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Innovations for a better world. E-mobility. Efficient battery electrode slurry production.

E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

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Page 1: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Innovations for a better world.

E-mobility.Efficient battery electrode slurry production.

Page 2: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

The biggest challenge of our time is to ensure sustainable global growth while conserving natural resources.

With the growing demand for mobility and the

serious environmental challenges in densely

populated urban areas, electric vehicles are

gaining significant support as a next-generation

means of transportation.

One of the key components of all-electric and

hybrid electric vehicles is the energy storage

device. Lithium-ion batteries (LIBs) can poten-

tially provide the required energy densities and

thus meet the driving range requirements of

electric cars.

E-mobility. Efficient battery electrode slurry production.

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Page 3: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Represented with a strong service network, in more than 140

countries, from planning through to start-up, Bühler supports

its customers in all investment phases while ensuring maximum

productivity and quality across a system’s entire life cycle.

Correct preparation of the electrode active materials is the

basis for high-performance LlBs. Bühler enhances the conver-

sion of these materials with outstanding wet grinding equip-

ment and extensive expertise in nanoparticle processing.

Furthermore, Bühler offers various production technologies

for electrode slurries: batch and quasi-continuous processes

for small to me dium-sized production and continuous mixing

technology for large-scale production.

These process solutions cover LIB anode, cathode, and sep-

arator slurries, including the handling, storage and dosing of

solid and liquid raw materials.

“ Bühler is an expert partner to the automobile and supplier

industry, for example in die casting solutions, coating tech-

nologies and the production of paints. The new solutions

for producing battery electrode slurries reinforce our com-

mitment in this important industry segment.”

Samuel Schär | CEO Bühler Advanced Materials

precursor

formation

chemical

conversion precursor

electrode

slurry preparation

electrode

manufacturing

cell

assembly

Bühler

Cenomic™

full-volume mill

Bühler

MicroMedia™

high-performance mill

Batch and

quasi-continuous

processes for small and

medium-sized production

Bühler ContiMixer

continuous mixing

process for large-scale

production

Global technology partner to the battery industry.Innovative solutions for crucial process steps.

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Page 4: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

E-mobility. Efficient battery electrode slurry production.

MicroMediaTM X for micro

wet grinding and dispersion

down to the nano range

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Page 5: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Perfect material transformation.Wet grinding processes for active materials.

Proper preparation of active materials is the basis for high-performance lithium-ion batteries. The particles must have the right size and the slurry must be optimized for downstream processing.

Bühler is a global leader in the field of process engineering,

especially for wet grinding and dispersion applications. With

the Cenomic™ full-volume bead mill and the MicroMedia™

high-performance bead mill technologies, Bühler draws on

decades of experience. The reliable, scalable and industry-

proven Bühler equipment is ideal for the preparation of LIB

active and separator materials.

Cenomic™

The horizontal full-volume mill with innovative functional

elements is ideal for pass operation and is also suitable for

economic recirculation mode.

The lean processing zone and EcoMizer™ high-performance

grinding discs enable energy-saving wet grinding processes.

All surfaces of the product chamber that come into contact

with the products are produced as individually exchangeable

components made of particularly hard-wearing materials.

MicroMedia™ X

The MicroMedia™ X stands out due to the extraordinary

product qualities and high level of grinding efficiency achieved.

The small-volume bead mill enables power densities of

0.1 to 4.0 kW/l and provides intensive cooling on the outer

stator surface and in the annular discharge channel between

the rotor and the inner stator. The MicroMedia™ X is suitable

for grinding beads of 20 to 800 µm and provides soft dispers-

ing in the lower nano range as well as high-energy true

grinding.

Flexible process solutions

Both machines are available in different sizes and scaled from

laboratory solutions through to large-scale production mills.

The Cenomic™ and the MicroMedia™ X are both character-

ized by high energy efficiency, ease of use, robustness and re-

liability in continuous operation.

To optimize production efficiency, Bühler supports its custom-

ers in selecting the right grinding equipment, optimizing the

process parameters and choosing appropriate small molecule

surface modifiers.

