35.77 0.00

Boiler, Ref. Gas 2 VOC Formaldehyde A3-v0 1.93E+00 1.79E+00 2.37E+00 1.62E+00 lbs/MMcf 1 20.37 50.60 1.00

Boiler, Ref. Gas 2 VOC Hydrogen Sulfide A3-v0 1.02E+00 1.10E+00 1.19E+00 6.74E-01 lbs/MMcf 2 19.03 19.97 0.00

Boiler, Ref. Gas 2 VOC Methylene Chloride A3-v0 2.41E+00 2.57E+00 2.57E+00 2.09E+00 lbs/MMcf 1 11.47 28.50 0.00

Boiler, Ref. Gas 2 VOC Tetrachloroethene A3-v0 1.30E-02 1.38E-02 1.38E-02 1.13E-02 lbs/MMcf 1 11.30 28.08 0.00

Boiler, Ref. Gas 2 VOC Toluene A3-v0 9.88E-02 9.59E-02 1.05E-01 9.59E-02 lbs/MMcf 1 5.09 12.63 0.00

103

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Ref. Gas 2 VOC Trichloroethene A3-v1 3.84E-02 4.91E-02 6.01E-02 6.01E-03 lbs/MMcf 1 74.44 184.93 0.00

Boiler, Ref. Gas 2 VOC Trichlorofluoromethane A3-v0 9.80E-03 1.04E-02 1.04E-02 8.52E-03 lbs/MMcf 1 11.24 27.92 0.00

Boiler, Ref. Gas 2 VOC Xylene (Total) A3-v0 1.14E-01 1.10E-01 1.21E-01 1.10E-01 lbs/MMcf 1 5.15 12.78 0.00

Boiler, Wood 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 6.75E-12 6.74E-12 9.74E-12 3.78E-12 lbs/ton 1 44.13 109.61 0.00

Boiler, Wood 1 Dioxin/Furan Dioxin:4D Total A3-v1 1.17E-09 7.39E-10 2.44E-09 3.34E-10 lbs/ton 1 95.36 236.89 1.00

Boiler, Wood 1 Dioxin/Furan Dioxin:5D 12378 A3-v1 1.57E-11 1.06E-11 3.32E-11 3.12E-12 lbs/ton 1 100.03 248.48 0.00

Boiler, Wood 1 Dioxin/Furan Dioxin:5D Total A3-v1 9.94E-10 5.65E-10 2.08E-09 3.34E-10 lbs/ton 1 95.57 237.40 1.00

Boiler, Wood 1 Dioxin/Furan Dioxin:6D 123478 A3-v1 2.56E-11 1.25E-11 5.54E-11 8.91E-12 lbs/ton 1 101.08 251.11 0.72

Boiler, Wood 1 Dioxin/Furan Dioxin:6D 123678 A3-v1 3.74E-11 2.39E-11 7.75E-11 1.07E-11 lbs/ton 1 94.71 235.28 0.90

Boiler, Wood 1 Dioxin/Furan Dioxin:6D 123789 A3-v1 2.64E-11 1.13E-11 5.98E-11 8.04E-12 lbs/ton 1 109.76 272.67 0.76

Boiler, Wood 1 Dioxin/Furan Dioxin:6D Total A3-v1 2.72E-09 1.24E-09 6.20E-09 7.34E-10 lbs/ton 1 110.88 275.44 1.00

Boiler, Wood 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 5.74E-10 4.56E-10 8.86E-10 3.78E-10 lbs/ton 1 47.65 118.37 1.00

Boiler, Wood 1 Dioxin/Furan Dioxin:7D Total A3-v0 1.08E-09 8.69E-10 1.64E-09 7.34E-10 lbs/ton 1 45.14 112.14 1.00

Boiler, Wood 1 Dioxin/Furan Dioxin:8D A3-v0 7.86E-09 8.46E-09 8.48E-09 6.64E-09 lbs/ton 1 13.39 33.26 1.00

Boiler, Wood 1 Dioxin/Furan Furan:4F 2378 A3-v0 3.74E-11 3.91E-11 4.87E-11 2.45E-11 lbs/ton 1 32.61 81.00 1.00

Boiler, Wood 1 Dioxin/Furan Furan:4F Total A3-v0 9.75E-10 1.13E-09 1.33E-09 4.67E-10 lbs/ton 1 46.24 114.88 1.00

Boiler, Wood 1 Dioxin/Furan Furan:5F 12378 A3-v0 2.24E-11 1.61E-11 3.76E-11 1.36E-11 lbs/ton 1 58.99 146.54 0.80

Boiler, Wood 1 Dioxin/Furan Furan:5F 23478 A3-v0 2.57E-11 2.39E-11 3.99E-11 1.34E-11 lbs/ton 1 51.92 128.97 0.83

Boiler, Wood 1 Dioxin/Furan Furan:5F Total A3-v0 3.69E-10 4.43E-10 4.78E-10 1.87E-10 lbs/ton 1 43.03 106.90 1.00

Boiler, Wood 1 Dioxin/Furan Furan:6F 123478 A3-v0 2.68E-11 3.26E-11 3.76E-11 1.02E-11 lbs/ton 1 54.38 135.08 0.87

Boiler, Wood 1 Dioxin/Furan Furan:6F 123678 A3-v0 2.72E-11 3.04E-11 3.54E-11 1.58E-11 lbs/ton 1 37.48 93.10 0.81

Boiler, Wood 1 Dioxin/Furan Furan:6F 123789 A3-v0 8.31E-12 8.23E-12 1.04E-11 6.30E-12 lbs/ton 1 24.71 61.38 0.00

Boiler, Wood 1 Dioxin/Furan Furan:6F 234678 A3-v0 3.14E-11 2.39E-11 5.09E-11 1.94E-11 lbs/ton 1 54.36 135.04 0.79

Boiler, Wood 1 Dioxin/Furan Furan:6F Total A3-v0 2.67E-10 2.66E-10 3.69E-10 1.65E-10 lbs/ton 1 38.40 95.39 1.00

Boiler, Wood 1 Dioxin/Furan Furan:7F 1234678 A3-v0 1.98E-10 2.14E-10 2.17E-10 1.62E-10 lbs/ton 1 15.75 39.14 1.00

Boiler, Wood 1 Dioxin/Furan Furan:7F 1234789 A3-v0 1.63E-11 1.46E-11 2.07E-11 1.37E-11 lbs/ton 1 23.30 57.88 0.00

Boiler, Wood 1 Dioxin/Furan Furan:7F Total A3-v0 3.75E-10 4.01E-10 4.13E-10 3.10E-10 lbs/ton 1 15.00 37.25 1.00

Boiler, Wood 1 Dioxin/Furan Furan:8F A3-v0 4.92E-10 5.09E-10 5.22E-10 4.45E-10 lbs/ton 1 8.35 20.74 1.00

104

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Boiler, Wood 1 PAH Acenaphthene A3-v0 3.72E-07 3.75E-07 3.84E-07 3.58E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Acenaphthylene A3-v0 2.17E-07 2.14E-07 3.16E-07 1.20E-07 lbs/ton 1 45.35 112.64 1.00

Boiler, Wood 1 PAH Anthracene A3-v0 3.07E-07 3.09E-07 3.16E-07 2.95E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Benzo(a)anthracene A3-v0 1.10E-08 1.10E-08 1.13E-08 1.05E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Benzo(a)pyrene A3-v0 1.10E-08 1.10E-08 1.13E-08 1.05E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Benzo(b)fluoranthene A3-v0 2.10E-08 1.96E-08 2.43E-08 1.92E-08 lbs/ton 1 13.46 33.43 1.00

Boiler, Wood 1 PAH Benzo(e)pyrene A3-v0 4.09E-08 4.21E-08 4.74E-08 3.31E-08 lbs/ton 1 17.69 43.94 1.00

Boiler, Wood 1 PAH Benzo(g,h,i)perylene A3-v0 1.31E-07 1.37E-07 1.51E-07 1.06E-07 lbs/ton 1 17.63 43.79 1.00

Boiler, Wood 1 PAH Benzo(k)fluoranthene A3-v0 1.10E-08 1.10E-08 1.13E-08 1.05E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Chrysene A3-v0 8.10E-08 8.17E-08 8.35E-08 7.80E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Dibenz(a,h)anthracene A3-v0 1.10E-08 1.10E-08 1.13E-08 1.05E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Fluoranthene A3-v0 9.86E-07 9.93E-07 1.02E-06 9.48E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Fluorene A3-v0 6.79E-07 6.84E-07 7.00E-07 6.53E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.28E-08 2.32E-08 2.48E-08 2.03E-08 lbs/ton 1 10.06 24.98 1.00

Boiler, Wood 1 PAH Naphthalene A3-v0 2.28E-05 2.21E-05 3.58E-05 1.04E-05 lbs/ton 1 55.94 138.95 1.00

Boiler, Wood 1 PAH Phenanthrene A3-v0 2.08E-06 2.10E-06 2.14E-06 2.00E-06 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PAH Pyrene A3-v0 5.48E-07 5.52E-07 5.64E-07 5.27E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 PCB PCB:Decachlorinatedbiphenyls

A3-v0 3.23E-10 3.48E-10 3.56E-10 2.66E-10 lbs/ton 1 15.44 38.36 0.00

Boiler, Wood 1 PCB PCB:Dichlorinated biphenyls A3-v0 8.77E-09 7.34E-09 1.44E-08 4.56E-09 lbs/ton 1 57.80 143.59 0.55

Boiler, Wood 1 PCB PCB:Heptachlorinatedbiphenyls

A3-v0 1.27E-09 1.35E-09 1.83E-09 6.45E-10 lbs/ton 1 46.61 115.79 0.83

Boiler, Wood 1 PCB PCB:Hexachlorinatedbiphenyls

A3-v0 5.14E-09 5.34E-09 6.08E-09 3.99E-09 lbs/ton 1 20.71 51.45 1.00

Boiler, Wood 1 PCB PCB:Monochlorinatedbiphenyls

A3-v0 3.89E-09 4.21E-09 4.56E-09 2.89E-09 lbs/ton 1 22.63 56.22 1.00

Boiler, Wood 1 PCB PCB:Nonachlorinatedbiphenyls

A3-v0 1.04E-10 1.09E-10 1.13E-10 8.86E-11 lbs/ton 1 12.66 31.44 0.00

Boiler, Wood 1 PCB PCB:Octachlorinatedbiphenyls

A3-v0 1.75E-10 1.78E-10 2.45E-10 1.02E-10 lbs/ton 1 40.88 101.55 0.00

Boiler, Wood 1 PCB PCB:Pentachlorinatedbiphenyls

A3-v0 1.15E-08 1.09E-08 1.35E-08 1.02E-08 lbs/ton 1 15.00 37.25 1.00

Boiler, Wood 1 PCB PCB:Tetrachlorinated A3-v0 2.85E-08 2.44E-08 3.91E-08 2.20E-08 lbs/ton 1 32.51 80.75 1.00

105

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

biphenyls

Boiler, Wood 1 PCB PCB:Trichlorinated biphenyls A3-v0 3.16E-08 2.89E-08 3.69E-08 2.88E-08 lbs/ton 1 14.79 36.74 1.00

Boiler, Wood 1 SVOC 2-Methylnaphthalene A3-v0 3.29E-07 3.31E-07 3.39E-07 3.16E-07 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 SVOC Perylene A3-v0 1.10E-08 1.10E-08 1.13E-08 1.05E-08 lbs/ton 1 3.50 8.70 0.00

Boiler, Wood 1 VOC Formaldehyde A3-v1 6.54E-04 6.49E-04 1.09E-03 2.18E-04 lbs/ton 1 67.06 166.60 1.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.46E-11 1.44E-11 1.99E-11 9.60E-12 lbs/1000 Barrels 1 35.18 87.40 0.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:4D Total A3-v0 1.46E-11 1.44E-11 1.99E-11 9.60E-12 lbs/1000 Barrels 1 35.18 87.40 0.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 4.19E-11 5.25E-11 5.31E-11 2.02E-11 lbs/1000 Barrels 1 44.84 111.40 0.42

Catalytic Reformer 1 Dioxin/Furan Dioxin:5D Total A3-v1 1.11E-10 1.03E-10 1.93E-10 3.70E-11 lbs/1000 Barrels 1 70.57 175.31 1.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 3.73E-11 3.94E-11 4.08E-11 3.15E-11 lbs/1000 Barrels 1 13.41 33.31 0.35

Catalytic Reformer 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 3.44E-11 3.67E-11 4.83E-11 1.82E-11 lbs/1000 Barrels 1 44.23 109.87 0.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 3.18E-11 2.88E-11 4.22E-11 2.43E-11 lbs/1000 Barrels 1 29.20 72.54 0.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:6D Total A3-v0 3.99E-10 3.13E-10 7.01E-10 1.84E-10 lbs/1000 Barrels 1 67.38 167.38 1.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 2.19E-10 1.73E-10 3.61E-10 1.21E-10 lbs/1000 Barrels 1 57.74 143.44 1.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:7D Total A3-v0 4.33E-10 3.13E-10 7.75E-10 2.10E-10 lbs/1000 Barrels 1 69.54 172.74 1.00

Catalytic Reformer 1 Dioxin/Furan Dioxin:8D A3-v0 7.95E-10 8.15E-10 8.91E-10 6.80E-10 lbs/1000 Barrels 1 13.45 33.41 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:4F 2378 A3-v1 7.22E-11 7.23E-11 1.26E-10 1.82E-11 lbs/1000 Barrels 1 74.76 185.72 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:4F Total A3-v0 8.42E-10 8.43E-10 1.24E-09 4.46E-10 lbs/1000 Barrels 1 46.91 116.53 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:5F 12378 A3-v0 1.46E-10 1.84E-10 2.09E-10 4.35E-11 lbs/1000 Barrels 1 61.34 152.39 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:5F 23478 A3-v1 3.41E-10 2.89E-10 6.50E-10 8.30E-11 lbs/1000 Barrels 1 84.28 209.37 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:5F Total A3-v1 1.59E-09 1.45E-09 2.89E-09 4.46E-10 lbs/1000 Barrels 1 77.09 191.50 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:6F 123478 A3-v0 3.29E-10 3.37E-10 4.57E-10 1.94E-10 lbs/1000 Barrels 1 39.86 99.01 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:6F 123678 A3-v0 3.35E-10 4.11E-10 4.25E-10 1.68E-10 lbs/1000 Barrels 1 43.10 107.06 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:6F 123789 A3-v0 4.25E-11 4.66E-11 4.73E-11 3.36E-11 lbs/1000 Barrels 1 18.18 45.15 0.00

Catalytic Reformer 1 Dioxin/Furan Furan:6F 234678 A3-v0 3.81E-10 4.23E-10 5.42E-10 1.79E-10 lbs/1000 Barrels 1 48.57 120.66 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:6F Total A3-v0 2.45E-09 2.89E-09 3.08E-09 1.37E-09 lbs/1000 Barrels 1 38.40 95.38 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:7F 1234678 A3-v1 9.15E-10 4.58E-10 2.12E-09 1.63E-10 lbs/1000 Barrels 1 115.60 287.16 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:7F 1234789 A3-v0 2.59E-10 1.78E-10 4.89E-10 1.10E-10 lbs/1000 Barrels 1 77.82 193.31 1.00

106

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Catalytic Reformer 1 Dioxin/Furan Furan:7F Total A3-v1 1.52E-09 7.95E-10 3.51E-09 2.63E-10 lbs/1000 Barrels 1 114.32 283.99 1.00

Catalytic Reformer 1 Dioxin/Furan Furan:8F A3-v1 3.14E-10 9.87E-11 7.54E-10 8.95E-11 lbs/1000 Barrels 1 121.33 301.40 1.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.93E-11 1.71E-11 3.36E-11 7.20E-12 lbs/1000 Barrels 1 69.03 171.49 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:4D Total A3-v0 1.93E-11 1.71E-11 3.36E-11 7.20E-12 lbs/1000 Barrels 1 69.03 171.49 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:5D 12378 A3-v0 8.57E-12 9.26E-12 9.94E-12 6.51E-12 lbs/1000 Barrels 1 21.17 52.58 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:5D Total A3-v1 3.95E-11 1.68E-11 9.53E-11 6.51E-12 lbs/1000 Barrels 1 122.84 305.14 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:6D 123478 A3-v0 2.39E-11 2.23E-11 3.36E-11 1.58E-11 lbs/1000 Barrels 1 37.77 93.82 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:6D 123678 A3-v0 2.61E-11 2.23E-11 3.36E-11 2.23E-11 lbs/1000 Barrels 1 25.07 62.28 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:6D 123789 A3-v0 2.29E-11 1.92E-11 3.36E-11 1.58E-11 lbs/1000 Barrels 1 41.39 102.81 0.00

Catalytic Reformer 2 Dioxin/Furan Dioxin:6D Total A3-v1 8.65E-11 4.49E-11 1.81E-10 3.36E-11 lbs/1000 Barrels 1 94.84 235.59 0.70

Catalytic Reformer 2 Dioxin/Furan Dioxin:7D 1234678 A3-v0 1.19E-10 1.07E-10 1.51E-10 1.01E-10 lbs/1000 Barrels 1 22.92 56.94 0.72

Catalytic Reformer 2 Dioxin/Furan Dioxin:7D Total A3-v0 1.92E-10 2.02E-10 2.72E-10 1.01E-10 lbs/1000 Barrels 1 44.91 111.55 0.82

Catalytic Reformer 2 Dioxin/Furan Dioxin:8D A3-v0 8.37E-10 8.13E-10 1.35E-09 3.52E-10 lbs/1000 Barrels 1 59.38 147.52 1.00

Catalytic Reformer 2 Dioxin/Furan Furan:4F 2378 A3-v0 1.79E-11 1.47E-11 3.09E-11 8.23E-12 lbs/1000 Barrels 1 64.92 161.27 0.00

Catalytic Reformer 2 Dioxin/Furan Furan:4F Total A3-v1 2.82E-10 1.88E-10 5.61E-10 9.67E-11 lbs/1000 Barrels 1 87.27 216.80 1.00

Catalytic Reformer 2 Dioxin/Furan Furan:5F 12378 A3-v0 3.37E-11 3.91E-11 4.49E-11 1.71E-11 lbs/1000 Barrels 1 43.44 107.90 0.61

Catalytic Reformer 2 Dioxin/Furan Furan:5F 23478 A3-v0 6.64E-11 5.31E-11 1.01E-10 4.53E-11 lbs/1000 Barrels 1 45.26 112.43 0.73

Catalytic Reformer 2 Dioxin/Furan Furan:5F Total A3-v0 4.47E-10 5.33E-10 6.17E-10 1.91E-10 lbs/1000 Barrels 1 50.42 125.25 1.00

Catalytic Reformer 2 Dioxin/Furan Furan:6F 123478 A3-v0 7.44E-11 8.13E-11 9.15E-11 5.04E-11 lbs/1000 Barrels 1 28.78 71.49 0.77

Catalytic Reformer 2 Dioxin/Furan Furan:6F 123678 A3-v0 9.99E-11 9.26E-11 1.51E-10 5.62E-11 lbs/1000 Barrels 1 47.79 118.72 0.81

Catalytic Reformer 2 Dioxin/Furan Furan:6F 123789 A3-v0 3.31E-11 3.36E-11 4.77E-11 1.82E-11 lbs/1000 Barrels 1 44.50 110.54 0.00

Catalytic Reformer 2 Dioxin/Furan Furan:6F 234678 A3-v0 1.96E-10 1.63E-10 3.42E-10 8.40E-11 lbs/1000 Barrels 1 67.45 167.54 0.86

Catalytic Reformer 2 Dioxin/Furan Furan:6F Total A3-v0 7.39E-10 7.01E-10 1.21E-09 3.09E-10 lbs/1000 Barrels 1 61.00 151.54 1.00

Catalytic Reformer 2 Dioxin/Furan Furan:7F 1234678 A3-v2 2.90E-10 1.35E-10 7.25E-10 1.10E-11 lbs/1000 Barrels 1 131.46 326.56 0.99

Catalytic Reformer 2 Dioxin/Furan Furan:7F 1234789 A3-v1 1.73E-10 3.36E-11 4.73E-10 1.23E-11 lbs/1000 Barrels 1 150.34 373.46 0.91

Catalytic Reformer 2 Dioxin/Furan Furan:7F Total A3-v2 5.40E-10 1.99E-10 1.41E-09 1.23E-11 lbs/1000 Barrels 1 140.36 348.68 0.99

Catalytic Reformer 2 Dioxin/Furan Furan:8F A3-v1 1.48E-10 1.91E-10 2.19E-10 3.36E-11 lbs/1000 Barrels 1 67.57 167.84 0.43

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:4D 2378 D3-v1 5.01E-11 3.98E-11 1.14E-10 7.52E-12 lbs/ton production 2 94.01 98.66 0.23

107

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:4D Total D3-v2 2.20E-09 1.36E-09 6.14E-09 2.32E-11 lbs/ton production 2 118.61 124.47 1.00

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:5D 12378 D3-v1 8.74E-11 8.21E-11 1.61E-10 2.04E-11 lbs/ton production 2 81.98 86.04 0.60

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:5D Total D3-v1 1.15E-09 9.37E-10 2.75E-09 1.42E-10 lbs/ton production 2 99.16 104.06 0.93

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123478 D3-v1 6.39E-11 6.14E-11 1.19E-10 2.14E-11 lbs/ton production 2 68.83 72.23 0.81

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123678 D3-v1 6.45E-11 5.88E-11 1.37E-10 1.42E-11 lbs/ton production 2 83.53 87.66 0.87

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123789 D3-v1 9.06E-11 8.71E-11 1.78E-10 1.72E-11 lbs/ton production 2 85.66 89.89 0.60

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:6D Total D3-v2 8.97E-10 8.62E-10 1.87E-09 2.14E-11 lbs/ton production 2 105.37 110.58 0.99

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:7D 1234678 D3-v1 2.61E-10 2.39E-10 6.05E-10 1.57E-11 lbs/ton production 2 100.03 104.98 0.99

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:7D Total D3-v2 5.71E-10 5.12E-10 1.28E-09 1.57E-11 lbs/ton production 2 101.46 106.48 1.00

Cement Kiln, Coal 1 Dioxin/Furan Dioxin:8D D3-v1 4.97E-10 3.98E-10 1.19E-09 9.16E-11 lbs/ton production 2 91.43 95.95 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:4F 2378 D3-v2 1.08E-09 8.88E-10 2.80E-09 1.42E-11 lbs/ton production 2 112.56 118.13 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:4F Total D3-v2 4.29E-08 3.66E-08 1.09E-07 3.14E-10 lbs/ton production 2 112.10 117.65 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:5F 12378 D3-v2 4.30E-10 3.07E-10 1.23E-09 1.72E-11 lbs/ton production 2 116.26 122.00 0.99

Cement Kiln, Coal 1 Dioxin/Furan Furan:5F 23478 D3-v2 5.66E-10 4.28E-10 1.49E-09 1.45E-11 lbs/ton production 2 112.66 118.22 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:5F Total D3-v3 7.58E-09 5.75E-09 2.13E-08 1.72E-11 lbs/ton production 2 117.22 123.01 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:6F 123478 D3-v2 3.96E-10 2.49E-10 1.31E-09 7.28E-12 lbs/ton production 2 130.04 136.47 0.99

Cement Kiln, Coal 1 Dioxin/Furan Furan:6F 123678 D3-v2 1.37E-10 9.57E-11 4.21E-10 5.42E-12 lbs/ton production 2 121.18 127.17 0.98

Cement Kiln, Coal 1 Dioxin/Furan Furan:6F 123789 D3-v1 2.74E-11 2.50E-11 5.09E-11 8.84E-12 lbs/ton production 2 67.88 71.23 0.27

Cement Kiln, Coal 1 Dioxin/Furan Furan:6F 234678 D3-v2 1.32E-10 9.39E-11 3.86E-10 6.42E-12 lbs/ton production 2 116.54 122.30 0.97

Cement Kiln, Coal 1 Dioxin/Furan Furan:6F Total D3-v3 1.51E-09 9.38E-10 5.00E-09 8.84E-12 lbs/ton production 2 130.18 136.61 1.00

Cement Kiln, Coal 1 Dioxin/Furan Furan:7F 1234678 D3-v1 1.10E-10 9.31E-11 2.54E-10 7.85E-12 lbs/ton production 2 97.10 101.90 0.97

Cement Kiln, Coal 1 Dioxin/Furan Furan:7F 1234789 D3-v1 3.57E-11 3.13E-11 6.77E-11 1.08E-11 lbs/ton production 2 72.40 75.98 0.29

Cement Kiln, Coal 1 Dioxin/Furan Furan:7F Total D3-v1 1.44E-10 1.10E-10 3.68E-10 1.18E-11 lbs/ton production 2 102.32 107.38 0.97

Cement Kiln, Coal 1 Dioxin/Furan Furan:8F D3-v1 9.08E-11 8.08E-11 1.92E-10 8.98E-12 lbs/ton production 2 97.32 102.13 0.63

Cement Kiln, Coal 1 Metals Arsenic D3-v1 3.02E-06 1.77E-06 6.97E-06 7.24E-07 lbs/ton production 2 91.30 95.82 0.81

Cement Kiln, Coal 1 Metals Beryllium D3-v1 2.25E-06 8.83E-07 7.34E-06 4.47E-07 lbs/ton production 2 122.29 128.34 0.90

Cement Kiln, Coal 1 Metals Cadmium D3-v2 1.46E-06 1.45E-06 2.79E-06 1.42E-08 lbs/ton production 2 60.81 63.82 0.51

Cement Kiln, Coal 1 Metals Chromium (Hex) C3-v0 6.70E-07 6.00E-07 8.64E-07 5.47E-07 lbs/ton production 1 25.35 62.98 1.00

108

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Cement Kiln, Coal 1 Metals Chromium (Total) D3-v0 2.43E-06 1.68E-06 4.34E-06 1.61E-06 lbs/ton production 2 48.89 60.70 1.00

Cement Kiln, Coal 1 Metals Copper D3-v0 8.00E-06 8.28E-06 1.27E-05 4.18E-06 lbs/ton production 2 40.29 42.28 0.62

Cement Kiln, Coal 1 Metals Lead D3-v2 9.70E-05 1.96E-05 3.06E-04 2.60E-06 lbs/ton production 2 139.85 146.76 1.00

Cement Kiln, Coal 1 Metals Manganese D3-v2 5.51E-04 3.27E-05 3.00E-03 9.52E-06 lbs/ton production 2 217.94 228.72 1.00

Cement Kiln, Coal 1 Metals Mercury D3-v0 7.59E-05 7.14E-05 1.27E-04 3.43E-05 lbs/ton production 2 50.05 52.53 1.00

Cement Kiln, Coal 1 Metals Nickel D3-v2 5.44E-06 4.24E-06 1.40E-05 2.70E-07 lbs/ton production 2 99.65 123.74 1.00

Cement Kiln, Coal 1 Metals Phosphorus E3-v1 1.31E-04 1.59E-04 2.14E-04 1.90E-05 lbs/ton production 1 76.94 191.13 1.00

Cement Kiln, Coal 1 Metals Selenium D3-v1 5.91E-06 1.41E-06 2.02E-05 4.26E-07 lbs/ton production 2 138.77 145.63 0.91

Cement Kiln, Coal 1 Metals Strontium E3-v0 4.68E-06 4.73E-06 4.76E-06 4.55E-06 lbs/ton production 1 2.51 6.24 0.00

Cement Kiln, Coal 1 Metals Zinc D3-v1 1.34E-03 6.99E-04 3.26E-03 7.14E-05 lbs/ton production 2 115.44 121.14 1.00

Cement Kiln, Coal 1 PAH Acenaphthene D3-v2 7.80E-06 6.95E-06 1.90E-05 5.00E-08 lbs/ton production 2 110.23 115.68 1.00

Cement Kiln, Coal 1 PAH Acenaphthylene D3-v1 2.35E-07 1.01E-07 9.10E-07 5.42E-08 lbs/ton production 2 140.95 147.92 1.00

Cement Kiln, Coal 1 PAH Anthracene D3-v2 2.84E-06 1.84E-06 9.52E-06 1.48E-07 lbs/ton production 2 126.38 132.62 1.00

Cement Kiln, Coal 1 PAH Benzo(a)anthracene D3-v1 2.11E-07 1.51E-07 6.14E-07 5.20E-08 lbs/ton production 2 96.39 101.15 1.00

Cement Kiln, Coal 1 PAH Benzo(a)pyrene D3-v0 1.86E-08 1.49E-08 3.07E-08 1.39E-08 lbs/ton production 2 43.34 68.96 0.41

Cement Kiln, Coal 1 PAH Benzo(b)fluoranthene D3-v1 1.75E-07 7.97E-08 6.57E-07 1.64E-08 lbs/ton production 2 137.44 144.24 1.00

Cement Kiln, Coal 1 PAH Benzo(e)pyrene E3-v1 1.84E-07 5.95E-08 4.60E-07 3.31E-08 lbs/ton production 1 129.80 322.44 1.00

Cement Kiln, Coal 1 PAH Benzo(g,h,i)perylene D3-v1 1.12E-08 1.44E-08 1.50E-08 8.76E-10 lbs/ton production 2 61.60 98.02 0.02

Cement Kiln, Coal 1 PAH Benzo(k)fluoranthene D3-v1 1.27E-08 8.74E-09 3.61E-08 8.50E-10 lbs/ton production 2 111.30 116.81 0.75

Cement Kiln, Coal 1 PAH Chrysene D3-v2 1.16E-06 5.34E-07 4.76E-06 5.49E-08 lbs/ton production 2 154.95 162.61 1.00

Cement Kiln, Coal 1 PAH Dibenz(a,h)anthracene C3-v0 1.46E-08 1.48E-08 1.50E-08 1.39E-08 lbs/ton production 1 4.27 10.60 0.00

Cement Kiln, Coal 1 PAH Fluoranthene D3-v1 2.00E-06 2.28E-06 3.64E-06 5.05E-07 lbs/ton production 2 61.06 64.08 1.00

Cement Kiln, Coal 1 PAH Fluorene D3-v1 9.59E-07 9.19E-07 1.79E-06 3.33E-07 lbs/ton production 2 57.98 60.85 1.00

Cement Kiln, Coal 1 PAH Indeno(1,2,3-cd)pyrene D3-v1 9.65E-09 1.39E-08 1.50E-08 1.75E-09 lbs/ton production 2 70.25 87.22 0.09

Cement Kiln, Coal 1 PAH Naphthalene D3-v0 1.64E-05 1.72E-05 1.82E-05 1.36E-05 lbs/ton production 2 12.16 12.76 1.00

Cement Kiln, Coal 1 PAH Phenanthrene D3-v0 3.68E-06 4.38E-06 4.76E-06 1.93E-06 lbs/ton production 2 35.53 37.29 1.00

Cement Kiln, Coal 1 PAH Pyrene D3-v1 2.03E-06 1.83E-06 4.82E-06 2.97E-07 lbs/ton production 2 84.40 88.57 1.00

Cement Kiln, Coal 1 VOC Acetaldehyde C3-v1 4.53E-04 5.33E-04 6.93E-04 1.33E-04 lbs/ton production 1 63.63 158.06 0.90

109

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Cement Kiln, Coal 1 VOC Benzene E3-v0 1.40E-03 1.10E-03 2.09E-03 1.00E-03 lbs/ton production 1 43.30 107.57 0.00

Cement Kiln, Coal 1 VOC Formaldehyde D3-v1 5.72E-05 5.29E-05 1.42E-04 9.09E-06 lbs/ton production 2 83.00 87.10 0.95

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:4D 2378 E3-v1 4.60E-13 3.39E-13 8.84E-13 1.57E-13 lbs/ton production 1 82.24 204.29 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:4D Total E3-v1 4.60E-13 3.39E-13 8.84E-13 1.57E-13 lbs/ton production 1 82.24 204.29 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:5D 12378 E3-v0 4.36E-13 3.62E-13 7.36E-13 2.09E-13 lbs/ton production 1 62.33 154.82 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:5D Total E3-v0 4.36E-13 3.62E-13 7.36E-13 2.09E-13 lbs/ton production 1 62.33 154.82 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:6D 123478 E3-v0 4.36E-13 3.76E-13 7.36E-13 1.94E-13 lbs/ton production 1 63.39 157.46 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:6D 123678 E3-v0 4.36E-13 3.76E-13 7.36E-13 1.94E-13 lbs/ton production 1 63.39 157.46 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:6D 123789 E3-v0 4.36E-13 3.76E-13 7.36E-13 1.94E-13 lbs/ton production 1 63.39 157.46 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:6D Total E3-v0 4.36E-13 3.76E-13 7.36E-13 1.94E-13 lbs/ton production 1 63.39 157.46 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:7D 1234678 E3-v0 3.21E-12 3.17E-12 3.31E-12 3.13E-12 lbs/ton production 1 2.98 7.40 1.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:7D Total E3-v0 5.65E-12 5.67E-12 6.27E-12 5.00E-12 lbs/ton production 1 11.32 28.11 1.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Dioxin:8D E3-v0 3.01E-11 2.95E-11 3.58E-11 2.50E-11 lbs/ton production 1 17.93 44.55 0.60

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:4F 2378 E3-v1 3.15E-13 1.12E-13 7.29E-13 1.03E-13 lbs/ton production 1 114.01 283.22 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:4F Total E3-v1 3.08E-12 3.06E-12 5.46E-12 7.29E-13 lbs/ton production 1 76.76 190.69 0.92

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:5F 12378 E3-v0 3.25E-13 4.05E-13 4.43E-13 1.27E-13 lbs/ton production 1 53.13 131.98 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:5F 23478 E3-v0 3.25E-13 4.05E-13 4.43E-13 1.27E-13 lbs/ton production 1 53.13 131.98 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:5F Total E3-v0 3.25E-13 4.05E-13 4.43E-13 1.27E-13 lbs/ton production 1 53.13 131.98 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:6F 123478 E3-v0 3.27E-13 2.07E-13 6.04E-13 1.71E-13 lbs/ton production 1 73.36 182.23 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:6F 123678 E3-v0 3.27E-13 2.07E-13 6.04E-13 1.71E-13 lbs/ton production 1 73.36 182.23 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:6F 123789 E3-v0 3.27E-13 2.07E-13 6.04E-13 1.71E-13 lbs/ton production 1 73.36 182.23 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:6F 234678 E3-v0 3.27E-13 2.07E-13 6.04E-13 1.71E-13 lbs/ton production 1 73.36 182.23 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:6F Total E3-v0 3.27E-13 2.07E-13 6.04E-13 1.71E-13 lbs/ton production 1 73.36 182.23 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:7F 1234678 E3-v0 6.55E-13 6.12E-13 9.57E-13 3.95E-13 lbs/ton production 1 43.28 107.51 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:7F 1234789 E3-v0 6.55E-13 6.12E-13 9.57E-13 3.95E-13 lbs/ton production 1 43.28 107.51 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:7F Total E3-v0 6.55E-13 6.12E-13 9.57E-13 3.95E-13 lbs/ton production 1 43.28 107.51 0.00

Cement Kiln, Coal/Coke 1 Dioxin/Furan Furan:8F E3-v0 1.26E-12 1.18E-12 1.99E-12 6.04E-13 lbs/ton production 1 55.29 137.35 0.00

Cement Kiln, Coal/Coke 1 Halogens HCl E3-v0 4.59E-05 4.30E-05 5.99E-05 3.47E-05 lbs/ton production 1 27.90 69.32 1.00

110

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Cement Kiln, Coal/Coke 1 Metals Arsenic E3-v0 2.59E-06 2.58E-06 2.91E-06 2.29E-06 lbs/ton production 1 11.87 29.50 0.00

Cement Kiln, Coal/Coke 1 Metals Beryllium E3-v0 5.03E-06 4.90E-06 5.71E-06 4.49E-06 lbs/ton production 1 12.39 30.77 0.00

Cement Kiln, Coal/Coke 1 Metals Cadmium E3-v0 2.90E-07 1.80E-07 5.61E-07 1.29E-07 lbs/ton production 1 81.33 202.03 1.00

Cement Kiln, Coal/Coke 1 Metals Chromium (Hex) E3-v0 2.80E-06 2.43E-06 3.57E-06 2.39E-06 lbs/ton production 1 23.98 59.58 1.00

Cement Kiln, Coal/Coke 1 Metals Chromium (Total) E3-v0 1.86E-06 1.62E-06 2.37E-06 1.60E-06 lbs/ton production 1 23.78 59.07 1.00

Cement Kiln, Coal/Coke 1 Metals Copper E3-v0 3.81E-06 4.12E-06 4.56E-06 2.76E-06 lbs/ton production 1 24.66 61.27 1.00

Cement Kiln, Coal/Coke 1 Metals Lead E3-v0 1.24E-06 8.91E-07 2.34E-06 5.03E-07 lbs/ton production 1 77.68 192.98 1.00

Cement Kiln, Coal/Coke 1 Metals Manganese E3-v0 8.85E-06 8.16E-06 1.04E-05 8.03E-06 lbs/ton production 1 14.88 36.96 0.00

Cement Kiln, Coal/Coke 1 Metals Mercury E3-v0 3.83E-06 3.35E-06 4.93E-06 3.20E-06 lbs/ton production 1 25.09 62.33 1.00

Cement Kiln, Coal/Coke 1 Metals Nickel E3-v0 2.60E-05 2.58E-05 2.93E-05 2.29E-05 lbs/ton production 1 12.24 30.42 0.00

Cement Kiln, Coal/Coke 1 Metals Selenium E3-v0 3.78E-06 3.57E-06 4.66E-06 3.11E-06 lbs/ton production 1 21.11 52.44 1.00

Cement Kiln, Coal/Coke 1 Metals Zinc E3-v0 1.02E-05 8.54E-06 1.43E-05 7.69E-06 lbs/ton production 1 35.29 87.68 1.00

Cement Kiln, Coal/Coke 1 PAH Acenaphthene E3-v1 1.95E-07 1.49E-07 4.05E-07 3.14E-08 lbs/ton production 1 97.86 243.09 0.69

Cement Kiln, Coal/Coke 1 PAH Acenaphthylene E3-v1 2.21E-06 6.41E-07 5.81E-06 1.95E-07 lbs/ton production 1 140.87 349.94 1.00

Cement Kiln, Coal/Coke 1 PAH Anthracene E3-v2 1.25E-07 1.25E-07 2.46E-07 4.74E-09 lbs/ton production 1 136.07 1222.55 0.98

Cement Kiln, Coal/Coke 1 PAH Benzo(a)anthracene E3-v0 8.19E-10 7.41E-10 9.87E-10 7.28E-10 lbs/ton production 1 17.87 44.40 1.00

Cement Kiln, Coal/Coke 1 PAH Benzo(a)pyrene E3-v0 2.50E-09 2.24E-09 3.43E-09 1.82E-09 lbs/ton production 1 33.37 82.90 1.00

Cement Kiln, Coal/Coke 1 PAH Benzo(b)fluoranthene E3-v1 1.84E-08 4.23E-09 4.86E-08 2.44E-09 lbs/ton production 1 141.94 352.59 0.12

Cement Kiln, Coal/Coke 1 PAH Benzo(g,h,i)perylene E3-v0 1.45E-09 1.66E-09 1.72E-09 9.87E-10 lbs/ton production 1 27.88 69.25 1.00

Cement Kiln, Coal/Coke 1 PAH Benzo(k)fluoranthene E3-v0 3.88E-09 3.63E-09 5.66E-09 2.34E-09 lbs/ton production 1 43.17 107.24 0.51

Cement Kiln, Coal/Coke 1 PAH Chrysene E3-v0 3.03E-09 3.12E-09 3.84E-09 2.12E-09 lbs/ton production 1 28.62 71.09 1.00

Cement Kiln, Coal/Coke 1 PAH Dibenz(a,h)anthracene E3-v0 1.19E-09 1.20E-09 1.46E-09 9.17E-10 lbs/ton production 1 22.86 56.79 1.00

Cement Kiln, Coal/Coke 1 PAH Fluoranthene E3-v0 1.64E-07 1.86E-07 2.39E-07 6.57E-08 lbs/ton production 1 54.36 135.04 1.00

Cement Kiln, Coal/Coke 1 PAH Fluorene E3-v1 3.51E-07 3.80E-07 6.29E-07 4.35E-08 lbs/ton production 1 83.76 208.06 1.00

Cement Kiln, Coal/Coke 1 PAH Indeno(1,2,3-cd)pyrene E3-v0 1.62E-09 1.62E-09 2.34E-09 9.17E-10 lbs/ton production 1 43.81 108.82 1.00

Cement Kiln, Coal/Coke 1 PAH Naphthalene E3-v1 3.24E-05 2.06E-05 7.37E-05 2.99E-06 lbs/ton production 1 113.47 281.88 1.00

Cement Kiln, Coal/Coke 1 PAH Phenanthrene E3-v1 7.44E-06 4.89E-06 1.64E-05 1.05E-06 lbs/ton production 1 107.26 266.44 1.00

Cement Kiln, Coal/Coke 1 PAH Pyrene E3-v0 8.24E-08 8.93E-08 1.27E-07 3.05E-08 lbs/ton production 1 59.16 146.95 1.00

111

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Cement Kiln, Coal/Coke 1 VOC Benzene E3-v0 2.99E-04 3.39E-04 3.45E-04 2.12E-04 lbs/ton production 1 25.04 62.20 1.00

Cement Kiln, Coal/Coke 1 VOC Formaldehyde E3-v0 8.60E-06 7.91E-06 1.03E-05 7.57E-06 lbs/ton production 1 17.44 43.31 1.00

Coating, Base/Catalyst/Solvent Mix 1 Metals Chromium (Hex) A3-v0 9.25E-05 8.83E-05 1.18E-04 7.08E-05 lbs/gal paint 1 25.94 64.44 1.00

Coating, Base/Catalyst/Solvent Mix 1 Metals Chromium (Total) A3-v0 9.94E-05 9.31E-05 1.21E-04 8.45E-05 lbs/gal paint 1 19.07 47.36 1.00

Coating, Base/Catalyst/Water Mix 1 Metals Chromium (Hex) B3-v1 2.59E-05 2.08E-05 5.00E-05 6.63E-06 lbs/gal paint 2 63.82 66.98 0.78

Coating, Base/Catalyst/Water Mix 1 Metals Chromium (Total) B3-v1 3.59E-05 3.04E-05 8.93E-05 9.38E-06 lbs/gal paint 2 84.27 88.43 0.81

Coating, Base/Catalyst/Water Mix 2 Metals Chromium (Hex) C3-v0 1.81E-04 1.73E-04 2.62E-04 1.07E-04 lbs/gal paint 1 42.89 106.54 1.00

Coating, Base/Catalyst/Water Mix 2 Metals Chromium (Total) C3-v0 2.16E-04 2.34E-04 2.35E-04 1.78E-04 lbs/gal paint 1 15.16 37.65 1.00

Coating, Base/Catalyst/Water Mix 3 Metals Chromium (Hex) A3-v0 9.44E-04 9.05E-04 1.05E-03 8.75E-04 lbs/gal paint 1 10.07 25.01 1.00

Coating, Base/Catalyst/Water Mix 3 Metals Chromium (Total) A3-v0 8.48E-04 8.06E-04 9.71E-04 7.66E-04 lbs/gal paint 1 12.80 31.79 1.00

Coating, Green PE 1 Metals Chromium (Hex) E3-v0 1.75E-04 1.48E-04 3.04E-04 7.20E-05 lbs/gal paint 1 67.70 168.17 1.00

Coating, Green PE 1 Metals Chromium (Total) E3-v0 3.33E-04 3.81E-04 4.06E-04 2.13E-04 lbs/gal paint 1 31.53 78.31 1.00

Coating, Green PE 2 Metals Chromium (Hex) E3-v0 3.10E-05 2.57E-05 5.77E-05 1.47E-05 lbs/gal paint 2 65.32 103.95 1.00

Coating, Green PE 2 Metals Chromium (Total) E3-v0 1.19E-04 1.15E-04 1.85E-04 6.19E-05 lbs/gal paint 2 45.10 71.77 0.68

Coating, Green PE 3 Metals Chromium (Hex) E3-v0 4.31E-06 4.31E-06 5.04E-06 3.58E-06 lbs/gal paint 1 23.93 215.04 1.00

Coating, Green PE 3 Metals Chromium (Total) E3-v0 4.15E-05 4.15E-05 4.73E-05 3.57E-05 lbs/gal paint 1 19.81 177.96 1.00

Coating, Green PE 4 Metals Chromium (Hex) E3-v0 3.99E-05 3.65E-05 5.11E-05 3.21E-05 lbs/gal paint 1 24.98 62.05 1.00

Coating, Green PE 4 Metals Chromium (Total) E3-v0 1.28E-04 1.30E-04 1.32E-04 1.20E-04 lbs/gal paint 1 4.81 11.95 1.00

Coating, Green Primer 1 Metals Chromium (Hex) E3-v0 1.28E-03 1.54E-03 1.83E-03 4.80E-04 lbs/gal paint 1 55.28 137.32 1.00

Coating, Green Primer 1 Metals Chromium (Total) E3-v0 1.53E-03 1.95E-03 1.95E-03 7.01E-04 lbs/gal paint 1 47.05 116.87 1.00

Coating, Green Primer 2 Metals Chromium (Hex) E3-v1 2.87E-04 2.24E-04 6.79E-04 2.06E-05 lbs/gal paint 2 111.31 177.12 1.00

Coating, Green Primer 2 Metals Chromium (Total) E3-v1 7.33E-04 5.82E-04 1.71E-03 5.92E-05 lbs/gal paint 2 106.55 169.54 0.95

Coating, Green Primer 3 Metals Chromium (Hex) E3-v0 1.42E-03 1.42E-03 1.71E-03 1.13E-03 lbs/gal paint 1 29.03 260.79 1.00

Coating, Green Primer 3 Metals Chromium (Total) E3-v0 1.93E-03 1.93E-03 2.47E-03 1.39E-03 lbs/gal paint 1 39.47 354.59 1.00

Coating, Green Primer 4 Metals Chromium (Hex) E3-v0 2.63E-04 2.63E-04 3.69E-04 1.57E-04 lbs/gal paint 1 57.22 514.08 1.00

Coating, Green Primer 4 Metals Chromium (Total) E3-v0 4.26E-04 4.26E-04 5.01E-04 3.50E-04 lbs/gal paint 1 25.10 225.52 1.00

Coating, Green Primer 5 Metals Chromium (Hex) E3-v0 8.32E-04 7.39E-04 1.32E-03 4.36E-04 lbs/gal paint 1 54.03 134.21 1.00

112

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Coating, Green Primer 5 Metals Chromium (Total) E3-v0 1.03E-03 1.02E-03 1.66E-03 4.12E-04 lbs/gal paint 1 60.64 150.63 1.00

Coating, Green Primer 6 Metals Chromium (Hex) E3-v1 2.26E-04 1.97E-04 5.18E-04 7.55E-05 lbs/gal paint 2 72.14 75.71 1.00

Coating, Green Primer 6 Metals Chromium (Total) E3-v0 2.60E-04 2.58E-04 4.39E-04 1.29E-04 lbs/gal paint 2 46.31 48.60 0.63

Coating, Powder 1 Metals Chromium (Hex) C3-v- 3.25E+01 3.25E+01 3.25E+01 3.25E+01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 1 Metals Chromium (Total) C3-v- 7.50E+02 7.50E+02 7.50E+02 7.50E+02 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 2 Metals Chromium (Total) C3-v- 6.97E-01 6.97E-01 6.97E-01 6.97E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 3 Metals Chromium (Hex) A3-v- 3.62E-01 3.62E-01 3.62E-01 3.62E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 3 Metals Chromium (Total) A3-v- 3.72E-01 3.72E-01 3.72E-01 3.72E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 4 Metals Chromium (Hex) A3-v- 6.01E-01 6.01E-01 6.01E-01 6.01E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 4 Metals Chromium (Total) A3-v- 8.05E-01 8.05E-01 8.05E-01 8.05E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 5 Metals Nickel C3-v- 3.21E+00 3.21E+00 3.21E+00 3.21E+00 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 6 Metals Chromium (Hex) C3-v- 5.15E-01 5.15E-01 5.15E-01 5.15E-01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 6 Metals Chromium (Total) C3-v- 3.71E+00 3.71E+00 3.71E+00 3.71E+00 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 7 Metals Chromium (Hex) C3-v- 1.78E+01 1.78E+01 1.78E+01 1.78E+01 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 7 Metals Chromium (Total) C3-v- 2.84E+02 2.84E+02 2.84E+02 2.84E+02 lbs/ton powder 1 0.00 0.00 1.00

Coating, Powder 8 Metals Chromium (Hex) C3-v1 6.67E-02 9.07E-02 9.50E-02 1.44E-02 lbs/ton powder 1 67.96 168.83 1.00

Coating, Powder 8 Metals Chromium (Total) C3-v0 7.64E+00 5.89E+00 1.15E+01 5.50E+00 lbs/ton powder 1 44.21 109.82 1.00

Coating, Powder 8 Metals Copper A3-v0 1.82E+00 2.07E+00 2.28E+00 1.10E+00 lbs/ton powder 1 34.52 85.76 1.00

Coating, Powder 8 Metals Nickel A3-v0 3.08E+00 3.38E+00 3.64E+00 2.21E+00 lbs/ton powder 1 24.62 61.16 1.00

Coating, Yellow PE 1 Metals Chromium (Hex) E3-v0 5.12E-03 4.86E-03 7.04E-03 3.46E-03 lbs/gal paint 1 35.23 87.51 1.00

Coating, Yellow PE 1 Metals Chromium (Total) E3-v0 5.98E-03 6.75E-03 7.63E-03 3.56E-03 lbs/gal paint 1 35.74 88.79 1.00

Coke Calcining 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.14E-11 1.18E-11 1.32E-11 9.05E-12 lbs/ton coke 1 18.56 46.10 0.00

Coke Calcining 1 Dioxin/Furan Dioxin:4D Other A3-v1 1.44E-10 1.01E-10 2.99E-10 3.17E-11 lbs/ton coke 1 96.53 239.78 1.00

Coke Calcining 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 9.56E-12 9.20E-12 1.35E-11 6.01E-12 lbs/ton coke 1 39.05 97.00 0.00

Coke Calcining 1 Dioxin/Furan Dioxin:5D Other A3-v0 8.45E-11 8.83E-11 1.02E-10 6.34E-11 lbs/ton coke 1 23.10 57.39 0.40

Coke Calcining 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 9.93E-12 9.24E-12 1.57E-11 4.83E-12 lbs/ton coke 1 55.10 136.87 0.31

Coke Calcining 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 1.38E-11 1.27E-11 2.04E-11 8.30E-12 lbs/ton coke 1 44.48 110.49 0.69

113

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Coke Calcining 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 1.29E-11 1.45E-11 1.50E-11 9.20E-12 lbs/ton coke 1 24.83 61.68 0.39

Coke Calcining 1 Dioxin/Furan Dioxin:6D Other A3-v0 6.36E-11 6.71E-11 8.96E-11 3.39E-11 lbs/ton coke 1 44.09 109.53 0.65

Coke Calcining 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 1.38E-10 1.18E-10 2.18E-10 7.96E-11 lbs/ton coke 1 51.62 128.22 1.00

Coke Calcining 1 Dioxin/Furan Dioxin:7D Other A3-v0 1.32E-10 1.09E-10 1.90E-10 9.72E-11 lbs/ton coke 1 38.24 95.00 1.00

Coke Calcining 1 Dioxin/Furan Dioxin:8D A3-v0 1.77E-09 1.79E-09 2.76E-09 7.60E-10 lbs/ton coke 1 56.40 140.11 1.00

Coke Calcining 1 Dioxin/Furan Furan:4F 2378 A3-v0 1.33E-11 1.19E-11 1.63E-11 1.18E-11 lbs/ton coke 1 19.13 47.53 0.70

Coke Calcining 1 Dioxin/Furan Furan:4F Other A3-v0 1.39E-10 1.10E-10 2.15E-10 9.21E-11 lbs/ton coke 1 47.70 118.50 1.00

Coke Calcining 1 Dioxin/Furan Furan:5F 12378 A3-v0 1.36E-11 1.43E-11 1.50E-11 1.16E-11 lbs/ton coke 1 13.01 32.31 0.65

Coke Calcining 1 Dioxin/Furan Furan:5F 23478 A3-v0 1.25E-11 1.38E-11 1.46E-11 9.10E-12 lbs/ton coke 1 23.87 59.28 0.63

Coke Calcining 1 Dioxin/Furan Furan:5F Other A3-v0 1.20E-10 9.47E-11 1.79E-10 8.70E-11 lbs/ton coke 1 42.57 105.75 0.74

Coke Calcining 1 Dioxin/Furan Furan:6F 123478 A3-v0 2.44E-11 2.49E-11 2.71E-11 2.12E-11 lbs/ton coke 1 12.27 30.48 1.00

Coke Calcining 1 Dioxin/Furan Furan:6F 123678 A3-v0 2.21E-11 2.19E-11 3.13E-11 1.31E-11 lbs/ton coke 1 41.02 101.91 1.00

Coke Calcining 1 Dioxin/Furan Furan:6F 123789 A3-v0 9.19E-12 8.96E-12 1.20E-11 6.64E-12 lbs/ton coke 1 29.03 72.11 0.67

Coke Calcining 1 Dioxin/Furan Furan:6F 234678 A3-v0 2.01E-11 2.04E-11 2.04E-11 1.96E-11 lbs/ton coke 1 2.55 6.33 1.00

Coke Calcining 1 Dioxin/Furan Furan:6F Other A3-v0 1.52E-10 1.31E-10 2.36E-10 9.04E-11 lbs/ton coke 1 49.18 122.18 1.00

Coke Calcining 1 Dioxin/Furan Furan:7F 1234678 A3-v0 1.50E-10 1.42E-10 1.76E-10 1.32E-10 lbs/ton coke 1 15.51 38.53 1.00

Coke Calcining 1 Dioxin/Furan Furan:7F 1234789 A3-v0 2.56E-11 2.56E-11 2.99E-11 2.12E-11 lbs/ton coke 1 17.09 42.44 0.72

Coke Calcining 1 Dioxin/Furan Furan:7F Other A3-v0 5.16E-11 5.16E-11 5.16E-11 5.16E-11 lbs/ton coke 1 0.00 0.00 0.50

Coke Calcining 1 Dioxin/Furan Furan:8F A3-v1 1.46E-10 1.36E-10 2.86E-10 1.61E-11 lbs/ton coke 1 92.60 230.03 1.00

Coke Calcining 1 Metals Antimony C3-v0 4.61E-05 4.64E-05 4.79E-05 4.41E-05 lbs/ton coke 1 4.04 10.04 0.34

Coke Calcining 1 Metals Arsenic C3-v0 4.66E-06 4.64E-06 4.92E-06 4.41E-06 lbs/ton coke 1 5.42 13.47 0.00

Coke Calcining 1 Metals Barium C3-v0 1.95E-05 1.99E-05 2.46E-05 1.39E-05 lbs/ton coke 1 27.51 68.35 1.00

Coke Calcining 1 Metals Beryllium C3-v0 1.93E-06 1.72E-06 2.43E-06 1.63E-06 lbs/ton coke 1 22.77 56.56 0.42

Coke Calcining 1 Metals Cadmium C3-v0 9.32E-06 9.27E-06 9.84E-06 8.84E-06 lbs/ton coke 1 5.34 13.27 0.00

Coke Calcining 1 Metals Chromium (Hex) C3-v0 6.31E-07 6.30E-07 7.17E-07 5.45E-07 lbs/ton coke 1 13.63 33.85 1.00

Coke Calcining 1 Metals Chromium (Total) C3-v0 2.05E-05 2.04E-05 2.09E-05 2.01E-05 lbs/ton coke 1 1.82 4.52 1.00

Coke Calcining 1 Metals Copper C3-v0 9.32E-06 9.27E-06 9.84E-06 8.84E-06 lbs/ton coke 1 5.34 13.27 0.00

Coke Calcining 1 Metals Lead C3-v0 6.20E-05 4.92E-05 9.27E-05 4.41E-05 lbs/ton coke 1 43.08 107.02 0.50

114

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Coke Calcining 1 Metals Manganese C3-v0 4.56E-05 4.41E-05 7.63E-05 1.63E-05 lbs/ton coke 1 65.87 163.64 0.88

Coke Calcining 1 Metals Mercury C3-v1 4.63E-05 1.63E-05 1.12E-04 1.08E-05 lbs/ton coke 1 122.58 304.51 1.00

Coke Calcining 1 Metals Nickel C3-v0 9.06E-05 4.92E-05 1.76E-04 4.64E-05 lbs/ton coke 1 81.90 203.45 0.65

Coke Calcining 1 Metals Phosphorus C3-v0 4.66E-04 4.64E-04 4.92E-04 4.41E-04 lbs/ton coke 1 5.42 13.47 0.00

Coke Calcining 1 Metals Selenium C3-v0 4.66E-06 4.64E-06 4.92E-06 4.41E-06 lbs/ton coke 1 5.42 13.47 0.00

Coke Calcining 1 Metals Silver C3-v0 1.63E-05 1.63E-05 1.72E-05 1.54E-05 lbs/ton coke 1 5.45 13.55 0.00

Coke Calcining 1 Metals Thallium C3-v0 6.99E-05 6.96E-05 7.38E-05 6.64E-05 lbs/ton coke 1 5.31 13.19 0.00

Coke Calcining 1 Metals Zinc C3-v0 1.17E-04 1.04E-04 1.63E-04 8.37E-05 lbs/ton coke 1 35.15 87.33 1.00

Coke Calcining 1 PAH Acenaphthene A3-v0 1.46E-08 1.38E-08 1.64E-08 1.37E-08 lbs/ton coke 1 10.68 26.52 1.00

Coke Calcining 1 PAH Acenaphthylene A3-v0 1.83E-08 1.69E-08 2.81E-08 9.87E-09 lbs/ton coke 1 50.39 125.18 1.00

Coke Calcining 1 PAH Anthracene A3-v0 1.82E-08 1.84E-08 1.97E-08 1.64E-08 lbs/ton coke 1 9.02 22.40 1.00

Coke Calcining 1 PAH Benzo(a)anthracene A3-v0 8.71E-09 8.25E-09 1.02E-08 7.67E-09 lbs/ton coke 1 15.15 37.64 0.39

Coke Calcining 1 PAH Benzo(a)pyrene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Benzo(b)fluoranthene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Benzo(g,h,i)perylene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Benzo(k)fluoranthene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Chrysene A3-v0 1.28E-08 1.18E-08 1.84E-08 8.25E-09 lbs/ton coke 1 40.02 99.41 0.79

Coke Calcining 1 PAH Dibenz(a,h)anthracene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Fluoranthene A3-v0 3.58E-08 3.30E-08 4.30E-08 3.13E-08 lbs/ton coke 1 17.64 43.82 1.00

Coke Calcining 1 PAH Fluorene A3-v0 5.64E-08 5.21E-08 6.61E-08 5.10E-08 lbs/ton coke 1 14.90 37.02 1.00

Coke Calcining 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 8.05E-09 8.22E-09 8.25E-09 7.67E-09 lbs/ton coke 1 4.04 10.04 0.00

