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2005051

EA om. SAFETY DATA SHEET |ECOLAB 7052HD-325

| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |

Product name

Other means of identification

Recommended use

Restrictions on use

Product dilution information

Company

Emergency healthinformation

Issuing date

HD-325

Not applicable

Cleaning product

Reserved for industrial and professional use.

0.26 %

Ecolab lnc.

1 Ecolab Place

SL Paul, Minnesota USA 551021-300-352-5326

1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

04/01/2019

| SECTION 2. HAZARDS IDENTIFICATION

GHSClassification

Product AS SOLDSkin corrosion

Serious eye damage

Product AT USE DILUTIONSkin corrosionSerious eye damage

GHSlabel elements

Product AS SOLDHazard pictograms

Signal Word

Hazard Statements

Precautionary Statements

Category 14Category 1

Category 1ACategory 1

Danger

Causes severe skin burns and eye damage.

Prevention:

Do not breathe dusts or mists. Wash skin theroughly after handling.

Wear protective gloves/ protective clothing! eye protection! faceprotection.

Response:

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN(or hair); Take off immediately all contaminated clothing. Rinse skinwith water/shower. IF INHALED: Remove persanlo fresh air and keepcomfortable for breathing. Immediately call a POISONCENTER/doctor. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue

finsing. Immediately call a POISON CENTER/doctor. Wash

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contaminated clothing before reuse.Storage:Slore locked up.Disposal:

Dispose of contents/ container to an approved waste disposal plant.

Product AT USE DILUTIONHazard pictograms

Signal Word : Danger

Hazard Statements : Causes severe skin burns and eye damage.

Precautionary Statements : Prevention:Wash skin thoroughly after handling. Wear protective gloves!protective clothing/ eye protection/ face protection.Response:IF SWALLOWED:Rinse mouth. Do NOT induce vomiting. IF ON SKIN(or hair): Take off immediately all contaminated clothing. Rinse skinwith water/shower, IF INHALED: Remove person to fresh air and keepcomfortable for breathing. immediately call a POISONCENTER/doctor, IF IN EYES: Rinse cautiously with water for severalminutes, Remove contactlenses, if present and easy to do. Continuerinsing. Immediately call a POISON CENTER/doctor. Washcontaminated clothing before reuse.Storage:

Stare locked up.Disposal:Dispose of contents/ container to an approved waste disposal plant.

Product AS SOLDOther hazards | Mixing this product with acid or ammonia releases chlorine gas,

Product AT USE DILUTIONOther hazards : Mixing this product with acid or ammonia releases chlorine gas.

| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Product AS SOLDPure substance/mixture > Mixture

Chemical name CAS-No. Concentration (%)Sodium Carbonate 497-19-8 30 - 60Sodium hydroxide 1310-73-2 10-30

sodium chloride 7647-14-5 5-10disodium metasilicate 6834-92-06 5-10Sadium dichlare-s-triazinetrione dihydrate 51580-86-0 1-5oxirane, methyl-, polymer with oxirane 9003-11-56 Feb ce

Product AT USE DILUTION

No hazardous ingredients

| SECTION 4. FIRST AID MEASURES

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Product AS SOLDIn case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at

least 15 minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Get medical attention immediately.

ALSO

In case of skin contact Wash off immediately with plenty of water for at least 15 minutes. Use

a mild soap if available. Wash clothing before reuse. Thoroughly cleanshoes before reuse, Get medical attention immediately.

2130000,

Es

E If swallowed > Rinse mouth with water. Do NOT induce vomiting. Never givea anything by mauth to an unconscious person. Get medical attention

immediately.

If inhaled : Removeto fresh air, Treat symptomatically. Get medical attention ifsymptoms occur.

Protection offirst-aiders : If potential for exposure exists refer to Section 8 for specific personalprotective equipment.

Notes to physician | Treat symptomatically.

Most important symptoms | See Section 11 for more detailed information on health effects andand effects, both acute and symptoms,delayed

Product AT USE DILUTIONIn case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at

least 15 minutes. Remove contact lenses, if present and easy to do.Continue rinsing. Get medical attention immediately.

