21
Disorder-induced entropic potential in a flux qubit quantum annealer Nicholas Chancellor* % , Philip J. D. Crowley* £ , Tanja Ðurić* $ , Walter Vinci* Mohammad H. Amin” , Andrew G. Green*, Paul A. Warburton*^, and Gabriel Aeppli & June 16, 2020 *London Centre For Nanotechnology, 19 Gordon Street, London UK, WC1H 0AH “ D-Wave Systems Inc. 3033 Beta Avenue Burnaby, British Columbia, Canada V5G 4M9 & Physics Department, ETH Zürich, Switzerland CH-8093; Institut de Physique, EPFL, Lausanne, Switzerland CH-1015; Paul Scherrer Institute, Villigen, Switzerland CH-5232 Department of Physics, Simon Fraser University, Burnaby, BC Canada V5A 1S6 ^Department of Electronic and Electrical Engineering, UCL, Torrington Place London UK WC1E 7JE % current affiliation: Department of Physics, Durham University, South Road, Durham, DH1 3LE £ current affiliation: Department of Physics, Boston University, Boston, MA 02215, USA $ current affiliation: Department of Physics, Faculty of Science, University of Zagreb, Bijeni˘ cka c. 32, 10000 Zagreb, Croatia Abstract In this manuscript we explore an experimentally ob- served statistical phenomenon by which domain walls on an Ising chain programmed onto a flux qubit quan- tum annealer tend toward a non-uniform distribu- tion. We find that this distribution can be theoret- ically well described by a combination of control er- rors and thermal effects. Interestingly, the effect that produces this distribution is purely entropic, as it ap- pears in cases where the average energy of all domain- wall locations is equal by definition. As well as being a counterintuitive statistical effect, we also show that our method can be applied to measure the strength of the noise on the device. The noise measured in this way is smaller than what is seen by other methods suggesting that the freeze time of a chain of coupled qubits on the device may be different than for iso- lated qubits with all couplings turned off, despite the fact that a qubit adjacent to a domain wall should effectively experience no coupling due to cancellation of the couplings one either side. Introduction The low energy states of natural systems can cor- respond to the solutions of computationally difficult problems [1]. Experiments suggest that these low en- ergy states can be accessed and measured by taking advantage of quantum mechanics, using a technique known as quantum annealing [2]. It is further sus- pected that quantum annealing could provide an im- provement over other methods for certain classes of interesting problems [3, 4]. To harness the power of quantum annealing, a machine may be constructed that has the same behavior as these natural systems. We refer to such a machine as an annealer. While the eventual outputs of annealers usually take dis- crete binary values, the parameters must be chosen from a continuous set of values. An annealer should therefore be considered an analog rather than a dig- ital computer. 1 arXiv:2006.07685v1 [quant-ph] 13 Jun 2020

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Page 1: Disorder …Disorder-inducedentropicpotentialinafluxqubitquantum annealer NicholasChancellor*%,PhilipJ.D.Crowley* $,TanjaÐurić* ,WalterVinci* MohammadH.Amin”z,AndrewG.Green

Disorder-induced entropic potential in a flux qubit quantumannealer

Nicholas Chancellor*%, Philip J. D. Crowley*£, Tanja Ðurić*$, Walter Vinci*Mohammad H. Amin”‡, Andrew G. Green*, Paul A. Warburton*^, and Gabriel Aeppli&

June 16, 2020

*London Centre For Nanotechnology, 19 GordonStreet, London UK, WC1H 0AH“ D-Wave Systems Inc. 3033 Beta Avenue Burnaby,British Columbia, Canada V5G 4M9&Physics Department, ETH Zürich, SwitzerlandCH-8093; Institut de Physique, EPFL, Lausanne,Switzerland CH-1015; Paul Scherrer Institute,Villigen, Switzerland CH-5232‡Department of Physics, Simon Fraser University,Burnaby, BC Canada V5A 1S6^Department of Electronic and ElectricalEngineering, UCL, Torrington Place London UKWC1E 7JE% current affiliation: Department of Physics,Durham University, South Road, Durham, DH1 3LE£current affiliation: Department of Physics, BostonUniversity, Boston, MA 02215, USA$ current affiliation: Department of Physics, Facultyof Science, University of Zagreb, Bijenicka c. 32,10000 Zagreb, Croatia

Abstract

In this manuscript we explore an experimentally ob-served statistical phenomenon by which domain wallson an Ising chain programmed onto a flux qubit quan-tum annealer tend toward a non-uniform distribu-tion. We find that this distribution can be theoret-ically well described by a combination of control er-rors and thermal effects. Interestingly, the effect thatproduces this distribution is purely entropic, as it ap-

pears in cases where the average energy of all domain-wall locations is equal by definition. As well as beinga counterintuitive statistical effect, we also show thatour method can be applied to measure the strength ofthe noise on the device. The noise measured in thisway is smaller than what is seen by other methodssuggesting that the freeze time of a chain of coupledqubits on the device may be different than for iso-lated qubits with all couplings turned off, despite thefact that a qubit adjacent to a domain wall shouldeffectively experience no coupling due to cancellationof the couplings one either side.

Introduction

The low energy states of natural systems can cor-respond to the solutions of computationally difficultproblems [1]. Experiments suggest that these low en-ergy states can be accessed and measured by takingadvantage of quantum mechanics, using a techniqueknown as quantum annealing [2]. It is further sus-pected that quantum annealing could provide an im-provement over other methods for certain classes ofinteresting problems [3, 4]. To harness the power ofquantum annealing, a machine may be constructedthat has the same behavior as these natural systems.We refer to such a machine as an annealer. Whilethe eventual outputs of annealers usually take dis-crete binary values, the parameters must be chosenfrom a continuous set of values. An annealer shouldtherefore be considered an analog rather than a dig-ital computer.