Coke Calcining 1 PAH Naphthalene A3-v0 2.41E-06 2.46E-06 3.14E-06 1.64E-06 lbs/ton coke 1 31.02 77.06 1.00

Coke Calcining 1 PAH Phenanthrene A3-v0 1.88E-07 1.81E-07 2.15E-07 1.69E-07 lbs/ton coke 1 12.67 31.48 1.00

Coke Calcining 1 PAH Pyrene A3-v0 2.67E-08 2.64E-08 3.23E-08 2.15E-08 lbs/ton coke 1 20.27 50.36 1.00

Coke Calcining 1 VOC Acetaldehyde A3-v0 1.02E-03 1.16E-03 1.22E-03 6.77E-04 lbs/ton coke 1 29.23 72.60 1.00

Coke Calcining 1 VOC Acrolein A3-v0 3.36E-04 3.41E-04 3.60E-04 3.08E-04 lbs/ton coke 1 7.79 19.36 0.00

Coke Calcining 1 VOC Benzene C3-v0 3.24E-04 4.06E-04 4.50E-04 1.15E-04 lbs/ton coke 1 56.20 139.61 1.00

Coke Calcining 1 VOC Formaldehyde A3-v0 3.36E-04 3.41E-04 3.60E-04 3.08E-04 lbs/ton coke 1 7.79 19.36 0.00

115

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Coke Calcining 1 VOC Toluene C3-v0 5.34E-05 4.46E-05 7.17E-05 4.39E-05 lbs/ton coke 1 29.73 73.85 1.00

Coke Calcining 1 VOC Xylene (m,p) C3-v0 3.09E-05 3.44E-05 3.79E-05 2.04E-05 lbs/ton coke 1 29.89 74.24 0.22

Coke Calcining 1 VOC Xylene (o) C3-v0 4.49E-05 4.34E-05 4.79E-05 4.34E-05 lbs/ton coke 1 5.72 14.20 0.00

Crematory 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 9.51E-11 9.51E-11 1.50E-10 3.98E-11 lbs/body 1 82.27 739.14 1.00

Crematory 1 Dioxin/Furan Dioxin:4D Total A3-v0 1.99E-09 1.99E-09 3.02E-09 9.55E-10 lbs/body 1 73.54 660.69 1.00

Crematory 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 3.18E-10 3.18E-10 4.42E-10 1.94E-10 lbs/body 1 55.11 495.15 1.00

Crematory 1 Dioxin/Furan Dioxin:5D Total A3-v1 2.93E-09 2.93E-09 5.11E-09 7.36E-10 lbs/body 1 105.84 950.95 1.00

Crematory 1 Dioxin/Furan Dioxin:6D 123478 A3-v1 3.73E-10 3.73E-10 6.26E-10 1.19E-10 lbs/body 1 96.13 863.71 1.00

Crematory 1 Dioxin/Furan Dioxin:6D 123678 A3-v1 5.55E-10 5.55E-10 9.51E-10 1.59E-10 lbs/body 1 100.88 906.40 1.00

Crematory 1 Dioxin/Furan Dioxin:6D 123789 A3-v1 7.13E-10 7.13E-10 1.28E-09 1.49E-10 lbs/body 1 111.82 1004.66 1.00

Crematory 1 Dioxin/Furan Dioxin:6D Total A3-v0 7.74E-09 7.74E-09 1.28E-08 2.69E-09 lbs/body 1 92.24 828.76 1.00

Crematory 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 5.41E-09 5.41E-09 8.37E-09 2.45E-09 lbs/body 1 77.42 695.61 1.00

Crematory 1 Dioxin/Furan Dioxin:7D Total A3-v0 1.16E-08 1.16E-08 1.74E-08 5.75E-09 lbs/body 1 71.28 640.39 1.00

Crematory 1 Dioxin/Furan Dioxin:8D A3-v0 8.60E-09 8.60E-09 1.02E-08 6.97E-09 lbs/body 1 26.75 240.35 1.00

Crematory 1 Dioxin/Furan Furan:4F 2378 A3-v1 4.75E-10 4.75E-10 8.01E-10 1.49E-10 lbs/body 1 97.00 871.51 1.00

Crematory 1 Dioxin/Furan Furan:4F Total A3-v1 1.47E-08 1.47E-08 2.56E-08 3.79E-09 lbs/body 1 104.87 942.19 1.00

Crematory 1 Dioxin/Furan Furan:5F 12378 A3-v0 4.12E-10 4.12E-10 6.74E-10 1.49E-10 lbs/body 1 90.20 810.37 0.82

Crematory 1 Dioxin/Furan Furan:5F 23478 A3-v1 9.63E-10 9.63E-10 1.74E-09 1.84E-10 lbs/body 1 114.40 1027.87 0.90

Crematory 1 Dioxin/Furan Furan:5F Total A3-v1 8.31E-09 8.31E-09 1.63E-08 3.53E-10 lbs/body 1 135.41 1216.63 1.00

Crematory 1 Dioxin/Furan Furan:6F 123478 A3-v1 1.16E-09 1.16E-09 1.97E-09 3.43E-10 lbs/body 1 99.56 894.48 1.00

Crematory 1 Dioxin/Furan Furan:6F 123678 A3-v1 1.15E-09 1.15E-09 1.97E-09 3.18E-10 lbs/body 1 102.17 917.96 1.00

Crematory 1 Dioxin/Furan Furan:6F 123789 A3-v1 2.20E-09 2.20E-09 3.72E-09 6.86E-10 lbs/body 1 97.34 874.59 1.00

Crematory 1 Dioxin/Furan Furan:6F 234678 A3-v1 4.38E-10 4.38E-10 7.42E-10 1.34E-10 lbs/body 1 98.11 881.45 1.00

Crematory 1 Dioxin/Furan Furan:6F Total A3-v1 1.46E-08 1.46E-08 2.56E-08 3.67E-09 lbs/body 1 105.91 951.60 1.00

Crematory 1 Dioxin/Furan Furan:7F 1234678 A3-v1 6.79E-09 6.79E-09 1.15E-08 2.08E-09 lbs/body 1 98.14 881.77 0.85

Crematory 1 Dioxin/Furan Furan:7F 1234789 A3-v1 4.16E-10 4.16E-10 7.76E-10 5.47E-11 lbs/body 1 122.81 1103.37 0.93

Crematory 1 Dioxin/Furan Furan:7F Total A3-v1 8.01E-09 8.01E-09 1.39E-08 2.08E-09 lbs/body 1 104.72 940.90 0.87

Crematory 1 Dioxin/Furan Furan:8F A3-v0 2.13E-09 2.13E-09 2.67E-09 1.59E-09 lbs/body 1 35.90 322.51 1.00

116

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Crematory 1 Halogens HCl C3-v0 6.75E-02 6.75E-02 9.47E-02 4.02E-02 lbs/body 1 57.06 512.62 1.00

Crematory 1 Halogens HF C3-v1 7.57E-04 7.57E-04 1.41E-03 1.01E-04 lbs/body 1 122.53 1100.90 1.00

Crematory 1 Metals Arsenic C3-v0 4.46E-05 4.46E-05 6.16E-05 2.76E-05 lbs/body 1 53.90 484.27 0.69

Crematory 1 Metals Barium C3-v0 2.19E-05 2.19E-05 2.60E-05 1.79E-05 lbs/body 1 25.86 232.35 1.00

Crematory 1 Metals Beryllium C3-v1 1.54E-06 1.54E-06 2.60E-06 4.85E-07 lbs/body 1 96.92 870.80 1.00

Crematory 1 Metals Cadmium C3-v0 9.95E-06 9.95E-06 1.02E-05 9.73E-06 lbs/body 1 3.15 28.29 1.00

Crematory 1 Metals Chromium (Hex) C3-v0 1.60E-05 1.60E-05 1.96E-05 1.24E-05 lbs/body 1 31.58 283.72 1.00

Crematory 1 Metals Chromium (Total) C3-v0 3.34E-05 3.42E-05 4.27E-05 2.27E-05 lbs/body 2 25.09 39.93 0.44

Crematory 1 Metals Cobalt C3-v1 7.76E-06 7.76E-06 1.36E-05 1.95E-06 lbs/body 1 105.93 951.78 0.13

Crematory 1 Metals Copper C3-v0 2.89E-05 2.89E-05 2.92E-05 2.86E-05 lbs/body 1 1.49 13.38 1.00

Crematory 1 Metals Lead C3-v0 6.27E-05 6.27E-05 6.29E-05 6.25E-05 lbs/body 1 0.48 4.34 1.00

Crematory 1 Metals Mercury C3-v0 4.88E-03 4.88E-03 4.99E-03 4.77E-03 lbs/body 1 3.17 28.50 1.00

Crematory 1 Metals Nickel C3-v0 3.63E-05 3.63E-05 3.83E-05 3.44E-05 lbs/body 1 7.54 67.78 1.00

Crematory 1 Metals Selenium C3-v0 4.35E-05 4.35E-05 4.48E-05 4.22E-05 lbs/body 1 4.25 38.19 0.00

Crematory 1 Metals Silver C3-v0 7.86E-06 7.86E-06 1.23E-05 3.39E-06 lbs/body 1 80.39 722.28 1.00

Crematory 1 Metals Zinc C3-v0 3.47E-04 3.47E-04 4.06E-04 2.88E-04 lbs/body 1 23.95 215.22 1.00

Crematory 1 PAH Acenaphthene C3-v0 1.14E-07 1.14E-07 1.16E-07 1.12E-07 lbs/body 1 2.26 20.33 1.00

Crematory 1 PAH Acenaphthylene C3-v0 7.85E-08 7.85E-08 8.38E-08 7.31E-08 lbs/body 1 9.63 86.51 0.53

Crematory 1 PAH Anthracene C3-v0 2.09E-07 2.09E-07 2.50E-07 1.68E-07 lbs/body 1 27.85 250.26 1.00

Crematory 1 PAH Benzo(a)anthracene C3-v0 1.02E-08 1.02E-08 1.30E-08 7.38E-09 lbs/body 1 39.19 352.12 0.00

Crematory 1 PAH Benzo(a)pyrene C3-v0 4.13E-08 4.13E-08 6.60E-08 1.65E-08 lbs/body 1 84.85 762.37 0.80

Crematory 1 PAH Benzo(b)fluoranthene C3-v0 1.52E-08 1.52E-08 1.84E-08 1.20E-08 lbs/body 1 30.15 270.89 0.00

Crematory 1 PAH Benzo(g,h,i)perylene C3-v0 5.14E-08 5.14E-08 6.18E-08 4.11E-08 lbs/body 1 28.49 255.96 0.60

Crematory 1 PAH Benzo(k)fluoranthene C3-v0 1.30E-08 1.30E-08 1.46E-08 1.14E-08 lbs/body 1 17.20 154.51 0.00

Crematory 1 PAH Chrysene C3-v0 2.52E-08 2.52E-08 3.03E-08 2.01E-08 lbs/body 1 28.67 257.58 0.00

Crematory 1 PAH Dibenz(a,h)anthracene C3-v0 1.18E-08 1.18E-08 1.36E-08 9.99E-09 lbs/body 1 21.51 193.22 0.00

Crematory 1 PAH Fluoranthene C3-v0 1.17E-07 1.17E-07 1.52E-07 8.21E-08 lbs/body 1 42.07 378.00 1.00

Crematory 1 PAH Fluorene C3-v0 3.29E-07 3.29E-07 3.39E-07 3.19E-07 lbs/body 1 4.43 39.82 1.00

117

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Crematory 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 1.26E-08 1.26E-08 1.46E-08 1.07E-08 lbs/body 1 21.69 194.86 0.00

Crematory 1 PAH Naphthalene C3-v0 6.58E-05 6.58E-05 6.78E-05 6.37E-05 lbs/body 1 4.43 39.78 1.00

Crematory 1 PAH Phenanthrene C3-v0 1.34E-06 1.34E-06 1.78E-06 9.05E-07 lbs/body 1 46.25 415.55 1.00

Crematory 1 PAH Pyrene C3-v0 1.29E-07 1.29E-07 1.64E-07 9.39E-08 lbs/body 1 38.55 346.36 1.00

Crematory 1 VOC Acetaldehyde C3-v1 8.11E-05 8.11E-05 1.39E-04 2.28E-05 lbs/body 1 101.69 913.65 1.00

Crematory 1 VOC Formaldehyde C3-v0 2.16E-05 2.16E-05 2.99E-05 1.32E-05 lbs/body 1 54.86 492.90 1.00

Dehydrator, Sludge 1 Metals Barium D3-v- 3.29E-07 3.29E-07 3.29E-07 3.29E-07 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Cadmium D3-v- 1.64E-07 1.64E-07 1.64E-07 1.64E-07 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Chromium (Total) D3-v- 6.33E-06 6.33E-06 6.33E-06 6.33E-06 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Cobalt D3-v- 1.23E-06 1.23E-06 1.23E-06 1.23E-06 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Copper D3-v- 4.02E-06 4.02E-06 4.02E-06 4.02E-06 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Lead D3-v- 4.93E-07 4.93E-07 4.93E-07 4.93E-07 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Mercury D3-v- 1.64E-08 1.64E-08 1.64E-08 1.64E-08 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Nickel D3-v- 1.31E-04 1.31E-04 1.31E-04 1.31E-04 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Silver D3-v- 1.64E-07 1.64E-07 1.64E-07 1.64E-07 lbs/ton 1 0.00 0.00 1.00

Dehydrator, Sludge 1 Metals Zinc D3-v- 3.37E-06 3.37E-06 3.37E-06 3.37E-06 lbs/ton 1 0.00 0.00 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.69E-09 1.50E-09 2.31E-09 1.27E-09 lbs/ton production 1 32.30 80.25 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 7.28E-09 5.62E-09 1.07E-08 5.50E-09 lbs/ton production 1 40.84 101.46 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 5.64E-09 4.37E-09 9.03E-09 3.52E-09 lbs/ton production 1 52.57 130.58 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 8.24E-09 5.83E-09 1.43E-08 4.62E-09 lbs/ton production 1 63.83 158.56 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 4.04E-09 3.74E-09 5.04E-09 3.33E-09 lbs/ton production 1 22.08 54.84 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 3.86E-08 2.71E-08 6.93E-08 1.96E-08 lbs/ton production 1 69.34 172.26 1.00

Delaquering, Aluminum 1 Dioxin/Furan Dioxin:8D A3-v1 4.85E-08 3.33E-08 9.37E-08 1.85E-08 lbs/ton production 1 82.17 204.11 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:4F 2378 A3-v0 9.68E-09 1.21E-08 1.32E-08 3.74E-09 lbs/ton production 1 53.49 132.88 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:5F 12378 A3-v0 2.36E-08 1.77E-08 3.57E-08 1.74E-08 lbs/ton production 1 44.43 110.38 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:5F 23478 A3-v0 4.66E-08 3.54E-08 7.14E-08 3.30E-08 lbs/ton production 1 46.15 114.64 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:6F 123478 A3-v0 3.53E-08 2.50E-08 5.88E-08 2.20E-08 lbs/ton production 1 57.95 143.95 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:6F 123678 A3-v0 3.39E-08 2.50E-08 5.46E-08 2.20E-08 lbs/ton production 1 53.21 132.17 1.00

118

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Delaquering, Aluminum 1 Dioxin/Furan Furan:6F 123789 A3-v0 2.69E-09 3.12E-09 3.99E-09 9.67E-10 lbs/ton production 1 57.77 143.50 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:6F 234678 A3-v0 3.19E-08 2.71E-08 5.25E-08 1.63E-08 lbs/ton production 1 58.20 144.56 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:7F 1234678 A3-v0 8.52E-08 6.67E-08 1.41E-07 4.84E-08 lbs/ton production 1 57.33 142.42 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:7F 1234789 A3-v0 1.24E-08 1.17E-08 1.60E-08 9.67E-09 lbs/ton production 1 25.82 64.13 1.00

Delaquering, Aluminum 1 Dioxin/Furan Furan:8F A3-v0 5.91E-08 4.79E-08 1.03E-07 2.64E-08 lbs/ton production 1 66.74 165.79 1.00

Delaquering, Aluminum 1 Halogens HCl A3-v0 3.21E+00 2.83E+00 4.30E+00 2.49E+00 lbs/ton production 1 30.03 74.60 1.00

Delaquering, Aluminum 1 Metals Antimony A3-v0 9.22E-05 9.57E-05 9.61E-05 8.49E-05 lbs/ton production 1 6.86 17.05 1.00

Delaquering, Aluminum 1 Metals Arsenic C3-v0 2.13E-05 1.97E-05 2.73E-05 1.67E-05 lbs/ton production 1 25.64 63.70 1.00

Delaquering, Aluminum 1 Metals Beryllium A3-v0 1.38E-06 1.38E-06 1.38E-06 1.38E-06 lbs/ton production 1 0.00 0.00 0.00

Delaquering, Aluminum 1 Metals Cadmium A3-v0 2.29E-05 2.74E-05 3.25E-05 8.68E-06 lbs/ton production 1 54.88 136.33 1.00

Delaquering, Aluminum 1 Metals Chromium (Hex) C3-v0 1.02E-05 1.01E-05 1.05E-05 9.95E-06 lbs/ton production 1 2.97 7.37 0.00

Delaquering, Aluminum 1 Metals Chromium (Total) C3-v0 3.77E-05 3.80E-05 4.04E-05 3.47E-05 lbs/ton production 1 7.53 18.70 1.00

Delaquering, Aluminum 1 Metals Copper A3-v0 7.93E-04 7.83E-04 8.90E-04 7.05E-04 lbs/ton production 1 11.74 29.15 1.00

Delaquering, Aluminum 1 Metals Lead A3-v0 2.15E-02 2.12E-02 2.25E-02 2.10E-02 lbs/ton production 1 3.93 9.77 1.00

Delaquering, Aluminum 1 Metals Manganese A3-v0 5.11E-04 4.60E-04 6.44E-04 4.28E-04 lbs/ton production 1 22.83 56.71 1.00

Delaquering, Aluminum 1 Metals Nickel A3-v0 1.24E-04 1.09E-04 2.12E-04 4.98E-05 lbs/ton production 1 66.39 164.91 1.00

Delaquering, Aluminum 1 Metals Selenium A3-v0 2.85E-06 2.76E-06 3.03E-06 2.76E-06 lbs/ton production 1 5.59 13.88 0.00

Delaquering, Aluminum 1 Metals Zinc A3-v0 2.30E-03 2.25E-03 2.52E-03 2.13E-03 lbs/ton production 1 8.61 21.39 1.00

Delaquering, Aluminum 1 VOC Acetaldehyde A3-v1 2.14E-05 2.96E-05 2.97E-05 4.80E-06 lbs/ton production 1 67.13 166.77 0.93

Delaquering, Aluminum 1 VOC Formaldehyde A3-v1 2.75E-04 1.59E-04 5.66E-04 1.01E-04 lbs/ton production 1 92.00 228.53 1.00

Drum Burning Furnace 1 Halogens HCl C3-v0 9.69E-04 6.94E-04 1.74E-03 4.70E-04 lbs/drum 1 70.23 174.46 1.00

Drum Burning Furnace 1 Metals Arsenic C3-v0 9.01E-07 9.59E-07 1.09E-06 6.58E-07 lbs/drum 1 24.38 60.55 0.40

Drum Burning Furnace 1 Metals Beryllium C3-v0 9.01E-07 9.59E-07 1.09E-06 6.58E-07 lbs/drum 1 24.38 60.55 0.00

Drum Burning Furnace 1 Metals Cadmium C3-v0 1.29E-05 1.18E-05 1.94E-05 7.53E-06 lbs/drum 1 46.41 115.29 1.00

Drum Burning Furnace 1 Metals Chromium (Hex) C3-v0 7.11E-06 7.18E-06 7.40E-06 6.75E-06 lbs/drum 1 4.65 11.55 1.00

Drum Burning Furnace 1 Metals Chromium (Total) C3-v0 1.04E-05 1.09E-05 1.12E-05 9.06E-06 lbs/drum 1 11.05 27.45 1.00

Drum Burning Furnace 1 Metals Copper C3-v0 2.54E-05 2.24E-05 3.41E-05 1.99E-05 lbs/drum 1 29.89 74.24 1.00

Drum Burning Furnace 1 Metals Lead C3-v0 3.75E-04 3.98E-04 4.98E-04 2.30E-04 lbs/drum 1 36.01 89.45 1.00

119

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Drum Burning Furnace 1 Metals Manganese C3-v0 9.14E-06 7.53E-06 1.40E-05 5.92E-06 lbs/drum 1 46.51 115.53 1.00

Drum Burning Furnace 1 Metals Mercury C3-v0 6.67E-07 7.53E-07 8.53E-07 3.95E-07 lbs/drum 1 36.12 89.73 0.20

Drum Burning Furnace 1 Metals Nickel C3-v0 7.11E-06 7.53E-06 8.53E-06 5.26E-06 lbs/drum 1 23.54 58.47 0.00

Drum Burning Furnace 1 Metals Selenium C3-v0 9.01E-07 9.59E-07 1.09E-06 6.58E-07 lbs/drum 1 24.38 60.55 1.00

Drum Burning Furnace 1 Metals Zinc C3-v1 4.37E-04 1.38E-04 1.06E-03 1.10E-04 lbs/drum 1 124.10 308.29 1.00

Drum Burning Furnace 1 PAH Acenaphthene A3-v2 1.76E-07 9.98E-09 5.11E-07 5.54E-09 lbs/drum 1 165.56 411.27 1.00

Drum Burning Furnace 1 PAH Acenaphthylene A3-v1 4.43E-08 1.08E-08 1.15E-07 6.92E-09 lbs/drum 1 138.58 344.25 1.00

Drum Burning Furnace 1 PAH Anthracene A3-v1 1.64E-07 4.24E-08 4.31E-07 1.94E-08 lbs/drum 1 140.82 349.82 1.00

Drum Burning Furnace 1 PAH Benzo(a)anthracene A3-v0 2.34E-08 2.63E-08 3.24E-08 1.14E-08 lbs/drum 1 46.16 114.66 1.00

Drum Burning Furnace 1 PAH Benzo(a)pyrene A3-v0 3.76E-09 2.77E-09 5.82E-09 2.69E-09 lbs/drum 1 47.48 117.94 0.00

Drum Burning Furnace 1 PAH Benzo(b)fluoranthene A3-v0 8.09E-09 7.61E-09 1.33E-08 3.36E-09 lbs/drum 1 61.63 153.09 1.00

Drum Burning Furnace 1 PAH Benzo(g,h,i)perylene A3-v0 3.76E-09 2.77E-09 5.82E-09 2.69E-09 lbs/drum 1 47.48 117.94 0.00

Drum Burning Furnace 1 PAH Benzo(k)fluoranthene A3-v0 3.76E-09 2.77E-09 5.82E-09 2.69E-09 lbs/drum 1 47.48 117.94 0.00

Drum Burning Furnace 1 PAH Chrysene A3-v0 4.45E-09 4.15E-09 5.82E-09 3.36E-09 lbs/drum 1 28.22 70.10 1.00

Drum Burning Furnace 1 PAH Dibenz(a,h)anthracene A3-v0 3.76E-09 2.77E-09 5.82E-09 2.69E-09 lbs/drum 1 47.48 117.94 0.00

Drum Burning Furnace 1 PAH Fluoranthene A3-v0 3.60E-08 4.08E-08 4.57E-08 2.15E-08 lbs/drum 1 35.46 88.08 1.00

Drum Burning Furnace 1 PAH Fluorene A3-v1 3.92E-07 5.74E-08 1.09E-06 2.77E-08 lbs/drum 1 154.47 383.74 1.00

Drum Burning Furnace 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 3.76E-09 2.77E-09 5.82E-09 2.69E-09 lbs/drum 1 47.48 117.94 0.00

Drum Burning Furnace 1 PAH Naphthalene A3-v1 1.06E-06 5.77E-07 2.30E-06 3.14E-07 lbs/drum 1 101.40 251.90 1.00

Drum Burning Furnace 1 PAH Phenanthrene A3-v0 3.00E-07 1.89E-07 5.34E-07 1.78E-07 lbs/drum 1 67.44 167.54 1.00

Drum Burning Furnace 1 PAH Pyrene A3-v0 4.39E-08 3.99E-08 5.72E-08 3.46E-08 lbs/drum 1 26.89 66.81 1.00

Drum Burning Furnace 1 VOC Benzene C3-v0 2.22E-05 2.35E-05 2.35E-05 1.95E-05 lbs/drum 1 10.31 25.62 0.00

Drum Burning Furnace 1 VOC Formaldehyde C3-v0 6.96E-05 7.20E-05 7.72E-05 5.96E-05 lbs/drum 1 12.95 32.17 1.00

Drum Burning Furnace 1 VOC Vinyl Chloride A3-v0 1.87E-05 1.98E-05 1.98E-05 1.64E-05 lbs/drum 1 10.31 25.62 0.00

Dryer, Fiberboard 1 VOC Formaldehyde A3-v0 4.66E-02 4.96E-02 5.19E-02 3.84E-02 lbs/ton production 1 15.48 38.46 1.00

Dryer, Pot ash 1 Metals Arsenic A3-v1 4.86E-03 1.69E-03 1.19E-02 1.02E-03 lbs/ton ore 1 125.06 310.68 1.00

Dryer, Pot ash 1 Metals Beryllium A3-v0 1.04E-05 1.32E-05 1.35E-05 4.56E-06 lbs/ton ore 1 48.81 121.25 0.42

Dryer, Pot ash 1 Metals Lead A3-v0 5.20E-05 6.62E-05 6.76E-05 2.21E-05 lbs/ton ore 1 49.86 123.85 0.42

120

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Dryer, Pot ash 1 SVOC 1,2-Dichlorobenzene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 SVOC Ethylbenzene A3-v0 8.79E-06 9.09E-06 9.09E-06 8.18E-06 lbs/ton ore 1 5.97 14.84 0.00

Dryer, Pot ash 1 VOC 1,1,1-Trichloroethane A3-v2 6.18E-05 1.82E-06 1.82E-04 1.82E-06 lbs/ton ore 1 168.11 417.61 0.98

Dryer, Pot ash 1 VOC 1,1,2,2-Tetrachloroethane A3-v0 3.64E-06 3.64E-06 3.64E-06 3.64E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,1,2-Trichloroethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,1-Dichloroethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,1-Dichloroethene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,2-Dichloroethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,2-Dichloroethene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC 1,2-Dichloropropane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Acetone A3-v2 3.38E+00 1.09E-01 1.00E+01 4.36E-02 lbs/ton ore 1 169.30 420.56 1.00

Dryer, Pot ash 1 VOC Benzene A3-v1 1.63E-04 1.78E-04 2.73E-04 3.82E-05 lbs/ton ore 1 72.38 179.81 1.00

Dryer, Pot ash 1 VOC Bromodichloromethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Bromoform A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Bromomethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Carbon disulfide A3-v1 2.24E-05 1.82E-06 6.36E-05 1.82E-06 lbs/ton ore 1 159.16 395.38 0.00

Dryer, Pot ash 1 VOC Carbon Tetrachloride A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Chlorobenzene A3-v0 2.73E-06 2.73E-06 3.64E-06 1.82E-06 lbs/ton ore 1 47.14 423.54 1.00

Dryer, Pot ash 1 VOC Chloroethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Chloroform A3-v0 8.79E-06 9.09E-06 9.09E-06 8.18E-06 lbs/ton ore 1 5.97 14.84 0.00

Dryer, Pot ash 1 VOC Chloromethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Dibromochloromethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Dichloromethane A3-v1 1.19E-02 4.55E-03 2.73E-02 4.00E-03 lbs/ton ore 1 111.24 276.35 1.00

Dryer, Pot ash 1 VOC Formaldehyde C3-v0 6.42E-03 6.73E-03 8.91E-03 3.64E-03 lbs/ton ore 1 41.24 102.45 1.00

Dryer, Pot ash 1 VOC Methyl Ethyl Ketone A3-v1 1.81E-04 7.27E-05 4.18E-04 5.09E-05 lbs/ton ore 1 114.08 283.39 1.00

Dryer, Pot ash 1 VOC Styrene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Tetrachloroethene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Toluene A3-v1 8.48E-05 1.04E-04 1.33E-04 1.82E-05 lbs/ton ore 1 70.17 174.31 1.00

121

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Dryer, Pot ash 1 VOC Trichloroethene A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Trichlorofluoromethane A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Vinyl Chloride A3-v0 1.82E-06 1.82E-06 1.82E-06 1.82E-06 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 1 VOC Xylene (Total) A3-v2 8.73E-05 3.64E-06 2.55E-04 3.64E-06 lbs/ton ore 1 165.99 412.34 0.97

Dryer, Pot ash 2 Metals Arsenic A3-v0 2.40E-03 2.33E-03 3.00E-03 1.86E-03 lbs/ton ore 1 23.95 59.50 1.00

Dryer, Pot ash 2 Metals Beryllium C3-v0 2.87E-04 3.43E-04 3.71E-04 1.47E-04 lbs/ton ore 1 42.63 105.91 0.00

Dryer, Pot ash 2 Metals Lead A3-v0 1.43E-03 1.71E-03 1.86E-03 7.33E-04 lbs/ton ore 1 42.63 105.91 0.00

Dryer, Pot ash 2 SVOC 1,2-Dichlorobenzene C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 SVOC Ethylbenzene C3-v1 3.58E-04 4.43E-05 1.00E-03 3.00E-05 lbs/ton ore 1 155.25 385.67 0.93

Dryer, Pot ash 2 VOC 1,1,1-Trichloroethane C3-v1 6.76E-03 4.43E-03 1.39E-02 2.00E-03 lbs/ton ore 1 92.63 230.10 1.00

Dryer, Pot ash 2 VOC 1,1,2,2-Tetrachloroethane C3-v1 6.30E-04 7.29E-04 1.09E-03 7.43E-05 lbs/ton ore 1 81.48 202.41 0.96

Dryer, Pot ash 2 VOC 1,1,2-Trichloroethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC 1,1-Dichloroethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC 1,1-Dichloroethene C3-v0 6.43E-05 4.43E-05 1.19E-04 3.00E-05 lbs/ton ore 1 73.97 183.75 0.61

Dryer, Pot ash 2 VOC 1,2-Dichloroethane C3-v0 7.24E-05 4.43E-05 1.43E-04 3.00E-05 lbs/ton ore 1 84.90 210.90 0.66

Dryer, Pot ash 2 VOC 1,2-Dichloroethene C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC 1,2-Dichloropropane C3-v1 1.19E-04 1.43E-04 2.00E-04 1.43E-05 lbs/ton ore 1 79.90 198.48 0.56

Dryer, Pot ash 2 VOC Acetone C3-v- 4.43E-03 4.43E-03 4.43E-03 4.43E-03 lbs/ton ore 1 0.00 0.00 0.00

Dryer, Pot ash 2 VOC Benzene C3-v0 1.33E-02 1.57E-02 1.86E-02 5.57E-03 lbs/ton ore 1 51.42 127.74 1.00

Dryer, Pot ash 2 VOC Bromodichloromethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Bromoform C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Bromomethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Carbon disulfide C3-v- 8.00E-04 8.00E-04 8.00E-04 8.00E-04 lbs/ton ore 1 0.00 0.00 1.00

Dryer, Pot ash 2 VOC Carbon Tetrachloride C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Chlorobenzene C3-v0 7.43E-04 7.86E-04 9.43E-04 5.00E-04 lbs/ton ore 1 30.22 75.08 1.00

Dryer, Pot ash 2 VOC Chloroethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Chloroform C3-v1 1.10E-04 3.00E-05 2.71E-04 3.00E-05 lbs/ton ore 1 126.17 313.43 0.82

Dryer, Pot ash 2 VOC Chloromethane C3-v1 3.34E-04 4.71E-04 4.86E-04 4.43E-05 lbs/ton ore 1 75.14 186.67 0.96

122

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Dryer, Pot ash 2 VOC Dibromochloromethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Dichloromethane C3-v1 1.38E-01 9.71E-02 3.00E-01 1.57E-02 lbs/ton ore 1 106.38 264.27 1.00

Dryer, Pot ash 2 VOC Formaldehyde A3-v0 2.29E-01 2.14E-01 2.71E-01 2.00E-01 lbs/ton ore 1 16.54 41.08 1.00

Dryer, Pot ash 2 VOC Methyl Ethyl Ketone C3-v2 1.49E-02 4.43E-03 4.00E-02 1.86E-04 lbs/ton ore 1 147.03 365.24 0.10

Dryer, Pot ash 2 VOC Styrene C3-v1 7.36E-04 7.36E-04 1.43E-03 4.43E-05 lbs/ton ore 1 132.92 1194.21 0.97

Dryer, Pot ash 2 VOC Tetrachloroethene C3-v0 3.52E-05 4.43E-05 4.43E-05 1.71E-05 lbs/ton ore 1 44.47 110.47 0.00

Dryer, Pot ash 2 VOC Toluene C3-v0 1.34E-02 1.34E-02 1.43E-02 1.26E-02 lbs/ton ore 1 9.03 81.10 1.00

Dryer, Pot ash 2 VOC Trichloroethene C3-v1 1.83E-04 1.19E-04 4.00E-04 3.00E-05 lbs/ton ore 1 105.65 262.46 0.73

Dryer, Pot ash 2 VOC Trichlorofluoromethane C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Vinyl Chloride C3-v0 3.95E-05 4.43E-05 4.43E-05 3.00E-05 lbs/ton ore 1 20.87 51.84 0.00

Dryer, Pot ash 2 VOC Xylene (Total) C3-v0 3.00E-03 3.29E-03 3.43E-03 2.29E-03 lbs/ton ore 1 20.76 51.56 1.00

Dryer, Sand/Gravel 1 VOC Benzene A3-v0 7.72E-04 5.59E-04 1.29E-03 4.72E-04 lbs/ton production 1 57.87 143.75 1.00

Dryer, Sand/Gravel 2 PAH Acenaphthene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Acenaphthylene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Anthracene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Benzo(a)anthracene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Benzo(a)pyrene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Benzo(b)fluoranthene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Benzo(g,h,i)perylene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Benzo(k)fluoranthene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Chrysene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Dibenz(a,h)anthracene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Fluoranthene C3-v0 6.63E-06 8.03E-06 8.27E-06 3.58E-06 lbs/ton production 1 39.91 99.14 0.82

Dryer, Sand/Gravel 2 PAH Fluorene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Indeno(1,2,3-cd)pyrene C3-v0 1.79E-05 1.79E-05 1.79E-05 1.79E-05 lbs/ton production 1 0.00 0.00 0.00

Dryer, Sand/Gravel 2 PAH Naphthalene C3-v0 5.90E-05 5.07E-05 8.66E-05 3.96E-05 lbs/ton production 1 41.62 103.38 1.00

Dryer, Sand/Gravel 2 PAH Phenanthrene C3-v1 1.55E-05 2.08E-05 2.23E-05 3.58E-06 lbs/ton production 1 66.85 166.06 0.92

Dryer, Sand/Gravel 2 PAH Pyrene C3-v0 3.58E-06 3.58E-06 3.58E-06 3.58E-06 lbs/ton production 1 0.00 0.00 0.00

123

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Dryer, Sand/Gravel 2 VOC Formaldehyde A3-v2 4.26E-03 3.31E-03 9.31E-03 1.69E-04 lbs/ton production 1 108.97 270.70 1.00

FBC, Biomass 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 2.89E-11 3.18E-11 3.74E-11 1.75E-11 lbs/ton 1 35.59 88.41 0.00

FBC, Biomass 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 3.28E-11 3.22E-11 4.45E-11 2.17E-11 lbs/ton 1 34.79 86.43 0.00

FBC, Biomass 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 4.36E-11 4.49E-11 4.76E-11 3.82E-11 lbs/ton 1 11.17 27.75 0.29

FBC, Biomass 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 6.38E-11 5.10E-11 9.53E-11 4.49E-11 lbs/ton 1 43.16 107.21 0.50

FBC, Biomass 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 4.77E-11 4.42E-11 5.72E-11 4.18E-11 lbs/ton 1 17.34 43.08 0.40

FBC, Biomass 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 6.90E-10 6.10E-10 9.19E-10 5.40E-10 lbs/ton 1 29.24 72.64 1.00

FBC, Biomass 1 Dioxin/Furan Dioxin:8D A3-v0 6.69E-09 6.74E-09 9.19E-09 4.13E-09 lbs/ton 1 37.79 93.87 1.00

FBC, Biomass 1 Dioxin/Furan Furan:4F 2378 A3-v0 1.29E-10 1.09E-10 1.88E-10 8.85E-11 lbs/ton 1 40.85 101.48 1.00

FBC, Biomass 1 Dioxin/Furan Furan:5F 12378 A3-v0 6.27E-11 5.10E-11 8.89E-11 4.81E-11 lbs/ton 1 36.33 90.26 1.00

FBC, Biomass 1 Dioxin/Furan Furan:5F 23478 A3-v0 1.03E-10 1.02E-10 1.31E-10 7.71E-11 lbs/ton 1 26.05 64.70 1.00

FBC, Biomass 1 Dioxin/Furan Furan:6F 123478 A3-v0 7.59E-11 6.67E-11 1.19E-10 4.18E-11 lbs/ton 1 52.08 129.37 1.00

FBC, Biomass 1 Dioxin/Furan Furan:6F 123678 A3-v0 1.12E-10 9.21E-11 1.70E-10 7.39E-11 lbs/ton 1 45.61 113.30 1.00

FBC, Biomass 1 Dioxin/Furan Furan:6F 123789 A3-v1 2.77E-11 1.53E-11 5.79E-11 9.96E-12 lbs/ton 1 94.79 235.47 0.70

FBC, Biomass 1 Dioxin/Furan Furan:6F 234678 A3-v0 3.02E-10 1.51E-10 6.13E-10 1.43E-10 lbs/ton 1 89.04 221.19 1.00

FBC, Biomass 1 Dioxin/Furan Furan:7F 1234678 A3-v1 1.37E-09 6.74E-10 3.02E-09 4.13E-10 lbs/ton 1 104.90 260.59 1.00

FBC, Biomass 1 Dioxin/Furan Furan:7F 1234789 A3-v1 8.97E-11 4.81E-11 2.01E-10 2.03E-11 lbs/ton 1 108.25 268.90 0.92

FBC, Biomass 1 Dioxin/Furan Furan:8F A3-v1 1.61E-09 7.06E-10 3.74E-09 3.82E-10 lbs/ton 1 115.15 286.05 1.00

FBC, Biomass 1 PAH Acenaphthene A3-v0 7.04E-07 5.15E-07 1.11E-06 4.86E-07 lbs/ton 1 50.11 124.47 1.00

FBC, Biomass 1 PAH Acenaphthylene A3-v0 2.67E-05 2.27E-05 4.13E-05 1.62E-05 lbs/ton 1 48.84 121.33 1.00

FBC, Biomass 1 PAH Anthracene A3-v0 5.68E-07 6.18E-07 7.31E-07 3.56E-07 lbs/ton 1 33.86 84.12 1.00

FBC, Biomass 1 PAH Benzo(a)anthracene A3-v0 2.05E-08 2.09E-08 2.45E-08 1.62E-08 lbs/ton 1 20.34 50.52 0.74

FBC, Biomass 1 PAH Benzo(a)pyrene A3-v0 1.64E-08 1.62E-08 1.71E-08 1.59E-08 lbs/ton 1 3.80 9.43 0.00

FBC, Biomass 1 PAH Benzo(b)fluoranthene A3-v0 1.25E-07 1.16E-07 1.44E-07 1.14E-07 lbs/ton 1 13.28 32.99 1.00

FBC, Biomass 1 PAH Benzo(e)pyrene A3-v0 1.20E-07 1.13E-07 1.41E-07 1.05E-07 lbs/ton 1 15.62 38.80 1.00

FBC, Biomass 1 PAH Benzo(g,h,i)perylene A3-v0 5.94E-08 4.86E-08 9.94E-08 3.02E-08 lbs/ton 1 60.34 149.90 1.00

FBC, Biomass 1 PAH Benzo(k)fluoranthene A3-v0 3.00E-08 2.53E-08 4.11E-08 2.35E-08 lbs/ton 1 32.29 80.21 1.00

FBC, Biomass 1 PAH Chrysene A3-v0 2.35E-07 2.42E-07 2.67E-07 1.97E-07 lbs/ton 1 14.96 37.16 1.00

124

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 1 PAH Dibenz(a,h)anthracene A3-v0 1.64E-08 1.62E-08 1.71E-08 1.59E-08 lbs/ton 1 3.80 9.43 0.00

FBC, Biomass 1 PAH Fluoranthene A3-v0 6.73E-06 5.50E-06 9.53E-06 5.15E-06 lbs/ton 1 36.21 89.95 1.00

FBC, Biomass 1 PAH Fluorene A3-v0 1.32E-06 1.13E-06 2.07E-06 7.76E-07 lbs/ton 1 50.33 125.03 1.00

FBC, Biomass 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.47E-08 2.04E-08 3.77E-08 1.59E-08 lbs/ton 1 46.52 115.55 0.78

FBC, Biomass 1 PAH Naphthalene A3-v0 2.99E-04 2.47E-04 4.13E-04 2.36E-04 lbs/ton 1 33.26 82.63 1.00

FBC, Biomass 1 PAH Phenanthrene A3-v0 1.92E-05 1.68E-05 2.54E-05 1.55E-05 lbs/ton 1 27.96 69.46 1.00

FBC, Biomass 1 PAH Pyrene A3-v0 4.78E-06 4.11E-06 6.67E-06 3.56E-06 lbs/ton 1 34.77 86.36 1.00

FBC, Biomass 1 PCB PCB:Decachlorinatedbiphenyls

A3-v0 6.47E-10 7.39E-10 7.95E-10 4.09E-10 lbs/ton 1 32.23 80.07 0.00

FBC, Biomass 1 PCB PCB:Dichlorinated biphenyls A3-v0 1.53E-08 1.61E-08 1.97E-08 1.02E-08 lbs/ton 1 31.46 78.15 0.00

FBC, Biomass 1 PCB PCB:Heptachlorinatedbiphenyls

A3-v0 7.62E-10 7.83E-10 8.35E-10 6.67E-10 lbs/ton 1 11.26 27.97 0.00

FBC, Biomass 1 PCB PCB:Hexachlorinatedbiphenyls

A3-v0 1.32E-09 9.85E-10 2.04E-09 9.31E-10 lbs/ton 1 47.49 117.98 0.00

FBC, Biomass 1 PCB PCB:Monochlorinatedbiphenyls

A3-v0 2.43E-08 2.39E-08 2.76E-08 2.15E-08 lbs/ton 1 12.62 31.35 1.00

FBC, Biomass 1 PCB PCB:Nonachlorinatedbiphenyls

A3-v0 8.25E-10 7.83E-10 1.12E-09 5.72E-10 lbs/ton 1 33.52 83.27 0.00

FBC, Biomass 1 PCB PCB:Octachlorinatedbiphenyls

A3-v0 1.16E-09 1.03E-09 1.46E-09 9.85E-10 lbs/ton 1 22.88 56.84 0.00

FBC, Biomass 1 PCB PCB:Pentachlorinatedbiphenyls

A3-v0 4.61E-09 3.82E-09 6.80E-09 3.22E-09 lbs/ton 1 41.66 103.50 1.00

FBC, Biomass 1 PCB PCB:Tetrachlorinatedbiphenyls

A3-v0 1.69E-08 1.61E-08 2.17E-08 1.28E-08 lbs/ton 1 26.92 66.88 1.00

FBC, Biomass 1 PCB PCB:Trichlorinated biphenyls A3-v0 1.53E-08 1.47E-08 1.97E-08 1.16E-08 lbs/ton 1 26.68 66.29 1.00

FBC, Biomass 1 VOC Formaldehyde A3-v0 3.66E-04 4.34E-04 4.54E-04 2.10E-04 lbs/ton 1 36.96 91.82 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:4D 2378 A3-v0 4.46E-10 4.33E-10 4.92E-10 4.12E-10 lbs/ton 1 9.35 23.23 0.00

FBC, Biomass 2 Dioxin/Furan Dioxin:4D Total A3-v1 2.16E-07 1.06E-07 4.85E-07 5.86E-08 lbs/ton 1 108.01 268.32 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:5D 12378 A3-v0 1.10E-09 1.11E-09 1.26E-09 9.38E-10 lbs/ton 1 14.62 36.31 0.28

FBC, Biomass 2 Dioxin/Furan Dioxin:5D Total A3-v1 5.85E-08 2.58E-08 1.26E-07 2.39E-08 lbs/ton 1 99.75 247.80 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:6D 123478 A3-v0 1.22E-09 1.02E-09 1.76E-09 8.89E-10 lbs/ton 1 38.42 95.45 0.00

FBC, Biomass 2 Dioxin/Furan Dioxin:6D 123678 A3-v0 1.27E-09 1.16E-09 1.76E-09 8.89E-10 lbs/ton 1 35.01 86.97 0.00

FBC, Biomass 2 Dioxin/Furan Dioxin:6D 123789 A3-v0 1.15E-09 9.21E-10 1.76E-09 7.77E-10 lbs/ton 1 45.98 114.23 0.00

125

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 2 Dioxin/Furan Dioxin:6D Total A3-v0 2.54E-08 2.05E-08 4.07E-08 1.50E-08 lbs/ton 1 53.27 132.34 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:7D 1234678 A3-v0 8.41E-09 8.24E-09 1.06E-08 6.45E-09 lbs/ton 1 24.46 60.77 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:7D Total A3-v0 1.81E-08 1.79E-08 2.28E-08 1.35E-08 lbs/ton 1 25.73 63.91 1.00

FBC, Biomass 2 Dioxin/Furan Dioxin:8D A3-v0 5.81E-08 5.81E-08 7.22E-08 4.40E-08 lbs/ton 1 24.30 60.37 1.00

FBC, Biomass 2 Dioxin/Furan Furan:4F 2378 A3-v0 3.20E-09 1.76E-09 6.30E-09 1.55E-09 lbs/ton 1 83.71 207.95 1.00

FBC, Biomass 2 Dioxin/Furan Furan:4F Total A3-v1 3.09E-07 1.44E-07 6.78E-07 1.05E-07 lbs/ton 1 103.45 256.99 1.00

FBC, Biomass 2 Dioxin/Furan Furan:5F 12378 A3-v0 3.09E-09 2.81E-09 4.51E-09 1.94E-09 lbs/ton 1 42.20 104.84 1.00

FBC, Biomass 2 Dioxin/Furan Furan:5F 23478 A3-v0 4.48E-09 3.16E-09 7.27E-09 3.00E-09 lbs/ton 1 54.01 134.17 1.00

FBC, Biomass 2 Dioxin/Furan Furan:5F Total A3-v0 8.58E-08 3.99E-08 1.79E-07 3.83E-08 lbs/ton 1 94.32 234.31 1.00

FBC, Biomass 2 Dioxin/Furan Furan:6F 123478 A3-v0 1.53E-09 1.47E-09 2.18E-09 9.44E-10 lbs/ton 1 40.57 100.78 1.00

FBC, Biomass 2 Dioxin/Furan Furan:6F 123678 A3-v0 1.56E-09 1.47E-09 1.99E-09 1.22E-09 lbs/ton 1 25.08 62.31 1.00

FBC, Biomass 2 Dioxin/Furan Furan:6F 123789 A3-v0 6.51E-10 3.54E-10 1.28E-09 3.22E-10 lbs/ton 1 83.32 206.98 0.00

FBC, Biomass 2 Dioxin/Furan Furan:6F 234678 A3-v0 1.75E-09 1.76E-09 1.89E-09 1.61E-09 lbs/ton 1 7.97 19.79 1.00

FBC, Biomass 2 Dioxin/Furan Furan:6F Total A3-v0 2.85E-08 2.87E-08 4.12E-08 1.55E-08 lbs/ton 1 45.00 111.80 1.00

FBC, Biomass 2 Dioxin/Furan Furan:7F 1234678 A3-v0 7.32E-09 7.62E-09 8.24E-09 6.11E-09 lbs/ton 1 14.95 37.15 1.00

FBC, Biomass 2 Dioxin/Furan Furan:7F 1234789 A3-v1 7.43E-10 5.45E-10 1.41E-09 2.78E-10 lbs/ton 1 79.33 197.07 0.63

FBC, Biomass 2 Dioxin/Furan Furan:7F Total A3-v0 9.79E-09 1.11E-08 1.21E-08 6.11E-09 lbs/ton 1 32.92 81.78 1.00

FBC, Biomass 2 Dioxin/Furan Furan:8F A3-v0 5.24E-09 3.52E-09 9.21E-09 3.00E-09 lbs/ton 1 65.72 163.26 0.81

FBC, Biomass 2 Halogens HCl A3-v0 7.21E-02 5.30E-02 1.13E-01 5.03E-02 lbs/ton 1 49.22 122.26 1.00

FBC, Biomass 2 Metals Arsenic C3-v1 1.57E-05 2.23E-06 4.29E-05 2.05E-06 lbs/ton 1 149.64 371.74 0.00

FBC, Biomass 2 Metals Beryllium C3-v0 2.16E-06 2.21E-06 2.23E-06 2.05E-06 lbs/ton 1 4.73 11.75 0.00

FBC, Biomass 2 Metals Cadmium C3-v1 8.87E-05 2.21E-05 2.23E-04 2.05E-05 lbs/ton 1 131.64 327.02 0.00

FBC, Biomass 2 Metals Chromium (Hex) C3-v0 4.28E-05 4.18E-05 4.94E-05 3.72E-05 lbs/ton 1 14.39 35.74 0.00

FBC, Biomass 2 Metals Chromium (Total) C3-v0 2.88E-06 2.97E-06 4.18E-06 1.49E-06 lbs/ton 1 46.87 116.43 0.52

FBC, Biomass 2 Metals Copper C3-v0 6.15E-05 5.15E-05 8.57E-05 4.72E-05 lbs/ton 1 34.28 85.16 1.00

FBC, Biomass 2 Metals Lead C3-v0 6.54E-05 6.71E-05 6.77E-05 6.15E-05 lbs/ton 1 5.20 12.91 0.00

FBC, Biomass 2 Metals Manganese C3-v1 2.86E-04 6.71E-05 7.29E-04 6.15E-05 lbs/ton 1 134.26 333.53 1.00

FBC, Biomass 2 Metals Mercury C3-v0 1.92E-04 1.89E-04 3.07E-04 8.00E-05 lbs/ton 1 59.11 146.84 1.00

126

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 2 Metals Nickel C3-v0 4.50E-05 4.48E-05 4.60E-05 4.41E-05 lbs/ton 1 2.15 5.35 0.34

FBC, Biomass 2 Metals Selenium C3-v0 1.90E-05 2.23E-05 2.45E-05 1.02E-05 lbs/ton 1 40.52 100.65 0.00

FBC, Biomass 2 Metals Zinc C3-v0 3.36E-04 2.12E-04 5.98E-04 2.00E-04 lbs/ton 1 67.27 167.10 1.00

FBC, Biomass 2 PAH Acenaphthene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Acenaphthylene A3-v1 9.47E-05 6.49E-05 2.04E-04 1.54E-05 lbs/ton 1 103.12 256.17 0.95

FBC, Biomass 2 PAH Anthracene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Benzo(a)anthracene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Benzo(a)pyrene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Benzo(b)fluoranthene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Benzo(g,h,i)perylene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Benzo(k)fluoranthene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Chrysene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Dibenz(a,h)anthracene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Fluoranthene A3-v0 4.79E-05 4.48E-05 6.07E-05 3.80E-05 lbs/ton 1 24.34 60.46 1.00

FBC, Biomass 2 PAH Fluorene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Indeno(1,2,3-cd)pyrene A3-v0 1.20E-05 1.08E-05 1.54E-05 9.74E-06 lbs/ton 1 25.11 62.38 0.00

FBC, Biomass 2 PAH Naphthalene A3-v0 7.17E-03 7.82E-03 7.95E-03 5.73E-03 lbs/ton 1 17.38 43.18 1.00

FBC, Biomass 2 PAH Phenanthrene A3-v0 1.13E-04 1.39E-04 1.53E-04 4.73E-05 lbs/ton 1 50.80 126.20 1.00

FBC, Biomass 2 PAH Pyrene A3-v0 4.93E-05 5.13E-05 6.36E-05 3.29E-05 lbs/ton 1 31.37 77.94 1.00

FBC, Biomass 2 VOC Benzene C3-v0 7.70E-04 7.49E-04 9.98E-04 5.62E-04 lbs/ton 1 28.47 70.74 0.76

FBC, Biomass 2 VOC Formaldehyde A3-v0 2.34E-02 2.21E-02 2.80E-02 2.03E-02 lbs/ton 1 17.17 42.64 1.00

FBC, Biomass 2 VOC Vinyl Chloride A3-v0 5.43E-04 4.73E-04 6.84E-04 4.73E-04 lbs/ton 1 22.35 55.52 0.00

FBC, Biomass 3 Dioxin/Furan Dioxin:4D 2378 A3-v0 5.79E-11 5.31E-11 7.59E-11 4.48E-11 lbs/ton 1 27.82 69.12 0.00

FBC, Biomass 3 Dioxin/Furan Dioxin:4D Total A3-v0 3.56E-09 3.24E-09 5.19E-09 2.26E-09 lbs/ton 1 41.80 103.84 1.00

FBC, Biomass 3 Dioxin/Furan Dioxin:5D 12378 A3-v0 8.69E-11 8.19E-11 1.24E-10 5.50E-11 lbs/ton 1 39.90 99.11 0.00

FBC, Biomass 3 Dioxin/Furan Dioxin:5D Total A3-v0 2.07E-09 2.29E-09 2.79E-09 1.11E-09 lbs/ton 1 41.90 104.08 1.00

FBC, Biomass 3 Dioxin/Furan Dioxin:6D 123478 A3-v0 9.07E-11 9.57E-11 1.01E-10 7.50E-11 lbs/ton 1 15.23 37.85 0.00

FBC, Biomass 3 Dioxin/Furan Dioxin:6D 123678 A3-v0 7.94E-11 7.50E-11 9.57E-11 6.75E-11 lbs/ton 1 18.41 45.73 0.00

127

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 3 Dioxin/Furan Dioxin:6D 123789 A3-v0 7.19E-11 6.99E-11 8.77E-11 5.80E-11 lbs/ton 1 20.80 51.68 0.00

FBC, Biomass 3 Dioxin/Furan Dioxin:6D Total A3-v0 7.55E-10 8.74E-10 9.57E-10 4.34E-10 lbs/ton 1 37.23 92.49 1.00

FBC, Biomass 3 Dioxin/Furan Dioxin:7D 1234678 A3-v0 2.19E-10 1.32E-10 4.18E-10 1.06E-10 lbs/ton 1 79.10 196.49 1.00

FBC, Biomass 3 Dioxin/Furan Dioxin:7D Total A3-v0 2.87E-10 2.75E-10 4.79E-10 1.06E-10 lbs/ton 1 65.08 161.66 1.00

FBC, Biomass 3 Dioxin/Furan Dioxin:8D A3-v0 4.12E-10 3.37E-10 5.99E-10 3.00E-10 lbs/ton 1 39.46 98.03 1.00

FBC, Biomass 3 Dioxin/Furan Furan:4F 2378 A3-v0 2.00E-10 1.95E-10 2.79E-10 1.25E-10 lbs/ton 1 38.53 95.73 1.00

FBC, Biomass 3 Dioxin/Furan Furan:4F Total A3-v0 6.56E-09 6.50E-09 8.58E-09 4.59E-09 lbs/ton 1 30.48 75.72 1.00

FBC, Biomass 3 Dioxin/Furan Furan:5F 12378 A3-v0 1.28E-10 1.58E-10 1.62E-10 6.52E-11 lbs/ton 1 42.69 106.06 1.00

FBC, Biomass 3 Dioxin/Furan Furan:5F 23478 A3-v0 1.63E-10 1.92E-10 1.98E-10 9.89E-11 lbs/ton 1 34.05 84.58 1.00

FBC, Biomass 3 Dioxin/Furan Furan:5F Total A3-v0 1.76E-09 2.19E-09 2.22E-09 8.68E-10 lbs/ton 1 43.93 109.13 1.00

FBC, Biomass 3 Dioxin/Furan Furan:6F 123478 A3-v0 5.86E-11 5.99E-11 6.99E-11 4.59E-11 lbs/ton 1 20.65 51.29 1.00

FBC, Biomass 3 Dioxin/Furan Furan:6F 123678 A3-v0 4.98E-11 5.79E-11 6.25E-11 2.90E-11 lbs/ton 1 36.46 90.57 1.00

FBC, Biomass 3 Dioxin/Furan Furan:6F 123789 A3-v0 4.35E-11 4.42E-11 4.96E-11 3.66E-11 lbs/ton 1 14.95 37.15 0.00

FBC, Biomass 3 Dioxin/Furan Furan:6F 234678 A3-v0 4.17E-11 3.99E-11 5.39E-11 3.13E-11 lbs/ton 1 27.35 67.95 1.00

FBC, Biomass 3 Dioxin/Furan Furan:6F Total A3-v0 1.78E-10 2.29E-10 2.39E-10 6.50E-11 lbs/ton 1 55.02 136.68 1.00

FBC, Biomass 3 Dioxin/Furan Furan:7F 1234678 A3-v0 1.21E-10 1.17E-10 1.43E-10 1.01E-10 lbs/ton 1 17.48 43.43 1.00

FBC, Biomass 3 Dioxin/Furan Furan:7F 1234789 A3-v0 4.72E-11 4.39E-11 5.50E-11 4.26E-11 lbs/ton 1 14.49 36.00 0.00

FBC, Biomass 3 Dioxin/Furan Furan:7F Total A3-v0 1.33E-10 1.38E-10 1.60E-10 1.01E-10 lbs/ton 1 22.29 55.36 1.00

FBC, Biomass 3 Dioxin/Furan Furan:8F A3-v0 1.66E-10 1.62E-10 1.98E-10 1.37E-10 lbs/ton 1 18.30 45.46 1.00

FBC, Biomass 3 Halogens HCl C3-v0 1.14E-04 9.99E-05 1.84E-04 5.84E-05 lbs/ton 1 56.25 139.72 1.00

FBC, Biomass 3 Metals Arsenic B3-v0 1.74E-05 1.72E-05 1.87E-05 1.63E-05 lbs/ton 1 6.92 17.19 1.00

FBC, Biomass 3 Metals Beryllium B3-v0 3.65E-07 3.69E-07 4.72E-07 2.53E-07 lbs/ton 1 30.05 74.65 0.77

FBC, Biomass 3 Metals Cadmium B3-v1 5.35E-06 3.42E-06 1.13E-05 1.34E-06 lbs/ton 1 98.10 243.68 1.00

FBC, Biomass 3 Metals Chromium (Hex) C3-v0 9.58E-07 9.68E-07 9.99E-07 9.07E-07 lbs/ton 1 4.88 12.12 0.00

FBC, Biomass 3 Metals Chromium (Total) C3-v0 4.57E-05 4.64E-05 4.73E-05 4.34E-05 lbs/ton 1 4.47 11.11 1.00

