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www.thalesgroup.com www.thales-cryogenics.com © THALES CRYOGENICS B.V. AND/OR ITS SUPPLIERS. THIS INFORMATION CARRIER CONTAINS PROPRIETARY INFORMATION WHICH SHALL NOT BE USED, REPRODUCED OR DISCLOSED TO THIRD PARTIES WITHOUT PRIOR WRITTEN AUTHORIZATION BY THALES CRYOGENICS B.V. AND/OR ITS SUPPLIERS, AS APPLICABLE. C R Y O G E N I C S Tailoring the size and performance of a reserve lithium battery for the next generation fuzes 56th Annual Fuze Conference : “Next Generation Fuzing for Next Generation Weapons” Baltimore, May 14-16, 2012 Date | Reference | Rubricering <via insert/headers/slide/footer> Olivier CLESCA Account Manager Lithium Batteries Thales Cryogenics B.V. THE NETHERLANDS

E Tailoring the size and performance of a reserve lithium ......Part of the Thales Group of companies (Fuzes, Batteries & Packs) 2005 Closure of Thales Munitronics B.V. 2007 Production

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Page 1: E Tailoring the size and performance of a reserve lithium ......Part of the Thales Group of companies (Fuzes, Batteries & Packs) 2005 Closure of Thales Munitronics B.V. 2007 Production

www.thalesgroup.com www.thales-cryogenics.com

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C R Y O G E N I C S

Tailoring the size and performance of a reserve

lithium battery for the next generation fuzes

56th Annual Fuze Conference : “Next Generation Fuzing for Next Generation Weapons”

Baltimore, May 14-16, 2012

Date | Reference | Rubricering <via insert/headers/slide/footer>

Olivier CLESCA

Account Manager Lithium Batteries

Thales Cryogenics B.V. THE NETHERLANDS

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Content

Introduction Thales

Current Products

Developments current products :

Robustness improvements (resistance to flick ramming)

Developments new products:

Multi stack to single cell; powering 3 V electronics

Small single cell battery

Outlook future developments

Conclusions

Date | Reference | Rubricering <via insert/headers/slide/footer>

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Introduction Thales : History

Date | Reference | Classification <via insert/headers/slide/footer>

1948 Philips Usfa B.V. manufacturing army and navy fuzes,

later also optronics en coolers.

1988 Signaal Usfa part of Hollandse Signaalapparaten B.V.

(Cryo, Optronics, Fuzes & Batteries)

1990 Signaal Usfa member of the Thomson-csf

(Cryo, Optronics, Fuzes & Batteries)

2000 Signaal Usfa B.V. separate legal entity with Fuzes,

Batteries & Battery Packs

2001 Thales Munitronics B.V.

Part of the Thales Group of companies

(Fuzes, Batteries & Packs)

2005 Closure of Thales Munitronics B.V.

2007 Production resumed under Thales Cryogenics,

existing lithium batteries only (no self-funded R&D).

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C R Y O G E N I C S

Introduction Thales : Products

THALES produces Lithium battery systems since 1970

Lithium – Vanadium pentoxide (V2O5)

Chromic acid Lithium - SOCl2

Date | Reference | Classification <via insert/headers/slide/footer>

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C R Y O G E N I C S

Current Products

Multi stack reserve Li-SOCl2 batteries :

Date | Reference | Classification <via insert/headers/slide/footer>

UA 6215 Army artillery fuze battery.

6-9 cells, bipolar electrodes

2 x 4 cell stack in parallel option

Release mechanism in the top

UA 6275 Navy fuze battery.

6-9 cells, bipolar electrodes

Release mechanism at the

bottom

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C R Y O G E N I C S

Robustness improvements

To reduce the risk of early fracture of ampoules due to radial and axial(-) forces

(drop test / flick ramming), robustness has been improved:

Date | Reference | Classification <via insert/headers/slide/footer>

UA 6215 : Army UA 6275 : Navy

Close tolerance gap

to avoid balancing of ampoule

Increase gap ampoule/structure

from 0.3 to 1.4 mm

Improvements :

Radial drop height increased

1.5 mtr (5ft) to >4.5 mtr (15ft)

Radial shock 8000g / 0.3 s

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Energy content batteries

Date | Reference | Classification <via insert/headers/slide/footer>

CURRENT MULTI CELL BATTERIES:

Typical 8 cell battery will provide 2200 J

Energy density (chemical system only)

860 kJ/kg (240 Wh/kg)

Current battery is overdesigned for typical fuze applications.

