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(( ة ي ش غ لا ة ري ص ب ل ص ا ئ صا خ ل ا دراسةZnO ( ت ل ا وب ك ل ا ب ة وي ش م ل وا ة وي ش م ل ر ا ي غZnO:Co ) ادي ي ت علا ا وي ج ل ط ا غ ض ل د ا ي غ ي ئ ا ي م ي ك ل ا اري خ ب ل ا ب ي س ر لي ا ة ي تB ق ت دام خ ت س ا ب( APCVD ) ور ض ب م ر ئ ا ار ب ي م ي س ي ق ل اع ا ز ه دوري لاح ق ص د.V اء ب ر ي ف ل م ا س قV- ة ي^ ب ر لي ا ة ي ل ك ة – ري ص بB ست م ل عة ا ام خ ل ا لاصة خ ل ا(( ة ي V ش غ لا ة ريV ص ب ل ص ا ئ اV ص خ ل ا ةV ودراسV ر ي V ض خ ت ب ح ب ل ا ا دV ه ي ف م تZnO ة وي V ش م ل وا ة وي V ش م ل ر ا ي V غ( ت ل ا V وب ك ل ا بZnO:Co ) ( ة V ي ب ور بV ش ن ب و% 1,3,5,7 اري V خ ب ل ا ب يV س ر لي ا ة V ي تB ق ت دام خ تV س ا ب) ادي V ي ت علا ا وي V ج ل ط ا غ V ض ل د ا V ي غ ي ئ ا V ي م ي ك ل ا( APCVD ) ( ي ل اB ةw ي حV س م ة V ي ج ا ج د رV واع ق ي عل400 .) ن ملV ك انV ص ق ت و ة V ي اد ق ن ل ا ادة V ب ر ج ت ا V يw لت ا رتV ه ظ ا رة V خص م ل ا ة ي V ش غ لا ل ة ريV ص ب ل ص ا ئ اV ص خ ل ا بV س در ة Vلطاق ا وة V ج ف ي ف ادة V ب ر اV م ي ب, ت ي و V ش لن ا ة يV ش ن و ي ج وV م ل ول اV لط ا ادة V ب ر عV م ة يV س كا ع تلا وا ة يV ص صا ب ملا ا. ت ي و V ش لن ا ة يV ش ن ادة V ب ع رV م ة ريV ص ب ل ا ة V ي اد ق ن ل ل ا V ي م ة ريV ص ب ل واص ا V ج ل ا ص غ ت م ي ق ب يV ش ج لك دV وك اصV ص ب ملا ل ا م عا م ل و ز لع ا ت ي ا وب ود م خ ل ل ا م عا م سار و ك بلا ل ا م عا م ة و ي س عكا تلا ة وا ي ص صا ب ملا وا( ن م مدي ل300 - 800 nm ) Abstract

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((ZnO (ZnO:Co) (APCVD)

. - ((ZnO (ZnO:Co) (% 1,3,5,7) (APCVD) (400 ). , . (300-800 nm)

Abstract In this research , undoped ZnO and doped with Cobalte ZnO:Co with different weight percentages of (1, 3, 5,7 )% have been prepared on pre-heated glass substrates up to (400 using atmospheric pressure chemical vapor deposition (APCVD) technique. The optical properties of the samples by using UV-VIS spectroscopy have been investigated. The result showed that transmittance increase and both reflectance and absorbance decrease with an increase in wavelength and doping concentration, while the optical optical energy gap increases with increasing doping concentration also Calculate same optical properties such as Transmittanace,absorpance,reflectance,refractive index,extinction coefficient ,dielectric constant ,absorption coefficient in the wavelength (300-800 nm)

: ZnO (Eg ~3.3 eV) . , [1-4] , [1] . ZnO (Co,Cu, In,Mn Fe, Al,Sb) [7] [1,6-8] . ZnO Co APCVD : ZnO Co (1) Zn(CH3COO)2.2H2O]] (99.9% ) . (5g) . (4000C) , ( ). , ( ) (l/min1) . (min 15)

(ZnO) :

.

.

g gPercentage

5.000.000

4.950.051%

4.850.153%

4.750.255%

4.650.357%

: (2) (R ) ( ) (ZnO:Co), %3 . (A) (3) . (4) , 3% [8]. () [9]: = ln (1/T)/t ---------- (1) t . (5) , )nm380-370) ( cm-1 104) [10] . Eg . [ 9 ]:h = B(h Eg)r ---------- (2) r , h B . 2(h ) E eV) ) (6) Eg (1) 3% [11-13] . (k) [9] : (3) ---------- , . (7) , k . [17,18,19]:

---------- (4) ---------- (5) ---------- (6) (8 10) .[ 14-16] .