FBC, Biomass 3 Metals Copper B3-v0 6.13E-05 5.40E-05 7.90E-05 5.09E-05 lbs/ton 1 25.07 62.29 1.00

FBC, Biomass 3 Metals Lead B3-v2 8.76E-05 1.28E-04 1.32E-04 2.44E-06 lbs/ton 1 84.23 209.25 1.00

FBC, Biomass 3 Metals Manganese B3-v2 7.65E-04 9.76E-04 1.31E-03 5.20E-06 lbs/ton 1 88.80 220.60 1.00

128

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 3 Metals Mercury B3-v0 9.41E-06 5.37E-06 1.83E-05 4.56E-06 lbs/ton 1 82.03 203.77 0.65

FBC, Biomass 3 Metals Nickel B3-v1 3.56E-05 3.17E-05 7.11E-05 4.03E-06 lbs/ton 1 94.69 235.24 1.00

FBC, Biomass 3 Metals Selenium B3-v1 9.78E-06 9.33E-06 1.76E-05 2.35E-06 lbs/ton 1 78.31 194.54 1.00

FBC, Biomass 3 Metals Zinc B3-v1 3.47E-04 4.51E-04 5.79E-04 1.25E-05 lbs/ton 1 85.49 212.38 1.00

FBC, Biomass 3 PAH Acenaphthene A3-v0 5.62E-07 5.74E-07 8.73E-07 2.39E-07 lbs/ton 1 56.40 140.11 1.00

FBC, Biomass 3 PAH Acenaphthylene A3-v1 5.14E-07 6.99E-07 7.31E-07 1.12E-07 lbs/ton 1 67.85 168.55 1.00

FBC, Biomass 3 PAH Anthracene A3-v0 6.80E-07 8.49E-07 8.73E-07 3.20E-07 lbs/ton 1 45.97 114.19 1.00

FBC, Biomass 3 PAH Benzo(a)anthracene A3-v0 1.21E-07 1.02E-07 1.62E-07 9.79E-08 lbs/ton 1 30.02 74.58 1.00

FBC, Biomass 3 PAH Benzo(a)pyrene A3-v0 3.70E-08 3.98E-08 4.99E-08 2.12E-08 lbs/ton 1 39.30 97.63 0.19

FBC, Biomass 3 PAH Benzo(b)fluoranthene A3-v0 3.48E-08 3.61E-08 4.24E-08 2.59E-08 lbs/ton 1 23.90 59.38 1.00

FBC, Biomass 3 PAH Benzo(g,h,i)perylene A3-v0 4.41E-08 4.25E-08 4.99E-08 3.98E-08 lbs/ton 1 11.84 29.41 0.00

FBC, Biomass 3 PAH Benzo(k)fluoranthene A3-v0 4.41E-08 4.25E-08 4.99E-08 3.98E-08 lbs/ton 1 11.84 29.41 0.00

FBC, Biomass 3 PAH Chrysene A3-v0 4.41E-08 4.25E-08 4.99E-08 3.98E-08 lbs/ton 1 11.84 29.41 0.00

FBC, Biomass 3 PAH Dibenz(a,h)anthracene A3-v0 4.41E-08 4.25E-08 4.99E-08 3.98E-08 lbs/ton 1 11.84 29.41 0.00

FBC, Biomass 3 PAH Fluoranthene A3-v0 3.15E-06 2.76E-06 4.50E-06 2.19E-06 lbs/ton 1 38.13 94.73 1.00

FBC, Biomass 3 PAH Fluorene A3-v1 1.39E-06 1.18E-06 2.75E-06 2.34E-07 lbs/ton 1 91.61 227.58 1.00

FBC, Biomass 3 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.41E-08 4.25E-08 4.99E-08 3.98E-08 lbs/ton 1 11.84 29.41 0.00

FBC, Biomass 3 PAH Naphthalene A3-v1 2.17E-05 1.07E-05 5.10E-05 3.40E-06 lbs/ton 1 118.04 293.23 1.00

FBC, Biomass 3 PAH Phenanthrene A3-v0 1.62E-05 2.00E-05 2.02E-05 8.38E-06 lbs/ton 1 41.84 103.94 1.00

FBC, Biomass 3 PAH Pyrene A3-v0 1.24E-06 1.19E-06 1.67E-06 8.58E-07 lbs/ton 1 33.02 82.03 1.00

FBC, Biomass 3 PCB PCB:Decachlorinatedbiphenyls

A3-v0 4.17E-09 3.13E-09 6.39E-09 3.00E-09 lbs/ton 1 45.99 114.25 1.00

FBC, Biomass 3 PCB PCB:Dichlorinated biphenyls A3-v0 1.30E-06 9.19E-07 2.08E-06 9.00E-07 lbs/ton 1 52.04 129.28 1.00

FBC, Biomass 3 PCB PCB:Heptachlorinatedbiphenyls

A3-v0 2.95E-08 2.90E-08 3.75E-08 2.19E-08 lbs/ton 1 26.48 65.79 1.00

FBC, Biomass 3 PCB PCB:Hexachlorinatedbiphenyls

A3-v0 6.11E-08 5.55E-08 8.00E-08 4.79E-08 lbs/ton 1 27.42 68.13 1.00

FBC, Biomass 3 PCB PCB:Monochlorinatedbiphenyls

A3-v0 1.40E-07 1.26E-07 2.00E-07 9.49E-08 lbs/ton 1 38.50 95.63 1.00

FBC, Biomass 3 PCB PCB:Nonachlorinatedbiphenyls

A3-v0 4.05E-09 4.59E-09 5.19E-09 2.38E-09 lbs/ton 1 36.54 90.78 1.00

129

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 3 PCB PCB:Octachlorinatedbiphenyls

A3-v0 6.41E-08 6.49E-08 6.75E-08 5.99E-08 lbs/ton 1 6.02 14.95 0.00

FBC, Biomass 3 PCB PCB:Pentachlorinatedbiphenyls

A3-v0 1.16E-07 1.04E-07 1.57E-07 8.58E-08 lbs/ton 1 32.20 79.99 1.00

FBC, Biomass 3 PCB PCB:Tetrachlorinatedbiphenyls

A3-v0 3.32E-07 2.79E-07 4.50E-07 2.65E-07 lbs/ton 1 30.98 76.95 1.00

FBC, Biomass 3 PCB PCB:Trichlorinated biphenyls A3-v0 4.12E-06 3.24E-06 6.52E-06 2.59E-06 lbs/ton 1 51.10 126.93 1.00

FBC, Biomass 3 VOC Acetaldehyde C3-v0 1.87E-04 1.83E-04 2.07E-04 1.70E-04 lbs/ton 1 10.02 24.88 1.00

FBC, Biomass 3 VOC Acrolein C3-v1 1.31E-04 5.04E-05 2.96E-04 4.72E-05 lbs/ton 1 108.83 270.34 0.75

FBC, Biomass 3 VOC Benzene A3-v0 1.34E-04 1.34E-04 1.38E-04 1.31E-04 lbs/ton 1 2.62 6.51 0.00

FBC, Biomass 3 VOC Formaldehyde C3-v0 2.65E-03 2.78E-03 2.94E-03 2.23E-03 lbs/ton 1 14.07 34.95 1.00

FBC, Biomass 3 VOC Toluene A3-v0 1.28E-04 1.25E-04 1.40E-04 1.19E-04 lbs/ton 1 8.19 20.34 0.64

FBC, Biomass 3 VOC Vinyl Chloride A3-v0 1.42E-04 1.41E-04 1.46E-04 1.38E-04 lbs/ton 1 2.63 6.52 0.00

FBC, Biomass 3 VOC Xylene (Total) A3-v0 1.50E-04 1.43E-04 2.35E-04 7.05E-05 lbs/ton 1 55.09 136.84 0.68

FBC, Biomass 4 Dioxin/Furan Dioxin:4D 2378 A3-v0 3.99E-11 4.07E-11 4.83E-11 3.08E-11 lbs/ton 1 22.06 54.79 0.00

FBC, Biomass 4 Dioxin/Furan Dioxin:4D Total A3-v0 1.79E-09 1.88E-09 2.38E-09 1.10E-09 lbs/ton 1 36.15 89.80 1.00

FBC, Biomass 4 Dioxin/Furan Dioxin:5D 12378 A3-v0 8.10E-11 7.50E-11 1.08E-10 5.98E-11 lbs/ton 1 30.60 76.03 0.00

FBC, Biomass 4 Dioxin/Furan Dioxin:5D Total A3-v0 1.54E-09 1.64E-09 2.11E-09 8.60E-10 lbs/ton 1 41.11 102.12 1.00

FBC, Biomass 4 Dioxin/Furan Dioxin:6D 123478 A3-v0 8.95E-11 9.38E-11 9.70E-11 7.78E-11 lbs/ton 1 11.47 28.48 0.00

FBC, Biomass 4 Dioxin/Furan Dioxin:6D 123678 A3-v0 8.95E-11 9.38E-11 9.70E-11 7.78E-11 lbs/ton 1 11.47 28.48 0.00

FBC, Biomass 4 Dioxin/Furan Dioxin:6D 123789 A3-v0 8.09E-11 8.53E-11 8.81E-11 6.93E-11 lbs/ton 1 12.51 31.08 0.00

FBC, Biomass 4 Dioxin/Furan Dioxin:6D Total A3-v0 9.50E-10 7.92E-10 1.38E-09 6.71E-10 lbs/ton 1 40.20 99.87 0.72

FBC, Biomass 4 Dioxin/Furan Dioxin:7D 1234678 A3-v0 1.08E-10 1.10E-10 1.36E-10 7.68E-11 lbs/ton 1 27.73 68.88 0.58

FBC, Biomass 4 Dioxin/Furan Dioxin:7D Total A3-v2 5.51E-09 1.99E-10 1.63E-08 6.82E-11 lbs/ton 1 169.01 419.85 1.00

FBC, Biomass 4 Dioxin/Furan Dioxin:8D A3-v0 3.32E-10 2.77E-10 4.97E-10 2.20E-10 lbs/ton 1 44.15 109.68 1.00

FBC, Biomass 4 Dioxin/Furan Furan:4F 2378 A3-v0 1.57E-10 1.77E-10 1.95E-10 9.91E-11 lbs/ton 1 32.39 80.47 1.00

FBC, Biomass 4 Dioxin/Furan Furan:4F Total A3-v0 4.46E-09 4.69E-09 6.06E-09 2.65E-09 lbs/ton 1 38.44 95.49 1.00

FBC, Biomass 4 Dioxin/Furan Furan:5F 12378 A3-v0 1.19E-10 9.74E-11 1.86E-10 7.50E-11 lbs/ton 1 49.18 122.17 1.00

FBC, Biomass 4 Dioxin/Furan Furan:5F 23478 A3-v0 1.60E-10 1.48E-10 2.34E-10 9.91E-11 lbs/ton 1 42.73 106.14 1.00

FBC, Biomass 4 Dioxin/Furan Furan:5F Total A3-v0 1.40E-09 1.30E-09 2.12E-09 7.71E-10 lbs/ton 1 48.80 121.23 1.00

130

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 4 Dioxin/Furan Furan:6F 123478 A3-v0 9.08E-11 6.28E-11 1.70E-10 3.96E-11 lbs/ton 1 76.61 190.32 1.00

FBC, Biomass 4 Dioxin/Furan Furan:6F 123678 A3-v0 8.18E-11 5.85E-11 1.38E-10 4.85E-11 lbs/ton 1 60.27 149.71 1.00

FBC, Biomass 4 Dioxin/Furan Furan:6F 123789 A3-v0 4.60E-11 4.77E-11 5.13E-11 3.92E-11 lbs/ton 1 13.53 33.60 0.00

FBC, Biomass 4 Dioxin/Furan Furan:6F 234678 A3-v0 5.41E-11 5.29E-11 7.24E-11 3.69E-11 lbs/ton 1 32.91 81.75 1.00

FBC, Biomass 4 Dioxin/Furan Furan:6F Total A3-v0 8.03E-10 6.28E-10 1.41E-09 3.75E-10 lbs/ton 1 66.98 166.40 1.00

FBC, Biomass 4 Dioxin/Furan Furan:7F 1234678 A3-v1 3.41E-10 1.96E-10 7.50E-10 7.80E-11 lbs/ton 1 105.04 260.93 1.00

FBC, Biomass 4 Dioxin/Furan Furan:7F 1234789 A3-v0 4.98E-11 3.09E-11 8.94E-11 2.90E-11 lbs/ton 1 68.96 171.31 0.00

FBC, Biomass 4 Dioxin/Furan Furan:7F Total A3-v0 1.16E-10 7.80E-11 1.96E-10 7.50E-11 lbs/ton 1 59.47 147.73 1.00

FBC, Biomass 4 Dioxin/Furan Furan:8F A3-v0 2.05E-10 1.68E-10 2.99E-10 1.48E-10 lbs/ton 1 40.05 99.48 1.00

FBC, Biomass 4 Halogens HCl C3-v1 1.55E-04 9.56E-05 3.28E-04 4.02E-05 lbs/ton 1 98.79 245.41 1.00

FBC, Biomass 4 Metals Arsenic B3-v1 6.06E-06 6.18E-06 1.08E-05 1.24E-06 lbs/ton 1 78.49 194.99 1.00

FBC, Biomass 4 Metals Beryllium B3-v0 2.75E-07 2.20E-07 3.99E-07 2.07E-07 lbs/ton 1 39.03 96.95 0.00

FBC, Biomass 4 Metals Cadmium B3-v1 5.29E-06 5.64E-06 9.09E-06 1.14E-06 lbs/ton 1 75.41 187.34 1.00

FBC, Biomass 4 Metals Chromium (Hex) C3-v0 1.02E-06 1.01E-06 1.03E-06 1.00E-06 lbs/ton 1 1.51 3.75 0.00

FBC, Biomass 4 Metals Chromium (Total) C3-v0 3.85E-05 3.86E-05 4.13E-05 3.56E-05 lbs/ton 1 7.50 18.64 1.00

FBC, Biomass 4 Metals Copper B3-v0 3.60E-05 3.44E-05 4.31E-05 3.06E-05 lbs/ton 1 17.82 44.26 1.00

FBC, Biomass 4 Metals Lead B3-v1 4.04E-05 5.94E-05 5.99E-05 2.06E-06 lbs/ton 1 82.20 204.20 1.00

FBC, Biomass 4 Metals Manganese B3-v2 1.64E-04 6.16E-05 4.26E-04 4.40E-06 lbs/ton 1 139.47 346.45 1.00

FBC, Biomass 4 Metals Mercury B3-v2 3.69E-04 4.85E-04 6.11E-04 1.08E-05 lbs/ton 1 85.79 213.12 1.00

FBC, Biomass 4 Metals Nickel B3-v0 8.51E-06 7.02E-06 1.51E-05 3.41E-06 lbs/ton 1 70.32 174.69 1.00

FBC, Biomass 4 Metals Selenium B3-v0 6.29E-06 4.38E-06 1.04E-05 4.14E-06 lbs/ton 1 55.95 139.00 1.00

FBC, Biomass 4 Metals Zinc B3-v1 1.74E-04 2.43E-04 2.68E-04 1.06E-05 lbs/ton 1 81.63 202.78 1.00

FBC, Biomass 4 PAH Acenaphthene A3-v3 6.96E-06 9.56E-08 2.08E-05 2.65E-08 lbs/ton 1 171.69 426.50 1.00

FBC, Biomass 4 PAH Acenaphthylene A3-v1 1.62E-07 6.72E-08 3.89E-07 3.09E-08 lbs/ton 1 121.41 301.60 1.00

FBC, Biomass 4 PAH Anthracene A3-v1 2.92E-07 6.51E-08 7.58E-07 5.29E-08 lbs/ton 1 138.21 343.33 1.00

FBC, Biomass 4 PAH Benzo(a)anthracene A3-v0 3.86E-08 4.33E-08 4.41E-08 2.86E-08 lbs/ton 1 22.62 56.18 0.25

FBC, Biomass 4 PAH Benzo(a)pyrene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Benzo(b)fluoranthene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

131

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 4 PAH Benzo(g,h,i)perylene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Benzo(k)fluoranthene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Chrysene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Dibenz(a,h)anthracene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Fluoranthene A3-v0 1.86E-07 2.03E-07 2.42E-07 1.13E-07 lbs/ton 1 35.65 88.56 1.00

FBC, Biomass 4 PAH Fluorene A3-v0 3.75E-07 4.07E-07 5.85E-07 1.32E-07 lbs/ton 1 60.88 151.23 1.00

FBC, Biomass 4 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.26E-08 4.33E-08 4.41E-08 4.06E-08 lbs/ton 1 4.27 10.60 0.00

FBC, Biomass 4 PAH Naphthalene A3-v1 1.00E-05 5.29E-06 2.16E-05 3.09E-06 lbs/ton 1 101.29 251.63 1.00

FBC, Biomass 4 PAH Phenanthrene A3-v1 7.06E-07 8.66E-07 1.14E-06 1.12E-07 lbs/ton 1 75.36 187.20 1.00

FBC, Biomass 4 PAH Pyrene A3-v0 1.03E-07 1.03E-07 1.32E-07 7.36E-08 lbs/ton 1 28.45 70.67 1.00

FBC, Biomass 4 PCB PCB:Decachlorinatedbiphenyls

A3-v0 2.95E-09 2.33E-09 4.33E-09 2.17E-09 lbs/ton 1 40.76 101.25 0.00

FBC, Biomass 4 PCB PCB:Dichlorinated biphenyls A3-v1 7.58E-08 8.53E-08 1.32E-07 9.95E-09 lbs/ton 1 81.35 202.07 0.00

FBC, Biomass 4 PCB PCB:Heptachlorinatedbiphenyls

A3-v0 4.37E-09 3.58E-09 6.06E-09 3.49E-09 lbs/ton 1 33.34 82.83 0.00

FBC, Biomass 4 PCB PCB:Hexachlorinatedbiphenyls

A3-v0 5.21E-09 5.54E-09 7.71E-09 2.38E-09 lbs/ton 1 51.39 127.65 1.00

FBC, Biomass 4 PCB PCB:Monochlorinatedbiphenyls

A3-v1 2.22E-07 1.77E-07 4.69E-07 1.94E-08 lbs/ton 1 102.83 255.45 1.00

FBC, Biomass 4 PCB PCB:Nonachlorinatedbiphenyls

A3-v0 2.03E-09 1.58E-09 3.28E-09 1.24E-09 lbs/ton 1 53.68 133.36 0.00

FBC, Biomass 4 PCB PCB:Octachlorinatedbiphenyls

A3-v0 3.67E-08 3.70E-08 4.33E-08 2.99E-08 lbs/ton 1 18.26 45.35 0.00

FBC, Biomass 4 PCB PCB:Pentachlorinatedbiphenyls

A3-v0 5.62E-09 3.22E-09 1.04E-08 3.18E-09 lbs/ton 1 74.51 185.10 0.62

FBC, Biomass 4 PCB PCB:Tetrachlorinatedbiphenyls

A3-v0 3.79E-08 4.85E-08 4.89E-08 1.62E-08 lbs/ton 1 49.49 122.95 1.00

FBC, Biomass 4 PCB PCB:Trichlorinated biphenyls A3-v1 1.94E-07 9.30E-08 4.26E-07 6.39E-08 lbs/ton 1 103.57 257.28 1.00

FBC, Biomass 4 VOC Acetaldehyde C3-v1 1.03E-03 1.14E-03 1.73E-03 2.12E-04 lbs/ton 1 74.39 184.79 1.00

FBC, Biomass 4 VOC Acrolein C3-v0 5.23E-05 5.18E-05 5.47E-05 5.03E-05 lbs/ton 1 4.23 10.50 0.00

FBC, Biomass 4 VOC Benzene A3-v0 1.49E-04 1.50E-04 1.50E-04 1.48E-04 lbs/ton 1 0.81 2.01 0.00

FBC, Biomass 4 VOC Formaldehyde C3-v0 6.04E-04 6.22E-04 7.62E-04 4.28E-04 lbs/ton 1 27.77 68.97 1.00

FBC, Biomass 4 VOC Toluene A3-v0 1.70E-04 1.51E-04 2.07E-04 1.51E-04 lbs/ton 1 18.80 46.70 0.00

132

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Biomass 4 VOC Vinyl Chloride A3-v0 1.57E-04 1.58E-04 1.58E-04 1.55E-04 lbs/ton 1 1.03 2.56 0.00

FBC, Biomass 4 VOC Xylene (Total) A3-v0 1.60E-04 1.61E-04 1.61E-04 1.59E-04 lbs/ton 1 0.81 2.01 0.00

FBC, Coal 1 Dioxin/Furan Dioxin/Furan:Total A3-v1 1.77E-09 2.32E-09 2.77E-09 2.27E-10 lbs/ton 1 76.58 190.24 0.00

FBC, Coal 1 Dioxin/Furan Dioxin:4D 2378 B1-v1 5.03E-10 3.27E-10 1.62E-09 4.49E-11 lbs/ton 5 97.77 56.45 0.00

FBC, Coal 1 Dioxin/Furan Dioxin:4D Total B1-v1 7.46E-10 3.55E-10 3.47E-09 8.07E-11 lbs/ton 5 119.78 66.33 0.00

FBC, Coal 1 Dioxin/Furan Dioxin:5D 12378 B1-v1 6.05E-10 3.41E-10 1.88E-09 6.85E-11 lbs/ton 5 102.15 61.73 0.00

FBC, Coal 1 Dioxin/Furan Dioxin:5D Total B1-v2 3.55E-09 4.22E-10 3.12E-08 1.90E-10 lbs/ton 5 234.95 130.11 0.01

FBC, Coal 1 Dioxin/Furan Dioxin:6D 123478 B1-v2 2.92E-09 5.79E-10 2.51E-08 1.39E-10 lbs/ton 5 228.39 126.48 0.01

FBC, Coal 1 Dioxin/Furan Dioxin:6D 123678 B1-v1 6.43E-10 5.79E-10 2.21E-09 1.39E-10 lbs/ton 5 91.17 55.10 0.05

FBC, Coal 1 Dioxin/Furan Dioxin:6D 123789 B1-v2 2.92E-09 5.65E-10 2.51E-08 1.31E-10 lbs/ton 5 228.54 126.56 0.01

FBC, Coal 1 Dioxin/Furan Dioxin:6D Total B1-v2 3.44E-09 7.40E-10 2.51E-08 1.68E-10 lbs/ton 5 192.58 106.65 0.16

FBC, Coal 1 Dioxin/Furan Dioxin:7D 1234678 B1-v1 2.21E-09 1.09E-09 9.87E-09 2.10E-10 lbs/ton 5 124.56 71.92 0.45

FBC, Coal 1 Dioxin/Furan Dioxin:7D Total B1-v2 4.70E-09 2.05E-09 2.45E-08 2.10E-10 lbs/ton 5 142.09 78.69 0.40

FBC, Coal 1 Dioxin/Furan Dioxin:8D B1-v2 1.36E-08 1.23E-09 7.45E-08 2.68E-10 lbs/ton 5 156.83 86.85 0.41

FBC, Coal 1 Dioxin/Furan Furan:4F 2378 B1-v2 1.24E-09 4.63E-10 5.83E-09 1.15E-10 lbs/ton 5 141.34 78.27 0.04

FBC, Coal 1 Dioxin/Furan Furan:4F Total B1-v1 2.03E-09 4.63E-10 5.83E-09 1.24E-10 lbs/ton 5 106.90 59.20 0.45

FBC, Coal 1 Dioxin/Furan Furan:5F 12378 B1-v2 1.31E-09 4.31E-10 8.81E-09 1.11E-10 lbs/ton 5 176.54 97.77 0.09

FBC, Coal 1 Dioxin/Furan Furan:5F 23478 B1-v2 1.38E-09 4.31E-10 8.81E-09 1.24E-10 lbs/ton 5 166.21 92.04 0.15

FBC, Coal 1 Dioxin/Furan Furan:5F Total B1-v2 3.10E-09 6.52E-10 1.41E-08 1.67E-10 lbs/ton 5 140.10 77.58 0.60

FBC, Coal 1 Dioxin/Furan Furan:6F 123478 B1-v2 1.89E-09 5.46E-10 1.09E-08 1.36E-10 lbs/ton 5 171.12 94.76 0.13

FBC, Coal 1 Dioxin/Furan Furan:6F 123678 B1-v2 1.98E-09 5.63E-10 1.09E-08 1.36E-10 lbs/ton 5 162.67 90.08 0.17

FBC, Coal 1 Dioxin/Furan Furan:6F 123789 B1-v2 1.85E-09 5.65E-10 1.09E-08 1.26E-10 lbs/ton 5 174.85 96.83 0.11

FBC, Coal 1 Dioxin/Furan Furan:6F 234678 B1-v2 2.28E-09 6.11E-10 1.09E-08 1.36E-10 lbs/ton 5 146.79 81.29 0.28

FBC, Coal 1 Dioxin/Furan Furan:6F Total B1-v2 5.06E-09 6.11E-10 2.91E-08 1.36E-10 lbs/ton 5 163.39 90.48 0.67

FBC, Coal 1 Dioxin/Furan Furan:7F 1234678 B1-v2 6.16E-09 9.41E-10 2.83E-08 2.36E-10 lbs/ton 5 152.72 84.57 0.53

FBC, Coal 1 Dioxin/Furan Furan:7F 1234789 B1-v2 3.28E-09 6.39E-10 2.38E-08 2.36E-10 lbs/ton 5 195.12 108.05 0.12

FBC, Coal 1 Dioxin/Furan Furan:7F Total B1-v2 9.04E-09 1.07E-09 5.08E-08 2.36E-10 lbs/ton 5 167.80 92.92 0.68

FBC, Coal 1 Dioxin/Furan Furan:8F B1-v2 1.41E-08 8.84E-10 1.15E-07 2.47E-10 lbs/ton 5 215.22 119.19 0.18

133

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Coal 1 Halogens HCl C1-v1 2.29E-02 2.33E-02 5.15E-02 8.25E-03 lbs/ton 5 52.96 29.33 1.00

FBC, Coal 1 Halogens HF C3-v0 6.22E-03 6.15E-03 8.61E-03 3.43E-03 lbs/ton 2 31.61 33.18 0.63

FBC, Coal 1 Metals Antimony C3-v0 1.15E-05 1.15E-05 1.18E-05 1.13E-05 lbs/ton 1 2.27 5.65 0.00

FBC, Coal 1 Metals Arsenic D1-v2 3.40E-05 8.25E-06 1.47E-04 9.67E-07 lbs/ton 5 130.21 72.11 0.43

FBC, Coal 1 Metals Barium C3-v0 4.98E-04 4.85E-04 5.26E-04 4.83E-04 lbs/ton 1 4.86 12.07 1.00

FBC, Coal 1 Metals Beryllium D1-v1 3.43E-06 2.14E-06 1.18E-05 5.77E-07 lbs/ton 5 123.38 68.33 0.00

FBC, Coal 1 Metals Cadmium D1-v1 1.19E-05 1.15E-05 2.19E-05 3.10E-06 lbs/ton 5 53.59 29.68 0.35

FBC, Coal 1 Metals Chromium (Hex) B1-v1 1.65E-05 9.28E-06 4.52E-05 4.58E-06 lbs/ton 5 82.92 45.92 0.47

FBC, Coal 1 Metals Chromium (Total) B1-v2 4.37E-05 1.86E-05 2.58E-04 3.63E-06 lbs/ton 5 153.73 85.13 0.99

FBC, Coal 1 Metals Copper D1-v1 1.33E-04 5.87E-05 3.98E-04 8.51E-06 lbs/ton 5 98.37 54.48 0.99

FBC, Coal 1 Metals Lead D1-v2 6.13E-05 3.30E-05 2.11E-04 1.25E-06 lbs/ton 5 123.35 68.31 0.78

FBC, Coal 1 Metals Manganese D1-v3 2.10E-03 8.33E-05 2.99E-02 1.17E-05 lbs/ton 5 366.37 202.89 1.00

FBC, Coal 1 Metals Mercury C1-v3 2.57E-04 3.04E-05 1.19E-03 2.51E-07 lbs/ton 5 177.33 98.20 0.09

FBC, Coal 1 Metals Nickel D1-v2 1.92E-04 5.90E-05 1.61E-03 2.87E-05 lbs/ton 5 207.41 114.86 0.94

FBC, Coal 1 Metals Phosphorus D3-v0 6.04E-04 6.00E-04 6.25E-04 5.85E-04 lbs/ton 1 3.35 8.33 0.00

FBC, Coal 1 Metals Selenium D1-v2 4.81E-05 1.96E-05 2.54E-04 1.13E-06 lbs/ton 5 162.66 90.08 0.00

FBC, Coal 1 Metals Silver C3-v0 1.15E-05 1.15E-05 1.18E-05 1.13E-05 lbs/ton 1 2.27 5.65 0.00

FBC, Coal 1 Metals Thallium C3-v0 1.53E-06 1.69E-06 1.77E-06 1.15E-06 lbs/ton 1 22.11 54.92 0.75

FBC, Coal 1 Metals Zinc D1-v1 1.06E-03 5.93E-04 4.62E-03 2.24E-04 lbs/ton 5 113.29 62.74 1.00

FBC, Coal 1 PAH Acenaphthene B1-v4 2.25E-06 1.53E-07 1.28E-05 2.94E-10 lbs/ton 6 215.25 107.04 0.03

FBC, Coal 1 PAH Acenaphthylene B1-v4 2.24E-06 1.37E-07 1.28E-05 2.94E-10 lbs/ton 6 216.58 107.70 0.02

FBC, Coal 1 PAH Anthracene B1-v4 2.24E-06 1.49E-07 1.28E-05 2.94E-10 lbs/ton 6 216.17 107.50 0.03

FBC, Coal 1 PAH Benzo(a)anthracene B1-v4 2.21E-06 1.29E-07 1.28E-05 2.94E-10 lbs/ton 6 219.85 109.33 0.00

FBC, Coal 1 PAH Benzo(a)pyrene B1-v4 2.44E-06 1.90E-07 1.28E-05 2.94E-10 lbs/ton 6 195.87 97.40 0.00

FBC, Coal 1 PAH Benzo(b)fluoranthene B2-v2 4.34E-06 1.39E-07 1.28E-05 6.36E-08 lbs/ton 3 145.56 111.89 0.01

FBC, Coal 1 PAH Benzo(b+k)fluoranthene C2-v3 9.80E-08 1.24E-07 1.72E-07 2.94E-10 lbs/ton 3 77.67 59.70 0.00

FBC, Coal 1 PAH Benzo(g,h,i)perylene B1-v4 2.23E-06 1.48E-07 1.28E-05 2.94E-10 lbs/ton 6 217.33 108.07 0.00

FBC, Coal 1 PAH Benzo(k)fluoranthene B2-v2 4.31E-06 1.35E-07 1.28E-05 2.68E-08 lbs/ton 3 146.90 112.92 0.00

134

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Coal 1 PAH Chrysene B1-v4 2.25E-06 1.55E-07 1.28E-05 2.94E-10 lbs/ton 6 215.17 107.00 0.02

FBC, Coal 1 PAH Dibenz(a,h)anthracene B1-v4 2.24E-06 1.48E-07 1.28E-05 2.94E-10 lbs/ton 6 216.23 107.53 0.00

FBC, Coal 1 PAH Fluoranthene B1-v4 2.26E-06 1.37E-07 1.28E-05 3.67E-10 lbs/ton 6 213.53 106.19 0.03

FBC, Coal 1 PAH Fluorene B1-v4 2.41E-06 2.81E-07 1.28E-05 2.94E-10 lbs/ton 6 198.01 98.47 0.10

FBC, Coal 1 PAH Indeno(1,2,3-cd)pyrene B1-v4 2.24E-06 1.48E-07 1.28E-05 2.94E-10 lbs/ton 6 215.85 107.34 0.00

FBC, Coal 1 PAH Naphthalene B1-v6 2.61E-04 9.37E-06 1.55E-03 1.76E-09 lbs/ton 6 215.05 106.94 0.99

FBC, Coal 1 PAH Phenanthrene B1-v4 3.15E-06 4.68E-07 1.28E-05 5.32E-10 lbs/ton 6 150.96 75.07 0.33

FBC, Coal 1 PAH Pyrene B1-v4 2.26E-06 1.70E-07 1.28E-05 2.94E-10 lbs/ton 6 214.02 106.43 0.03

FBC, Coal 1 PCB PCB:Decachlorinatedbiphenyls

C3-v0 2.45E-07 2.45E-07 2.53E-07 2.38E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Dichlorinated biphenyls C3-v0 1.13E-07 1.13E-07 1.17E-07 1.10E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Heptachlorinatedbiphenyls

C3-v0 2.45E-07 2.45E-07 2.53E-07 2.38E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Hexachlorinatedbiphenyls

C3-v0 1.76E-07 1.75E-07 1.83E-07 1.69E-07 lbs/ton 1 4.02 9.99 0.00

FBC, Coal 1 PCB PCB:Monochlorinatedbiphenyls

C3-v0 1.13E-07 1.13E-07 1.17E-07 1.10E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Nonachlorinatedbiphenyls

C3-v0 2.45E-07 2.45E-07 2.53E-07 2.38E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Octachlorinatedbiphenyls

C3-v0 2.45E-07 2.45E-07 2.53E-07 2.38E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Pentachlorinatedbiphenyls

C3-v0 1.13E-07 1.13E-07 1.17E-07 1.10E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Tetrachlorinatedbiphenyls

C3-v0 1.13E-07 1.13E-07 1.17E-07 1.10E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 PCB PCB:Trichlorinated biphenyls C3-v0 1.13E-07 1.13E-07 1.17E-07 1.10E-07 lbs/ton 1 3.02 7.51 0.00

FBC, Coal 1 SVOC Phenol E3-v0 4.37E-04 4.28E-04 4.57E-04 4.27E-04 lbs/ton 1 3.94 9.79 0.00

FBC, Coal 1 VOC Acetaldehyde B3-v0 4.24E-04 4.21E-04 5.93E-04 2.74E-04 lbs/ton 2 32.18 33.77 0.36

FBC, Coal 1 VOC Acrolein C3-v0 6.35E-04 6.22E-04 6.91E-04 5.93E-04 lbs/ton 1 7.94 19.72 0.00

FBC, Coal 1 VOC Benzene C3-v0 2.67E-04 2.55E-04 3.10E-04 2.38E-04 lbs/ton 1 14.09 35.00 1.00

FBC, Coal 1 VOC Formaldehyde C1-v1 2.53E-03 5.95E-04 8.18E-03 2.49E-04 lbs/ton 6 125.19 62.25 0.97

FBC, Coke 1 Halogens HCl E3-v1 7.37E-02 6.51E-02 1.37E-01 2.06E-02 lbs/ton 2 70.28 73.75 1.00

FBC, Coke 1 Halogens HF E3-v1 7.10E-04 5.59E-04 1.64E-03 1.05E-04 lbs/ton 2 87.92 92.27 0.98

135

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Coke 1 Metals Arsenic C3-v1 4.62E-05 4.16E-05 9.39E-05 6.39E-06 lbs/ton 2 95.03 99.73 0.93

FBC, Coke 1 Metals Beryllium C3-v0 2.14E-06 1.68E-06 4.07E-06 1.29E-06 lbs/ton 2 51.83 54.39 0.00

FBC, Coke 1 Metals Cadmium C3-v0 1.69E-05 1.85E-05 2.70E-05 6.13E-06 lbs/ton 2 50.92 53.43 0.64

FBC, Coke 1 Metals Chromium (Hex) A3-v0 9.31E-06 8.98E-06 1.32E-05 6.69E-06 lbs/ton 2 29.24 30.69 0.00

FBC, Coke 1 Metals Chromium (Total) A3-v0 1.01E-05 9.17E-06 1.79E-05 7.22E-06 lbs/ton 2 39.00 40.93 1.00

FBC, Coke 1 Metals Copper C3-v1 7.95E-05 7.38E-05 1.67E-04 3.08E-05 lbs/ton 2 60.58 63.57 1.00

FBC, Coke 1 Metals Lead C3-v2 1.57E-04 8.49E-05 4.12E-04 1.87E-06 lbs/ton 2 118.47 124.32 1.00

FBC, Coke 1 Metals Manganese C3-v1 1.32E-04 8.94E-05 2.80E-04 3.85E-05 lbs/ton 2 80.66 84.65 1.00

FBC, Coke 1 Metals Mercury C3-v2 1.25E-03 9.24E-04 3.51E-03 7.99E-06 lbs/ton 2 117.50 123.31 0.00

FBC, Coke 1 Metals Nickel C3-v1 1.24E-04 1.13E-04 2.69E-04 2.05E-05 lbs/ton 2 85.42 89.64 1.00

FBC, Coke 1 Metals Selenium C3-v1 8.91E-05 7.48E-05 1.71E-04 3.20E-05 lbs/ton 2 72.45 76.03 0.00

FBC, Coke 1 Metals Zinc C3-v1 9.96E-03 1.05E-02 1.86E-02 1.02E-03 lbs/ton 2 76.52 80.30 1.00

FBC, Coke 1 PAH Acenaphthene B3-v1 6.12E-07 5.34E-07 1.30E-06 1.97E-07 lbs/ton 2 69.84 73.30 0.53

FBC, Coke 1 PAH Acenaphthylene B3-v0 3.97E-07 3.37E-07 7.64E-07 1.97E-07 lbs/ton 2 54.64 57.35 0.23

FBC, Coke 1 PAH Anthracene B3-v0 2.34E-07 2.05E-07 3.82E-07 1.94E-07 lbs/ton 2 31.20 32.75 0.27

FBC, Coke 1 PAH Benzo(a)anthracene B3-v0 2.35E-07 2.05E-07 3.94E-07 1.91E-07 lbs/ton 2 33.39 35.04 0.28

FBC, Coke 1 PAH Benzo(a)pyrene B3-v0 2.03E-07 1.97E-07 2.24E-07 1.91E-07 lbs/ton 2 6.22 6.53 0.00

FBC, Coke 1 PAH Benzo(b+k)fluoranthene B3-v0 3.08E-07 2.18E-07 6.95E-07 1.94E-07 lbs/ton 2 63.65 66.80 0.18

FBC, Coke 1 PAH Benzo(g,h,i)perylene B3-v0 2.09E-07 2.05E-07 2.29E-07 1.94E-07 lbs/ton 2 7.17 7.53 0.18

FBC, Coke 1 PAH Chrysene B3-v1 5.75E-07 5.18E-07 1.22E-06 2.17E-07 lbs/ton 2 63.17 66.29 0.40

FBC, Coke 1 PAH Dibenz(a,h)anthracene B3-v0 2.66E-07 2.05E-07 5.73E-07 1.94E-07 lbs/ton 2 56.59 59.39 0.36

FBC, Coke 1 PAH Fluoranthene B3-v1 9.71E-07 1.02E-06 1.99E-06 1.97E-07 lbs/ton 2 62.66 65.76 1.00

FBC, Coke 1 PAH Fluorene B3-v1 1.13E-06 1.26E-06 2.44E-06 1.97E-07 lbs/ton 2 74.72 78.41 0.94

FBC, Coke 1 PAH Indeno(1,2,3-cd)pyrene B3-v0 2.04E-07 1.98E-07 2.24E-07 1.94E-07 lbs/ton 2 5.66 5.94 0.16

FBC, Coke 1 PAH Naphthalene B3-v1 4.96E-05 2.17E-05 1.25E-04 1.18E-05 lbs/ton 2 101.34 106.35 1.00

FBC, Coke 1 PAH Phenanthrene B3-v1 5.35E-06 4.09E-06 1.53E-05 3.31E-07 lbs/ton 2 102.67 107.75 1.00

FBC, Coke 1 PAH Pyrene B3-v1 1.30E-06 6.97E-07 4.65E-06 1.97E-07 lbs/ton 2 130.36 136.80 0.97

FBC, Coke 1 Particulate Particulate E3-v1 1.20E-01 9.95E-02 2.90E-01 1.87E-02 lbs/ton 2 81.16 85.18 1.00

136

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FBC, Coke 1 VOC Ammonia E3-v0 3.66E-01 4.02E-01 4.33E-01 2.62E-01 lbs/ton 1 24.88 61.81 1.00

FBC, Coke 1 VOC Benzene C3-v0 1.60E-05 1.60E-05 1.60E-05 1.60E-05 lbs/ton 1 0.00 0.00 0.00

FCCU, Refinery gas 1 Halogens HCl A3-v1 5.29E-01 5.52E-01 8.85E-01 1.50E-01 lbs/MBarrels 1 69.54 172.75 1.00

FCCU, Refinery gas 1 Metals Arsenic A3-v1 3.02E-04 4.05E-04 4.18E-04 8.32E-05 lbs/MBarrels 1 62.80 156.01 0.00

FCCU, Refinery gas 1 Metals Beryllium A3-v0 3.28E-05 3.27E-05 3.33E-05 3.23E-05 lbs/MBarrels 1 1.65 4.10 0.00

FCCU, Refinery gas 1 Metals Cadmium A3-v0 8.34E-05 8.32E-05 8.47E-05 8.24E-05 lbs/MBarrels 1 1.40 3.47 0.00

FCCU, Refinery gas 1 Metals Chromium (Hex) C3-v0 2.77E-05 2.76E-05 2.96E-05 2.59E-05 lbs/MBarrels 1 6.61 16.43 0.00

FCCU, Refinery gas 1 Metals Chromium (Total) C3-v0 4.98E-04 4.99E-04 5.04E-04 4.92E-04 lbs/MBarrels 1 1.23 3.05 1.00

FCCU, Refinery gas 1 Metals Copper A3-v0 6.58E-04 4.31E-04 1.21E-03 3.39E-04 lbs/MBarrels 1 72.29 179.58 1.00

FCCU, Refinery gas 1 Metals Lead A3-v0 3.96E-04 3.43E-04 5.76E-04 2.70E-04 lbs/MBarrels 1 40.29 100.09 1.00

FCCU, Refinery gas 1 Metals Manganese A3-v0 6.28E-04 7.63E-04 7.93E-04 3.28E-04 lbs/MBarrels 1 41.41 102.87 1.00

FCCU, Refinery gas 1 Metals Mercury A3-v0 1.62E-04 9.61E-05 2.94E-04 9.54E-05 lbs/MBarrels 1 70.67 175.56 0.00

FCCU, Refinery gas 1 Metals Nickel A3-v0 6.90E-03 5.25E-03 1.04E-02 5.07E-03 lbs/MBarrels 1 43.65 108.45 1.00

FCCU, Refinery gas 1 Metals Selenium A3-v0 1.21E-03 1.22E-03 1.58E-03 8.39E-04 lbs/MBarrels 1 30.48 75.72 0.77

FCCU, Refinery gas 1 Metals Zinc A3-v0 2.30E-03 1.56E-03 4.04E-03 1.29E-03 lbs/MBarrels 1 66.02 164.01 1.00

FCCU, Refinery gas 1 PAH Acenaphthene A3-v0 4.90E-07 4.34E-07 6.17E-07 4.17E-07 lbs/MBarrels 1 22.65 56.26 1.00

FCCU, Refinery gas 1 PAH Acenaphthylene A3-v0 3.53E-07 3.65E-07 4.37E-07 2.59E-07 lbs/MBarrels 1 25.40 63.10 0.76

FCCU, Refinery gas 1 PAH Anthracene A3-v0 1.13E-06 1.13E-06 1.59E-06 6.72E-07 lbs/MBarrels 1 40.50 100.60 1.00

FCCU, Refinery gas 1 PAH Benzo(a)anthracene A3-v0 5.23E-07 2.59E-07 1.05E-06 2.57E-07 lbs/MBarrels 1 87.78 218.06 0.67

FCCU, Refinery gas 1 PAH Benzo(a)pyrene A3-v0 2.60E-07 2.59E-07 2.64E-07 2.57E-07 lbs/MBarrels 1 1.39 3.45 0.00

FCCU, Refinery gas 1 PAH Benzo(b)fluoranthene A3-v1 1.06E-06 4.34E-07 2.33E-06 4.17E-07 lbs/MBarrels 1 103.66 257.50 1.00

FCCU, Refinery gas 1 PAH Benzo(e)pyrene A3-v0 4.54E-07 2.59E-07 8.47E-07 2.57E-07 lbs/MBarrels 1 74.87 185.98 0.62

FCCU, Refinery gas 1 PAH Benzo(g,h,i)perylene A3-v0 2.60E-07 2.59E-07 2.64E-07 2.57E-07 lbs/MBarrels 1 1.39 3.45 0.00

FCCU, Refinery gas 1 PAH Benzo(k)fluoranthene A3-v0 3.65E-07 2.59E-07 5.81E-07 2.57E-07 lbs/MBarrels 1 50.99 126.66 0.53

FCCU, Refinery gas 1 PAH Chrysene A3-v1 2.56E-06 4.62E-07 6.87E-06 3.52E-07 lbs/MBarrels 1 145.68 361.90 1.00

FCCU, Refinery gas 1 PAH Dibenz(a,h)anthracene A3-v0 2.60E-07 2.59E-07 2.64E-07 2.57E-07 lbs/MBarrels 1 1.39 3.45 0.00

FCCU, Refinery gas 1 PAH Fluoranthene A3-v1 4.50E-06 3.24E-06 9.00E-06 1.24E-06 lbs/MBarrels 1 89.60 222.58 1.00

FCCU, Refinery gas 1 PAH Fluorene A3-v0 1.92E-06 1.95E-06 2.11E-06 1.71E-06 lbs/MBarrels 1 10.40 25.84 0.37

137

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

FCCU, Refinery gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 2.60E-07 2.59E-07 2.64E-07 2.57E-07 lbs/MBarrels 1 1.39 3.45 0.00

FCCU, Refinery gas 1 PAH Naphthalene A3-v0 1.02E-04 9.31E-05 1.21E-04 9.23E-05 lbs/MBarrels 1 16.16 40.15 0.00

FCCU, Refinery gas 1 PAH Phenanthrene A3-v0 1.15E-05 1.13E-05 1.69E-05 6.20E-06 lbs/MBarrels 1 46.55 115.64 0.82

FCCU, Refinery gas 1 PAH Pyrene A3-v1 2.48E-06 9.23E-07 5.81E-06 7.24E-07 lbs/MBarrels 1 115.86 287.80 1.00

FCCU, Refinery gas 1 SVOC 2-Methylnaphthalene A3-v0 4.57E-06 4.55E-06 4.65E-06 4.52E-06 lbs/MBarrels 1 1.42 3.53 0.00

FCCU, Refinery gas 1 SVOC Ethylbenzene A3-v0 2.03E-02 2.03E-02 2.03E-02 2.03E-02 lbs/MBarrels 1 0.00 0.00 0.00

FCCU, Refinery gas 1 SVOC Perylene A3-v0 2.60E-07 2.59E-07 2.64E-07 2.57E-07 lbs/MBarrels 1 1.39 3.45 0.00

FCCU, Refinery gas 1 SVOC Phenol A3-v0 2.27E-04 2.33E-04 3.05E-04 1.44E-04 lbs/MBarrels 1 35.46 88.09 1.00

FCCU, Refinery gas 1 VOC Acetaldehyde A3-v0 2.62E-02 2.60E-02 2.68E-02 2.58E-02 lbs/MBarrels 1 1.98 4.93 0.00

FCCU, Refinery gas 1 VOC Ammonia B3-v0 2.02E-01 1.79E-01 2.66E-01 1.60E-01 lbs/MBarrels 1 27.82 69.10 1.00

FCCU, Refinery gas 1 VOC Benzene A3-v0 1.49E-02 1.49E-02 1.49E-02 1.49E-02 lbs/MBarrels 1 0.00 0.00 0.00

FCCU, Refinery gas 1 VOC Carbonyl Sulfide A3-v0 1.68E-01 1.68E-01 1.68E-01 1.67E-01 lbs/MBarrels 1 0.41 1.02 0.00

FCCU, Refinery gas 1 VOC Cyanide E3-v0 3.55E-02 4.44E-02 4.76E-02 1.44E-02 lbs/MBarrels 1 51.60 128.18 1.00

FCCU, Refinery gas 1 VOC Formaldehyde A3-v0 4.81E-02 4.78E-02 4.91E-02 4.73E-02 lbs/MBarrels 1 1.98 4.92 0.00

FCCU, Refinery gas 1 VOC Hydrogen Sulfide A3-v0 1.55E-01 1.56E-01 1.56E-01 1.54E-01 lbs/MBarrels 1 0.54 1.34 0.00

FCCU, Refinery gas 1 VOC Toluene A3-v0 1.76E-02 1.76E-02 1.76E-02 1.76E-02 lbs/MBarrels 1 0.00 0.00 0.00

FCCU, Refinery gas 1 VOC Xylene (Total) A3-v0 2.03E-02 2.03E-02 2.03E-02 2.03E-02 lbs/MBarrels 1 0.00 0.00 0.67

Flare, Landfill gas 1 Halogens HCl B2-v1 2.12E+02 1.97E+02 3.73E+02 7.33E+01 lbs/MMcf 4 49.45 45.73 1.00

Flare, Landfill gas 1 Halogens HF A3-v0 1.41E+02 1.47E+02 1.87E+02 8.93E+01 lbs/MMcf 1 34.72 86.26 1.00

Flare, Landfill gas 1 Metals Arsenic C3-v0 5.68E-01 5.68E-01 5.92E-01 5.43E-01 lbs/MMcf 1 6.13 55.09 1.00

Flare, Landfill gas 1 Metals Cadmium C3-v0 4.87E-01 4.87E-01 6.43E-01 3.31E-01 lbs/MMcf 1 45.35 407.48 1.00

Flare, Landfill gas 1 Metals Chromium (Hex) C3-v0 1.39E-01 1.39E-01 1.40E-01 1.39E-01 lbs/MMcf 1 0.47 4.22 0.00

Flare, Landfill gas 1 Metals Chromium (Total) C3-v0 2.00E+01 2.00E+01 2.34E+01 1.66E+01 lbs/MMcf 1 23.93 215.03 1.00

Flare, Landfill gas 1 Metals Copper C3-v0 4.61E+00 4.61E+00 4.86E+00 4.35E+00 lbs/MMcf 1 7.79 70.00 1.00

Flare, Landfill gas 1 Metals Manganese C3-v0 1.68E+01 1.68E+01 1.91E+01 1.45E+01 lbs/MMcf 1 19.09 171.55 1.00

Flare, Landfill gas 1 Metals Nickel C3-v0 1.83E+02 1.83E+02 2.38E+02 1.27E+02 lbs/MMcf 1 42.94 385.78 1.00

Flare, Landfill gas 1 Metals Zinc C3-v0 2.57E+00 2.57E+00 4.28E+00 8.62E-01 lbs/MMcf 1 94.00 844.54 1.00

Flare, Landfill gas 1 PAH Acenaphthene A3-v2 2.17E-02 1.20E-03 5.60E-02 9.17E-04 lbs/MMcf 2 130.47 161.99 0.00

138

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Flare, Landfill gas 1 PAH Acenaphthylene A3-v2 2.16E-02 1.05E-03 5.60E-02 8.03E-04 lbs/MMcf 2 131.31 163.04 0.00

Flare, Landfill gas 1 PAH Anthracene A3-v1 2.21E-02 1.95E-03 5.60E-02 1.49E-03 lbs/MMcf 2 126.34 156.87 0.00

Flare, Landfill gas 1 PAH Benzo(a)anthracene A3-v3 2.12E-02 4.59E-04 5.60E-02 7.48E-05 lbs/MMcf 2 135.89 168.73 0.01

Flare, Landfill gas 1 PAH Benzo(a)pyrene A3-v3 2.11E-02 7.48E-05 5.60E-02 5.73E-05 lbs/MMcf 2 136.97 170.07 0.00

Flare, Landfill gas 1 PAH Benzo(b)fluoranthene A3-v3 2.11E-02 1.63E-04 5.60E-02 6.31E-05 lbs/MMcf 2 136.76 169.81 0.00

Flare, Landfill gas 1 PAH Benzo(e)pyrene A3-v0 6.88E-05 7.41E-05 7.48E-05 5.73E-05 lbs/MMcf 1 14.40 35.76 0.00

Flare, Landfill gas 1 PAH Benzo(g,h,i)perylene A3-v3 2.11E-02 7.48E-05 5.60E-02 5.73E-05 lbs/MMcf 2 136.97 170.07 0.00

Flare, Landfill gas 1 PAH Benzo(k)fluoranthene A3-v3 2.11E-02 7.48E-05 5.60E-02 5.73E-05 lbs/MMcf 2 136.97 170.07 0.00

Flare, Landfill gas 1 PAH Chrysene A3-v2 2.12E-02 5.93E-04 5.60E-02 1.95E-04 lbs/MMcf 2 135.20 167.88 0.01

Flare, Landfill gas 1 PAH Dibenz(a,h)anthracene A3-v3 2.11E-02 7.48E-05 5.60E-02 5.73E-05 lbs/MMcf 2 136.97 170.07 0.00

Flare, Landfill gas 1 PAH Fluoranthene A3-v1 2.27E-02 3.71E-03 5.60E-02 2.17E-03 lbs/MMcf 2 121.07 150.33 0.05

Flare, Landfill gas 1 PAH Fluorene A3-v1 2.38E-02 4.93E-03 5.60E-02 3.79E-03 lbs/MMcf 2 111.26 138.14 0.00

Flare, Landfill gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v3 2.11E-02 7.48E-05 5.60E-02 5.73E-05 lbs/MMcf 2 136.97 170.07 0.00

Flare, Landfill gas 1 PAH Naphthalene A3-v6 1.30E+01 3.56E-02 3.54E+01 3.59E-05 lbs/MMcf 2 137.56 170.81 1.00

Flare, Landfill gas 1 PAH Phenanthrene A3-v1 2.80E-02 1.27E-02 5.60E-02 9.75E-03 lbs/MMcf 2 80.43 99.87 0.00

Flare, Landfill gas 1 PAH Pyrene A3-v1 2.23E-02 2.24E-03 5.60E-02 1.72E-03 lbs/MMcf 2 124.73 154.87 0.00

Flare, Landfill gas 1 SVOC 2-Methylnaphthalene A3-v0 1.51E-02 1.63E-02 1.64E-02 1.26E-02 lbs/MMcf 1 14.29 35.50 0.00

Flare, Landfill gas 1 SVOC Perylene A3-v0 6.88E-05 7.41E-05 7.48E-05 5.73E-05 lbs/MMcf 1 14.40 35.76 0.00

Flare, Landfill gas 1 VOC 1,1,1-Trichloroethane A2-v1 1.17E-01 8.90E-02 3.37E-01 3.15E-02 lbs/MMcf 4 78.50 56.16 0.95

Flare, Landfill gas 1 VOC 1,1-Dichloroethane A2-v1 1.43E-01 1.04E-01 4.37E-01 4.92E-02 lbs/MMcf 3 92.75 85.78 0.66

Flare, Landfill gas 1 VOC 1,2-Dichloroethane A2-v2 2.54E-01 5.19E-02 1.35E+00 2.46E-02 lbs/MMcf 4 165.26 118.22 0.87

Flare, Landfill gas 1 VOC 1,4-Dioxane A3-v3 2.32E+01 1.08E-01 5.80E+01 9.63E-02 lbs/MMcf 2 136.33 169.27 0.00

Flare, Landfill gas 1 VOC Acetaldehyde A3-v1 2.58E-01 6.67E-02 6.53E-01 5.33E-02 lbs/MMcf 1 132.92 330.18 0.84

Flare, Landfill gas 1 VOC Acetonitrile A2-v2 1.60E+00 1.24E-01 7.96E+00 5.86E-02 lbs/MMcf 4 169.52 121.27 0.95

Flare, Landfill gas 1 VOC Acrolein A3-v0 8.44E-02 9.33E-02 9.33E-02 6.67E-02 lbs/MMcf 1 18.23 45.29 0.00

Flare, Landfill gas 1 VOC Acrylonitrile A3-v2 1.60E+01 2.15E+00 3.85E+01 2.60E-01 lbs/MMcf 2 127.82 158.71 0.03

Flare, Landfill gas 1 VOC Benzene A2-v1 1.83E-01 9.78E-02 8.59E-01 1.87E-02 lbs/MMcf 4 136.02 97.30 0.99

Flare, Landfill gas 1 VOC Carbon Tetrachloride A2-v0 2.39E-02 2.01E-02 3.76E-02 1.15E-02 lbs/MMcf 4 39.25 30.17 0.14

139

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Flare, Landfill gas 1 VOC Chlorobenzene A2-v1 1.51E-01 3.97E-02 8.69E-01 2.51E-02 lbs/MMcf 4 174.73 124.99 0.90

Flare, Landfill gas 1 VOC Chloroform A2-v0 3.22E-02 2.66E-02 5.60E-02 2.41E-02 lbs/MMcf 4 37.38 28.73 0.46

Flare, Landfill gas 1 VOC Dichloromethane A2-v1 2.76E+00 9.00E-01 9.41E+00 6.91E-01 lbs/MMcf 3 125.85 116.39 1.00

Flare, Landfill gas 1 VOC Diochloromethane A3-v0 2.74E-01 2.21E-01 4.29E-01 1.72E-01 lbs/MMcf 1 49.80 123.72 1.00

Flare, Landfill gas 1 VOC Formaldehyde B3-v3 2.95E+01 2.37E+01 6.74E+01 1.33E-01 lbs/MMcf 2 105.23 130.67 1.00

Flare, Landfill gas 1 VOC Toluene A2-v2 1.76E+01 3.11E+00 1.09E+02 4.85E-01 lbs/MMcf 4 193.61 138.50 1.00

Flare, Landfill gas 1 VOC Trichloroethene A2-v2 2.15E-01 2.94E-02 1.13E+00 1.99E-02 lbs/MMcf 4 171.84 132.09 0.97

Flare, Landfill gas 1 VOC Vinyl Chloride A2-v1 3.86E-02 3.56E-02 7.64E-02 1.64E-03 lbs/MMcf 4 79.68 57.00 0.67

Flare, Landfill gas 1 VOC Xylene (m,p) A2-v0 3.26E-01 3.13E-01 4.61E-01 2.33E-01 lbs/MMcf 3 22.35 20.67 1.00

Flare, Landfill gas 1 VOC Xylene (o) A2-v0 2.28E-01 2.01E-01 3.35E-01 1.38E-01 lbs/MMcf 3 33.89 31.35 0.80

Furnace, Alloy Stock 1 Metals Aluminum D3-v2 2.23E+00 2.04E-01 6.41E+00 8.09E-02 lbs/ton production 1 162.18 402.88 1.00

Furnace, Alloy Stock 1 Metals Antimony D3-v0 3.88E-03 3.84E-03 3.99E-03 3.80E-03 lbs/ton production 1 2.53 6.29 0.00

Furnace, Alloy Stock 1 Metals Arsenic D3-v1 5.36E-04 1.65E-04 1.28E-03 1.63E-04 lbs/ton production 1 120.33 298.91 1.00

Furnace, Alloy Stock 1 Metals Barium D3-v0 2.41E-02 3.16E-02 3.26E-02 8.26E-03 lbs/ton production 1 57.00 141.59 1.00

Furnace, Alloy Stock 1 Metals Beryllium D3-v0 1.96E-03 1.93E-03 2.02E-03 1.91E-03 lbs/ton production 1 2.94 7.30 0.00