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Precision of controls is a fundamental issue in ana-log computing, not present in its digital counterpart[5]. It is therefore interesting to ask what new com-plications these errors may add. One could hope,for example, that small uncorrelated control errorssimply average out, and will therefore not have a no-ticeable effect as long as they are below a threshold[6].

We examine experimentally the effect of controlerrors on the annealer constructed by D-Wave Sys-tems, which mimics an Ising spin system. Our ex-periment shows a non-uniform distribution within aground state manifold that can be explained by clas-sical Boltzmann distributions under the influence offield control errors, demonstrating that even small er-rors affect the solution to strikingly simple problems.We find that even a domain wall in a one-dimensionalsystem subject to uncorrelated field control errorsyields a non-trivial U-shaped domain wall distribu-tion. An effective potential for the domain walls isgenerated by combinatoric effects in the averagingover disorder in the Hamiltonian. In this sense thephenomenon that we observe is due to an entropic po-tential. While it can be easily demonstrated that theaverage domain wall energy is the same at every site,the average value of the partition function is smallerfor noise realizations where the domain wall is likelyto be near the end of the chain, and there are moreconfigurations where the lowest energy configurationhas the domain wall near the end, therefore the prob-ability of observing it in this position is higher. Thiscan be thought of as finite size effect which is similarto order by disorder which occurs in infinite systems,where the term was originally used [7] to describeentropic effects of the thermal distribution. We fur-ther demonstrate that this distribution can be usedto measure noise in the device and discuss the ad-vantages over the conventional method of examiningsingle qubit auto-correlation.

Quantum annealing, computation based on slowlyvarying the Hamiltonian of a quantum system, hasgained a lot of experimental attention recently, [8,9, 10, 11, 12, 13, 14, 15]. This is understandablegiven the wide variety of applications, from tradi-tional computer science problems [14, 16], to moreexotic uses such as aiding genetic algorithms to calcu-

late radar waveforms [15], search engine ranking [17],graph isomorphism [12], and portfolio optimization[18]. In addition, thermal sampling using a quan-tum annealer, which is effectively what this paper isstudying, is highly relevant to many machine learn-ing and statistical inference tasks [19, 20, 21, 22, 23,24, 25].

One difficulty with quantum annealing, however,is that it must be implemented in analog physicalsystems, and therefore any implementation is subjectto random control errors. We define a control error asany case where the final Hamiltonian implemented bythe system differs from that which the user intended.As the name suggests, these errors could arise fromintrinsic inaccuracies in controls. An example wouldbe specifying a problem at a higher precision thanavailable on the physical hardware. Long timescalenoise should also be considered a source of controlerror; this noise will be indistinguishable from theproblem being mis-specified by the device.

There is a growing literature on error correction inquantum annealing. Most of these studies focus uponthe effect of coupling to an external bath rather thancontrol errors [26, 28, 29, 30, 31]. The work in [6,33, 32] does mention techniques that can reduce theeffect of control errors, at the cost of some overhead,but cannot completely eliminate them.

Since control errors are unavoidable in a realisticsystem, it is imperative that we understand the na-ture of these errors and their effects on computation.The study in [6] focuses mainly upon reduction ofcontrol errors without systematically identifying theirroot cause.

We demonstrate that the effects of control errorscan be counter-intuitive, giving non-uniform distri-butions within a degenerate manifold even for un-correlated errors. We further argue that this effectcaptures error-causing noise that would be missed ifwe try to measure the errors with a different protocol.

The hardware that we use implements a transversefield Ising model with a time-dependent Hamiltonianof the form,

H(t) = −A(t)∑i=1

σxi +B(t)Hprob, (1)

where Hprob is a user-specified Ising Hamiltonian,

2

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...+h -h1 2 N-1 N

-J

Figure 1: Illustration of the Hamiltonian we studyshowing one of the ground states assuming that h > Jand the qubits on the end satisfy the applied fields.Numbers indicate domain-wall sites.

which is diagonal in the z basis, and A(t), B(t) arethe annealing schedule, the time dependences thatcontrol the relative strength of each term.

The specific problem instance that we choose tostudy is a ferromagnetic chain with opposing fieldson either end as shown in Fig. 1. As long as h > J ,Hprob will have an (N − 1)-fold degenerate groundstate manifold consisting of all states with a singledomain wall; | ↑↓↓ . . . ↓〉 ,| ↑↑↓ . . . ↓〉 ... | ↑↑ . . . ↑↓〉. This same system has been shown in [34] to bean effective method to encode discrete variables. Inour experiments, we use h = 2 J with a problemHamiltonian of the form

Hprob = J

N∑i=1

−σzi σzi+1 + h (σz1 − σzN+1). (2)

We focus upon control errors arising from straymagnetic fields from free spins and dangling bondswithin the materials that make up the QPU. Thiscould be considered equivalent to adding a term ofthe form,

Hfields =∑i

ζi σzi , (3)

to the overall Hamiltonian, where ζi are uncorre-lated and Gaussianly distributed with a standard de-viation σζ � J and zero mean ζi = 0. The over-line indicates an ensemble average. One can alsoconsider coupler control errors of the form H =∑i ζ

(J)i σzi σ

zi+1, where ζ(J)

i satisfy the same condi-tions as ζi with a standard deviation σJ � J . Thistype of control error produces an uncorrelated po-tential for the domain walls, and therefore has noeffect upon the shape of the mean thermal domain-wall distribution. We demonstrate this in Sec. 2.1 of

the supplemental material. It is worth noting brieflythat [10] describes a similar experiment, but with thegoal of demonstrating quantum tunneling. A quali-tatively similar domain wall distribution to the onethat we see can be found in the supplemental mate-rial of that paper, although there is no discussion ofthe distribution.