:

1- ZnO ZnO:Co 2-

References [1] J. M.Bian, X. M. Li, C. Y. Zhang, W. D. Yu, X. D. Gao, Effect of Different Substrate Temperature on Sb-Doped ZnO Thin Films Prepared by Pulsed Laser Deposition on Sapphire Substrates . Chin. Phys. Lett.. 27, 1. (2010)623-627.[2] Y. Liu and M. Liu, Ordered ZnO nanorods synthesized by combustion chemical vapor deposition, Journal of Nanoscience andNanotechnology, 7( 12) ,( 2007) 45294533.[3] S. Dixit, A. Srivastava, A. Srivastava, and R. K. Shukla, Sol-gel derived zinc oxide films and their sensitivity to humidity, Japanese Journal of Applied Physics, 47( 7) (2008)5613 5618.[4] L. P. Schuler, M. M. Alkaisi, P. Miller, and R. J. Reeves, UV sensing using surface acoustic wave device on DC sputtered ZnO monolayer,Microelectronic Engineering, 83( 49)( 2006) 14031406. [5] P. Nunes, E. Fortunato, A. Lopes, and R.Martins, Influence of the deposition conditions on the gas sensitivity of zinc oxide thin films deposited by spray pyrolysis, International Journal of Inorganic Materials, 3( 8) (2001) 11291131., [6] P. P. Sahay and R. K. Nath, Al-doped ZnO thin films as methanol sensors, Sensors and Actuators B, 134(2) (2008) 654659.[7] D. F. Paraguay, M. Miki-Yoshida, J. Morales, J. Solis, and L.W. Estrada, Influence of Al, In, Cu, Fe and Sn dopants on the response of thin film ZnO gas sensor to ethanol vapour, Thin Solid Films, 373( 1-2)(2000) 137140.[8] M. Nirmala, A. Anukaliani," Structural and optical properties of an undoped and Mn doped ZnO nanocrysatlline thin film", PHOTONICS LETTERS OF POLAND, VOL. 2 (4) (2010)189-191 [9] S. Ilican, Y. Caglar, M. Caglar and F. Yakuphanoglu, "Structural, optical and electrical properties of F-doped ZnO nanorod semiconductor thin films deposited by sol-gel process", Applied Surface Science, 255 (2008) 2353-2359[10] J. Tauc,"Amorphous and Liquid Semiconductors", Plenum Press, London, (1974).[11] A.S. Menon, N. Kalarikkal and S.Thomas,"Studies On structural and optical properties of ZnO and Mn-doped ZnO nanopowders", Indian Journal of Nanoscience, 1 (2) (2013)16-24.[12] K.rekha,M.Nirmala,G.Manjula and A.Anukaliani," Structural, optical,photocatalytic and antibacterial activity of zinc oxide and manganese doped zinc oxide nanoparticles", Physica B. Physics of Condensed Matter,405(15)(2010)3180-3185. [13] G.Sharma,P. Chawla,S.Lochab and N.Singh ,"Burstein Moss effect in nanocrystalline CaS:Ce",Bull Mater. Sci.34(4)(2011)673-676.[14] Z. T. K. AL-Magmaee, Design and Fabrication Nanostructures growth of (ZnO:Fe) Compound by APCVD Technique and Study Some Physical Properties and Deposition Parameters," Ph .D Thesis, University of Baghdad,(2011). [15] K. Aurangzb Synthesis, Characterization and Luminescence Properties of Znic Oxide Nanostructures Ph.D Dissertation, The College of Arts and Science, Ohio University, (2006).[16] K. Kongjai, S. Choopun, N. Hongsith and A. Gardchareon, Zinc Oxide Whiskers by Thermal Oxidation Method,J. Chiang Mai J. Sci, 38(1) (2011) 39-46.

" " 29 . 16(2011) [17][18] E.Cetinorgu S: Gold smith yurosenbrg R.L.Boxman influences of annealing on the physical properties of filtered vacuum are deposited in the oxide thin film ''journal of non-crystalline solids vol.353 pp.25 5- 2602 2007. [19] K.Matras-Postolek" University of Applied Sciences Department of Chemical Engineering Steinfurt/Muenster " (2009).

(2) (3)

(4) (5)

(6) (h)2 ((ZnO (ZnO:Co) (% 1,3,5,7)

(7) (8)

(9) (10)

(1) pure%1%3%5%7

Eg eV3.243.293.3153.273.28