In case of skin contact . Wash off immediately with plenty of water for at least 15 minutes. Usea mild soapif available. Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never giveanything by mouth to an unconscious person. Get medical attentionimmediately,

If inhaled : Removeto fresh air. Treat symptomatically. Get medical attention ifsymptoms occur.

| SECTION 5. FIRE-FIGHTING MEASURES

Product AS SOLD

Suitable extinguishing media : Use extinguishing measures that are appropriate to localcircumslances and the surrounding environment.

Unsuitable extinguishing : None known.media

Specific hazards during fire : Not flammable or combustible, -fighting

Hazardous combustion : Decomposition products may include the following materials:products Carbon oxides

Nitrogen oxides (NOx)

Oxides of phosphorus

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Special protective equipment : Use personal protective equipment.forfire-fighters

Specific extinguishing | Fire residues and contaminatedfire extinguishing water must bemethods disposed of inawith local regulations. In the event offire

and/or explosión do not breathe fumes,

| SECTION 6. ACCIDENTAL RELEASE MEASURES !

Product AS SOLDPersonal precautions, >» Ensure adequate ventilation. Keep people away fram and upwind ofprotective equipment and spillleak. Avoid inhalation, ingestion and contact with skin and ayes.emergency procedures When workers are facing concentrations above the exposurelimit they

must use appropriate certified respirators. Ensure clean-up is

conducted by trained personnel only. Refer to protective measureslisted in sections 7 and 8.

"= ‘ronmental precautions > Do not allow contact with soil, surface or ground water,

ads and materials for > Sweep up and shovel into suitable containers for disposal.containment and cleaning up

Product AT USE DILUTION

Personal precautions, : Ensure adequate Ventilation. Keep people away from and upwind ofprotective equipment and spillleak. Avoid inhalation, Ingestion and contact with skin and eyes.emergency procedures When workers are facing concentrations above the exposure limit they

Must use appropriate certified respirators. Ensure clean-up isconducted by trained personnel only. Refer to protective measureslisted in sections 7 and 8.

Envircamental precautions : De not allow contact with soil, surface or ground water.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous

earth, vermiculite) and place in container for disposal according tolocal / national regulations (see section 13). For large spills, dikespilled material or otherwise contain material to ensure runoff does notreach a waterway.

[SECTION 7. HANDLING AND STORAGE

Product AS SOLD

Advice on safe handling : Do not ingest. Do not get in eyes. on skin, or on clothing. Do notbreathe dust! fume/ gas/ mist! vapors/ spray. Use only with adequateventilation. Wash hands thoroughly after handling, Mixing this productwith acid or ammonia releases chlorine gas.

Conditions for safe storage : Do not store near acids. Keep out of reach of children. Store insuitable labeled containers.

Storage temperature : -30 °C to 40°C

Product AT USE DILUTION

Advice on safe handling : De not ingest. Do not get |n eyes, on skin, or on clothing. Do notbreathe dust fume! gas! mist/ vapors/ spray. Use only with adequateventilation. Wash hands thoroughly after handling. Mixing this productwith acid or ammonia releases chlorine gas.

Conditions for safe storage . Do not store near acids. Keep out of reach of children, Store in

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suitable labeled containers.

[SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Product AS SOLDIngredients with workplace control parameters

Components CAS-No. Form of Permissible Basisexposure concentration

sodium hydroxide 1310-73-2 Ceiling 2 mgim3 ACGIHCeiling 2 mgim3 NIOSH REL

TWA 2 mama OSHA Z1 Engineering measures

Personal protective equipment

Eye protection

Hand protection

Skin protection

Respiratory protection

Hygiene measures

Product AT USE DILUTIONEngineering measures

Personal protective equipment

Eye protection

Hand protection

Skin protection

Respiratory protection

Effective exhaust ventilation system. Maintain air concentrationsbelow occupational exposure standards.

: Wear eye protection! face protection.

Wearthe following personal protective equipment:Standard glove type.

Gloves should be discarded and replacedif there is any indication ofdegradation or chemical breakthrough.

Personal protective equipment comprising: suitable protective glaves,: safety goggles and protective clothing

: When workers are facing concentrations above the éxposure limit theymust use appropriate certified respirators.

Handle in accordance with good industrial hygiene and safetypractice, Remove and wash contaminated clothing before re-use.

Wash face, hands and any expased skin thoroughly after handling,Provide sultable facilities for quick drenching or flushing of the eyesand body in case of contact or splash hazard.

