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sbmplus.com1
DRAINAGE B-ComponentSAFETY DATA SHEET ACCORDING TO REGULATION (EC) NO. 1907/2006
S1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier: Jointex Drainage B-Component
1.2 Relevant identified uses of the substance or mixture and uses advised againstUse of the substance/mixture: Hardender
1.3. Details of the supplier:
SBM+ bvba, Kapellei 152, 2980 Zoersel, BelgiumTelephone information: +32 (0) 3 380 10 35
1.4. Emergency telephone number+32 (0)475/
S2: Hazards identification
2.1 Classification of the substance or mixture: Hazard classes and hazard categories Hazard statements Classification
procedure
Acute toxicity (oral) (Acute Tox. 4) H302: Harmful if swallowed.
Acute toxicity (dermal) (Acute Tox. 4) H312: Harmful in contact with skin.
Skin corrosion/irritation (Skin Corr. 1A) H314: Causes severe skin burns and eye damage.
Respiratory or skin sensitisation (SkinSens. 1)
H317: May cause an allergic skin reaction.
Serious eye damage/eye irritation (Eye Dam. 1)
H318: Causes serious eye damage.
Acute toxicity (inhalative) (Acute Tox. 4) H332: Harmful if inhaled.
2.2 Label elements: Labelling according to Regulation (EC) No. 1272/2008 [CLP]Hazard pictograms:
GHS05 GHS07 Corrosion Exclamation mark Signal word: DangerHazard components for labelling:
1,3-Cyclohexylenbis (methylamine)N’-(3-Aminopropyl)-N,N-dimethylpropane-1,3-diamineDecanedioic acid, compds. w/ 1,3-benzenedimethanamineoxo alcohol (C9/11)-5 EO
Hazard classes and hazard categories hazard statements for health hazards
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
Supplemental Hazard information (EU)
Precautionary statements
P102 Keep out of reach of children.
Precautionary statements Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection
Precautionary statements Response
P303 + P361 +P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
Precautionary statements Storage
P405 Store locked up.
2.3 Other hazards: No data available
S3: Composition / information on ingredients
3.2 MixturesHazardous ingredients / Hazardous impurities / Stabilisers:
Product identifiers Substance nameClassification according to 67/548/EECClassification according to Regulation (EC) No. 1272/2008 [CLP]
Concentration
CAS No.: 100-51-6EC No.: 202-859-9
benzyl alcoholAcute Tox. 4
Warning H302-H332
Xn; R20/22
< 25Wt %
CAS No.: 2855-13-2EC No.: 220-666-8
3-aminomethyl-3,5,5-trimethylcyclohexylamineSkin Corr. 1B, Acute Tox. 4, Skin Sens. 1, Aquatic Chronic 3
Danger H302-H312-H314-H317-H412
Xn; R21/22 — C; R34 — R43 — R52-R53
< 15Wt %
CAS No.: 2579-20-6EC No.: 219-941-5
1,3-CyclohexanedimethanamineSkin Corr. 1C, Acute Tox. 4, Skin Sens. 1
Danger H302-H312-H314-H317
< 15Wt %
CAS No.: 10563-29-8EC No.: 234-148-4
N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamineSkin Corr. 1A, Acute Tox. 4, Skin Sens. 1
Danger H302-H312-H314-H317
< 15Wt %
CAS No.: 260549-92-6 Decanedioic acid, compds. w/ 1,3-benzenedimethanamineEye Dam. 1
Danger H318
Xi; R41
5 – 10Wt %
CAS No.: 68439-46-3 Oxoalkohol(C9/11)-5 EOEye Dam. 1, Acute Tox. 4
Danger H302-H318
Xn; R22 — Xi; R41
< 2Wt %
Full text of R-, H- and EUH-phrases: see section 16.
S4: First aid measures
4.1 Description of first aid measures General information: Remove contaminated, saturated clothing immediately.Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician.In case of skin contact: Wash immediately with: Water and soap. In case of skin irritati-on, consult a physician.After eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.After ingestion: Rinse mouth immediately and drink plenty of water. Get immediate medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayedNo information available.
4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.
S5: Firefighting measures
5.1 Extinguishing mediaSuitable extinguishing media: Carbon dioxide (CO2) - Extinguishing powder - Water spray Unsuitable extinguishing media: Full water jet5.2. Special hazards arising from the substance or mixtureDuring heating or in case of fire, toxic gases is possible.Hazardous combustion products: CNitrogen oxides (NOx) Carbon monoxide. Carbon dioxide (CO2)5.3. Advice for firefightersIn case of fire: Wear self-contained breathing apparatus.5.4. Additional informationDo not inhale explosion and combustion gases. Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
S6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures:
2017
1017
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sbmplus.com 2
Eye/face protection: Eye glasses with side protectionSkin protection:Hand protectionSuitable material: NR (natural rubber, natural latex) FKM (fluoro rubber) PVC (Polyvinyl chloride) Thickness of the glove material: >= 0,5 mm. Check leak tightness/impermeability prior to use. Breakthrough times and swelling properties of thematerial must be taken into consideration. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.Body protection: Protective clothingRespiratory protection: Respiratory protection necessary at: exceeding exposure limit values insufficient ventilation Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190).8.2.3. Recommended Filter type: A -P2 Environmental exposure controls: See section 7. No additional measures necessary.