One concept that helps explain the behaviour ofthese systems is freeze time, which is the time atwhich the dynamics of the QPU effectively stop andthe spins are effectively fixed. Because the deviceappears to be reaching thermal equilibrium in theseexperiments, we can think of these experiments asmeasuring the ratio of the noise level to the devicetemperature at the freeze time. Since the suscepti-bility of flux qubits to external noise will, in general,be different at different points in the experiment, thefreeze time is an important (but not directly measur-able) parameter.

Theoretical Analysis

While the domain-wall distributions considered inour study can be easily obtained through numericalsampling, it is informative to perform an analyticalcalculation. Let us start by considering the energycontribution from the field control errors in the caseof a single domain wall on the nth coupler in thechain, En =

∑Ni=1 sign(n− i+ 0.5) ζi. The difference

in energy between two domain-wall positions is there-fore En − Em = 2

∑ni=m+1 ζi where n > m.

Assuming that ζi = 0 and ζ2i = ζ2, we note that

En − Em = 2∑ni=m+1 ζi = 0, but

(En − Em) (En − Ek)

= 4 ζ2 min(|n−k|, |n−m|) Θ [(n− k)(n−m)] , (4)

where Θ is a Heaviside theta. Note that this for-mula explicitly demonstrates that the domain wallenergies are correlated, even for uncorrelated fields.Also note that for a Gaussian distribution ζ2 = σ2

ζ .The probability of finding a domain wall at site n ina thermal ensemble averaged over noise is given by

Pn = Z−1e−β En =[1 +

∑m 6=n e

−β (Em−En)]−1

.

3

Page 4: Disorder …Disorder-inducedentropicpotentialinafluxqubitquantum annealer NicholasChancellor*%,PhilipJ.D.Crowley* $,TanjaÐurić* ,WalterVinci* MohammadH.Amin”z,AndrewG.Green

Let us now consider a high-temperature approxi-mation to obtain an analytical formula. By expand-ing this probability to second order in β = 1

kBTand

applying Eq. (4) we obtain

Pn ≈ P + β2 ζ22

N2

(n− N + 1

2

)2

(5)

where P = 1N −

β2

N3 ζ2( 54N

3 +N2 + 16N + 1). This

demonstrates that even small field control errors cre-ate a parabolic (U-shaped) distribution of domainwalls. Simple, uncorrelated errors can have a highlynon-trivial effect on the equilibrium behavior of asimple domain-wall system. Note that this calcu-lation relies upon the assumption that the systemis in thermal equilibrium. We justify this assump-tion numerically in Sec. 2.2 of the supplemental ma-terial that accompanies this manuscript. We alsodemonstrate other derivations at finite and zero tem-perature in Sec. 2.3 and 2.4 of the supplementalmaterial. The expansion used in Eq. (5) is onlyguaranteed to be valid for temperatures much higherthan the maximum difference in domain-wall ener-gies, β ζ

√N � 1. We therefore expect that this

approximation will break down for long chains, andwe experimentally demonstrate this breakdown in thepaper.

This phenomenon is interesting as an experimen-tal tool, because it provides a way of directly mea-suring the effect of the control errors on the evolu-tion of a non-trivial Hamiltonian. For this reason, weshould expect that the control errors measured thisway should give a more accurate portrayal of the er-rors experienced in a real computation than in singlequbit methods.

Results

Let us first consider what happens when an individualinstance of the Hamiltonian shown in Fig. 1 is usedas the problem Hamiltonian in a quantum annealingprotocol. Fig. 2 demonstrates an example of suchan experiment, in particular of the same chain runrepeatedly over time with no gauge averaging. Thedistribution of domain walls is non-uniform, as should

2.9 2.91 2.92 2.93 2.94 2.950

5000

10000

Co

un

ts

2.961 2.962 2.963 2.964

t-tstart

(seconds x 10 5 )

0

5000

10000

Figure 2: Experimentally observed domain-wallcounts for a single embedding and gauge choice ver-sus sample time for a 10-qubit chain (domain wallsites are color coded in cartoon). Top and bottomare different time scales. Error bars on the bottomfigure are standard deviation of the mean, and aresuppressed in the top figure for clarity. Dashed linesin the top figure represent times when the systemupdates an internal self correction of biases.

be expected in the presence of control errors. To mostclearly observe U-shaped distribution and avoid ef-fects such as local variations in qubits and couplers,we average over different chains and gauges. It is alsoworth noting from this figure that the deviation be-tween runs is much larger than that expected purelyfrom fluctuations due to finite system size. This indi-cates that the control error has components that arefaster than the time between samples. Fast errorsare more difficult to detect, as well as to remove. Formore discussion on this subject, see Sec. 2.6 of thesupplemental material.

The difference in domain-wall probabilities in Fig.2 is due to a combination of control errors, of the formgiven in Eq. 3, and coupler control errors. However,as we have previously demonstrated, measuring theaverage domain-wall distribution removes the effectof coupler errors, allowing us to measure only thefield errors.

We now examine an averaged version of thedomain-wall system. Fig. 3 displays the results from

4

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running the QPU with the final Hamiltonian corre-sponding to the chain configuration shown in Fig.1, while averaging over many embedding and gaugechoices. An embedding corresponds to a process ofmapping a problem on a QPU such that every vari-able of the problem is represented by a subset of thequbits on the QPU. Note that chains can always beembedded in a one-to-one fashion, where every log-ical variable corresponds to one physical qubit; thisis not true for more complicated graphs for whichembedding is a more involved process [36]. Gaugechoices arise due to an invariance of the target Hamil-tonian under flips in the sign of a particular spin andthe corresponding local field and couplings betweenit and other spins. This averaging is explained in theMethods section and Sec. 1.1 of the accompanyingsupplemental material.