Effective exhaust ventilation system. Maintain air concentrationsbelow occupational exposure standards,

Wear eye protection! face protection.

: Wearthe following personal protective equipment:Standard glove type.Gloves should be discarded and replacedif there is anyindication ofdegradation or chemical breakthrough.

Personal protective equipment comprising: suitable protective gloves,

safety goggles and protective clothing

When workers are facing concentrations above the exposurelimit theymust Use appropriate certified respirators.

SECTION 9, PHYSICAL AND CHEMICAL PROPERTIES

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Appearance

Color

Odor

pH

Flash point

Odor Threshold

Melting pointreezing paint

Initial boiling point andboiling range

Evaporation rate

Flammability (solid, gas)

Upper explosion limit

Lower explosion limit

Wapor pressure

Reiative vapor densily

Relative density

Water solubility

Solubility in other solvents

Partition coefficient: n-octanol/water

Autoignition temperature

Thermal decomposition

Viscosity, kinematic

Explosive properties

Oxidizing properties

Molecular weight

Yoo

Product AS SOLD Product AT USE DILUTION

powder liquid

tan tan

Chlorine slight

13,0, (1%) 12.5 - 13.4

Not applicable

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data. available Swen SE

No data available

No data available

No data available

No data available

No data available

Ho data available

[SECTION 10. STABILITY AND REACTIVITY

Product AS SOLD

Chemical stability

Passibility of hazardousreactions

Conditions to avoid

Incompatible materials

Hazardous decompositionproducts

Stable under normal candjtions.

Mixing this product with acid or ammonia releases chlorine gas.

None known.

> Acids

Metals

In case offire hazardous decomposition products may be producedsuch as:Carbon oxidesNitrogen oxides (NOx)

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Oxides of phosphorus

BED20000L0SO

0-00

5E

[ SECTION 11, TOXICOLOGICAL INFORMATION

Information on likely roules ofexposure

Potential Health Effects

Product AS SOLDEyes

Skin

Ingestion

Inhalation

Chronic Exposure

Product AT USE DILUTIONEyes

Skin

Ingestion

Inhalation

Chronic Exposure

Inhalation, Eye contact, Skin contact

: Causes serious eye damage.

Causes severe skin burns.

Causes digestive tract bums.

May cause nose, throat, and lund irritation.

Health injuries are not known or expected under notmal use.

: Causes serious eye damage.

: Causes severe skin burns.

Causes digestive tract burns.

May cause nose, throat, and lungirritation,

Health injuries are not known or expected under normal use:

Experience with human exposure

Product AS SOLDEye contact

Skin contact

Ingestion

Inhalation

Product AT USE DILUTIONEye contact

Skin contact

Ingestion

Inhalation

Toxicity

Product AS SOLDProduct

Acute oral toxicity

Acute inhalalion toxicity

Redness, Pain, Corrosion

Redness, Pain, Corrosion

Corrosion, Abdominal pain

Respiratoryirritation, Cough

Redness, Pain, Corrosion

Redness, Pain, Corrasion

Corrosion, Abdominal pain

Respiratory irritation, Gough

| Acute toxicity estimate : 2,754 mg/kg

. 4h Acute toxicity estimate : 144.23 mg/lTest atmosphere: dust/mist

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Acute dermal toxieity

Skin corrosion/irrilation

Serious eye damageleyeirritation

Respiratory or skinsensitization

Carcinogenicity

Reproductive effects

Germ cell mutagenicity

Teratogenicity

STOT-single exposure

STOT-repeated exposure

Aspiration toxicity

Components

Acute dermal toxicity

No data available

No data available +

Na data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

sodium chloride

LDS0 Rabbit: > 10,000 mg/kg

Sodium dichloro-s+triazinetrione dihydrateLD50 Rat: > 5,000 mg/kg

| SECTION 12. ECOLOGICAL INFORMATION

Product AS SOLDEcotoxicity

Environmental Effects

Product

Toxicity to fish

Toxicity to daphnia and otheraquatic invertebrates

Toxicity to algae

Components

Toxicity to fish

Components

Toxicity ta daphnia and other

aquatic invertebrates

Toxic to aquatic life.