Customer benefits:

– Efficient size reduction, stabilization and homo-

genization down to the nano range

– Slurries can have a high solid content and low

viscosity at the same time

– Effective grinding with 10 –15% less energy

con sumption

– Positive impact on downstream processing

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Page 6: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

E-mobility. Efficient battery electrode slurry production.

Fully continuous mixing

system for the production

of electrode slurries

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Page 7: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Conventional production methods for Lithium-Ion Battery

(LIB) electrode slurries are based on batch or quasi contin-

uous processes. However, for the expected growth created

by electric vehicles and energy storage systems, these

methods will no longer fulfill the requirements of the respec-

tive industry.

Large production capacities can only be reached by multipli-

cation of batch machines which linearly increases production

area, investment and operation costs. The Bühler fully conti-

nuous mixing process for LIB electrode slurry production

meets the requirements of large scale battery manufacturing

and provides various benefits to the customer.

Large-scale electrode slurry production.Fully continuous mixing technology.

A crucial process step in the production of lithium-ion batteries is the preparation of the electrode slurries.

LIB electrode slurry

production based on proven

Bühler extrusion technology.

The continuous mixing process

is based on proven and robust

twin screw extrusion technology

developed by Bühler for multiple

applications and industries.

Continuous powder dosing(active materials, conductive additives, binder)

Continuous liquid dosing(binder solution, solvent)

Coatingline

Immediate continuous mixing after dosing

[ t ]seconds

Powder components

Liquid components

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Page 8: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Continuous mixing technology

The continuous mixing process is based on a twin-screw

mixer which combines the basic operations of continuous raw

material dosing, pre-mixing, kneading, fine-dispersing and de-

gassing in a single device.

In a conventional batch mixing system, the process comprises

two steps. First, the addition of pre-weighted liquid and solid

components followed by subsequent distribution of the solid

components in the liquid phase. In order to achieve the re-

quired homogeneity at macroscopic and microscopic level,

several hours of process time are typically needed.

On the other hand, the continuous mixing process consists of

controlled continuous dosing of all liquid and solid components

and micro distribution of the solid particles in the liquid phase.

Since a large part of the mixing work is performed by continu-

ous dosing of the raw materials, the residence time in the con-

tinuous mixer is typically less than one minute.

Investment – economies of scale

Due to high productivity (up to 2,500 l/h), the continuous mix-

ing process can replace multiple batch mixers with a single

fully continuously operated production line. As a result the

required investment can be significantly reduced for large

production scale installations.

The Bühler fully continuous mixing process for LIB electrode slurry production meets the needs for large scale battery manufacturing.

E-mobility. Efficient battery electrode slurry production.

Customer benefits:

– Significantly lower investment costs due to eco nomies

of scale

– Lower operating costs due to energy savings, a high

degree of automation and less manpower required

– Enhanced reproducibility and controllability of product

properties

– More consistent product quality thanks to inline quality

control

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Operation costs

Compared to batch mixers, the continuous mixing process

requires three times less specific energy input to achieve the

same product properties. Furthermore, due to a smaller foot-

print, the needed dry room volume can be significantly re-

duced for the continuous mixing system. As a result, the

energy consumption to maintain the dry room climate is

much smaller than for conventional batch mixing systems.

The high degree of automation of the continuous mixing

system can reduce the required man-power to operate the

plant by 50%.

Process automation and inline quality control

The fully automated operation of raw material dosing (powders

and liquids), mixing, dispersing and degassing allows higher

recipe accuracies, enhanced process control and better trace-

ability. This is enhanced by continuous inline monitoring of the

critical process parameters such as raw material flow rates,

temperatures, pressures and power consumption. Further-

more, the quality control expert system QuaLIBTM enables

inline monitoring and control of the electrode slurry parameters.