Furnace, Alloy Stock 1 Metals Cadmium D3-v1 2.26E-03 1.11E-03 5.43E-03 2.42E-04 lbs/ton production 1 122.88 305.26 1.00

Furnace, Alloy Stock 1 Metals Chromium (Hex) C3-v0 6.86E-04 7.40E-04 7.72E-04 5.45E-04 lbs/ton production 1 17.89 44.44 0.00

Furnace, Alloy Stock 1 Metals Chromium (Total) D3-v0 2.43E-02 1.71E-02 4.07E-02 1.51E-02 lbs/ton production 1 58.67 145.74 1.00

Furnace, Alloy Stock 1 Metals Copper D3-v0 2.11E-01 1.92E-01 2.85E-01 1.57E-01 lbs/ton production 1 31.39 77.99 1.00

Furnace, Alloy Stock 1 Metals Iron D3-v0 2.01E-01 2.17E-01 2.71E-01 1.17E-01 lbs/ton production 1 38.81 96.40 1.00

Furnace, Alloy Stock 1 Metals Lead D3-v0 7.96E-03 8.55E-03 8.64E-03 6.69E-03 lbs/ton production 1 13.82 34.32 1.00

Furnace, Alloy Stock 1 Metals Manganese D3-v0 1.98E-01 1.71E-01 2.71E-01 1.51E-01 lbs/ton production 1 32.68 81.18 1.00

Furnace, Alloy Stock 1 Metals Mercury D3-v0 2.15E-04 1.71E-04 3.80E-04 9.47E-05 lbs/ton production 1 68.67 170.58 1.00

Furnace, Alloy Stock 1 Metals Nickel D3-v1 5.73E-02 2.61E-02 1.33E-01 1.28E-02 lbs/ton production 1 115.02 285.74 1.00

Furnace, Alloy Stock 1 Metals Phosphorus D3-v0 7.16E-02 7.27E-02 9.37E-02 4.84E-02 lbs/ton production 1 31.62 78.56 1.00

Furnace, Alloy Stock 1 Metals Selenium D3-v0 1.31E-04 1.29E-04 1.35E-04 1.28E-04 lbs/ton production 1 3.14 7.81 0.00

Furnace, Alloy Stock 1 Metals Silver D3-v0 8.31E-04 8.23E-04 8.54E-04 8.14E-04 lbs/ton production 1 2.53 6.29 1.00

Furnace, Alloy Stock 1 Metals Thallium D3-v0 1.57E-02 1.55E-02 1.62E-02 1.53E-02 lbs/ton production 1 3.04 7.55 0.00

140

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Furnace, Alloy Stock 1 Metals Zinc D3-v0 4.99E-02 5.70E-02 6.11E-02 3.16E-02 lbs/ton production 1 32.07 79.67 1.00

Furnace, Alloy Stock 1 VOC Hydrogen Sulfide C3-v0 1.64E+00 1.54E+00 1.85E+00 1.51E+00 lbs/ton production 1 11.57 28.74 0.00

Furnace, Aluminum 1 Metals Beryllium D3-v0 8.00E-05 8.00E-05 8.00E-05 8.00E-05 lbs/ton production 1 0.00 0.00 0.00

Furnace, Aluminum 1 Metals Cadmium D3-v1 4.37E-04 3.36E-04 8.48E-04 1.28E-04 lbs/ton production 1 84.73 210.48 1.00

Furnace, Aluminum 1 Metals Copper D3-v0 1.15E-03 1.14E-03 1.28E-03 1.04E-03 lbs/ton production 1 10.49 26.05 1.00

Furnace, Aluminum 1 Metals Lead D3-v0 4.48E-04 4.16E-04 5.28E-04 4.00E-04 lbs/ton production 1 15.57 38.67 1.00

Furnace, Aluminum 1 Metals Manganese D3-v0 1.87E-04 1.92E-04 2.24E-04 1.44E-04 lbs/ton production 1 21.57 53.59 1.00

Furnace, Aluminum 1 Metals Nickel D3-v0 2.51E-04 2.08E-04 3.52E-04 1.92E-04 lbs/ton production 1 35.15 87.33 1.00

Furnace, Aluminum 1 VOC Benzene A3-v1 1.17E-02 4.32E-03 2.64E-02 4.32E-03 lbs/ton production 1 109.14 271.13 0.75

Furnace, Aluminum 1 VOC Formaldehyde C3-v0 1.34E-01 1.33E-01 1.41E-01 1.27E-01 lbs/ton production 1 5.05 12.55 1.00

Furnace, Aluminum 1 VOC Hydrogen Sulfide C3-v0 2.90E-01 2.96E-01 2.96E-01 2.78E-01 lbs/ton production 1 3.50 8.70 1.00

Furnace, Aluminum 2 Metals Beryllium D3-v0 4.00E-07 4.00E-07 4.00E-07 4.00E-07 lbs/ton production 1 0.00 0.00 0.00

Furnace, Aluminum 2 Metals Cadmium D3-v0 1.73E-06 2.00E-06 2.00E-06 1.20E-06 lbs/ton production 1 26.65 66.19 1.00

Furnace, Aluminum 2 Metals Copper D3-v0 2.53E-06 2.40E-06 3.60E-06 1.60E-06 lbs/ton production 1 39.74 98.71 1.00

Furnace, Aluminum 2 Metals Lead D3-v0 1.33E-06 1.20E-06 1.60E-06 1.20E-06 lbs/ton production 1 17.32 43.03 1.00

Furnace, Aluminum 2 Metals Manganese D3-v1 6.95E-07 8.00E-07 1.20E-06 8.50E-08 lbs/ton production 1 81.28 201.91 1.00

Furnace, Aluminum 2 Metals Nickel D3-v0 8.00E-07 8.00E-07 1.20E-06 4.00E-07 lbs/ton production 1 50.00 124.21 1.00

Furnace, Aluminum 2 VOC Benzene A3-v0 8.00E-06 8.00E-06 8.00E-06 8.00E-06 lbs/ton production 1 0.00 0.00 0.00

Furnace, Aluminum 2 VOC Formaldehyde C3-v0 2.56E-04 2.44E-04 3.52E-04 1.72E-04 lbs/ton production 1 35.38 87.89 1.00

Furnace, Aluminum 2 VOC Hydrogen Sulfide C3-v0 5.47E-04 5.60E-04 5.60E-04 5.20E-04 lbs/ton production 1 4.22 10.49 1.00

Furnace, Aluminum 3 Metals Beryllium D3-v0 1.33E-05 1.33E-05 1.33E-05 1.33E-05 lbs/ton production 1 0.00 0.00 0.00

Furnace, Aluminum 3 Metals Cadmium D3-v1 1.40E-04 8.80E-05 3.17E-04 1.33E-05 lbs/ton production 1 113.52 282.00 1.00

Furnace, Aluminum 3 Metals Copper D3-v1 4.38E-04 3.73E-04 8.45E-04 9.60E-05 lbs/ton production 1 86.45 214.76 1.00

Furnace, Aluminum 3 Metals Lead D3-v0 3.14E-04 3.36E-04 3.87E-04 2.19E-04 lbs/ton production 1 27.46 68.22 1.00

Furnace, Aluminum 3 Metals Manganese D3-v1 1.17E-04 1.31E-04 2.08E-04 1.33E-05 lbs/ton production 1 83.54 207.52 1.00

Furnace, Aluminum 3 Metals Nickel D3-v1 1.35E-04 1.31E-04 2.61E-04 1.33E-05 lbs/ton production 1 91.82 228.09 1.00

Furnace, Aluminum 3 VOC Benzene A3-v0 5.84E-02 6.35E-02 8.51E-02 2.67E-02 lbs/ton production 1 50.56 125.60 1.00

Furnace, Aluminum 3 VOC Formaldehyde C3-v0 8.88E-02 8.81E-02 1.05E-01 7.34E-02 lbs/ton production 1 17.76 44.12 1.00

141

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Furnace, Aluminum 3 VOC Hydrogen Sulfide C3-v0 1.66E-01 1.67E-01 1.69E-01 1.63E-01 lbs/ton production 1 1.81 4.49 1.00

Furnace, Aluminum 4 Metals Arsenic D3-v0 7.52E-06 7.20E-06 8.16E-06 7.20E-06 lbs/ton production 1 7.37 18.31 0.00

Furnace, Aluminum 4 Metals Beryllium D3-v0 2.99E-05 2.88E-05 3.31E-05 2.78E-05 lbs/ton production 1 9.40 23.35 0.00

Furnace, Aluminum 4 Metals Cadmium D3-v0 4.77E-05 5.76E-05 5.76E-05 2.78E-05 lbs/ton production 1 36.04 89.52 0.81

Furnace, Aluminum 4 Metals Chromium (Hex) C3-v1 2.21E-05 1.65E-05 5.28E-05 4.50E-06 lbs/ton production 2 93.68 98.31 1.00

Furnace, Aluminum 4 Metals Chromium (Total) C3-v1 5.07E-05 2.99E-05 1.54E-04 7.62E-06 lbs/ton production 2 110.40 115.86 1.00

Furnace, Aluminum 4 Metals Copper D3-v0 1.22E-04 9.12E-05 2.16E-04 5.76E-05 lbs/ton production 1 68.64 170.50 1.00

Furnace, Aluminum 4 Metals Lead D3-v1 7.71E-04 2.98E-04 1.87E-03 1.44E-04 lbs/ton production 1 124.02 308.07 1.00

Furnace, Aluminum 4 Metals Manganese D3-v2 1.26E-02 3.74E-04 3.74E-02 1.20E-04 lbs/ton production 1 169.82 421.86 1.00

Furnace, Aluminum 4 Metals Mercury D3-v0 4.64E-06 3.12E-06 7.68E-06 3.12E-06 lbs/ton production 1 56.74 140.95 1.00

Furnace, Aluminum 4 Metals Nickel D3-v1 3.31E-04 1.58E-04 7.68E-04 6.72E-05 lbs/ton production 1 115.04 285.78 1.00

Furnace, Aluminum 4 Metals Selenium D3-v0 8.16E-06 7.20E-06 1.06E-05 6.72E-06 lbs/ton production 1 25.64 63.69 0.73

Furnace, Aluminum 4 Metals Zinc D3-v1 5.14E-04 4.18E-04 9.60E-04 1.63E-04 lbs/ton production 1 79.24 196.85 1.00

Furnace, Aluminum 4 VOC Hydrogen Sulfide C3-v0 2.32E-02 2.40E-02 2.50E-02 2.06E-02 lbs/ton production 1 9.78 24.29 1.00

Furnace, Brass/Bronze 1 Metals Arsenic A3-v0 3.70E-05 3.70E-05 4.11E-05 3.29E-05 lbs/ton production 1 15.71 141.18 1.00

Furnace, Brass/Bronze 1 Metals Beryllium A3-v0 5.76E-05 5.76E-05 5.76E-05 5.76E-05 lbs/ton production 1 0.00 0.00 0.00

Furnace, Brass/Bronze 1 Metals Cadmium A3-v0 4.11E-05 4.11E-05 6.58E-05 1.65E-05 lbs/ton production 1 84.85 762.37 1.00

Furnace, Brass/Bronze 1 Metals Chromium (Hex) C3-v0 2.29E-03 2.17E-03 2.53E-03 2.16E-03 lbs/ton production 1 9.04 22.45 0.00

Furnace, Brass/Bronze 1 Metals Chromium (Total) C3-v0 3.29E-04 3.29E-04 4.94E-04 1.65E-04 lbs/ton production 1 50.00 124.21 1.00

Furnace, Brass/Bronze 1 Metals Copper A3-v1 2.13E-03 2.57E-03 3.27E-03 5.51E-04 lbs/ton production 1 66.24 164.55 1.00

Furnace, Brass/Bronze 1 Metals Lead A3-v0 1.04E-03 1.02E-03 1.32E-03 7.73E-04 lbs/ton production 1 26.57 65.99 1.00

Furnace, Brass/Bronze 1 Metals Manganese A3-v1 3.89E-04 2.63E-04 8.23E-04 8.23E-05 lbs/ton production 1 99.12 246.24 1.00

Furnace, Brass/Bronze 1 Metals Mercury A3-v0 5.76E-05 5.76E-05 6.58E-05 4.94E-05 lbs/ton production 1 14.29 35.49 0.00

Furnace, Brass/Bronze 1 Metals Nickel A3-v0 9.10E-04 9.21E-04 9.87E-04 8.23E-04 lbs/ton production 1 9.10 22.60 0.30

Furnace, Brass/Bronze 1 Metals Selenium A3-v0 1.81E-04 1.81E-04 1.89E-04 1.73E-04 lbs/ton production 1 4.55 11.29 0.00

Furnace, Brass/Bronze 1 Metals Zinc A3-v1 1.14E-03 1.02E-03 2.03E-03 3.70E-04 lbs/ton production 1 73.41 182.36 1.00

Furnace, Carbonization 1 PAH Acenaphthene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Acenaphthylene C3-v0 3.30E-05 2.56E-05 4.92E-05 2.41E-05 lbs/ton material 1 42.70 106.08 0.50

142

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Furnace, Carbonization 1 PAH Anthracene C3-v0 2.49E-05 2.46E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.19 10.41 0.33

Furnace, Carbonization 1 PAH Benzo(a)anthracene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Benzo(a)pyrene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Benzo(b)fluoranthene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Benzo(g,h,i)perylene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Benzo(k)fluoranthene C3-v0 2.94E-05 2.56E-05 3.87E-05 2.41E-05 lbs/ton material 1 27.18 67.53 0.00

Furnace, Carbonization 1 PAH Chrysene C3-v0 2.63E-05 2.61E-05 2.86E-05 2.41E-05 lbs/ton material 1 8.62 21.40 0.00

Furnace, Carbonization 1 PAH Dibenz(a,h)anthracene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Fluoranthene C3-v0 4.95E-05 4.37E-05 6.53E-05 3.97E-05 lbs/ton material 1 27.80 69.06 1.00

Furnace, Carbonization 1 PAH Fluorene C3-v0 1.34E-04 9.54E-05 2.36E-04 7.03E-05 lbs/ton material 1 66.70 165.68 1.00

Furnace, Carbonization 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 2.53E-05 2.56E-05 2.61E-05 2.41E-05 lbs/ton material 1 4.14 10.27 0.00

Furnace, Carbonization 1 PAH Naphthalene C3-v3 2.36E-02 1.05E-02 6.02E-02 3.36E-05 lbs/ton material 1 136.24 338.43 1.00

Furnace, Carbonization 1 PAH Phenanthrene C3-v0 1.62E-04 1.86E-04 2.16E-04 8.53E-05 lbs/ton material 1 42.10 104.59 1.00

Furnace, Carbonization 1 PAH Pyrene C3-v0 3.48E-05 3.87E-05 3.97E-05 2.61E-05 lbs/ton material 1 21.70 53.90 1.00

Furnace, Carbonization 1 SVOC Ethylbenzene C3-v0 1.59E-03 1.18E-03 2.41E-03 1.18E-03 lbs/ton material 1 44.80 111.30 0.00

Furnace, Carbonization 1 VOC Benzene C3-v0 1.55E-03 1.74E-03 1.78E-03 1.13E-03 lbs/ton material 1 23.44 58.23 0.62

Furnace, Carbonization 1 VOC Formaldehyde A3-v0 3.21E-02 3.32E-02 3.96E-02 2.34E-02 lbs/ton material 1 25.47 63.26 1.00

Furnace, Carbonization 1 VOC Toluene C3-v0 2.36E-03 1.02E-03 5.02E-03 1.02E-03 lbs/ton material 1 97.92 243.25 0.86

Furnace, Carbonization 1 VOC Xylene (Total) C3-v0 1.60E-03 1.18E-03 2.42E-03 1.18E-03 lbs/ton material 1 44.66 110.95 0.00

Furnace, Glass 1 Metals Arsenic A3-v0 3.70E-05 3.28E-05 4.64E-05 3.18E-05 lbs/ton production 1 22.09 54.88 1.00

Furnace, Glass 1 Metals Chromium (Hex) C3-v0 4.09E-06 4.15E-06 4.20E-06 3.93E-06 lbs/ton production 1 3.46 8.61 0.00

Furnace, Glass 1 Metals Chromium (Total) C3-v1 1.60E-05 7.86E-06 3.53E-05 4.98E-06 lbs/ton production 1 104.25 258.96 1.00

Furnace, Glass 2 Metals Arsenic C3-v1 2.28E-04 1.49E-04 5.38E-04 6.99E-05 lbs/ton production 2 84.45 88.63 1.00

Furnace, Glass 2 Metals Chromium (Hex) D2-v3 1.02E-03 1.87E-05 3.89E-03 2.45E-06 lbs/ton production 3 152.85 117.49 0.99

Furnace, Glass 2 Metals Chromium (Total) D3-v1 2.06E-04 1.86E-04 4.30E-04 7.30E-05 lbs/ton production 2 70.34 73.81 1.00

Furnace, Glass 2 Metals Lead E3-v0 4.61E-04 5.13E-04 5.21E-04 3.50E-04 lbs/ton production 1 20.94 52.01 1.00

Furnace, Lead 1 Metals Antimony D2-v1 1.26E-03 5.33E-04 4.95E-03 2.84E-04 lbs/ton charged 3 129.46 99.51 0.74

Furnace, Lead 1 Metals Arsenic D2-v0 5.94E-05 5.16E-05 8.84E-05 1.80E-05 lbs/ton charged 3 43.91 33.75 0.51

143

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Furnace, Lead 1 Metals Barium D2-v2 9.88E-04 2.99E-04 2.95E-03 5.05E-05 lbs/ton charged 3 125.06 96.13 1.00

Furnace, Lead 1 Metals Beryllium D2-v1 9.60E-05 2.69E-05 2.48E-04 1.41E-05 lbs/ton charged 3 117.72 90.49 0.00

Furnace, Lead 1 Metals Cadmium D2-v1 4.52E-04 1.27E-04 1.15E-03 6.70E-05 lbs/ton charged 3 114.84 88.27 0.06

Furnace, Lead 1 Metals Chromium (Hex) A3-v0 2.58E-07 2.55E-07 2.69E-07 2.52E-07 lbs/ton charged 1 3.39 8.42 0.00

Furnace, Lead 1 Metals Chromium (Total) D2-v1 7.09E-04 1.76E-04 1.67E-03 9.13E-05 lbs/ton charged 3 110.47 92.35 0.59

Furnace, Lead 1 Metals Copper D2-v1 1.03E-03 2.69E-04 3.17E-03 9.07E-05 lbs/ton charged 3 111.47 85.69 1.00

Furnace, Lead 1 Metals Lead D2-v0 2.86E-03 2.77E-03 4.57E-03 1.85E-03 lbs/ton charged 3 29.66 22.80 1.00

Furnace, Lead 1 Metals Manganese D2-v3 3.62E-02 1.12E-03 3.10E-01 1.31E-04 lbs/ton charged 3 283.95 218.26 1.00

Furnace, Lead 1 Metals Mercury D2-v1 7.01E-05 2.37E-05 2.66E-04 8.44E-06 lbs/ton charged 3 144.62 111.17 0.96

Furnace, Lead 1 Metals Nickel D2-v1 9.78E-04 2.89E-04 2.48E-03 1.42E-04 lbs/ton charged 3 114.16 87.75 0.13

Furnace, Lead 1 Metals Selenium D2-v1 6.17E-05 1.73E-05 1.59E-04 9.07E-06 lbs/ton charged 3 117.71 90.48 0.86

Furnace, Lead 1 Metals Silver D2-v1 3.25E-04 9.66E-05 8.33E-04 5.05E-05 lbs/ton charged 3 115.89 89.08 0.00

Furnace, Lead 1 Metals Thallium D2-v1 7.70E-03 2.17E-03 1.99E-02 1.14E-03 lbs/ton charged 3 117.46 90.29 0.00

Furnace, Lead 1 Metals Zinc D2-v1 7.14E-03 3.25E-03 2.01E-02 9.65E-04 lbs/ton charged 3 100.87 77.54 1.00

Furnace, Lead 2 Metals Antimony D3-v0 4.26E-04 4.08E-04 4.81E-04 3.89E-04 lbs/ton production 1 11.42 28.37 0.38

Furnace, Lead 2 Metals Arsenic D3-v0 7.37E-06 6.96E-06 9.00E-06 6.16E-06 lbs/ton production 1 19.83 49.26 1.00

Furnace, Lead 2 Metals Barium D3-v0 4.36E-04 4.25E-04 5.77E-04 3.06E-04 lbs/ton production 1 31.12 77.30 1.00

Furnace, Lead 2 Metals Beryllium D3-v0 1.87E-05 1.88E-05 1.95E-05 1.80E-05 lbs/ton production 1 4.00 9.95 0.00

Furnace, Lead 2 Metals Cadmium D3-v0 8.71E-05 8.71E-05 9.05E-05 8.37E-05 lbs/ton production 1 3.93 9.77 0.00

Furnace, Lead 2 Metals Chromium (Hex) A3-v0 4.84E-05 4.86E-05 4.91E-05 4.74E-05 lbs/ton production 1 1.80 4.47 0.00

Furnace, Lead 2 Metals Chromium (Total) D3-v0 1.26E-04 1.26E-04 1.31E-04 1.21E-04 lbs/ton production 1 3.92 9.74 0.00

Furnace, Lead 2 Metals Copper D3-v0 1.79E-04 1.32E-04 2.75E-04 1.30E-04 lbs/ton production 1 46.45 115.38 1.00

Furnace, Lead 2 Metals Lead D3-v0 1.26E-03 1.16E-03 2.05E-03 5.64E-04 lbs/ton production 1 59.62 148.10 1.00

Furnace, Lead 2 Metals Manganese D3-v2 1.93E-02 1.38E-02 4.39E-02 1.93E-04 lbs/ton production 1 115.94 288.02 1.00

Furnace, Lead 2 Metals Mercury D3-v0 6.58E-05 5.78E-05 9.24E-05 4.72E-05 lbs/ton production 1 35.98 89.37 1.00

Furnace, Lead 2 Metals Nickel D3-v0 1.92E-04 1.93E-04 1.95E-04 1.88E-04 lbs/ton production 1 1.96 4.88 0.00

Furnace, Lead 2 Metals Selenium D3-v0 1.21E-05 1.21E-05 1.25E-05 1.16E-05 lbs/ton production 1 3.92 9.75 0.00

Furnace, Lead 2 Metals Silver D3-v0 6.30E-05 6.30E-05 6.55E-05 6.04E-05 lbs/ton production 1 4.04 10.04 0.00

144

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Furnace, Lead 2 Metals Thallium D3-v0 1.50E-03 1.50E-03 1.56E-03 1.44E-03 lbs/ton production 1 3.88 9.63 0.00

Furnace, Lead 2 Metals Zinc D3-v0 1.23E-03 1.31E-03 1.38E-03 9.89E-04 lbs/ton production 1 16.90 41.99 1.00

Heater, Natural Gas 1 PAH Acenaphthene A3-v0 1.39E-06 1.40E-06 1.62E-06 1.15E-06 lbs/MMcf 1 16.72 41.54 0.72

Heater, Natural Gas 1 PAH Acenaphthylene A3-v1 1.21E-05 2.84E-06 3.23E-05 1.15E-06 lbs/MMcf 1 144.82 359.76 0.97

Heater, Natural Gas 1 PAH Anthracene A3-v0 1.61E-06 1.83E-06 1.85E-06 1.15E-06 lbs/MMcf 1 24.62 61.15 0.76

Heater, Natural Gas 1 PAH Benzo(a)anthracene A3-v0 1.96E-06 1.97E-06 2.85E-06 1.15E-06 lbs/MMcf 2 36.13 37.92 0.80

Heater, Natural Gas 1 PAH Benzo(a)pyrene A3-v0 9.80E-07 9.96E-07 1.18E-06 7.52E-07 lbs/MMcf 2 18.79 19.72 0.42

Heater, Natural Gas 1 PAH Benzo(b)fluoranthene A3-v0 1.14E-06 1.15E-06 1.18E-06 1.08E-06 lbs/MMcf 1 4.76 11.83 0.00

Heater, Natural Gas 1 PAH Benzo(g,h,i)perylene A3-v0 1.25E-06 1.18E-06 1.42E-06 1.15E-06 lbs/MMcf 1 11.81 29.34 0.38

Heater, Natural Gas 1 PAH Benzo(k)fluoranthene A3-v0 9.90E-07 9.96E-07 1.18E-06 7.52E-07 lbs/MMcf 2 17.59 18.46 0.42

Heater, Natural Gas 1 PAH Chrysene A3-v0 1.39E-06 1.18E-06 1.83E-06 1.15E-06 lbs/MMcf 1 27.63 68.65 0.44

Heater, Natural Gas 1 PAH Dibenz(a,h)anthracene A3-v0 9.17E-07 9.15E-07 1.18E-06 5.91E-07 lbs/MMcf 2 27.43 28.78 0.38

Heater, Natural Gas 1 PAH Fluoranthene A3-v0 1.19E-05 1.07E-05 1.79E-05 7.15E-06 lbs/MMcf 1 46.07 114.45 1.00

Heater, Natural Gas 1 PAH Fluorene A3-v0 4.59E-06 4.50E-06 5.82E-06 3.46E-06 lbs/MMcf 1 25.79 64.07 1.00

Heater, Natural Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 1.17E-06 1.17E-06 1.50E-06 6.98E-07 lbs/MMcf 2 24.34 25.54 0.52

Heater, Natural Gas 1 PAH Naphthalene A3-v1 1.12E-03 9.20E-04 2.47E-03 1.94E-04 lbs/MMcf 2 90.11 94.56 1.00

Heater, Natural Gas 1 PAH Phenanthrene A3-v0 3.37E-05 3.31E-05 4.74E-05 2.05E-05 lbs/MMcf 1 39.96 99.27 1.00

Heater, Natural Gas 1 PAH Pyrene A3-v1 5.60E-06 2.84E-06 1.16E-05 2.31E-06 lbs/MMcf 1 93.70 232.75 1.00

Heater, Natural Gas 1 SVOC Ethylbenzene A3-v0 2.25E-03 2.25E-03 2.25E-03 2.25E-03 lbs/MMcf 1 0.00 0.00 0.00

Heater, Natural Gas 1 VOC Acetaldehyde A3-v1 1.40E-02 7.41E-03 5.00E-02 4.41E-03 lbs/MMcf 2 127.73 134.04 0.89

Heater, Natural Gas 1 VOC Acrolein A3-v0 4.84E-03 4.44E-03 1.00E-02 2.56E-03 lbs/MMcf 2 55.28 58.01 0.00

Heater, Natural Gas 1 VOC Benzene B3-v1 1.12E-02 6.85E-03 4.00E-02 1.65E-03 lbs/MMcf 2 131.02 137.49 0.65

Heater, Natural Gas 1 VOC Formaldehyde A3-v2 7.40E-02 3.27E-02 3.00E-01 4.32E-03 lbs/MMcf 2 154.79 162.44 0.98

Heater, Natural Gas 1 VOC Propylene B3-v2 2.35E-01 1.63E-01 6.13E-01 6.00E-03 lbs/MMcf 2 113.80 119.42 0.99

Heater, Natural Gas 1 VOC Toluene B3-v1 2.95E-02 2.00E-02 7.47E-02 8.37E-03 lbs/MMcf 2 83.45 87.58 1.00

Heater, Natural Gas 1 VOC Xylene (Total) B3-v1 1.43E-02 1.00E-02 2.97E-02 5.71E-03 lbs/MMcf 2 62.87 65.98 0.65

Heater, Natural/Ref. Gas 1 PAH Acenaphthene A3-v1 7.53E-06 2.44E-06 1.81E-05 2.05E-06 lbs/MMcf 1 121.63 302.15 1.00

Heater, Natural/Ref. Gas 1 PAH Acenaphthylene A3-v2 5.88E-05 2.32E-06 1.72E-04 2.11E-06 lbs/MMcf 1 166.69 414.08 1.00

145

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Natural/Ref. Gas 1 PAH Anthracene A3-v0 1.04E-05 8.97E-06 1.43E-05 7.89E-06 lbs/MMcf 1 33.12 82.27 1.00

Heater, Natural/Ref. Gas 1 PAH Benzo(a)anthracene A3-v0 9.57E-06 7.66E-06 1.67E-05 4.34E-06 lbs/MMcf 1 66.91 166.22 1.00

Heater, Natural/Ref. Gas 1 PAH Benzo(a)pyrene A3-v1 6.07E-06 6.67E-06 1.10E-05 5.25E-07 lbs/MMcf 1 86.79 215.60 0.97

Heater, Natural/Ref. Gas 1 PAH Benzo(b)fluoranthene A3-v0 2.63E-06 1.91E-06 4.19E-06 1.79E-06 lbs/MMcf 1 51.36 127.58 1.00

Heater, Natural/Ref. Gas 1 PAH Benzo(g,h,i)perylene A3-v1 4.13E-07 1.59E-07 9.55E-07 1.25E-07 lbs/MMcf 1 113.74 282.56 0.77

Heater, Natural/Ref. Gas 1 PAH Benzo(k)fluoranthene A3-v1 1.46E-06 8.35E-07 3.18E-06 3.70E-07 lbs/MMcf 1 103.06 256.01 0.92

Heater, Natural/Ref. Gas 1 PAH Chrysene A3-v0 7.91E-07 6.38E-07 1.24E-06 4.91E-07 lbs/MMcf 1 50.32 125.01 0.52

Heater, Natural/Ref. Gas 1 PAH Dibenz(a,h)anthracene A3-v0 1.38E-07 1.07E-07 2.08E-07 1.01E-07 lbs/MMcf 1 43.36 107.70 0.00

Heater, Natural/Ref. Gas 1 PAH Fluoranthene A3-v1 1.80E-05 1.03E-05 3.82E-05 5.49E-06 lbs/MMcf 1 98.02 243.49 1.00

Heater, Natural/Ref. Gas 1 PAH Fluorene A3-v1 6.48E-04 1.50E-04 1.69E-03 1.01E-04 lbs/MMcf 1 139.64 346.87 1.00

Heater, Natural/Ref. Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.56E-07 4.04E-07 6.67E-07 2.96E-07 lbs/MMcf 1 41.87 104.01 0.49

Heater, Natural/Ref. Gas 1 PAH Naphthalene A3-v1 2.31E-03 4.04E-04 6.18E-03 3.45E-04 lbs/MMcf 1 145.12 360.49 1.00

Heater, Natural/Ref. Gas 1 PAH Phenanthrene A3-v1 2.06E-04 1.06E-04 4.30E-04 8.36E-05 lbs/MMcf 1 93.74 232.86 1.00

Heater, Natural/Ref. Gas 1 PAH Pyrene A3-v1 1.25E-05 7.14E-06 2.62E-05 4.04E-06 lbs/MMcf 1 96.40 239.46 1.00

Heater, Natural/Ref. Gas 1 SVOC Phenol A3-v0 1.72E-03 1.82E-03 2.08E-03 1.26E-03 lbs/MMcf 1 24.34 60.47 1.00

Heater, Natural/Ref. Gas 1 VOC Acetaldehyde C3-v0 1.47E-02 1.43E-02 1.67E-02 1.30E-02 lbs/MMcf 1 12.83 31.87 1.00

Heater, Natural/Ref. Gas 1 VOC Acrolein C3-v0 2.29E-03 2.10E-03 2.84E-03 1.93E-03 lbs/MMcf 1 21.23 52.74 0.00

Heater, Natural/Ref. Gas 1 VOC Benzene C3-v0 2.12E-02 1.99E-02 2.44E-02 1.94E-02 lbs/MMcf 1 13.02 32.34 0.00

Heater, Natural/Ref. Gas 1 VOC Formaldehyde C3-v1 4.33E-02 2.38E-02 8.89E-02 1.73E-02 lbs/MMcf 1 91.33 226.88 1.00

Heater, Natural/Ref. Gas 1 VOC Propylene C3-v0 1.20E-02 1.13E-02 1.38E-02 1.10E-02 lbs/MMcf 1 13.02 32.34 0.00

Heater, Natural/Ref. Gas 1 VOC Toluene C3-v0 2.63E-02 2.46E-02 3.03E-02 2.41E-02 lbs/MMcf 1 13.02 32.34 0.00

Heater, Natural/Ref. Gas 1 VOC Xylene (Total) C3-v0 3.03E-02 2.84E-02 3.49E-02 2.77E-02 lbs/MMcf 1 13.02 32.34 0.00

Heater, Oil 1 Dioxin/Furan Dioxin:4D 2378 C3-v0 4.96E-10 5.94E-10 5.97E-10 2.97E-10 lbs/Mgal 1 34.70 86.20 0.00

Heater, Oil 1 Dioxin/Furan Dioxin:5D 12378 C3-v1 2.49E-09 5.94E-10 6.57E-09 2.97E-10 lbs/Mgal 1 142.30 353.49 0.00

Heater, Oil 1 Dioxin/Furan Dioxin:6D 123478 C3-v1 2.19E-09 5.94E-10 5.68E-09 2.97E-10 lbs/Mgal 1 138.10 343.07 0.00

Heater, Oil 1 Dioxin/Furan Dioxin:6D 123678 C3-v1 2.99E-09 5.94E-10 8.07E-09 2.97E-10 lbs/Mgal 1 147.43 366.24 0.07

Heater, Oil 1 Dioxin/Furan Dioxin:6D 123789 C3-v1 4.78E-09 5.94E-10 1.34E-08 2.97E-10 lbs/Mgal 1 157.08 390.20 0.04

Heater, Oil 1 Dioxin/Furan Dioxin:7D 1234678 C3-v1 1.33E-08 4.45E-09 3.29E-08 2.68E-09 lbs/Mgal 1 127.05 315.60 1.00

146

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Oil 1 Dioxin/Furan Dioxin:8D C3-v0 4.68E-08 5.64E-08 5.97E-08 2.41E-08 lbs/Mgal 1 42.12 104.64 1.00

Heater, Oil 1 Dioxin/Furan Furan:4F 2378 C3-v2 8.93E-08 1.48E-09 2.66E-07 5.95E-10 lbs/Mgal 1 171.19 425.26 1.00

Heater, Oil 1 Dioxin/Furan Furan:5F 12378 C3-v2 8.56E-09 5.94E-10 2.48E-08 2.97E-10 lbs/Mgal 1 164.20 407.89 0.00

Heater, Oil 1 Dioxin/Furan Furan:5F 23478 C3-v2 1.52E-08 5.94E-10 4.48E-08 2.97E-10 lbs/Mgal 1 168.14 417.68 0.00

Heater, Oil 1 Dioxin/Furan Furan:6F 123478 C3-v2 1.92E-08 5.94E-10 5.68E-08 1.49E-10 lbs/Mgal 1 169.85 421.94 0.01

Heater, Oil 1 Dioxin/Furan Furan:6F 123678 C3-v2 6.12E-09 2.97E-10 1.79E-08 1.49E-10 lbs/Mgal 1 166.91 414.62 0.02

Heater, Oil 1 Dioxin/Furan Furan:6F 123789 C3-v0 4.96E-10 5.94E-10 5.97E-10 2.97E-10 lbs/Mgal 1 34.70 86.20 0.00

Heater, Oil 1 Dioxin/Furan Furan:6F 234678 C3-v1 8.76E-09 8.91E-10 2.48E-08 5.95E-10 lbs/Mgal 1 158.52 393.80 0.03

Heater, Oil 1 Dioxin/Furan Furan:7F 1234678 C3-v2 1.95E-08 1.19E-09 5.68E-08 5.95E-10 lbs/Mgal 1 165.30 410.63 1.00

Heater, Oil 1 Dioxin/Furan Furan:7F 1234789 C3-v1 1.19E-09 5.94E-10 2.69E-09 2.97E-10 lbs/Mgal 1 109.22 271.31 0.00

Heater, Oil 1 Dioxin/Furan Furan:8F C3-v1 1.04E-08 4.75E-09 2.54E-08 1.19E-09 lbs/Mgal 1 125.10 310.78 1.00

Heater, Oil 1 Metals Arsenic D3-v0 8.34E-04 8.28E-04 8.62E-04 8.13E-04 lbs/Mgal 1 3.01 7.48 0.00

Heater, Oil 1 Metals Beryllium D3-v0 7.78E-05 7.64E-05 8.66E-05 7.04E-05 lbs/Mgal 1 10.51 26.11 0.00

Heater, Oil 1 Metals Cadmium D3-v1 8.21E-04 1.19E-03 1.23E-03 4.29E-05 lbs/Mgal 1 82.13 204.02 1.00

Heater, Oil 1 Metals Chromium (Hex) A3-v0 2.86E-04 3.06E-04 3.13E-04 2.39E-04 lbs/Mgal 1 14.20 35.28 0.00

Heater, Oil 1 Metals Chromium (Total) A3-v0 2.54E-03 2.66E-03 2.74E-03 2.22E-03 lbs/Mgal 1 11.14 27.66 1.00

Heater, Oil 1 Metals Copper D3-v0 2.62E-03 1.64E-03 4.58E-03 1.63E-03 lbs/Mgal 1 64.94 161.31 1.00

Heater, Oil 1 Metals Lead D3-v0 2.96E-04 1.79E-04 5.48E-04 1.62E-04 lbs/Mgal 1 73.61 182.86 0.62

Heater, Oil 1 Metals Manganese D3-v0 1.89E-03 1.79E-03 2.22E-03 1.67E-03 lbs/Mgal 1 15.12 37.57 0.39

Heater, Oil 1 Metals Mercury D3-v0 1.72E-05 1.29E-05 2.83E-05 1.04E-05 lbs/Mgal 1 56.41 140.14 0.00

Heater, Oil 1 Metals Nickel D3-v0 3.46E-01 3.47E-01 4.09E-01 2.81E-01 lbs/Mgal 1 18.57 46.12 1.00

Heater, Oil 1 Metals Selenium D3-v0 4.63E-03 3.96E-03 6.59E-03 3.33E-03 lbs/Mgal 1 37.32 92.71 0.00

Heater, Oil 1 Metals Zinc D3-v0 8.93E-03 8.35E-03 1.22E-02 6.27E-03 lbs/Mgal 1 33.43 83.04 1.00

Heater, Oil 1 PAH Acenaphthene C3-v1 1.75E-06 2.20E-06 2.99E-06 6.81E-08 lbs/Mgal 1 86.27 214.31 1.00

Heater, Oil 1 PAH Acenaphthylene C3-v0 8.02E-08 5.33E-08 1.37E-07 5.03E-08 lbs/Mgal 1 61.23 152.12 1.00

Heater, Oil 1 PAH Anthracene C3-v0 6.62E-08 6.81E-08 7.41E-08 5.65E-08 lbs/Mgal 1 13.48 33.49 1.00

Heater, Oil 1 PAH Benzo(a)anthracene C3-v2 3.84E-06 2.05E-07 1.12E-05 1.33E-07 lbs/Mgal 1 165.56 411.28 1.00

Heater, Oil 1 PAH Benzo(a)pyrene C3-v1 9.80E-08 8.63E-08 1.84E-07 2.40E-08 lbs/Mgal 1 82.16 204.09 1.00

147

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Oil 1 PAH Benzo(b)fluoranthene C3-v0 7.95E-07 6.37E-07 1.15E-06 5.98E-07 lbs/Mgal 1 38.74 96.24 1.00

Heater, Oil 1 PAH Benzo(e)pyrene C3-v0 5.54E-07 5.30E-07 7.73E-07 3.60E-07 lbs/Mgal 1 37.44 93.00 1.00

Heater, Oil 1 PAH Benzo(g,h,i)perylene C3-v1 2.12E-06 5.50E-07 5.57E-06 2.55E-07 lbs/Mgal 1 140.55 349.14 1.00

Heater, Oil 1 PAH Benzo(k)fluoranthene C3-v1 3.36E-08 2.08E-08 6.81E-08 1.18E-08 lbs/Mgal 1 90.02 223.61 1.00

Heater, Oil 1 PAH Chrysene C3-v1 1.12E-05 2.80E-06 2.92E-05 1.54E-06 lbs/Mgal 1 139.73 347.12 1.00

Heater, Oil 1 PAH Dibenz(a,h)anthracene C3-v2 1.76E-06 1.18E-07 5.09E-06 6.54E-08 lbs/Mgal 1 164.18 407.84 1.00

Heater, Oil 1 PAH Fluoranthene C3-v0 1.97E-06 2.28E-06 2.48E-06 1.13E-06 lbs/Mgal 1 37.09 92.13 1.00

Heater, Oil 1 PAH Fluorene C3-v1 7.48E-05 3.25E-05 1.67E-04 2.52E-05 lbs/Mgal 1 106.53 264.64 1.00

Heater, Oil 1 PAH Indeno(1,2,3-cd)pyrene C3-v1 1.81E-06 1.55E-07 5.12E-06 1.48E-07 lbs/Mgal 1 158.71 394.25 1.00

Heater, Oil 1 PAH Naphthalene C3-v0 8.46E-04 1.04E-03 1.11E-03 3.88E-04 lbs/Mgal 1 47.07 116.92 1.00

Heater, Oil 1 PAH Phenanthrene C3-v1 2.49E-05 1.18E-05 6.02E-05 2.83E-06 lbs/Mgal 1 123.75 307.42 1.00

Heater, Oil 1 PAH Pyrene C3-v0 1.32E-06 1.19E-06 2.14E-06 6.28E-07 lbs/Mgal 1 57.94 143.92 1.00

Heater, Oil 1 SVOC 2-Chloronaphthalene C3-v3 1.17E-05 5.33E-08 3.50E-05 3.57E-08 lbs/Mgal 1 172.55 428.63 1.00

Heater, Oil 1 SVOC 2-Methylnaphthalene C3-v1 3.60E-05 1.06E-05 9.29E-05 4.54E-06 lbs/Mgal 1 137.05 340.46 1.00

Heater, Oil 1 SVOC Perylene C3-v1 7.41E-08 3.57E-08 1.66E-07 2.07E-08 lbs/Mgal 1 107.75 267.67 1.00

Heater, Oil 1 VOC 1,3-Butadiene A3-v0 1.95E-02 1.96E-02 2.01E-02 1.89E-02 lbs/Mgal 1 3.14 7.80 0.00

Heater, Oil 1 VOC Acetaldehyde C3-v0 5.43E-04 5.44E-04 5.48E-04 5.38E-04 lbs/Mgal 1 0.98 2.44 0.00

Heater, Oil 1 VOC Acrolein C3-v0 5.98E-04 5.99E-04 6.03E-04 5.91E-04 lbs/Mgal 1 0.95 2.35 0.00

Heater, Oil 1 VOC Benzene A3-v0 8.47E-03 8.49E-03 8.74E-03 8.19E-03 lbs/Mgal 1 3.22 8.01 0.00

Heater, Oil 1 VOC Chloroform A3-v0 8.63E-03 8.65E-03 8.88E-03 8.35E-03 lbs/Mgal 1 3.06 7.60 0.00

Heater, Oil 1 VOC Formaldehyde C3-v0 3.80E-03 3.81E-03 3.84E-03 3.77E-03 lbs/Mgal 1 0.95 2.37 0.00

Heater, Oil 1 VOC Propylene A3-v0 1.52E-02 1.52E-02 1.56E-02 1.47E-02 lbs/Mgal 1 3.01 7.48 0.00

Heater, Oil 1 VOC Toluene A3-v0 9.99E-03 1.00E-02 1.03E-02 9.67E-03 lbs/Mgal 1 3.06 7.60 0.00

Heater, Oil 1 VOC Xylene (Total) A3-v0 1.92E-02 1.92E-02 1.98E-02 1.86E-02 lbs/Mgal 1 3.21 7.97 0.00

Heater, Ref. Gas 1 Halogens HCl A3-v0 2.36E-01 2.46E-01 2.63E-01 1.98E-01 lbs/MMcf 1 14.20 35.28 0.00

Heater, Ref. Gas 1 Metals Antimony B3-v1 4.55E-04 4.46E-04 8.51E-04 7.30E-05 lbs/MMcf 2 79.51 83.44 0.94

Heater, Ref. Gas 1 Metals Arsenic B2-v1 8.39E-04 7.30E-04 1.69E-03 3.19E-04 lbs/MMcf 3 60.15 46.23 0.68

Heater, Ref. Gas 1 Metals Barium B3-v1 3.91E-03 3.90E-03 6.64E-03 1.08E-03 lbs/MMcf 2 72.44 76.02 0.17

148

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Ref. Gas 1 Metals Beryllium B2-v1 1.55E-04 1.42E-04 2.95E-04 2.92E-05 lbs/MMcf 3 71.10 54.65 0.00

Heater, Ref. Gas 1 Metals Cadmium B2-v0 5.96E-04 3.62E-04 1.33E-03 3.09E-04 lbs/MMcf 3 67.02 51.52 0.80

Heater, Ref. Gas 1 Metals Chromium (Hex) B2-v2 1.28E-03 1.27E-03 2.66E-03 2.66E-05 lbs/MMcf 4 97.07 61.67 0.50

Heater, Ref. Gas 1 Metals Chromium (Total) B2-v0 1.16E-03 9.44E-04 2.16E-03 4.89E-04 lbs/MMcf 4 49.48 31.44 0.62

Heater, Ref. Gas 1 Metals Cobalt A3-v0 2.13E-04 2.09E-04 2.60E-04 1.71E-04 lbs/MMcf 1 21.08 52.37 1.00

Heater, Ref. Gas 1 Metals Copper B2-v1 5.71E-03 2.16E-03 1.21E-02 1.35E-03 lbs/MMcf 3 86.64 66.60 0.92

Heater, Ref. Gas 1 Metals Lead B2-v1 2.47E-03 1.50E-03 8.43E-03 3.43E-04 lbs/MMcf 3 107.79 82.85 0.95

Heater, Ref. Gas 1 Metals Manganese B3-v1 4.63E-03 2.11E-03 1.37E-02 1.24E-03 lbs/MMcf 2 106.39 111.65 1.00

Heater, Ref. Gas 1 Metals Mercury B2-v1 2.41E-04 1.97E-04 5.03E-04 3.65E-05 lbs/MMcf 3 79.16 60.85 0.10

Heater, Ref. Gas 1 Metals Nickel B2-v1 4.95E-03 1.63E-03 2.88E-02 1.15E-03 lbs/MMcf 3 181.23 139.31 0.77

Heater, Ref. Gas 1 Metals Phosphorus B3-v1 9.08E-03 7.67E-03 1.90E-02 7.03E-04 lbs/MMcf 2 102.29 107.35 0.00

Heater, Ref. Gas 1 Metals Selenium B2-v3 4.95E-03 3.65E-04 4.24E-02 1.48E-05 lbs/MMcf 3 283.98 218.29 0.95

Heater, Ref. Gas 1 Metals Silver B3-v1 9.69E-04 2.53E-04 3.61E-03 8.03E-05 lbs/MMcf 2 144.07 151.19 0.94

Heater, Ref. Gas 1 Metals Thallium B3-v2 3.27E-03 3.19E-03 6.64E-03 3.65E-05 lbs/MMcf 2 108.13 113.47 0.00

Heater, Ref. Gas 1 Metals Zinc B2-v1 1.46E-02 1.53E-02 3.18E-02 2.06E-03 lbs/MMcf 3 76.78 59.02 1.00

Heater, Ref. Gas 1 PAH Acenaphthene A1-v2 4.08E-06 1.83E-06 2.32E-05 3.62E-07 lbs/MMcf 12 118.28 39.19 0.43

Heater, Ref. Gas 1 PAH Acenaphthylene A1-v2 4.00E-06 1.51E-06 3.69E-05 3.62E-07 lbs/MMcf 12 191.56 64.39 0.34

Heater, Ref. Gas 1 PAH Anthracene A1-v3 5.83E-06 2.22E-06 5.91E-05 4.73E-08 lbs/MMcf 12 207.19 68.64 0.34

Heater, Ref. Gas 1 PAH Benzo(a)anthracene A1-v3 2.02E-05 1.44E-06 3.97E-04 3.51E-07 lbs/MMcf 17 353.09 97.87 0.98

Heater, Ref. Gas 1 PAH Benzo(a)pyrene A1-v3 5.19E-05 1.30E-06 1.32E-03 3.51E-07 lbs/MMcf 17 478.22 132.55 0.97

Heater, Ref. Gas 1 PAH Benzo(b)fluoranthene A1-v3 2.51E-05 1.55E-06 6.04E-04 3.51E-07 lbs/MMcf 17 424.05 117.54 0.98

Heater, Ref. Gas 1 PAH Benzo(e)pyrene A1-v1 1.25E-06 1.13E-06 6.05E-06 3.51E-07 lbs/MMcf 7 97.17 44.23 0.23

Heater, Ref. Gas 1 PAH Benzo(g,h,i)perylene A1-v1 1.11E-06 1.14E-06 2.46E-06 3.51E-07 lbs/MMcf 12 40.96 13.57 0.05

Heater, Ref. Gas 1 PAH Benzo(k)fluoranthene A1-v3 1.47E-05 1.31E-06 3.40E-04 3.51E-07 lbs/MMcf 17 417.90 115.83 0.93

Heater, Ref. Gas 1 PAH Chrysene A1-v1 1.88E-06 1.29E-06 1.49E-05 3.51E-07 lbs/MMcf 12 134.58 44.59 0.70

Heater, Ref. Gas 1 PAH Dibenz(a,h)anthracene A1-v2 6.00E-06 1.29E-06 1.31E-04 3.58E-07 lbs/MMcf 17 339.62 94.14 0.00

Heater, Ref. Gas 1 PAH Fluoranthene A1-v2 8.71E-06 3.66E-06 5.69E-05 8.83E-07 lbs/MMcf 12 134.19 44.46 0.63

Heater, Ref. Gas 1 PAH Fluorene A1-v1 1.66E-05 9.13E-06 1.08E-04 2.81E-06 lbs/MMcf 12 130.79 43.33 0.34

149

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Ref. Gas 1 PAH Indeno(1,2,3-cd)pyrene A1-v3 6.06E-05 1.31E-06 1.55E-03 3.51E-07 lbs/MMcf 17 475.63 131.83 0.98

Heater, Ref. Gas 1 PAH Naphthalene A1-v2 4.74E-04 1.84E-04 5.17E-03 5.05E-05 lbs/MMcf 12 191.43 63.42 0.54

Heater, Ref. Gas 1 PAH Phenanthrene A1-v2 5.20E-05 2.17E-05 3.94E-04 7.69E-06 lbs/MMcf 12 166.44 55.14 0.36

Heater, Ref. Gas 1 PAH Pyrene A1-v1 6.29E-06 2.83E-06 3.45E-05 1.55E-06 lbs/MMcf 12 121.14 40.13 0.47

Heater, Ref. Gas 1 SVOC 2-Methylnaphthalene A1-v2 7.80E-05 3.02E-05 4.92E-04 7.79E-06 lbs/MMcf 7 161.60 73.56 0.16

Heater, Ref. Gas 1 SVOC Ethylbenzene A1-v2 1.77E-02 3.99E-03 9.50E-02 5.94E-04 lbs/MMcf 11 147.19 50.22 0.35

Heater, Ref. Gas 1 SVOC Perylene A1-v1 1.02E-06 1.13E-06 2.46E-06 3.51E-07 lbs/MMcf 7 51.10 23.26 0.00

Heater, Ref. Gas 1 SVOC Phenol C1-v2 4.63E-03 1.69E-03 1.93E-02 2.93E-04 lbs/MMcf 7 116.58 53.06 0.92

Heater, Ref. Gas 1 VOC Acetaldehyde B1-v3 5.18E-02 3.14E-02 1.77E-01 1.10E-04 lbs/MMcf 15 97.95 28.62 0.48

Heater, Ref. Gas 1 VOC Ammonia B3-v0 1.42E-01 1.06E-01 2.33E-01 8.77E-02 lbs/MMcf 1 55.68 138.32 1.00

Heater, Ref. Gas 1 VOC Benzene B1-v3 4.76E-02 1.06E-02 2.76E-01 2.18E-04 lbs/MMcf 18 144.16 38.45 0.07

Heater, Ref. Gas 1 VOC Carbonyl Sulfide A3-v0 9.47E-01 9.56E-01 9.74E-01 9.11E-01 lbs/MMcf 1 3.39 8.43 0.00

Heater, Ref. Gas 1 VOC Cyanide E3-v0 6.16E-03 6.08E-03 7.09E-03 5.31E-03 lbs/MMcf 1 14.43 35.83 0.00

Heater, Ref. Gas 1 VOC Formaldehyde B1-v3 9.93E-02 3.07E-02 1.76E+00 7.92E-04 lbs/MMcf 15 272.08 80.39 0.91

Heater, Ref. Gas 1 VOC Hydrogen Sulfide A1-v2 4.45E-01 3.78E-01 1.20E+00 1.82E-02 lbs/MMcf 8 83.40 35.22 0.00

Heater, Ref. Gas 1 VOC Propylene A2-v0 2.05E-03 2.14E-03 2.91E-03 1.00E-03 lbs/MMcf 3 25.36 19.49 0.05

Heater, Ref. Gas 1 VOC Toluene B1-v3 8.39E-02 3.79E-02 1.21E+00 1.35E-03 lbs/MMcf 17 213.61 58.62 0.62

Heater, Ref. Gas 1 VOC Xylene (m,p) A1-v1 3.49E-03 2.47E-03 1.18E-02 5.94E-04 lbs/MMcf 6 95.10 47.29 0.83

Heater, Ref. Gas 1 VOC Xylene (o) A1-v2 8.80E-03 2.16E-03 1.01E-01 5.94E-04 lbs/MMcf 5 289.29 160.20 0.83

Heater, Ref. Gas 1 VOC Xylene (Total) A1-v1 4.16E-02 5.06E-02 9.90E-02 4.27E-03 lbs/MMcf 5 79.17 43.84 0.43

Heater, Ref. Gas 2 Halogens HCl A3-v0 8.13E-01 8.64E-01 1.15E+00 4.27E-01 lbs/MMcf 1 44.77 111.22 0.83

Heater, Ref. Gas 2 Metals Arsenic A3-v0 5.12E-04 5.10E-04 5.50E-04 4.77E-04 lbs/MMcf 1 7.16 17.80 0.00

Heater, Ref. Gas 2 Metals Beryllium A3-v0 2.01E-04 2.00E-04 2.17E-04 1.87E-04 lbs/MMcf 1 7.27 18.05 0.00

Heater, Ref. Gas 2 Metals Cadmium A3-v0 5.12E-04 5.10E-04 5.50E-04 4.77E-04 lbs/MMcf 1 7.16 17.80 0.00

Heater, Ref. Gas 2 Metals Chromium (Hex) C3-v1 4.71E-04 2.00E-04 1.04E-03 1.76E-04 lbs/MMcf 1 104.14 258.70 0.00

Heater, Ref. Gas 2 Metals Chromium (Total) C3-v0 1.92E-03 1.87E-03 2.17E-03 1.72E-03 lbs/MMcf 1 11.87 29.50 0.00

Heater, Ref. Gas 2 Metals Copper A3-v0 2.01E-03 2.00E-03 2.17E-03 1.87E-03 lbs/MMcf 1 7.27 18.05 0.00

Heater, Ref. Gas 2 Metals Lead A3-v0 9.02E-04 9.19E-04 9.28E-04 8.60E-04 lbs/MMcf 1 4.07 10.10 1.00

150

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Ref. Gas 2 Metals Manganese A3-v0 1.98E-03 2.33E-03 2.48E-03 1.13E-03 lbs/MMcf 1 37.33 92.73 1.00

Heater, Ref. Gas 2 Metals Mercury A3-v0 9.01E-04 8.73E-04 1.01E-03 8.17E-04 lbs/MMcf 1 11.31 28.10 0.00

Heater, Ref. Gas 2 Metals Nickel A3-v0 5.87E-03 5.29E-03 7.39E-03 4.95E-03 lbs/MMcf 1 22.47 55.83 1.00

Heater, Ref. Gas 2 Metals Selenium A3-v0 1.99E-03 2.05E-03 2.19E-03 1.72E-03 lbs/MMcf 1 12.30 30.56 1.00

Heater, Ref. Gas 2 Metals Zinc A3-v0 8.61E-03 8.86E-03 9.46E-03 7.52E-03 lbs/MMcf 1 11.53 28.64 1.00

Heater, Ref. Gas 2 PAH Acenaphthene A3-v1 1.95E-04 7.31E-05 4.60E-04 5.26E-05 lbs/MMcf 1 117.54 292.00 1.00

Heater, Ref. Gas 2 PAH Acenaphthylene A3-v0 8.14E-05 7.60E-05 9.83E-05 6.99E-05 lbs/MMcf 1 18.36 45.62 1.00

Heater, Ref. Gas 2 PAH Anthracene A3-v0 3.22E-04 3.81E-04 4.29E-04 1.55E-04 lbs/MMcf 1 45.52 113.07 1.00

Heater, Ref. Gas 2 PAH Benzo(a)anthracene A3-v0 1.31E-04 1.14E-04 1.87E-04 9.19E-05 lbs/MMcf 1 38.12 94.69 1.00

Heater, Ref. Gas 2 PAH Benzo(a)pyrene A3-v1 4.68E-05 4.68E-05 8.58E-05 7.93E-06 lbs/MMcf 1 83.13 206.52 1.00

Heater, Ref. Gas 2 PAH Benzo(b)fluoranthene A3-v1 3.22E-04 3.99E-04 5.26E-04 4.13E-05 lbs/MMcf 1 78.02 193.82 1.00

Heater, Ref. Gas 2 PAH Benzo(e)pyrene A3-v1 1.80E-04 2.37E-04 2.82E-04 2.07E-05 lbs/MMcf 1 77.68 192.97 1.00

Heater, Ref. Gas 2 PAH Benzo(g,h,i)perylene A3-v0 2.64E-05 2.64E-05 3.51E-05 1.77E-05 lbs/MMcf 1 32.85 81.60 1.00

Heater, Ref. Gas 2 PAH Benzo(k)fluoranthene A3-v1 1.01E-04 1.16E-04 1.72E-04 1.58E-05 lbs/MMcf 1 78.05 193.90 1.00

Heater, Ref. Gas 2 PAH Chrysene A3-v0 4.76E-04 5.26E-04 5.52E-04 3.49E-04 lbs/MMcf 1 23.17 57.56 1.00

Heater, Ref. Gas 2 PAH Dibenz(a,h)anthracene A3-v1 1.63E-05 1.81E-05 2.92E-05 1.58E-06 lbs/MMcf 1 85.29 211.88 0.97

Heater, Ref. Gas 2 PAH Fluoranthene A3-v0 7.73E-04 6.67E-04 1.01E-03 6.43E-04 lbs/MMcf 1 26.55 65.94 1.00

Heater, Ref. Gas 2 PAH Fluorene A3-v1 1.99E-03 5.71E-04 5.21E-03 1.93E-04 lbs/MMcf 1 140.33 348.59 1.00

Heater, Ref. Gas 2 PAH Indeno(1,2,3-cd)pyrene A3-v1 2.69E-05 2.67E-05 5.26E-05 1.58E-06 lbs/MMcf 1 94.63 235.08 0.98

Heater, Ref. Gas 2 PAH Naphthalene A3-v0 1.25E-02 1.24E-02 1.87E-02 6.43E-03 lbs/MMcf 1 49.20 122.21 1.00