No data available

No data available

No data available

Sodium Carbonate

96 h LCS0 Lepomis macrochirus (Bluegill sunfish): 300 mg/l

sodium chloride

86 h LCSG Fish: 5,840 mgd

disodium metasilicate .96 h LC50 Fish: 210 mall

oxirane, methyl-, polymer with oxirane96 h LC50 Fish: > 100 img!

Sodium Carbonate |" 48h EC5O Geriodaphnia (water flea): 213.5 mg/l

Sodium hydroxide

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48 h EC50: 40 mgll

Sodium dichloro-s-triazinetrione dihydrate48 h EC50 Daphnia: 0.196 mail

Persistence and degradability

Product AS SOLD

Readily biodegradable,

Preduct AT USE DILUTIONReadily biodegradable.

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

| SECTION 13. DISPOSAL CONSIDERATIONS

Product AS SOLDDisposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to dispasal orincineration. If recycling is not practicable, dispase of in compliancewith local regulations. Dispose of wastes in an approved waste

disposal facility.

Disposal considerations > Dispose of as unused product, Empty containers should be taken toan approved waste handling site for recycling or disposal. Do not re-use empty conlainers. Dispose of in accordance with local, state, andfederal requlations.

Product AT USE DILUTIONDisposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal orincineration, If recycling is not practicable, dispose of in compliancewith local regulations. Dispose of wastes in an approved wastedisposalfacility.

Disposal considerations : Dispose of as unused product, Empty containers should be taken toan approved waste handling site for recycling or disposal, Do not re-use emply containers. Dispose of in accordance with local, state, andfederal regulations.

[SECTION 14. TRANSPORT INFORMATION

Product AS SOLD

The shipper/consignor/senderis responsible to ensure that the packaging, labeling, and markings arein compliance with the selected mode of transport.

Land transport (DOT)

UN number : 3262

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Description of the goods

Glass

Packing group

Environmentally hazardous

Sea transport (IMDG/IMO)

UN numberDescription of the goods

ClassPacking groupMarine pollutant

Corrosive solid, basic, inorganic, n.o.s.

(sodium hydroxide}

8

il

no

3262CORROSIVE SOLID, BASIC, INORGANIC, N.O.S;

{sodium hydroxide): 6

Ulho

| SECTION 15. REGULATORY INFORMATION

Product AS SOLD

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

Camponents CAS-Na, Compenent RQ (lbs) Calculated product RQ(lbs)

Sodium hydroxide 1310-73-2 1000 5000

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

SARA 302

SARA 313

California Prop. 65

> Skin corrosion orirritation

Serious eye damage or ayeinvitation

This material does not contain any components with a section 302EHS TFQ.

: This material does not contain any chemical components with knownCAS numbers that exceed the threshold (De Minimis) reporting levelsestablished by SARATitle |||, Section 313.

This product does not contain any chemicals known to the State of California to cause cancer, birth, orany other reproductive defects.

The ingredients of this product are reported in the following Inventories:

United States TSCA Inventory :

On the inventory, or in compliance with the inventory

Canadian Domestic Substances List (DSL):All components of this product are on (he Canadian DSL

Australia Inventory of Chemical Substances (AICS):

Onthe inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances :On the inventory, or in compliance with the inventory

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Japan. ENCS - Existing and New Chemical Substances Inventory |On the inventory, or in compliance with the inventory

Korea. Korean Existing Chemicals Inventory (KECI) :On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (FICCS) :Onthe inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC}:On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI):not determined

[SECTION 16. OTHER INFORMATION

Product AS SOLD

NFPA: HMIS Ill:Flammability

HEALTH

5 = FLAMMABILITY= =

| PHYSICAL HAZARD 0

o 0 = not significant. 1 =Slight.

Special hazard. 2 = Moderate, 3 = High4 Exireme, *= Chronic

Product AT USE DILUTION

NFPA: HMISIll:Flammability .

HEALTH

E 3 ; := E FLAMMABILITY=z =

=PHYSICAL HAZARD 0

D <= not significant, 4 =Slighl,Special harard, 2 = Moderate, 3 = High

4 = Extreme, * = Chronic

Issuing date : 04/01/2019Version 1 1.2Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health informationfor this revision isindicated by a barin the left-hand margin of the SDS.

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of ts publication, The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and is

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not to be considered a warranty or qualily specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, Unless specified in the text,

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