This experiment yields a U-shaped distribution,with the probability for the domain wall to be locatedat the very end of the chain suppressed. The sup-pression is predicted from well understood rf-SQUIDbackground susceptibility effects, and can be removedby applying a simple linear correction. For more de-tails see Sec. 1.2 of the supplemental material. Simi-larly we can perform the same experiments on a muchlarger chain, Fig. 4 shows the behaviour of such achain, were the distribution deviates from parabolicdue to the breakdown of the underlying assumptionsbehind Eq. (5).

Returning to analysis of the 10-qubit chain, theexperimental data match the numerical data ob-tained by Boltzmann sampling over field noise of thetype in Eq. (3) with σζ

T = 0.24. This fitting wasperformed against numerical sampling results ratherthan Eq. (5) to allow for higher-order corrections.Specifically, the fitting was performed by numericallysampling over disorder realizations and varying theparameter σζ

T until the least squares error with theexperimental distribution was minimized. By con-trast, a naive estimate made by sampling uncoupledqubit polarization yields σζ

T = 0.13. This is likely tobe because each sample is averaged over many an-nealing runs and is therefore blind to any errors witha timescale less than the time to sample, which isapproximately 1 second. A more sophisticated anal-ysis based upon calculating autocorrelation via the

0 2 4 6 8 100.102

0.104

0.106

0.108

0.11

0.112

0.114

0.116

0.118

0.12

0.122

Site Number, i

Pd

w(i)

Figure 3: Domain-wall probability distributions for10-qubit frustrated chain. Crosses are raw experi-mental data. Asterisks are the same with a correc-tion applied for background susceptibility. Circlesare numerically calculated data from sampling Boltz-mann distributions with field noise of the form Eq. (3)with σζ

T = 0.2363 as well as the weak transverse fieldpresent at the freeze time. Lines joining points are aguide to the eye.

0 5 10 15 20 25 30 35 40 45 500.017

0.018

0.019

0.02

0.021

0.022

0.023

0.024

0.025

0.026

0.027

Site Number

Pdw

Figure 4: Domain-wall distribution for a 50-qubit chain using the same experimental setup asFig. 3 (including background susceptibility correc-tions) Dashed line is a parabolic fit. Error bars arestandard error.

5

Page 6: Disorder …Disorder-inducedentropicpotentialinafluxqubitquantum annealer NicholasChancellor*%,PhilipJ.D.Crowley* $,TanjaÐurić* ,WalterVinci* MohammadH.Amin”z,AndrewG.Green

Fourier transform of the single-qubit results yieldsσζT = 0.35 (see Sec. 1.3 of the supplemental materialfor details). This method is expected to be sensitiveto a wider bandwidth of errors than the naive mea-surement, but should still be blind to any noise fasterthan the Nyquist interval, which in this case is about178µs.

Autocorrelation measures more error than thedomain-wall technique. One possible interpretationof these data could be that the single qubit actuallyhas a later freeze time than expected, but more ex-periments are required to say this conclusively. Wedemonstrate later, however, that correlations whichremain after gauge averaging are not a viable expla-nation.

Methods based on measuring the U-shaped distri-bution can further be used to address questions aboutthe source of the control error. For example, we canmeasure the coupling dependence of the field controlerror by fixing the gauge of the chain and averagingover only embeddings. With a fixed gauge, we mustuse a different embedding strategy to reduce corre-lations in the control errors caused by embedding toqubits in the same unit cell, see Sec. 1.1 of the supple-mental material. As Fig. 5 demonstrates, the depthof the U is different depending upon the gauge, thisis consistent with measurements performed by othersthat indicate that ferromagnetic couplers should cou-ple more strongly to noise [2]. It is interesting to notethat our method of measuring the coupler-dependentportion of the control error does not require opera-tion of the control lines outside of the preprogrammedannealing schedule of the device, while the methodemployed by [2] does.

For the U-Shaped distribution to be useful to mea-sure field control errors requires the underlying as-sumption that the errors are uncorrelated. Mosttypes of correlation between nearby qubits will beremoved by the process of gauge averaging. How-ever, coupler-mediated errors from a shared couplermay depend on the state (ferro or anti-ferro) of thecoupler [2], and therefore may contain some correla-tions that survive gauge averaging. We suspect thatthis part of the error should be relatively small be-cause these correlations will only come from one ofthe 6 to 8 couplers connected to a given qubit, and

0 2 4 6 8 100.102

0.104

0.106

0.108

0.11

0.112

0.114

0.116

0.118

0.12

0.122

Site Number

Pd

w

random gauge

ferromagnetic gauge

antiferromagnetic gauge

Figure 5: Domain-wall distribution with differentgauge choices. X represents data taken in the gaugewhich all couplers are anti-ferromagnetic. Asterisksare averaged over random gauges. Circles are datataken in the gauge in which all couplers are ferro-magnetic. All data in this figure have been correctedfor background susceptibility.

only a fraction of the error from each coupler is statedependent [2].

It is still worth checking experimentally if state-dependent errors have a significant effect. Fig. 6demonstrates that the depth of the distribution doesnot change within statistical error when the strengthof the coupling is reduced by a factor of 2. If therewere a strong component of the control error whichdepended on the state of the couplers, we would ex-pect a substantial difference between the depth ofthese two distributions.

Conclusions

The effects studied here occur even for completely un-correlated errors, and provide an example of a finitesize analog to order by disorder. The most strikingfeature of this behavior is that it can be observed fora very simple Ising Hamiltonian in thermal equilib-rium.