Heater, Ref. Gas 2 PAH Phenanthrene A3-v0 1.52E-03 1.36E-03 2.11E-03 1.08E-03 lbs/MMcf 1 35.00 86.94 1.00

Heater, Ref. Gas 2 PAH Pyrene A3-v1 9.37E-04 9.03E-04 1.63E-03 2.79E-04 lbs/MMcf 1 72.08 179.05 1.00

Heater, Ref. Gas 2 SVOC 2-Methylnaphthalene A3-v0 2.29E-03 2.10E-03 3.68E-03 1.08E-03 lbs/MMcf 1 57.11 141.86 1.00

Heater, Ref. Gas 2 SVOC Ethylbenzene A3-v0 9.46E-02 9.46E-02 9.46E-02 9.46E-02 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 SVOC Perylene A3-v0 1.62E-05 1.30E-05 2.84E-05 7.36E-06 lbs/MMcf 1 66.90 166.19 0.73

Heater, Ref. Gas 2 SVOC Phenol B3-v1 2.23E-02 1.25E-02 6.99E-02 5.84E-03 lbs/MMcf 2 110.10 115.55 0.91

Heater, Ref. Gas 2 VOC 1,1,1-Trichloroethane A3-v0 5.80E-02 5.80E-02 5.80E-02 5.80E-02 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC 1,2-Dichloroethane A3-v0 1.85E+00 1.85E+00 1.85E+00 1.85E+00 lbs/MMcf 1 0.00 0.00 0.00

151

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Heater, Ref. Gas 2 VOC Acetaldehyde A3-v1 5.05E-02 5.06E-02 9.78E-02 4.77E-03 lbs/MMcf 2 95.50 100.22 0.39

Heater, Ref. Gas 2 VOC Ammonia B3-v0 2.76E+00 2.99E+00 3.33E+00 1.96E+00 lbs/MMcf 1 25.87 64.27 1.00

Heater, Ref. Gas 2 VOC Benzene B3-v0 2.14E-01 1.61E-01 4.09E-01 1.48E-01 lbs/MMcf 2 47.74 50.10 0.63

Heater, Ref. Gas 2 VOC Carbon Tetrachloride A3-v0 1.48E-02 1.68E-02 1.68E-02 1.08E-02 lbs/MMcf 1 23.58 58.57 0.00

Heater, Ref. Gas 2 VOC Carbonyl Sulfide A3-v0 2.16E+00 2.25E+00 2.43E+00 1.81E+00 lbs/MMcf 1 14.76 36.66 0.00

Heater, Ref. Gas 2 VOC Chloroform A3-v0 5.19E-02 5.19E-02 5.19E-02 5.19E-02 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC Cyanide E3-v0 1.24E-02 1.37E-02 1.42E-02 9.28E-03 lbs/MMcf 1 21.72 53.96 0.00

Heater, Ref. Gas 2 VOC Formaldehyde A3-v1 1.88E+00 1.65E+00 3.80E+00 1.90E-01 lbs/MMcf 1 96.70 240.22 0.97

Heater, Ref. Gas 2 VOC Hydrogen Sulfide A3-v1 9.33E-01 7.98E-01 1.90E+00 1.61E-01 lbs/MMcf 2 91.13 95.63 0.00

Heater, Ref. Gas 2 VOC Methylene Chloride A3-v0 2.18E+00 2.18E+00 2.18E+00 2.18E+00 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC Tetrachloroethene A3-v0 1.18E-02 1.18E-02 1.18E-02 1.18E-02 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC Toluene C3-v0 1.33E-01 1.28E-01 1.93E-01 8.17E-02 lbs/MMcf 2 42.48 44.58 0.00

Heater, Ref. Gas 2 VOC Trichloroethene A3-v0 5.13E-02 5.13E-02 5.13E-02 5.13E-02 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC Trichlorofluoromethane A3-v0 8.90E-03 8.90E-03 8.90E-03 8.90E-03 lbs/MMcf 1 0.00 0.00 0.00

Heater, Ref. Gas 2 VOC Xylene (Total) A3-v0 1.42E-01 9.46E-02 2.36E-01 9.46E-02 lbs/MMcf 1 57.49 142.81 0.00

ICE, Diesel 1 PAH Acenaphthene B3-v0 4.71E-04 3.62E-04 8.67E-04 2.72E-04 lbs/Mgal 2 52.37 54.96 1.00

ICE, Diesel 1 PAH Acenaphthylene B3-v0 1.09E-03 1.17E-03 1.32E-03 7.56E-04 lbs/Mgal 2 22.61 23.73 1.00

ICE, Diesel 1 PAH Anthracene B3-v0 1.79E-04 1.54E-04 2.89E-04 8.61E-05 lbs/Mgal 2 43.47 45.61 1.00

ICE, Diesel 1 PAH Benzo(a)anthracene B3-v1 5.03E-05 4.89E-05 9.69E-05 8.44E-06 lbs/Mgal 2 81.10 85.11 1.00

ICE, Diesel 1 PAH Benzo(a)pyrene B3-v2 1.81E-05 1.05E-05 4.77E-05 8.24E-07 lbs/Mgal 2 115.27 120.97 0.44

ICE, Diesel 1 PAH Benzo(b)fluoranthene B3-v1 7.96E-05 6.63E-05 1.92E-04 4.72E-06 lbs/Mgal 2 105.09 110.28 0.30

ICE, Diesel 1 PAH Benzo(g,h,i)perylene B3-v2 3.89E-05 3.51E-05 8.30E-05 8.24E-07 lbs/Mgal 2 107.69 113.01 0.99

ICE, Diesel 1 PAH Benzo(k)fluoranthene B3-v2 1.56E-05 5.09E-06 6.92E-05 8.24E-07 lbs/Mgal 2 171.85 180.35 0.74

ICE, Diesel 1 PAH Chrysene B3-v2 1.06E-04 9.32E-05 2.28E-04 1.06E-06 lbs/Mgal 2 109.03 114.42 1.00

ICE, Diesel 1 PAH Dibenz(a,h)anthracene B3-v2 2.43E-05 2.35E-05 5.07E-05 8.24E-07 lbs/Mgal 2 105.82 111.05 0.00

ICE, Diesel 1 PAH Fluoranthene B3-v0 3.73E-04 3.79E-04 5.84E-04 1.69E-04 lbs/Mgal 2 54.05 56.72 1.00

ICE, Diesel 1 PAH Fluorene B3-v0 1.28E-03 1.31E-03 1.81E-03 7.16E-04 lbs/Mgal 2 42.47 44.57 1.00

ICE, Diesel 1 PAH Indeno(1,2,3-cd)pyrene B3-v2 2.89E-05 2.35E-05 6.61E-05 8.24E-07 lbs/Mgal 2 108.49 113.86 0.34

152

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Diesel 1 PAH Naphthalene B3-v0 1.63E-02 1.72E-02 1.85E-02 1.24E-02 lbs/Mgal 2 14.91 15.64 1.00

ICE, Diesel 1 PAH Phenanthrene B3-v0 3.96E-03 4.17E-03 5.76E-03 1.89E-03 lbs/Mgal 2 46.88 49.19 1.00

ICE, Diesel 1 PAH Pyrene B3-v1 2.90E-04 2.89E-04 5.60E-04 2.95E-05 lbs/Mgal 2 84.76 88.94 1.00

ICE, Diesel 1 VOC Acetaldehyde A3-v0 3.47E-03 2.25E-03 6.46E-03 1.69E-03 lbs/Mgal 1 75.34 187.15 1.00

ICE, Diesel 1 VOC Acrolein A3-v0 1.07E-03 7.15E-04 1.79E-03 7.15E-04 lbs/Mgal 1 57.74 143.42 0.56

ICE, Diesel 1 VOC Benzene A3-v0 1.01E-01 9.93E-02 1.04E-01 9.93E-02 lbs/Mgal 1 2.71 6.72 1.00

ICE, Diesel 1 VOC Formaldehyde A3-v1 1.32E-02 1.29E-02 2.63E-02 1.74E-03 lbs/Mgal 2 70.70 74.20 1.00

ICE, Diesel 1 VOC Propylene A3-v0 3.85E-01 4.03E-01 4.03E-01 3.49E-01 lbs/Mgal 1 8.06 20.01 1.00

ICE, Diesel 1 VOC Toluene A3-v0 3.74E-02 3.70E-02 3.87E-02 3.64E-02 lbs/Mgal 1 3.27 8.12 1.00

ICE, Diesel 1 VOC Xylene (Total) A3-v0 2.68E-02 2.70E-02 2.77E-02 2.57E-02 lbs/Mgal 1 3.85 9.57 1.00

ICE, Diesel 2 PAH Acenaphthene B3-v1 8.71E-04 3.30E-04 3.59E-03 2.80E-04 lbs/Mgal 2 153.18 160.76 0.84

ICE, Diesel 2 PAH Acenaphthylene B3-v1 9.45E-04 8.61E-04 2.05E-03 2.80E-04 lbs/Mgal 2 77.77 81.61 0.90

ICE, Diesel 2 PAH Anthracene B3-v0 2.67E-04 2.80E-04 2.86E-04 2.36E-04 lbs/Mgal 2 8.73 9.16 0.47

ICE, Diesel 2 PAH Benzo(a)anthracene B3-v2 1.42E-04 1.42E-04 2.80E-04 2.64E-06 lbs/Mgal 2 106.95 112.24 0.01

ICE, Diesel 2 PAH Benzo(a)pyrene B3-v3 1.40E-04 1.40E-04 2.80E-04 5.27E-07 lbs/Mgal 2 109.13 114.52 0.00

ICE, Diesel 2 PAH Benzo(b)fluoranthene B3-v1 1.44E-04 1.44E-04 2.80E-04 7.39E-06 lbs/Mgal 2 103.58 108.70 0.03

ICE, Diesel 2 PAH Benzo(g,h,i)perylene B3-v2 1.42E-04 1.42E-04 2.80E-04 3.84E-06 lbs/Mgal 2 106.23 111.48 0.02

ICE, Diesel 2 PAH Benzo(k)fluoranthene B3-v2 1.41E-04 1.41E-04 2.80E-04 8.45E-07 lbs/Mgal 2 108.58 113.95 0.00

ICE, Diesel 2 PAH Chrysene B3-v1 1.53E-04 1.54E-04 2.80E-04 2.27E-05 lbs/Mgal 2 90.69 95.17 0.09

ICE, Diesel 2 PAH Dibenz(a,h)anthracene B3-v3 1.40E-04 1.40E-04 2.80E-04 5.27E-07 lbs/Mgal 2 109.13 114.52 0.00

ICE, Diesel 2 PAH Fluoranthene B3-v0 2.84E-04 2.80E-04 3.30E-04 2.57E-04 lbs/Mgal 2 8.42 8.84 0.51

ICE, Diesel 2 PAH Fluorene B3-v0 6.49E-04 5.90E-04 1.24E-03 2.80E-04 lbs/Mgal 2 65.14 68.36 0.78

ICE, Diesel 2 PAH Indeno(1,2,3-cd)pyrene B3-v2 1.40E-04 1.41E-04 2.80E-04 7.55E-07 lbs/Mgal 2 108.84 114.22 0.00

ICE, Diesel 2 PAH Naphthalene B3-v1 1.56E-02 1.48E-02 3.19E-02 2.28E-03 lbs/Mgal 2 89.99 94.44 1.00

ICE, Diesel 2 PAH Phenanthrene B3-v2 3.11E-03 2.89E-03 6.48E-03 8.00E-05 lbs/Mgal 2 98.67 103.55 1.00

ICE, Diesel 2 PAH Pyrene B3-v0 2.37E-04 2.60E-04 2.80E-04 1.57E-04 lbs/Mgal 2 22.88 24.01 0.41

ICE, Diesel 2 SVOC Ethylbenzene C3-v0 6.76E-03 6.64E-03 8.03E-03 5.60E-03 lbs/Mgal 1 18.09 44.94 1.00

ICE, Diesel 2 VOC Benzene C3-v0 2.85E-01 2.79E-01 3.30E-01 2.44E-01 lbs/Mgal 1 15.21 37.80 1.00

153

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Diesel 2 VOC Formaldehyde B3-v1 8.79E-02 7.33E-02 1.76E-01 1.46E-02 lbs/Mgal 2 77.77 81.61 1.00

ICE, Diesel 2 VOC Hexane C3-v0 1.39E-03 1.45E-03 1.47E-03 1.24E-03 lbs/Mgal 1 9.06 22.51 0.00

ICE, Diesel 2 VOC Propylene C3-v0 2.97E-01 2.90E-01 3.45E-01 2.55E-01 lbs/Mgal 1 15.30 38.00 1.00

ICE, Diesel 2 VOC Toluene C3-v0 8.50E-02 8.05E-02 1.11E-01 6.37E-02 lbs/Mgal 1 28.04 69.66 1.00

ICE, Diesel 2 VOC Xylene (Total) C3-v0 1.51E-02 1.74E-02 2.06E-02 7.32E-03 lbs/Mgal 1 45.85 113.90 1.00

ICE, Diesel 3 PAH Acenaphthene C3-v3 3.35E-03 3.35E-03 6.72E-03 2.76E-06 lbs/Mgal 2 109.45 114.86 0.00

ICE, Diesel 3 PAH Acenaphthylene C3-v3 3.35E-03 3.35E-03 6.72E-03 2.76E-06 lbs/Mgal 2 109.45 114.86 0.00

ICE, Diesel 3 PAH Anthracene C3-v1 4.02E-03 4.12E-03 6.72E-03 1.12E-03 lbs/Mgal 2 73.24 76.86 0.17

ICE, Diesel 3 PAH Benzo(a)anthracene C3-v1 3.90E-03 3.91E-03 6.72E-03 1.10E-03 lbs/Mgal 2 78.42 82.30 0.14

ICE, Diesel 3 PAH Benzo(a)pyrene C3-v3 3.35E-03 3.35E-03 6.72E-03 2.76E-06 lbs/Mgal 2 109.45 114.86 0.00

ICE, Diesel 3 PAH Benzo(b)fluoranthene C3-v0 6.70E-03 6.69E-03 6.72E-03 6.69E-03 lbs/Mgal 1 0.27 0.68 0.00

ICE, Diesel 3 PAH Benzo(b+k)fluoranthene C3-v0 2.85E-06 2.81E-06 2.98E-06 2.76E-06 lbs/Mgal 1 4.05 10.05 0.00

ICE, Diesel 3 PAH Benzo(g,h,i)perylene C3-v1 3.52E-03 3.53E-03 6.72E-03 2.59E-04 lbs/Mgal 2 99.01 103.90 0.05

ICE, Diesel 3 PAH Benzo(k)fluoranthene C3-v0 6.70E-03 6.69E-03 6.72E-03 6.69E-03 lbs/Mgal 1 0.27 0.68 0.00

ICE, Diesel 3 PAH Chrysene C3-v1 3.58E-03 3.60E-03 6.72E-03 4.09E-04 lbs/Mgal 2 95.47 100.19 0.06

ICE, Diesel 3 PAH Dibenz(a,h)anthracene C3-v1 3.49E-03 3.52E-03 6.72E-03 2.25E-04 lbs/Mgal 2 100.62 105.60 0.04

ICE, Diesel 3 PAH Fluoranthene C3-v1 4.00E-03 4.06E-03 6.72E-03 1.11E-03 lbs/Mgal 2 74.09 77.75 0.16

ICE, Diesel 3 PAH Fluorene C3-v1 2.11E-02 1.27E-02 4.34E-02 6.72E-03 lbs/Mgal 2 76.44 80.22 0.95

ICE, Diesel 3 PAH Indeno(1,2,3-cd)pyrene C3-v1 3.46E-03 3.47E-03 6.72E-03 2.02E-04 lbs/Mgal 2 102.44 107.50 0.03

ICE, Diesel 3 PAH Naphthalene C3-v1 5.64E-02 5.17E-02 1.03E-01 1.66E-02 lbs/Mgal 2 73.72 77.37 1.00

ICE, Diesel 3 PAH Phenanthrene C3-v1 3.90E-02 3.13E-02 8.68E-02 1.33E-02 lbs/Mgal 2 76.66 80.45 1.00

ICE, Diesel 3 PAH Pyrene C3-v0 8.42E-03 7.18E-03 1.47E-02 6.69E-03 lbs/Mgal 2 36.92 38.75 0.73

ICE, Diesel 3 VOC Benzene C3-v0 3.25E-02 3.29E-02 3.64E-02 2.81E-02 lbs/Mgal 1 12.86 31.93 1.00

ICE, Diesel 3 VOC Formaldehyde B3-v2 1.11E+00 1.08E+00 2.23E+00 3.23E-02 lbs/Mgal 2 102.99 108.08 1.00

ICE, Diesel 4 PAH Acenaphthene B2-v4 3.14E-03 2.64E-04 2.04E-02 1.41E-06 lbs/Mgal 3 210.34 161.68 1.00

ICE, Diesel 4 PAH Acenaphthylene B2-v4 4.07E-03 1.72E-03 1.47E-02 1.41E-06 lbs/Mgal 3 135.61 104.24 1.00

ICE, Diesel 4 PAH Anthracene B2-v2 8.48E-04 3.03E-04 2.56E-03 3.11E-05 lbs/Mgal 3 113.05 86.90 1.00

ICE, Diesel 4 PAH Benzo(a)anthracene B2-v1 2.34E-04 2.45E-04 6.75E-04 1.55E-05 lbs/Mgal 3 82.91 63.73 1.00

154

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Diesel 4 PAH Benzo(a)pyrene B2-v1 1.81E-05 2.10E-06 5.83E-05 1.41E-06 lbs/Mgal 3 139.83 107.48 0.03

ICE, Diesel 4 PAH Benzo(b)fluoranthene B3-v1 8.66E-05 8.86E-05 1.63E-04 1.17E-05 lbs/Mgal 2 78.09 81.95 0.93

ICE, Diesel 4 PAH Benzo(b+k)fluoranthene C3-v0 1.44E-06 1.45E-06 1.46E-06 1.41E-06 lbs/Mgal 1 1.90 4.71 0.00

ICE, Diesel 4 PAH Benzo(g,h,i)perylene B2-v1 4.94E-05 4.29E-05 1.55E-04 7.14E-06 lbs/Mgal 3 95.94 73.75 0.48

ICE, Diesel 4 PAH Benzo(k)fluoranthene B3-v0 3.28E-05 2.83E-05 6.22E-05 1.60E-05 lbs/Mgal 2 53.02 55.65 0.68

ICE, Diesel 4 PAH Chrysene B2-v0 5.30E-05 5.41E-05 7.33E-05 2.72E-05 lbs/Mgal 3 29.72 22.84 1.00

ICE, Diesel 4 PAH Dibenz(a,h)anthracene B2-v2 5.50E-05 5.05E-05 1.44E-04 1.75E-06 lbs/Mgal 3 92.94 71.44 0.36

ICE, Diesel 4 PAH Fluoranthene B2-v1 1.33E-03 1.57E-03 2.70E-03 6.99E-05 lbs/Mgal 3 65.01 49.97 1.00

ICE, Diesel 4 PAH Fluorene B2-v1 5.52E-03 6.75E-03 1.05E-02 2.10E-04 lbs/Mgal 3 68.98 53.02 1.00

ICE, Diesel 4 PAH Indeno(1,2,3-cd)pyrene B2-v1 4.63E-05 3.25E-05 1.32E-04 7.00E-06 lbs/Mgal 3 109.00 83.79 0.35

ICE, Diesel 4 PAH Naphthalene B2-v1 5.44E-02 1.25E-02 1.58E-01 5.92E-03 lbs/Mgal 3 119.29 91.69 1.00

ICE, Diesel 4 PAH Phenanthrene B2-v2 9.47E-03 5.82E-03 2.31E-02 3.11E-04 lbs/Mgal 3 90.25 69.37 1.00

ICE, Diesel 4 PAH Pyrene B2-v1 9.02E-04 1.01E-03 1.44E-03 1.17E-04 lbs/Mgal 3 49.81 38.29 1.00

ICE, Diesel 4 SVOC Benzaldehyde A3-v0 1.26E-02 1.24E-02 1.35E-02 1.20E-02 lbs/Mgal 1 6.29 15.64 0.68

ICE, Diesel 4 VOC 1,3-Butadiene C3-v0 5.41E-03 5.41E-03 5.41E-03 5.41E-03 lbs/Mgal 1 0.00 0.00 0.00

ICE, Diesel 4 VOC Acetaldehyde A3-v0 1.07E-01 1.07E-01 1.52E-01 5.82E-02 lbs/Mgal 2 43.11 45.24 1.00

ICE, Diesel 4 VOC Acrolein A3-v0 1.30E-02 8.43E-03 3.16E-02 6.62E-03 lbs/Mgal 2 74.07 77.73 0.82

ICE, Diesel 4 VOC Benzene B3-v0 1.22E-01 1.13E-01 1.91E-01 6.57E-02 lbs/Mgal 2 48.35 50.74 1.00

ICE, Diesel 4 VOC Formaldehyde A2-v1 1.16E-01 9.03E-02 3.35E-01 9.66E-03 lbs/Mgal 3 90.24 69.36 1.00

ICE, Diesel 4 VOC Propylene B3-v0 3.58E-01 3.38E-01 5.83E-01 1.45E-01 lbs/Mgal 2 56.61 59.41 1.00

ICE, Diesel 4 VOC Toluene B3-v0 5.50E-02 5.49E-02 7.56E-02 3.44E-02 lbs/Mgal 2 38.06 39.94 1.00

ICE, Diesel 4 VOC Xylene (m,p) C3-v0 2.16E-02 2.09E-02 2.40E-02 1.98E-02 lbs/Mgal 1 10.07 25.02 1.00

ICE, Diesel 4 VOC Xylene (o) C3-v0 2.09E-02 2.09E-02 2.09E-02 2.09E-02 lbs/Mgal 1 0.00 0.00 0.00

ICE, Diesel 4 VOC Xylene (Total) A3-v0 3.59E-02 4.44E-02 4.44E-02 1.88E-02 lbs/Mgal 1 41.24 102.44 1.00

ICE, Diesel 5 VOC Ammonia B3-v0 4.85E+00 4.85E+00 5.39E+00 4.30E+00 lbs/Mgal 1 15.98 143.54 1.00

ICE, Field Gas 1 VOC Benzene A2-v0 1.72E+00 2.07E+00 2.24E+00 9.25E-01 lbs/MMcf 3 35.58 37.33 1.00

ICE, Field Gas 1 VOC Formaldehyde A2-v1 4.15E+01 3.14E+01 9.78E+01 4.62E+00 lbs/MMcf 3 76.73 58.98 1.00

ICE, Field Gas 1 VOC Propylene A2-v0 1.59E+01 1.84E+01 2.02E+01 9.48E+00 lbs/MMcf 3 30.49 32.00 1.00

155

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Field Gas 1 VOC Toluene A2-v0 7.68E-01 9.38E-01 1.17E+00 2.69E-01 lbs/MMcf 3 51.12 53.65 1.00

ICE, Field Gas 1 VOC Xylene (m,p) A2-v1 3.02E-01 1.90E-01 9.03E-01 7.74E-02 lbs/MMcf 3 99.71 104.64 1.00

ICE, Field Gas 1 VOC Xylene (o) A2-v0 8.97E-02 9.57E-02 1.22E-01 6.13E-02 lbs/MMcf 3 25.60 26.87 1.00

ICE, Field Gas 2 VOC Benzene A3-v0 1.31E+01 1.31E+01 1.36E+01 1.25E+01 lbs/MMcf 1 5.89 52.94 1.00

ICE, Field Gas 2 VOC Formaldehyde A3-v0 7.60E+01 7.25E+01 8.53E+01 7.01E+01 lbs/MMcf 1 10.80 26.83 1.00

ICE, Field Gas 2 VOC Propylene A3-v0 4.02E+01 4.02E+01 4.02E+01 4.02E+01 lbs/MMcf 1 0.00 0.00 1.00

ICE, Field Gas 2 VOC Toluene A3-v0 4.83E+00 4.83E+00 5.74E+00 3.92E+00 lbs/MMcf 1 26.70 239.91 1.00

ICE, Field Gas 2 VOC Xylene (m,p) A3-v0 1.13E+00 1.13E+00 1.25E+00 1.01E+00 lbs/MMcf 1 14.63 131.44 1.00

ICE, Field Gas 2 VOC Xylene (o) A3-v0 5.64E-01 5.64E-01 5.91E-01 5.37E-01 lbs/MMcf 1 6.83 61.34 1.00

ICE, Field Gas 4 VOC Benzene A3-v0 1.10E+01 1.10E+01 1.11E+01 1.09E+01 lbs/MMcf 1 1.15 10.33 1.00

ICE, Field Gas 4 VOC Formaldehyde A3-v0 5.05E+00 4.65E+00 5.98E+00 4.53E+00 lbs/MMcf 1 15.91 39.52 1.00

ICE, Field Gas 4 VOC Propylene A3-v0 3.04E+00 3.04E+00 3.04E+00 3.04E+00 lbs/MMcf 1 0.00 0.00 0.00

ICE, Field Gas 4 VOC Toluene A3-v0 3.44E+00 3.44E+00 3.55E+00 3.33E+00 lbs/MMcf 1 4.56 40.99 1.00

ICE, Field Gas 4 VOC Xylene (m,p) A3-v0 5.37E-01 5.37E-01 5.62E-01 5.11E-01 lbs/MMcf 1 6.73 60.51 1.00

ICE, Field Gas 4 VOC Xylene (o) A3-v0 2.68E-01 2.68E-01 2.81E-01 2.56E-01 lbs/MMcf 1 6.73 60.51 1.00

ICE, Field Gas 5 PAH Acenaphthene A3-v0 7.41E-04 7.41E-04 1.08E-03 4.00E-04 lbs/MMcf 1 65.08 584.68 0.00

ICE, Field Gas 5 PAH Acenaphthylene A3-v0 1.11E-02 1.11E-02 1.57E-02 6.44E-03 lbs/MMcf 1 59.06 530.66 1.00

ICE, Field Gas 5 PAH Anthracene A3-v0 4.50E-03 4.50E-03 6.67E-03 2.34E-03 lbs/MMcf 1 67.84 609.52 1.00

ICE, Field Gas 5 PAH Benzo(a)anthracene A3-v0 8.97E-04 8.97E-04 9.11E-04 8.83E-04 lbs/MMcf 1 2.17 19.50 1.00

ICE, Field Gas 5 PAH Benzo(a)pyrene A3-v1 8.75E-04 8.75E-04 1.53E-03 2.16E-04 lbs/MMcf 1 106.44 956.35 0.00

ICE, Field Gas 5 PAH Benzo(b)fluoranthene A3-v0 1.48E-04 1.48E-04 1.71E-04 1.24E-04 lbs/MMcf 1 22.41 201.32 0.00

ICE, Field Gas 5 PAH Benzo(g,h,i)perylene A3-v0 9.40E-05 9.40E-05 9.92E-05 8.89E-05 lbs/MMcf 1 7.74 69.50 0.00

ICE, Field Gas 5 PAH Benzo(k)fluoranthene A3-v0 4.57E-03 4.57E-03 4.69E-03 4.44E-03 lbs/MMcf 1 3.78 33.93 1.00

ICE, Field Gas 5 PAH Chrysene A3-v0 1.69E-03 1.69E-03 1.80E-03 1.58E-03 lbs/MMcf 1 9.43 84.71 1.00

ICE, Field Gas 5 PAH Dibenz(a,h)anthracene A3-v0 7.70E-05 7.70E-05 8.29E-05 7.11E-05 lbs/MMcf 1 10.86 97.62 0.00

ICE, Field Gas 5 PAH Fluoranthene A3-v0 1.66E-04 1.66E-04 2.16E-04 1.16E-04 lbs/MMcf 1 42.96 385.95 0.00

ICE, Field Gas 5 PAH Fluorene A3-v0 2.44E-03 2.44E-03 3.61E-03 1.27E-03 lbs/MMcf 1 67.90 610.07 0.00

ICE, Field Gas 5 PAH Indeno(1,2,3-cd)pyrene A3-v0 1.37E-04 1.37E-04 1.46E-04 1.29E-04 lbs/MMcf 1 8.83 79.35 0.00

156

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Field Gas 5 PAH Naphthalene A3-v0 2.19E-01 2.19E-01 2.22E-01 2.16E-01 lbs/MMcf 1 1.88 16.92 1.00

ICE, Field Gas 5 PAH Phenanthrene A3-v0 4.91E-03 4.91E-03 6.49E-03 3.33E-03 lbs/MMcf 1 45.46 408.44 1.00

ICE, Field Gas 5 PAH Pyrene A3-v0 2.39E-04 2.39E-04 3.06E-04 1.71E-04 lbs/MMcf 1 40.10 360.26 0.64

ICE, Field Gas 5 VOC Acetaldehyde A3-v0 8.77E+00 9.42E+00 1.14E+01 5.53E+00 lbs/MMcf 1 33.90 84.22 1.00

ICE, Field Gas 5 VOC Acrolein A3-v1 2.00E+00 1.44E+00 4.36E+00 2.00E-01 lbs/MMcf 1 106.79 265.28 1.00

ICE, Field Gas 5 VOC Benzene A3-v0 4.39E+00 4.33E+00 4.60E+00 4.23E+00 lbs/MMcf 1 4.34 10.79 1.00

ICE, Field Gas 5 VOC Formaldehyde A3-v1 2.58E+01 7.45E+00 6.56E+01 4.21E+00 lbs/MMcf 1 134.14 333.23 1.00

ICE, Field Gas 5 VOC Propylene A3-v0 1.47E+01 1.50E+01 1.77E+01 1.14E+01 lbs/MMcf 1 21.50 53.41 1.00

ICE, Field Gas 5 VOC Toluene A3-v1 1.54E+00 2.03E+00 2.36E+00 2.23E-01 lbs/MMcf 1 74.82 185.86 1.00

ICE, Field Gas 5 VOC Xylene (m,p) A3-v0 2.54E-01 2.57E-01 3.17E-01 1.89E-01 lbs/MMcf 1 25.26 62.75 1.00

ICE, Field Gas 5 VOC Xylene (o) A3-v0 1.03E-01 1.06E-01 1.36E-01 6.80E-02 lbs/MMcf 1 32.99 81.96 1.00

ICE, Landfill Gas 1 Halogens HCl C3-v0 1.50E+00 1.57E+00 2.07E+00 8.62E-01 lbs/MMcf 2 39.55 41.50 1.00

ICE, Landfill Gas 1 PAH Acenaphthene B3-v3 1.65E-04 1.80E-04 3.01E-04 1.11E-07 lbs/MMcf 2 82.13 130.69 0.37

ICE, Landfill Gas 1 PAH Acenaphthylene B3-v3 4.33E-04 8.14E-05 1.23E-03 1.03E-06 lbs/MMcf 2 140.91 147.87 1.00

ICE, Landfill Gas 1 PAH Anthracene B3-v5 1.71E-04 1.55E-04 3.71E-04 1.14E-09 lbs/MMcf 2 110.02 115.45 0.30

ICE, Landfill Gas 1 PAH Benzo(a)anthracene A3-v0 2.24E-04 2.06E-04 2.88E-04 1.78E-04 lbs/MMcf 1 25.49 63.33 0.00

ICE, Landfill Gas 1 PAH Benzo(a)pyrene B3-v4 3.29E-04 3.20E-04 6.77E-04 1.30E-07 lbs/MMcf 2 89.94 143.12 0.86

ICE, Landfill Gas 1 PAH Benzo(b)fluoranthene B3-v3 2.93E-04 3.26E-04 8.00E-04 5.34E-07 lbs/MMcf 2 112.09 139.17 0.23

ICE, Landfill Gas 1 PAH Benzo(g,h,i)perylene B3-v3 3.76E-04 2.84E-04 8.54E-04 4.19E-07 lbs/MMcf 2 107.36 133.31 1.00

ICE, Landfill Gas 1 PAH Benzo(k)fluoranthene A3-v0 4.26E-04 4.12E-04 6.77E-04 1.90E-04 lbs/MMcf 1 57.15 141.98 0.15

ICE, Landfill Gas 1 PAH Chrysene A3-v0 3.10E-04 3.38E-04 3.42E-04 2.51E-04 lbs/MMcf 1 16.62 41.28 0.00

ICE, Landfill Gas 1 PAH Dibenz(a,h)anthracene A3-v0 1.82E-05 1.91E-05 2.37E-05 1.17E-05 lbs/MMcf 1 33.33 82.79 0.00

ICE, Landfill Gas 1 PAH Fluoranthene B3-v3 1.00E-03 6.47E-04 2.48E-03 1.07E-06 lbs/MMcf 2 116.40 122.16 1.00

ICE, Landfill Gas 1 PAH Fluorene B3-v3 3.68E-04 5.24E-04 6.99E-04 3.37E-07 lbs/MMcf 2 92.74 115.15 1.00

ICE, Landfill Gas 1 PAH Indeno(1,2,3-cd)pyrene B3-v3 1.38E-04 1.27E-04 3.14E-04 1.60E-07 lbs/MMcf 2 103.35 128.33 1.00

ICE, Landfill Gas 1 PAH Naphthalene B3-v3 2.18E-02 1.82E-02 5.05E-02 2.25E-05 lbs/MMcf 2 110.82 116.30 1.00

ICE, Landfill Gas 1 PAH Phenanthrene B3-v3 2.51E-03 2.00E-03 5.82E-03 1.64E-06 lbs/MMcf 2 111.92 117.46 1.00

ICE, Landfill Gas 1 PAH Pyrene B3-v3 1.87E-03 1.23E-03 4.66E-03 1.81E-06 lbs/MMcf 2 116.04 121.78 1.00

157

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Landfill Gas 1 VOC Benzene C3-v0 1.75E-01 1.82E-01 2.09E-01 1.16E-01 lbs/MMcf 2 22.65 23.77 1.00

ICE, Landfill Gas 1 VOC Carbon Tetrachloride C3-v0 7.78E-03 7.78E-03 7.89E-03 7.67E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Chloroform C3-v0 6.02E-03 6.02E-03 6.11E-03 5.94E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Ethylene dibromide C3-v0 9.51E-03 9.51E-03 9.64E-03 9.37E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Ethylene dichloride C3-v0 5.01E-03 5.01E-03 5.08E-03 4.94E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Formaldehyde C3-v2 1.29E+00 6.95E-01 4.47E+00 5.70E-02 lbs/MMcf 2 127.39 133.69 1.00

ICE, Landfill Gas 1 VOC Methyl Chloroform C3-v0 1.00E-02 6.75E-03 2.64E-02 6.66E-03 lbs/MMcf 2 80.11 84.07 0.44

ICE, Landfill Gas 1 VOC Methylene Chloride C3-v2 2.23E-01 2.11E-01 4.66E-01 8.72E-03 lbs/MMcf 2 88.27 92.63 0.99

ICE, Landfill Gas 1 VOC Perchloroethylene C3-v0 1.26E-02 1.26E-02 1.28E-02 1.24E-02 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Trichloroethylene C3-v0 8.31E-03 8.31E-03 8.43E-03 8.19E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Landfill Gas 1 VOC Vinyl Chloride C3-v0 3.95E-03 3.95E-03 4.01E-03 3.90E-03 lbs/MMcf 2 1.55 1.63 0.00

ICE, Natural Gas 1 PAH Acenaphthene A3-v0 7.17E-04 6.36E-04 9.60E-04 5.57E-04 lbs/MMcf 1 29.79 74.00 1.00

ICE, Natural Gas 1 PAH Acenaphthylene A3-v0 7.59E-03 7.65E-03 1.07E-02 4.40E-03 lbs/MMcf 1 41.56 103.24 1.00

ICE, Natural Gas 1 PAH Anthracene A3-v0 2.56E-04 2.40E-04 3.69E-04 1.60E-04 lbs/MMcf 1 41.20 102.34 1.00

ICE, Natural Gas 1 PAH Benzo(a)anthracene A3-v0 7.78E-05 7.83E-05 9.60E-05 5.91E-05 lbs/MMcf 1 23.70 58.87 1.00

ICE, Natural Gas 1 PAH Benzo(a)pyrene A3-v0 3.55E-05 2.93E-05 5.17E-05 2.54E-05 lbs/MMcf 1 39.97 99.29 0.76

ICE, Natural Gas 1 PAH Benzo(b)fluoranthene A3-v2 3.27E-04 4.43E-05 9.29E-04 6.26E-06 lbs/MMcf 1 159.90 397.22 0.95

ICE, Natural Gas 1 PAH Benzo(g,h,i)perylene A3-v1 1.03E-04 2.93E-05 2.58E-04 2.09E-05 lbs/MMcf 1 131.00 325.43 1.00

ICE, Natural Gas 1 PAH Benzo(k)fluoranthene A3-v1 5.30E-04 4.87E-04 1.07E-03 3.08E-05 lbs/MMcf 1 98.44 244.54 0.98

ICE, Natural Gas 1 PAH Chrysene A3-v0 9.64E-05 1.11E-04 1.12E-04 6.61E-05 lbs/MMcf 1 27.27 67.75 1.00

ICE, Natural Gas 1 PAH Dibenz(a,h)anthracene A3-v0 1.09E-05 1.11E-05 1.47E-05 6.96E-06 lbs/MMcf 1 35.41 87.97 1.00

ICE, Natural Gas 1 PAH Fluoranthene A3-v0 2.50E-04 2.64E-04 3.32E-04 1.53E-04 lbs/MMcf 1 36.21 89.96 1.00

ICE, Natural Gas 1 PAH Fluorene A3-v0 4.60E-04 4.16E-04 6.28E-04 3.37E-04 lbs/MMcf 1 32.63 81.05 0.00

ICE, Natural Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v1 1.20E-04 3.91E-05 2.95E-04 2.43E-05 lbs/MMcf 1 127.40 316.47 1.00

ICE, Natural Gas 1 PAH Naphthalene A3-v1 1.22E-01 1.60E-01 1.86E-01 1.99E-02 lbs/MMcf 1 73.21 181.87 1.00

ICE, Natural Gas 1 PAH Phenanthrene A3-v0 8.93E-04 8.31E-04 1.26E-03 5.91E-04 lbs/MMcf 1 37.66 93.56 1.00

ICE, Natural Gas 1 PAH Pyrene A3-v0 1.23E-04 1.42E-04 1.62E-04 6.61E-05 lbs/MMcf 1 41.10 102.10 1.00

ICE, Natural Gas 1 VOC Acetaldehyde A1-v1 3.99E+00 2.96E+00 9.94E+00 1.52E+00 lbs/MMcf 5 64.91 35.94 1.00

158

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Natural Gas 1 VOC Acrolein A1-v1 1.63E+00 1.10E+00 5.48E+00 2.01E-01 lbs/MMcf 5 92.02 53.13 1.00

ICE, Natural Gas 1 VOC Benzene A1-v1 1.21E+00 1.22E+00 2.47E+00 2.47E-01 lbs/MMcf 7 47.28 27.30 1.00

ICE, Natural Gas 1 VOC Formaldehyde A1-v0 2.87E+01 2.77E+01 4.79E+01 9.68E+00 lbs/MMcf 7 38.56 17.55 1.00

ICE, Natural Gas 1 VOC Propylene A1-v1 1.87E+01 8.81E+00 5.85E+01 4.12E+00 lbs/MMcf 7 109.05 62.96 0.97

ICE, Natural Gas 1 VOC Toluene A1-v0 4.12E-01 3.96E-01 5.70E-01 1.65E-01 lbs/MMcf 7 33.98 19.62 1.00

ICE, Natural Gas 1 VOC Xylene (m,p) A1-v0 8.63E-02 8.13E-02 1.59E-01 3.53E-02 lbs/MMcf 7 46.27 26.72 1.00

ICE, Natural Gas 1 VOC Xylene (o) A1-v1 4.94E-02 4.95E-02 9.14E-02 1.06E-02 lbs/MMcf 7 39.52 22.82 0.95

ICE, Natural Gas 2 PAH Acenaphthene A3-v0 1.94E-03 1.32E-03 3.39E-03 1.11E-03 lbs/MMcf 1 64.90 161.23 1.00

ICE, Natural Gas 2 PAH Acenaphthylene A3-v0 1.45E-02 1.45E-02 1.62E-02 1.27E-02 lbs/MMcf 1 12.00 29.81 1.00

ICE, Natural Gas 2 PAH Anthracene A3-v0 1.84E-03 1.77E-03 2.26E-03 1.48E-03 lbs/MMcf 1 21.34 53.01 1.00

ICE, Natural Gas 2 PAH Benzo(a)anthracene A3-v0 2.94E-04 2.82E-04 3.39E-04 2.60E-04 lbs/MMcf 1 13.89 34.51 1.00

ICE, Natural Gas 2 PAH Benzo(a)pyrene A3-v0 1.15E-04 1.04E-04 1.51E-04 9.01E-05 lbs/MMcf 1 27.70 68.80 1.00

ICE, Natural Gas 2 PAH Benzo(b)fluoranthene A3-v0 2.37E-04 2.07E-04 3.01E-04 2.04E-04 lbs/MMcf 1 23.27 57.81 1.00

ICE, Natural Gas 2 PAH Benzo(g,h,i)perylene A3-v0 1.95E-04 1.81E-04 2.45E-04 1.59E-04 lbs/MMcf 1 22.89 56.85 1.00

ICE, Natural Gas 2 PAH Benzo(k)fluoranthene A3-v0 1.03E-04 1.13E-04 1.17E-04 7.91E-05 lbs/MMcf 1 20.11 49.97 1.00

ICE, Natural Gas 2 PAH Chrysene A3-v0 3.10E-04 2.91E-04 3.95E-04 2.45E-04 lbs/MMcf 1 24.83 61.68 1.00

ICE, Natural Gas 2 PAH Dibenz(a,h)anthracene A3-v0 1.25E-05 1.17E-05 1.45E-05 1.14E-05 lbs/MMcf 1 13.71 34.06 1.00

ICE, Natural Gas 2 PAH Fluoranthene A3-v0 9.95E-04 9.60E-04 1.20E-03 8.21E-04 lbs/MMcf 1 19.50 48.45 1.00

ICE, Natural Gas 2 PAH Fluorene A3-v0 6.91E-03 6.62E-03 9.04E-03 5.08E-03 lbs/MMcf 1 28.82 71.59 1.00

ICE, Natural Gas 2 PAH Indeno(1,2,3-cd)pyrene A3-v0 1.69E-04 1.60E-04 2.07E-04 1.40E-04 lbs/MMcf 1 20.25 50.31 1.00

ICE, Natural Gas 2 PAH Naphthalene A3-v0 7.65E-02 8.47E-02 8.66E-02 5.83E-02 lbs/MMcf 1 20.68 51.38 1.00

ICE, Natural Gas 2 PAH Phenanthrene A3-v0 7.07E-03 7.34E-03 8.85E-03 5.03E-03 lbs/MMcf 1 27.15 67.45 1.00

ICE, Natural Gas 2 PAH Pyrene A3-v0 1.79E-03 1.54E-03 2.64E-03 1.19E-03 lbs/MMcf 1 42.04 104.42 1.00

ICE, Natural Gas 2 SVOC Ethylbenzene C3-v0 1.16E-02 1.23E-02 1.44E-02 8.21E-03 lbs/MMcf 1 26.96 66.96 1.00

ICE, Natural Gas 2 VOC 1,3-Butadiene A3-v0 1.04E-01 1.05E-01 1.05E-01 1.04E-01 lbs/MMcf 1 0.38 0.93 1.00

ICE, Natural Gas 2 VOC Acetaldehyde A3-v1 8.83E-01 8.34E-01 1.82E+00 5.18E-02 lbs/MMcf 2 102.49 107.56 1.00

ICE, Natural Gas 2 VOC Acrolein A2-v3 5.47E-01 6.14E-01 1.37E+00 2.59E-03 lbs/MMcf 3 83.56 64.23 1.00

ICE, Natural Gas 2 VOC Benzene C2-v3 1.91E+00 1.29E-01 1.02E+01 1.38E-02 lbs/MMcf 4 206.43 138.68 1.00

159

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Natural Gas 2 VOC Formaldehyde B1-v3 2.35E+00 4.21E-01 1.14E+01 2.03E-02 lbs/MMcf 5 173.64 96.16 1.00

ICE, Natural Gas 2 VOC Propylene B3-v2 1.60E+01 4.39E-01 4.20E+01 2.87E-01 lbs/MMcf 2 134.24 166.68 1.00

ICE, Natural Gas 2 VOC Toluene B3-v1 1.07E+00 1.09E-01 2.62E+00 9.44E-02 lbs/MMcf 2 123.82 153.75 1.00

ICE, Natural Gas 2 VOC Xylene (m,p) A3-v0 4.41E-01 4.41E-01 4.54E-01 4.28E-01 lbs/MMcf 1 4.04 36.30 1.00

ICE, Natural Gas 2 VOC Xylene (o) A3-v0 2.17E-01 2.17E-01 2.22E-01 2.12E-01 lbs/MMcf 1 3.29 29.55 1.00

ICE, Natural Gas 2 VOC Xylene (Total) C3-v0 6.02E-02 6.77E-02 7.38E-02 3.90E-02 lbs/MMcf 1 30.93 76.84 1.00

ICE, Natural Gas 3 PAH Acenaphthene A3-v0 1.51E-04 1.56E-04 2.17E-04 9.58E-05 lbs/MMcf 2 33.63 35.29 1.00

ICE, Natural Gas 3 PAH Acenaphthylene A3-v0 5.25E-04 5.16E-04 7.35E-04 3.58E-04 lbs/MMcf 2 23.88 25.06 1.00

ICE, Natural Gas 3 PAH Anthracene A3-v0 1.19E-04 1.13E-04 1.71E-04 6.28E-05 lbs/MMcf 2 32.95 34.58 1.00

ICE, Natural Gas 3 PAH Benzo(a)anthracene A3-v0 5.88E-05 5.03E-05 9.92E-05 2.61E-05 lbs/MMcf 2 56.36 59.14 1.00

ICE, Natural Gas 3 PAH Benzo(a)pyrene A3-v0 2.70E-06 2.52E-06 3.88E-06 1.84E-06 lbs/MMcf 2 35.83 37.60 0.00

ICE, Natural Gas 3 PAH Benzo(b)fluoranthene A3-v1 4.09E-05 3.49E-05 7.98E-05 1.22E-05 lbs/MMcf 2 56.71 59.51 1.00

ICE, Natural Gas 3 PAH Benzo(g,h,i)perylene A3-v1 7.54E-06 6.81E-06 1.71E-05 1.84E-06 lbs/MMcf 2 80.22 84.19 0.92

ICE, Natural Gas 3 PAH Benzo(k)fluoranthene A3-v0 7.83E-06 8.54E-06 1.21E-05 3.19E-06 lbs/MMcf 2 45.21 47.44 0.93

ICE, Natural Gas 3 PAH Chrysene A3-v1 1.43E-05 1.58E-05 2.25E-05 3.19E-06 lbs/MMcf 2 50.42 52.91 0.96

ICE, Natural Gas 3 PAH Dibenz(a,h)anthracene A3-v0 2.70E-06 2.52E-06 3.88E-06 1.84E-06 lbs/MMcf 2 35.83 37.60 0.00

ICE, Natural Gas 3 PAH Fluoranthene A3-v0 2.91E-04 2.99E-04 4.57E-04 1.29E-04 lbs/MMcf 2 50.10 52.58 1.00

ICE, Natural Gas 3 PAH Fluorene A3-v0 4.36E-04 3.49E-04 7.98E-04 1.92E-04 lbs/MMcf 2 58.05 60.92 1.00

ICE, Natural Gas 3 PAH Indeno(1,2,3-cd)pyrene A3-v1 7.17E-06 8.06E-06 1.09E-05 1.85E-06 lbs/MMcf 2 43.57 45.72 0.96

ICE, Natural Gas 3 PAH Naphthalene A3-v0 2.51E-02 2.34E-02 3.10E-02 2.07E-02 lbs/MMcf 2 18.15 19.05 1.00

ICE, Natural Gas 3 PAH Phenanthrene A3-v0 1.85E-03 1.80E-03 2.75E-03 1.11E-03 lbs/MMcf 2 37.16 39.00 1.00

ICE, Natural Gas 3 PAH Pyrene A3-v0 1.87E-04 1.91E-04 3.26E-04 6.65E-05 lbs/MMcf 2 49.82 52.28 1.00

ICE, Natural Gas 3 SVOC Ethylbenzene C3-v0 7.11E-02 7.00E-02 1.15E-01 2.59E-02 lbs/MMcf 2 50.37 52.86 1.00

ICE, Natural Gas 3 VOC 1,3-Butadiene A3-v0 3.67E-01 3.78E-01 4.15E-01 2.76E-01 lbs/MMcf 2 14.65 15.37 1.00

ICE, Natural Gas 3 VOC Acetaldehyde A3-v2 5.29E-01 3.92E-02 2.62E+00 2.08E-02 lbs/MMcf 2 196.36 206.07 0.96

ICE, Natural Gas 3 VOC Acrolein A3-v1 5.90E-02 3.92E-02 1.61E-01 2.08E-02 lbs/MMcf 2 88.08 92.43 0.45

ICE, Natural Gas 3 VOC Benzene C3-v0 2.18E-01 2.12E-01 2.59E-01 1.83E-01 lbs/MMcf 2 12.23 12.83 1.00

ICE, Natural Gas 3 VOC Formaldehyde B2-v3 4.71E+00 3.65E-01 2.09E+01 1.56E-02 lbs/MMcf 3 157.78 121.28 0.97

160

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

ICE, Natural Gas 3 VOC Propylene C3-v0 5.38E+00 4.25E+00 1.21E+01 3.56E+00 lbs/MMcf 2 61.42 64.46 1.00

ICE, Natural Gas 3 VOC Toluene C3-v0 2.39E-01 2.59E-01 3.94E-01 9.08E-02 lbs/MMcf 2 46.93 49.25 1.00

ICE, Natural Gas 3 VOC Xylene (Total) C3-v0 6.46E-01 6.85E-01 9.65E-01 2.46E-01 lbs/MMcf 2 45.98 48.25 1.00

ICE, Natural Gas 4 SVOC Ethylbenzene C3-v0 6.46E-02 6.46E-02 6.46E-02 6.46E-02 lbs/MMcf 1 0.00 0.00 0.00

ICE, Natural Gas 4 VOC Benzene C3-v0 2.95E-01 2.89E-01 3.34E-01 2.62E-01 lbs/MMcf 1 12.37 30.73 1.00

ICE, Natural Gas 4 VOC Formaldehyde C2-v1 5.15E+00 7.20E-01 2.14E+01 5.98E-01 lbs/MMcf 3 145.69 111.99 0.91

ICE, Natural Gas 4 VOC Toluene C3-v0 1.89E-01 1.23E-01 3.37E-01 1.08E-01 lbs/MMcf 1 67.56 167.83 1.00

ICE, Natural Gas 4 VOC Xylene (Total) C3-v0 1.29E-01 1.29E-01 1.29E-01 1.29E-01 lbs/MMcf 1 0.00 0.00 0.00

ICE, Natural Gas 5 VOC Benzene C3-v1 7.39E-02 7.19E-02 1.38E-01 1.47E-02 lbs/MMcf 2 77.27 81.09 1.00

ICE, Natural Gas 5 VOC Formaldehyde A3-v2 4.99E-02 1.86E-02 1.40E-01 1.43E-03 lbs/MMcf 2 126.22 132.46 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.16E-09 9.45E-10 1.89E-09 6.45E-10 lbs/ton 1 56.01 139.14 0.54

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:4D Total A3-v1 1.40E-07 4.64E-08 3.42E-07 3.16E-08 lbs/ton 1 125.03 310.60 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 4.64E-09 3.78E-09 7.83E-09 2.32E-09 lbs/ton 1 61.45 152.66 0.83

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:5D Total A3-v1 1.34E-07 1.41E-07 2.41E-07 2.03E-08 lbs/ton 1 82.38 204.65 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 2.48E-09 3.04E-09 3.17E-09 1.23E-09 lbs/ton 1 43.87 108.97 0.84

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:6D 123678 A3-v1 4.17E-09 5.67E-09 5.81E-09 1.03E-09 lbs/ton 1 65.18 161.93 0.92

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 3.47E-09 4.39E-09 4.79E-09 1.23E-09 lbs/ton 1 56.31 139.88 0.88

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:6D Total A3-v0 9.72E-08 1.05E-07 1.11E-07 7.55E-08 lbs/ton 1 19.53 48.52 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:7D 1234678 A3-v1 1.17E-08 1.40E-08 1.77E-08 3.48E-09 lbs/ton 1 62.85 156.13 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:7D Total A3-v1 2.28E-08 2.61E-08 3.58E-08 6.64E-09 lbs/ton 1 64.95 161.35 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Dioxin:8D A3-v0 1.72E-08 1.77E-08 2.81E-08 5.81E-09 lbs/ton 1 64.84 161.07 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:4F 2378 A3-v1 3.56E-09 2.30E-09 7.22E-09 1.16E-09 lbs/ton 1 90.53 224.90 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:4F Total A3-v1 4.47E-07 3.58E-07 8.64E-07 1.19E-07 lbs/ton 1 85.17 211.58 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:5F 12378 A3-v1 8.01E-09 5.06E-09 1.61E-08 2.90E-09 lbs/ton 1 88.13 218.92 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:5F 23478 A3-v1 1.33E-08 1.03E-08 2.61E-08 3.48E-09 lbs/ton 1 87.23 216.69 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:5F Total A3-v1 1.74E-07 1.58E-07 3.21E-07 4.35E-08 lbs/ton 1 80.14 199.07 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:6F 123478 A3-v1 7.32E-09 5.87E-09 1.34E-08 2.64E-09 lbs/ton 1 75.68 188.00 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:6F 123678 A3-v0 7.62E-09 6.35E-09 1.30E-08 3.48E-09 lbs/ton 1 64.29 159.71 1.00

161

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Medical Waste 1 Dioxin/Furan Furan:6F 123789 A3-v1 3.38E-09 2.09E-09 7.22E-09 8.39E-10 lbs/ton 1 99.94 248.26 0.92

Incinerator, Medical Waste 1 Dioxin/Furan Furan:6F 234678 A3-v1 9.81E-09 8.84E-09 1.77E-08 2.90E-09 lbs/ton 1 75.83 188.36 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:6F Total A3-v1 8.09E-08 8.24E-08 1.34E-07 2.61E-08 lbs/ton 1 66.86 166.10 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:7F 1234678 A3-v0 1.52E-08 1.85E-08 2.00E-08 6.97E-09 lbs/ton 1 47.11 117.03 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:7F 1234789 A3-v0 4.41E-09 5.60E-09 5.87E-09 1.74E-09 lbs/ton 1 52.46 130.31 0.87

Incinerator, Medical Waste 1 Dioxin/Furan Furan:7F Total A3-v0 9.37E-08 8.84E-08 1.24E-07 6.82E-08 lbs/ton 1 30.44 75.62 1.00

Incinerator, Medical Waste 1 Dioxin/Furan Furan:8F A3-v0 7.84E-09 8.84E-09 1.09E-08 3.74E-09 lbs/ton 1 47.20 117.26 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:4D 2378 A3-v1 5.67E-10 1.61E-10 1.43E-09 1.09E-10 lbs/ton 1 132.12 328.20 0.84

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:4D Total A3-v2 2.13E-07 4.41E-09 6.32E-07 2.11E-09 lbs/ton 1 170.56 423.68 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:5D 12378 A3-v1 2.17E-09 8.70E-10 5.49E-09 1.50E-10 lbs/ton 1 133.49 331.62 0.98

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:5D Total A3-v2 5.67E-08 1.28E-08 1.55E-07 2.21E-09 lbs/ton 1 150.62 374.17 0.99

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:6D 123478 A3-v1 1.28E-09 7.20E-10 2.74E-09 3.61E-10 lbs/ton 1 100.79 250.37 0.91

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:6D 123678 A3-v1 1.98E-09 1.51E-09 4.18E-09 2.51E-10 lbs/ton 1 101.31 251.66 0.96

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:6D 123789 A3-v1 1.27E-09 8.70E-10 2.63E-09 3.01E-10 lbs/ton 1 95.73 237.80 0.92

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:6D Total A3-v2 4.12E-08 2.67E-08 9.55E-08 1.40E-09 lbs/ton 1 118.18 293.58 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:7D 1234678 A3-v1 6.26E-09 4.87E-09 1.31E-08 7.82E-10 lbs/ton 1 100.42 249.46 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:7D Total A3-v1 1.60E-08 1.28E-08 3.34E-08 1.71E-09 lbs/ton 1 100.82 250.46 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Dioxin:8D A3-v0 9.13E-09 7.22E-09 1.55E-08 4.64E-09 lbs/ton 1 62.23 154.60 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:4F 2378 A3-v2 2.39E-08 1.74E-09 6.92E-08 6.42E-10 lbs/ton 1 164.57 408.82 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:4F Total A3-v2 1.75E-06 9.40E-08 5.13E-06 3.51E-08 lbs/ton 1 166.84 414.44 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:5F 12378 A3-v2 2.77E-08 2.90E-09 7.99E-08 3.21E-10 lbs/ton 1 163.20 405.42 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:5F 23478 A3-v2 5.01E-08 6.73E-09 1.43E-07 5.02E-10 lbs/ton 1 160.83 399.53 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:5F Total A3-v2 7.40E-07 6.50E-08 2.15E-06 8.23E-09 lbs/ton 1 164.68 409.10 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:6F 123478 A3-v3 6.11E-08 4.06E-09 1.79E-07 3.41E-10 lbs/ton 1 166.99 414.84 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:6F 123678 A3-v2 5.79E-08 6.38E-09 1.67E-07 3.71E-10 lbs/ton 1 163.19 405.39 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:6F 123789 A3-v2 6.29E-09 8.12E-10 1.79E-08 1.50E-10 lbs/ton 1 160.03 397.53 0.99

Incinerator, Medical Waste 2 Dioxin/Furan Furan:6F 234678 A3-v2 3.55E-08 7.20E-09 9.90E-08 4.01E-10 lbs/ton 1 154.99 385.02 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:6F Total A3-v3 6.18E-07 6.27E-08 1.79E-06 2.31E-09 lbs/ton 1 164.18 407.84 1.00

162

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Medical Waste 2 Dioxin/Furan Furan:7F 1234678 A3-v3 1.55E-07 9.87E-09 4.53E-07 5.92E-10 lbs/ton 1 167.38 415.78 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:7F 1234789 A3-v2 8.29E-09 8.70E-10 2.39E-08 1.20E-10 lbs/ton 1 162.91 404.69 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:7F Total A3-v3 2.12E-07 1.39E-08 6.20E-07 5.92E-10 lbs/ton 1 167.29 415.58 1.00

Incinerator, Medical Waste 2 Dioxin/Furan Furan:8F A3-v2 1.21E-08 2.79E-10 3.58E-08 2.01E-10 lbs/ton 1 169.77 421.74 0.99