Space requirements per line– Batch mixing process: 630 m3

– Bühler ContiMixer 62 mm: 450 m3

– Bühler ContiMixer 93 mm: 858 m3

– Bühler ContiMixer 125 mm: 990 m3

Assumptions:– 70 MI eletrode slurry

per year (35 GWh)– Dry room power

consumption: 200 W/m3

– 6,000 hours per yearBatch mixing

process(24 lines)

ContiMixer 62 mm

(24 lines)

ContiMixer 93 mm

(10 lines)

ContiMixer 125 mm(6 lines)

18.1GWh

-60%

Energy consumption– Batch mixing process: 75 Wh/l– Bühler ContiMixer: 25 Wh/l

Assumptions:– 70 MI eletrode slurry per year (35 GWh)– 6,000 hours per year Batch mixing process Bühler ContiMixer

-60%5.3 GWhSignificant lower investment cost: up to -60% compared to conventional batch mixing.

Investment for mixing capacity of 70 million liters

of electrode slurry per yearExample for annual equipment energy consumption

Example for annual dry room energy consumption

Assumptions: 70 MI of electrode slurry per year corresponds to 35 GWh annual production capacity, operation 6,000 h/y

Batch mixing process(24 lines)

ContiMixer 62 mm(24 lines)

ContiMixer 93 mm(10 lines)

ContiMixer 125 mm(6 lines)

-60%

QuaLIBTM

Data

Feedback

Quality A

Quality B

Inline quality control expert system

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Page 10: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Processes can be tested and optimized at the company's

own test facilities for battery materials in Europe and Asia.

Professional analyses ensures accurate evaluation of the dif-

ferent process steps and their results.

Process engineer specialists carry out pilot trials and test

series with the customer. The test facilities are designed for

tests on a small industrial scale. The results provide an insight

into the required dimensioning of the potential plant and allow

realistic product and process optimizations to be carried out.

The Bühler Central Laboratory in Uzwil is the ideal point of

contact for analysis tasks and also offers services such as

consulting, training and method development for customer’s

laboratories.

Customers also benefit from interdisciplinary exchange with

other areas of expertise within the Bühler group and from

close collaboration with universities and researchers world-

wide.

Process and product optimization.Practice-based pilot plant and laboratory trials.

Bühler operates its own test facilities and laboratories worldwide and provides sup-port to optimize production systems with regard to yield, throughput and reduction of the energy required.

E-mobility. Efficient battery electrode slurry production.

Bühler – a trustworthy partner:

– Global network of labs and pilot plants

– Skills in engineering and plant building

– Extensive expertise in LIB electrode slurry pro cessing

– Customer support for process development

– Wide range of reference projects in the battery industry

relating to precursor/active material grinding and

electrode slurry mixing

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Bühler maintains its own service locations worldwide and is

represented on every continent and can therefore be on site

quickly when customers need support. Technicians procure

spare parts quickly and install them professionally while spe-

cialized Bühler workshops carry out extensive repair work

and retrofits.

Customized maintenance and reconditioning packages

ensure that machines are always state of the art. This allows

customers to produce their articles profitably and safely even

with older plants.

Specially tailored training options ensure smooth operation of

the machines, allowing you to produce excellent product qual-

ity with optimum throughput. The training courses help im-

prove plant output and keep operating staff abreast of current

technologies and safety standards.

24 hours a day, seven days a week, worldwide.Services for more productivity and safety.

Bühler partners with a host of industries worldwide. The tried-and-tested production systems for food, automobile parts, coatings, chemical products and colors combine first-class process quality and a high level of efficiency.

Bühler

Headquarters Uzwil

Mahwah

Wuxi

Saitama

1

2

3

4

Bühler Grinding & Dispersion Centres of Competence with pilot plants for battery materials

2

3

4

1

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Page 12: E-mobility. Efficient battery electrode slurry - Buhler …. Efficient battery electrode slurry production. 2. ... the quality control expert system QuaLIBTM ... E-mobility. Efficient

Bühler AG

CH-9240 Uzwil

Switzerland

T +41 71 955 11 11

F +41 71 955 31 49

[email protected]

buhlergroup.com

1610

14_B

atte

ry3_

EN

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