Remaining energy available for :

Higher current rating

Longer flight times

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C R Y O G E N I C S

3V electronics; single cell

Disadvantages of stacked cells: Complexity

Losses due to not fully utilizing all cells and/or internal parasitic currents

High energy content, overkill

Increasing application of lower voltage electronics (2.5 - 3V) Single cell design in Li-SOCl2 is feasible

Very efficient DC-DC converters available for higher voltage requirements

Advantages of single cell design: Simple design; no common electrolyte path (internal short circuit)

Spin / Non-spin independent

Large surface area higher current density

Dimensional freedom, miniaturization

Date | Reference | Classification <via insert/headers/slide/footer>

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Development single cell:

CURRENT MULTI CELL BATTERY SINGLE CELL:

Example of typical requirement for application with improved (3V) electronics:

Typical current 350 mA

Operational time 200 s

Power requirement 210 J

Date | Reference | Classification <via insert/headers/slide/footer>

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Development single cell: smaller size

DOWNSCALING Ø32 X 25 MM SINGLE CELL BATTERY : Ø13 x 15

Typical application requirement:

Dimension 15 x 13 mm

Current 100 mA

Operational time 100 s

Power 30 J

DESIGN GOAL:

Dimension Ø10 x 10 mm

Current 50 mA

Operational time <30 s

Power > 5 J

Date | Reference | Classification <via insert/headers/slide/footer>

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Development single cell: 30 – 40 mm fuze

Design goal for 30 and 40 mm Fuze applications:

Dimensions: Ø 10 mm x 10 mm height.

Voltage level > 3.0 V

Typical Power requirements :

20 mA constant current level

Peak currents 50 mA / 200 ms

Current density level : 50 mA/cm2

Operational temperature range -46°C to +70°C

Set back acceleration 10.000 - 65.000 g

Operational time : < 30 s

Date | Reference | Classification <via insert/headers/slide/footer>

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Development single cell: 30 – 40 mm fuze : Challenges

Challenges :

Glass ampoule no longer feasible

Minimum wall thickness is limited,

making it increasingly difficult to shatter the ampoule

Internal volume ampoule insufficient for cell filling

Metal Container

Very thin walls possible (compared to glass)

Integrated in battery housing

Spin and Non spin applications possible

Cell can be positioned right under electrolyte container opening, allowing for immediate

wetting of the complete cell

Cell can be wrapped around electrolyte container, standing in electrolyte pool once

activated;

Production techniques for high volume small batteries.

Date | Reference | Classification <via insert/headers/slide/footer>

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Future developments

Development in single cell batteries :

Replacement of glass container with metal container

▪ Use the battery stainless steel housing to form

an electrolyte container.

▪ Close welding the container after filling

▪ Placement of the cell stack :

▪ Vertically around container part (wrap)

▪ Horizontally below the internal opening

of the container

Date | Reference | Classification <via insert/headers/slide/footer>

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C R Y O G E N I C S

Conclusions

Thales is actively tailoring it’s Lithium-Thionylchloride batteries

to meet future developments in fuze applications

Developments are focussed on:

Single cell battery; current size smaller (10 x 10 mm)

Alternative electrolyte containers; metal (stainless steel)

Alternative activation / electrolyte release mechanisms;

Lithium batteries for small caliber fuze are a promising prospect

Date | Reference | Classification <via insert/headers/slide/footer>

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C R Y O G E N I C S

Questions ?

Date | Reference | Classification <via insert/headers/slide/footer>

Thank you for your attention

Thales Cryogenics

Battery Department

Hooge Zijde 14 , Eindhoven The Netherlands

www.Thales-Cryogenics.com