We further examine how measurements of the Udistribution can can be used as a direct measurementof control errors. This method has the advantagethat it runs with the standard annealing protocol, re-

6

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0 2 4 6 8 10−2

0

2

4

6

8

10

12x 10

−3

i

Pd

w(i)−

Pd

w(5

)

|J|=1

|J|=0.5

Figure 6: Difference between domain wall probabil-ity on site i from the probability that domain wall isfound on site 5 for two scales of the coupling. Notethat background susceptibility corrections have notbeen performed.

quiring no privileged access to the control lines, andmeasures the component of the noise which acts ascontrol error by construction, with no frequency cut-off that depends on the annealing time. The secondof these observations means that this method couldbe used for arbitrarily long annealing times to ob-serve deviations from the user-specified fields duringthe annealing process. In spite of the fact that ourmethod should be sensitive to a wider spectrum ofnoise, it measures less noise than we observe using acurrently established method. Our method measuresdifferent error levels than the established methods,one possible explanation for both of these observa-tions is that the single qubit freezes at a different timethan expected; more experiments are required to saythis conclusively. While it is known that freeze timecan effectively vary locally depending on coupling, ashas been observed experimentally [38], it is unclearwhether this should be expected in our domain-wallcase, since the coupling experienced by a qubit adja-cent to a domain wall should effectively cancel out.

Methods

The data in Fig. 3 were taken on the USC Infor-mation Sciences Institute Vesuvius 6 D-Wave QPU.

Except where otherwise stated, these data were av-eraged over gauges, as well as over ways of embed-ding on the QPU. For more details about the em-bedding see Sec. 1.2 of the supplemental material.Data in Fig. 2 were taken using a QPU intermediatebetween the Vesuvius and Washington QPU gener-ations made available by D-Wave Systems Inc. Alldata were taken using an annealing time of 20µs. Allindividual data sets are taken with 10,000 annealingruns.

Acknowledgments

The authors would like to thank Trevor Lanting,Murray Thom, Anatoly Smirnov, Stefan Zohren, andJack Raymond for useful discussion. NC was sup-ported by Lockheed Martin corporation and EP-SRC fellowship EP/S00114X/1 while completingthis work. TD was supported by EPSRC grantEP/K02163X/1. WV was supported by EPSRCgrant EP/K004506/1. AGG was supported by EP-SRC grant EP/I004831/2. The authors thank theUniversity of Southern California for allowing accessto their D-Wave 2 quantum annealer as well as D-Wave Systems Inc. for access to the intermediate-generation annealer. Collaboration with USC is sup-ported under EPSRC grant EP/K004506/1.

Author Contributions

NC performed the experiments. MHA and NC per-formed the calculations with useful assistance fromAGG. MHA produced the simulations which demon-strated that the system can be treated as equili-brated. NC wrote the paper. WV performed earlyexperiments which demonstrated the effect. PJDCand TD performed simulations which informed theearly directions of the project. AGG recognized thatthe effect was related to order by disorder. NC andGA designed the experiment with PAW providing aparticularly useful suggestion. All authors were in-volved in discussions of the results.

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[20] Amin, M. H. Andriyash, E. Rolfe, J. Kulchyt-skyy, B. and Melko, R. Quantum Boltzmann ma-chine ,arXiv:quant-ph:1601.02036 (2016).

[21] Benedetti, M. Realpe-Gómez, J. Biswas, R. andPerdomo-Ortiz, A. Estimation of effective tem-peratures in quantum annealers for sampling ap-plications: A case study with possible applica-tions in deep learning, Phys.Rev. A94, 022308(2016).

[22] Benedetti, M. Realpe-Gómez, J. Biswas, R. andPerdomo-Ortiz, A. Quantum-assisted learning ofgraphical models with arbitrary pairwise connec-tivity arXiv:1609.02542 (2016).

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[23] Khoshaman, A. et. al. Quantum VariationalAutoencoder, Quantum Sci. Technol. 4 014001(2019).

[24] Sadeghi, H. et. al. PixelVAE++: Improved Pix-elVAE with Discrete Prior, arXiv:1908.09948(2019).

[25] Vinci W. et. al. A Path Towards QuantumAdvantage in Training Deep Generative Mod-els with Quantum Annealers, arXiv:1912.02119(2019).

[26] Jordan, S. P. Farhi, E. and Shor, P. W. Error-correcting codes for adiabatic quantum compu-tation Phys. Rev. A 74, 052322 (2006).

[27] Lidar, D. A. Rezakhani, A. T. and Hamma, A.Adiabatic approximation with exponential accu-racy for many-body systems and quantum com-putation. J. Math. Phys 50, 102106 (2009)

[28] Lidar, D. A. Towards Fault Tolerant AdiabaticQuantum Computation Phys. Rev. Lett. 100,160506 (2008).

[29] Young, K. C. Sarovar, M. and Blume-Kohut, R.Error Suppression and Error Correction in Adi-abatic Quantum Computation: Techniques andChallenges Phys. Rev. X 3, 041013 (2013).

[30] Quiroz, G. and Lidar, D. A. High-fidelity adia-batic quantum computation via dynamical de-coupling Phys. Rev. A 86, 042333 (2012).

[31] Ganti, A. Onunkwo, U. and Young, K. A familyof [[6k, 2k, 2]] codes for practical, scalable adi-abatic quantum computation arXiv:1309.1674(2013).

[32] Matsuura, S. Nishimori, H. Vinci, W. and Lidar,D. A. Nested quantum annealing correction atfinite temperature: p-spin models. Phys. Rev. A99, 062307 (2019).

[33] Pudenz, K. L. Albash, T. and Lidar, D. A. Errorcorrected quantum annealing with hundreds ofqubits, Nature Comm. 5, 3243 (2014).

[34] Chancellor, N. Domain wall encoding of discretevariables for quantum annealing and QAOA,Quantum Science and Technology 4 045004(2019).

[35] Childs, A. M. Farhi, E. and Preskill, J. Robust-ness of adiabatic quantum computation Phys.Rev. A 65, 012322 (2001).