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:4D 2378 A3-v0 1.50E-06 1.64E-06 2.11E-06 7.57E-07 lbs/ton 1 45.82 113.82 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:5D 12378 A3-v0 8.53E-06 1.06E-05 1.09E-05 4.11E-06 lbs/ton 1 44.91 111.57 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:6D 123478 A3-v0 1.36E-05 1.48E-05 2.16E-05 4.37E-06 lbs/ton 1 63.71 158.28 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:6D 123678 A3-v0 3.19E-05 3.24E-05 5.07E-05 1.26E-05 lbs/ton 1 59.65 148.17 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:6D 123789 A3-v0 2.20E-05 2.22E-05 3.50E-05 8.72E-06 lbs/ton 1 59.86 148.70 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:7D 1234678 A3-v0 5.69E-05 5.47E-05 9.10E-05 2.49E-05 lbs/ton 1 58.23 144.66 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Dioxin:8D A3-v0 3.25E-05 2.93E-05 5.28E-05 1.54E-05 lbs/ton 1 58.10 144.34 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:4F 2378 A3-v3 2.21E-05 1.25E-07 6.62E-05 8.32E-08 lbs/ton 1 172.39 428.24 0.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:5F 12378 A3-v0 2.39E-05 2.93E-05 2.93E-05 1.31E-05 lbs/ton 1 39.09 97.11 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:5F 23478 A3-v0 4.25E-05 4.52E-05 5.02E-05 3.21E-05 lbs/ton 1 22.00 54.64 0.61

Incinerator, Medical Waste 3 Dioxin/Furan Furan:6F 123478 A3-v0 6.48E-05 5.87E-05 8.27E-05 5.29E-05 lbs/ton 1 24.36 60.50 0.57

Incinerator, Medical Waste 3 Dioxin/Furan Furan:6F 123678 A3-v0 2.45E-05 2.62E-05 3.50E-05 1.23E-05 lbs/ton 1 46.80 116.25 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:6F 123789 A3-v0 2.38E-07 2.35E-07 2.88E-07 1.90E-07 lbs/ton 1 20.58 51.11 0.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:6F 234678 A3-v0 2.38E-07 2.35E-07 2.88E-07 1.90E-07 lbs/ton 1 20.58 51.11 0.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:7F 1234678 A3-v0 1.98E-04 2.15E-04 3.11E-04 6.88E-05 lbs/ton 1 61.54 152.88 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:7F 1234789 A3-v1 1.53E-05 1.48E-05 2.64E-05 4.75E-06 lbs/ton 1 70.83 175.94 1.00

Incinerator, Medical Waste 3 Dioxin/Furan Furan:8F A3-v0 3.60E-05 3.21E-05 5.94E-05 1.65E-05 lbs/ton 1 60.23 149.62 1.00

Incinerator, Medical Waste 3 Halogens HCl C3-v0 4.29E+01 4.43E+01 5.50E+01 2.94E+01 lbs/ton 1 30.05 74.64 1.00

Incinerator, Medical Waste 3 Metals Chromium (Hex) A3-v0 1.29E-04 1.29E-04 1.74E-04 8.46E-05 lbs/ton 1 34.64 86.06 0.67

Incinerator, Medical Waste 3 PAH Acenaphthene C3-v1 1.07E-02 9.40E-03 2.03E-02 2.51E-03 lbs/ton 1 83.57 207.59 0.92

Incinerator, Medical Waste 3 PAH Acenaphthylene C3-v1 2.78E-01 3.12E-01 4.55E-01 6.68E-02 lbs/ton 1 70.67 175.55 1.00

Incinerator, Medical Waste 3 PAH Anthracene C3-v1 9.74E-02 1.01E-01 1.66E-01 2.51E-02 lbs/ton 1 72.52 180.16 0.91

Incinerator, Medical Waste 3 PAH Benzo(a)anthracene C3-v1 3.56E-02 4.31E-02 5.93E-02 4.32E-03 lbs/ton 1 79.40 197.23 1.00

Incinerator, Medical Waste 3 PAH Benzo(a)pyrene C3-v0 6.26E-03 7.55E-03 8.71E-03 2.51E-03 lbs/ton 1 52.66 130.81 0.87

163

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Medical Waste 3 PAH Benzo(b)fluoranthene C3-v1 1.90E-02 1.49E-02 3.70E-02 5.13E-03 lbs/ton 1 85.90 213.40 1.00

Incinerator, Medical Waste 3 PAH Benzo(g,h,i)perylene C3-v0 6.91E-03 8.66E-03 9.55E-03 2.51E-03 lbs/ton 1 55.48 137.81 0.88

Incinerator, Medical Waste 3 PAH Benzo(k)fluoranthene C3-v1 2.61E-02 2.62E-02 4.80E-02 4.12E-03 lbs/ton 1 84.08 208.87 1.00

Incinerator, Medical Waste 3 PAH Chrysene C3-v1 4.99E-02 6.87E-02 7.19E-02 9.21E-03 lbs/ton 1 70.69 175.61 1.00

Incinerator, Medical Waste 3 PAH Dibenz(a,h)anthracene C3-v0 3.00E-03 2.82E-03 3.65E-03 2.51E-03 lbs/ton 1 19.71 48.95 0.00

Incinerator, Medical Waste 3 PAH Fluoranthene C3-v0 1.77E-01 2.07E-01 2.63E-01 5.96E-02 lbs/ton 1 59.55 147.94 1.00

Incinerator, Medical Waste 3 PAH Fluorene C3-v1 1.37E-01 1.80E-01 2.13E-01 1.78E-02 lbs/ton 1 76.32 189.58 1.00

Incinerator, Medical Waste 3 PAH Indeno(1,2,3-cd)pyrene C3-v0 5.69E-03 6.60E-03 7.97E-03 2.51E-03 lbs/ton 1 49.85 123.83 0.85

Incinerator, Medical Waste 3 PAH Naphthalene C3-v0 3.84E-01 3.65E-01 5.64E-01 2.21E-01 lbs/ton 1 44.94 111.64 0.19

Incinerator, Medical Waste 3 PAH Phenanthrene C3-v0 3.29E-01 3.68E-01 4.93E-01 1.27E-01 lbs/ton 1 56.46 140.26 1.00

Incinerator, Medical Waste 3 PAH Pyrene C3-v1 1.61E-01 1.88E-01 2.50E-01 4.51E-02 lbs/ton 1 65.33 162.29 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:4D 2378 A3-v1 8.39E-08 9.84E-08 1.36E-07 1.75E-08 lbs/ton 1 72.08 179.05 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:4D Total A3-v1 2.39E-06 3.01E-06 3.83E-06 3.50E-07 lbs/ton 1 75.91 188.56 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:5D 12378 A3-v1 1.67E-07 1.42E-07 3.46E-07 1.42E-08 lbs/ton 1 99.93 248.24 0.97

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:5D Total A3-v1 1.76E-06 1.69E-06 3.46E-06 1.33E-07 lbs/ton 1 94.40 234.51 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:6D 123478 A3-v1 9.24E-08 7.10E-08 1.85E-07 2.08E-08 lbs/ton 1 91.20 226.55 0.92

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:6D 123678 A3-v1 9.48E-08 7.10E-08 1.98E-07 1.58E-08 lbs/ton 1 98.26 244.09 0.94

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:6D 123789 A3-v1 8.77E-08 7.10E-08 1.73E-07 1.92E-08 lbs/ton 1 89.16 221.49 0.93

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:6D Total A3-v1 1.42E-06 1.26E-06 2.84E-06 1.75E-07 lbs/ton 1 94.12 233.81 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:7D 1234678 A3-v1 2.70E-07 2.40E-07 5.19E-07 5.25E-08 lbs/ton 1 86.68 215.33 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:7D Total A3-v1 5.29E-07 4.86E-07 1.00E-06 1.00E-07 lbs/ton 1 85.39 212.11 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Dioxin:8D A3-v0 3.51E-07 3.08E-07 4.81E-07 2.62E-07 lbs/ton 1 32.95 81.86 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:4F 2378 A3-v1 5.90E-07 6.01E-07 1.06E-06 1.08E-07 lbs/ton 1 80.76 200.62 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:4F Total A3-v1 1.74E-05 1.91E-05 2.96E-05 3.33E-06 lbs/ton 1 76.23 189.38 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:5F 12378 A3-v1 3.76E-07 3.44E-07 7.28E-07 5.42E-08 lbs/ton 1 90.04 223.68 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:5F 23478 A3-v1 6.09E-07 5.25E-07 1.22E-06 8.08E-08 lbs/ton 1 94.45 234.62 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:5F Total A3-v1 7.10E-06 6.56E-06 1.36E-05 1.17E-06 lbs/ton 1 87.65 217.74 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:6F 123478 A3-v1 3.31E-07 3.01E-07 6.67E-07 2.67E-08 lbs/ton 1 96.92 240.78 1.00

164

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Waste explosives 1 Dioxin/Furan Furan:6F 123678 A3-v1 3.23E-07 2.62E-07 6.67E-07 4.08E-08 lbs/ton 1 98.17 243.86 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:6F 123789 A3-v1 3.53E-08 3.01E-08 6.67E-08 9.17E-09 lbs/ton 1 82.46 204.85 0.91

Incinerator, Waste explosives 1 Dioxin/Furan Furan:6F 234678 A3-v1 2.48E-07 2.02E-07 4.94E-07 4.75E-08 lbs/ton 1 91.45 227.17 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:6F Total A3-v1 3.53E-06 2.84E-06 7.28E-06 4.58E-07 lbs/ton 1 98.19 243.93 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:7F 1234678 A3-v1 4.49E-07 3.66E-07 8.89E-07 9.17E-08 lbs/ton 1 90.22 224.13 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:7F 1234789 A3-v1 3.40E-08 2.62E-08 6.67E-08 9.17E-09 lbs/ton 1 86.80 215.63 0.91

Incinerator, Waste explosives 1 Dioxin/Furan Furan:7F Total A3-v1 6.65E-07 5.46E-07 1.36E-06 9.17E-08 lbs/ton 1 96.41 239.50 1.00

Incinerator, Waste explosives 1 Dioxin/Furan Furan:8F A3-v0 6.09E-08 5.25E-08 1.06E-07 2.42E-08 lbs/ton 1 68.36 169.82 0.87

Incinerator, Waste explosives 1 Halogens HCl C3-v0 6.33E+00 6.33E+00 1.03E+01 2.35E+00 lbs/ton 1 88.93 799.00 1.00

Incinerator, Waste explosives 1 Metals Antimony A3-v1 1.23E-03 1.22E-03 2.25E-03 2.08E-04 lbs/ton 1 83.25 206.81 0.39

Incinerator, Waste explosives 1 Metals Arsenic A3-v0 1.11E-03 6.01E-04 2.25E-03 4.81E-04 lbs/ton 1 88.97 221.02 0.14

Incinerator, Waste explosives 1 Metals Barium A3-v0 4.12E-03 5.33E-03 5.56E-03 1.48E-03 lbs/ton 1 55.67 138.28 1.00

Incinerator, Waste explosives 1 Metals Beryllium A3-v0 5.18E-05 6.05E-05 7.42E-05 2.08E-05 lbs/ton 1 53.54 133.01 0.00

Incinerator, Waste explosives 1 Metals Cadmium A3-v0 1.35E-03 1.75E-03 1.85E-03 4.37E-04 lbs/ton 1 58.60 145.58 1.00

Incinerator, Waste explosives 1 Metals Chromium (Total) A3-v0 1.59E-03 1.73E-03 2.50E-03 5.46E-04 lbs/ton 1 61.82 153.57 1.00

Incinerator, Waste explosives 1 Metals Copper A3-v0 8.85E-03 8.33E-03 1.11E-02 7.10E-03 lbs/ton 1 23.20 57.63 1.00

Incinerator, Waste explosives 1 Metals Lead A3-v1 1.14E-02 7.42E-03 2.47E-02 2.08E-03 lbs/ton 1 103.74 257.70 1.00

Incinerator, Waste explosives 1 Metals Manganese A3-v0 1.21E-03 1.23E-03 1.42E-03 9.84E-04 lbs/ton 1 17.95 44.58 1.00

Incinerator, Waste explosives 1 Metals Mercury A3-v0 1.04E-03 1.17E-03 1.48E-03 4.81E-04 lbs/ton 1 49.05 121.86 1.00

Incinerator, Waste explosives 1 Metals Nickel A3-v1 2.86E-03 1.22E-03 6.75E-03 6.01E-04 lbs/ton 1 118.45 294.25 1.00

Incinerator, Waste explosives 1 Metals Phosphorus A3-v1 4.96E-03 4.50E-03 9.14E-03 1.26E-03 lbs/ton 1 79.77 198.16 0.61

Incinerator, Waste explosives 1 Metals Selenium A3-v2 9.57E-03 6.01E-03 2.25E-02 1.85E-04 lbs/ton 1 121.00 300.58 0.00

Incinerator, Waste explosives 1 Metals Silver A3-v0 3.30E-04 3.70E-04 4.50E-04 1.69E-04 lbs/ton 1 43.83 108.88 0.17

Incinerator, Waste explosives 1 Metals Thallium A3-v0 1.57E-02 1.85E-02 2.25E-02 6.01E-03 lbs/ton 1 54.89 136.34 0.00

Incinerator, Waste explosives 1 Metals Zinc A3-v1 2.39E+00 1.73E+00 4.92E+00 5.19E-01 lbs/ton 1 95.13 236.32 1.00

Incinerator, Waste explosives 1 PAH Acenaphthene A3-v1 1.68E-02 1.48E-02 3.17E-02 3.99E-03 lbs/ton 1 82.91 205.95 1.00

Incinerator, Waste explosives 1 PAH Acenaphthylene A3-v0 1.25E-02 1.60E-02 1.75E-02 3.83E-03 lbs/ton 1 60.29 149.78 1.00

Incinerator, Waste explosives 1 PAH Anthracene A3-v1 9.00E-03 5.93E-03 1.83E-02 2.73E-03 lbs/ton 1 91.60 227.55 1.00

165

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Waste explosives 1 PAH Benzo(a)anthracene A3-v1 2.73E-04 1.85E-04 5.58E-04 7.65E-05 lbs/ton 1 92.46 229.68 1.00

Incinerator, Waste explosives 1 PAH Benzo(a)pyrene A3-v1 6.08E-05 7.67E-05 9.63E-05 9.29E-06 lbs/ton 1 75.12 186.60 1.00

Incinerator, Waste explosives 1 PAH Benzo(b)fluoranthene A3-v0 2.67E-04 2.47E-04 4.17E-04 1.37E-04 lbs/ton 1 52.89 131.39 1.00

Incinerator, Waste explosives 1 PAH Benzo(g,h,i)perylene A3-v1 1.90E-04 2.10E-04 3.25E-04 3.61E-05 lbs/ton 1 76.43 189.86 1.00

Incinerator, Waste explosives 1 PAH Benzo(k)fluoranthene A3-v1 8.02E-05 7.53E-05 1.42E-04 2.35E-05 lbs/ton 1 73.90 183.57 1.00

Incinerator, Waste explosives 1 PAH Chrysene A3-v0 7.61E-04 4.44E-04 1.42E-03 4.21E-04 lbs/ton 1 74.71 185.59 1.00

Incinerator, Waste explosives 1 PAH Dibenz(a,h)anthracene A3-v1 1.35E-05 1.83E-05 1.85E-05 3.61E-06 lbs/ton 1 63.45 157.61 1.00

Incinerator, Waste explosives 1 PAH Fluoranthene A3-v0 2.07E-03 1.73E-03 3.33E-03 1.15E-03 lbs/ton 1 54.70 135.88 1.00

Incinerator, Waste explosives 1 PAH Fluorene A3-v1 5.45E-02 5.93E-02 9.17E-02 1.26E-02 lbs/ton 1 72.96 181.25 1.00

Incinerator, Waste explosives 1 PAH Indeno(1,2,3-cd)pyrene A3-v1 1.10E-04 1.36E-04 1.67E-04 2.73E-05 lbs/ton 1 66.57 165.38 1.00

Incinerator, Waste explosives 1 PAH Naphthalene A3-v0 3.04E-01 2.72E-01 4.83E-01 1.58E-01 lbs/ton 1 54.16 134.55 1.00

Incinerator, Waste explosives 1 PAH Phenanthrene A3-v0 1.10E-01 8.02E-02 2.00E-01 5.08E-02 lbs/ton 1 71.60 177.87 1.00

Incinerator, Waste explosives 1 PAH Pyrene A3-v1 1.23E-02 9.63E-03 2.33E-02 3.83E-03 lbs/ton 1 81.69 202.92 1.00

Incinerator, Waste explosives 1 PCB PCB:Decachlorinatedbiphenyls

A3-v0 5.42E-07 6.17E-07 6.25E-07 3.83E-07 lbs/ton 1 25.45 63.22 0.00

Incinerator, Waste explosives 1 PCB PCB:Dichlorinated biphenyls A3-v0 1.95E-05 1.11E-05 3.83E-05 9.17E-06 lbs/ton 1 83.34 207.03 1.00

Incinerator, Waste explosives 1 PCB PCB:Heptachlorinatedbiphenyls

A3-v2 2.25E-06 4.64E-07 6.17E-06 1.17E-07 lbs/ton 1 151.05 375.22 0.91

Incinerator, Waste explosives 1 PCB PCB:Hexachlorinatedbiphenyls

A3-v1 2.10E-06 4.75E-07 5.43E-06 3.83E-07 lbs/ton 1 137.80 342.32 0.86

Incinerator, Waste explosives 1 PCB PCB:Monochlorinatedbiphenyls

A3-v0 4.84E-05 4.32E-05 7.10E-05 3.08E-05 lbs/ton 1 42.58 105.77 1.00

Incinerator, Waste explosives 1 PCB PCB:Nonachlorinatedbiphenyls

A3-v0 1.92E-07 1.75E-07 2.84E-07 1.17E-07 lbs/ton 1 44.27 109.97 0.00

Incinerator, Waste explosives 1 PCB PCB:Octachlorinatedbiphenyls

A3-v0 4.23E-07 3.01E-07 7.78E-07 1.92E-07 lbs/ton 1 73.64 182.94 0.00

Incinerator, Waste explosives 1 PCB PCB:Pentachlorinatedbiphenyls

A3-v1 2.79E-06 3.46E-06 4.43E-06 4.92E-07 lbs/ton 1 73.43 182.42 0.94

Incinerator, Waste explosives 1 PCB PCB:Tetrachlorinatedbiphenyls

A3-v1 3.77E-06 2.24E-06 8.40E-06 6.75E-07 lbs/ton 1 108.25 268.90 0.94

Incinerator, Waste explosives 1 PCB PCB:Trichlorinated biphenyls A3-v0 1.43E-05 8.08E-06 2.84E-05 6.56E-06 lbs/ton 1 84.99 211.12 1.00

Incinerator, Waste explosives 1 VOC Benzene A3-v1 2.73E-01 3.11E-01 4.94E-01 1.50E-02 lbs/ton 1 88.38 219.56 1.00

Incinerator, Waste explosives 1 VOC Methylene Chloride C3-v0 7.52E-02 8.33E-02 1.10E-01 3.22E-02 lbs/ton 1 52.51 130.44 1.00

166

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Incinerator, Waste explosives 1 VOC Toluene A3-v1 1.17E-01 1.20E-01 2.22E-01 9.17E-03 lbs/ton 1 90.92 225.86 1.00

Incinerator, Waste explosives 1 VOC Vinyl Chloride A3-v0 1.15E-01 1.00E-01 1.73E-01 7.10E-02 lbs/ton 1 45.76 113.67 0.00

Incinerator, Waste Gas 1 VOC Benzene C3-v0 8.27E+01 8.43E+01 1.10E+02 5.38E+01 lbs/MMcf 1 33.96 84.37 1.00

Incinerator, Waste Gas 1 VOC Hydrogen Sulfide C3-v0 5.35E+02 5.35E+02 6.12E+02 4.59E+02 lbs/MMcf 1 20.20 181.52 1.00

Incinerator, Waste Gas 1 VOC Toluene C3-v0 6.99E+01 6.90E+01 9.37E+01 4.70E+01 lbs/MMcf 1 33.40 82.98 1.00

Incinerator, Waste Gas 1 VOC Xylene (Total) C3-v0 2.65E+01 2.85E+01 3.82E+01 1.26E+01 lbs/MMcf 1 48.83 121.30 1.00

Oven, Curing Tools 1 VOC Formaldehyde A3-v0 3.64E-02 3.90E-02 4.20E-02 2.84E-02 lbs/ton processed 1 19.59 48.67 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin/Furan:Total A3-v0 9.93E-06 8.50E-06 1.58E-05 5.46E-06 lbs/ton charged 1 53.64 133.26 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 7.78E-09 4.69E-09 1.46E-08 4.05E-09 lbs/ton charged 1 75.99 188.76 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:4D Total A3-v1 1.18E-06 1.25E-06 1.99E-06 3.06E-07 lbs/ton charged 1 71.36 177.26 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:5D 12378 A3-v1 2.36E-08 1.19E-08 4.91E-08 9.78E-09 lbs/ton charged 1 93.76 232.92 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:5D Total A3-v1 9.07E-07 6.86E-07 1.72E-06 3.11E-07 lbs/ton charged 1 80.69 200.45 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:6D 123478 A3-v1 1.55E-08 7.28E-09 3.49E-08 4.42E-09 lbs/ton charged 1 108.32 269.08 0.75

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:6D 123678 A3-v1 2.78E-08 1.43E-08 6.56E-08 3.48E-09 lbs/ton charged 1 119.35 296.47 0.79

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:6D 123789 A3-v1 1.91E-08 7.28E-09 4.60E-08 3.88E-09 lbs/ton charged 1 122.81 305.07 0.80

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:6D Total A3-v0 7.48E-07 5.41E-07 1.42E-06 2.88E-07 lbs/ton charged 1 79.07 196.43 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 1.67E-07 8.11E-08 3.40E-07 7.91E-08 lbs/ton charged 1 90.03 223.64 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:7D Total A3-v0 3.31E-07 1.69E-07 6.64E-07 1.60E-07 lbs/ton charged 1 87.13 216.45 1.00

Oven, Wire Coatings 1 Dioxin/Furan Dioxin:8D A3-v0 2.38E-07 1.56E-07 4.29E-07 1.28E-07 lbs/ton charged 1 69.99 173.88 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:4F 2378 A3-v0 9.35E-08 8.32E-08 1.24E-07 7.36E-08 lbs/ton charged 1 28.49 70.78 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:4F Total A3-v0 2.94E-06 3.11E-06 4.47E-06 1.23E-06 lbs/ton charged 1 55.33 137.44 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:5F 12378 A3-v0 9.72E-08 8.96E-08 1.42E-07 6.03E-08 lbs/ton charged 1 42.35 105.20 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:5F 23478 A3-v0 8.38E-08 9.14E-08 1.33E-07 2.73E-08 lbs/ton charged 1 63.40 157.50 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:5F Total A3-v0 4.02E-06 2.91E-06 6.86E-06 2.29E-06 lbs/ton charged 1 61.74 153.36 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:6F 123478 A3-v1 1.54E-07 1.60E-07 2.51E-07 4.99E-08 lbs/ton charged 1 65.57 162.88 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:6F 123678 A3-v1 1.08E-07 1.23E-07 1.68E-07 3.14E-08 lbs/ton charged 1 64.76 160.88 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:6F 123789 A3-v0 1.57E-08 2.10E-08 2.12E-08 4.91E-09 lbs/ton charged 1 59.59 148.03 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:6F 234678 A3-v0 1.25E-07 1.50E-07 1.78E-07 4.58E-08 lbs/ton charged 1 55.99 139.09 1.00

167

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Oven, Wire Coatings 1 Dioxin/Furan Furan:6F Total A3-v0 1.19E-06 1.37E-06 1.59E-06 6.03E-07 lbs/ton charged 1 43.65 108.43 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:7F 1234678 A3-v0 2.79E-07 3.58E-07 3.66E-07 1.13E-07 lbs/ton charged 1 51.65 128.30 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:7F 1234789 A3-v0 2.10E-08 1.60E-08 3.80E-08 9.15E-09 lbs/ton charged 1 71.62 177.90 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:7F Total A3-v0 3.85E-07 4.80E-07 5.53E-07 1.23E-07 lbs/ton charged 1 59.70 148.30 1.00

Oven, Wire Coatings 1 Dioxin/Furan Furan:8F A3-v0 4.66E-08 4.30E-08 6.73E-08 2.96E-08 lbs/ton charged 1 41.03 101.91 1.00

Oven, Wire Coatings 1 Halogens HCl C3-v0 1.58E+00 1.82E+00 2.13E+00 7.88E-01 lbs/ton charged 1 44.57 110.72 1.00

Oven, Wire Coatings 1 Metals Arsenic D3-v1 3.47E-02 4.47E-02 5.67E-02 2.78E-03 lbs/ton charged 1 81.52 202.51 0.03

Oven, Wire Coatings 1 Metals Beryllium D3-v0 3.05E-04 3.04E-04 3.59E-04 2.53E-04 lbs/ton charged 1 17.35 43.11 0.00

Oven, Wire Coatings 1 Metals Cadmium D3-v2 4.87E-02 3.83E-03 1.41E-01 1.00E-03 lbs/ton charged 1 164.65 409.01 1.00

Oven, Wire Coatings 1 Metals Chromium (Total) D3-v0 1.39E-03 1.43E-03 1.60E-03 1.15E-03 lbs/ton charged 1 16.59 41.20 1.00

Oven, Wire Coatings 1 Metals Copper D3-v0 9.23E-03 8.48E-03 1.16E-02 7.60E-03 lbs/ton charged 1 22.77 56.56 1.00

Oven, Wire Coatings 1 Metals Lead D3-v0 1.32E-02 1.51E-02 1.78E-02 6.70E-03 lbs/ton charged 1 43.78 108.75 1.00

Oven, Wire Coatings 1 Metals Manganese D3-v1 8.97E-02 8.48E-02 1.81E-01 3.76E-03 lbs/ton charged 1 98.64 245.04 1.00

Oven, Wire Coatings 1 Metals Mercury D3-v1 4.83E-04 7.07E-05 1.32E-03 6.42E-05 lbs/ton charged 1 149.04 370.24 1.00

Oven, Wire Coatings 1 Metals Nickel D3-v0 2.89E-03 2.78E-03 4.49E-03 1.41E-03 lbs/ton charged 1 53.23 132.24 1.00

Oven, Wire Coatings 1 Metals Selenium D3-v0 9.52E-04 8.62E-04 1.24E-03 7.54E-04 lbs/ton charged 1 26.80 66.58 0.43

Oven, Wire Coatings 1 Metals Zinc D3-v0 4.75E-01 5.34E-01 5.42E-01 3.50E-01 lbs/ton charged 1 22.85 56.77 1.00

Oven, Wire Coatings 1 PAH Acenaphthene C3-v0 1.69E-04 1.24E-04 2.92E-04 9.16E-05 lbs/ton charged 1 63.72 158.29 1.00

Oven, Wire Coatings 1 PAH Acenaphthylene C3-v0 9.66E-05 6.79E-05 1.84E-04 3.74E-05 lbs/ton charged 1 80.31 199.51 1.00

Oven, Wire Coatings 1 PAH Anthracene C3-v0 4.10E-05 3.51E-05 6.26E-05 2.53E-05 lbs/ton charged 1 47.27 117.42 1.00

Oven, Wire Coatings 1 PAH Benzo(a)anthracene C3-v0 2.85E-05 2.80E-05 4.17E-05 1.57E-05 lbs/ton charged 1 45.81 113.79 0.49

Oven, Wire Coatings 1 PAH Benzo(a)pyrene C3-v1 4.68E-05 4.92E-05 7.65E-05 1.48E-05 lbs/ton charged 1 65.99 163.93 0.00

Oven, Wire Coatings 1 PAH Benzo(b)fluoranthene C3-v0 3.25E-05 3.51E-05 4.52E-05 1.73E-05 lbs/ton charged 1 43.34 107.66 0.00

Oven, Wire Coatings 1 PAH Benzo(g,h,i)perylene C3-v0 6.77E-05 7.25E-05 1.08E-04 2.27E-05 lbs/ton charged 1 63.24 157.10 0.00

Oven, Wire Coatings 1 PAH Benzo(k)fluoranthene C3-v0 3.64E-05 3.98E-05 5.22E-05 1.73E-05 lbs/ton charged 1 48.45 120.36 0.00

Oven, Wire Coatings 1 PAH Chrysene C3-v0 2.82E-05 3.13E-05 3.51E-05 1.83E-05 lbs/ton charged 1 31.10 77.25 0.37

Oven, Wire Coatings 1 PAH Dibenz(a,h)anthracene C3-v0 3.82E-05 4.17E-05 4.68E-05 2.62E-05 lbs/ton charged 1 28.15 69.93 0.00

Oven, Wire Coatings 1 PAH Fluoranthene C3-v0 1.44E-04 1.28E-04 2.47E-04 5.74E-05 lbs/ton charged 1 66.41 164.97 1.00

168

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Oven, Wire Coatings 1 PAH Fluorene C3-v0 2.24E-04 2.29E-04 3.23E-04 1.19E-04 lbs/ton charged 1 45.65 113.40 1.00

Oven, Wire Coatings 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 5.18E-05 2.93E-05 9.74E-05 2.87E-05 lbs/ton charged 1 76.26 189.44 0.19

Oven, Wire Coatings 1 PAH Naphthalene C3-v1 5.55E-03 5.15E-03 9.76E-03 1.74E-03 lbs/ton charged 1 72.46 180.01 1.00

Oven, Wire Coatings 1 PAH Phenanthrene C3-v0 8.46E-04 7.02E-04 1.36E-03 4.78E-04 lbs/ton charged 1 54.02 134.20 1.00

Oven, Wire Coatings 1 PAH Pyrene C3-v1 1.04E-04 7.48E-05 2.02E-04 3.66E-05 lbs/ton charged 1 82.82 205.74 1.00

Oven, Wire Coatings 1 VOC Benzene A3-v0 2.90E-03 3.66E-03 3.71E-03 1.34E-03 lbs/ton charged 1 46.69 115.98 1.00

Oven, Wire Coatings 1 VOC Formaldehyde C3-v1 9.83E-02 5.01E-02 2.07E-01 3.79E-02 lbs/ton charged 1 95.96 238.39 1.00

Oven, Wire Coatings 1 VOC Vinyl Chloride A3-v1 3.55E-05 3.38E-05 6.25E-05 1.02E-05 lbs/ton charged 1 73.79 183.32 0.90

Plating, Anodizing 1 Metals Chromium (Hex) B2-v2 2.52E-01 1.44E-01 7.51E-01 7.12E-03 mg/amp-hr 3 103.86 74.30 1.00

Plating, Anodizing 1 Metals Chromium (Total) C1-v2 2.48E-01 1.40E-01 1.08E+00 1.64E-02 mg/amp-hr 5 124.40 68.89 1.00

Plating, Anodizing 2 Metals Chromium (Hex) C3-v0 4.15E-02 4.15E-02 4.22E-02 4.09E-02 mg/amp-hr 1 2.27 20.36 0.00

Plating, Anodizing 2 Metals Chromium (Total) C3-v0 4.14E-03 4.13E-03 4.41E-03 3.92E-03 mg/amp-hr 1 5.02 7.99 0.00

Plating, Decorative 1 Metals Chromium (Hex) C3-v0 4.71E+00 4.75E+00 4.78E+00 4.62E+00 mg/amp-hr 1 1.73 4.30 0.00

Plating, Decorative 1 Metals Chromium (Total) C3-v1 3.60E+00 3.88E+00 6.33E+00 5.93E-01 mg/amp-hr 1 79.93 198.57 1.00

Plating, Decorative 1 Metals Copper D3-v1 7.49E+02 9.66E+02 1.12E+03 1.63E+02 mg/amp-hr 1 68.51 170.19 1.00

Plating, Decorative 1 Metals Lead D3-v0 1.22E+02 1.29E+02 1.53E+02 8.42E+01 mg/amp-hr 1 28.64 71.14 1.00

Plating, Decorative 1 Metals Nickel D3-v0 1.43E+02 1.18E+02 2.18E+02 9.47E+01 mg/amp-hr 1 45.60 113.27 1.00

Plating, Decorative 2 Metals Chromium (Hex) B3-v1 8.48E-05 1.38E-05 2.29E-04 1.16E-05 mg/amp-hr 1 147.26 365.81 1.00

Plating, Decorative 2 Metals Chromium (Total) B3-v0 2.48E-03 2.37E-03 2.77E-03 2.32E-03 mg/amp-hr 1 9.92 24.63 1.00

Plating, Hard 1 Metals Chromium (Hex) B1-v2 2.44E-02 1.04E-02 2.24E-01 1.23E-03 mg/amp-hr 23 177.44 43.47 0.93

Plating, Hard 1 Metals Chromium (Total) B1-v2 3.92E-02 2.53E-02 2.64E-01 1.95E-03 mg/amp-hr 28 121.98 26.90 0.93

Plating, Hard 2 Metals Chromium (Hex) B1-v2 6.19E-03 2.96E-03 3.77E-02 2.88E-04 mg/amp-hr 11 148.36 52.23 0.92

Plating, Hard 2 Metals Chromium (Total) B1-v2 1.02E-02 6.07E-03 8.95E-02 3.10E-04 mg/amp-hr 11 167.83 57.26 0.94

Plating, Hard 3 Metals Chromium (Total) C3-v0 1.66E+00 1.66E+00 1.83E+00 1.48E+00 mg/amp-hr 1 10.54 26.18 1.00

Plating, Hard/Anodizing 1 Metals Chromium (Hex) B2-v1 2.45E-02 1.65E-02 5.68E-02 7.91E-03 mg/amp-hr 3 72.23 55.52 1.00

Plating, Hard/Anodizing 1 Metals Chromium (Total) B2-v1 2.45E-02 2.23E-02 4.66E-02 5.64E-03 mg/amp-hr 3 71.03 54.60 1.00

PM, Devolatizer 1 SVOC Ethylbenzene C3-v- 4.09E-06 4.09E-06 4.09E-06 4.09E-06 lbs/lbs production 1 0.00 0.00 1.00

PM, Devolatizer 1 VOC Benzene C3-v- 1.29E-09 1.29E-09 1.29E-09 1.29E-09 lbs/lbs production 1 0.00 0.00 0.00

169

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

PM, Devolatizer 1 VOC Styrene C3-v- 2.36E-05 2.36E-05 2.36E-05 2.36E-05 lbs/lbs production 1 0.00 0.00 1.00

PM, Devolatizer 1 VOC Toluene C3-v- 2.98E-07 2.98E-07 2.98E-07 2.98E-07 lbs/lbs production 1 0.00 0.00 1.00

PM, Devolatizer 1 VOC Xylene (m,p) C3-v- 1.96E-07 1.96E-07 1.96E-07 1.96E-07 lbs/lbs production 1 0.00 0.00 1.00

PM, Devolatizer 1 VOC Xylene (o) C3-v- 6.22E-08 6.22E-08 6.22E-08 6.22E-08 lbs/lbs production 1 0.00 0.00 1.00

PM, Extruder 1 SVOC Ethylbenzene C3-v- 1.11E-06 1.11E-06 1.11E-06 1.11E-06 lbs/lbs production 1 0.00 0.00 1.00

PM, Extruder 1 VOC Benzene C3-v- 1.11E-07 1.11E-07 1.11E-07 1.11E-07 lbs/lbs production 1 0.00 0.00 0.00

PM, Extruder 1 VOC Styrene C3-v- 1.53E-05 1.53E-05 1.53E-05 1.53E-05 lbs/lbs production 1 0.00 0.00 1.00

PM, Extruder 1 VOC Toluene C3-v- 2.34E-07 2.34E-07 2.34E-07 2.34E-07 lbs/lbs production 1 0.00 0.00 1.00

PM, Extruder 1 VOC Xylene (m,p) C3-v- 1.53E-07 1.53E-07 1.53E-07 1.53E-07 lbs/lbs production 1 0.00 0.00 0.00

PM, Extruder 1 VOC Xylene (o) C3-v- 1.53E-07 1.53E-07 1.53E-07 1.53E-07 lbs/lbs production 1 0.00 0.00 0.00

PM, Mix Tank 1 SVOC Ethylbenzene C3-v- 4.35E-08 4.35E-08 4.35E-08 4.35E-08 lbs/lbs production 1 0.00 0.00 1.00

PM, Mix Tank 1 VOC Benzene C3-v- 2.75E-09 2.75E-09 2.75E-09 2.75E-09 lbs/lbs production 1 0.00 0.00 0.00

PM, Mix Tank 1 VOC Styrene C3-v- 2.41E-05 2.41E-05 2.41E-05 2.41E-05 lbs/lbs production 1 0.00 0.00 1.00

PM, Mix Tank 1 VOC Toluene C3-v- 2.75E-09 2.75E-09 2.75E-09 2.75E-09 lbs/lbs production 1 0.00 0.00 1.00

PM, Mix Tank 1 VOC Xylene (m,p) C3-v- 3.67E-09 3.67E-09 3.67E-09 3.67E-09 lbs/lbs production 1 0.00 0.00 0.00

PM, Mix Tank 1 VOC Xylene (o) C3-v- 3.67E-09 3.67E-09 3.67E-09 3.67E-09 lbs/lbs production 1 0.00 0.00 0.00

PM, Reactor 1 SVOC Ethylbenzene D3-v1 2.43E-07 2.05E-08 6.90E-07 1.97E-08 lbs/lbs production 2 158.91 394.76 1.00

PM, Reactor 1 VOC Benzene C3-v- 2.76E-09 2.76E-09 2.76E-09 2.76E-09 lbs/lbs production 1 0.00 0.00 0.00

PM, Reactor 1 VOC Styrene D3-v2 8.41E-06 2.07E-07 2.48E-05 1.96E-07 lbs/lbs production 2 169.06 419.97 1.00

PM, Reactor 1 VOC Toluene C3-v- 4.37E-08 4.37E-08 4.37E-08 4.37E-08 lbs/lbs production 1 0.00 0.00 1.00

PM, Reactor 1 VOC Xylene (m,p) C3-v- 2.00E-08 2.00E-08 2.00E-08 2.00E-08 lbs/lbs production 1 0.00 0.00 1.00

PM, Reactor 1 VOC Xylene (o) C3-v- 3.68E-09 3.68E-09 3.68E-09 3.68E-09 lbs/lbs production 1 0.00 0.00 0.00

PM, Storage Silo 1 SVOC Ethylbenzene E3-v2 5.60E-06 3.27E-06 1.58E-05 4.18E-08 lbs/lbs production 2 132.78 211.28 1.00

PM, Storage Silo 1 VOC Styrene D3-v3 2.87E-05 6.37E-08 7.38E-05 5.99E-08 lbs/lbs production 2 136.73 169.77 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:4D 2378 A3-v0 3.14E-11 2.37E-11 4.81E-11 2.23E-11 lbs/ton production 1 46.28 114.96 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:4D Total A3-v0 3.29E-10 3.31E-10 4.09E-10 2.46E-10 lbs/ton production 1 24.85 61.73 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:5D 12378 A3-v0 8.61E-11 7.10E-11 1.20E-10 6.70E-11 lbs/ton production 1 34.48 85.65 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:5D Total A3-v1 3.64E-10 3.57E-10 6.15E-10 1.20E-10 lbs/ton production 1 67.93 168.76 1.00

170

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123478 A3-v0 2.43E-10 2.13E-10 3.37E-10 1.79E-10 lbs/ton production 1 34.26 85.11 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123678 A3-v0 4.62E-10 4.02E-10 6.26E-10 3.57E-10 lbs/ton production 1 31.11 77.28 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:6D 123789 A3-v0 9.87E-10 9.23E-10 1.32E-09 7.15E-10 lbs/ton production 1 31.34 77.84 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:6D Total A3-v0 4.34E-09 3.78E-09 7.22E-09 2.01E-09 lbs/ton production 1 61.03 151.60 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:7D 1234678 A3-v0 1.02E-08 1.16E-08 1.20E-08 6.92E-09 lbs/ton production 1 27.79 69.03 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:7D Total A3-v0 1.93E-08 2.15E-08 2.41E-08 1.23E-08 lbs/ton production 1 32.12 79.80 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Dioxin:8D A3-v0 5.19E-08 5.32E-08 6.01E-08 4.24E-08 lbs/ton production 1 17.13 42.55 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:4F 2378 A3-v0 2.49E-09 1.87E-09 4.09E-09 1.52E-09 lbs/ton production 1 55.94 138.96 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:4F Total A3-v0 1.11E-08 8.52E-09 1.88E-08 6.03E-09 lbs/ton production 1 60.79 151.01 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:5F 12378 A3-v0 8.57E-10 8.04E-10 1.06E-09 7.10E-10 lbs/ton production 1 21.04 52.28 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:5F 23478 A3-v0 1.39E-09 1.37E-09 1.92E-09 8.71E-10 lbs/ton production 1 37.93 94.22 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:5F Total A3-v0 1.05E-08 1.09E-08 1.37E-08 6.92E-09 lbs/ton production 1 32.45 80.62 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:6F 123478 A3-v0 4.54E-09 4.73E-09 5.77E-09 3.13E-09 lbs/ton production 1 29.34 72.88 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:6F 123678 A3-v0 2.05E-09 2.11E-09 2.65E-09 1.38E-09 lbs/ton production 1 30.94 76.85 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:6F 123789 A3-v0 4.31E-10 4.97E-10 5.05E-10 2.90E-10 lbs/ton production 1 28.24 70.16 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:6F 234678 A3-v0 6.43E-09 7.33E-09 7.70E-09 4.24E-09 lbs/ton production 1 29.54 73.37 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:6F Total A3-v0 2.26E-08 2.65E-08 2.65E-08 1.50E-08 lbs/ton production 1 29.36 72.93 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:7F 1234678 A3-v0 1.75E-08 1.94E-08 2.24E-08 1.07E-08 lbs/ton production 1 34.60 85.95 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:7F 1234789 A3-v0 6.34E-09 7.22E-09 7.33E-09 4.47E-09 lbs/ton production 1 25.59 63.56 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:7F Total A3-v0 4.25E-08 4.73E-08 5.44E-08 2.59E-08 lbs/ton production 1 34.84 86.56 1.00

Preheater Kiln, Coal 1 Dioxin/Furan Furan:8F A3-v0 1.03E-07 9.82E-08 1.30E-07 8.11E-08 lbs/ton production 1 24.24 60.21 1.00

Preheater Kiln, Coal 1 Metals Arsenic D3-v0 3.87E-05 3.89E-05 4.01E-05 3.72E-05 lbs/ton production 1 3.85 9.57 0.00

Preheater Kiln, Coal 1 Metals Beryllium D3-v0 1.54E-05 1.56E-05 1.57E-05 1.49E-05 lbs/ton production 1 2.96 7.35 0.00

Preheater Kiln, Coal 1 Metals Cadmium D3-v0 1.05E-05 9.85E-06 1.34E-05 8.20E-06 lbs/ton production 1 25.16 62.51 1.00

Preheater Kiln, Coal 1 Metals Chromium (Hex) A3-v0 7.00E-05 7.17E-05 7.80E-05 6.04E-05 lbs/ton production 1 12.71 31.57 1.00

Preheater Kiln, Coal 1 Metals Chromium (Total) A3-v0 1.12E-04 7.80E-05 1.88E-04 7.10E-05 lbs/ton production 1 58.25 144.70 1.00

Preheater Kiln, Coal 1 Metals Copper D3-v1 1.06E-04 4.42E-05 2.33E-04 4.07E-05 lbs/ton production 1 103.71 257.64 1.00

Preheater Kiln, Coal 1 Metals Lead D3-v0 4.57E-05 3.92E-05 5.89E-05 3.90E-05 lbs/ton production 1 24.95 61.98 0.00

171

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Preheater Kiln, Coal 1 Metals Manganese D3-v0 2.55E-04 1.68E-04 4.43E-04 1.54E-04 lbs/ton production 1 63.93 158.82 0.00

Preheater Kiln, Coal 1 Metals Mercury D3-v0 2.23E-04 2.44E-04 2.61E-04 1.64E-04 lbs/ton production 1 23.11 57.41 0.00

Preheater Kiln, Coal 1 Metals Nickel D3-v0 5.11E-05 4.49E-05 6.92E-05 3.92E-05 lbs/ton production 1 31.18 77.45 0.00

Preheater Kiln, Coal 1 Metals Selenium D3-v0 4.09E-05 3.92E-05 4.63E-05 3.72E-05 lbs/ton production 1 11.79 29.28 0.00

Preheater Kiln, Coal 1 Metals Zinc D3-v0 8.09E-04 8.93E-04 1.07E-03 4.65E-04 lbs/ton production 1 38.39 95.36 1.00

Preheater Kiln, Coal 1 PAH Acenaphthene C3-v0 3.57E-07 2.31E-07 6.69E-07 1.71E-07 lbs/ton production 1 76.13 189.13 1.00

Preheater Kiln, Coal 1 PAH Acenaphthylene C3-v1 7.57E-07 3.28E-07 1.68E-06 2.63E-07 lbs/ton production 1 105.67 262.49 1.00

Preheater Kiln, Coal 1 PAH Anthracene C3-v2 9.30E-08 9.62E-10 2.77E-07 9.46E-10 lbs/ton production 1 171.43 425.85 0.99

Preheater Kiln, Coal 1 PAH Benzo(a)anthracene C3-v0 1.64E-07 8.40E-08 3.32E-07 7.57E-08 lbs/ton production 1 88.86 220.75 1.00

Preheater Kiln, Coal 1 PAH Benzo(a)pyrene C3-v0 2.91E-08 2.08E-08 4.88E-08 1.77E-08 lbs/ton production 1 58.88 146.27 1.00

Preheater Kiln, Coal 1 PAH Benzo(b)fluoranthene C3-v0 2.05E-07 1.24E-07 3.90E-07 1.02E-07 lbs/ton production 1 77.93 193.58 1.00

Preheater Kiln, Coal 1 PAH Benzo(e)pyrene C3-v0 5.96E-08 4.11E-08 1.04E-07 3.41E-08 lbs/ton production 1 64.29 159.71 1.00

Preheater Kiln, Coal 1 PAH Benzo(g,h,i)perylene C3-v0 7.06E-08 6.50E-08 9.72E-08 4.97E-08 lbs/ton production 1 34.34 85.31 1.00

Preheater Kiln, Coal 1 PAH Benzo(k)fluoranthene C3-v0 4.67E-10 4.73E-10 4.81E-10 4.47E-10 lbs/ton production 1 3.85 9.57 0.00

Preheater Kiln, Coal 1 PAH Chrysene C3-v0 5.19E-07 2.90E-07 1.02E-06 2.48E-07 lbs/ton production 1 83.37 207.10 1.00

Preheater Kiln, Coal 1 PAH Dibenz(a,h)anthracene C3-v0 2.77E-08 2.81E-08 3.85E-08 1.63E-08 lbs/ton production 1 40.12 99.65 1.00

Preheater Kiln, Coal 1 PAH Fluoranthene C3-v0 2.89E-06 1.46E-06 5.94E-06 1.26E-06 lbs/ton production 1 91.74 227.90 1.00

Preheater Kiln, Coal 1 PAH Fluorene C3-v0 9.44E-07 5.30E-07 1.88E-06 4.22E-07 lbs/ton production 1 86.09 213.87 1.00

Preheater Kiln, Coal 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 8.25E-08 7.08E-08 1.33E-07 4.42E-08 lbs/ton production 1 54.90 136.39 1.00

Preheater Kiln, Coal 1 PAH Naphthalene C3-v1 7.74E-05 3.87E-05 1.87E-04 6.48E-06 lbs/ton production 1 124.45 309.16 1.00

Preheater Kiln, Coal 1 PAH Phenanthrene C3-v0 7.06E-06 5.96E-06 9.84E-06 5.37E-06 lbs/ton production 1 34.39 85.44 1.00

Preheater Kiln, Coal 1 PAH Pyrene C3-v1 2.44E-06 1.22E-06 5.12E-06 9.70E-07 lbs/ton production 1 95.62 237.53 1.00

Preheater Kiln, Coal 1 Particulate Particulate E3-v0 2.10E-01 1.62E-01 3.51E-01 1.17E-01 lbs/ton production 1 59.15 146.94 0.56

Preheater Kiln, Coal 1 SVOC 2-Chloronaphthalene C3-v0 1.55E-07 1.05E-07 2.79E-07 8.00E-08 lbs/ton production 1 70.12 174.19 1.00

Preheater Kiln, Coal 1 SVOC 2-Methylnaphthalene C3-v0 4.81E-06 2.57E-06 9.31E-06 2.55E-06 lbs/ton production 1 80.98 201.17 1.00

Preheater Kiln, Coal 1 SVOC Perylene C3-v1 8.84E-09 5.36E-09 2.00E-08 1.18E-09 lbs/ton production 1 111.61 277.26 0.96

Presser, Fiberboard 1 VOC Formaldehyde A3-v0 6.60E-02 6.89E-02 9.15E-02 3.75E-02 lbs/ton production 1 41.12 102.14 1.00

Reboiler, Ethylene Glycol 1 SVOC Ethylbenzene C3-v0 7.29E-03 7.23E-03 9.15E-03 5.49E-03 lbs/MMcf 1 25.12 62.41 1.00

172

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Reboiler, Ethylene Glycol 1 VOC Benzene C3-v0 2.45E-01 2.43E-01 2.83E-01 2.09E-01 lbs/MMcf 1 15.16 37.66 1.00

Reboiler, Ethylene Glycol 1 VOC Formaldehyde C3-v0 3.79E-05 3.28E-05 4.90E-05 3.20E-05 lbs/MMcf 1 25.40 63.09 1.00

Reboiler, Ethylene Glycol 1 VOC Hydrogen Sulfide C3-v1 5.49E-02 2.94E-02 1.15E-01 2.07E-02 lbs/MMcf 1 94.42 234.56 1.00

Reboiler, Ethylene Glycol 1 VOC Toluene C3-v0 1.64E-01 1.51E-01 1.92E-01 1.51E-01 lbs/MMcf 1 14.68 36.46 1.00

Reboiler, Ethylene Glycol 1 VOC Xylene (m) C3-v0 1.67E-02 1.64E-02 2.31E-02 1.06E-02 lbs/MMcf 1 37.54 93.25 1.00

Reboiler, Ethylene Glycol 1 VOC Xylene (o) C3-v0 6.36E-03 6.65E-03 8.58E-03 3.85E-03 lbs/MMcf 1 37.33 92.73 1.00

Reboiler, Ethylene Glycol 1 VOC Xylene (p) C3-v0 6.14E-03 6.26E-03 7.81E-03 4.34E-03 lbs/MMcf 1 28.33 70.38 1.00

Reboiler, Triethylene Glycol 1 SVOC Ethylbenzene C3-v0 2.69E-02 2.74E-02 2.88E-02 2.45E-02 lbs/MMcf 1 8.18 20.33 1.00

Reboiler, Triethylene Glycol 1 VOC Benzene C3-v0 1.51E-01 1.41E-01 1.92E-01 1.21E-01 lbs/MMcf 1 24.04 59.71 1.00

Reboiler, Triethylene Glycol 1 VOC Formaldehyde C3-v1 3.50E-05 2.20E-05 6.97E-05 1.33E-05 lbs/MMcf 1 86.74 215.48 1.00

Reboiler, Triethylene Glycol 1 VOC Hydrogen Sulfide C3-v0 4.42E-03 3.75E-03 6.49E-03 3.01E-03 lbs/MMcf 1 41.43 102.93 1.00

Reboiler, Triethylene Glycol 1 VOC Toluene C3-v0 1.75E-01 1.63E-01 2.00E-01 1.63E-01 lbs/MMcf 1 12.37 30.73 1.00

Reboiler, Triethylene Glycol 1 VOC Xylene (m) C3-v0 3.56E-02 3.61E-02 3.75E-02 3.32E-02 lbs/MMcf 1 6.19 15.38 1.00

Reboiler, Triethylene Glycol 1 VOC Xylene (o) C3-v0 2.50E-02 2.60E-02 2.60E-02 2.31E-02 lbs/MMcf 1 6.66 16.55 1.00

Reboiler, Triethylene Glycol 1 VOC Xylene (p) C3-v0 1.32E-02 1.33E-02 1.41E-02 1.23E-02 lbs/MMcf 1 7.10 17.63 1.00

Roaster, Green beans 1 VOC Acrolein C3-v0 1.21E-04 1.21E-04 1.23E-04 1.20E-04 lbs/ton production 1 1.32 3.29 0.00

SG, Crude Oil 1 Halogens HCl C3-v0 1.90E-04 1.83E-04 2.09E-04 1.77E-04 lbs/Mgal 1 8.92 22.16 1.00

SG, Crude Oil 1 Metals Arsenic D2-v1 9.97E-04 6.35E-04 2.85E-03 3.58E-04 lbs/Mgal 3 83.25 63.99 1.00

SG, Crude Oil 1 Metals Beryllium D2-v1 2.08E-04 2.40E-04 3.19E-04 4.71E-05 lbs/Mgal 3 58.45 44.93 0.47

SG, Crude Oil 1 Metals Cadmium D2-v1 1.63E-04 1.46E-04 5.45E-04 2.40E-05 lbs/Mgal 3 100.53 77.27 1.00

SG, Crude Oil 1 Metals Chromium (Hex) B2-v1 1.65E-04 1.50E-04 3.36E-04 5.73E-05 lbs/Mgal 3 55.52 42.68 0.47

SG, Crude Oil 1 Metals Chromium (Total) B2-v1 8.58E-04 5.76E-04 2.16E-03 1.53E-04 lbs/Mgal 3 84.23 64.74 1.00

SG, Crude Oil 1 Metals Copper D2-v0 9.93E-04 9.31E-04 1.84E-03 4.78E-04 lbs/Mgal 3 47.12 36.22 1.00

SG, Crude Oil 1 Metals Lead D2-v0 2.83E-04 2.60E-04 4.90E-04 1.79E-04 lbs/Mgal 3 33.44 25.71 0.52

SG, Crude Oil 1 Metals Manganese D2-v1 3.02E-03 2.81E-03 5.73E-03 2.44E-04 lbs/Mgal 3 63.89 59.09 1.00

SG, Crude Oil 1 Metals Mercury D2-v3 2.19E-03 5.18E-05 5.17E-03 8.63E-06 lbs/Mgal 3 122.81 113.58 1.00

SG, Crude Oil 1 Metals Nickel D2-v0 3.61E-01 3.58E-01 4.01E-01 3.26E-01 lbs/Mgal 3 5.82 4.48 1.00

SG, Crude Oil 1 Metals Phosphorus D3-v1 2.65E-02 1.45E-02 6.78E-02 2.73E-03 lbs/Mgal 2 101.41 106.42 1.00

173

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

SG, Crude Oil 1 Metals Selenium D2-v1 1.18E-03 4.44E-04 3.09E-03 1.79E-04 lbs/Mgal 3 107.66 82.76 0.96

SG, Crude Oil 1 Metals Zinc D2-v2 8.11E-02 2.87E-02 2.60E-01 2.40E-03 lbs/Mgal 3 127.20 97.77 0.94

SG, Crude Oil 1 PAH Acenaphthene C3-v2 3.80E-05 2.07E-05 9.22E-05 1.07E-06 lbs/Mgal 2 110.99 116.47 1.00

SG, Crude Oil 1 PAH Acenaphthylene C2-v2 7.48E-06 6.56E-06 1.79E-05 2.13E-07 lbs/Mgal 3 83.42 64.12 0.47

SG, Crude Oil 1 PAH Anthracene C2-v2 7.69E-06 3.14E-06 2.51E-05 3.20E-07 lbs/Mgal 3 134.01 112.03 1.00

SG, Crude Oil 1 PAH Benzo(a)anthracene C2-v1 7.74E-06 8.22E-06 1.49E-05 5.34E-07 lbs/Mgal 3 72.06 60.25 0.42

SG, Crude Oil 1 PAH Benzo(a)pyrene C3-v1 8.03E-06 9.50E-06 1.25E-05 5.34E-07 lbs/Mgal 2 60.41 63.40 0.24

SG, Crude Oil 1 PAH Benzo(b)fluoranthene C3-v1 7.11E-06 4.27E-06 1.60E-05 1.07E-06 lbs/Mgal 1 110.57 274.66 0.00

SG, Crude Oil 1 PAH Benzo(b+k)fluoranthene C3-v0 1.20E-05 1.19E-05 1.25E-05 1.15E-05 lbs/Mgal 1 4.07 10.12 0.00

SG, Crude Oil 1 PAH Benzo(g,h,i)perylene C3-v1 7.76E-06 8.96E-06 1.25E-05 1.07E-06 lbs/Mgal 2 63.37 66.51 0.21

SG, Crude Oil 1 PAH Benzo(k)fluoranthene C3-v1 6.05E-07 5.34E-07 1.07E-06 2.13E-07 lbs/Mgal 1 71.32 177.17 0.00

SG, Crude Oil 1 PAH Chrysene C2-v1 1.12E-05 1.15E-05 3.45E-05 1.07E-06 lbs/Mgal 3 93.50 71.87 0.64

SG, Crude Oil 1 PAH Dibenz(a,h)anthracene C3-v1 7.94E-06 9.50E-06 1.25E-05 1.07E-06 lbs/Mgal 2 61.45 64.49 0.00

SG, Crude Oil 1 PAH Fluoranthene C2-v1 1.31E-05 1.15E-05 5.23E-05 1.07E-06 lbs/Mgal 3 116.13 89.26 0.70

SG, Crude Oil 1 PAH Fluorene C2-v1 1.42E-05 7.13E-06 4.59E-05 1.07E-06 lbs/Mgal 3 116.91 89.86 1.00

SG, Crude Oil 1 PAH Indeno(1,2,3-cd)pyrene C3-v1 7.94E-06 1.00E-05 1.25E-05 1.07E-06 lbs/Mgal 2 64.32 67.50 0.22

SG, Crude Oil 1 PAH Naphthalene C2-v1 7.96E-04 4.51E-04 1.62E-03 2.12E-04 lbs/Mgal 3 81.32 67.99 1.00

SG, Crude Oil 1 PAH Phenanthrene C2-v2 2.49E-05 6.99E-06 1.62E-04 2.20E-06 lbs/Mgal 3 208.44 160.22 1.00

SG, Crude Oil 1 PAH Pyrene C2-v2 2.27E-05 1.25E-05 7.22E-05 1.07E-06 lbs/Mgal 3 95.89 73.70 0.82

SG, Crude Oil 1 SVOC Benzaldehyde A3-v0 7.03E-03 7.27E-03 7.34E-03 6.49E-03 lbs/Mgal 1 6.71 16.68 0.00

SG, Crude Oil 1 VOC Acetaldehyde A3-v0 2.67E-03 2.16E-03 5.10E-03 1.18E-03 lbs/Mgal 2 52.69 40.50 0.54

SG, Crude Oil 1 VOC Acrolein A3-v1 1.78E-03 4.99E-04 4.55E-03 4.99E-04 lbs/Mgal 2 108.34 83.28 0.00

SG, Crude Oil 1 VOC Benzene B3-v0 6.13E-04 6.60E-04 9.90E-04 3.00E-04 lbs/Mgal 2 44.18 33.96 0.36

SG, Crude Oil 1 VOC Formaldehyde A3-v0 9.44E-04 8.09E-04 1.64E-03 4.05E-04 lbs/Mgal 2 52.64 40.46 0.44