8.3. Additional informationNo data available
S9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance• Physical state: liquid • Colour: light yellow• Odour: AminesSafety relevant basis data:
at °C method remark
pH not determined
Melting point/freezing point not determined
Freezing point not determined not determined
Initial boiling point and boiling range > 100 °C
Decomposition temperature (°C): not determined
Flash point > 100 °C
Evaporation rate not determined
Ignition temperature in °C not determined
Upper/lower flammability or explosive limits
not determined
Vapour pressure 23 hPa 20 °C
Vapour density not determined
Density 1.009 g/cm³ 20 °C
Bulk density not determined
Water solubility (g/L) partially miscible
Partition coefficient: n-octanol/ water not determined
Dynamic viscosity not determined
Kinematic viscosity not determined 40 °C
9.2. Other informationNo data available
S10: Stability and reactivity10.1 Reactivity: No hazardous reaction when handled and stored according to provisions.10.2 Chemical stability: The mixture is chemically stable under recommended conditions of storage, use and temperature.
10.3 Possibility of hazardous reactions: No hazardous reaction when handled and stored according to provisions.
10.4 Conditions to avoid: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
10.5. Incompatible materialsAlkali (lye) - Acid - Oxidising agent, strong
10.6. Hazardous decomposition productsDuring heating or in case of fire, toxic gases is possible.
S11: Toxicological information
6.1.1. For non-emergency personnelPersonal precautions: Use personal protection equipment. Avoid contact with skin, eyes and clothes.6.1.2. For emergency respondersPersonal protection equipment: Use appropriate respiratory protection.
6.2. Environmental precautionsDo not allow to enter into soil/subsoil. Do not empty into drains.
6.3. Methods and material for containment and cleaning upFor containment: Suitable material for taking up: Sand Kieselguhr Universal binder Chemical binding agents, containing acidsFor cleaning up: Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
6.4. Reference to other sectionsSafe handling: see section 7Personal protection equipment: see section 8Disposal: see section 13
6.5. Additional informationClear spills immediately.
S7: Handling and storage7.1 Precautions for safe handling: Protective measuresAdvices on safe handling: Keep container tightly closed. Minimum standard for preven-tive measures while handling with working materials are specified in the TRGS 500.Fire prevent measures: Keep away from sources of ignition. - No smoking.Environmental precautions: Shafts and sewers must be protected from entry of the product.Advices on general occupational hygieneMinimum standard for preventive measures while handling with working materials are specified in the TRGS 500. Wash hands before breaks and after work. Apply skin care products after work. When using do not eat, drink, smoke, sniff. Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing immediately.
7.2 Conditions for safe storage, including any incompatibilities: Requirements for storage rooms and vessels: Shafts and sewers must be protected from entry of the product. Keep/Store only in original container.Hints on storage assembly: Do not store together with: Food and feedingstuffsStorage class: 8 AFurther information on storage conditions: Keep locked up and out of reach of children.