[36] Fang, Y., Warburton, P.A. Minimizing minorembedding energy: an application in quantumannealing. Quantum Inf Process 19, 191 (2020).https://doi.org/10.1007/s11128-020-02681-x

[37] Trevor Lanting, D-Wave Systems Inc. privatecommunication

[38] Raymond, J. Yarkoni, S. Andriyash, E. Globalwarming: temperature estimation in annealers.Frontiers in ICT 3, 23 (2016).

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Figure 7: Periodic chain spanning the entire QPU for a single embedding. Dotted lines indicate allowedconnections while solid lines show the connections that are used.

Supplemental Material for: Disorder-inducedentropic potential in a flux qubit quantumannealer

1 Supplemental Methods

1.1 Gauge and embedding averaging

High-Density Embedding

Eliminating of systematic biasing effects on the QPU is crucial for this kind of study. We use two techniquesto counteract such effects. The first technique is to average over the local Z2 gauge on each qubit. For thistechnique we select each qubit within a given problem instance and with a 50% probability either do nothingor flip the sign of all bonds and fields related to that qubit.

The second technique is to average over different ways of mapping the spin chain Hamiltonian to the graphof the QPU. We will refer to this mapping as an embedding. To create a random embedding, we first createa periodic chain that spans the entire QPU with randomly selected bonds as seen in Fig. 7. Starting at arandom point on this chain, we than cut as many chains of the desired length as is possible. The results ofthis process plus gauge averaging are shown in Fig. 8.

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Figure 8: Final embedding produced from the periodic chain shown in Fig. 7. Solid lines are ferromagneticbonds, dashed are antiferromagnetic. The dot-dashed line indicates the location of the initial cut.

Low-Density Embedding

When the data is gauge averaged, any correlation in the noise caused by physical proximity of qubits withinthe unit cells is removed by the random gauge. However, data that are not gauge averaged do not havethis protection, and therefore should be embedded in a way that minimizes the extent to which unit cellsare shared. Fig. 9 gives an example of one such embedding. Fig. 10 shows that data collected using thehigh-density embedding scheme (as shown in Fig. 8) but without gauge averaging do not have the U-shapedbias found with gauge averaging.

1.2 Background Susceptibility Correction

We have used the model of background susceptibility used in [1] which has the form

J ′ij = χ∑k

Jik Jjk h′i = χ∑k

Jikhk, (6)

using the convention that H(t) = B(t)(−∑ij Jij σ

zi σ

zj +

∑i hi σ

zi )−A(t)

∑Ni=1 σ

xi . This imperfection has

the effect of increasing the energy of the terminal domain-wall sites by a value proportional to J(h − J),while leaving all other site energies unchanged. To compensate for background susceptibility, we assumethat the system is in a Boltzmann state at the freeze time and further approximate that the effect of thebackground susceptibility is linear, such that

Pdw(1)→ Pdw(1) (1 +B(tfreeze)

kBTχJ(h− J)). (7)

A similar approximation is made for Pdw(N − 1).

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Figure 9: Embedding with a lower qubit density, which minimizes the number of qubits in the same unitcell.

0 1 2 3 4 5 6 7 8 9 100.08

0.085

0.09

0.095

0.1

0.105

0.11

0.115

0.12

0.125

Site Number

Pdw

Figure 10: Domain-wall probability versus site number for high-density embeddings without gauge averag-ing. Circles are antiferromagnetic gauge results for dense embeddings while squares are ferromagnetic chainresults using this embedding.

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1.3 Field errorsLet us first consider uncoupled qubits with no applied field. In this case, the only contribution will be fromthe control errors,

H = ζσz. (8)

Single measurements of the qubit will be ±1 and, assuming a thermal distribution, will take the form,

P± =[1 + e±ζ/T

]−1

=1

2

[1∓ ζ

T

]+O(

ζ3

T 3). (9)

We define the symmetrized correlation function

C(t) =1

2〈σz(t)σz(0) + σz(0)σz(t)〉. (10)

For two samples taken at different times, we therefore expect the correlation to be

Cij =ζiζjT 2

. (11)

Making use of the Fourier transform we can define the correlation spectral density for the control errors

Sζ(fk) = T 2S(fk) = T 2 |sk|2

Nfsampling, (12)

where fsampling = 1/δt is the sampling frequency and N is the number of samples. The rms value of thenoise is therefore

ζ2 ≈ 1

Nζjζj+1

≈ T 2

N3

∑j

∑k,k′

sksk′e2πi[(j−1)(k−1)−j(k′−1)]/N

=T 2

N2

N∑k=1

|sk|2e−2πi(k−1)/N .

2 Supplemental Discussion

2.1 Analytical and Numerical Demonstration that the Effect of Coupler Errorsare Negligible

In contrast to the calculation for field errors, let us consider the effect of coupler control errors in the formH =

∑i ζ

(J)i σzi σ

zi+1. In this case the energy contribution from the control errors is given by

E(J)n = 2 ζ(J)

n . (13)

By inserting this energy into

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Pn = Z−1e−β En =

1 +∑m 6=n

e−β (Em−En)

−1

and assuming that∑m 6=n′ e−2 β(ζ(J)

m −ζ(J)n ) < 1, we can write

Pn =

1 +∑m′ 6=n′

e−2 β(ζ(J)

m′ −ζ(J)

n′ )

−1

(14)

=∑k

(−1)k

∑m6=n

e−2 β(ζ(J)m −ζ(J)

n )

k

=∑k

(−1)k (N − 1)k =1

N,

where we have assumed that ζ(J)i = 0 and (ζ

(J)i ) = (ζ(J)), and therefore that (ζ

(J)m − ζ(J)

n )q = 0 for anyq > 0. Unlike field-control errors, which effect the domain-wall distribution even at infinitesimal levels,coupler-control errors have no effect provided that

∑m6=n′ e−2 β(ζ(J)

m −ζ(J)n ) < 1 and the system remains in the

single domain wall sector.As a further check that coupler errors can be neglected, we simply compare the results of numerically sam-

pling with no coupler errors to those from sampling with coupler errors of 5% Jmax. As Fig. 11 demonstrates,the difference between the two cases is completely negligible.

