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STEEL quakerchem.com | [email protected] ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOL QUINTOLUBRIC® 888-46 THE SOLUTION CHALLENGES » A Thailand steel producer had a fire incident in the Electric Arc Furnace (EAF) process of their long products manufacturing » The fire incident occurred due to metal sparks igniting mineral oil that leaked and accumulated to form a pool » The steel producer was looking for a hydraulic fluid that had a reduced instance of fire propagation and severity compared to mineral oil © 2017 Quaker Chemical Corporation. All Rights Reserved. » In any steel making process involving heavy equipment and liquid or red hot steel, fire hazards exist when using mineral oil in the hydraulic system » Mineral oil presents a fire risk due to its relative low auto ignition temperature and a low specific heat and high heat of combustion » Quaker Chemical Corporation (‘Quaker’) suggested the steel producer convert to QUINTOLUBRIC® 888-46, HFD-U hydraulic fluid, due to its increased auto ignition point and heat of combustion compared to mineral oil PROPERTY MINERAL OIL QUINTOLUBRIC® 888-46 HFD-U Auto Ignition Point 300°C | 572°F 460°C | 860°F Specific Heat 1.7-1.8 J/gK 2.06 J/gK Heat of Combustion 43 KJ/g 38 KJ/g The chart above shows: » The auto ignition point indicates when a fluid can self-ignite for mineral oil this point is much lower than that of QUINTOLUBRIC® 888-46, 300°C vs 460°C (572°F vs. 860°F) » Specific heat is the amount of energy needed to heat 1g fluid 1°K. The above shows that you need 10- 15% more energy to heat QUINTOLUBRIC® 888-46 compared to mineral oil, making the mineral oil more flammable. In combination with the auto ignition point, this means that it takes exponentially more energy to get the pool temperature over the critical ignition temperature when using QUINTOLUBRIC® 888-46 » The heat of combustion of a mineral oil based hydraulic fluid is typically about 43-44 kJ/g, whereas QUINTOLUBRIC® has a heat of combustion of about 38 kJ/g. Which means burning QUINTOLUBRIC® generates 10- 15% less energy during combustion, making it less likely to propagate » Combining all the points together, compared to QUINTOLUBRIC® 888-46, mineral oil releases more energy while burning, requires less energy to heat, and has a lower auto-ignition point. Making it possible for the mineral oil to continue to burn and propagate increasing fire hazards in the working environment

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Page 1: ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOL€¦ · ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOL QUINTOLUBRIC® 888-46 THE SOLUTION CHALLENGES » A Thailand steel producer

STEEL

quakerchem.com | [email protected]

ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOLQUINTOLUBRIC® 888-46

THE SOLUTION

CHALLENGES » A Thailand steel producer

had a fire incident in the Electric Arc Furnace (EAF) process of their long products manufacturing

» The fire incident occurred due to metal sparks igniting mineral oil that leaked and accumulated to form a pool

» The steel producer was looking for a hydraulic fluid that had a reduced instance of fire propagation and severity compared to mineral oil

© 2017 Quaker Chemical Corporation. All Rights Reserved.

» In any steel making process involving heavy equipment and liquid or red hot steel, fire hazards exist when using mineral oil in the hydraulic system

» Mineral oil presents a fire risk due to its relative low auto ignition temperature and a low specific heat and high heat of combustion

» Quaker Chemical Corporation (‘Quaker’) suggested the steel producer convert to QUINTOLUBRIC® 888-46, HFD-U hydraulic fluid, due to its increased auto ignition point and heat of combustion compared to mineral oil

PROPERTY MINERAL OIL QUINTOLUBRIC® 888-46 HFD-U

Auto Ignition Point 300°C | 572°F 460°C | 860°F

Specific Heat 1.7-1.8 J/gK 2.06 J/gK

Heat of Combustion 43 KJ/g 38 KJ/g

The chart above shows:

» The auto ignition point indicates when a fluid can self-ignite for mineral oil this point is much lower than that of QUINTOLUBRIC® 888-46, 300°C vs 460°C (572°F vs. 860°F)

» Specific heat is the amount of energy needed to heat 1g fluid 1°K. The above shows that you need 10-15% more energy to heat QUINTOLUBRIC® 888-46 compared to mineral oil, making the mineral oil more flammable. In combination with the auto ignition point, this means that it takes exponentially more energy to get the pool temperature over the critical ignition temperature when using QUINTOLUBRIC® 888-46

» The heat of combustion of a mineral oil based hydraulic fluid is typically about 43-44 kJ/g, whereas QUINTOLUBRIC® has a heat of combustion of about 38 kJ/g. Which means burning QUINTOLUBRIC® generates 10- 15% less energy during combustion, making it less likely to propagate

» Combining all the points together, compared to QUINTOLUBRIC® 888-46, mineral oil releases more energy while burning, requires less energy to heat, and has a lower auto-ignition point. Making it possible for the mineral oil to continue to burn and propagate increasing fire hazards in the working environment

Page 2: ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOL€¦ · ELECTRIC ARC FURNACE - AVOIDING AN OIL FIRE POOL QUINTOLUBRIC® 888-46 THE SOLUTION CHALLENGES » A Thailand steel producer

STEEL

quakerchem.com | [email protected]

10.17-V001 - EN© 2017 Quaker Chemical Corporation. All Rights Reserved.

THE PRODUCT

QUINTOLUBRIC® 888-46 was designed to replace anti-wear, mineral oil-based hydraulic fluids used in applications where fire hazards exist. QUINTOLUBRIC® 888-46 can also be used in environmentally sensitive hydraulic applications without compromising the overall hydraulic system operations. This fluid does not contain water, mineral oil, or phosphate ester, and is based on high-quality, synthetic, organic esters and carefully selected additives to achieve excellent hydraulic fluid performance. QUINTOLUBRIC® 888- 46 offers the lubrication level of premium, anti-wear hydraulic oils, and can be used with hydraulic components from all major manufacturers.

THE EXPERTISE

Quaker was the first company to offer HFD-U fluids and has been the market leader in this type of technology. Quaker’s current HFD-U fluids are based on both synthetic organic compounds and naturally occurring esters. QUINTOLUBRIC® 888 Series synthetic polyol esters are industry leaders in ester based technology. Quaker HFD-U fluids are readily biodegradable and have low aquatic toxicity, making them ideal for use where environmental protection is required. Quaker HFD-U fluids are globally available and give outstanding performance in fire resistance, lubrication and long service life. Fluids with the highest performance without compromise. Fluids that sharpen your competitive edge.

ELECTRIC ARC FURNACE - AVOIDING AN OIL FIREQUINTOLUBRIC® 888-46