SG, Crude Oil 1 VOC Propylene B3-v2 5.80E-02 1.87E-03 1.70E-01 1.87E-03 lbs/Mgal 2 145.15 111.58 0.00

SG, Crude Oil 1 VOC Toluene B3-v1 3.56E-03 2.05E-03 1.16E-02 2.05E-03 lbs/Mgal 2 88.54 68.06 0.74

SG, Crude Oil 1 VOC Xylene (Total) B3-v1 3.29E-03 4.72E-03 4.72E-03 4.29E-04 lbs/Mgal 2 65.22 50.13 0.00

SG, Natural Gas 1 VOC Acetaldehyde A3-v0 1.56E-02 1.57E-02 1.66E-02 1.44E-02 lbs/MMcf 1 7.27 18.05 1.00

174

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

SG, Natural Gas 1 VOC Acrolein A3-v0 1.84E-02 1.75E-02 2.22E-02 1.55E-02 lbs/MMcf 1 18.73 46.53 1.00

SG, Natural Gas 1 VOC Benzene B3-v0 3.86E-03 3.87E-03 3.88E-03 3.83E-03 lbs/MMcf 2 0.57 0.60 0.00

SG, Natural Gas 1 VOC Formaldehyde A3-v1 2.95E-02 1.83E-02 9.16E-02 3.96E-03 lbs/MMcf 2 111.23 116.73 1.00

SG, Natural Gas 1 VOC Propylene C3-v0 1.09E-01 1.09E-01 1.09E-01 1.09E-01 lbs/MMcf 1 0.36 0.89 0.00

SG, Natural Gas 1 VOC Toluene B3-v0 1.20E-02 1.20E-02 1.20E-02 1.19E-02 lbs/MMcf 2 0.57 0.60 0.00

SG, Natural Gas 1 VOC Xylene (Total) B3-v0 2.76E-02 2.76E-02 2.77E-02 2.74E-02 lbs/MMcf 2 0.57 0.60 0.00

SG, Natural/CVR Gas 1 PAH Acenaphthene A3-v1 1.04E-06 7.23E-07 2.38E-06 4.12E-07 lbs/MMcf 2 69.67 73.12 0.72

SG, Natural/CVR Gas 1 PAH Acenaphthylene A3-v1 2.70E-06 6.70E-07 1.03E-05 4.12E-07 lbs/MMcf 2 144.60 151.75 0.85

SG, Natural/CVR Gas 1 PAH Anthracene A3-v1 2.09E-06 2.28E-06 3.82E-06 4.12E-07 lbs/MMcf 2 62.45 65.54 0.97

SG, Natural/CVR Gas 1 PAH Benzo(a)anthracene A3-v0 1.22E-06 1.12E-06 2.16E-06 6.82E-07 lbs/MMcf 2 40.32 42.31 0.45

SG, Natural/CVR Gas 1 PAH Benzo(a)pyrene A3-v0 6.86E-07 6.46E-07 1.33E-06 3.98E-07 lbs/MMcf 2 49.51 51.96 0.32

SG, Natural/CVR Gas 1 PAH Benzo(b)fluoranthene A3-v1 2.00E-06 9.18E-07 4.78E-06 6.36E-07 lbs/MMcf 2 95.49 100.21 0.84

SG, Natural/CVR Gas 1 PAH Benzo(g,h,i)perylene A3-v0 9.80E-07 6.70E-07 1.75E-06 4.12E-07 lbs/MMcf 2 61.38 64.41 0.59

SG, Natural/CVR Gas 1 PAH Benzo(k)fluoranthene A3-v0 8.21E-07 6.70E-07 1.39E-06 4.12E-07 lbs/MMcf 2 44.95 47.18 0.52

SG, Natural/CVR Gas 1 PAH Chrysene A3-v0 1.55E-06 1.83E-06 2.16E-06 6.82E-07 lbs/MMcf 2 38.63 40.54 0.33

SG, Natural/CVR Gas 1 PAH Dibenz(a,h)anthracene A3-v0 5.30E-07 5.24E-07 6.82E-07 3.96E-07 lbs/MMcf 2 26.65 27.97 0.00

SG, Natural/CVR Gas 1 PAH Fluoranthene A3-v1 3.66E-06 1.71E-06 9.03E-06 1.01E-06 lbs/MMcf 2 98.55 103.43 1.00

SG, Natural/CVR Gas 1 PAH Fluorene A3-v1 5.63E-06 2.47E-06 1.30E-05 1.77E-06 lbs/MMcf 2 95.48 100.20 1.00

SG, Natural/CVR Gas 1 PAH Indeno(1,2,3-cd)pyrene A3-v1 1.17E-06 6.70E-07 2.38E-06 4.12E-07 lbs/MMcf 2 76.13 79.90 0.66

SG, Natural/CVR Gas 1 PAH Naphthalene A3-v0 2.89E-04 2.24E-04 5.54E-04 1.50E-04 lbs/MMcf 2 56.04 58.81 1.00

SG, Natural/CVR Gas 1 PAH Phenanthrene A3-v0 1.64E-05 1.21E-05 3.17E-05 6.59E-06 lbs/MMcf 2 64.15 67.32 1.00

SG, Natural/CVR Gas 1 PAH Pyrene A3-v1 6.00E-06 2.78E-06 1.74E-05 8.19E-07 lbs/MMcf 2 109.69 115.11 1.00

SG, Natural/CVR Gas 1 SVOC Ethylbenzene A3-v1 9.22E-03 7.34E-03 1.86E-02 3.69E-03 lbs/MMcf 2 55.96 58.72 0.54

SG, Natural/CVR Gas 1 VOC Acetaldehyde A2-v1 1.12E-02 1.02E-02 2.67E-02 5.02E-03 lbs/MMcf 4 55.73 35.41 0.84

SG, Natural/CVR Gas 1 VOC Acrolein A2-v0 1.05E-02 1.07E-02 1.82E-02 5.02E-03 lbs/MMcf 4 37.86 24.06 0.88

SG, Natural/CVR Gas 1 VOC Benzene B1-v0 3.33E-03 2.68E-03 6.21E-03 2.36E-03 lbs/MMcf 5 44.41 24.59 0.00

SG, Natural/CVR Gas 1 VOC Formaldehyde A2-v1 1.58E-02 9.51E-03 7.01E-02 5.02E-03 lbs/MMcf 4 117.82 74.86 0.70

SG, Natural/CVR Gas 1 VOC Hydrogen Sulfide C3-v0 1.48E-01 1.43E-01 2.28E-01 7.39E-02 lbs/MMcf 1 51.99 129.14 1.00

175

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

SG, Natural/CVR Gas 1 VOC Propylene C2-v2 1.83E-01 7.80E-02 6.30E-01 6.71E-03 lbs/MMcf 4 117.13 74.42 0.72

SG, Natural/CVR Gas 1 VOC Toluene B1-v0 1.37E-02 9.47E-03 3.08E-02 7.33E-03 lbs/MMcf 5 59.41 32.90 0.64

SG, Natural/CVR Gas 1 VOC Xylene (Total) B1-v0 1.85E-02 1.70E-02 4.03E-02 1.11E-02 lbs/MMcf 5 36.66 20.30 0.23

Shredding & Delaquering, Aluminum 1 Metals Antimony C3-v0 2.54E-05 2.46E-05 2.87E-05 2.31E-05 lbs/ton production 1 11.52 28.62 1.00

Shredding & Delaquering, Aluminum 1 Metals Arsenic C3-v0 4.29E-06 3.93E-06 5.03E-06 3.90E-06 lbs/ton production 1 15.10 37.50 0.39

Shredding & Delaquering, Aluminum 1 Metals Barium C3-v0 1.08E-03 1.35E-03 1.47E-03 4.31E-04 lbs/ton production 1 52.42 130.22 1.00

Shredding & Delaquering, Aluminum 1 Metals Beryllium C3-v0 7.77E-05 7.79E-05 7.86E-05 7.66E-05 lbs/ton production 1 1.36 3.37 0.00

Shredding & Delaquering, Aluminum 1 Metals Cadmium C3-v0 9.39E-06 1.23E-05 1.25E-05 3.37E-06 lbs/ton production 1 55.56 138.01 1.00

Shredding & Delaquering, Aluminum 1 Metals Chromium (Total) C3-v0 1.36E-04 1.38E-04 1.42E-04 1.28E-04 lbs/ton production 1 5.57 13.83 1.00

Shredding & Delaquering, Aluminum 1 Metals Copper C3-v0 7.83E-05 7.86E-05 9.66E-05 5.97E-05 lbs/ton production 1 23.57 58.55 0.67

Shredding & Delaquering, Aluminum 1 Metals Lead C3-v0 3.48E-05 3.19E-05 4.97E-05 2.28E-05 lbs/ton production 1 39.33 97.71 1.00

Shredding & Delaquering, Aluminum 1 Metals Manganese C3-v0 2.21E-04 1.67E-04 3.49E-04 1.47E-04 lbs/ton production 1 50.46 125.36 1.00

Shredding & Delaquering, Aluminum 1 Metals Mercury C3-v0 1.88E-05 1.80E-05 2.20E-05 1.66E-05 lbs/ton production 1 14.91 37.05 1.00

Shredding & Delaquering, Aluminum 1 Metals Nickel C3-v0 1.58E-04 1.12E-04 2.70E-04 9.17E-05 lbs/ton production 1 61.89 153.74 1.00

Shredding & Delaquering, Aluminum 1 Metals Selenium C3-v0 8.05E-06 8.07E-06 8.14E-06 7.93E-06 lbs/ton production 1 1.31 3.25 0.00

Shredding & Delaquering, Aluminum 1 Metals Silver C3-v0 7.77E-05 7.79E-05 7.86E-05 7.66E-05 lbs/ton production 1 1.36 3.37 0.00

Shredding & Delaquering, Aluminum 1 Metals Thallium C3-v0 1.74E-06 1.72E-06 1.91E-06 1.59E-06 lbs/ton production 1 9.25 22.98 1.00

Shredding & Delaquering, Aluminum 1 Metals Zinc C3-v0 3.53E-04 3.24E-04 4.14E-04 3.21E-04 lbs/ton production 1 14.92 37.07 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:4D 2378 C3-v0 4.41E-11 4.41E-11 4.48E-11 4.34E-11 lbs/ton production 1 2.18 19.60 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:4D Total C3-v0 1.07E-09 1.07E-09 1.16E-09 9.77E-10 lbs/ton production 1 12.29 110.45 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:5D 12378 C3-v0 1.59E-10 1.59E-10 1.63E-10 1.55E-10 lbs/ton production 1 3.45 31.03 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:5D Total C3-v0 1.43E-09 1.43E-09 1.47E-09 1.38E-09 lbs/ton production 1 4.41 39.61 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:6D 123478 C3-v0 9.54E-11 9.54E-11 9.77E-11 9.31E-11 lbs/ton production 1 3.45 31.03 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:6D 123678 C3-v0 1.19E-10 1.19E-10 1.22E-10 1.16E-10 lbs/ton production 1 3.44 30.94 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:6D 123789 C3-v0 1.19E-10 1.19E-10 1.22E-10 1.16E-10 lbs/ton production 1 3.44 30.93 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:6D Total C3-v0 1.75E-09 1.75E-09 1.79E-09 1.71E-09 lbs/ton production 1 3.44 30.95 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:7D 1234678 C3-v0 6.49E-10 6.49E-10 6.92E-10 6.05E-10 lbs/ton production 1 9.52 85.49 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:7D Total C3-v0 1.31E-09 1.31E-09 1.38E-09 1.24E-09 lbs/ton production 1 7.73 69.49 1.00

176

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Dioxin:8D C3-v0 7.43E-10 7.43E-10 7.61E-10 7.25E-10 lbs/ton production 1 3.43 30.83 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:4F 2378 C3-v0 5.20E-10 5.20E-10 5.35E-10 5.05E-10 lbs/ton production 1 4.11 36.94 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:4F Total C3-v0 1.39E-08 1.39E-08 1.55E-08 1.22E-08 lbs/ton production 1 16.81 151.00 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:5F 12378 C3-v0 7.58E-10 7.58E-10 7.76E-10 7.41E-10 lbs/ton production 1 3.21 28.88 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:5F 23478 C3-v0 1.07E-09 1.07E-09 1.09E-09 1.06E-09 lbs/ton production 1 1.79 16.04 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:5F Total C3-v0 1.31E-08 1.31E-08 1.40E-08 1.22E-08 lbs/ton production 1 9.42 84.66 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:6F 123478 C3-v0 1.03E-09 1.03E-09 1.06E-09 1.01E-09 lbs/ton production 1 3.45 31.03 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:6F 123678 C3-v0 1.03E-09 1.03E-09 1.06E-09 1.01E-09 lbs/ton production 1 3.46 31.05 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:6F 123789 C3-v0 4.93E-10 4.93E-10 4.97E-10 4.89E-10 lbs/ton production 1 1.17 10.54 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:6F 234678 C3-v0 8.75E-10 8.75E-10 8.96E-10 8.53E-10 lbs/ton production 1 3.44 30.95 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:6F Total C3-v0 1.15E-08 1.15E-08 1.16E-08 1.14E-08 lbs/ton production 1 1.42 12.78 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:7F 1234678 C3-v0 2.74E-09 2.74E-09 2.85E-09 2.64E-09 lbs/ton production 1 5.50 49.44 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:7F 1234789 C3-v0 6.08E-10 6.08E-10 6.11E-10 6.05E-10 lbs/ton production 1 0.68 6.12 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:7F Total C3-v0 5.53E-09 5.53E-09 5.70E-09 5.35E-09 lbs/ton production 1 4.47 40.18 1.00

Shredding & Delaquering, Aluminum 2 Dioxin/Furan Furan:8F C3-v0 1.35E-09 1.35E-09 1.38E-09 1.32E-09 lbs/ton production 1 3.46 31.04 1.00

Turbine, Distillate 1 PAH Acenaphthene B2-v2 9.69E-05 3.93E-05 3.06E-04 2.19E-06 lbs/Mgal 3 119.31 91.71 0.12

Turbine, Distillate 1 PAH Acenaphthylene B2-v2 8.61E-05 6.19E-06 3.06E-04 2.59E-06 lbs/Mgal 3 141.88 109.06 0.06

Turbine, Distillate 1 PAH Anthracene B2-v2 9.80E-05 4.94E-05 3.06E-04 2.46E-06 lbs/Mgal 3 119.62 91.95 0.17

Turbine, Distillate 1 PAH Benzo(a)anthracene B2-v2 8.53E-05 7.48E-06 3.06E-04 2.46E-06 lbs/Mgal 3 143.88 110.60 0.01

Turbine, Distillate 1 PAH Benzo(a)pyrene B2-v2 8.33E-05 4.31E-06 3.06E-04 2.46E-06 lbs/Mgal 3 148.87 114.43 0.01

Turbine, Distillate 1 PAH Benzo(b)fluoranthene A3-v2 1.32E-04 1.03E-04 3.06E-04 4.93E-06 lbs/Mgal 2 97.77 102.61 0.08

Turbine, Distillate 1 PAH Benzo(b+k)fluoranthene C3-v0 2.52E-06 2.52E-06 2.59E-06 2.46E-06 lbs/Mgal 1 2.62 6.50 0.00

Turbine, Distillate 1 PAH Benzo(g,h,i)perylene B2-v2 8.26E-05 2.74E-06 3.06E-04 9.86E-07 lbs/Mgal 3 150.78 115.90 0.01

Turbine, Distillate 1 PAH Benzo(k)fluoranthene A3-v2 1.30E-04 1.07E-04 3.06E-04 2.67E-06 lbs/Mgal 2 100.54 105.51 0.07

Turbine, Distillate 1 PAH Chrysene B2-v2 1.03E-04 8.11E-05 3.06E-04 2.46E-06 lbs/Mgal 3 111.88 86.00 0.21

Turbine, Distillate 1 PAH Dibenz(a,h)anthracene B2-v2 8.25E-05 2.59E-06 3.06E-04 1.55E-06 lbs/Mgal 3 150.98 116.06 0.01

Turbine, Distillate 1 PAH Fluoranthene B2-v2 1.25E-04 7.73E-05 3.06E-04 4.25E-06 lbs/Mgal 3 95.95 73.75 0.35

Turbine, Distillate 1 PAH Fluorene B2-v2 1.27E-04 1.07E-04 3.06E-04 2.59E-06 lbs/Mgal 3 82.64 63.52 0.36

177

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Distillate 1 PAH Indeno(1,2,3-cd)pyrene B2-v2 8.26E-05 2.59E-06 3.06E-04 9.65E-07 lbs/Mgal 3 150.63 115.79 0.01

Turbine, Distillate 1 PAH Naphthalene B2-v1 1.08E-02 6.53E-03 2.77E-02 3.41E-03 lbs/Mgal 3 79.58 61.17 1.00

Turbine, Distillate 1 PAH Phenanthrene B2-v2 4.12E-04 2.49E-04 2.04E-03 8.39E-06 lbs/Mgal 3 155.54 119.56 1.00

Turbine, Distillate 1 PAH Pyrene B2-v2 1.01E-04 4.25E-05 3.06E-04 2.59E-06 lbs/Mgal 3 112.94 86.82 0.20

Turbine, Distillate 1 VOC Formaldehyde C3-v1 3.19E-02 3.12E-02 7.31E-02 3.80E-03 lbs/Mgal 2 83.25 87.36 1.00

Turbine, Distillate 2 Dioxin/Furan Dioxin:4D Total C3-v1 3.74E-09 1.12E-09 9.61E-09 4.84E-10 lbs/Mgal 1 136.40 338.83 0.86

Turbine, Distillate 2 Dioxin/Furan Dioxin:5D Total C3-v2 7.15E-09 8.22E-10 2.04E-08 2.21E-10 lbs/Mgal 1 160.64 399.05 0.95

Turbine, Distillate 2 Dioxin/Furan Dioxin:6D Total C3-v1 9.00E-09 2.52E-09 2.22E-08 2.26E-09 lbs/Mgal 1 127.17 315.91 1.00

Turbine, Distillate 2 Dioxin/Furan Dioxin:7D Total C3-v0 1.68E-08 1.23E-08 2.76E-08 1.05E-08 lbs/Mgal 1 55.86 138.76 1.00

Turbine, Distillate 2 Dioxin/Furan Dioxin:8D C3-v0 1.07E-07 1.17E-07 1.20E-07 8.41E-08 lbs/Mgal 1 18.67 46.38 1.00

Turbine, Distillate 2 Dioxin/Furan Furan:4F Total C3-v2 3.34E-08 2.64E-09 9.61E-08 1.37E-09 lbs/Mgal 1 162.81 404.44 1.00

Turbine, Distillate 2 Dioxin/Furan Furan:5F Total C3-v2 4.67E-08 7.04E-09 1.32E-07 9.99E-10 lbs/Mgal 1 158.43 393.56 1.00

Turbine, Distillate 2 Dioxin/Furan Furan:6F Total C3-v2 2.41E-08 5.52E-09 6.60E-08 7.36E-10 lbs/Mgal 1 151.06 375.26 1.00

Turbine, Distillate 2 Dioxin/Furan Furan:7F Total C3-v1 1.67E-08 6.46E-09 3.96E-08 4.00E-09 lbs/Mgal 1 119.21 296.13 1.00

Turbine, Distillate 2 Dioxin/Furan Furan:8F C3-v0 8.61E-09 7.04E-09 1.50E-08 3.79E-09 lbs/Mgal 1 67.04 166.55 0.85

Turbine, Distillate 2 Halogens HCl C3-v0 8.09E-02 8.22E-02 8.61E-02 7.43E-02 lbs/Mgal 1 7.47 18.55 1.00

Turbine, Distillate 2 Metals Arsenic D3-v0 2.02E-04 2.56E-04 2.72E-04 7.88E-05 lbs/Mgal 1 52.99 131.63 1.00

Turbine, Distillate 2 Metals Beryllium D3-v1 5.43E-05 1.69E-05 1.37E-04 8.96E-06 lbs/Mgal 1 132.14 328.26 0.84

Turbine, Distillate 2 Metals Cadmium D3-v0 3.25E-04 3.49E-04 3.56E-04 2.71E-04 lbs/Mgal 1 14.64 36.38 0.00

Turbine, Distillate 2 Metals Chromium (Hex) A3-v0 1.08E-05 1.04E-05 1.64E-05 5.60E-06 lbs/Mgal 1 50.06 124.34 1.00

Turbine, Distillate 2 Metals Chromium (Total) A3-v0 4.24E-04 4.10E-04 5.60E-04 3.04E-04 lbs/Mgal 1 30.31 75.30 0.76

Turbine, Distillate 2 Metals Copper D3-v0 9.98E-04 1.00E-03 1.48E-03 5.11E-04 lbs/Mgal 1 48.58 120.68 1.00

Turbine, Distillate 2 Metals Lead D3-v0 6.08E-04 7.04E-04 7.18E-04 4.02E-04 lbs/Mgal 1 29.34 72.88 1.00

Turbine, Distillate 2 Metals Manganese D3-v0 1.03E-02 8.96E-03 1.43E-02 7.60E-03 lbs/Mgal 1 34.45 85.58 1.00

Turbine, Distillate 2 Metals Mercury D3-v0 2.71E-06 1.64E-06 5.14E-06 1.34E-06 lbs/Mgal 1 78.01 193.78 1.00

Turbine, Distillate 2 Metals Nickel D3-v2 4.88E-02 2.71E-03 1.42E-01 1.12E-03 lbs/Mgal 1 166.42 413.41 1.00

Turbine, Distillate 2 Metals Selenium D3-v0 8.39E-06 8.96E-06 9.13E-06 7.09E-06 lbs/Mgal 1 13.50 33.53 0.00

Turbine, Distillate 2 Metals Zinc D3-v1 5.38E-02 1.35E-02 1.42E-01 5.58E-03 lbs/Mgal 1 142.77 354.67 1.00

178

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Distillate 2 PAH Acenaphthene C3-v1 1.82E-05 1.23E-05 5.53E-05 2.37E-06 lbs/Mgal 2 111.57 117.08 0.76

Turbine, Distillate 2 PAH Acenaphthylene C3-v1 6.32E-06 3.23E-06 2.22E-05 2.70E-06 lbs/Mgal 2 123.35 129.45 0.59

Turbine, Distillate 2 PAH Anthracene C3-v1 1.56E-05 7.68E-06 4.92E-05 2.35E-06 lbs/Mgal 2 116.84 122.62 0.32

Turbine, Distillate 2 PAH Benzo(a)anthracene C3-v1 4.22E-06 3.39E-06 9.47E-06 9.01E-07 lbs/Mgal 2 69.39 72.82 0.00

Turbine, Distillate 2 PAH Benzo(a)pyrene C3-v1 8.61E-06 5.05E-06 2.89E-05 2.90E-06 lbs/Mgal 2 117.12 122.91 0.56

Turbine, Distillate 2 PAH Benzo(b)fluoranthene C3-v0 2.15E-05 1.82E-05 3.73E-05 9.01E-06 lbs/Mgal 1 67.21 166.95 0.86

Turbine, Distillate 2 PAH Benzo(b+k)fluoranthene C3-v0 3.23E-06 3.14E-06 3.65E-06 2.90E-06 lbs/Mgal 1 11.83 29.38 0.00

Turbine, Distillate 2 PAH Benzo(g,h,i)perylene C3-v1 2.18E-06 2.34E-06 3.65E-06 4.32E-07 lbs/Mgal 2 57.33 60.16 0.00

Turbine, Distillate 2 PAH Benzo(k)fluoranthene C3-v0 6.92E-06 8.41E-06 9.99E-06 2.35E-06 lbs/Mgal 1 58.35 144.95 0.00

Turbine, Distillate 2 PAH Chrysene C3-v0 4.82E-06 3.68E-06 9.99E-06 2.90E-06 lbs/Mgal 2 55.94 58.71 0.00

Turbine, Distillate 2 PAH Dibenz(a,h)anthracene C3-v0 2.30E-06 2.63E-06 3.65E-06 8.41E-07 lbs/Mgal 2 51.65 54.20 0.00

Turbine, Distillate 2 PAH Fluoranthene C3-v1 1.34E-05 1.06E-05 2.68E-05 2.90E-06 lbs/Mgal 2 86.76 91.05 0.88

Turbine, Distillate 2 PAH Fluorene C3-v1 1.76E-05 1.67E-05 3.48E-05 3.82E-06 lbs/Mgal 2 69.22 72.65 0.21

Turbine, Distillate 2 PAH Indeno(1,2,3-cd)pyrene C3-v1 2.29E-06 2.58E-06 3.65E-06 3.36E-07 lbs/Mgal 2 53.19 55.82 0.00

Turbine, Distillate 2 PAH Naphthalene C3-v0 3.87E-04 3.81E-04 5.34E-04 2.62E-04 lbs/Mgal 2 27.98 29.36 1.00

Turbine, Distillate 2 PAH Phenanthrene C3-v1 6.91E-05 5.41E-05 1.62E-04 1.27E-05 lbs/Mgal 2 86.32 90.58 1.00

Turbine, Distillate 2 PAH Pyrene C3-v1 1.44E-05 1.05E-05 3.78E-05 2.90E-06 lbs/Mgal 2 97.30 102.11 0.89

Turbine, Distillate 2 VOC Benzene C3-v0 1.13E-02 1.13E-02 1.18E-02 1.07E-02 lbs/Mgal 1 7.01 63.01 1.00

Turbine, Distillate 2 VOC Formaldehyde C3-v1 7.05E-02 5.93E-02 1.56E-01 8.17E-03 lbs/Mgal 2 96.86 101.64 1.00

Turbine, Field Gas 1 PAH Acenaphthene C3-v0 1.62E-05 1.24E-05 2.58E-05 1.04E-05 lbs/MMcf 1 51.80 128.68 0.75

Turbine, Field Gas 1 PAH Acenaphthylene C3-v0 1.10E-06 1.07E-06 1.24E-06 9.98E-07 lbs/MMcf 1 11.17 27.75 0.00

Turbine, Field Gas 1 PAH Anthracene C3-v0 2.48E-07 2.80E-07 2.85E-07 1.80E-07 lbs/MMcf 1 23.99 59.61 0.00

Turbine, Field Gas 1 PAH Benzo(a)anthracene C3-v0 3.30E-07 3.74E-07 4.28E-07 1.89E-07 lbs/MMcf 1 38.00 94.40 0.00

Turbine, Field Gas 1 PAH Benzo(a)pyrene C3-v0 7.99E-07 8.55E-07 1.12E-06 4.22E-07 lbs/MMcf 1 44.15 109.67 0.00

Turbine, Field Gas 1 PAH Benzo(b)fluoranthene C3-v0 1.44E-06 1.40E-06 2.02E-06 9.03E-07 lbs/MMcf 1 38.84 96.47 0.47

Turbine, Field Gas 1 PAH Benzo(e)pyrene C3-v0 2.24E-06 1.79E-06 3.88E-06 1.05E-06 lbs/MMcf 1 65.68 163.15 0.27

Turbine, Field Gas 1 PAH Benzo(g,h,i)perylene C3-v0 5.31E-06 5.89E-06 7.38E-06 2.64E-06 lbs/MMcf 1 45.66 113.42 0.17

Turbine, Field Gas 1 PAH Benzo(k)fluoranthene C3-v0 4.25E-07 5.14E-07 5.23E-07 2.38E-07 lbs/MMcf 1 38.11 94.68 0.00

179

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Field Gas 1 PAH Chrysene C3-v0 1.95E-05 1.78E-05 2.79E-05 1.28E-05 lbs/MMcf 1 39.24 97.48 1.00

Turbine, Field Gas 1 PAH Dibenz(a,h)anthracene C3-v0 6.91E-06 8.55E-06 8.83E-06 3.36E-06 lbs/MMcf 1 44.58 110.75 0.00

Turbine, Field Gas 1 PAH Fluoranthene C3-v0 1.46E-05 1.20E-05 2.15E-05 1.03E-05 lbs/MMcf 1 41.42 102.88 1.00

Turbine, Field Gas 1 PAH Fluorene C3-v0 6.03E-05 3.24E-05 1.17E-04 3.17E-05 lbs/MMcf 1 81.17 201.63 1.00

Turbine, Field Gas 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 3.92E-06 4.53E-06 5.27E-06 1.96E-06 lbs/MMcf 1 44.39 110.27 0.00

Turbine, Field Gas 1 PAH Naphthalene C3-v0 5.79E-03 6.02E-03 6.39E-03 4.94E-03 lbs/MMcf 1 13.00 32.30 1.00

Turbine, Field Gas 1 PAH Phenanthrene C3-v0 6.19E-05 5.33E-05 8.93E-05 4.31E-05 lbs/MMcf 1 39.18 97.32 1.00

Turbine, Field Gas 1 PAH Pyrene C3-v0 1.28E-05 9.67E-06 1.97E-05 9.22E-06 lbs/MMcf 1 45.95 114.14 1.00

Turbine, Field Gas 1 SVOC 2-Chloronaphthalene C3-v0 8.53E-08 9.34E-08 9.50E-08 6.73E-08 lbs/MMcf 1 18.23 45.29 0.00

Turbine, Field Gas 1 SVOC 2-Methylnaphthalene C3-v0 8.10E-05 8.33E-05 9.03E-05 6.95E-05 lbs/MMcf 1 13.02 32.33 1.00

Turbine, Field Gas 1 SVOC Perylene C3-v0 8.62E-07 9.50E-07 1.07E-06 5.61E-07 lbs/MMcf 1 31.07 77.19 0.00

Turbine, Field Gas 1 VOC Benzene A3-v0 1.46E-02 1.48E-02 1.49E-02 1.42E-02 lbs/MMcf 1 2.61 6.48 0.00

Turbine, Field Gas 1 VOC Formaldehyde A3-v0 1.84E-01 1.65E-01 2.78E-01 1.10E-01 lbs/MMcf 1 46.36 115.16 1.00

Turbine, Landfill Gas 1 VOC Benzene C3-v1 3.96E-01 2.47E-01 7.89E-01 1.51E-01 lbs/MMcf 1 87.06 216.26 1.00

Turbine, Landfill Gas 1 VOC Chloroform C3-v0 2.79E-03 1.81E-03 5.15E-03 1.41E-03 lbs/MMcf 1 73.63 182.91 0.62

Turbine, Landfill Gas 1 VOC Formaldehyde A3-v0 1.80E-01 1.70E-01 2.00E-01 1.70E-01 lbs/MMcf 1 9.62 23.90 1.00

Turbine, Landfill Gas 1 VOC Methyl Chloroform C3-v0 1.12E-02 1.13E-02 1.13E-02 1.11E-02 lbs/MMcf 1 0.90 2.23 1.00

Turbine, Landfill Gas 1 VOC Methylene Chloride C3-v0 1.37E+00 1.07E+00 2.15E+00 8.77E-01 lbs/MMcf 1 50.21 124.72 1.00

Turbine, Landfill Gas 1 VOC Perchloroethylene C3-v0 2.23E-03 2.24E-03 2.25E-03 2.21E-03 lbs/MMcf 1 0.90 2.23 0.00

Turbine, Landfill Gas 1 VOC Vinyl Chloride C3-v0 2.10E-03 2.11E-03 2.11E-03 2.08E-03 lbs/MMcf 1 0.90 2.23 0.00

Turbine, Natural Gas 1 VOC Benzene B3-v0 9.09E-02 9.42E-02 9.90E-02 7.84E-02 lbs/MMcf 2 8.48 8.89 1.00

Turbine, Natural Gas 1 VOC Formaldehyde A1-v0 4.04E+00 3.93E+00 6.37E+00 1.47E+00 lbs/MMcf 5 31.61 17.51 1.00

Turbine, Natural Gas 2 PAH Acenaphthene B1-v2 1.90E-05 5.23E-06 1.22E-04 3.63E-07 lbs/MMcf 6 182.93 90.97 0.16

Turbine, Natural Gas 2 PAH Acenaphthylene B1-v2 1.47E-05 2.88E-06 8.25E-05 2.03E-07 lbs/MMcf 6 187.51 93.24 0.40

Turbine, Natural Gas 2 PAH Anthracene B1-v2 3.38E-05 9.38E-06 1.53E-04 3.20E-07 lbs/MMcf 6 141.08 70.16 0.49

Turbine, Natural Gas 2 PAH Benzo(a)anthracene B1-v2 2.26E-05 3.61E-06 1.34E-04 3.20E-07 lbs/MMcf 6 201.28 100.09 0.04

Turbine, Natural Gas 2 PAH Benzo(a)pyrene B1-v2 1.39E-05 2.57E-06 9.16E-05 5.52E-07 lbs/MMcf 6 194.99 96.96 0.37

Turbine, Natural Gas 2 PAH Benzo(b)fluoranthene B1-v2 1.13E-05 2.87E-06 6.72E-05 6.68E-07 lbs/MMcf 6 174.76 86.91 0.04

180

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Natural Gas 2 PAH Benzo(e)pyrene C3-v0 5.44E-07 4.63E-07 7.33E-07 4.36E-07 lbs/MMcf 1 30.18 74.97 0.00

Turbine, Natural Gas 2 PAH Benzo(g,h,i)perylene B1-v2 1.37E-05 3.03E-06 8.25E-05 1.19E-06 lbs/MMcf 6 185.37 92.18 0.01

Turbine, Natural Gas 2 PAH Benzo(k)fluoranthene B1-v2 1.10E-05 2.87E-06 6.72E-05 3.49E-07 lbs/MMcf 6 180.41 89.71 0.02

Turbine, Natural Gas 2 PAH Chrysene B1-v3 2.52E-05 4.99E-06 1.50E-04 1.16E-07 lbs/MMcf 6 194.70 96.82 0.05

Turbine, Natural Gas 2 PAH Dibenz(a,h)anthracene B1-v2 2.35E-05 3.03E-06 1.34E-04 1.26E-06 lbs/MMcf 6 200.54 99.72 0.00

Turbine, Natural Gas 2 PAH Fluoranthene B1-v3 4.32E-05 1.07E-05 3.05E-04 1.63E-07 lbs/MMcf 6 193.80 96.37 1.00

Turbine, Natural Gas 2 PAH Fluorene B1-v3 5.80E-05 1.56E-05 4.58E-04 4.53E-07 lbs/MMcf 6 193.25 96.10 1.00

Turbine, Natural Gas 2 PAH Indeno(1,2,3-cd)pyrene B1-v2 2.35E-05 2.87E-06 1.34E-04 1.26E-06 lbs/MMcf 6 200.51 99.71 0.01

Turbine, Natural Gas 2 PAH Naphthalene B1-v2 1.66E-03 9.26E-04 7.88E-03 2.10E-05 lbs/MMcf 6 136.18 67.72 0.85

Turbine, Natural Gas 2 PAH Phenanthrene B1-v3 3.13E-04 8.57E-05 2.35E-03 8.14E-07 lbs/MMcf 6 191.49 95.22 0.99

Turbine, Natural Gas 2 PAH Pyrene B1-v3 2.77E-05 1.18E-05 1.27E-04 2.12E-07 lbs/MMcf 6 135.65 67.46 1.00

Turbine, Natural Gas 2 SVOC 2-Chloronaphthalene C3-v0 2.72E-07 1.74E-07 4.69E-07 1.74E-07 lbs/MMcf 1 62.54 155.36 0.00

Turbine, Natural Gas 2 SVOC 2-Methylnaphthalene C3-v0 5.29E-06 5.07E-06 6.30E-06 4.50E-06 lbs/MMcf 1 17.39 43.21 1.00

Turbine, Natural Gas 2 SVOC Ethylbenzene B1-v1 1.79E-02 9.74E-03 5.70E-02 5.63E-03 lbs/MMcf 5 83.52 46.25 0.49

Turbine, Natural Gas 2 SVOC Perylene C3-v0 7.00E-07 5.79E-07 9.68E-07 5.52E-07 lbs/MMcf 1 33.22 82.54 0.00

Turbine, Natural Gas 2 VOC 1,3-Butadiene C3-v0 1.27E-04 1.24E-04 1.33E-04 1.24E-04 lbs/MMcf 1 4.22 10.49 0.00

Turbine, Natural Gas 2 VOC Acetaldehyde A1-v2 1.37E-01 5.38E-02 5.11E-01 4.09E-03 lbs/MMcf 5 122.61 74.09 0.99

Turbine, Natural Gas 2 VOC Acrolein A1-v1 1.89E-02 1.09E-02 6.93E-02 4.79E-03 lbs/MMcf 6 103.16 51.30 0.59

Turbine, Natural Gas 2 VOC Benzene B1-v1 1.33E-02 1.01E-02 4.72E-02 5.50E-03 lbs/MMcf 8 69.15 29.20 0.38

Turbine, Natural Gas 2 VOC Formaldehyde B1-v2 9.17E-01 1.12E-01 6.87E+00 1.73E-02 lbs/MMcf 9 220.68 91.09 1.00

Turbine, Natural Gas 2 VOC Hexane A3-v0 2.59E-01 2.19E-01 3.82E-01 1.77E-01 lbs/MMcf 1 41.69 103.55 1.00

Turbine, Natural Gas 2 VOC Propylene B2-v2 7.71E-01 5.71E-01 2.00E+00 2.89E-02 lbs/MMcf 3 98.01 75.33 0.76

Turbine, Natural Gas 2 VOC Propylene Oxide E3-v0 4.78E-02 4.48E-02 5.87E-02 3.97E-02 lbs/MMcf 1 20.56 51.07 0.00

Turbine, Natural Gas 2 VOC Toluene B1-v1 7.10E-02 5.91E-02 1.68E-01 8.22E-03 lbs/MMcf 5 76.00 42.09 0.99

Turbine, Natural Gas 2 VOC Xylene (m,p) B3-v1 4.89E-02 4.27E-02 1.08E-01 8.77E-03 lbs/MMcf 2 89.78 94.22 0.97

Turbine, Natural Gas 2 VOC Xylene (o) B3-v1 2.40E-02 2.15E-02 4.88E-02 5.67E-03 lbs/MMcf 2 74.70 78.39 0.86

Turbine, Natural Gas 2 VOC Xylene (Total) B2-v1 2.61E-02 1.93E-02 6.26E-02 5.63E-03 lbs/MMcf 3 82.19 63.17 0.35

Turbine, Natural/Ref. Gas 1 Metals Antimony A3-v0 6.62E-05 6.56E-05 6.79E-05 6.52E-05 lbs/MMcf 1 2.18 5.42 0.00

181

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Natural/Ref. Gas 1 Metals Arsenic A3-v0 6.62E-05 6.56E-05 6.79E-05 6.52E-05 lbs/MMcf 1 2.18 5.42 0.00

Turbine, Natural/Ref. Gas 1 Metals Barium A3-v0 8.73E-04 7.58E-04 1.14E-03 7.17E-04 lbs/MMcf 1 26.85 66.71 1.00

Turbine, Natural/Ref. Gas 1 Metals Beryllium A3-v0 2.65E-05 2.63E-05 2.72E-05 2.61E-05 lbs/MMcf 1 2.18 5.42 0.00

Turbine, Natural/Ref. Gas 1 Metals Cadmium B3-v1 1.28E-03 7.92E-04 4.16E-03 3.17E-04 lbs/MMcf 2 113.19 118.78 0.73

Turbine, Natural/Ref. Gas 1 Metals Chromium (Hex) C2-v2 4.99E-03 1.68E-03 1.50E-02 3.06E-05 lbs/MMcf 3 124.20 95.47 0.00

Turbine, Natural/Ref. Gas 1 Metals Chromium (Total) C2-v2 3.59E-02 1.53E-02 1.84E-01 6.74E-04 lbs/MMcf 3 160.39 123.29 1.00

Turbine, Natural/Ref. Gas 1 Metals Cobalt A3-v0 1.55E-04 1.67E-04 1.67E-04 1.29E-04 lbs/MMcf 1 14.32 35.56 1.00

Turbine, Natural/Ref. Gas 1 Metals Copper A3-v1 5.87E-03 5.12E-03 1.32E-02 1.04E-03 lbs/MMcf 2 81.24 85.26 1.00

Turbine, Natural/Ref. Gas 1 Metals Lead A3-v0 1.66E-03 1.81E-03 1.90E-03 1.26E-03 lbs/MMcf 1 21.17 52.58 1.00

Turbine, Natural/Ref. Gas 1 Metals Manganese A3-v2 5.09E-02 4.88E-03 2.78E-01 1.32E-03 lbs/MMcf 2 219.09 229.92 1.00

Turbine, Natural/Ref. Gas 1 Metals Mercury A2-v3 3.09E-03 2.67E-03 8.27E-03 5.43E-06 lbs/MMcf 3 96.45 74.14 1.00

Turbine, Natural/Ref. Gas 1 Metals Nickel B3-v1 4.57E-03 2.19E-03 1.43E-02 9.32E-04 lbs/MMcf 2 116.02 121.76 1.00

Turbine, Natural/Ref. Gas 1 Metals Phosphorus A3-v0 1.93E-02 1.97E-02 2.52E-02 1.30E-02 lbs/MMcf 1 31.45 78.12 0.77

Turbine, Natural/Ref. Gas 1 Metals Selenium A3-v0 3.31E-04 3.28E-04 3.39E-04 3.26E-04 lbs/MMcf 1 2.18 5.42 0.00

Turbine, Natural/Ref. Gas 1 Metals Silver A3-v1 1.37E-04 4.53E-05 3.33E-04 3.26E-05 lbs/MMcf 1 124.00 308.03 0.92

Turbine, Natural/Ref. Gas 1 Metals Thallium A3-v0 3.31E-05 3.28E-05 3.39E-05 3.26E-05 lbs/MMcf 1 2.18 5.42 0.00

Turbine, Natural/Ref. Gas 1 Metals Zinc A3-v0 1.57E-02 1.59E-02 1.93E-02 1.18E-02 lbs/MMcf 2 15.79 16.58 1.00

Turbine, Natural/Ref. Gas 1 PAH Acenaphthene B2-v1 9.00E-06 2.13E-06 3.82E-05 9.82E-07 lbs/MMcf 3 144.09 110.75 0.96

Turbine, Natural/Ref. Gas 1 PAH Acenaphthylene B2-v1 4.75E-06 1.80E-06 1.32E-05 9.35E-07 lbs/MMcf 3 110.89 85.23 0.81

Turbine, Natural/Ref. Gas 1 PAH Anthracene B2-v1 1.39E-05 1.07E-05 3.66E-05 1.06E-06 lbs/MMcf 3 80.82 62.12 0.92

Turbine, Natural/Ref. Gas 1 PAH Benzo(a)anthracene B2-v1 6.24E-06 1.80E-06 4.15E-05 9.35E-07 lbs/MMcf 3 212.47 163.32 0.74

Turbine, Natural/Ref. Gas 1 PAH Benzo(a)pyrene B2-v1 4.32E-06 1.80E-06 1.36E-05 9.35E-07 lbs/MMcf 3 110.83 85.19 0.00

Turbine, Natural/Ref. Gas 1 PAH Benzo(b)fluoranthene B2-v1 9.88E-06 1.80E-06 3.44E-05 9.35E-07 lbs/MMcf 3 140.50 108.00 0.74

Turbine, Natural/Ref. Gas 1 PAH Benzo(e)pyrene A3-v0 1.36E-06 1.28E-06 1.92E-06 9.35E-07 lbs/MMcf 2 33.78 35.45 0.00

Turbine, Natural/Ref. Gas 1 PAH Benzo(g,h,i)perylene B2-v1 7.79E-06 1.80E-06 2.71E-05 9.41E-07 lbs/MMcf 3 129.42 99.48 0.02

Turbine, Natural/Ref. Gas 1 PAH Benzo(k)fluoranthene B2-v1 5.37E-06 1.80E-06 2.00E-05 9.35E-07 lbs/MMcf 3 125.82 96.71 0.00

Turbine, Natural/Ref. Gas 1 PAH Chrysene B2-v2 3.94E-05 1.80E-06 2.43E-04 9.35E-07 lbs/MMcf 3 202.89 155.95 0.98

Turbine, Natural/Ref. Gas 1 PAH Dibenz(a,h)anthracene B2-v1 3.27E-06 1.80E-06 8.59E-06 9.35E-07 lbs/MMcf 3 94.56 72.69 0.00

182

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Natural/Ref. Gas 1 PAH Fluoranthene B2-v2 3.84E-05 6.28E-06 1.58E-04 2.16E-06 lbs/MMcf 3 149.02 114.55 1.00

Turbine, Natural/Ref. Gas 1 PAH Fluorene B2-v2 6.73E-05 6.48E-06 4.46E-04 5.27E-06 lbs/MMcf 3 214.54 164.91 0.98

Turbine, Natural/Ref. Gas 1 PAH Indeno(1,2,3-cd)pyrene B2-v1 4.18E-06 1.80E-06 1.18E-05 9.35E-07 lbs/MMcf 3 105.73 81.27 0.00

Turbine, Natural/Ref. Gas 1 PAH Naphthalene B2-v2 1.37E-02 7.31E-04 4.30E-02 1.09E-04 lbs/MMcf 3 145.82 112.09 0.98

Turbine, Natural/Ref. Gas 1 PAH Phenanthrene B2-v1 2.55E-04 6.12E-05 9.72E-04 2.07E-05 lbs/MMcf 3 135.29 103.99 0.90

Turbine, Natural/Ref. Gas 1 PAH Pyrene B2-v2 4.82E-05 1.35E-05 2.29E-04 2.55E-06 lbs/MMcf 3 156.71 120.46 0.98

Turbine, Natural/Ref. Gas 1 SVOC 2-Methylnaphthalene A3-v0 3.29E-05 3.03E-05 5.78E-05 1.27E-05 lbs/MMcf 2 67.27 70.59 0.00

Turbine, Natural/Ref. Gas 1 SVOC Ethylbenzene A3-v0 1.82E-03 1.73E-03 2.26E-03 1.28E-03 lbs/MMcf 2 19.62 20.59 0.52

Turbine, Natural/Ref. Gas 1 SVOC Perylene A3-v0 1.36E-06 1.28E-06 1.92E-06 9.35E-07 lbs/MMcf 2 33.78 35.45 0.00

Turbine, Natural/Ref. Gas 1 SVOC Phenol B3-v4 7.67E-03 7.16E-03 1.59E-02 7.48E-07 lbs/MMcf 2 109.78 115.21 0.00

Turbine, Natural/Ref. Gas 1 VOC Acetaldehyde A2-v1 8.84E-02 1.13E-01 1.62E-01 3.38E-03 lbs/MMcf 3 73.22 56.29 0.46

Turbine, Natural/Ref. Gas 1 VOC Ammonia B3-v0 1.07E+01 1.06E+01 1.13E+01 1.01E+01 lbs/MMcf 1 5.83 14.49 1.00

Turbine, Natural/Ref. Gas 1 VOC Benzene B2-v2 8.37E-02 7.44E-02 1.81E-01 1.32E-03 lbs/MMcf 4 103.09 65.50 0.01

Turbine, Natural/Ref. Gas 1 VOC Formaldehyde A2-v1 1.22E-01 9.23E-02 3.42E-01 2.48E-02 lbs/MMcf 3 80.89 62.17 0.57

Turbine, Natural/Ref. Gas 1 VOC Hydrogen Sulfide A3-v0 1.65E-01 1.64E-01 1.72E-01 1.59E-01 lbs/MMcf 1 4.20 10.44 0.00

Turbine, Natural/Ref. Gas 1 VOC Toluene B2-v2 6.54E-02 9.86E-03 1.87E-01 3.53E-03 lbs/MMcf 3 130.39 100.23 0.09

Turbine, Natural/Ref. Gas 1 VOC Xylene (m,p) A3-v1 5.96E-03 6.29E-03 1.04E-02 1.73E-03 lbs/MMcf 2 67.92 71.27 0.95

Turbine, Natural/Ref. Gas 1 VOC Xylene (o) A3-v0 1.68E-03 1.73E-03 1.96E-03 1.28E-03 lbs/MMcf 2 13.19 13.85 0.48

Turbine, Natural/Ref. Gas 1 VOC Xylene (Total) E3-v0 4.13E-01 4.14E-01 4.15E-01 4.11E-01 lbs/MMcf 1 0.50 1.23 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Acenaphthene A3-v0 6.56E-06 7.21E-06 7.72E-06 4.76E-06 lbs/MMcf 1 24.06 59.77 1.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Acenaphthylene A3-v0 4.21E-06 4.10E-06 4.82E-06 3.73E-06 lbs/MMcf 1 13.22 32.83 0.38

Turbine, Natural/Ref. Gas/Butane 1 PAH Anthracene A3-v0 4.94E-05 5.10E-05 5.49E-05 4.24E-05 lbs/MMcf 1 12.90 32.04 1.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(a)anthracene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(a)pyrene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(b)fluoranthene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(e)pyrene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(g,h,i)perylene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Benzo(k)fluoranthene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

183

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Natural/Ref. Gas/Butane 1 PAH Chrysene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Dibenz(a,h)anthracene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Fluoranthene A3-v0 1.79E-05 1.84E-05 1.88E-05 1.64E-05 lbs/MMcf 1 7.33 18.20 1.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Fluorene A3-v0 1.89E-05 1.97E-05 2.37E-05 1.34E-05 lbs/MMcf 1 27.37 68.00 1.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Indeno(1,2,3-cd)pyrene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Naphthalene A3-v0 1.30E-03 1.31E-03 1.41E-03 1.19E-03 lbs/MMcf 1 8.10 20.13 0.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Phenanthrene A3-v0 1.69E-04 1.80E-04 1.84E-04 1.42E-04 lbs/MMcf 1 13.94 34.63 1.00

Turbine, Natural/Ref. Gas/Butane 1 PAH Pyrene A3-v0 4.73E-05 4.56E-05 5.15E-05 4.48E-05 lbs/MMcf 1 7.77 19.30 1.00

Turbine, Natural/Ref. Gas/Butane 1 SVOC 2-Methylnaphthalene A3-v0 1.22E-04 1.23E-04 1.32E-04 1.12E-04 lbs/MMcf 1 8.18 20.32 0.00

Turbine, Natural/Ref. Gas/Butane 1 SVOC Ethylbenzene A3-v0 8.79E-03 7.30E-03 1.26E-02 6.42E-03 lbs/MMcf 1 38.33 95.22 1.00

Turbine, Natural/Ref. Gas/Butane 1 SVOC Perylene A3-v0 4.07E-06 4.10E-06 4.39E-06 3.73E-06 lbs/MMcf 1 8.18 20.33 0.00

Turbine, Natural/Ref. Gas/Butane 1 VOC Acetaldehyde C3-v0 3.00E-01 2.26E-01 4.90E-01 1.83E-01 lbs/MMcf 1 55.31 137.41 0.80

Turbine, Natural/Ref. Gas/Butane 1 VOC Benzene A3-v0 4.05E-03 3.15E-03 5.85E-03 3.15E-03 lbs/MMcf 1 38.39 95.36 0.48

Turbine, Natural/Ref. Gas/Butane 1 VOC Formaldehyde C3-v2 4.85E-01 5.65E-01 8.75E-01 1.56E-02 lbs/MMcf 1 89.69 222.80 0.00

Turbine, Natural/Ref. Gas/Butane 1 VOC Toluene A3-v0 1.97E-02 1.92E-02 2.27E-02 1.73E-02 lbs/MMcf 1 13.90 34.53 1.00

Turbine, Natural/Ref. Gas/Butane 1 VOC Xylene (m,p) A3-v0 8.60E-03 8.60E-03 8.60E-03 8.60E-03 lbs/MMcf 1 0.00 0.00 0.00

Turbine, Natural/Ref. Gas/Butane 1 VOC Xylene (o) A3-v0 4.94E-03 4.30E-03 6.22E-03 4.29E-03 lbs/MMcf 1 22.56 56.05 0.71

Turbine, Natural/Ref./LP Gas 1 Metals Arsenic B3-v0 1.70E-02 1.71E-02 1.79E-02 1.61E-02 lbs/MMcf 1 5.27 13.08 0.00

Turbine, Natural/Ref./LP Gas 1 Metals Beryllium B3-v0 3.40E-03 3.43E-03 3.57E-03 3.21E-03 lbs/MMcf 1 5.28 13.11 0.00

Turbine, Natural/Ref./LP Gas 1 Metals Cadmium B3-v0 7.41E-03 6.85E-03 8.94E-03 6.44E-03 lbs/MMcf 1 18.06 44.86 0.40

Turbine, Natural/Ref./LP Gas 1 Metals Copper B3-v1 4.08E-02 1.88E-02 8.74E-02 1.61E-02 lbs/MMcf 1 99.07 246.10 0.87

Turbine, Natural/Ref./LP Gas 1 Metals Lead B3-v0 6.82E-02 6.85E-02 7.16E-02 6.44E-02 lbs/MMcf 1 5.25 13.05 0.00

Turbine, Natural/Ref./LP Gas 1 Metals Manganese B3-v1 1.75E-01 9.89E-02 3.71E-01 5.58E-02 lbs/MMcf 1 97.56 242.36 1.00

Turbine, Natural/Ref./LP Gas 1 Metals Nickel B3-v1 2.78E-01 9.70E-02 6.60E-01 7.79E-02 lbs/MMcf 1 118.86 295.27 1.00

Turbine, Natural/Ref./LP Gas 1 Metals Selenium B3-v0 1.70E-02 1.71E-02 1.79E-02 1.61E-02 lbs/MMcf 1 5.27 13.08 0.00

Turbine, Natural/Ref./LP Gas 1 Metals Zinc B3-v0 4.12E-01 4.08E-01 6.80E-01 1.47E-01 lbs/MMcf 1 64.69 160.70 1.00

Turbine, Natural/Ref./LP Gas 1 SVOC Phenol C3-v1 5.80E-02 2.31E-02 1.45E-01 5.55E-03 lbs/MMcf 1 131.32 326.21 1.00

Turbine, Ref. Gas 1 Metals Arsenic B3-v0 4.09E-03 4.15E-03 4.18E-03 3.95E-03 lbs/MMcf 1 3.09 7.66 0.00

184

TABLE 19. POINT SOURCE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Maximum Minimum Unit Tests RSD, % Uncertainty,%

DetRatio

Turbine, Ref. Gas 1 Metals Beryllium B3-v0 2.05E-03 2.08E-03 2.08E-03 1.98E-03 lbs/MMcf 1 2.78 6.90 0.00

Turbine, Ref. Gas 1 Metals Cadmium B3-v0 7.41E-03 5.21E-03 1.29E-02 4.15E-03 lbs/MMcf 1 64.24 159.59 1.00

Turbine, Ref. Gas 1 Metals Chromium (Hex) C3-v0 2.04E-03 2.04E-03 2.05E-03 2.02E-03 lbs/MMcf 1 0.70 1.74 0.00

Turbine, Ref. Gas 1 Metals Chromium (Total) C3-v1 1.84E-02 1.01E-02 3.93E-02 5.93E-03 lbs/MMcf 1 98.65 245.07 0.82

Turbine, Ref. Gas 1 Metals Copper B3-v0 5.78E-02 5.49E-02 9.72E-02 2.12E-02 lbs/MMcf 1 65.90 163.70 1.00

Turbine, Ref. Gas 1 Metals Lead B3-v0 3.99E-02 4.15E-02 4.18E-02 3.64E-02 lbs/MMcf 1 7.62 18.93 0.30

Turbine, Ref. Gas 1 Metals Manganese B3-v1 1.80E-01 1.45E-01 3.40E-01 5.55E-02 lbs/MMcf 1 80.76 200.62 1.00

Turbine, Ref. Gas 1 Metals Mercury A3-v0 2.15E-02 1.55E-02 3.63E-02 1.27E-02 lbs/MMcf 1 59.94 148.90 1.00

Turbine, Ref. Gas 1 Metals Nickel B3-v0 2.33E-01 2.64E-01 2.86E-01 1.48E-01 lbs/MMcf 1 31.93 79.32 1.00

Turbine, Ref. Gas 1 Metals Selenium B3-v0 5.42E-03 4.18E-03 7.93E-03 4.15E-03 lbs/MMcf 1 40.11 99.64 0.00

Turbine, Ref. Gas 1 Metals Zinc B3-v0 6.99E+00 8.23E+00 9.17E+00 3.56E+00 lbs/MMcf 1 42.95 106.70 1.00

Turbine, Ref. Gas 1 SVOC Phenol C3-v0 9.41E-03 5.99E-03 1.72E-02 5.07E-03 lbs/MMcf 1 71.54 177.71 1.00

Turbine, Ref. Gas 1 VOC Acetaldehyde C3-v0 2.18E-02 2.22E-02 2.65E-02 1.67E-02 lbs/MMcf 1 22.53 55.97 1.00

Turbine, Ref. Gas 1 VOC Benzene C3-v0 1.49E-01 1.51E-01 1.53E-01 1.44E-01 lbs/MMcf 1 3.34 8.29 0.00

Turbine, Ref. Gas 1 VOC Formaldehyde C3-v0 8.41E-01 8.36E-01 8.90E-01 7.97E-01 lbs/MMcf 1 5.57 13.85 1.00

Turbine, Ref. Gas 1 VOC Hydrogen Sulfide A3-v0 1.63E-01 1.64E-01 1.67E-01 1.58E-01 lbs/MMcf 1 3.06 7.59 0.00

Turbine, Ref. Gas 1 VOC Toluene E3-v1 1.09E+00 4.34E-01 2.58E+00 2.56E-01 lbs/MMcf 1 118.63 294.68 1.00

Turbine, Ref. Gas 1 VOC Xylene (Total) E3-v1 3.14E+00 3.39E-01 8.85E+00 2.33E-01 lbs/MMcf 1 157.44 391.11 1.00

Unloader, Fiberboard 1 VOC Formaldehyde A3-v1 9.67E-03 1.21E-02 1.41E-02 2.82E-03 lbs/ton production 1 62.24 154.62 1.00

Det Ratio: Ratio of sum of detected values to the sum of detected and non-detected values.

RSD: 100 times the standard deviation divided by the arithmetic average

Uncertainty: 100 times the 95% confidence interval divided by the arithmetic average.