7.3 Specific end use(s): No data available
S8: Exposure controls/personal protection8.1 Control parameters: 8.1.1. Occupational exposure limit values: No data available8.1.2. biological limit values: No data available8.1.3. DNEL-/PNEC-values:
Substance name DNEL value DNEL type Exposure route
benzyl alcoholCAS No.: 100-51-6
90 mg/m³ DNEL worker DNEL long-term inhalative (systemic)
benzyl alcoholCAS No.: 100-51-6
9.5 mg/kgbw/day
DNEL worker DNEL long-term dermal (systemic)
3-aminomethyl-3,5,5-trimethylcyclohexylamineCAS No.: 2855-13-2
20.1 mg/m³ DNEL worker DNEL acute inhalative (systemic)
Substance name PNEC value PNEC type
benzyl alcoholCAS No.: 100-51-6
1 mg/l PNEC aquatic, freshwater
benzyl alcoholCAS No.: 100-51-6
0.1 mg/l PNEC aquatic, marine water
3-aminomethyl-3,5,5-trimethylcyclohexylamineCAS No.: 2855-13-2
0.06 mg/l PNEC aquatic, freshwater
3-aminomethyl-3,5,5-trimethylcyclohexylamineCAS No.: 2855-13-2
0.006 mg/l PNEC aquatic, marine water
8.2 Exposure controls8.2.1. Appropriate engineering controls: No data available8.2.2. Personal protection equipment:
DRAINAGE B-ComponentSAFETY DATA SHEET ACCORDING TO REGULATION (EC) NO. 1907/2006
3 sbmplus.com
DRAINAGE B-ComponentSAFETY DATA SHEET ACCORDING TO REGULATION (EC) NO. 1907/2006
11.1. Information on toxicological effects
CAS No. Substance name Toxicological information
100-51-6 benzyl alcohol LD50 oral: 1,230 mg/l (Rat)LD50 dermal: 2,000 mg/l (Rabbit)ATE inhalativ Dämpfe: 11 mg/l
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
LD50 oral: 1,030 mg/kg (Mouse)LD50 dermal: 1,840 mg/kg (Rabbit)
2579-20-6 1,3-Cyclohexanedimethanamine LD50 oral: 700 mg/kg (Rat)LD50 dermal: 1,700 mg/kg (Rabbit)
2605-49-92-6
Decanedioic acid, compds. w/ 1,3-benzenedimethanamine
LD50 oral: 2 mg/kg (Rat)LD50 dermal: 2 mg/kg (Rabbit)
10563-29-8 N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine
LD50 oral: 2,000 mg/kg (Rat)LD50 dermal: 1,310 mg/kg (Rat)
68439-46-3 Oxoalkohol(C9/11)-5 EO LD50 oral: 2,000 mg/kg (Rat)
• Acute oral toxicity: There are no data available on the preparation/mixture itself.• Acute dermal toxicity: There are no data available on the preparation/mixture itself.• Acute inhalation toxicity: There are no data available on the preparation/mixture
itself.• Skin corrosion/irritation: Corrosive• Eye damage/irritation: strongly corrosive.• Respiratory or skin sensitisation: May cause sensitization by inhalation and skin
contact.• Germ cell mutagenicity: No indications of human germ cell mutagenicity exist.• Carcinogenicity: No indication of human carcinogenicity.• Reproductive toxicity: No indications of human reproductive toxicity exist.• Additional information: If ingested, severe burns of the mouth and throat and to the
danger of perforation of the esophagus and stomach.
S12: Ecological information 12.1. Toxicity
CAS No. Substance name Toxicological information
100-51-6 benzyl alcohol LC50: 645 mg/l 4 d (Leuciscus idus (golden orfe))EC50: 400 mg/l 4 d (Daphnia magna)ErC50: 640 mg/l 4 d
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
LC50: 110 mg/l 4 d (Leuciscus idus (golden orfe))EC50: 23 mg/l 2 d (Daphnia magna)ErC50: 50 mg/l 3 d
2579-20-6 1,3-Cyclohexanedimethanamine EC50: 90 mg/lLC50: 130 mg/l
10563-29-8 N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine
EC50: 181 mg/l 1 dLC50: 220 mg/l 4 dEC50: 9.2 mg/l 2 d
Aquatic toxicity: There are no data available on the preparation/mixture itself.Sediment toxicity: There are no data available on the preparation/mixture itself.Terrestrial toxicity: There are no data available on the preparation/mixture itself.12.2. Persistence and degradabilityAbiotic degradation: No information available.12.3. Bioaccumulative potentialAccumulation / Evaluation: No information available.12.4. Mobility in soilNo information available.12.5. Results of PBT and vPvB assessmentThe substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.12.6. Other adverse effects: No information available.
S13: Disposal considerations13.1. Waste treatment methodsDispose of waste according to applicable legislation.13.1.1. Product/Packaging disposalWaste codes/waste designations according to EWC/AVV.Waste code product:remark: The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.Waste treatment optionsAppropriate disposal / Product: Dispose of waste according to applicable legislation.Appropriate disposal / Package: Handle contaminated packages in the same way as the
substance itself.13.2. Additional informationDelivery to an approved waste disposal company.
S14: Transport information
Land transport (ADR/RID)
Inland waterway craft(ADN)
Sea transport (IMDG) Air transport (ICAOTI/ IATA-DGR)