2.2 Justification for Treating the System as Equilibrated

Modeling an equilibrium quantum system is much less computationally expensive than simulating the fulldynamics of the quantum annealing process. Given the relative simplicity and small size of the Hamiltonianunder consideration, it is reasonable to suspect that the bath will drive the system into equilibrium relativelyquickly. This assumption should be checked however. As Fig. 12 shows, Redfield-formalism open-quantum-system simulations predict that the system will in fact be very close to equilibrium at all times, includingthe freeze time.

2.3 More elaborate finite temperature calculation

Let us consider a thermal average over instances of uncorrelated random field noise. In this case, thecontribution of field control errors to the energy of a domain wall between qubit n and n+ 1 is

En =

n∑i=1

ζi −N∑i=n

ζi. (15)

From this formula we observe that |Ei − Ej | ∝√|i− j|. Even though the fields, ζ are not correlated, the

domain-wall energies E are such that close domain walls have similar energies.

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1 2 3 4 5 6 7 8 90.1

0.105

0.11

0.115

0.12

0.125

0.13

Site Number

Pdw

Figure 11: Plots of domain-wall distribution from numerical sampling with field errors of 5% Jmaxwithoutcoupler errors (circles), and with coupler errors of 5% Jmax(squares).

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

0.5

t/tf

Domain

WallProbability

0 0.2 0.4 0.6 0.8 1−2

−1

0

1

2

3x 10

−3

t/tf

Pdynam

ic−

Pequili

brium

Figure 12: Comparison of open quantum system simulation based on the Redfield equation of annealingprocess (dashed) with equilibrium values at the physical temperature of the QPU (solid). Dotted lineindicates freeze time. The inset shows the difference between the expected domain wall probability in thetwo models. The maximum difference between these two models is of the order 10−3. Note that both plotscontain five datasets, but some are obscured in the main plot.

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To calculate the domain-wall distribution we can take advantage of the fact that 〈ζi〉 =∑N−1m=1 P (m)

´d~ζP (~ζ|m) ζi = 0, where i indexes the fields over sites and m is the domain wall location. If

the integral´d~ζP (~ζ|m) ζi can be performed, we can therefore obtain a set of linear equations which, coupled

with the fact that∑N−1m=1 P (m) = 1, can be solved for P (m), the domain wall probability.

Let us consider what the average values of the field errors will be given that the domain wall is found onsite m,

〈ζn〉m =

ˆd~ζP (~ζ,m)ζn =

ˆd~ζP (m|~ζ)P (~ζ) =

ˆd~ζζn exp(−En({~ζ})β)

∏i p(ζi)

Z(~ζ)Nm. (16)

In this equation β is the inverse temperature. Z(~ζ) =∑Ni′=1 exp(−En({~ζ})β) and Nm =´

d~ζexp(−En({~ζ})β)

∏i p(ζi)

Z(~ζ)P (m)is a normalization factor. p(ζ) is the probability distribution for ζ. Perform-

ing the multi-dimensional integral in Eq. 16 is prohibitively difficult for most choices of p(ζ), although itcan be solved exactly in the case of p(ζ) = 1

2 (δ(ζ − σζ) + δ(ζ + σζ)). We can however consider a simplifiedversion of Eq. 16 by replacing the values of all but one of the fields with their mean values

〈ζn〉m =ˆdζn

ζn exp(−(En({~ζ}))β) p(ζm)∏i6=m δ(ζi − 〈ζi〉)∑

m′ exp(−(En({~ζ}))β) p(ζm′)∏i 6=m δ(ζi − 〈ζi〉)Nm

. (17)

Eq. 17 can be solved as long as we can solve´dζ ζ exp(±ζβ)

Z(ζ) p(ζ). This integral is now straightforward tocompute.

As a test of this method, let us consider p(ζ) = 12 (δ(ζ − σζ) + δ(ζ + σζ)) and compare the approximation

in Eq. 17 to the exhaustive sum of exponentially many terms in Eq. 16. Fig. 13 demonstrates that thismethod works well in the temperature regime which the D-Wave chip operates. We also found a similarcalculation technique which works well at zero temperature and can be found in Sec. 2.4.

2.4 Zero temperature calculation

Solving the zero-temperature case amounts to finding the probability that a given domain-wall site has thelowest energy given random field noise. We now calculate this probability by examining the probability thatprogressively further sites will have a greater energy than the original site (site 0 in our notation). We areinterested in the case where no sites have lower energy than the original. We introduce the mean energy ata site given this constraint,

El =

ˆd~ζ εEl(~ζ)P (~ζ|E0(~ζ) < Ei(~ζ)) ∀ 0 < i < l.

Using in a Gaussian for P (~ζ), we now approximate the probability that a given site has a greater energythan site 0,

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1 2 3 4 5 6 7 8 90.105

0.11

0.115

0.12

Site Number

Pdw

Figure 13: Calculated domain-wall distribution for 10 spin frustrated chain with a discrete distribution withp(ζ) = 1

2 (δ(ζ − σζ) + δ(ζ + σζ)) and σζ = 0.2T . Circles are exact results from exhaustively summing whilesquares are the approximate result from using Eq. 17.