185

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Abrasive Blasting, Dust 1 Metals Arsenic A3-v3 6.58E+01 1.71E+00 4.00E-01 2.87E+02 mg/kg 1 175.03 105.77 1.00

Abrasive Blasting, Dust 1 Metals Beryllium A3-v1 2.42E-01 1.90E-01 3.00E-02 6.00E-01 mg/kg 1 88.72 53.62 0.97

Abrasive Blasting, Dust 1 Metals Cadmium A3-v3 4.94E+02 2.61E+01 2.13E+00 5.44E+03 mg/kg 1 303.19 183.21 1.00

Abrasive Blasting, Dust 1 Metals Chromium (Hex) A3-v2 2.35E+00 5.35E-01 2.70E-02 9.58E+00 mg/kg 1 149.50 94.99 1.00

Abrasive Blasting, Dust 1 Metals Copper A3-v3 2.06E+03 2.57E+02 1.47E+01 7.74E+03 mg/kg 1 140.67 85.00 1.00

Abrasive Blasting, Dust 1 Metals Lead A3-v2 8.52E+02 5.75E+02 4.97E+01 3.62E+03 mg/kg 1 109.77 66.33 1.00

Abrasive Blasting, Dust 1 Metals Manganese A3-v2 1.52E+02 1.36E+02 7.60E+00 5.12E+02 mg/kg 1 85.01 51.37 1.00

Abrasive Blasting, Dust 1 Metals Mercury A3-v2 3.62E-01 1.07E-01 6.00E-03 2.17E+00 mg/kg 1 180.99 115.00 1.00

Abrasive Blasting, Dust 1 Metals Nickel A3-v2 7.19E+01 4.42E+01 5.52E+00 3.68E+02 mg/kg 1 131.60 79.53 1.00

Abrasive Blasting, Dust 1 Metals Selenium A3-v0 2.00E+01 2.00E+01 2.00E+01 2.00E+01 mg/kg 1 0.00 0.00 0.00

Abrasive Blasting, Dust 1 Metals Zinc A3-v2 1.51E+03 1.20E+03 7.19E+01 4.96E+03 mg/kg 1 96.28 58.18 1.00

Aeration Basin, Wastewater 1 SVOC Ethylbenzene A3-v0 1.12E+00 1.15E+00 1.00E+00 1.17E+00 ppbv 1 7.04 11.21 1.00

Aeration Basin, Wastewater 1 VOC 1,1,1-Trichloroethane A3-v0 3.69E-01 3.60E-01 3.48E-01 4.09E-01 ppbv 1 7.30 11.61 1.00

Aeration Basin, Wastewater 1 VOC 1,2-Dichloroethane A3-v0 2.47E-01 2.47E-01 2.47E-01 2.47E-01 ppbv 1 0.00 0.00 0.00

Aeration Basin, Wastewater 1 VOC Acetaldehyde A3-v0 3.18E+00 3.24E+00 2.66E+00 3.60E+00 ppbv 1 12.50 19.89 1.00

Aeration Basin, Wastewater 1 VOC Ammonia B3-v0 2.13E+03 2.15E+03 1.88E+03 2.34E+03 ppbv 1 10.58 16.84 1.00

Aeration Basin, Wastewater 1 VOC Benzene A3-v0 1.09E+00 1.10E+00 1.06E+00 1.11E+00 ppbv 1 1.98 3.15 1.00

Aeration Basin, Wastewater 1 VOC Carbon Tetrachloride A3-v0 1.59E-01 1.59E-01 1.59E-01 1.59E-01 ppbv 1 0.00 0.00 0.00

Aeration Basin, Wastewater 1 VOC Chlorobenzene A3-v0 1.99E+00 2.00E+00 1.92E+00 2.06E+00 ppbv 1 2.94 4.67 1.00

Aeration Basin, Wastewater 1 VOC Chloroform A3-v0 2.05E-01 2.05E-01 2.05E-01 2.05E-01 ppbv 1 0.00 0.00 0.00

Aeration Basin, Wastewater 1 VOC Formaldehyde A3-v0 5.97E+00 5.68E+00 5.28E+00 7.26E+00 ppbv 1 14.76 23.49 1.00

Aeration Basin, Wastewater 1 VOC Freon 11 A3-v0 2.68E+00 2.68E+00 2.52E+00 2.82E+00 ppbv 1 4.83 7.69 1.00

Aeration Basin, Wastewater 1 VOC Hydrogen Sulfide A3-v0 1.44E+03 1.42E+03 1.39E+03 1.51E+03 ppbv 1 3.62 5.76 0.00

Aeration Basin, Wastewater 1 VOC Methylene Chloride A3-v0 1.47E+03 1.48E+03 1.41E+03 1.53E+03 ppbv 1 3.41 5.42 1.00

Aeration Basin, Wastewater 1 VOC p-Dichlorobenzene A3-v0 3.37E+01 3.38E+01 3.22E+01 3.50E+01 ppbv 1 3.76 5.98 1.00

Aeration Basin, Wastewater 1 VOC Tetrachloroethene A3-v0 9.72E-01 9.77E-01 9.46E-01 9.88E-01 ppbv 1 1.90 3.03 1.00

Aeration Basin, Wastewater 1 VOC Toluene A3-v0 4.20E+00 4.04E+00 3.76E+00 4.94E+00 ppbv 1 12.74 20.27 1.00

Aeration Basin, Wastewater 1 VOC Trichloroethene A3-v0 4.88E-01 4.90E-01 4.70E-01 5.00E-01 ppbv 1 2.58 4.11 1.00

186

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Aeration Basin, Wastewater 1 VOC Xylene (Total) A3-v0 3.94E+00 4.00E+00 3.64E+00 4.13E+00 ppbv 1 5.45 8.67 1.00

Asphalt Prod., Dust 1 Metals Arsenic D3-v0 4.50E+00 4.50E+00 3.80E+00 5.20E+00 mg/kg 2 22.00 197.65 1.00

Asphalt Prod., Dust 1 Metals Beryllium D3-v0 6.00E-01 6.00E-01 5.00E-01 7.00E-01 mg/kg 2 23.57 211.77 1.00

Asphalt Prod., Dust 1 Metals Cadmium D3-v0 1.90E+00 1.90E+00 1.90E+00 1.90E+00 mg/kg 2 0.00 0.00 1.00

Asphalt Prod., Dust 1 Metals Chromium (Hex) C2-v1 4.00E-02 1.00E-02 1.00E-02 1.00E-01 mg/kg 3 129.90 322.70 0.00

Asphalt Prod., Dust 1 Metals Chromium (Total) D3-v- 5.90E+01 5.90E+01 5.90E+01 5.90E+01 mg/kg 1 0.00 0.00 1.00

Asphalt Prod., Dust 1 Metals Copper D3-v0 1.70E+01 1.70E+01 1.20E+01 2.20E+01 mg/kg 2 41.59 373.71 1.00

Asphalt Prod., Dust 1 Metals Lead D3-v0 1.40E+01 1.40E+01 1.40E+01 1.40E+01 mg/kg 2 0.00 0.00 1.00

Asphalt Prod., Dust 1 Metals Manganese D3-v- 6.00E+02 6.00E+02 6.00E+02 6.00E+02 mg/kg 1 0.00 0.00 1.00

Asphalt Prod., Dust 1 Metals Mercury D3-v- 1.10E-01 1.10E-01 1.10E-01 1.10E-01 mg/kg 1 0.00 0.00 1.00

Asphalt Prod., Dust 1 Metals Nickel D3-v0 5.35E+01 5.35E+01 1.90E+01 8.80E+01 mg/kg 2 91.20 819.37 1.00

Asphalt Prod., Dust 1 Metals Zinc D3-v- 4.30E+01 4.30E+01 4.30E+01 4.30E+01 mg/kg 1 0.00 0.00 1.00

Composition, Crude oil 1 Metals Arsenic D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Beryllium D3-v- 1.98E+02 1.98E+02 1.98E+02 1.98E+02 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Cadmium D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Chromium (Hex) D3-v- 1.98E+01 1.98E+01 1.98E+01 1.98E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Chromium (Total) D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Copper D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Lead D3-v- 2.97E+02 2.97E+02 2.97E+02 2.97E+02 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Manganese D3-v- 2.97E+02 2.97E+02 2.97E+02 2.97E+02 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Mercury D3-v- 7.93E+00 7.93E+00 7.93E+00 7.93E+00 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Nickel D3-v- 1.29E+04 1.29E+04 1.29E+04 1.29E+04 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 Metals Phosphorus D3-v- 9.91E+03 9.91E+03 9.91E+03 9.91E+03 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 Metals Selenium D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 Metals Zinc D3-v- 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Acenaphthene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Acenaphthylene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Anthracene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

187

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Composition, Crude oil 1 PAH Benzo(a)anthracene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Benzo(a)pyrene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Benzo(b)fluoranthene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Benzo(g,h,i)perylene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Benzo(k)fluoranthene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Chrysene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 PAH Dibenz(a,h)anthracene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Fluoranthene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Fluorene C3-v- 1.88E+05 1.88E+05 1.88E+05 1.88E+05 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 PAH Indeno(1,2,3-cd)pyrene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 PAH Naphthalene C3-v- 8.82E+05 8.82E+05 8.82E+05 8.82E+05 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 PAH Phenanthrene C3-v- 2.48E+05 2.48E+05 2.48E+05 2.48E+05 ug/l 1 0.00 0.00 1.00

Composition, Crude oil 1 PAH Pyrene C3-v- 4.96E+04 4.96E+04 4.96E+04 4.96E+04 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 SVOC Ethylbenzene C3-v0 1.28E+06 1.28E+06 7.73E+05 1.78E+06 ug/l 1 55.91 502.34 1.00

Composition, Crude oil 1 VOC Benzene C3-v2 4.25E+05 3.57E+05 5.65E+03 9.12E+05 ug/l 2 107.57 267.21 1.00

Composition, Crude oil 1 VOC Propylene C3-v- 4.96E+03 4.96E+03 4.96E+03 4.96E+03 ug/l 1 0.00 0.00 0.00

Composition, Crude oil 1 VOC Toluene C3-v2 1.69E+06 1.49E+06 2.08E+04 3.57E+06 ug/l 2 105.36 261.72 1.00

Composition, Crude oil 1 VOC Xylene (Total) C3-v2 1.70E+06 1.49E+06 5.05E+04 3.57E+06 ug/l 2 103.93 258.17 1.00

Composition, Diesel 1 Metals Arsenic D3-v0 1.29E+02 1.29E+02 6.88E+01 1.89E+02 ug/l 2 66.00 592.95 0.73

Composition, Diesel 1 Metals Beryllium D3-v0 3.70E+02 3.70E+02 1.72E+02 5.68E+02 ug/l 2 75.64 679.63 0.77

Composition, Diesel 1 Metals Cadmium D3-v1 2.37E+02 2.37E+02 6.88E+01 4.04E+02 ug/l 2 100.28 900.98 0.85

Composition, Diesel 1 Metals Chromium (Hex) D3-v- 1.72E+01 1.72E+01 1.72E+01 1.72E+01 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 Metals Chromium (Total) D3-v0 3.27E+02 3.27E+02 1.72E+02 4.82E+02 ug/l 2 66.99 601.87 1.00

Composition, Diesel 1 Metals Copper D3-v0 5.55E+02 5.55E+02 3.35E+02 7.74E+02 ug/l 2 55.91 502.34 0.30

Composition, Diesel 1 Metals Lead D3-v0 4.17E+02 4.17E+02 2.58E+02 5.76E+02 ug/l 2 53.94 484.67 0.69

Composition, Diesel 1 Metals Magnesium C3-v- 1.72E+01 1.72E+01 1.72E+01 1.72E+01 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 Metals Manganese D3-v0 3.40E+02 3.40E+02 2.58E+02 4.21E+02 ug/l 2 34.01 305.59 0.62

Composition, Diesel 1 Metals Mercury D3-v- 6.88E+00 6.88E+00 6.88E+00 6.88E+00 ug/l 1 0.00 0.00 0.00

188

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Composition, Diesel 1 Metals Nickel D3-v0 5.68E+02 5.68E+02 4.47E+02 6.88E+02 ug/l 2 30.00 269.52 0.39

Composition, Diesel 1 Metals Phosphorus D3-v- 8.60E+03 8.60E+03 8.60E+03 8.60E+03 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 Metals Selenium D3-v1 9.55E+02 9.55E+02 6.88E+01 1.84E+03 ug/l 2 131.23 1179.04 0.96

Composition, Diesel 1 Metals Zinc D3-v2 2.14E+04 2.14E+04 6.19E+02 4.21E+04 ug/l 2 137.33 1233.82 1.00

Composition, Diesel 1 PAH Acenaphthene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Acenaphthylene C3-v- 2.58E+05 2.58E+05 2.58E+05 2.58E+05 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Anthracene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Benzo(a)anthracene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Benzo(a)pyrene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Benzo(b)fluoranthene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Benzo(g,h,i)perylene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Benzo(k)fluoranthene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Chrysene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Dibenz(a,h)anthracene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Fluoranthene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Fluorene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Indeno(1,2,3-cd)pyrene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Naphthalene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Phenanthrene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 PAH Pyrene C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 SVOC Ethylbenzene C3-v- 8.80E+05 8.80E+05 8.80E+05 8.80E+05 ug/l 1 0.00 0.00 1.00

Composition, Diesel 1 SVOC Phenol C3-v- 2.58E+06 2.58E+06 2.58E+06 2.58E+06 ug/l 1 0.00 0.00 0.00

Composition, Diesel 1 VOC Benzene C3-v- 1.80E+06 1.80E+06 1.80E+06 1.80E+06 ug/l 1 0.00 0.00 1.00

Composition, Diesel 1 VOC Toluene C3-v- 1.40E+06 1.40E+06 1.40E+06 1.40E+06 ug/l 1 0.00 0.00 1.00

Composition, Diesel 1 VOC Xylene (o) C3-v- 6.90E+05 6.90E+05 6.90E+05 6.90E+05 ug/l 1 0.00 0.00 1.00

Composition, Jp-4 1 Metals Arsenic C3-v- 3.28E+03 3.28E+03 3.28E+03 3.28E+03 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Beryllium C3-v- 4.10E+02 4.10E+02 4.10E+02 4.10E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Cadmium C3-v- 4.10E+02 4.10E+02 4.10E+02 4.10E+02 ug/l 1 0.00 0.00 0.00

189

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Composition, Jp-4 1 Metals Chromium (Total) C3-v- 9.84E+02 9.84E+02 9.84E+02 9.84E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-4 1 Metals Copper C3-v- 8.20E+02 8.20E+02 8.20E+02 8.20E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Lead C3-v- 1.64E+03 1.64E+03 1.64E+03 1.64E+03 ug/l 1 0.00 0.00 1.00

Composition, Jp-4 1 Metals Manganese C3-v- 4.10E+02 4.10E+02 4.10E+02 4.10E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Mercury C3-v- 2.05E+02 2.05E+02 2.05E+02 2.05E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Nickel C3-v- 8.20E+02 8.20E+02 8.20E+02 8.20E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Phosphorus C3-v- 3.77E+03 3.77E+03 3.77E+03 3.77E+03 ug/l 1 0.00 0.00 1.00

Composition, Jp-4 1 Metals Selenium C3-v- 8.20E+02 8.20E+02 8.20E+02 8.20E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-4 1 Metals Zinc C3-v- 2.87E+03 2.87E+03 2.87E+03 2.87E+03 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Arsenic C3-v- 5.74E+01 5.74E+01 5.74E+01 5.74E+01 ug/l 1 0.00 0.00 0.00

Composition, Jp-5 1 Metals Beryllium C3-v- 3.12E+02 3.12E+02 3.12E+02 3.12E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Cadmium C3-v- 2.30E+02 2.30E+02 2.30E+02 2.30E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Chromium (Total) C3-v- 3.69E+02 3.69E+02 3.69E+02 3.69E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Copper C3-v- 7.38E+02 7.38E+02 7.38E+02 7.38E+02 ug/l 1 0.00 0.00 0.00

Composition, Jp-5 1 Metals Lead C3-v- 2.05E+02 2.05E+02 2.05E+02 2.05E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Magnesium C3-v- 1.64E+01 1.64E+01 1.64E+01 1.64E+01 ug/l 1 0.00 0.00 0.00

Composition, Jp-5 1 Metals Manganese C3-v- 2.38E+02 2.38E+02 2.38E+02 2.38E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Nickel C3-v- 2.05E+02 2.05E+02 2.05E+02 2.05E+02 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Selenium C3-v- 1.39E+03 1.39E+03 1.39E+03 1.39E+03 ug/l 1 0.00 0.00 1.00

Composition, Jp-5 1 Metals Zinc C3-v- 4.18E+02 4.18E+02 4.18E+02 4.18E+02 ug/l 1 0.00 0.00 1.00

Composition, Lube Oil 1 Metals Arsenic D2-v0 8.59E+01 7.93E+01 7.93E+01 9.91E+01 ug/l 3 13.32 33.10 0.00

Composition, Lube Oil 1 Metals Beryllium D2-v0 1.65E+02 1.98E+02 9.91E+01 1.98E+02 ug/l 3 34.64 86.05 0.00

Composition, Lube Oil 1 Metals Cadmium D2-v0 9.41E+01 8.92E+01 7.93E+01 1.19E+02 ug/l 3 20.16 32.07 0.32

Composition, Lube Oil 1 Metals Chromium (Hex) D2-v0 2.97E+01 1.98E+01 1.98E+01 4.96E+01 ug/l 3 57.74 143.42 0.00

Composition, Lube Oil 1 Metals Chromium (Total) D3-v0 7.93E+01 7.93E+01 7.93E+01 7.93E+01 ug/l 2 0.00 0.00 0.00

Composition, Lube Oil 1 Metals Copper D2-v1 4.06E+02 3.62E+02 2.97E+01 8.72E+02 ug/l 3 85.59 136.19 1.00

Composition, Lube Oil 1 Metals Lead D2-v0 2.64E+02 2.97E+02 1.98E+02 2.97E+02 ug/l 3 21.65 53.78 0.00

Composition, Lube Oil 1 Metals Manganese D2-v0 2.64E+02 2.97E+02 1.98E+02 2.97E+02 ug/l 3 21.65 53.78 0.00

190

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Composition, Lube Oil 1 Metals Mercury D2-v0 5.95E+00 7.93E+00 1.98E+00 7.93E+00 ug/l 3 57.74 143.42 0.00

Composition, Lube Oil 1 Metals Nickel D2-v0 6.94E+02 7.93E+02 4.96E+02 7.93E+02 ug/l 3 24.74 61.47 0.00

Composition, Lube Oil 1 Metals Phosphorus D2-v0 1.24E+05 1.24E+05 4.96E+04 1.98E+05 ug/l 3 54.06 86.02 1.00

Composition, Lube Oil 1 Metals Selenium D2-v0 6.94E+01 7.93E+01 4.96E+01 7.93E+01 ug/l 3 24.74 61.47 0.00

Composition, Lube Oil 1 Metals Zinc D2-v2 6.37E+04 6.29E+04 3.07E+02 1.29E+05 ug/l 3 101.29 161.18 1.00

Composition, Produced water 1 SVOC Ethylbenzene A1-v2 1.43E+02 3.70E+01 1.70E+00 4.80E+02 ug/l 6 135.67 142.38 1.00

Composition, Produced water 1 VOC Ammonia B3-v- 1.00E+02 1.00E+02 1.00E+02 1.00E+02 ug/l 1 0.00 0.00 0.00

Composition, Produced water 1 VOC Benzene A1-v2 1.60E+03 1.75E+03 2.50E+01 2.60E+03 ug/l 6 62.25 65.33 1.00

Composition, Produced water 1 VOC Hydrogen Sulfide C3-v- 1.20E+03 1.20E+03 1.20E+03 1.20E+03 ug/l 1 0.00 0.00 1.00

Composition, Produced water 1 VOC Toluene A1-v2 6.93E+02 3.65E+02 7.80E+00 1.90E+03 ug/l 6 107.13 112.43 1.00

Composition, Produced water 1 VOC Xylene (Total) A1-v1 3.12E+02 9.35E+01 3.30E+01 1.10E+03 ug/l 6 135.65 142.36 1.00

Composition, Sour Water 1 VOC Ammonia B3-v0 2.30E+02 2.30E+02 1.60E+02 3.00E+02 ug/l 1 30.43 75.60 1.00

Composition, Sour Water 1 VOC Hydrogen Sulfide C3-v1 3.07E+05 3.42E+05 4.70E+04 5.32E+05 ug/l 1 79.67 197.91 1.00

Composition, Wastewater 1 SVOC Ethylbenzene A2-v2 4.06E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 143.83 49.83 0.01

Composition, Wastewater 1 VOC 1,1,1-Trichloroethane A2-v2 1.44E+02 2.50E+01 5.00E+00 9.00E+02 ug/l 4 176.12 61.02 0.82

Composition, Wastewater 1 VOC 1,1,2,2-Tetrachloroethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 1,1,2-Trichloroethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 1,1-Dichloroethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 1,1-Dichloroethene A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 1,2-Dichloroethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 1,2-Dichloroethene A2-v2 3.52E+01 5.00E+00 5.00E+00 2.50E+02 ug/l 3 193.02 81.51 0.00

Composition, Wastewater 1 VOC 1,2-Dichloropropane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 2-Chloroethyl Vinyl Ether A2-v2 7.47E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 157.76 54.66 0.00

Composition, Wastewater 1 VOC 2-Hexanone A2-v2 7.78E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC 4-Methyl-2-pentanone A2-v2 7.70E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 153.27 53.11 0.00

Composition, Wastewater 1 VOC Acetone A2-v3 1.27E+03 6.65E+02 1.10E+01 1.40E+04 ug/l 4 197.73 68.51 1.00

Composition, Wastewater 1 VOC Acrolein A2-v2 4.45E+02 1.00E+02 1.00E+02 5.00E+03 ug/l 3 244.16 114.27 0.00

Composition, Wastewater 1 VOC Acrylonitrile A2-v2 7.78E+02 5.00E+02 1.00E+02 5.00E+03 ug/l 4 151.38 52.45 0.00

191

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Composition, Wastewater 1 VOC Benzene A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Bromodichloromethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Bromoform A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Bromomethane A2-v2 7.78E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Carbon disulfide A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Carbon Tetrachloride A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Chlorobenzene A3-v0 5.00E+01 5.00E+01 5.00E+01 5.00E+01 ug/l 1 0.00 0.00 0.00

Composition, Wastewater 1 VOC Chloroethane A2-v2 7.78E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Chloroform A2-v2 3.91E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 150.55 52.16 0.02

Composition, Wastewater 1 VOC Chloromethane A2-v2 7.78E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC cis-1,3-Dichloropropene A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Dibromochloromethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Dichlorodifluoromethane A2-v2 3.89E+03 2.50E+03 5.00E+02 2.50E+04 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Methyl Ethyl Ketone A2-v2 7.88E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 149.96 51.96 0.05

Composition, Wastewater 1 VOC Methylene Chloride A2-v2 6.91E+01 2.50E+01 5.00E+00 9.20E+02 ug/l 4 240.78 83.42 0.44

Composition, Wastewater 1 VOC Styrene A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Tetrachloroethene A2-v2 3.97E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 147.49 51.10 0.05

Composition, Wastewater 1 VOC Toluene A2-v2 1.16E+02 5.00E+01 5.00E+00 4.50E+02 ug/l 4 128.50 44.52 0.75

Composition, Wastewater 1 VOC trans-1,2-Dichloroethene A3-v0 5.00E+01 5.00E+01 5.00E+01 5.00E+01 ug/l 1 0.00 0.00 0.00

Composition, Wastewater 1 VOC trans-1,3-Dichloropropene A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Trichloroethene A2-v2 4.11E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 141.83 49.14 0.06

Composition, Wastewater 1 VOC Trichlorofluoromethane A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Vinyl Acetate A2-v2 7.00E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 135.67 47.01 0.00

Composition, Wastewater 1 VOC Vinyl Chloride A2-v2 7.78E+01 5.00E+01 1.00E+01 5.00E+02 ug/l 4 151.38 52.45 0.00

Composition, Wastewater 1 VOC Xylene (Total) A2-v2 3.89E+01 2.50E+01 5.00E+00 2.50E+02 ug/l 4 151.38 52.45 0.00

DAF Tank, Wastewater 1 SVOC Ethylbenzene A3-v0 4.65E-01 4.76E-01 4.19E-01 4.89E-01 ppbv 1 6.73 10.71 1.00

DAF Tank, Wastewater 1 VOC 1,1,1-Trichloroethane A3-v0 1.86E-01 1.83E-01 1.83E-01 1.93E-01 ppbv 1 2.47 3.93 0.26

DAF Tank, Wastewater 1 VOC 1,2-Dichloroethane A3-v0 2.47E-01 2.47E-01 2.47E-01 2.47E-01 ppbv 1 0.00 0.00 0.00

192

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

DAF Tank, Wastewater 1 VOC Acetaldehyde A3-v0 4.48E+00 4.36E+00 4.18E+00 5.01E+00 ppbv 1 8.49 13.51 1.00

DAF Tank, Wastewater 1 VOC Ammonia B3-v0 2.99E+03 2.79E+03 2.39E+03 3.99E+03 ppbv 1 23.47 37.35 1.00

DAF Tank, Wastewater 1 VOC Benzene A3-v0 5.39E-01 5.40E-01 5.23E-01 5.51E-01 ppbv 1 2.18 3.46 1.00

DAF Tank, Wastewater 1 VOC Carbon Tetrachloride A3-v0 1.59E-01 1.59E-01 1.59E-01 1.59E-01 ppbv 1 0.00 0.00 0.00

DAF Tank, Wastewater 1 VOC Chlorobenzene A3-v0 2.17E-01 2.17E-01 2.17E-01 2.17E-01 ppbv 1 0.00 0.00 0.00

DAF Tank, Wastewater 1 VOC Chloroform A3-v0 2.05E-01 2.05E-01 2.05E-01 2.05E-01 ppbv 1 0.00 0.00 0.00

DAF Tank, Wastewater 1 VOC Formaldehyde A3-v0 2.65E+00 2.66E+00 2.45E+00 2.81E+00 ppbv 1 5.59 8.90 1.00

DAF Tank, Wastewater 1 VOC Freon 11 A3-v0 2.02E-01 2.02E-01 2.02E-01 2.02E-01 ppbv 1 0.00 0.00 0.00

DAF Tank, Wastewater 1 VOC Hydrogen Sulfide A3-v0 6.73E+02 6.60E+02 6.60E+02 7.10E+02 ppbv 1 3.72 5.92 0.00

DAF Tank, Wastewater 1 VOC Methylene Chloride A3-v0 6.02E+02 6.04E+02 5.78E+02 6.24E+02 ppbv 1 3.41 5.42 1.00

DAF Tank, Wastewater 1 VOC p-Dichlorobenzene A3-v0 1.25E+01 1.25E+01 1.19E+01 1.30E+01 ppbv 1 3.76 5.98 1.00

DAF Tank, Wastewater 1 VOC Tetrachloroethene A3-v0 3.88E-01 3.89E-01 3.78E-01 3.95E-01 ppbv 1 1.94 3.09 1.00

DAF Tank, Wastewater 1 VOC Toluene A3-v0 1.42E+00 1.37E+00 1.27E+00 1.68E+00 ppbv 1 12.76 20.31 1.00

DAF Tank, Wastewater 1 VOC Trichloroethene A3-v0 1.86E-01 1.86E-01 1.86E-01 1.86E-01 ppbv 1 0.00 0.00 0.00

DAF Tank, Wastewater 1 VOC Xylene (m,p) A3-v0 5.85E-01 5.83E-01 5.55E-01 6.20E-01 ppbv 1 4.70 7.48 1.00

DAF Tank, Wastewater 1 VOC Xylene (o) A3-v0 1.16E+00 1.18E+00 1.06E+00 1.22E+00 ppbv 1 6.48 10.30 1.00

Flanges, Crude oil 1 VOC Hydrogen Sulfide C3-v0 1.02E+04 1.02E+04 9.40E+03 1.10E+04 ppbv 1 11.09 99.66 1.00

Flanges, Field gas 1 SVOC Ethylbenzene B3-v1 8.05E+03 8.05E+03 2.10E+03 1.40E+04 ppbv 2 104.53 939.15 1.00

Flanges, Field gas 1 VOC Ammonia B3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Flanges, Field gas 1 VOC Benzene B3-v1 2.44E+05 2.44E+05 2.30E+04 4.65E+05 ppbv 2 128.08 1150.72 1.00

Flanges, Field gas 1 VOC Formaldehyde B3-v2 2.55E+02 2.55E+02 1.00E+01 5.00E+02 ppbv 2 135.88 1220.79 0.00

Flanges, Field gas 1 VOC Hydrogen Sulfide C3-v1 4.30E+03 4.30E+03 5.00E+02 8.10E+03 ppbv 2 124.98 1122.87 0.94

Flanges, Field gas 1 VOC Toluene B3-v1 1.91E+05 1.91E+05 5.70E+04 3.26E+05 ppbv 2 99.29 892.12 1.00

Flanges, Field gas 1 VOC Xylene (o) C3-v- 3.80E+03 3.80E+03 3.80E+03 3.80E+03 ppbv 1 0.00 0.00 1.00

Flanges, Field gas 1 VOC Xylene (Total) A3-v- 1.80E+04 1.80E+04 1.80E+04 1.80E+04 ppbv 1 0.00 0.00 1.00

Fugitive, Sulfur 1 VOC Hydrogen Sulfide C3-v0 6.85E+04 6.85E+04 5.80E+04 7.90E+04 ppbv 1 21.68 194.77 1.00

Fugitives, Casing/Natural Gas 1 Metals Arsenic B3-v0 1.87E-03 1.80E-03 1.80E-03 2.00E-03 ppbv 2 6.19 15.37 0.00

193

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Fugitives, Casing/Natural Gas 1 Metals Beryllium B3-v1 2.12E-01 3.01E-01 3.31E-02 3.01E-01 ppbv 2 73.07 181.53 0.00

Fugitives, Casing/Natural Gas 1 Metals Cadmium B3-v0 2.33E-04 2.00E-04 2.00E-04 3.00E-04 ppbv 2 24.74 61.47 0.00

Fugitives, Casing/Natural Gas 1 Metals Chromium (Hex) B3-v0 2.70E-03 2.60E-03 2.60E-03 2.90E-03 ppbv 2 6.42 15.94 0.00

Fugitives, Casing/Natural Gas 1 Metals Chromium (Total) B3-v0 2.70E-03 2.60E-03 2.60E-03 2.90E-03 ppbv 2 6.42 15.94 0.00

Fugitives, Casing/Natural Gas 1 Metals Copper B3-v0 1.13E-03 1.10E-03 1.10E-03 1.20E-03 ppbv 2 5.09 12.65 0.32

Fugitives, Casing/Natural Gas 1 Metals Lead B3-v0 1.70E-03 2.00E-03 1.10E-03 2.00E-03 ppbv 2 30.57 75.93 0.61

Fugitives, Casing/Natural Gas 1 Metals Manganese B3-v0 1.28E-02 1.24E-02 1.24E-02 1.36E-02 ppbv 2 5.41 13.45 0.00

Fugitives, Casing/Natural Gas 1 Metals Mercury B3-v0 1.00E-04 1.00E-04 1.00E-04 1.00E-04 ppbv 2 0.00 0.00 0.00

Fugitives, Casing/Natural Gas 1 Metals Nickel B3-v0 2.39E-02 2.31E-02 2.31E-02 2.54E-02 ppbv 2 5.56 13.82 0.00

Fugitives, Casing/Natural Gas 1 Metals Phosphorus B3-v0 3.15E-01 3.22E-01 3.01E-01 3.22E-01 ppbv 2 3.69 9.16 0.34

Fugitives, Casing/Natural Gas 1 Metals Selenium B3-v0 1.77E-03 1.70E-03 1.70E-03 1.90E-03 ppbv 2 6.54 16.24 0.32

Fugitives, Casing/Natural Gas 1 Metals Zinc B3-v0 5.87E-03 3.10E-03 3.10E-03 1.14E-02 ppbv 2 81.68 202.91 1.00

Fugitives, Casing/Natural Gas 1 PAH Acenaphthene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Acenaphthylene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Anthracene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Benzo(a)anthracene C3-v0 3.00E-04 3.00E-04 3.00E-04 3.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Benzo(a)pyrene C3-v0 2.67E-04 3.00E-04 2.00E-04 3.00E-04 ppbv 2 21.65 53.78 1.00

Fugitives, Casing/Natural Gas 1 PAH Benzo(b)fluoranthene C3-v0 3.00E-04 3.00E-04 3.00E-04 3.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Benzo(g,h,i)perylene C3-v0 2.00E-04 2.00E-04 1.00E-04 3.00E-04 ppbv 2 50.00 124.21 1.00

Fugitives, Casing/Natural Gas 1 PAH Benzo(k)fluoranthene C3-v0 3.00E-04 3.00E-04 3.00E-04 3.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Chrysene C3-v0 1.67E-04 2.00E-04 1.00E-04 2.00E-04 ppbv 2 34.64 86.05 1.00

Fugitives, Casing/Natural Gas 1 PAH Dibenz(a,h)anthracene C3-v0 2.33E-04 2.00E-04 2.00E-04 3.00E-04 ppbv 2 24.74 61.47 1.00

Fugitives, Casing/Natural Gas 1 PAH Fluoranthene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Fluorene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Indeno(1,2,3-cd)pyrene C3-v0 2.33E-04 2.00E-04 2.00E-04 3.00E-04 ppbv 2 24.74 61.47 1.00

Fugitives, Casing/Natural Gas 1 PAH Naphthalene C3-v0 2.05E-02 1.24E-02 1.24E-02 3.67E-02 ppbv 2 68.44 170.01 1.00

Fugitives, Casing/Natural Gas 1 PAH Phenanthrene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 PAH Pyrene C3-v0 2.00E-04 2.00E-04 2.00E-04 2.00E-04 ppbv 2 0.00 0.00 1.00

194

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Fugitives, Casing/Natural Gas 1 VOC Benzene C3-v0 1.03E+05 1.05E+05 1.01E+05 1.05E+05 ppbv 2 2.40 5.97 1.00

Fugitives, Casing/Natural Gas 1 VOC Hydrogen Sulfide C3-v0 2.16E+05 2.02E+05 2.02E+05 2.44E+05 ppbv 2 11.45 28.44 1.00

Fugitives, Casing/Natural Gas 1 VOC Propylene C3-v0 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 2 0.00 0.00 1.00

Fugitives, Casing/Natural Gas 1 VOC Toluene C3-v0 6.11E+04 5.39E+04 5.38E+04 7.55E+04 ppbv 2 20.47 50.85 1.00

Fugitives, Casing/Natural Gas 1 VOC Xylene (Total) C3-v0 4.79E+04 3.18E+04 3.17E+04 8.03E+04 ppbv 2 58.48 145.27 1.00

Gas Processing, Field gas 1 VOC Benzene C3-v0 1.55E+05 1.55E+05 1.50E+05 1.60E+05 ppbv 1 4.56 40.99 1.00

Gas Processing, Field gas 1 VOC Formaldehyde A3-v0 8.54E+02 8.71E+02 7.45E+02 9.47E+02 ppbv 1 11.97 29.73 1.00

Gas Processing, Field gas 1 VOC Hydrogen Sulfide C3-v0 3.35E+03 3.35E+03 2.10E+03 4.60E+03 ppbv 1 52.77 474.11 1.00

Gas Processing, Field gas 1 VOC Propylene C3-v0 4.11E+06 4.11E+06 4.05E+06 4.17E+06 ppbv 1 2.06 18.55 1.00

Gas Processing, Field gas 1 VOC Toluene C3-v0 1.60E+05 1.60E+05 1.60E+05 1.60E+05 ppbv 1 0.00 0.00 1.00

Gas Processing, Field gas 1 VOC Xylene (Total) C3-v0 1.75E+04 1.75E+04 1.70E+04 1.80E+04 ppbv 1 4.04 36.30 1.00

Gas Processing, Fuel Gas 1 Metals Arsenic D3-v2 3.84E+00 4.90E+00 3.27E-02 5.53E+00 ppbv 2 66.57 105.92 0.00

Gas Processing, Fuel Gas 1 Metals Beryllium D3-v0 8.50E+01 8.34E+01 8.05E+01 9.11E+01 ppbv 1 6.41 15.93 0.00

Gas Processing, Fuel Gas 1 Metals Cadmium D3-v2 8.96E+00 9.45E+00 4.35E-02 1.69E+01 ppbv 2 83.25 132.47 1.00

Gas Processing, Fuel Gas 1 Metals Chromium (Hex) D3-v0 1.32E+01 1.35E+01 1.25E+01 1.36E+01 ppbv 1 4.77 11.85 0.00

Gas Processing, Fuel Gas 1 Metals Chromium (Total) B3-v- 1.88E-01 1.88E-01 1.88E-01 1.88E-01 ppbv 1 0.00 0.00 1.00

Gas Processing, Fuel Gas 1 Metals Copper D3-v1 9.11E+00 1.16E+01 2.69E-01 1.29E+01 ppbv 2 65.06 103.53 0.00

Gas Processing, Fuel Gas 1 Metals Lead D3-v1 2.83E+00 3.56E+00 2.36E-01 3.96E+00 ppbv 2 61.49 97.84 0.00

Gas Processing, Fuel Gas 1 Metals Manganese D3-v3 1.32E+02 1.16E+02 2.67E-01 2.94E+02 ppbv 2 114.24 181.78 1.00

Gas Processing, Fuel Gas 1 Metals Mercury D3-v1 3.54E+00 1.08E+00 4.31E-01 1.16E+01 ppbv 2 152.35 242.42 0.82

Gas Processing, Fuel Gas 1 Metals Nickel D3-v1 9.90E+00 1.26E+01 4.58E-01 1.40E+01 ppbv 2 63.95 101.76 0.00

Gas Processing, Fuel Gas 1 Metals Selenium D3-v1 7.62E-01 9.30E-01 9.30E-02 1.09E+00 ppbv 2 59.69 94.99 0.00

Gas Processing, Fuel Gas 1 Metals Zinc D3-v0 9.54E+00 1.13E+01 3.03E+00 1.26E+01 ppbv 2 45.95 73.11 0.00

Gas Processing, Fuel Gas 1 SVOC Ethylbenzene C3-v- 1.80E+04 1.80E+04 1.80E+04 1.80E+04 ppbv 1 0.00 0.00 1.00

Gas Processing, Fuel Gas 1 VOC 1,1,1-Trichloroethane C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,1,2,2-Tetrachloroethane C3-v- 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,1,2-Trichloroethane C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,1-Dichloroethane C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

195

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Gas Processing, Fuel Gas 1 VOC 1,1-Dichloroethene C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,2,4-Trichlorobenzene C3-v- 3.50E+03 3.50E+03 3.50E+03 3.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,2-Dichloroethane C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 1,2-Dichloropropane C3-v- 4.00E+03 4.00E+03 4.00E+03 4.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 2-Hexanone C3-v- 2.50E+03 2.50E+03 2.50E+03 2.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC 4-Methyl-2-pentanone C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Acetone C3-v- 5.00E+03 5.00E+03 5.00E+03 5.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Ammonia B3-v0 3.21E+01 3.21E+01 3.21E+01 3.21E+01 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Benzene A1-v4 5.25E+05 1.10E+05 2.70E+02 1.40E+06 ppbv 5 121.41 93.33 1.00

Gas Processing, Fuel Gas 1 VOC Bromodichloromethane C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Bromoform C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Bromomethane C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Carbon disulfide C3-v- 5.00E+03 5.00E+03 5.00E+03 5.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Carbon Tetrachloride C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Chlorobenzene C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Chloroethane C3-v- 2.50E+03 2.50E+03 2.50E+03 2.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Chloroform C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Chloromethane C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC cis-1,2-Dichloroethene C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC cis-1,3-Dichloropropene C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Dibromochloromethane C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Dichlorodifluoromethane C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Freon 113 C3-v- 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Hydrogen Sulfide B2-v1 5.01E+02 2.70E+02 1.00E+02 1.36E+03 ppbv 3 108.91 91.05 0.24

Gas Processing, Fuel Gas 1 VOC Methyl Ethyl Ketone C3-v- 2.60E+03 2.60E+03 2.60E+03 2.60E+03 ppbv 1 0.00 0.00 1.00

Gas Processing, Fuel Gas 1 VOC Methylene Chloride C3-v- 3.00E+03 3.00E+03 3.00E+03 3.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Propylene A3-v0 1.00E+05 1.00E+05 1.00E+05 1.00E+05 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Styrene C3-v- 3.50E+03 3.50E+03 3.50E+03 3.50E+03 ppbv 1 0.00 0.00 0.00

196

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Gas Processing, Fuel Gas 1 VOC Tetrachloroethene C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Toluene A1-v4 1.28E+05 9.00E+04 6.00E+01 3.40E+05 ppbv 5 107.02 82.26 1.00

Gas Processing, Fuel Gas 1 VOC trans-1,2-Dichloroethene C3-v- 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC trans-1,3-Dichloropropene C3-v- 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Trichloroethene C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Trichlorofluoromethane C3-v- 5.00E+02 5.00E+02 5.00E+02 5.00E+02 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Vinyl Acetate C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Vinyl Chloride C3-v- 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Gas Processing, Fuel Gas 1 VOC Xylene (Total) A1-v3 1.22E+05 1.90E+04 7.50E+01 3.12E+05 ppbv 5 117.55 90.35 1.00

Gas Processing, Produced Gas 1 VOC Acetaldehyde C2-v1 4.10E+02 2.38E+02 4.25E+01 1.25E+03 ppbv 4 115.55 121.26 1.00

Gas Processing, Produced Gas 1 VOC Benzene A2-v0 6.85E+04 7.25E+04 3.40E+04 1.00E+05 ppbv 4 36.09 37.87 1.00

Gas Processing, Produced Gas 1 VOC Formaldehyde C2-v1 1.52E+01 1.16E+01 3.17E+00 2.98E+01 ppbv 4 74.45 78.13 1.00

Gas Processing, Produced Gas 1 VOC Hydrogen Sulfide C2-v2 5.42E+03 3.50E+03 2.00E+02 1.54E+04 ppbv 4 98.54 103.41 0.99

Gas Processing, Produced Gas 1 VOC Toluene A2-v1 3.91E+04 9.20E+03 5.00E+03 1.20E+05 ppbv 4 129.84 136.26 1.00

Gas Processing, Produced Gas 1 VOC Xylene (m,p) A2-v2 1.17E+04 3.90E+02 1.10E+02 3.60E+04 ppbv 4 151.73 159.23 1.00

Gas Processing, Produced Gas 1 VOC Xylene (o) A2-v3 6.22E+03 1.32E+02 3.20E+01 2.00E+04 ppbv 4 153.58 161.17 1.00

Headworks, Wastewater 1 VOC Hydrogen Sulfide A3-v0 7.05E+02 7.05E+02 7.00E+02 7.10E+02 ppbv 1 0.82 1.30 0.00

Main Trap, Produced Gas 1 VOC Benzene C3-v0 2.48E+04 2.48E+04 2.40E+04 2.56E+04 ppbv 1 4.56 40.99 1.00

Main Trap, Produced Gas 1 VOC Formaldehyde C3-v0 4.58E+02 4.29E+02 2.72E+02 6.73E+02 ppbv 1 44.13 109.62 1.00

Main Trap, Produced Gas 1 VOC Hydrogen Sulfide C3-v1 2.25E+03 2.25E+03 1.00E+02 4.40E+03 ppbv 1 135.14 1214.14 0.98

Main Trap, Produced Gas 1 VOC Propylene C3-v0 7.00E+06 7.00E+06 6.80E+06 7.20E+06 ppbv 1 4.04 36.30 1.00

Main Trap, Produced Gas 1 VOC Toluene C3-v0 2.92E+04 2.92E+04 2.70E+04 3.14E+04 ppbv 1 10.66 95.73 1.00

Main Trap, Produced Gas 1 VOC Xylene (Total) C3-v0 9.40E+03 9.40E+03 7.80E+03 1.10E+04 ppbv 1 24.07 216.27 1.00

PST, Wastewater 1 SVOC Ethylbenzene C3-v0 7.50E-01 7.50E-01 7.40E-01 7.60E-01 ppbv 1 1.54 2.45 1.00

PST, Wastewater 1 VOC 1,1,1-Trichloroethane C3-v0 3.20E-01 3.35E-01 1.83E-01 4.29E-01 ppbv 1 32.10 51.08 0.86

PST, Wastewater 1 VOC 1,2-Dichloroethane C3-v0 2.47E-01 2.47E-01 2.47E-01 2.47E-01 ppbv 1 0.00 0.00 0.00

PST, Wastewater 1 VOC Acetaldehyde A3-v0 7.43E+00 7.71E+00 4.92E+00 9.40E+00 ppbv 1 30.07 47.85 1.00

197

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

PST, Wastewater 1 VOC Ammonia B3-v0 1.90E+03 1.88E+03 1.06E+03 2.78E+03 ppbv 1 43.43 69.10 1.00

PST, Wastewater 1 VOC Benzene C3-v0 9.00E-01 9.00E-01 8.60E-01 9.40E-01 ppbv 1 4.54 7.22 1.00

PST, Wastewater 1 VOC Carbon Tetrachloride C3-v0 1.59E-01 1.59E-01 1.59E-01 1.59E-01 ppbv 1 0.00 0.00 0.00

PST, Wastewater 1 VOC Chlorobenzene C3-v1 7.08E-01 7.00E-01 1.10E-01 1.32E+00 ppbv 1 97.53 155.20 0.54

PST, Wastewater 1 VOC Chloroform C3-v0 2.05E-01 2.05E-01 2.05E-01 2.05E-01 ppbv 1 0.00 0.00 0.00

PST, Wastewater 1 VOC Formaldehyde A3-v0 6.91E+00 6.99E+00 4.86E+00 8.80E+00 ppbv 1 24.24 38.57 1.00

PST, Wastewater 1 VOC Freon 11 C3-v0 2.02E-01 2.02E-01 2.02E-01 2.02E-01 ppbv 1 0.00 0.00 0.00

PST, Wastewater 1 VOC Hydrogen Sulfide A3-v0 1.40E+03 1.42E+03 1.29E+03 1.45E+03 ppbv 1 5.15 8.20 0.00

PST, Wastewater 1 VOC Methylene Chloride C3-v0 2.29E+03 2.28E+03 2.08E+03 2.50E+03 ppbv 1 8.10 12.89 1.00

PST, Wastewater 1 VOC p-Dichlorobenzene C3-v1 1.71E+01 1.68E+01 3.71E+00 3.12E+01 ppbv 1 89.83 142.94 1.00

PST, Wastewater 1 VOC Tetrachloroethene C3-v0 2.90E-01 2.89E-01 1.48E-01 4.35E-01 ppbv 1 56.78 90.36 0.75

PST, Wastewater 1 VOC Toluene C3-v0 1.78E+00 1.78E+00 1.62E+00 1.94E+00 ppbv 1 9.33 14.84 1.00

PST, Wastewater 1 VOC Trichloroethene C3-v0 1.86E-01 1.86E-01 1.86E-01 1.86E-01 ppbv 1 0.00 0.00 0.00

PST, Wastewater 1 VOC Xylene (Total) C3-v0 3.00E+00 3.00E+00 2.92E+00 3.08E+00 ppbv 1 2.65 4.21 1.00

Solids odor processing, Sludge 1 SVOC Ethylbenzene A3-v0 3.88E-01 3.98E-01 3.48E-01 4.08E-01 ppbv 1 6.99 11.12 1.00

Solids odor processing, Sludge 1 VOC 1,1,1-Trichloroethane A3-v0 1.83E-01 1.83E-01 1.83E-01 1.83E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC 1,2-Dichloroethane A3-v0 2.47E-01 2.47E-01 2.47E-01 2.47E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Acetaldehyde A3-v0 1.78E+00 1.65E+00 1.40E+00 2.43E+00 ppbv 1 25.57 40.69 1.00

Solids odor processing, Sludge 1 VOC Benzene A3-v0 3.13E-01 3.13E-01 3.13E-01 3.13E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Carbon Tetrachloride A3-v0 1.59E-01 1.59E-01 1.59E-01 1.59E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Chlorobenzene A3-v0 2.17E-01 2.17E-01 2.17E-01 2.17E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Chloroform A3-v0 2.05E-01 2.05E-01 2.05E-01 2.05E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Formaldehyde A3-v0 2.96E+00 2.94E+00 2.15E+00 3.82E+00 ppbv 1 25.27 40.21 1.00

Solids odor processing, Sludge 1 VOC Freon 11 A3-v0 2.02E-01 2.02E-01 2.02E-01 2.02E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Hydrogen Sulfide A3-v0 7.15E+02 7.10E+02 7.10E+02 7.30E+02 ppbv 1 1.40 2.23 0.00

Solids odor processing, Sludge 1 VOC Methylene Chloride A3-v0 2.72E+02 2.73E+02 2.62E+02 2.82E+02 ppbv 1 3.41 5.43 1.00

Solids odor processing, Sludge 1 VOC p-Dichlorobenzene A3-v0 1.13E+01 1.13E+01 1.08E+01 1.17E+01 ppbv 1 3.76 5.98 1.00

Solids odor processing, Sludge 1 VOC Tetrachloroethene A3-v0 6.97E-01 7.00E-01 6.79E-01 7.10E-01 ppbv 1 1.90 3.02 1.00

198

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Solids odor processing, Sludge 1 VOC Toluene A3-v0 8.27E-01 7.97E-01 7.41E-01 9.75E-01 ppbv 1 12.76 20.30 1.00

Solids odor processing, Sludge 1 VOC Trichloroethene A3-v0 1.86E-01 1.86E-01 1.86E-01 1.86E-01 ppbv 1 0.00 0.00 0.00

Solids odor processing, Sludge 1 VOC Xylene (m,p) A3-v0 3.76E-01 3.74E-01 3.55E-01 3.99E-01 ppbv 1 4.93 7.85 1.00

Solids odor processing, Sludge 1 VOC Xylene (o) A3-v0 8.19E-01 8.34E-01 7.44E-01 8.62E-01 ppbv 1 6.52 10.38 1.00

Tank, Crude oil 1 SVOC Ethylbenzene A3-v1 3.20E+04 3.20E+04 4.00E+03 6.00E+04 ppbv 2 123.74 1111.79 1.00

Tank, Crude oil 1 VOC Acetaldehyde C1-v4 2.75E+04 7.40E+01 1.19E+01 2.47E+05 ppbv 9 299.45 230.18 1.00

Tank, Crude oil 1 VOC Acrolein C3-v- 2.00E+00 2.00E+00 2.00E+00 2.00E+00 ppbv 1 0.00 0.00 0.00

Tank, Crude oil 1 VOC Ammonia B2-v1 1.58E+03 4.12E+02 1.00E+02 3.49E+03 ppbv 3 100.11 92.59 0.01

Tank, Crude oil 1 VOC Benzene B1-v2 6.80E+05 7.70E+05 4.50E+03 1.90E+06 ppbv 17 90.67 41.27 1.00

Tank, Crude oil 1 VOC Chlorobenzene A3-v0 2.00E+00 2.00E+00 2.00E+00 2.00E+00 ppbv 1 0.00 0.00 0.00

Tank, Crude oil 1 VOC Formaldehyde C1-v4 2.17E+03 1.57E+01 2.00E+00 2.86E+04 ppbv 12 351.67 203.05 1.00

Tank, Crude oil 1 VOC Hydrogen Sulfide C1-v4 3.90E+04 1.70E+03 4.00E+01 2.44E+05 ppbv 15 184.09 88.73 0.93

Tank, Crude oil 1 VOC Propylene C1-v4 1.58E+06 2.50E+03 1.00E+03 6.50E+06 ppbv 5 185.03 154.69 1.00

Tank, Crude oil 1 VOC Toluene B1-v2 4.10E+05 4.50E+05 6.20E+03 1.20E+06 ppbv 17 88.22 40.16 0.94

Tank, Crude oil 1 VOC Xylene (m,p) A1-v1 1.02E+05 8.65E+04 3.80E+04 2.20E+05 ppbv 8 58.56 48.96 1.00

Tank, Crude oil 1 VOC Xylene (o) A1-v1 3.03E+04 2.70E+04 8.70E+03 5.70E+04 ppbv 8 54.35 45.43 1.00

Tank, Crude oil 1 VOC Xylene (Total) B1-v2 1.07E+05 2.70E+04 2.30E+03 3.66E+05 ppbv 9 118.84 71.82 1.00

Tank, Diluent 1 SVOC Ethylbenzene C3-v0 4.90E+04 4.90E+04 3.60E+04 6.20E+04 ppbv 1 37.52 337.10 1.00

Tank, Diluent 1 VOC 1,1,1-Trichloroethane C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,1,2,2-Tetrachloroethane C3-v0 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,1,2-Trichloroethane C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,1-Dichloroethane C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,1-Dichloroethene C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,2,4-Trichlorobenzene C3-v0 3.50E+03 3.50E+03 3.50E+03 3.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,2-Dichloroethane C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 1,2-Dichloropropane C3-v0 4.00E+03 4.00E+03 4.00E+03 4.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 2-Hexanone C3-v0 2.50E+03 2.50E+03 2.50E+03 2.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC 4-Methyl-2-pentanone C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

199

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Tank, Diluent 1 VOC Acetone C3-v0 5.00E+03 5.00E+03 5.00E+03 5.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Benzene C3-v0 5.45E+04 5.45E+04 5.20E+04 5.70E+04 ppbv 1 6.49 58.29 1.00

Tank, Diluent 1 VOC Bromodichloromethane C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Bromoform C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Bromomethane C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Carbon disulfide C3-v0 6.95E+03 6.95E+03 6.90E+03 7.00E+03 ppbv 1 1.02 9.14 1.00

Tank, Diluent 1 VOC Carbon Tetrachloride C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Chlorobenzene C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Chloroethane C3-v0 2.50E+03 2.50E+03 2.50E+03 2.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Chloroform C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Chloromethane C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC cis-1,2-Dichloroethene C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC cis-1,3-Dichloropropene C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Dibromochloromethane C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Dichlorodifluoromethane C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Freon 113 C3-v0 1.00E+03 1.00E+03 1.00E+03 1.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Methyl Ethyl Ketone C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Methylene Chloride C3-v0 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Styrene C3-v0 2.40E+03 2.40E+03 1.30E+03 3.50E+03 ppbv 1 64.82 582.37 0.00

Tank, Diluent 1 VOC Tetrachloroethene C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Toluene C3-v0 3.20E+04 3.20E+04 2.70E+04 3.70E+04 ppbv 1 22.10 198.53 1.00

Tank, Diluent 1 VOC trans-1,2-Dichloroethene C3-v0 2.00E+03 2.00E+03 2.00E+03 2.00E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC trans-1,3-Dichloropropene C3-v0 1.50E+03 1.50E+03 1.50E+03 1.50E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Trichloroethene C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Trichlorofluoromethane C3-v0 5.00E+02 5.00E+02 5.00E+02 5.00E+02 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Vinyl Acetate C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Vinyl Chloride C3-v0 1.30E+03 1.30E+03 1.30E+03 1.30E+03 ppbv 1 0.00 0.00 0.00

Tank, Diluent 1 VOC Xylene (Total) C3-v0 5.00E+04 5.00E+04 3.80E+04 6.20E+04 ppbv 1 33.94 304.95 1.00

200

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Tank, Distillate oil 1 VOC Benzene A3-v- 7.10E+02 7.10E+02 7.10E+02 7.10E+02 ppbv 1 0.00 0.00 1.00

Tank, Distillate oil 1 VOC Toluene A3-v- 3.70E+02 3.70E+02 3.70E+02 3.70E+02 ppbv 1 0.00 0.00 1.00

Tank, Distillate oil 1 VOC Xylene (Total) A3-v- 2.26E+02 2.26E+02 2.26E+02 2.26E+02 ppbv 1 0.00 0.00 1.00

Tank, Produced water 1 Metals Arsenic D3-v- 2.00E-03 2.00E-03 2.00E-03 2.00E-03 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Beryllium D3-v- 3.31E-02 3.31E-02 3.31E-02 3.31E-02 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Cadmium D3-v- 3.00E-04 3.00E-04 3.00E-04 3.00E-04 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Chromium (Hex) D3-v- 2.90E-03 2.90E-03 2.90E-03 2.90E-03 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Chromium (Total) D3-v- 2.90E-03 2.90E-03 2.90E-03 2.90E-03 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Copper D3-v- 1.20E-02 1.20E-02 1.20E-02 1.20E-02 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Lead D3-v- 7.00E-04 7.00E-04 7.00E-04 7.00E-04 ppbv 1 0.00 0.00 1.00

Tank, Produced water 1 Metals Manganese D3-v- 1.36E-02 1.36E-02 1.36E-02 1.36E-02 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Mercury D3-v- 1.00E-04 1.00E-04 1.00E-04 1.00E-04 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Nickel D3-v- 2.54E-02 2.54E-02 2.54E-02 2.54E-02 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Phosphorus D3-v- 3.01E-01 3.01E-01 3.01E-01 3.01E-01 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Selenium D3-v- 1.90E-03 1.90E-03 1.90E-03 1.90E-03 ppbv 1 0.00 0.00 0.00

Tank, Produced water 1 Metals Zinc D3-v- 1.90E-03 1.90E-03 1.90E-03 1.90E-03 ppbv 1 0.00 0.00 1.00

Tank, Produced water 1 PAH Naphthalene C3-v- 3.67E-02 3.67E-02 3.67E-02 3.67E-02 ppbv 1 0.00 0.00 1.00

Tank, Produced water 1 VOC Ammonia B3-v0 6.21E+02 3.80E+02 2.94E+02 1.45E+03 ppbv 2 74.08 77.74 0.63

Tank, Produced water 1 VOC Benzene B1-v2 4.19E+05 1.10E+05 1.70E+04 1.20E+06 ppbv 5 130.64 120.83 1.00

Tank, Produced water 1 VOC Hydrogen Sulfide C1-v4 1.12E+05 4.70E+03 4.00E+01 4.38E+05 ppbv 6 168.84 113.43 1.00

Tank, Produced water 1 VOC Propylene C3-v0 8.33E+02 1.00E+03 5.00E+02 1.00E+03 ppbv 2 34.64 86.05 0.20

Tank, Produced water 1 VOC Toluene B1-v2 1.34E+05 2.70E+04 6.00E+03 3.50E+05 ppbv 5 114.30 105.71 1.00

Tank, Produced water 1 VOC Xylene (m,p) A3-v1 9.10E+04 9.10E+04 1.20E+04 1.70E+05 ppbv 2 122.77 1103.06 1.00

Tank, Produced water 1 VOC Xylene (o) A3-v1 2.15E+04 2.15E+04 5.00E+03 3.80E+04 ppbv 2 108.53 975.12 1.00

Tank, Produced water 1 VOC Xylene (Total) C2-v1 8.70E+03 2.70E+03 1.00E+03 2.18E+04 ppbv 3 114.23 141.84 0.95

Tank, Wastewater 1 VOC Ammonia B3-v1 2.13E+02 2.13E+02 3.21E+01 3.94E+02 ppbv 2 120.14 1079.44 0.92

Tank, Wastewater 1 VOC Benzene A2-v5 4.77E+05 4.85E+05 2.10E+01 1.10E+06 ppbv 4 81.75 85.80 1.00

Tank, Wastewater 1 VOC Hydrogen Sulfide C3-v1 6.57E+03 6.57E+03 5.00E+02 1.26E+04 ppbv 2 130.65 1173.84 0.96

201

TABLE 20. FUGITIVE EMISSION FACTORS.

Major Group SubGroup

Category Substance ARBRating

Mean Median Minimum Maximum EF Unit Tests RSD, % Uncertainty,%

DetRatio

Tank, Wastewater 1 VOC Toluene A2-v4 3.02E+05 2.30E+05 1.60E+01 6.90E+05 ppbv 4 93.97 98.62 1.00

Tank, Wastewater 1 VOC Xylene (Total) A2-v4 9.59E+04 8.59E+04 3.05E+01 2.09E+05 ppbv 4 93.08 97.68 1.00

Det Ratio: Ratio of sum of detected values to the sum of detected and non-detected values.

RSD: 100 times the standard deviation divided by the arithmetic average

Uncertainty: 100 times the 95% confidence interval divided by the arithmetic average.