14.1. UN-No.
2735 2735 2735 2735
14.2. UN proper shipping name
AMINES, LIQUID, CORROSIVE,N.O.S. (ISOPHO-RONEDIAMINE,Benzyl alcohol )
AMINES, LIQUID, CORROSIVE,N.O.S. (ISOPHO-RONEDIAMINE,Benzyl alcohol )
AMINES, LIQUID, CORROSIVE,N.O.S. (ISOPHO-RONEDIAMINE,Benzyl alcohol )
AMINES, LIQUID, CORROSIVE,N.O.S. (ISOPHO-RONEDIAMINE,Benzyl alcohol )
14.3. Transport hazard class(es)
8 8 8 8
14.4. Packing group
III III III III
14.5. Environmental hazards
no no no no
14.6. Special precautions for user
Special provisions:Limited quantity(LQ): 5 LHazard identificationnumber (Kemler No.): 80Classification code: C7tunnel restriction code: Eremark:
Special provisions:Limited quantity(LQ): 5 LClassification code:C7remark:
Special provisions:Limited quantity(LQ): 5 LEmS-No.: F-A, S-Bremark:
Special provisions:Limited quantity(LQ):remark:
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable not applicable not applicable not applicable
S15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixture 15.1.1. EU legislation: No data available15.1.2. National regulations[DE] National regulationsRestrictions of occupation: 22 JArbSchG. 5 MuSchRiV.Water hazard class (WGK)WGK: 2 - deutlich wassergefährdendDescription: hazardous to water (WGK 2)Berufsgenossenschaftliche Vorschriften (BGV):
Berufsgenossenschaftliche Regeln (BGR) 190, 192, 195BG code: M 042 “skin protection”; M 004 “Irritating substances / corrosive substances”UVV: “Processing of coating materials” (BGV D 25)Practice Guide for the handling of epoxy resins (issued by the professional association in the construction industry) - www.bgbau.de or www.gisbau.deEpoxy systems safely handle (published by Plastics Europe) - www.plasticseurope.orgBGR 227 “Epoxy Resins” (issued by the Association of BGs) - www.dguv.de
15.2. Chemical Safety Assessment: No data available15.3. Additional information: No data available
S16: Other information16.1. Indication of changesSECTION 1: Identification of the substance/mixture and of the company/undertaking16.2. Abbreviations and acronymsSee overview table at www.euphrac.eu
• AGW: workplace exposure limit• Technical Rule: Technical Guidelines for Hazardous Substances• TLV - Threshold Limit Value TWA - Time Weighted Average• STEL - short term exposure limit for permissible workplace concentration -
Permissible Workplace concentration
4sbmplus.com
DRAINAGE B-ComponentSAFETY DATA SHEET ACCORDING TO REGULATION (EC) NO. 1907/2006
• STOT RE - Specific target organ toxicity (repeated exposure)• Acute Tox. - Acute toxicity• PBT - substances which are persistent, bioaccumulative and toxic• vPvB - substances which are very persistent and very bioaccumulative• ADR: Accord européen sur le transport of marchandises dangereuses par Route
(European agreemen• Concerning the International Carriage of Dangerous Goods by Road)• RID: Government regulation internationally concernant le transport of
marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
• IMDG: International Maritime Code for Dangerous Goods• IATA: International Air Transport Association• IATA-DGR: Dangerous Goods Regulations by the “International Air Transport
Association” (IATA) • ICAO: International Civil Aviation Organization• ICAO-TI: Technical Instructions by the “International Civil Aviation Organization”
(ICAO)• GHS: Globally Harmonized System of Classification and Labeling of Chemicals• EEC: Hazardous Substances (Ordinance on Hazardous Substances, Germany)
16.3. Key literature references and sources for dataEuropean Chemicals Agency (ECHA), ECHA CHEM Registered substancesOECD The Global Portal to Information on Chemical Substances (ChemPortal)Institute for Occupational Safety and Health of the German Social Accident Insurance (IFA): GESTISsubstance database and International limit values for chemical substancesFederal Environment Agency, Section IV 2.4: Documentation and Information Centre substances hazardous to water Rigoletto (catalog substances hazardous to water)
16.4. Classification for mixtures and used evaluation method according toregulation (EC) 1272/2008 [CLP]Classification according to Regulation (EC) No. 1272/2008 [CLP]:
Hazard classes and hazard categories
Hazard statements Classification procedure
Acute toxicity (oral) (Acute Tox. 4) H302: Harmful if swallowed.
Acute toxicity (dermal) (Acute Tox. 4) H312: Harmful in contact with skin.
Skin corrosion/irritation (Skin Corr. 1A)
H314: Causes severe skin burns and eye damage.
Respiratory or skin sensitisation (Skin Sens. 1)
H317: May cause an allergic skin reaction.
Serious eye damage/eye irritation (Eye Dam. 1)
H318: Causes serious eye damage.
Acute toxicity (inhalative) (Acute Tox. 4)
H332: Harmful if inhaled.
16.5. Relevant R-, H- and EUH-phrases (Number and full text)
Hazard statements (R-phrases)
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Hazard statements
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H412 Harmful to aquatic life with long lasting effects.16.6. Training advice: No data available
16.7. Additional information
The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new madeup material.
Creator of the safety data sheet:Uta Sabath GefahrgutberatungPostfach 15 01 0533731 Bielefeld