P>(E, σζ) ≈ˆd~ζ Θ(El(~ζ) + El)P (~ζ) =

1√πσζ

0

dε exp(− (ε− E)2

σ2ζ

) =1

2(1 + erf(

E

σζ)), (18)

where Θ is the Heaviside theta.We define E recursively in the following way:

El =1√πσζ

0

dε ε exp(− (ε− El−1)2

σ2ζ

) =1

2(El−1(1 + erf(

El−1

σζ)) +

σζ√π

exp(−E2l−1

σ2ζ

)). (19)

This recursive calculation can readily be performed by a computer algebra system yielding the resultsshown in Fig. 14.

Once the mean site energies are known, we can use Eq. 18 to calculate the relative probabilities that agiven site will have the lowest energy by realizing that

Pmin(n) ∝N−1∏m6=n

P>(E|n−m|−1, σζ). (20)

As Fig. 15 shows, this approximation gives a result which is quite close to the one we obtain by numericalsampling, indicating that it captures most of the important underlying physics.

2.5 More on error timescales and effectiveness of shimsIt is natural to ask whether the relevant field control errors occur with a short or long timescale. Longtimescale errors can be removed relatively easily because they need to be measured and corrected relativelyless frequently. There is in fact already an effort to correct for these implemented on the QPU. Each hour the

17

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0 2 4 6 8 10 12 14 16 18 200.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

1.1

1.2

l

η/σζ

100

101

102

103

0

0.5

1

1.5

2

2.5

Figure 14: Mean energy of a site versus distance from original site given that no sites between them have alower energy than the original. Inset: Lin-Log scale.

0 2 4 6 8 10 12 14 16 18 20 220

0.02

0.04

0.06

0.08

0.1

0.12

0.14

0.16

0.18

Site Number

Pdw

Figure 15: Domain-wall probability versus site number. Circles are the results from numeric sampling atσζ = 0.01T , while squares are the zero temperature recursive solution.

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1 2 3 4 5 6 7 8 9 10 110

0.01

0.02

0.03

0.04

0.05

0.06

Shim Number

Po

lariza

tio

n

2 4 6 8 10 12

−0.15

−0.1

−0.05

0

0.05

0.1

0.15

Shim Number

Po

lariza

tio

n

1

2

3

4

<σz>

shim

<|<σz>

run−<σ

z>

shim|>

Figure 16: Experimental data for uncoupled qubits with no fields. Circles: mean of average magnitudeof polarization for each shim |〈σzi 〉shim|. Squares: mean magnitude of difference from mean polarizationwithin each shim (Eq. 21). Inset: mean polarization averaged over shims. shown with qubits and couplers(inactive).

software computes the solution to a problem with all fields and couplers turned off, from this the softwareestimates and compensates for the fields. This process is called a shim.

An interesting quantity to examine related to the effectiveness of the shims is the mean polarization takenbetween two shims; 〈σzi 〉shim = 1

nrun

∑run∈shim〈σzi 〉run. Because it is averaged over the short timescale

control errors, this quantity tells us about how effective a shim was at removing errors that are on atimescale of one hour or longer. However, we can probe at least part of the short timescale control errors bytaking the average magnitude of deviations from this value,

〈|〈σzi 〉run − 〈σzi 〉shim|〉shim =1

nrun

∑run∈shim

|〈σzi 〉run − 〈σzi 〉shim|,

This quantity does not capture control errors that occur on timescales faster than the time it takes forthe system to collect the samples, in this case roughly 1 second.

A first check is whether the shims actually change the polarization direction of uncoupled qubits, as Fig.16 (inset) demonstrates this is the case. An immediate consequence of this is that the behavior in Fig. 17,where the domain-wall probabilities on some sites are consistently higher over many shims, must not befrom field control errors. Rather this is probably due to long timescale control errors in the couplers. Bycomparing the two lines in Fig. 16, we can see that field control errors with the time scale between 1 secondand 1 hour are stronger than errors due to imperfect shims, but both are similar in magnitude.

2.6 More discussion of chain without averaging

Fig. 2 of the main text demonstrates that the domain-wall distribution on a single chain persists for hours.A natural next step is to examine an even longer interval and see if the behavior still persists. As Fig.17 demonstrates, the distribution persists for days at least. A skeptical reader may ask if this behavior istypical or an anomaly. We demonstrate in Fig. 18 that such persistent distributions are typical.

As Fig. 18 shows, the mean polarization typically differs significantly from the expected value of zero.This behavior indicates that the domain walls are more probable in particular areas of the chain over the

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1 1.5 2 2.5 3 3.50

2000

4000

6000

8000

10000

t−tstart

(s x 105)

Counts

Figure 17: Same plot as Fig. 2 of the main text but plotted on a much longer timescale.

timescale of the sampling; which in this case is days. Based upon these data, we can conclude that thereis a strong contribution from errors with a typical timescale that is at least days. We can also see fromthis figure that the majority of the variance in the domain-wall position is not from fluctuations due to theshims. Furthermore the standard deviation is much larger than that predicted due to finite sample effects.These fluctuations would be smaller than the symbol size.

References[1] W. Vinci et al., Hearing the shape of the Ising model with a programmable superconducting-flux annealer,

Scientific Reports 4 5703 (2014).

[2] T. Lanting, private communication

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−6

−4

−2

0

2

4

6

Mean P

ola

rization

Figure 18: Mean chain polarization of whole chain where dark error bars are standard deviation for 38different chains embedded on the same problem Hamiltonian as was used in Fig. 2 of the main paper and runfor days. Given that each run consists of 10,000 samples, the expectation for randomly distributed domainwalls would be to have a mean of zero and a standard deviation of 0.02. Light color error bars are the meanstandard deviation from within shims. NB: error bars are standard deviation, not standard deviation of themean. Given that the number of runs in this case was 8820, the standard deviation of the mean is smallerthan the symbols.

21